the columbia river as a source of marine light scattering particles

120
AN ABSTRACT OF THE THESIS OF HASONG PAK for the (Name) DOCTOR OF PHILOSOPHY (Degree) in OCEANOGRAPHY presented on July 14, 1969 (Major) Title: THE COLUMBIA RIVER AS A SOURCE OF MARINE LIGHT SCATTERING PARTICLES Abstract approved: orge F. Beardley, Jr. The Columbia River plume region was investigated during the period of ZO June to 3 July, 1968 by light scattering measurements and standard hydrographic station observations. The Columbia River plume was traced by the light scattering particles of the plume water. The light scattering particles are estimated to be contained in the plume water for 30 to 50 days. On the basis of the data taken in the Columbia River plume region, a conceptual model is made to describe the flow of river originated particles to the ocean water. In the distribution of the light scattering particles a northward deep current under the plume near the river mouth and a subsurface off- shore flow near the bottom of the Columbia River plume are shown. Redacted for Privacy

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Page 1: The Columbia River as a source of marine light scattering particles

AN ABSTRACT OF THE THESIS OF

HASONG PAK for the(Name)

DOCTOR OF PHILOSOPHY(Degree)

in OCEANOGRAPHY presented on July 14, 1969(Major)

Title: THE COLUMBIA RIVER AS A SOURCE OF MARINE LIGHT

SCATTERING PARTICLES

Abstract approved:orge F. Beardley, Jr.

The Columbia River plume region was investigated during the

period of ZO June to 3 July, 1968 by light scattering measurements

and standard hydrographic station observations. The Columbia

River plume was traced by the light scattering particles of the plume

water. The light scattering particles are estimated to be contained

in the plume water for 30 to 50 days. On the basis of the data taken

in the Columbia River plume region, a conceptual model is made to

describe the flow of river originated particles to the ocean water.

In the distribution of the light scattering particles a northward deep

current under the plume near the river mouth and a subsurface off-

shore flow near the bottom of the Columbia River plume are

shown.

Redacted for Privacy

Page 2: The Columbia River as a source of marine light scattering particles

The Columbia River as a Source ofMarine Light Scattering Particles

by

Hasong Pak

A THESIS

submitted to

Oregon State University

in partial fulfillment ofthe requirements for the

degree of

Doctor of Philosophy

June 1970

Page 3: The Columbia River as a source of marine light scattering particles

APPROVED:

Assin charge of major

C hairm.n of Department of ceanography

Dean o'f Graduate School

Date thesis is presented \cJ) (k9

Typed by Donna L. Olson for Hasong Pak

Redacted for Privacy

Redacted for Privacy

Redacted for Privacy

Page 4: The Columbia River as a source of marine light scattering particles

ACKNOWLEDGMENT

The author is deeply indebted to Dr. George F. Beardsley, Jr.,

my thesis advisor, for providing the indispensable means and needs

for the investigation. He also would like to express his sincere

appreciation to Dr. Robert L, Smith, who provided many construc-

tive criticisms and advice, Kendall Carder, who helped in light

scattering measurements, data reduction, and error analysis, and

Robert Hodgeson, who also helped in error analysis.

Special thanks are due to Dr. P. K. Park, who provided space

and water samples on the 6806C Columbia Plume Cruise.

This investigation was supported by the Office of Naval Re-

search, Grant No. 1Z86(1O).

Page 5: The Columbia River as a source of marine light scattering particles

TABLE OF CONTENTS

Page

INTRODUCTION 1

Problem 1

History 3

EXPERIMENTAL PROGRAM 5

INTERPRETATION OF SEA WATER LIGHT SCATTERINGDATA 10

DATA 14

RESULTS 55

General Features of 1968 Summer ColumbiaRiver Plume 55

Flows 67Model Plume 73

DISCUSSION 77

BIBLIOGRAPHY 90

APPENDIX I - COLUMBIA RIVER AND ITS ESTUARY 94

APPENDD( II REVIEW OF REGIOi'AL OCEANOGRAPHICCONDITIONS OFF THE OREGON-WASHING-TON COAST 97

APPENDIX III - BRICE PHOENIX LIGHT SCATTERINGPHOTOMETER 100

Page 6: The Columbia River as a source of marine light scattering particles

LIST OF FIGURES

Figure Page

1. The cruise track and positions of the hydro-graphic stations of the R/V YAQUINA 6806C,20 June to 3 July, 1968. Section I followsclosely to the plume axis, and sections II to Vare approximately along the latitude. 8

2. An example of the volume scattering functionfor coastal and oceanic water, and the theoreti-cal curve for pure water (Spilhaus, 1965). 11

3. Salinity distribution on the sea surface. 30

4. Scattering particle distribution on the seasurface. 31

5. Salinity distribution on the 3m surface. 32

6. Scattering particle distribution on the 3msurface. 33

7, Salinity distribution on the lOm surface. 34

8. Scattering particle distribution on the lOmsurface. 35

9. Salinity distribution on the ZOm surface. 36

10. Scattering particle distribution on the ZOmsurface. 37

11. Salinity distribution on the 30m surface. 38

12. Scattering particle distribution on the 30msurface. 39

13. Salinity distribution on Section I. 40

14. Scattering particle distribution on Section I. 41

Page 7: The Columbia River as a source of marine light scattering particles

Figure Page

15. Temperature distribution on Section I. 42

16. Sigma-t distribution on Section I. 43

17. Oxygen distribution on Section I. 44

18. Salinity distribution on Section II. 45

19. Scattering particle distribution on Section II. 46

20. Temperature distribution on Section II. 47

21. Sigma-t distribution on Section U. 48

22. Oxygen distribution on Section II. 49

23. Scattering distribution on Section III. 50

24. Salinity distribution on Section III. 51

25. Scattering particle on Section IV. 52

26. Salinity distribution on Section IV. 53

27. Scattering particle on Section V. 54

28. Temperature and salinity vs. depth curvesfor stations MC-5 and MC-6. 56

29. Sigma-t distribution on the 3m surface. 58

30. Temperature distribution on the 3m surface. 59

31. Columbia River plume axes defined by salinity,temperature, sigma -t, and scattering particleon the 3m surface. 61

32. Salinity distribution at sea surface, Brown BearCruise 308, 7-19 June 1962 (Budinger et al.,1964). 65

33. Temperature vs. scattering particle on SectionII. 70

Page 8: The Columbia River as a source of marine light scattering particles

Figure Page

34. Distribution of Holocene clay-mineral groups. 72

35. Plume model in the vertical section along theplume axis. 75

36. Plume model on a section across the plumeaxis. 76

37. Scattering particle profile at MC-5 and MC-6. 80

38. Stability (Brunt-Vaisrd. Frequency) profiles atMC-5,6. 81

39. Profiles of stability and scattering particles atMC-25, near the river mouth. 82

40. Profiles of stability and scattering particles atMC-33, at the edge of the plume. 83

41. Stability profiles at MC-5 and MC-15. 85

42. Columbia River basin. 95

Page 9: The Columbia River as a source of marine light scattering particles

LIST OF TABLES

Table Page

1. 6806C Columbia plume cruise data, 16

2. Meridional components of geostrophic currentand Ekman transport. 66

3. Results of error analysis. 108

Page 10: The Columbia River as a source of marine light scattering particles

THE COLUMBIA RIVER AS A SOURCE OFMARINE LIGHT SCATTERING PARTICLES

INTRODUCTION

Problem

The various dissolved and suspended substances in the ocean

produce optical properties which vary markedly from place to place.

A systematic method of interpreting the spatial and temporal distri-

bution of these properties will assist in the solution of many oceano-

graphic problems. Such a systematic approach to the analysis and

interpretation of optical properties must include considerations of

the sources, sinks, and reservoirs of these particles.

