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238 23rd Annual Keck Symposium: 2010 Houston, Texas INTRODUCTION AND PURPOSE e Devonian System (418.1±3.0 – 365.7±2.7 Ma) is subdivided into three epochs, Lower, Middle, and Upper, which are further subdivided into seven stag- es. e Middle Devonian is subdivided into the Eif- elian (391.9±3.4 – 388.1±2.6 Ma) and the Givetian (388.1±2.6 - 383.7±3.1 Ma; Kaufmann, 2006). e stage boundary is defined by the first appearance of Polygnathus hemiansatus at the Eifelian-Givetian Stage Global Stratotype Section and Point (GSSP), which is a section at Jebel Mech Irdane in the Tifilalt of Morocco (Walliser et al. 1995). At some sections, the appearance of the goniatite Maenioceras undu- latum has been used as a proxy for the boundary (Kutcher and Schmidt, 1958). e Eifelian-Givetian stage boundary occurs just above a globally recognized hypoxic episode called the Kaĉák Event (House, 1995). Due to its associa- tion with the Dacryoconarid Nowakia otomari, the Kaĉák Event is also referred to as the Kaĉák-otomari Event. Crick et al. (2000) discovered a period of low magnetic susceptibility values associated with the Kaĉák-otomari Event, reflecting a lower detrital iron concentration within the sedimentary record. Lower concentrations of detrital iron are interpreted as the result of a transgressive episode and conse- quent migration of clastic input landward. e end of the Kaĉák-otomari Event coincides with a sharp rise in magnetic susceptibility levels roughly concur- rent with the Eifelian-Givetian boundary (Crick et al. 2000). Travis et al. (2009) have used the positive magnetic susceptibility spike to approximate the Eif- elian-Givetian boundary in eastern North America. e purpose of this paper is to analyze and approxi- mate the Eifelian-Givetian stage boundary of the Tsakhir Section, which is located near Shine Jinst in the Govi Altai Region of southern Mongolia. GEOLOGIC SETTING Badarch et al. (2002) argued that Mongolia consists of numerous terranes that were accreted onto small Precambrian cratonic blocks in the Hangay Region during the Paleozoic and Mesozoic. e focus of this investigation are strata in a region recognized as part of one of these accretionary wedges, which is referred to as the Gobi Altai Terrane (Figure 1; Ba- darch et al., 2002; Minjin and Soja, 2009a). Badarch et al. (2002) characterized the Gobi Altai Terrane as a backarc basin, as evidenced by abundant volcano- clastic sedimentary rocks. e volcanics within the Gobi Altai Terrane are believed to be derived from a prehistoric island arc represented by the Mandalo- voo Terrane, which was active throughout the Lower and Middle Devonian (Badarch et al., 2002). e study area near Shine Jinst (Fig. 1) represents a series of relatively continuous and mildly deformed rock strata, ranging from the Ordovician to the THE EIFELIAN GIVETIAN BOUNDARY (MIDDLE DEVONIAN) AT TSAKHIR, GOVI ALTAI REGION, SOUTHERN MONGOLIA NICHOLAS SULLIVAN State University of New York at Geneseo Faculty Advisor: D. Jeffrey Over Figure 1 – Simplified tectonostratigraphic terrane map for Mongolia with the Gobi Altai and Mandalovoo Terranes high- lighted. (modified from Badarch et al. 2002)

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INTRODUCTION AND PURPOSETheDevonianSystem(418.1±3.0–365.7±2.7Ma)issubdividedintothreeepochs,Lower,Middle,andUpper,whicharefurthersubdividedintosevenstag-es.TheMiddleDevonianissubdividedintotheEif-elian(391.9±3.4–388.1±2.6Ma)andtheGivetian(388.1±2.6-383.7±3.1Ma;Kaufmann,2006).ThestageboundaryisdefinedbythefirstappearanceofPolygnathushemiansatusattheEifelian-GivetianStageGlobalStratotypeSectionandPoint(GSSP),whichisasectionatJebelMechIrdaneintheTifilaltofMorocco(Walliseretal.1995).Atsomesections,theappearanceofthegoniatiteMaenioceras undu-latum hasbeenusedasaproxyfortheboundary(KutcherandSchmidt,1958).TheEifelian-GivetianstageboundaryoccursjustaboveagloballyrecognizedhypoxicepisodecalledtheKaĉákEvent(House,1995).Duetoitsassocia-tionwiththeDacryoconaridNowakiaotomari,theKaĉákEventisalsoreferredtoastheKaĉák-otomariEvent.Cricketal.(2000)discoveredaperiodoflowmagneticsusceptibilityvaluesassociatedwiththeKaĉák-otomariEvent,reflectingalowerdetritalironconcentrationwithinthesedimentaryrecord.Lowerconcentrationsofdetritalironareinterpretedastheresultofatransgressiveepisodeandconse-quentmigrationofclasticinputlandward.TheendoftheKaĉák-otomariEventcoincideswithasharpriseinmagneticsusceptibilitylevelsroughlyconcur-rentwiththeEifelian-Givetianboundary(Cricketal.2000).Travisetal.(2009)haveusedthepositivemagneticsusceptibilityspiketoapproximatetheEif-elian-GivetianboundaryineasternNorthAmerica.Thepurposeofthispaperistoanalyzeandapproxi-matetheEifelian-GivetianstageboundaryoftheTsakhirSection,whichislocatednearShineJinstintheGoviAltaiRegionofsouthernMongolia.

