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Stepan Trade Name INCI Name Actives (%) Form at 25°C Shake Foam without oil (ml)

Shake Foam with oil (ml)

Biorenewable Carbon Index CMC (mg/L)

STEPANOL® WA-EXTRA* Sodium Lauryl Sulfate 29 Liquid 313 225 100 185

STEOL® CS-230* Sodium Laureth Sulfate 26 Liquid 400 370 67 171

ALPHA-STEP® PC-48 Sodium Methyl 2-Sulfolaurate,

Disodium 2-Sulfolaurate 39 Liquid 275 250 94 177

BIO-TERGE® AS-40 Sodium C14-16 Olefin

Sulfonate 39 Liquid 550 350 0 301

LATHANOL® LAL POWDER Sodium Lauryl Sulfoacetate 65 Solid 375 343 86 131

STEPAN-MILD® LSB Sodium Lauryl

Sulfoacetate, Disodium Laureth Sulfosuccinate

25 Liquid 413 373 64 105

STEPAN-MILD® PCL

Sodium Methyl 2-Sulfolaurate,

Disodium 2-Sulfolaurate, Sodium Lauryl Sulfoacetate

23 Liquid 448 430 90 65

Competitive Product Coco-Glucoside 50 Liquid 332 175 NE 30

Competitive Product Disodium Cocoyl

Glutamate, Sodium Cocoyl Glutamate

25 Liquid 125 115 NE 226

Competitive Product Potassium Laureth-1 Phosphate 35 Liquid 257 175 NE 36

Competitive Product Sodium Cocoyl Glycinate 25 Liquid 202 105 NE 334

Competitive Product Sodium Cocoyl Isethionate 80 Solid 275 230 NE 84

Competitive Product Sodium Lauroyl Methyl Isethionate 80 Solid 285 178 NE 104

Competitive Product Sodium Methyl Cocoyl Taurate 25 Solid 310 275 NE 101

The following information is provided to assist in product recommendation associated with Stepan’s “sulfate-free” surfactants and blends for Personal Care applications. It outlines flash foam, Biorenewable Carbon Index, and other surfactant properties of a select group of Stepan surfactants compared to competitive chemistries in the market place today. Stepan defines a product to be “sulfate-free” if it does not contain Alkyl Sulfates and Alkyl Ether Sulfates as per INCI nomenclature. This definition does not include inorganic sulfates, e.g. Sodium Sulfate formed as a by-product. Two representative sulfate products are noted for comparison purposes.

*These products do not meet Stepan’s definition of sulfate-free as defined above. NE - Not Evaluated

Stepan Trade Name INCI Name Form at 25°C

Appearance at 25°C

Viscosity, cps at 25°C

ALPHA-STEP® PC-48 Sodium Methyl 2-Sulfolaurate,

Disodium 2-Sulfolaurate Thin Liquid Clear <200

BIO-TERGE® AS-40 Sodium C14-16 Olefin

Sulfonate Thin Liquid Clear <200

LATHANOL® LAL POWDER Sodium Lauryl Sulfoacetate Thick Paste Opaque 12,000

STEPAN-MILD® LSB Sodium Lauryl

Sulfoacetate, Disodium Laureth Sulfosuccinate

Thin Liquid Clear <200

STEPAN-MILD® PCL

Sodium Methyl 2-Sulfolaurate,

Disodium 2-Sulfolaurate, Sodium Lauryl Sulfoacetate

Gel Clear 20,000

Competitive Product Coco-Glucoside Thin Liquid Hazy <200

Competitive Product Disodium Cocoyl

Glutamate, Sodium Cocoyl Glutamate

Thin Liquid Clear <200

Competitive Product Potassium Laureth-1 Phosphate Gel Clear 22,000

Competitive Product Sodium Cocoyl Glycinate Thin Liquid Opaque <200

Competitive Product Sodium Cocoyl Isethionate Paste Opaque 4,450

Competitive Product Sodium Lauroyl Methyl Isethionate Paste Opaque 6,250

Competitive Product Sodium Methyl Cocoyl Taurate Thin Liquid Hazy <200

The information on the following pages reflect a system containing 12% active of the noted surfactant and 3% active of AMPHOSOL® HCA (Cocamidopropyl Betaine). This includes appearance, foaming, and sensory properties.

Surfactant System Properties

A 12% active surfactant to 3% active Betaine ratio is typical of conventional sulfate systems. Use levels and ratios of sulfate-free systems will vary.

Sodium Cocoyl Sodium Cocoyl IsethionateIsethionate

Sodium Lauroyl Methyl Sodium Lauroyl Methyl IsethionateIsethionate

Sodium Methyl Cocoyl Sodium Methyl Cocoyl TaurateTaurate

Fine, stable bubbles Creamy foam feel Skin feels moisturized

Large and small bubbles Creamy foam feel Tacky skin feel Rinses easily

Large bubbles Airy to creamy foam feel Rinses easily

Sodium Cocoyl Isethionate

Sodium Lauroyl Methyl Isethionate

Sodium Methyl Cocoyl Taurate

Coco-Glucoside

Sodium Cocoyl Sodium Cocoyl GlycinateGlycinate

Disodium Cocoyl Glutamate, Disodium Cocoyl Glutamate, Sodium Cocoyl Glutamate Sodium Cocoyl Glutamate

Potassium LaurethPotassium Laureth--1 1 PhosphatePhosphate

CocoCoco--GlucosideGlucoside

Foam Appearance and Sensory Properties

5g surfactant system dispensed onto a wet pouf and squeezed 7 times with both hands (5 panelists). Foam appearance, foam feel,

skin feel and risibility was observed.