Rivers are sources of optical properties just as they are

sources of fresh water. The Columbia River is the major river

bringing fresh water from the North American continent to the North-

eastern Pacific ocean. This thesis is the result of an experimental

effort to understand the process by which particles are introduced

into an oceanic region by a localized source (a major river), and

to develop a conceptual model which describes the basic process by

which rivers introduce one type of optical property, light scattering

by particulate matter, into the ocean. The experimental program

was carried out in the Columbia River plume region.

Page 11: The Columbia River as a source of marine light scattering particles

2

Light scattering by suspended material is the specific para-

meter studied in this thesis, and the word "optical property" is used

to imply this scattering property. The process of light scattering

has been treated theoretically by the application of electromagnetic

wave theory. Mie (1908) derived a rigorous expression in this way

for the light field resulting from the scattering of a plane monochro-

matic wave by spherical, non-absorbing particles. He showed that

the light scattering depends in a complicated way upon the particle

size and relative index of refraction. However, assuming that the

particles are separated by at least three times their radii and

scattered light has the same wavelength as the incident light, then

one useful consequence of the Mie theory is that the scattering by a

system of particles is the sum of the scattered light from individual

particles. Thus the light scattering is directly related to the

particle concentration.

Theoretical analysis of light scattering to obtain particle sizes,

shapes, and constituents is not possible with present techniques, thus

an experimental method is needed. Since for a given set of those

parameters, a unique scattering field is derived, the study of

changes in the scattered light reflects the variations in these para-

meters themselves.

Page 12: The Columbia River as a source of marine light scattering particles

3

History

The progress of optical oceanography has been slow mainly

because of the difficulties in making suitable instruments. Kalle

(Jerlov, 1968) applied the photoelectric cell and made a scattering

meter to determine particle distributions in the deep ocean. Jerlov

(1953) made an extensive application of these optical properties of

sea water to the study of water masses and circulation. During the

Swedish Deep Sea Expedition (1947-1948), Jerlov (1953) determined

the particle concentration using the Tyndall meter measurements.

He applied the method to an identification of water types, the Equa-

tonal current system, deep water circulation, and particle detach-

ment from bottom sediments in connection with bottom topography.

Jerlov (1959) applied the turbulence and diffusion theory to

describe the vertical particle distribution and presented several

empirical measurements. He concluded the following:

* . . . It seems established that there is often an indisputablerelationship between particle distribution and salinity dis-tribution inasmuch as particle distribution is much con-trolled by the turbulence and ultimately by the flow of thedifferent water masses.

The application of light scattering measurements to the outflow

of river effluent has been made by Jerlov (1953a, 1953b and 1958)

and by Ketchum and Shonting (1958). These studies are considered

incomplete due to insufficient area coverage. The Po River plume,

Page 13: The Columbia River as a source of marine light scattering particles

4

studied by the former author (1958), provided a comprehensive guide

to the problem, but geographic and hydrographic conditions of the

plume region complicated the results,

The latter authors traced the Orinoco River plume in the

Cariaco Trench, which is more than 250 nautical miles from the

source. Their findings are considered incomplete since the path be-

tween the region of the studied plume and the source of the plume

was not studied. It seems imperative for the interpretation of the

measurements made in the Cariaco Trench to consider the progress

of the plume between the source and the Cariaco Trench, The parti-

cle constituents, sizes, shapes, and dispersion processes of the

plume may or may not support the interpretation made by the latter

authors on the particle distributions observed in the Cariaco Trench.

On this basis, a thorough study of the optical properties at their

source region is believed to improve and extend the use of these

properties.

Page 14: The Columbia River as a source of marine light scattering particles

5

EXPERIMENTAL PROGRAM

An ideal scientific experiment is one in which the whole

system can be controlled. Usually such controlled experiments are

not feasible in oceanography, so field experiment programs must be

used instead, A good field program is easiest to develop when the

phenomena to be studied are simple, with a well defined geometry,

and with features that vary slowly in comparison with the possible

speed of survey. Approximations of synoptic observations, which

are often practiced in oceanographic works, are based on such con-

ditions. The availability of supporting data from previous studies is

also helpful in planning field programs.

The Columbia River plume region was considered excellent for

the proposed study. The use of the Columbia River water as a cool-

ant for nuclear power plants at Hanford has motivated many prior

cruises in the plume area, and the basic physical, chemical, bio-

logical, and geological features are well known (References are given

in Appendix II). The plume is well developed during the summer

months, and shows a persistency during this season. Previous

studies (Budinger et al., 1964; Frederick, 1967; and Cissel, 1969)

have shown that fourteen days at sea are sufficient to obtain an

accurate and nearly synoptic picture of the plume during the summer

in a region about 100 by ZOO nautical miles.

Page 15: The Columbia River as a source of marine light scattering particles

The oceanic region into which the Columbia River effluent

flows is characterized as an Eastern Boundary current region of the

North Pacific Ocean with a weak but recognizable southward surface

flow during the summer. North or Northwesterly wind persists

during the summer, and coastal upwelling is observed along the

coasts of Washington, Oregon, and California. Thus during the

summer, the weak southward surface current, a persistant north or

northwesterly wind, and upwelling along the coast cause the Columbia

effluent to form a tongue-shaped plume extending toward the south or

southwest. This plume is bounded by upwelled water on the coast

side and by clear oceanic water on the offshore side. It is clearly

identified by a salinity minimum.

The Columbia River plume maintains a well defined, simple

form during the summer because the dry regional climate during

that season eliminates the complicating effects of coastal streams,

and the persistent wind system keeps the plume position at an

approximately steady state.

Further details of the Columbia River, its estuary and regional

oceanographic conditions are presented in Appendices I and II.

The Columbia River plume cruise (6806C)1 was planned to

study the physical, chemical, and biological aspects of the Columbia

'The 6806C Cruise was planned and executed by Dr. P. K. Park

Page 16: The Columbia River as a source of marine light scattering particles

7

River plume and its environmental water during summer upwelling

conditions. The addition of an optics program to this cruise allowed

us to obtain the data required for this study. The cruise took place

during the period of June 20 to July 3, 1968, and included 67 hydro-

graphic stations and another hundred auxiliary stations of bucket

samples placed between hydrographic stations (Figure 1).

The data obtained at each hydrographic station and used in this

study include temperature, salinity, dissolved oxygen, and light

scattering, listed in Table 1, along with computed values of sigma-t

(density) and the stability parameter (Brunt-Väisälä frequency). All

the measurements were made on samples taken with Teflon-coated

Nans en-bottles.

The hydro-casts and samples were taken according to standard

procedures. The temperature was measured by reversing thermo-

meters attached to the Nans en-bottles. The salinity was measured

by an hlHytechH inductive salinometer, The dissolved oxygen was

measured by the Winkler method. Light scattering was measured

in the ship?s laboratory with a Brice-Phoenix light scattering photo-

meter. This instrument measures the light scattered by a water

sample contained in a glass scattering cell. The instrument and its

operational procedures are presented in Appendix LII.

The standard sampling depths were 0, 3, 6, 10, 20, 30, 40,

50, 75, 100, 125, and 150 meters. A BT was cast before each

Page 17: The Columbia River as a source of marine light scattering particles

a .uoô..I.-___

-

-...- S.

/ - ''n óS_/'

. .!---"/ -11

SC O I I / / 3'0:,,0:o ---/ r6.

-

a.-'in 'a

I'w /a

SECT ION I / \o2' ) ,A I i 0.

/0F()

in 0çsj 4 in'

in I)

SECTION V

°N ,

0

0

--c &.0/

N?,. -_. . (cjJ',,/'

5,a:

'0(. I...'

.0I:.:

: k.-'

.5

'Io 00 0 0

0' I::

2 N-:f-I

F::'.'

