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The Geological and Cultural Significance of Impact Melt Nodules from Lake Mistastin in Northern Labrador Tania Evans 1 , Cari Corrigan 2 , Stephen Loring 2 University of Maryland, Baltimore County 1 , Smithsonian Institution 2 After a meteorite collides with the ground, intense shock waves and extremely high temperatures are produced, resulting in the melting of the target rock. This cools to form a very glassy rock, referred to as impact melt. Lake Mistasin in Northern Labrador is a meteorite impact site and a significant location for the native Innu. Before the impact, the rocks at this location were anorthosites and granodiorites. The impact melt from this site is an obsidian-like, black, shiny material, which looks very similar to the lithic raw material that have been found in several parts of North America. Our goal is to characterize the impact melt in order to determine if recovered stone tools originate from the Mistastin region. The ability to determine an artifact’s origin can provide valuable insight into cultural exchange and trading practices. Background Methodology Among multiple specimens, we chose two for analysis. Cut each rock in half, then cut a 30 micron thin section from each sample. The remainder of the rock was polished to make a thick section. Used a FEI Nova NanoSEM 600 (with <5% deadtime and a 15 KV electron beam) to take backscattered electron images (BSE) and perform energy dispersive spectroscopy (EDS) elemental analysis. Used Noran System Six software to process the images and data. Results For over 8000 years, Innu living in Labrador used a variety of different stones from which they shaped the tools necessary for their survival. The discovery, identification and interpretation of the impact melt from Lake Mistastin sheds new light on the on the events of a meteorite impact ~38 million years ago and documents a unique lithic raw material that was sought by Innu ancestors to fashion the tools they needed for survival. By “fingerprinting” the Mistastin impact melt it will be possible to distinguish it from other look alike raw materials (especially obsidians from the western U.S.) and contribute to a better understanding of the ancient systems of trade/interaction that linked ancient peoples across North America. Knowing the origin of the stone that was used to make tools provides clues to former settlement as well as economic and exchange systems. Acknowledgements: Special thank you to the NSF, the Smithsonian Women’s Committee, Tim Gooding, Tim McCoy, Elizabeth Cottrell, Gene Hunt, and Virginia Power. Diagram of meteorite impact site (B. French 1998) Mistastin Lake impact site (B. French 1998) Thin Section Thick Section Samples taken from Mistastin Lake. Samples chosen for analysis are circled. As first steps, bulk glass was measured separately from inclusions. Future work will include determining the overall bulk composition of the entire assemblage and the structure of the silica inclusions. These will be done using the electron microprobe as well as other techniques possibly to include electron microprobe, X- ray Fluorescence and X-ray Diffraction. Future Work Mosaic backscattered electron images of a thin section (left) and a thick section (right), produced using a scanning electron microscope. Reference Aluminum Mercury Chromium Iron Calcium Potassium Magnesium Manganese Sodium Oxygen Silicon Tantalum Titanium Thallium Na2O 2% Al2O3 6% SiO2 23% CaO 7% FeO 36% SnO2 26% Na2O 1% Al2O3 1% SiO2 98% Discussion/Implications Na2O 2% Al2O3 11% SiO2 43% CaO 17% TiO2 4% FeO 23% Elemental maps (left) and greyscale backscattered electron image (above). Produced using SEM, electron beam 15 kV, spot size 4.5. Oxide Weight Percentages in Glass (%) Oxide Na 2 O MgO Al 2 O 3 SiO 2 K 2 O CaO TiO 2 MnO FeO HgO Tl 2 O 3 Ta 2 O 5 Weight Percent 5.6 ± 0.5 0.8 ± 0.2 21.6 ± 2.4 53.3 ± 4.4 2.1 ± 0.1 8.4 ± 0.6 1.3 ± 0.1 0.1 ± 0.0 6.7 ± 0.4 0.1 ± 0.0 0.1 ± 0.1 0.12±0.11 Elemental Weight Percentages in Glass Element O Na Mg Al Si K Ca Ti Mn Fe Hg Tl Weight Percent 44.4 ± 6.1 3.9 ± 0.3 0.5 ± 0.1 10.2 ± 1.3 28.8 ± 3.0 2.0 ± 0.3 5.3 ± 1.0 0.7 ± 0.2 0.01 ± 0.0 4.04 ± 1.6 0.0 ± 0.0 0.0 ± 0.0 500 microns 5.58 0.77 21.59 53.29 2.12 8.38 1.34 0.08 6.66 0.02 0.06 0.11 -5.00 5.00 15.00 25.00 35.00 45.00 55.00 Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO FeO HgO Tl2O3 Ta2O5 Weight Percent (%) Bulk Glass Composition The glass bulk composition is similar to that found in literature (Marion, 2010 and Pickersgill, 2015). However, the textures were slightly different, as ours was more glassy and had fewer crystals. References: French BM (1998) Traces of catastrophe – a handbook of shock-metamorphic effects in terrestrial meteorite impact structures. Lunar Planet Ins Contr 954, Lunar and Planetary Institute Loring (2009) Chance Favors the Prepared Mind: The Identification of a New Lithic Source from the Interior of Northern Labrador. Provincial Archaeology Office Marion & Sylvester (2010). Composition and heterogeneity of anorthositic impact melt at Mistastin Lake crater, Labrador. Planetary and Space Sciences Pickersgill (2014). Shock effects in plagioclase feldspar from the Mistastin Lake impact structure, Canada. Meteoritics & Planetary Science 100% SiO2 Al2O3 8% SiO2 55% Cl 4% K2O 2% CaO 8% FeO 23% O 70% Cl 30% Na2O 2% MgO 1% Al2O3 7% SiO2 27% CaO 3% FeO 3% SnO2 57% SiO2 12% Cl 88% 100% SiO2 Na2O 5% MgO 1% Al2O3 19% SiO2 58% K2O 2% CaO 8% TiO2 1% FeO 6% Location of the basalt headland where the impact melt was found Arrowheads made from various lithic materials Innu people Arrowheads made from obsidian Amazon.con 5 cm x 2.5 cm 5 cm x 2.5 cm