The significant attributes were noted for skin feel and risibility. For additional information, please contact Stepan U.S. Technical Service at [email protected].

STEPAN-MILD® LSB

BIOBIO--TERGETERGE®® ASAS--4040

Small bubbles Creamy foam feel Skin feels moisturized

ALPHAALPHA--STEPSTEP®® PCPC--4848

Small bubbles Airy foam feel Rinses easily

LATHANOLLATHANOL®®

LAL PowderLAL Powder

Very fine, stable bubbles Creamy foam feel Skin not dry

STEPANSTEPAN--MILDMILD®® LSBLSB

Fine bubbles Stable foam Creamy foam feel Skin not dry

ALPHA-STEP® PC-48

BIO-TERGE® AS-40

LATHANOL® LAL Powder

Sodium Cocoyl Glycinate

Disodium Cocoyl Glutamate, Sodium Cocoyl Glutamate

Potassium Laureth-1 Phosphate

Coco-Glucoside

Small bubbles Dry, airy foam feel Tacky skin feel Rinses easily

Small and large bubbles Creamy foam feel Skin not dry Rinses easily

Small bubbles Creamy foam feel Skin not dry Rinses easily

Small and large bubbles Creamy and airy foam feel Skin not dry Rinses easily

STEPANSTEPAN--MILDMILD®® PCLPCL

Quick flash foam Small bubbles Creamy foam feel Skin not dry

STEPAN-MILD® PCL

Foaming Properties Shake Foam Test (0.2% active solution at 25°C)

Shake Foam: This method evaluates the initial foam generation (flash foam) of a surfactant in solution as well as foam stability (after 5 minutes). The test simulates the generation of foam via agitation of the test solution and then is repeated with the addition of oil.

Stepan Sulfate-free Surfactants and Surfactant Blends provide equivalent or improved foam volume compared to the competitive surfactants listed above.

Zein Score: Amount of Zein protein solubilized by a given surfactant compared to the amount solubilized by Sodium Lauryl Sulfate (SLS). The Zein Score for SLS is 100. The less protein solubilized, the milder the surfactant.

There are many sulfate-free surfactants in the marketplace; most of them are mild. Differences may be seen in lather and sensory attributes. Stepan Sulfate-free Surfactants and Surfactant Blends provide equivalent to improved foam and skin feel attributes compared to the competitive surfactants noted in this document. LATHANOL® LAL products give a rich, luxurious lather. ALPHA-STEP® PC-48 is a methyl ester sulfonate-based surfactant- your top Stepan surfactant choice when you want high foam volume and quick rinsing. BIO-TERGE® AS-40 is a cost-effective, high-foaming surfactant to consider for non-natural Personal Care cleansing products. STEPAN-MILD® PCL and STEPAN-MILD® LSB are easy-to-handle, high-performing blends.

Biorenewable Carbon Index (BCI): The BCI is a value based on the percent carbon derived from a biorenewable resource. Biorenewable is defined by Stepan as originating from animal, plant or marine material. BCI is calculated by taking the number of biorenewable carbons divided by the total number of carbons in the idealized molecule, multiplied by 100. Critical Micelle Concentration (CMC): The minimum amount of surfactant needed to form a stable micelle. Stable micelles are required to form emulsions. It is an emulsion that captures dirt and oil and carries it away from the surface being cleaned. It is important to be above the CMC to maximize the formulations cleaning ability.

Stepan COLOMBIA

Tel: ++571-636-2808

Fax: ++571-636-2815/2816

Email: [email protected]

Stepan ASIA

Tel: ++656 879 9855

Fax: ++656 879 9870

Email: [email protected]

Stepan PHILIPPINES

Tel: ++63-43-727-2828

Fax: ++63-43-727-2831

Email: [email protected], [email protected]

Stepan EUROPE

Tel: ++33-476-505-160

Email: [email protected]

© 2014 Stepan Company. All rights reserved. Nothing contained herein grants or extends a license, expressed or implied, in connection with patents, issued or pending, of the manufacturer or others. The information contained herein is based on the manufacturer’s own study and the work of others. The manufacturer makes no warranties, expressed or implied, as to the accuracy, completeness, or adequacy of the information contained herein. THE MANUFACTURER SHALL NOT BE LIABLE (REGARDLESS OF FAULT) TO THE VENDEE’S EMPLOYEES, OR ANYONE FOR ANY DIRECT, INDIRECT, SPECIAL OR CONSEQUENTIAL DAMAGES ARISING OUT OF OR IN CONNECTION WITH THE ACCURACY, COMPLETENESS ADEQUACY OR FURNISHING OF SUCH INFORMATION.

ALPHA-STEP®, AMPHOSOL®, BIO-TERGE®, LATHANOL®, STEPAN-MILD®, STEOL® and STEPANOL® are registered trademarks of Stepan Company.

For technical assistance contact:

Stepan Company USA

Tel: ++1-800-745-7837

Fax: ++1-847-446-3925

Email: [email protected]

Stepan CANADA Inc.

Tel: ++1-705-330-3367

Fax: ++1-705-326-4523

Email: [email protected]

Stepan MEXICO

Tel: +55-11-5089-2208

Fax: +55-11-5539-4587

Email: [email protected]

Stepan QUIMICA

Tel: ++55-11-5089-2200

Fax: ++55-11-5539-4587