N) IU)i-I

'/E-.

1.0 5'sIC)' ,

0

i

R.

Figure 1. The cruise track and positions of the hydrographic stations

of the RIV YAQUINA 6806 C, 20 June to 3 July, 1968.Section I follows closely to the plume axis, and sectionsII to V are approximately along the latitude.

Page 18: The Columbia River as a source of marine light scattering particles

hydro-cast and additional Nansen-bottles were added to the standard

depths whenever significant features, such as temperature inversions

or any other rapid changes with depth,were found on the BT slide,

Since the casts were all shallow and made under good conditions, no

corrections for wire angle were necessary.

Page 19: The Columbia River as a source of marine light scattering particles

10

INTERPRETATION OF SEA WATER LIGHT SCATTERING DATA

The volume scattering function, p(8), is defined by:

(8) J(6)(1)

HV

where J(0) is the intensity of scattered light in the direction of 8, H

is the input irradiance, and V the scattering volume defined by inter-

section of the light beam and the detectivity beam. Figure 2 shows

three observed volume scattering functions plotted against scatter-

ing angle, 8. The total scattering coefficient can be defined by:

(111

b = Zrr 13(8) sin8dO (2)0

The total scattering coefficient is usually computed from 13(8)

measured at certain intervals of 0. The measurement of 13(8) at a

small angle is considerably difficult, and a separate instrument is

usually used for the small angle measurement (Spilhaus, 1965; and

Morrison, 1967).

FTom the regular behavior of the angular dependence of the

volume scattering function, Jerlov (1953a), Tyler (1961c), Spilhaus

(1965),*and Morrison (1967) concluded that the total scattering co-

efficient can be computed by 13 (45) with small error showing b and

13 (45) are linearly dependent. Thus the total scattering coefficient

Page 20: The Columbia River as a source of marine light scattering particles

11

0C OASTAL

00

00

OCEANIC 00 0

00 0

o 000000000

0

DC

CC

ATHEORETICAL c 0 0

300 600 90° 1200 1500

L!J

Figure 2. An example of the volume scattering functionfor coastal and oceanic water, and the theoreti-cal curve for pure water (Spilhaus, 1965).

Page 21: The Columbia River as a source of marine light scattering particles

12

in the form of equation (2) is not computed considering 1) 3 (45) is

an adequate substitute for b, 2) more time involved in measuring

() at many angles to apply equation (2), and 3) the difficulties in

small angle (0) measurement, which has some uncertainty remain-

ing.

According to the Mie theory, the scattering coefficient from

N particles per unit volume can be represented by:

b=KNirD2/4=KNA (3)

where K is efficiency factor or the effective area coefficient, D is

the diameter of the particles, and A is the cross-sectional area of

particle. In case of polydispersed particles, the scattering coeffi-

cient is given by:

b K. N. (4)

Burt (1956) computed the effective area coefficient, on the

basis of Rayleigh's equation and Mie theory for non-absorbing

spheres, as a function of refractive index, size, and wavelengths.

With increasing particle size, K increases rapidly at small radii,

then it passes a maximum for sizes of the same order as the wave-

length, and it tends thereafter toward a constant value of 2 for larger

radii irrespective of the wavelength.

Page 22: The Columbia River as a source of marine light scattering particles

13

On the basis of the equation (3) or (4), the scattering coefficient

measured in sea water can be interpreted as a measure of particle

concentration with a mean diameter D Particularly for a system of

polydispersed particles in which the mean size remains constant, or

then the volume scattering function measured at 450,D N'

p (45), is proportional to the concentration of particles.

Page 23: The Columbia River as a source of marine light scattering particles

14

DATA

The final reduced data are listed in Table 1, The data were

analyzed on horizontal surfaces at several depths and in vertical

sections along the plume axis and across the plume axis, Figures

relevant to the discussion and results are listed below and collected

in the following pages.

The volume scattering function measured at 450 angle is ex-

pressed in absolute unit of (meter-steradian) Through the rela-

tion between the total scattering coefficient and the volume scatter-

ing function measured at 450P (45), as described in the previous

section,1

(45) is directly interpreted as a parameter indicating

suspended particle concentrations.

List of Analysis

Figure

3, Salinity distribution on the sea surface,

4, Scattering particle distribution on the sea surface,

5. Salinity distribution on the 3m surface,

6. Scattering particle distribution on the 3m surface,

7. Salinity distribution on the lOm surface.

8, Scattering particle distribution on the lOm surface,

9, Salinity distribution on the ZOm surface,

10, Scattering particle distribution on the ZOm surface,

Page 24: The Columbia River as a source of marine light scattering particles

15

11. Salinity distribution on the 30m surface.

12. Scattering particle distribution on the 30m surface.

13, Salinity distribution on Section I

14, Scattering particle distribution on Section I.

15, Temperature distribution on Section L

16. Sigma-t distribution on Section I.

17. Oxygen distribution on Section I.

18, Salinity distribution on Section II.

19. Scattering particle distribution on Section II.

20. Temperature distribution on Section II.

21. Sigma-t distribution on Section II.

22. Oxygen distribution on Section II.

23. Scattering distribution on Section III.

24. Salinity distribution on Section III.

25. Scattering distribution on Section IV.

26. Salinity distribution on Section IV.

27. Scattering particle distribution on Section V.

Page 25: The Columbia River as a source of marine light scattering particles

16

Table 1. 6806c Columbia Plume Cruise data.2 T S 02 Ni S45 S90

LI (mi/i)

DB-1 0 10.08 32.959 5.6 25.36 2.975 9.9694 10.9545 9.17 33.290 4.46 25.77 2.008 3.7758 47343

10 8.68 33.L1.5 3.81 25.98 1.657 4.1484 5.594920 7.95 33.65 2.52 26.25 3.0679 4.8993

DB-3 0 io.06 32.794 ,64 25,24 2,901 4.1786 5.0924

5 9.10 33.137 4.53 25,66 1.238 3.4251 4.718610 8.96 33.202 4.39 25.74 1.63 2.0741 2.442920 8.18 33.369 3.17 25.98 2.139 2.4086 3.221530 7.41 33.803 2.12 26.44 .9547 2.0173 3.24504o 7,21 33.884 1.54 26.53 ----- 2.0037 3.176650 7.22 33.888 1.46 26.53 ----- 2.6520 3.7981

DB-5 0 11.73 31.208 6.6i 23.71 3.463 3.1312 3.46515 10.79 31.763 6.35 24.31 3.201 4.1571 4.o75

10 9.53 32.150 5.31 24.83 2,Q48 2,1977 2.769420 7.83 32.934 4.05 25.70 1.947 1.4583 2.118530 7.75 33.352 3.46 26.04 i.5L4 1.0858 1.835340 7.62 33.632 2.60 26.28 1.3921 2.350650 7.45 33,756 2.32 26.39 1.73 1.9191 3.249160 7,10 33.899 1.87 26.55 1.1353 1.4008

DB-7 0 12.67 33.932 1.88 23.10 4.654 3.9774 5.62595. 11.36 33.888 2.55 24.18 3.375 1.4694 2.5910

10 9.55 33.860 2.74 24.75 2,759 1.1190 2.129920 7.89 33.843 2.88 25.52 1.979 1.3215 2.378130 7.62 33.746 2.i0 2.91 1.353 .72796 .881724o 7.71 33.532 3.13 26.09 1.021 9Y-o3 1.769650 7.64 33.419 3.44 26.19 1,40? .27741 2.03476o 7.41 33.162 3.95 26.39 .9331 i.07c4 1.Q7970 7.35 32.716 4.41 26.49 .197 1.4208 3.002580 7.19 32.066 5.48 2.52 .5949 2.5326 3.303090 7.05 31.720 6.70 26.55 .7004 3.4528 Li..6652

