the pu technology platform for sound attenuation library/a... · the pu technology platform for...
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Johan Peters, Automotive Product manager Johan Peters, Automotive Product manager AcousticsAcousticsDr. Chris Skinner, Automotive Platform managerDr. Chris Skinner, Automotive Platform managerVDI conference Bad Neuenahr, 24 VDI conference Bad Neuenahr, 24 25/01/200725/01/2007
The PU technology platform for sound attenuation The PU technology platform for sound attenuation in automotive applications.in automotive applications.
VDI conference Bad Neuenahr, 2007VDI conference Bad Neuenahr, 2007
Polyurethanes
Huntsman Polyurethanes & European Automotive market trendsHuntsman Polyurethanes & European Automotive market trends
Moulded applications : Undercarpet & bulkhead Moulded applications : Undercarpet & bulkhead
What are the trends in this market segmentWhat are the trends in this market segmentHow does a PU supplier innovate within this environment : How does a PU supplier innovate within this environment :
Example : Acoustiflex VEF+Example : Acoustiflex VEF+
Thermoforming applications : Engine bay & Thermoforming applications : Engine bay & rooflinersroofliners
ACOUSTIFLEXACOUSTIFLEX®® AbsorbersAbsorbers
How morphology drives performanceHow morphology drives performance
Manufacturing of ACOUSTIFLEXManufacturing of ACOUSTIFLEX®® materialsmaterials
ACOUSTIFLEXACOUSTIFLEX®® S, R & FS, R & FAcoustic characteristics & performanceAcoustic characteristics & performance
Physical property setPhysical property set
ConclusionsConclusions
Overview of presentationOverview of presentation
VDI conference Bad Neuenahr, 2007
Polyurethanes
Who is Huntsman?Who is Huntsman?The Huntsman growth storyThe Huntsman growth story
Huntsman has been a leader in the consolidation of the global chHuntsman has been a leader in the consolidation of the global chemical industryemical industry
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1985 1987 1989 1991 1993 1995 1997 1999 2001 2003 2005 PF
Rev
enu
e ($
in B
illio
ns)
Ciba TEC4 Sale
Compounded AnnualGrowth Rate: ~24%
Rexene
Packaging Spinoff
Nova Styrenics Sale
Shell PP
American Hoechst
MonsantoMAn/LAB
Texaco Chemical
TexacoPO/MTBE
Dow Ethyleneamines and Rhodia Surfactants
Vantico
ICI
VDI conference Bad Neuenahr, 2007
Polyurethanes
Differentiated ChemicalsDifferentiated Chemicals
Who is Huntsman?
Mainly differentiated businesses
Materials and Effects
AdvancedMaterials
Design & Composites Engineering
Power & Electronics
Coatings, Construction &
Adhesives
Polyurethanes
Adhesives Coatings
and Elastomers
Automotive
Construction
Compositewood products
Footwear
Furniture
TPU
Pigments
Titanium Dioxide
Performance Products
Performance Specialties
Performance Intermediates
Maleic Anhydride & Licensing
TextileEffects
Apparel
Home textiles
Technical textiles
Base Chemicals and Polymers
EthylenePropylene
CyclohexaneParaxylene
MTBEPolyethylene
PolypropyleneAPAOEPS
Commodity Chemicals
2005 Revenue: $6,164m 2005 Revenue: $8,638m
VDI conference Bad Neuenahr, 2007
HuntsmanHuntsman Polyurethanes & Polyurethanes & thethe European European Automotive Automotive marketmarket trendstrends
Huntsman Polyurethanes CONFIDENTIALVDI conference Bad Neuenahr, 2007
Polyurethanes
EAME Automotive acoustics market: What do we see as the criticalEAME Automotive acoustics market: What do we see as the critical drivers in the drivers in the market impacting polyurethanes ?market impacting polyurethanes ?