GEOLOGIC SETTINGBadarchetal.(2002)arguedthatMongoliaconsistsofnumerousterranesthatwereaccretedontosmallPrecambriancratonicblocksintheHangayRegionduringthePaleozoicandMesozoic.Thefocusofthisinvestigationarestratainaregionrecognizedaspartofoneoftheseaccretionarywedges,whichisreferredtoastheGobiAltaiTerrane(Figure1;Ba-darchetal.,2002;MinjinandSoja,2009a).Badarchetal.(2002)characterizedtheGobiAltaiTerraneasabackarcbasin,asevidencedbyabundantvolcano-clasticsedimentaryrocks.ThevolcanicswithintheGobiAltaiTerranearebelievedtobederivedfromaprehistoricislandarcrepresentedbytheMandalo-vooTerrane,whichwasactivethroughouttheLowerandMiddleDevonian(Badarchetal.,2002).

ThestudyareanearShineJinst(Fig.1)representsaseriesofrelativelycontinuousandmildlydeformedrockstrata,rangingfromtheOrdoviciantothe

THE EIFELIAN GIVETIAN BOUNDARY (MIDDLE DEVONIAN) AT TSAKHIR, GOVI ALTAI REGION, SOUTHERN MONGOLIA

NICHOLAS SULLIVANStateUniversityofNewYorkatGeneseoFacultyAdvisor:D.JeffreyOver

Figure 1 – Simplified tectonostratigraphic terrane map for Mongolia with the Gobi Altai and Mandalovoo Terranes high-lighted. (modified from Badarch et al. 2002)

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Carboniferous(MinjinandSoja,2009b).Wangetal.(2005)arguedthattheEifelian-Givetianbound-arylieseithernearthetopoftheTsagaankhaalgaFormation,ornearthebottomoftheoverlyingGovialtaiFormation,suggestingthepossibilityofagapinthestratigraphicrecordthatincludesthestageboundary.Alekseeva(1993)describedtheTsagaankhaalgaFormationaspredominantlymassive,beddedlimestonesandassociatedconglomeratesandsand-stonelayers.Wangetal.(2005)reportedthecon-odonts Caudicriodus angustus cauda,Caudicriodus stelcki,andCaudicriodus unwoschmidti,withintheTsagaankhaalgaFormation,therebyconstrainingitsagetotheEifelian.Alekseeva(1993)subdividedtheGovialtaiForma-tionintotwomembers.ThelowerorTentaculiteMemberischaracterizedbyblacksiltstonesandclaystoneswithoccasionalsandstoneandsandylimestonelayers.TheupperorKharMemberischaracterizedbyvolcanoclasticsedimentswithoccasionalinterbeddedbasalts.ConodontsoftheUpperensensisZonewerereportedbyAlekseeva(1993)intheTentaculiteMember,therebycon-strainingitsagetotheGivetian.TheEifelian-GivetianStageboundaryisbelievedtofallwithintheupperTsagaankhalgaorlowerGovi-altai.Alekseeva(1993)suggestedthattheTsakhirsectionisincompleteandthetwoformationsareunconformable,asentimentsharedbyWangetal.(2005).LITHOLOGY AND LOCATION OF THE TSAKHIR SECTION

From3August2009to6August2009,thesectionatTsakhirwasmeasuredandsampled.Theap-proximatelocationofthesectionis44º22’53”Nand99º28’46”E.Theoutcropliesonaridgethattrendsroughlynorthwest-southeastbetweentwodrainagedividesthatcontaindirtroads.Thecrestoftheridgeconsistsofmassivelybedded,fossiliferouscarbonates.Asmallsampleofthesecarbonatebeds,believedtocorrespondtothebaseofUnit18from

Alekseeva(1993),wascollectedformicrofossilsandthinsectionproduction.