100 6.98 30.631 6.69 26.60 5.8627 8.2474DB-10 0 14.17 30.353 6,44 22.59 4.481 2.8980 3,3557

5. 13.54 31.496 6.56 23.59 4.295 2.2710 3.055210 10.27 31.919 6.84 24.2 2.542 2.23R1 2.448320 8.35 32.355 4.95 25.17 1.983 1.2367 1.909030 7,75 32.747 4.31 25,56 1.655 1.2317 1.9i640 7.70 33.085 4.15 25.84 1.438 1.6739 2.23250 7.68 33.340 3.88 26.04 1.340 1.2857 2.288660 7.74 33.583 3.38 26.22 1.022 1.1335 2.084470 7.56 33.682 3.08 26.32 1.150 1.4553 3.106680 7.35 33.816 2.78 26.45 .7598 .87232 1.653790 7.22 33.866 2.76 26.51 .6316 1.9179 3.5635

100 7.16 33.901 2.70 26.55 .5049 1.9168 3.0723125 6.93 33.949 1.60 26.62 3.8258 5.2577

TDB-15 0 14.75 29.526 6.39 21.83 4,4oi 2,4970 3.12210 13.95 31.805 6,30 23.77 2.706 1.4658 2.213420 r'.50 31.925 7.11 24.51 2.43631 8.22 32.247 5.61 25.10 2.046 1.029 1.8043

Page 26: The Columbia River as a source of marine light scattering particles

17

Table 1. (continued)

Z T S 02 Ni S45 S90

(°C) (mi/i)

DR-IS 3 7,75 32.426 5.84 25.31 1.366 .81544 1.63004() 7.81 32,58 5.81 25.40 i.6o6 .63250 1.264945 7.84 32.724 4.31 25.53 1.288 1.7834 3.0257

50 790 32.206 !i57 25.61 1.533 1.1006 1.8591

60 7.R1 33.124 4.60 25.85 1.481 .91483 1.705770 7.81 33.401 3.82 26.07 1.186 1.0920 2.175880 .76 33.572 3.54 26.21 .17 .S0005 1.613890 7.61 33.657 3.16 26.29 1.13.5 1.208 2.7850100 7.3? 33,777 2.71 26.42 .8023 1,1367 2.1712125 7.01 33.910 2.53 26.58 .75 1.0714 1.8715149 6.66 33.959 2.30 26.66 ---- .o3942 2.0171

DB-20 0 14.78 29.603 6.40 21.89 3.Ri 2.4559 3.096020 2,92 32.279 7.16 24.86 1.409 .9467 1.690030 9.17 32.372 7.05 25.06 1.028 .96973 1.666740 ,74 32,428 6.63 25.16 1.104 .8561P 1.667459 Q,19 32,475 6.18 25.28 1.688 .74369 1.345660 7,63 32.234 4.85 25.57 1.893 .82060 1.6282

70 7.70 33.202 4.27 25.93 1.322 1.3414 2.416175 ?.0 33.338 3,27 26.01 1.271 1.1202 1.978120 7.73 33.427 3.64 26.09 1.372 1.2'425 2.3664

.73 3.540 3.40 26.19 l.31 1.2607 2.474390 7,62 33.639 3.07 26.28 .8312 1.2563 i.9899100 7.63 33.727 3.20 26.34 .8802125 7.10 33.877 2.46 26.54 .6475 .373'J2 .42975

150 (-.80 33.95 2.38 26.64 .4372 .03307 1.6391

DB-25 0 1.3Q 28.080 6.27 20.60 5.652 2.5707. 3.13310 13.86 31.936 6.34 23.79 2.391 1.2248 2,270520 12.15 32.147 6.92 24,36 2.93 1,013 2.086830 9.42 32.414 7.13 25.04 .9562 1.4255 1.930140 8.82 32.449 6.87 25.13 .5973 1.6434 2.0218

8.82 32.442 6.70 25.17 .8693 .89434 1.7732.50

60 8.53 32.488 6.31 25.24 1.135 .94445 1.8255

70 8.35 32.614 6.02 25.37 1.623 .98506 1.9347

75 7.99 32.712 5.56 25.50 1.717 1.0110 1.660380 8.21 32.949 5.17 2.65 i.6n8 .68275 1.392285 8.13 33.093 4.85 25.78 1.155 .77413 1.52830 8.05 33.163 4.69 25.84 i.i6 .73198 1.3088

100 7D4 3.315 4.33 25.98 1.026 .884qo 1.6230125 7.93 3.44 26.27 1.042 .73322 1.3716

150 7.10 33.871 2.49 26.54 .5717 1.6654 2.8878DB-30 0 16.09 26.499 6.26 19.23 3.436 2.5675 3.0607

50 9,00 32.447 6.90 25.14 1.239 1.1923 2.166975 8.33 32.809 5.50 25.52 1.338 .77895 1.473586 8.32 33.055 4.95 25.72 1.640 .79265 1.427691 8.31 33.222 4.72 25.85 1.457 .80357 1.5277lot 0,20 33,479 4.12 26.o6 1,068 257LL9 1.2074111 8.17 33.612 3.78 26.18 .5570 1.4467 2,7109121 8.12 33.640 3.67 2.21 .9621 .6063 1.1741130 7.93 33.713 3.59 26.29 .8524 .60744 12334140 7.81 33.788 3.46 26.37 7L144

150 7.65 33.821 3.30 26./42 ---- 1.°127 2.9974

Page 27: The Columbia River as a source of marine light scattering particles

18

Table 1. (continued)

Z T S 02 Ni S45 S90

St't. J (mi/i) (3)

DB_LI.0 0 16.70 25.206 6.08 18.12 7.435 1.7008 2.090510 13.96 31.679 6.32 23.65 3.'21 1.7081 2.684520 11.79 32.474 6.00 24.69 1.718 .96888 1.731130 10.16 32.525 7.24 2501 .8970 1.026 2.1313

0.72 32.c32 7.05 25.09 .7726 .02018 1.988650 9.35 32.535 6.68 25.15 .8232 1.4200 2.053460 0.02 32.555 6.32 25.22 1.454 .73563 1.973870 8.1 32.727 5,79 25.43 1,420 .60261 1.246780 S.4i 32.978 5.43 25,63 i.cio 1.6153 3.310090 8.41 33,22 4.75 25,89 1.284 1.0750 1.8652100 9,20 33.421 4.24 26.03 1.004 .o6?56 1.7712125 .12 33.711 3.49 26.27 .7291 1.293 2.3308150 7.84 33,838 3.10 26.40 --- 1.2450 2.0276

1C-1 0 16.25 20.940 5,92 21.83 R4 1.1858 1.72003 16.22 2P9t2 5.97 21.86 --- .96718 1.72556 16.24 20.020 5.89 21.82 3.242 .80989 1.570

10 15,86 30.369 6.76 22.24 4.c9 1,2185 1.869720 12.28 32.lco 5.98 24.35 2.464 .87247 1.582730 o.84 32.380 7.37 24.96 1.l3 1.0284 2.1088

0.38 32.457 7.13 2,09 .0544 1.1616 2.270850 9,1 32,521 6.47 2.18 1.250 .61388 1.407355 8.20 32.572 6.16 25.25 1.124 .67832 1.391960 8.91 32.657 5.Q 25,32 1.302 .93750 1.68455

89Q 32.770 .89 25,41 1.802 .85757 1.730370 9,75 32.953 5,43 25.7 1.287 1.4523 2.466275 8,72 3329 .09 25.66 1.185 .89961 1.4692

100 .j6 33.327 U.3 26.01 .9725 .oi8o4 1.6814150 7.60 33.777 2.85 26.' 1.7180 2.8677