Predicted European vehicle build for MPV & SUVCAGR 10.3 % 2004-2009
700
900
1100
1300
1500
1700
1900
2000 2001 2002 2003 2004 2005 2006 2007 2008 2009
Thou
sand
Un
its
0
5
10
15
20
25
30
EAME Market 16.2 16.9 18 19.1 19.5 20.2 20.2 20.2 20.6 21.4 21.6 22.1 23.2 23.9 24.5
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009
M Units
Source : LMC Q4 2004
0
5
10
15
20
25
30
EAME Market 16.2 16.9 18 19.1 19.5 20.2 20.2 20.2 20.6 21.4 21.6 22.1 23.2 23.9 24.5
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009
M Units
Source : LMC Q4 2004
Vehicle build 2004 Vehicle build 2004 2009 CAGR ~2.8% pa2009 CAGR ~2.8% pa
A mature market growing at GDPA mature market growing at GDPOverOver 21 21 millionmillion vehiclesvehicles builtbuilt in EAME in EAME duringduring 20042004
0
5
10
15
20
25
30
EAME Market 16.2 16.9 18 19.1 19.5 20.2 20.2 20.2 20.6 21.4 21.6 22.1 23.2 23.9 24.5
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009
M Units
Source : LMC Q4 2004
0
5
10
15
20
25
30
EAME Market 16.2 16.9 18 19.1 19.5 20.2 20.2 20.2 20.6 21.4 21.6 22.1 23.2 23.9 24.5
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009
M Units
Source : LMC Q4 2004
Vehicle build 2004 Vehicle build 2004 2009 CAGR ~2.8% pa2009 CAGR ~2.8% pa
A mature market growing at GDPA mature market growing at GDPOverOver 21 21 millionmillion vehiclesvehicles builtbuilt in EAME in EAME duringduring 20042004
Total EAME 04-0921,404 24,519CAGR 2.8 %
Emerging Markets 04-095,135 7,282CAGR 7.2 %
West Europe 04-0916,269 17,237CAGR 1.7 %
Total EAME 04-0921,404 24,519CAGR 2.8 %
Emerging Markets 04-095,135 7,282CAGR 7.2 %
West Europe 04-0916,269 17,237CAGR 1.7 %
Total EAME 04-0921,404 24,519CAGR 2.8 %
Emerging Markets 04-095,135 7,282CAGR 7.2 %
West Europe 04-0916,269 17,237CAGR 1.7 %
Europe is running at two speeds Europe is running at two speeds -- emerging markets grow emerging markets grow above industry averageabove industry average
Total EAME 04-0921,404 24,519CAGR 2.8 %
Emerging Markets 04-095,135 7,282CAGR 7.2 %
West Europe 04-0916,269 17,237CAGR 1.7 %
Total EAME 04-0921,404 24,519CAGR 2.8 %
Emerging Markets 04-095,135 7,282CAGR 7.2 %
West Europe 04-0916,269 17,237CAGR 1.7 %
Total EAME 04-0921,404 24,519CAGR 2.8 %
Emerging Markets 04-095,135 7,282CAGR 7.2 %
West Europe 04-0916,269 17,237CAGR 1.7 %
Europe is running at two speeds Europe is running at two speeds -- emerging markets grow emerging markets grow above industry averageabove industry average
Change in kerb mass with time for Golf
500
700
900
1100
1300
1500
1978
1983
1990
1993
1995
2000
2003
year
kg
Consumer demand results in weight and cost Consumer demand results in weight and cost increaseincrease
Source : Automotive engineer Oct 2004 & trade site; Source : Automotive engineer Oct 2004 & trade site; febiacfebiac; Urethanes Technology Oct 2003; Urethanes Technology Oct 2003
17172008200815 (>18kg PU)15 (>18kg PU)20032003
2 2 -- 5519601960% vehicle weight of % vehicle weight of polymerspolymers
Year Year
ref Audi models ref Audi models
Polymers bring innovationPolymers bring innovation
95
100
105
110
115
1997 1998 1999 2000 2001 2002 2003
Cost of living Index Vehicle Selling Price
OEMs struggle to pass costs onOEMs struggle to pass costs on
1996 = 1001996 = 100Change in kerb mass with time for Golf
500
700
900
1100
1300
1500
1978
1983
1990
1993
1995
2000
2003
year
kg
Consumer demand results in weight and cost Consumer demand results in weight and cost increaseincrease
Change in kerb mass with time for Golf
500
700
900
1100
1300
1500
1978
1983
1990
1993
1995
2000
2003
year
kg
Consumer demand results in weight and cost Consumer demand results in weight and cost increaseincrease
Source : Automotive engineer Oct 2004 & trade site; Source : Automotive engineer Oct 2004 & trade site; febiacfebiac; Urethanes Technology Oct 2003; Urethanes Technology Oct 2003
17172008200815 (>18kg PU)15 (>18kg PU)20032003