Theprimaryfocusofthisstudywasanoutcropthatcanbefoundonthethirdhilleastofthedrainagedividethatcrossestheridgetothewest(Fig.2).Thestratawerefoundtohaveatrendof058withadipof50tothesouth.However,theyweredeterminedtobeoverturned;indicatingstratigraphicupwastothenortheast.

A103metersectionofrockwasstudiedwithzeroestablishedatthelevelwherealightpinkishgraysiltstoneisoverlainbyalightgraysiltyshale(Fig.3).The3.6m–25.0m,28.8m-43.0m,and49.0m–53.0msectionintervalswereobscuredbyalluviumandthereforewerenotrecorded.Magneticsusceptibil-itysampleswerecollectedathalfmeterintervalsthroughthesection.Fivebulksampleswerecol-lectedforthinsectionsandmicrofossilanalysisat65.2m,68.8m,76.5-77.0m,87.0mand96.0-97.0m(Fig.3).

Figure 2 – Location of the Tsakhir section (outlined in the black box) on a simplified geologic map of the study area. Faults are indicated by red lines. Drainage channels are indicated by dotted blue lines. The Tsakhir Well is represented by a red dot. Geologic units are labeled below (modified from Wang et al. 2005; and Minjin and Soja, 2009).

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Thestratigraphicsectionconsistsprimarilyoffinegrainedsiliclastics;mostlydarkbluetodarkgraysiltyshales.Alsopresentaregreenishgraytuffaceousconglomerates,mediumgreentograyfeldspathicrhyolitesiliciousbeds,andinterbeddedcarbonateswhichweresampledformicrofossils.

MICROFOSSIL DATA AND SYSTEMATICSThecarbonatebedsampledat68.8m,76.5-77.0m,87.0m,and96.0-97.0mwereprocessedforcon-odontsusingasolutionofformicacid.Conodontswererecoveredfromthe68.8mintervalandimagedusingascanningelectronmicroscope(Fig.4).

Icriodus sp.Remarks:ThemainP1elementofIcriodusischar-acterizedbythreelongitudinalrowsofnodeswithsomeformsincludingtransverseridges(Clarketal.,1981).ThestratigraphicrangeisbetweenthePridolianandtheFamennian.Specimen4AisaP1elementdisplayingbythethreelongitudinalrowsofnodescharacteristicofIcriodus.Thenodesofthecentralrowareconnectedbyalongitudinalridge.Transverseridgesarepresent,runningbetweenlateralandcentralnodes.

Polygnathus linguiformis linguiformisRemarks:P. linguiformislinguiformisisdefinedbyanelongateplatewithoneextremityproducedintoatonguelikeprojectionwhichismarkedbytrans-verseridges.Theanteriorportionoftheplatformischaracterizedbyadcarinaltroughsstraddlingtheblade(Hinde,1879).ThistaxonisknowntohaveastratigraphicrangebetweenthelateEifelianandearlyGivetian(Ziegleretal.,1979).AlthoughFigure

Figure 3a – Stratigraphic column compiled from data collected from the Tsakhir Section. Figure 3b – Key to lithologies

Figure 4 – Conodonts from the sample collected at 68.8 m car-bonate bed. Images were acquired using the scanning electron microscope. White bar represents two millimeters.Icriodus sp.A; Upper view of TSEG 01726, (long axis; 1.19 mm), Polygnathus linguiformis linguiformisB; Upper view of TSEG 01734 (long axis; 1.45 mm)Polygnathus sp.C; Upper view of TSEG 01730 (long axis 0.84 mm)D; Upper view of TSEG 01736 (long axis 0.72 mm), most likely the posterior end of sample TSEG 01730Polygnathus ensensis E; Upper view of TSEG 01736 (long axis 0.77 mm)F; Oblique view of TSEG 01731 (long axis 0.77 mm)Polygnathus xylus xylusG; Upper view of TSEG 01735 (long axis .78 mm)

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4Bdoesnotrepresentacompleteandundamagedconodont,itisintactenoughtoviewthetonguelikeprojectionandlateralridgescharacteristicofP. linguiformis linguiformis.

Polygnathus sp.Remarks:ThegenusPolygnathusisdefinedbycar-miniplanateP1elements.P1elementsofPolygnathusconsistofaflatplatformextendingawayfromtheposteriorsectionofablade.Figures4Cand4Darebelievedtorepresenttwofragmentsofthesameconodont.Thespecimenswerenotidentifiedtothetriviallevel.ThestraightoutermarginsofthebladeanddistinctadcarinaltroughsarereminiscentofP. linguiformis.However,thespecimenslackthelateralridgesandtonguelikeprojections.Relativelyflatbutdiscreteprotrusionsontheplatformarealsovisible.Thespecimenbearsresemblancetospeci-mensidentifiedasPolygnathus pseudofoliatusbyWalliser(1996,Fig.4A,4B)fromMorocco.