MC-2 0 15.53 31.634 5,94 23.29 2.548 .78142 1.40083 14.58 31.626 .03 23.49 p77476 1.50086 i5.c4 31.633 5.05 23,29 1.278 .85013 1.4631

10 i.28 31.769 5.95 23.44 2.930 .73423 1.22.56

20 1.62 32.356 6.31 24,24 1.891 .85085 1.378932 12.21 32.459 6.78 24.60 1.750 1.0224 1.605040 10.64 32,492 7,03 2LJ.91 1.142 .91625 1,646250 9.90 32.497 7.14 25.04 1.018 .93443 1.5285

75 8.82 32.610 6.I 25.30 1.450 2.3084 4.5551100 8.11 33.16 4,99 25.82 1.042 1,2409 2.5231150 900 33.790 3.40 26.36 --- 1.1609 1.6946

MC-3 0 15.86 30.94 5.90 2268 .1962 .84870 1.69433 15.82 30.93 5.04 22,69 --- .88025 1.66926 15.86 30.93 5.92 22.68 2.298 1.2224 2.1076

10 1.77, 31.18 5.95 22.89 3.958 .91711 1.537220 13.59 32.62 6.28 24.45 --- 1.042 1.740030 12.89 32.37 6.55 24,40 2.378 .05831 1.69214n 9.96 32.42 7,20 24.07 1.209 i.6636 2.863950 0.15 32.44 7,30 2.11 .6767 1.6156 2.392675 8.51 32.46 6.20 25.23 1.602 1.4354 3.0454

100 7.89 33.16 14.96 25.87 1.206 1.3144 2,5154105 9.1.8 33.31 4.51 25.94 1.045 1.7636 3.0963149 7.79 33.95 3.08 26.42 .5507 .88342 1,7590

Page 28: The Columbia River as a source of marine light scattering particles

19

Table 1. (continued)

Z T S 02 Ni S45 S90

Stat. j (mi/i) j

MC-4 0 16.Li.LI. 28.729 5.92 20.86 4.290 1.6961 2.5290

3 16.36 29.42 5.95 21.41 4.753 1.1998 2.04036 16.1) 30.24 5.99 22.09 5.182 .97840 1.737610 15.03 31.33 6.08 23.16 3.402 1.1227 1.846720 12.78 32.24 6.75 24.32 2.366 .97788 1.565130 10.51 32.43 7.24 24.88 1.237 1.1427 2.177240 9.79 32.47 7.28 25.04 .8698 1.4467 2.256050 9.36 32.48 7.09 25.11 1.029 .72316 1.5763

75 8.87 32.72 5.93 25.38 .99963 2.0113100 8.41 4.55 7.307 .66110 1.3008149 7.73 33.77 3.38 26.37 .61A9 .98260 1.8242

0 16.76 27.32 6.04 19.72 3.292 1.3506 2.18363 16.53 27.68 6.15 20.05 9.313 3.9800 6.47326 1.57 30.81 6.16 22.65 3.992 6.9934 2.4474

10 i.i4 31.52 6.17 23.29 3.402 1.8726 2.412420 12.05 32.22 6.88 24.45 2.151 1.3538 2.834330 10.13 32.44 7.31 24.96 1.093 .84853 1.626640 9.30 32.42 7.24 25.08 .9924 1.6453 2.337650 92 32.45 .68 25.17 .8951 1.0242 1.6855

8.50 32.40 --- 25.25 .9413 1.3820 2.12558.62 32.5'? 6.25 25.30 1.502 2.5339 5.2966

70 9.13 32.62 6.22 25.11.1 .76698 1.273485 2.37 33.13 5.11 25.77 1.540 1.1381 2.151790 9.31 33.27 4.75 25.89 1.073 .61793 1.313395 8.24 33,3 4.64 25.95 1.258 .75626 1.5619

100 8.13 33.41 4.42 26.03 .899? 2.2366 3,5455150 .73 33,9/4 26.42 .77713 1.4963

?'lc-6 0 16.79 25.94 6.21 18.66 6.059 1.3713 2.22033 16.42 2.29 ,27 19.76 10.46 1.9488 3.02306 1.97 31.16 6.37 23.05 2.753 1.6439 2.3857

10 l'i)L4 3,Lj 6,49 23.35 3.856 1.3203 1.938920 9.7 32.20 7.30 24,8/4 1.605 1.6120 L887930 '06 37,39 7.03 25.10 .6815 .87785 1.476340 .74 6.6o 25.14 .8781 1.5118 1.9162

8.51 32,45 6.47 2.22 1.408 1.3635 2.172075 8.02 32.Q9 .12 25.72 1.341 1.0077 2.0200

100 7.84 33.53 3,81 26.17 .2260 .H1022 1.49891/49 7.21 33.4 2.2 26.50 1.6867 2,7889

MC-7 0 16,47 26.105 6.45 18.85 9.705 3.C26 4.85923 1.73 28.78 6.46 21.13 6.096 ?.T /4.48096 15.17 30.17 6.40 22.24 3.327 2.5382 3.338910 14.89 30.67 6,46 22.69 3.57? 2.5629 3.045430 7.90 32.37 5.16 25.25 1.433 1.0868 1.9294SQ 7.77 32.87 5.01 25.66 1.693 .68628 1.679955 7,97 33.09 /4.81 25.99 1,559 .87479 2,006160 7.89 33.23 4.59 25.92 1.346 .55349 1.267065 7,86 33.34 4.28 26.01 1.107 .56849 1.292770 7.87 33,42 4,21 26,07 1.236 2.6840 5.092675 7.83 33.51 4.00 26.15 1.023 .73826 1.601380 774 33.56 3.67 26.20 1.235 .75980 1.6645

Page 29: The Columbia River as a source of marine light scattering particles

Table 1. (continued)

Z T S

L cJ

MC -7

MC-8

NC-9

MC-l0

NC-il

MC-12

90 7.39100 7.33150 6.75

0 15.963 15.916 13. 7810 12.3820 8.4830 7.5340 7,4750 7.5855 7.7860 7.8865 7.8170 7,7475 7.66

100 7.28150 6.62

0 12.563.10.016 9.67

10 9.3420 7.7930 7.7240 7.6450 7.390 12.053 11.626 11.4910 11.3620 7.9830 7.5140 7.6550 7.500 12.883 12.086 9.55

10 8,9420 7.8230 7.7040 7.6550 7.6075 7.150 12.743 12.766 12.7510 12.0820 7.82:30

757,2;

33.69933.84133.94726.1672..22630. 22931. 59232.32032.63332.8 7633. 11233. 30433. 36533.44033.51033. 54333. 849

31.22331. 96532.17532.27732.89233. 43633. 6 50

33.80130. 97831. 30231.47731. 62632. 61833.05833. 53033. 73430.42 530.85932. 01832. 322

33. 09833. 40833. 59233. 79233. 97130. 82430. 84730. 86231.16833. 21633.74633. 842

02

(mi/i)

2.61 26,362.81 26.482,51 26.646.84 19.026.84 19.076.61 22.587.26 23.904.78 25.135.24 25.514.43 25.71

3,93 25,884.28 26.004.38 26.044.07 26.10

3.83 26.16

3,55 26,202,88 26.501.786.27 23.585.68 24,605.39 24.825,28 24.954.08 25.673.10 26.102.72 26.292.12 26.446.09 23.148

6.03 23.826.13 23.986.16 24.114.49 25.434.40 25,842.88 26.192.73 26.386.44 22,916.22 23.404.96 24.734.78 25.053.77 25.833.19 26.092.83 26.243.01 26.411.98 '6.6i6.51 23.236.52 23.256.54 2.?66.56 23,f23.'0 25,022.42 26.3'2,15 Lp