2 2 -- 5519601960% vehicle weight of % vehicle weight of polymerspolymers
Year Year
ref Audi models ref Audi models
Polymers bring innovationPolymers bring innovation
17172008200815 (>18kg PU)15 (>18kg PU)20032003
2 2 -- 5519601960% vehicle weight of % vehicle weight of polymerspolymers
Year Year
ref Audi models ref Audi models
Polymers bring innovationPolymers bring innovation
95
100
105
110
115
1997 1998 1999 2000 2001 2002 2003
Cost of living Index Vehicle Selling Price
OEMs struggle to pass costs onOEMs struggle to pass costs on
1996 = 1001996 = 100
95
100
105
110
115
1997 1998 1999 2000 2001 2002 2003
Cost of living Index Vehicle Selling Price
OEMs struggle to pass costs onOEMs struggle to pass costs on
95
100
105
110
115
1997 1998 1999 2000 2001 2002 2003
Cost of living Index Vehicle Selling Price
OEMs struggle to pass costs onOEMs struggle to pass costs on
1996 = 1001996 = 100
Mature marketMature market
Differential growth ratesDifferential growth rates
Continuous cost downContinuous cost down
Enhanced comfortEnhanced comfort
Weight reductionWeight reduction
Recycling & ELDRecycling & ELD
Acoustic comfortAcoustic comfort
Weight reductionWeight reduction
VDI conference Bad Neuenahr, 2007
Polyurethanes
Interesting distribution of technologies, some very competitive Interesting distribution of technologies, some very competitive areas with the low areas with the low end under carpet PU foam market being an end under carpet PU foam market being an uglyugly placeplace to beto be ..
Our view of the Our view of the underunder--carpetcarpet market from an OEM market from an OEM perspectiveperspective ..(majority of European EOMs)..(majority of European EOMs)
Key Points:Key Points:-- Increasing cost pressure from OEMsIncreasing cost pressure from OEMs-- Trend away from HR to fibre (cost)Trend away from HR to fibre (cost)-- Some conversion to VEF (German OEMs)Some conversion to VEF (German OEMs)
quality
FibresLower mid downwards
carpet onlycarpet only
highhigh
FibresLower mid downwards
carpet onlycarpet only
VEF
Standard PU Foam
HR
Upper mid upwardsUpper mid upwards(German OEMs)(German OEMs)
Mid sizes
VEF
Standard PU Foam
HR
Upper mid upwardsUpper mid upwards(German OEMs)(German OEMs)
Mid sizes
Perceived quality
Perceived quality
low
high
high
VDI conference Bad Neuenahr, 2007
Polyurethanes
quality
VEF
Standard PU Foam
HR
Fibres
Upper mid upwardsUpper mid upwards(German OEMs)(German OEMs)
Lower mid downwards
carpet onlycarpet only
highhigh
Mid sizes
VEF
Standard PU Foam
HR
Fibres
Upper mid upwardsUpper mid upwards(German OEMs)(German OEMs)
Lower mid downwards
carpet onlycarpet only
Mid sizes
WeWe havehave a a rangerange of of technologiestechnologies to to supportsupport thethe challengeschallenges ourour customerscustomers faceface
VEF Platform (VEF / VEF+)VEF / VEF+)
HR Platform F Platform
Perceived quality
Perceived cost
low
high
high
VDI conference Bad Neuenahr, 2007
VDI conference Bad Neuenahr, 2007
Polyurethanes
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%
Basic LowerMidsize
UpperMidsize
SUV Sports
VEF HR Others
Our view of the relative technology share per segment in theOur view of the relative technology share per segment in theundercarpetundercarpet market. Interesting to see the clear distribution of themarket. Interesting to see the clear distribution of theVEF technology in upper midsizeVEF technology in upper midsize
VDI conference Bad Neuenahr, 2007
VEF
Standard PU FoamHR
Upper mid upwardsUpper mid upwards(German OEMs)(German OEMs)
Mid sizes
VEF
Standard PU FoamHR
Upper mid upwardsUpper mid upwards(German OEMs)(German OEMs)
Mid sizes
Polyurethanes
An example of innovation in the An example of innovation in the undercarpetundercarpet market. Ourmarket. Ourtechnology offers a patented, unique balance of E modulus /technology offers a patented, unique balance of E modulus /hardness and hardness and ....