Polygnathus ensensis Remarks:P. ensensis(synonymouswithP. xylus ensensis)isdefinedbydistinctlyserratedplatformmarginsjustposteriortothegeniculationpoint(Zeigleretal.,1976).Polygnathus ensensisfirstap-pearsintheupperEifelian,rangingintotheearlyGivetian(BultynckandHollevoet,1999).Figure4Eisfragmentedandthebladeisnotintact.However,thedistinctlyserratedmarginsintheposteriormar-ginoftheplatformarevisible.Figure4Fshowsanobliqueviewoftheplatform.

Polygnathus xylus xylus Remarks:P. xylus xylusischaracterizedbyplatformmarginsjustposteriortothegeniculationpointthatarenotsignificantlyserrated.ThetaxonappearsintheupperEifelian,rangingintotheLower varcus-SubzoneoftheearlyGivetian(Ziegleretal.1976).Figure4GshowsthespecimenwhichdisplaystheunserratedmargincharacteristicofP. xylus xylus.Thespecimenalsoshowsanelongatedbladewhichisalsocharacteristicofthetaxon.

MAGNETIC SUSCEPTIBILITY DATA

MagneticsusceptibilitydatawasacquiredusinganAGICPKappabridgehousedintheSUNYGeneseoDepartmentofGeology.DatawerecompiledandorganizedinMicrosoftExcelandmagneticsuscep-tibility(m3/kg)wasplottedagainststratigraphicthicknessinmeters(Fig.5A).Magneticsusceptibil-itydatashowanoverallpositivetrendmovingupthesection.Therearethreemajorpositivespikesinmagneticsusceptibilityatapproximately0.0m,47.0m,and63.0m.

Thesepositivespikesovershortintervals,combinedwiththeoverallpositivetrendofmagneticsuscepti-bilitymovingupsection,issimilartodatacollectedfromtheEifelian-GivetianGSSPatJbelMechIrdaneinMorocco(Cricketal.,2000)andfromMiddleDevonianstratasampledinNewYork(Travisetal.,2009).

Figure 5 –Magnetic susceptibility (m3/kg) of samples collected at Tsakhir Section plotted against stratigraphic thickness in me-ters. Blue line represents magnetic susceptibility of individual samples. Red curved line represents mean magnetic susceptibil-ity for sets of eight samples.

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CONCLUSIONS

ThesiliclasticandvolcanicsedimentsattheTsakhirSectionareassignedtotheTentaculiteMemberoftheGovialtaiFormation.ThisisconsistentwiththegeologicmapproducedbyWangetal.(2005)andtheobservationsofAlekseeva(1993).

Thelithologyofthesectionshowsmanysignifi-cantsimilaritiestoMiddleDevonianoutcropsinNorthAmerica.ThemassivecarbonatesoftheTsagaankhaalgaFormationoverlainbythemorefinelybeddedsiliclasticshalesoftheGovialtaiFor-mationarestrikinglysimilartooutcropsineasternNorthAmericawherecarbonatesoftheOnondagaFormationareoverlainbytheMarcellusandSka-neatelesshales.Theabundanceofvolcanoclasticsthroughoutthesectionisconsistentwiththecon-clusionsofBadarchetal.(2002)whodefinedtheShineJinstareaasabackarcterranethathadformedbehindavolcanicislandarcthatwasactiveduringtheDevonian.ThepresenceofPolygnathus xylus xylusandPolyg-nathus linguiformis linguiformisindicatethatthecar-bonatebedfoundat65.8mostlikelyrepresentstheLowervarcus-ZoneofthelowerGivetian.TheEif-elian-Givetianboundaryistentativelyplacedabovethepositivemagneticsusceptibilityshiftobservedatapproximately0.0meters,wherethemeasurementsappeartostabilizeatalevelbetween6.00x10-8and9.00x10-8m3/kg.However,biostratigraphiccontrolisnotsufficienttoconstraintheboundaryintervalandthickintervalsofthesectionareobscuredbyalluvium,thuslimitingtheresolutionofmagneticsusceptibilitytrends.

REFERENCES

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Hinde,G.J.,1879,OnconodontsfromtheChazyandCincinnatigroupoftheCambro-Silurian,andfromtheHamiltonandGenesee-ShaledivisionsoftheDevonian,inCanadaandtheUnitedStates:GeologicalSocietyofLondon,QuarterlyJournalv.35,pp.351-369,pls.15-17,London

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