Ni

1.1245658

1.33510.805.7443.5051.9511.4161.3021.551.86721.1751.102.89901.091

5.8402.7021.8082.6822,0831.3571 .239

3.3282.3141.8263.6382.0241.8761. 3.58

4.0556.6512.8452,792i.6io1.2371.293.8859

.7032.P74,7922,150r)ry) 5

20

S45 S90

2)

1.1031 1.9830.87938 1.65593.0)33 4.73734.8697 5.48704.5601 5.59602.7263 3.17722,9601 3.36541.2495 2.0101.84042 1.6014.94987 2.6584.8266 1.7852.70859 1.4586.88685 1.8376.72413 1.5251.81384 1.8416.62036 1.3243.84265 1.4997

3.6908 4.71593,3464 4.02082.9015 3.78972.6362 3.36471.2926 1.81341.1415 2.02231.3030 .21462.5161 3.40924.5658 5.20945.5601 7.98483.7080 4.55623.1660 3.82511.9408 2.36491.1121 1.79691.3792 2.3ce571.41.76 2,29574.7637 6.00634.8996 5.33812.8917 3.84171.9385 2.64351.6772 2.61031.4844 2.54531.5036 2.64241.5527 2.45674.0454 5.20414.1717 5.42114.24.06 5.47174.0205 5.11393.434 5.00242.2447 2.8/431

1.5700 2.70861.0025 3.0328

Page 30: The Columbia River as a source of marine light scattering particles

21

Table 1. (continued)

Z T S 02 Ni S45 S90

§ J ic.i (mi/i)

MC-l3 0 15.68 24.566 6.87 17.85 12.03 7.1610 8.'4.564

3 13.26 29.608 6.66 22.19 8.143 4.6055 5,50116 11.01 31.640 5.58 24.18 3.940 4.1537 5.0645

10 9.72 32.164 4.67 24.81 3.394 2.9349 3.823420 .2 33.267 3.36 25.96 1.682 2,3547 3,513930 7.60 33.587 2.73 26.24 1.165 12273 2,242040 7.42 33.729 2.51 26.37 .9548 1.5275 2.449250 7.22 33.803 2.41 26.47 .7699 1.1166 1.9667

75 .89 33.938 1.76 26,61 3.3367 5,2679MC-14 0 15.55 25.772 6.66 18.80 2,306 6.3011 7.4663

3 15.48 2c.965 6,61 18.96 10.10 6.446 8.01026 13.72 2c,,14Q3 .90 22.02 6.751 5.1342 6.1236

10 12.13 31.462 6.77 23.84 '3,010 3,5774 4.422520 9.82 32.110 4.93 24,75

25,622.957 2.4674 3.0080

30 7.79 32.831 3.75 2,140 1.5881 2.615240 7.44 33.356 3.20 26.08 - 1,Qc 2.i84250 7.55 --- '-- --- 10.2775 6.8? 33.924 1.73 26.61 .5232 1.5174 2,5254

100 6.6o 33.966 i.66 26.68 2.5209 4.1680MC-15 0 15.97 21.268 6.93 15.27 10.31 10.394 12.586

3 15.23 25.255 7.01 19,46 12.12 6.4398 8,07916 14.17 30.221 6.67 22.87 2.542 3.4015 4.4053

10 13.65 30.927 6.70 23.13 2.708 3.6643 4.596020 12.12 31.490 .38 23.87 3.396 3.5277 4.437030 8.74 32.243 4.78 25.01 2.33240 7.71 32.743 14.10 25.56 1.940 1.2533 2.199550 7.38 33.160 3.64 25,94 1.778 1.6126 2.310160 7.53 33.592 2,80 26,26 .-- 1,5393 2.619365 .62 33.571 2.86 26/23 1.512 1.3801 2.269270 7.48 33.696 2.83 26.34 1.253 1.6268 2.747875 7,37 33,774 2.93 26.41 .9700 .86690 1.722480 7.26 33.91 2.75 26,147 .8203 1.2080 2.4629100 6.86 33.913 2.01 26.60 1,9252 2.4561

MC-16 0 1.31 31.751 6.03 23.43 --- 1.1814 2.16173 15.30 31.739 6.o 23.41 1.307 .89599 1.70907 15.09 31.764 6.10 23.48 2.257 .92428 1.4900

10 14.66 31.844 6.18 23.63 2.718 .93123 1.460920 13.11 32.394 6.46 24.37 1.693 .73346 1.366330 11.72 '32.423 7.07 24.66 1.858 2.4018 2.668340 9,77 32.!436 7.32 25,01 .8919 1.5540 2.362950 9.52 32.484 7.22 25.09 1.191 1.5235 2,279575 8.19 32.670 6.07 25.44 2.475 3.5047 3.773580 8.39 33.100 5.09 25.75 1.359 1.2369 2.170385 8.40 33.221 4.80 25,84 1.782 .88564 1.798390 8.23 33.397 4.43 26.00 .8727 1.1803 2.3006

100 8.14 33.476 4.28 26.07 .8262 .46570 1.1541149 7,52 33.780 3.57 26.141 .48528 1.0725

MC-17 0 15.24 32.149 6.04 23,74 --- .82019 1.40203 15,22 32.075 6.05 23.69 .2686 .83428 1.42216 15.21 32.072 6.05 23.69 .4027 .74090 1.2420

10 i,i8 32.070 6.05 23.70 2.690 .77798 1.3465

Page 31: The Columbia River as a source of marine light scattering particles

22

Table 1. (continued)

Z T S 02 NI S45 S90

Stat. J j (mi/i)

MC-17 20 13,01 32.LJ.30 6.54 214.42 1.995 .7599 1.4209

30 11.12 32.494 7.09 24.82 1.1375 1.8414

40 9,69 32.c09 7.26 25.07 .8364 1.0537 1.8062

50 9.20 32.506 6.75 25.15 1.077 1,1454 2.0668

75 R14 32.745 5.87 25.44 i.34'4 1.3110 2.7615

100 8.40 33.290 4.54 25.89 .9944 1.0554 2.0663

149 7.62 33.763 3.55 26.38 - -

?'C-18 0 14.94 31.954 *15 23.66 .3578 .68199 1.3910

3 14.94 31.959 .10 23.67 ---- .7c602 1.48446 14.°3 31.9c7 6.13 23.67 1.182 ,7o528 1.2066

10 14.73 31.QSfl .07 23.72 2.524 .56820 1.102020 13.06 32.360 6.50 24.36 2.108 .92741 1.395830 11.00 32,438 7.34 24.81 1.517 1.7207 2.979340 9.76 32.464 7.44 25,04 .9888 1.0387 1.865950 9.15 32.462 7.08 25.13 1.057 1.0768 1.752375 7.95 32.c96 6.43 25.41 1.635 1.1754 1.956580 7.85 32,737 6.04 2.55 i,45i .98415 1.898385 7.88 32.877 5.68 25.65 1,670 1.1314 2.675890 7,77 33.042 5.24 25.79 1.196 .49402 1.2381

100 7.84 33.232 4.81 25.93 .9751 .60674 1.2539150 7.80 33.826 3.17 26,41 .56401 1.2684

MC-19 0 15.11 31.761 6.14 23.48 ---- .97769 1.4445

3 15.10 31.758 6.io 23.48 ---- 1.1626 1.75906 15.12 31.758 '.12 23.48 ---- .95543 1.5711

10 15.12 31.762 6.10 23.47 2.262 .79363 1.375320 13.10 31.858 6.49 23.98 2.131 .84623 2.128330 p.46 32.314 7.20 24.97 1.282 4.9769 2.118940 8.86 32,402 6.79 25.13 .8416 .95203 1.836950 P57 32.434 6.49 25,20 1.376 .64529 1.0999