Emodulus f(CLD)
0.00
50.00
100.00
150.00
200.00
250.00
300.00
2.50 3.50 4.50 5.50 6.50 7.50 8.50
CLD 40 %
E m
od
ulu
s (k
Pa)
Emod VEF Emod VEF+
TL - influence of modulus
0
10
20
30
40
50
60
70
80
315 400 500 630 800 1000 1250 1600 2000 2500 3150
Frequency (Hz)
Db
Influence of Modulus on STL : typical data obtainedInfluence of Modulus on STL : typical data obtainedfrom machine test plates of 20 mm thicknessfrom machine test plates of 20 mm thickness
EmodulusEmodulus as a function of compression hardness : typical dataas a function of compression hardness : typical dataobtained from machine test plates of 20 mm thicknessobtained from machine test plates of 20 mm thickness
65kPa
140kPa
VDI conference Bad Neuenahr, 2007
Polyurethanes
When plotting loss factor as a function of hardnessWhen plotting loss factor as a function of hardness
Loss factorLoss factor ..
VDI conference Bad Neuenahr, 2007
0.20
0.22
0.24
0.26
0.28
0.30
0.32
0.34
0.36
6.00 7.00 8.00 9.00 10.00 11.00 12.00CLD (40%)
loss
fac
tor
loss factor ACOUSTIFLEX VEF
loss factor
Polyurethanes
Interesting to also have a look at emissions, acoustics and Interesting to also have a look at emissions, acoustics and TrittfestigkeitTrittfestigkeit . The properties can be varied to meet a wide . The properties can be varied to meet a wide
range of specsrange of specs
VDI conference Bad Neuenahr, 2007
Acoustiflex VEF+
Density g/l 72
CLD 40% compression kPa 4.9
CLD after hydrolysis % delta 43 % loss
CLD after 7 days 140°C % delta no losscompression set % 9.5
Compression set after 7
days 140°C% 11
Compression set after hydrolysis
% 23
Tensile strength kPa 110Elongation % 108Hysteresis % 21Loss factor 0.40E-Modulus kPa 45 kPa
VOC ppm 65 ppm (typical)FOG ppm 30 ppm (typical)
VDI conference Bad Neuenahr, 2007
Polyurethanes
Morphology closely aligned to fibresMorphology closely aligned to fibres
High sound absorptionHigh sound absorption
No
vel R
igid
PU
Mo
rph
olo
gy
No
vel R
igid
PU
Mo
rph
olo
gy
Th
ermo
form
able
Th
ermo
form
able
Huntsman developed these novel absorbers which deliver high sounHuntsman developed these novel absorbers which deliver high sound absorption d absorption thermoformabilitythermoformability & stiffness using simple production assets& stiffness using simple production assets
Conventional PU Rigid FoamConventional PU Rigid Foam
ACOUSTIFLEX ACOUSTIFLEX ®® acoustic absorberacoustic absorber
Conventional PU Rigid FoamConventional PU Rigid FoamConventional PU Rigid FoamConventional PU Rigid Foam
ACOUSTIFLEX ACOUSTIFLEX ®® acoustic absorberacoustic absorber
The very good acoustic attenuation The very good acoustic attenuation properties of spotproperties of spot--welded fibres are welded fibres are matched at lower density by open matched at lower density by open cell foamscell foamsLow density open Low density open
celled foamcelled foamFibre technologyFibre technology Low density open Low density open
celled foamcelled foamLow density open Low density open celled foamcelled foam
Fibre technologyFibre technologyFibre technologyFibre technology
Rigid material designed to Rigid material designed to be flexible during be flexible during ThermoformingThermoforming
Material beam deflection Material beam deflection lowlow
Same beam material Same beam material with high deflectionwith high deflection
Material beam deflection Material beam deflection lowlow
Same beam material Same beam material with high deflectionwith high deflection