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Page 1: The Geological and Cultural Significance of Impact Melt ... · • French BM (1998) Traces of catastrophe –a handbook of shock-metamorphic effects in terrestrial meteorite impact

The Geological and Cultural Significance of

Impact Melt Nodules from Lake Mistastin in Northern LabradorTania Evans1, Cari Corrigan2, Stephen Loring2

University of Maryland, Baltimore County1, Smithsonian Institution2

After a meteorite collides with the ground, intense shock waves and extremely high temperatures are produced, resulting in the melting of the target rock. This cools to form a very glassy rock, referred to as impact melt. Lake Mistasin in Northern Labrador is a meteorite impact site and a significant location for the native Innu. Before the impact, the rocks at this location were anorthosites and granodiorites. The impact melt from this site is an obsidian-like, black, shiny material, which looks very similar to the lithic raw material that have been found in several parts of North America. Our goal is to characterize the impact melt in order to determine if recovered stone tools originate from the Mistastin region. The ability to determine an artifact’s origin can provide valuable insight into cultural exchange and trading practices.

Background

Methodology

• Among multiple specimens, we chose two for analysis.

• Cut each rock inhalf, then cut a30 micron thinsection fromeach sample.The remainder ofthe rock waspolished to makea thick section.

• Used a FEI Nova NanoSEM 600 (with <5% deadtimeand a 15 KV electron beam) to take backscatteredelectron images (BSE) and perform energydispersive spectroscopy (EDS) elemental analysis.

• Used Noran System Six software to process the images and data.

Results

For over 8000 years, Innu living in Labrador used a variety of different stones from which they shaped the tools necessary for their survival. The discovery, identification and interpretation of the impact melt from Lake Mistastin sheds new light on the on the events of a meteorite impact ~38 million years ago and documents a unique lithic raw material that was sought by Innu ancestors to fashion the tools they needed for survival.

By “fingerprinting” the Mistastin impact melt it will be possible to distinguish it from other look alike raw materials (especially obsidians from the western U.S.) and contribute to a better understanding of the ancient systems of trade/interaction that linked ancient peoples across North America. Knowing the origin of the stone that was used to make tools provides clues to former settlement as well as economic and exchange systems.