7 7.89 32.91 .19 25.67 1.463 .68989 1.217780 7,98 33.063 .01 25.78 1.218 .70587 1.533085 7.89 '33,13° 4.84 25.86 1.125 .60394 1.381190 7.93 33.233 4.71 25.02 1.298 4.7995 2.1622100 7.87 33.433 4.46 2.09 .8277 .59201 1.3223150 7.53 33.803 3.65 26.1.i3 .57713 1,3543

MC-20 0 14.76 31.692 6.29 23.50 .0769 2.0694 2.7514

3 14.73 31.684 6.29 23.50 2.1289 2.77576 14.76 31.684 6.28 23.49 2.8214 2.0065 2,534410 13.59 31.789 .5? 23.81 2,603 2.3403 2.644730 8.25 32.336 6.15 25.17 1.589 1.3464 1.881840 "57 32.531 5.66 2c.4i 1.189 1.1803 2.1729so 7,50 32.704 5.68 25,57 1.476 .89450 1.4831

75 7.40 33.377 3.73 26.11 1.322 1.1466 2.0929

80 7.64 33.536 3.67 26.20 1.222 .99018 1.819985 7,44 33.589 3.29 26.27 1.194 1.3784 2.608190 7.32 33.658 2,89 26.34 .9881 1.1934 1.9632

100 7,26 33,777 2,53 26.4'12447 2.1829

MC-21 0 14.67 31.185 6.30 23.13 .2640 3.4377

3 14.67 31.185 6.30 23.13 .2640 ---- 3.60106 14.65 31,185 6,30 23.13 1.748 3.730 3.9583

10 14.30 31.255 6,40 23.26 3.846 - 3.929070 9.91 32.107 6,6o 24.74 2.292 1.5Ah6 2.1422

Page 32: The Columbia River as a source of marine light scattering particles

23

Table 1. (continued)

Z

-

T

L1S

i%Dl

02

(in 1/1) .&!Ni

iiS45 S90

L:1MC-21 30 7.98 32,402 .17 25,26 1.572 1.0760 1.7227

40 7,411. 32.619 '5.52 25.51 1.945 .81657 1.458350 7.46 33.103 3.56 25.89 1.612 1.5458 2.4130

75 7.13 33.875 1.24 26.54 .8052 4,6705 6.7147100 6.50 33.964 1.40 26.70 5.4491 7.7418

MC-22 0 13.94 31.430 6.31 23.46 .5435 4.2514 .2512

3 13.93 31.431 6.33 23.47 3.9425 4.99236 13.92 31.427 6.31 23,47 2.115 3.8671 4.5398

10 13.29 31.499 6.25 23.65 5.327 3.9093 4.758615 8.86 32.320 4.35 25.07 2.577 1.8720 2.697120 8.42 32,665 3.76 25.40 2.705 2.5414 3.889330 7.66 33,1454 2.11 26.13 1.835 6.1568 8.699740 7.33 33.822 2.26 26.47 .5463 4.4503 6.118850 7.31 33.859 2.16 26.50 7.3715 io;o4i

MC-23 0 14.67 12.129 6.12 8.54 16.67 32.253 39.905

3 13.25 22.745 5.70 16.93 11.19 21.025 26,8546 13.34 27.658 6.31 20.69 8.495 9.8785 11.80910 12.73 31.258 6.41 23.57 --- 7.2061 8.649915 9.79 12.546 6.17 9.5? 17.82 29.255 34.83120 8.25 32.744 3.70 25.49 2.7581 4.3799

MC-24 0 17.10 1.364 7.18 3.186 59.593 57.848

3 16.o6 1.740 7.02 .18 6.256 56.718 74.9426 16.65 3.241 6.66 1.36 11.10 57,476 63.236

10 15.06 9,447 6.io 6,41 18.3315 9.07 .30,092 3.78 23.30

MC-25 0 12.05 29.931i- 5.76 21.90 7.269 192.40 184.80

3 10.73 30.680 4.92 23.49 8.552 6.1619 7.68916 8.47 33.036 3.36 25.68 2.512 L1..392 4.7857

10 7,66 33.205 3.30 25.93 1,729 2.0989 2.877220 7.60 33.570 2.91 26.23 1.108 1.7351 2.628230 753 33.740 2.78 26.37 .7559 1.7360 2.905414.9 7.46 33.807 2.52 26.43 .8445 2.1361 3.050750 7.29 3.3.863 2.91 26.50 .5935 1.7957 2.840560 7.16 33.887 2.28 26,54 - - 3.5793 5.0794

MC-26 0 12.58 29.279 6.63 22.07 6.614 7.2308 8.32363 11.54 30.728 5.98 23,39 7.787 6.3221 7.44626 8.41 32.403 4.12 25.20 3.155 4.3885 4.9916

10 7.99 32.823 3.93 25,60 2.107 2.9934 3.851820 7.72 33.3c4 723 26.05 1.388 1.9010 2.952030 .6i 33.581 2.62 26.24 1.8509 3.039040 7.50 29.898 2.89 1.7232 2.687950 7.38 33.836 2.01 26.47 4.8074 6.2982

MC-27 0 13.98 28.731 7.00 21.38 6.092 5.5646 6.8774

3 13.58. 30.071 7.06 22.50 7.142 4.8106 5.57096 11.58 31.564 6.20 214.,03 4,759 2.8521 3.252310 9.40 32.260 4.91 24,93 2.709 2.0976 2.844120 7.70 32.868 4.03 25.67 2,130 1.2184 2.210130 7.70 33.14.53 2.94 26,12 1.457 .99840 1.906740 7.55 33.696 2.59 26.34 1.3017 2.441250 7,43 32,Q13 3.12 2c.74 2.5225 3.3874

MC-28 0 12.77 30.8c6 6.72 23.26 2.502 3.8677 4,7537

3 12.69 31.077 6.70 23.44 4.084 3.7919 4.94566 11.64 31.469 6.17 23.94 4.767 3.1982 3.9001

Page 33: The Columbia River as a source of marine light scattering particles

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Page 34: The Columbia River as a source of marine light scattering particles

25

Table 1. (continued)

Z T S 02 Ni S45 S90

J (mi/i)

MC-33 76 7.98 32.859 5.31 25.61 1.087 .57735 1.3836

86 8.29 33.063 4.89 25.73 1.485 .59018 1.3378

91 8.44 33.230 4.66 25,84 1.557 1.3472 1.361796 8.26 33.354 4,29 25.96 1.885 .65623 i.05i8

101 8.12 33.558 3.96 26,14 .9144 .84500 1.5030125 7.93 33.773 3.34 26.34 .6221 .44801 1,1314

150 7,514. 33,920 3,18 26.44 .93317 1.9536

MC-34 0 16.02 29.628 5.94 21,64 .7643 .98559 1.8123

3 1.94 29.624 5.97 21.66 ---- .99540 1.91036 15.97 20,625 5,97 21,65 1.524 .81265 1.5798

10 1.93 29.731 5.97 21.74 4.592 .86646 1.731620 14.79 32.127 6.03 23.85 2.852 .71696 1.3146

30 11,56 32.394 6.97 24.67 1.784 .86917 1.593040 io,iS 32.497 7.16 24,99 .9909 .86170 1.2870

50 9.68 32.514 7.13 25,08 .8193 .74089 1.2757

75 9.12 32.618 6.42 25.25 1.332 .83125 1.3679

100 9.22 33.009 .4o 2s.6o 1.202 .80852 i.56i4

125 8.26 33.479 4.10 26.'6 .8889 .77831 1.4823

io 8.o4 33.81 3.71 26.25 .49483 1.1454

MC-35 0 14.66 32.438 6.09 24,10 .3831 1.1793 1.4339

3 14.61 32.430 6.06 24,10 .77770 1.3369

6 14.64 32.432 6.08 24.09 .98920 1,734210 14.64 32.&i.32 6.o8 24,09 1.798 .64700 1,190520 13.7 32.49 6.143 24.41 1.872 .65299 1.1995