Conventional flexible foam @ Conventional flexible foam @ density 40kg/mdensity 40kg/m33
FibreFibre technology @ density technology @ density 35kg/m35kg/m33
ACOUSTIFLEXACOUSTIFLEX®® technology technology @ density 16kg/m@ density 16kg/m33
Conventional flexible foam @ Conventional flexible foam @ density 40kg/mdensity 40kg/m33
FibreFibre technology @ density technology @ density 35kg/m35kg/m33
ACOUSTIFLEXACOUSTIFLEX®® technology technology @ density 16kg/m@ density 16kg/m33
VDI conference Bad Neuenahr, 2007
Polyurethanes
Clearly the most interesting feature is the morphology of the foClearly the most interesting feature is the morphology of the foam. Using am. Using the technique of xthe technique of x--ray tomography we can show this more clearly:ray tomography we can show this more clearly:
Polyurethanes
The technology provides a platform designed to meet the challengThe technology provides a platform designed to meet the challenge of increased e of increased absorption & reduction in mass across a broad range of applicatiabsorption & reduction in mass across a broad range of applicationsons
VDI conference Bad Neuenahr, 2007
Polyurethanes
The technology is versatile, tunable and competitive The technology is versatile, tunable and competitive against alternative materialsagainst alternative materials
KEY PointsKEY PointsThe technology is superior in acoustics to alternative The technology is superior in acoustics to alternative
technology at significantly lower densitiestechnology at significantly lower densitiesThe economics of the PU foam process on a green field The economics of the PU foam process on a green field
site are again better than site are again better than fibrefibre / felt / PU / felt / PU slabstockslabstockThe technology is extremely tunable (acoustics / fire The technology is extremely tunable (acoustics / fire
resistance / density)resistance / density)
Broad density range possibleBroad density range possibleCapable of meeting a range of fire standardsCapable of meeting a range of fire standardsStiff post thermoforming / fewer fixturesStiff post thermoforming / fewer fixturesExcelllentExcelllent acousticsacoustics
Broad density range possibleBroad density range possibleRange of fire standardsRange of fire standards
ThermoformableThermoformableTunable acousticsTunable acoustics
Broad density range possibleBroad density range possibleCapable of meeting a range of fire standardsCapable of meeting a range of fire standards
Stiff post thermoforming / fewer fixturesStiff post thermoforming / fewer fixturesExcelllentExcelllent acousticsacoustics
Broad density range possibleBroad density range possibleCapable of meeting a range of fire standardsCapable of meeting a range of fire standards
Stiff post thermoforming / fewer fixturesStiff post thermoforming / fewer fixturesExcellent acousticsExcellent acoustics
VDI conference Bad Neuenahr, 2007
Polyurethanes
Making the material is relatively simpleMaking the material is relatively simple ..
Golden BucketGolden Bucket ProcessProcessMax shot independent of cream Max shot independent of cream
Bucket sits on the mould baseBucket sits on the mould base
Chemicals fed into the bucketChemicals fed into the bucket
Stirrer mixes chemicals [~500 to 800 rpm]Stirrer mixes chemicals [~500 to 800 rpm]
Bucket & stirrer assembly liftedBucket & stirrer assembly lifted
Liquid flows to cover base surfaceLiquid flows to cover base surface
Material creams & starts to rise filling mould.Material creams & starts to rise filling mould.