Acknowledgements:

Special thank you to the NSF, the Smithsonian Women’s Committee, Tim

Gooding, Tim McCoy, Elizabeth Cottrell, Gene Hunt, and Virginia Power.

Diagram of meteorite impact site (B. French 1998) Mistastin Lake impact site (B. French 1998)

Thin Section Thick Section

Samples taken from Mistastin Lake. Samples chosen for analysis are circled.

As first steps, bulk glass was measured separately from inclusions. Future work will include determining the overall bulk composition of the entire assemblage and the structure of the silica inclusions. These will be done using the electron microprobe as well as other techniques possibly to include electron microprobe, X-ray Fluorescence and X-ray Diffraction.

Future Work

Mosaic backscattered electron images of a

thin section (left) and a thick section (right),

produced using a scanning electron

microscope.

Reference

Aluminum MercuryChromium IronCalcium Potassium Magnesium

Manganese Sodium Oxygen Silicon Tantalum Titanium Thallium

Na2O2%

Al2O36%

SiO223%

CaO7%

FeO36%

SnO226%

Na2O1%

Al2O31%

SiO298%

Discussion/Implications

Na2O2%

Al2O311%

SiO243%

CaO17%

TiO24%

FeO23%

Elemental maps (left) and greyscale backscattered electron image (above).

Produced using SEM, electron beam 15 kV, spot size 4.5.

Oxide Weight Percentages in Glass (%)

Oxide Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO FeO HgO Tl2O3 Ta2O5

Weight Percent 5.6 ± 0.5 0.8 ± 0.2 21.6 ± 2.4 53.3 ±

4.4

2.1 ± 0.1 8.4 ± 0.6 1.3 ± 0.1 0.1 ± 0.0 6.7 ± 0.4 0.1 ± 0.0 0.1 ± 0.1 0.12±0.11

Elemental Weight Percentages in Glass

Element O Na Mg Al Si K Ca Ti Mn Fe Hg Tl

Weight Percent 44.4 ± 6.1 3.9 ± 0.3 0.5 ± 0.1 10.2 ±

1.3

28.8 ±

3.0

2.0 ± 0.3 5.3 ± 1.0 0.7 ± 0.2 0.01 ±

0.0

4.04 ±

1.6

0.0 ± 0.0 0.0 ± 0.0

500 microns

5.58

0.77

21.59

53.29

2.12

8.38

1.340.08

6.66

0.02 0.06 0.11

-5.00

5.00

15.00

25.00

35.00

45.00

55.00

Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO FeO HgO Tl2O3 Ta2O5

Wei

ght

Pe

rcen

t (%

)

Bulk Glass Composition

The glass bulk composition is similar to that found in literature (Marion, 2010 and Pickersgill, 2015). However, the textures were slightly different, as ours was more glassy and had fewer crystals.

References: • French BM (1998) Traces of catastrophe – a handbook of shock-metamorphic effects in terrestrial

meteorite impact structures. Lunar Planet Ins Contr 954, Lunar and Planetary Institute• Loring (2009) Chance Favors the Prepared Mind: The Identification of a New Lithic Source from the

Interior of Northern Labrador. Provincial Archaeology Office• Marion & Sylvester (2010). Composition and heterogeneity of anorthositic impact melt at Mistastin

Lake crater, Labrador. Planetary and Space Sciences• Pickersgill (2014). Shock effects in plagioclase feldspar from the Mistastin Lake impact structure,

Canada. Meteoritics & Planetary Science

100%SiO2

Al2O38%

SiO255%

Cl4%

K2O2%

CaO8%

FeO23%

O70%

Cl30%

Na2O2%

MgO1% Al2O3

7%

SiO227%

CaO3%FeO

3%

SnO257%

SiO212%

Cl88%

100%

SiO2

Na2O5%

MgO1%

Al2O319%

SiO258%

K2O2%

CaO8%

TiO21%

FeO6%

Location of the basalt headland where the impact melt was found Arrowheads made from various lithic materials

Innu people Arrowheads made from obsidian

Am

azon

.con

5 cm x 2.5 cm 5 cm x 2.5 cm