Block Block demouldeddemoulded
Block size & storageBlock size & storageHigh High exothermexotherm processprocessLimited block height Limited block height Not to be stacked on top of each otherNot to be stacked on top of each otherEnvironment for cooling important Environment for cooling important Standing prior to slitting is importantStanding prior to slitting is important
Block is produced (discontinuous process)Block is produced (discontinuous process)
After resting period the block is slit to form foam blanksAfter resting period the block is slit to form foam blanks
Blank is sandwiched between fabric (& Blank is sandwiched between fabric (& glassfibresglassfibres) as required by application) as required by application
Thermoformed in hot pressThermoformed in hot press
Formed composite is cut and packagedFormed composite is cut and packaged
Typical process routeTypical process route
KEY ELEMENTS OF PROCESSKEY ELEMENTS OF PROCESSFollowing the cutting of the block the full absorbance is reachFollowing the cutting of the block the full absorbance is reachededNo additional processes to enhance the acoustic performance of No additional processes to enhance the acoustic performance of
the ACOUSTIFLEXthe ACOUSTIFLEX®® material material are requiredare requiredCapital investment cost is very low to achieve significant voluCapital investment cost is very low to achieve significant volumeme
Schematic of process routeSchematic of process route
Block Machine BBBlock Machine BB3 Stream 3 Stream
Horizontal slitterHorizontal slitterFlat bladeFlat blade
FoamFoamBlanksBlanks
Blank converted (pressed)Blank converted (pressed)tool temp 150 tool temp 150 -- 160 C160 C
~90 bar~90 bar30 30 -- 60 sec60 sec
Fabric & other materials Fabric & other materials (as required)(as required)top & bottom top & bottom
of blankof blank
StorageFoam blockFoam block
Block Machine BBBlock Machine BB3 Stream 3 Stream
StorageStorageHorizontal slitterHorizontal slitter
Flat bladeFlat bladeFoamFoamBlanksBlanks
Blank converted (pressed)Blank converted (pressed)tool temp 150 tool temp 150 -- 160 C160 C
~90 bar~90 bar30 30 -- 60 sec60 sec
Fabric & other materials Fabric & other materials (as required)(as required)top & bottom top & bottom
of blankof blank
StorageFoam blockFoam block
VDI conference Bad Neuenahr, 2007
Polyurethanes
Kundt tube Acoustiflex range - 20mm
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00
100 1000 10000
Frequency (Hz)
Ab
sorp
tio
n c
oef
fici
ent
Acoustiflex R22A
Acoustiflex S18F1
Acoustiflex F16F1
S18F1
R22A
F16F1
What does the acoustic performance look like in an What does the acoustic performance look like in an absorption test ? absorption test ?
VDI conference Bad Neuenahr, 2007
Polyurethanes
System tuning possible across a broad range of featuresSystem tuning possible across a broad range of featuresE.g. Fire resistance, Foam hardness.E.g. Fire resistance, Foam hardness.
VDI conference Bad Neuenahr, 2007
Density kg/m3 16 - 25
CLD 40% - ISO 3386/1 kPa 2.2 - 4.5
Tear strength - ISO 8087 N/m 90 - 130
Tensile strength - ISO 1798 kPa 44 - 50
Elongation - ISO 1798 % 95 - 75
Comp. Set dry 50% Th - ISO 1856 % 38 - 44
FMVSS 302 mm/min 162 - NBR
Polyurethanes
0
10
20
30
40
50
60
70
8016
0
200
250
315
400
500
630
800
1000
1250
1600
2000
2500
3150
4000
5000
Frequency (Hz)
ST
L (
dB
)
moulded HR 60 g/l 20 mm moulded HR 45 g/l ; 20 mm moulded HR 35 g/l ; 20mm
Cost down targets drivenby OEM pressure
Driving down the density as a response to cost Driving down the density as a response to cost pressure, makes the classic mass / decoupler systems pressure, makes the classic mass / decoupler systems have difficulty living up to the specifications, unlesshave difficulty living up to the specifications, unless ..
VDI conference Bad Neuenahr, 2007
Polyurethanes
..we change the way we develop the composite..we change the way we develop the composite
0
10
20
30
40
50
60
70
80
160 200 250 315 400 500 630 800 1000 1250 1600 2000 2500 3150 4000 5000
Frequency (Hz)
ST
L (
dB
)
moulded HR 60 g/l 20 mm moulded HR 45 g/l ; 20 mm
LWA 16 g/l ; 20 mm moulded HR 35 g/l ; 20mm
Soft LWA foam
0
10
20
30
40
50
60
70
80
160 200 250 315 400 500 630 800 1000 1250 1600 2000 2500 3150 4000 5000
Frequency (Hz)
ST
L (
dB
)
moulded HR 60 g/l 20 mm moulded HR 45 g/l ; 20 mm
LWA 20g/l 20 mm moulded HR 35 g/l ; 20mm
Soft LWA foam
VDI conference Bad Neuenahr, 2007
Polyurethanes
Density kg/m3 23 28 33
compression hardness - Iso 844 kPa 70 - 80 90 100
Stiffness - SAE J949 N/m 6 8 11
Tensile strength - Iso 1798 kPa 140 155 180
Elongation - Iso 1798 % 14 - 18 17 - 20 24 - 28
Fogging - DIN 75201 % 92 92 92
Fogging - DIN 75201 mg 0.7 0.7 0.7
FMVSS 302 mm/min 72 - 80 < 70 < 70
VDI conference Bad Neuenahr, 2007
System tuning possible across a broad range of featuresSystem tuning possible across a broad range of featuresE.g. Fire resistance, Foam hardness.E.g. Fire resistance, Foam hardness.
Polyurethanes
-0.10
0.10
0.30
0.50
0.70
0.90
1.10
0 1000 2000 3000 4000 5000 6000
Frequency (Hz)
Abso
rption
Coef
fici
ent
Acoustiflex R 22 industry reference 33 density
KundtKundt tube assessment of standard commercial headliner tube assessment of standard commercial headliner foam versus ACOUSTIFLEXfoam versus ACOUSTIFLEX®® R22 (foam samples)R22 (foam samples)
VDI conference Bad Neuenahr, 2007
Polyurethanes
Probably the best headliners in the world
The materials are also made using the simple batch block The materials are also made using the simple batch block processprocess
LightweightLightweightAcousticAcousticPhenolicPhenolic / amine free/ amine freeThermoformableThermoformableLow Low odourodourConsistent qualityConsistent qualityClean processClean processNo needle punching requiredNo needle punching required
Simple processSimple processRelatively low wasteRelatively low wasteEasy to change systemEasy to change systemLow investment costLow investment cost
VDI conference Bad Neuenahr, 2007
UnderUnder--bonnet & Engine Bay Componentsbonnet & Engine Bay Components
Polyurethanes
Properties range of current systems
Density kg/m3 17 - 19 17 - 19
CLD 40% - ISO 3386/1 kPa 25 - 32 26 - 34
Tensile - ISO 1798 kPa 60 - 70 65 - 77
Elongation - ISO 1798 % 17 - 19 15 - 20
Fogging - DIN 75201 % 86 97
Fogging - DIN 75201 mg 0.8 0.5
FMVSS 302 mm/min 72 - 80 NBR
VDI conference Bad Neuenahr, 2007
Polyurethanes
Kundt tube 20mm. Acoustiflex S versus Felt
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
100 1000 10000
Frequency (Hz)
Abs
orpt
ion
coe
ffic
ient
Acoustiflex S18F1 Dual density fibre Felt 1 - 1000 gr Felt 2 - 1000 gr Felt 3 - 1200 gr
A lightweight solution with excellent sound attenuation A lightweight solution with excellent sound attenuation properties & better low frequency performance vs. properties & better low frequency performance vs. fibrous materialsfibrous materials
VDI conference Bad Neuenahr, 2007
171020Felt 3
20.91045Felt 2
19.2960Felt 1
231840Dual density
20360Acoustiflex S
thickness (mm)
weight / m2type
Polyurethanes
A lightweight solution with excellent sound attenuation A lightweight solution with excellent sound attenuation properties & better low frequency performance vs. properties & better low frequency performance vs. alternative foamsalternative foams ....
VDI conference Bad Neuenahr, 2007
Acoustiflex S vs alternative foams20 mm foam thickness
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
100 1000 10000
Frequency (Hz)
Ab
sorp
tio
n c
oef
fici
ent
Acoustiflex S PU market reference Melamine Foam
Polyurethanes
Conclusions on the technologyConclusions on the technology
No additional steps to acoustic activityNo additional steps to acoustic activity
Simple and clean processingSimple and clean processing
Less work in progress Less work in progress
Deep draw potential (elongation >70%)Deep draw potential (elongation >70%)
Low waste & simple productionLow waste & simple production
ACOUSTIFLEXACOUSTIFLEX®® RR
Excellent acousticsExcellent acoustics
Interesting CLD / E mod ratioInteresting CLD / E mod ratio
Low emissionLow emission
Wide hardness range possibleWide hardness range possible
Good physical propertiesGood physical properties
Fast demould time (<80s)Fast demould time (<80s)
ACOUSTIFLEXACOUSTIFLEX®® SS
VDI conference Bad Neuenahr, 2007
Acoustic comfort and weight reductionAcoustic comfort and weight reduction
ACOUSTIFLEXACOUSTIFLEX®®
Polyurethanes
Conclusions on the technologyConclusions on the technology
No additional steps to acoustic activityNo additional steps to acoustic activity
Simple and clean processingSimple and clean processing
Less work in progress Less work in progress
Deep draw potential (elongation>20%)Deep draw potential (elongation>20%)
High stiffness to allow modular designHigh stiffness to allow modular design
Low waste & simple productionLow waste & simple production
Reduced debris on airbag deploymentReduced debris on airbag deployment
Superior acousticsSuperior acoustics
ACOUSTIFLEXACOUSTIFLEX®® RR
Fire retardant to a range of standardsFire retardant to a range of standards
Cost competitive Cost competitive vsvs felt felt
Simple and clean processingSimple and clean processing
Not friableNot friable
Deep draw potentialDeep draw potential
Low waste & simple productionLow waste & simple production
Self supporting Self supporting fewer clipsfewer clips
Superior acousticsSuperior acoustics
ACOUSTIFLEXACOUSTIFLEX®® SS
Acoustic comfort and weight reductionAcoustic comfort and weight reduction
ACOUSTIFLEXACOUSTIFLEX®®
VDI conference Bad Neuenahr, 2007
Polyurethanes
While the information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE. In all cases, it is the responsibility of the user to determine the applicability of such information and recommendations and the suitability of any product for its own particular purpose.NOTHING IN THIS PUBLICATION IS TO BE CONSTRUED AS RECOMMENDING THE INFRINGEMENT OF ANY PATENT OR OTHER INTELLECTUAL PROPERTY RIGHT, AND NO LIABILITY ARISING FROM ANY SUCH INFRINGEMENT IS ASSUMED. NOTHING IN THIS PUBLICATION IS TO BE VIEWED AS A LICENCE UNDER ANY INTELLECTUAL PROPERTY RIGHT.Except where explicitly agreed otherwise, the sale of products referred to in this publication is subject to the general terms and conditions of Huntsman International LLC or of its affiliated companies.Huntsman Polyurethanes is an international business unit of Huntsman International LLC. Huntsman Polyurethanes trades through Huntsman affiliated companies in different countries such as HuntsmanInternational LLC in the USA and Huntsman Holland BV in Western Europe.
Advanced ComfortTM & ACOUSTIFLEX® is a registered trademark of Huntsman Corporation or an affiliate thereof in one or more, but not all, countries.Copyright © 2007 Huntsman Corporation or an affiliate thereof. All rights reserved.
Thank you for your attention. Thank you for your attention.
Perceived Perceived qualityquality
VEF
Standard PU Foam
HR
Fibres
PerceivedPerceivedcostcost
Upper mid upwardsUpper mid upwards(German OEMs)(German OEMs)
Lower mid downwards
carpet onlycarpet only
highhigh
highhigh
lowlow
Mid sizes
Perceived Perceived qualityquality
VEF
Standard PU Foam
HR
Fibres
PerceivedPerceivedcostcost
Upper mid upwardsUpper mid upwards(German OEMs)(German OEMs)
Lower mid downwards
carpet onlycarpet only
highhigh
highhigh
lowlow
Mid sizes
VEF Platform (VEF / VEF+)VEF / VEF+)
HR Platform (HR / HR+HR / HR+)F Platform
Perceived Perceived qualityquality
VEF
Standard PU Foam
HR
Fibres
PerceivedPerceivedcostcost
Upper mid upwardsUpper mid upwards(German OEMs)(German OEMs)
Lower mid downwards
carpet onlycarpet only
highhigh
highhigh
lowlow
Mid sizes
Perceived Perceived qualityquality
VEF
Standard PU Foam
HR
Fibres
PerceivedPerceivedcostcost
Upper mid upwardsUpper mid upwards(German OEMs)(German OEMs)
Lower mid downwards
carpet onlycarpet only
highhigh
highhigh
lowlow
Mid sizes
VEF Platform (VEF / VEF+)VEF / VEF+)
HR Platform (HR / HR+HR / HR+)F Platform
My contact details should you have other questions:My contact details should you have other questions:
Johan PetersJohan PetersHuntsman PolyurethanesHuntsman PolyurethanesEverbergEverbergTel: +32 2 758 9332 / Fax : +32 2 758 7332Tel: +32 2 758 9332 / Fax : +32 2 758 [email protected][email protected]
VDI conference Bad Neuenahr, 2007