31 11.23 32.485 7.01 24.80 1.416 1.0569 1.8386

41 10.31 32,540 7.09 25.00 .8247 1.1354 1.8320

51 0,97 32,60 7,14 25.07 .9282 1.001 1.7148

76 9.13 32.656 6.40 25,29 1194 1.1079 1.6559

101 8.55 32.993 5.55 25.64 1.224 .97675 1.6945125 8.34 33.409 4,53 26.00 .92'l-4 .99940 1.7107150 8.16 13.655 3.91 26.22 .7395 .70907 1.3815

MC-36 0 14.68 32.396 6.11 24.06 .4082 .69739 1.2709

3 14.67 32.397 6.11 24,06 .92916 8.43176 14.68 32.394 6.11 24.06 .79577 1.3860

10 14.67 32.395 6.08 24.05 1.211 .64328 1.3102

20 14.14 32.436 6.40 24.20 2.400 .85926 1.449430 11.52 32,522 6.95 24.78 1.514 .90974 2.03034o 10.35 32.5c8 7.11 25.01 1.150 .9738 1.910850 0.62 32.566 .92 25.14 .84io 1.4206 2.10075 8.91 32.652 6.37 25.32 1.222 .76295 1.4572

100 9.56 33,057 .37 25.69 1.186 .65542 1.3621

125 8.55 33.503 4,22 26.04 .9342 .6i84 1.3812

iso 8.25 33.731 3.49 26,26 .78268 1.6304

MC-37 0 14.73 32.359 6.13 24.02 .314.91 1.167 1.8621

3 14.72 32.361 .13 24.02 .9593 1.6855

6 14.74 32.360 6.13 24.01 .8663s 1.2824

10 14.74 32,360 6.11 24.01 .3168 .74149 1.2040

20 14.71 32.362 6.10 24.02 1.080 .0951 1.5917

o 14.28 32.396 6.36 24.14 2.438 .96174 1,4171

Page 35: The Columbia River as a source of marine light scattering particles

26

Table 1. (continued)

Stat.

Z

JJT

c_

S 02

(mi/i)

Ni S45 S90

(3)

MC-37 40 11,72 32.17 6.87 24.73 1.5114' .89690 1.368250 10.33 32,LI.86 7.23 24,96 .8820 1.2134 1.5436

75 9.30 32.529 6.56 25.16 1.245 1.1387 1.6159100 8.61 32.883 5.65 25.5 1.305 .98395 1.7927125 8.04 33.311 4.77 25.97 1.030 .76522 1.3777150 7.97 33.646 3.68 2,24 .87578 1.6805

MC-38 0 15.35 32.138 5.90 23.72 .68029 1.19126 15.36 32.128 5.88 -- .71499 1.309210 15.36 32.139 5.92 23.7fl .2403 .86164 1.345)4

20 15.32 32.129 5.92 23.71 2.414 .83710 1.3138

30 13.63 32.420 6.33 24.29 1.869 .74385 1.206640 11.88 32.437 6.75 24,64 1.829 .95686 1.5703

50 10.28 32.493 7.10 24.98 .9005 .78773 1.4322

75 9.21 32.537 6.46 25.18 1.388 .78069 1.3657

100 8.05 32.922 5.37 25.66 1.295 .53051 1.1460125 7.92 33.431 4,32 26.08 .9177 .62638 1.2558

150 7.71 33.666 3.90 26.29 .149762 1.1849

NC-39 0 15.39 32.013 5.98 23.61 .4755 .91179 1.5110

3 15,37 32.019 6.00 23.62 --- 1.1340 1.81316 15.39 32.018 5.97 23.61 .3664 1.0512 1.549310 15.37 32.025 5.98 23,62 .5174 1.0596 1.522820 15.31 32.040 1,00 23.65 2.679 90775 1.377730 12,90 32.322 6.60 24.36 2,054 .92130 1.748340 11.36 32.500 6.94 24.79 1.549 1,4436 2.466250 10.17 32.534 7.05 25.04 .7928 1.3574 2.0781

75 9.42 32.584 6.57 25.28 1.155 .92614 1.6191100 8.85 32.894 5.68 25.52 1.435 1.0570 1.9182125 8.38 33.454 4.39 26.03 .9106 .81638 1.398?150 8.17 33.686 3.70 26.24 --- 1,1511 1.9307

MC-40 0 15.28 32.163 6.02 23,76 .95234 1.11.120

3 15.22 32.158 6.00 23.76 .91424 1.49516 15.26 32.160 6.00 23.75 .80113 1.3366

10 15,28 32.158 6.02 23.74 .5871 .96551 1.430820 15.16 32,169 6.02 23,78 3,266 .82502 1.3024

31 10.65 32.551 7,07 24.95 1.17)4 1.1591 1.8765

41 10.16 32.619 7.01 25.09 .9286 1.4216 2.0345

51 9,43 32.574 6.66 25.18 .8996 1.0708 1.534576 8.82 32.714 6.21 25.38 1.513 .84838 1.4692

101 8.41 33.362 '.54 25,95 1.019 1.0106 1.7767125 8.18 33.634 3.92 26.20 .8221 .60623 1.4760

150 7.89 33.800 3.57 26.37 .76636 1.2719

NC-4i 0 i.6o 32.003 6.oi 23.56 .1489 .,91609 1.7048

3 15.58 32.001 6.07 23.56 .8110 .84033 1.4260

6 15,56 32.021 6.01 23.58 1.529 1.1129 1.7830

10 15.39 32.100 6.02 23.67 .8188 .88760 1.7845

20 15.18 32.125 6.04 23.74 2,888 1.2092 2.3906

30 12.25 32.433 6.86 24.57 1.832 .97924 1.750640 10.67 32.503 7.17 24.91 1.136 .6865i 1.4763

50 9,96 32.506 7.22 25.04 1.068 .73258 1.3071

Page 36: The Columbia River as a source of marine light scattering particles

27Table 1. (continued)

Z

J1T

LclS

1i

02(mi/i)

Ni S45 S90(3)

MC-41 75 9.08 32.696 6.04 25.33 1.62 .57028 1.2152100 8.69 33.124 5.25 25.72 1.024 .54845 1.3305125 8.34 33.387 4.69 25.99 1.070 .52631 1.2858150 8.00 33.697 3,94 26.27 .55161 1.3764

?1C-42 0 14.72 30.898 6.22 22.90 .5068 1.1086 1.626310 14.70 30.926 6.28 22.93 3.591 1.0836 1.845120 13.05 32.170 6.8 24.22 2.601 .83041 1.564430 10.42 32.424 7.17 24.89 1.269 .5684 1.180340 9.71 32.475 7.21 25.06 .8970 .73278 1.288350 9.36 32.510 6.72 25.14 1.091 .79224 1.506775 8.86 32.788 5.78 25.43 1.536 .57709 1.135580 8.84 32.933 5.43 25.55 1.911 1.5555 1.360785 8.60 33.125 5.02 25.73 1.820 .69252 1.552890 8.35 33.282 4.68 25.90 1.380 .61208 1.2482100 8.03 33.462 4.45 26.09 .8906 .74194 1.2331125. 7.93 33.702 3.80 26.29 .7445 .67976 1.1887150 7.67 33.826 3.75 26.42 .60875 1.1655

NC-43 0 12.13 31.816 6.71 24.12 .4480 2.3511 2.82693 12.14 31.819 6.71 24.12 2.4356 2.99346 12.16 31.815 6.74 24.11 .2563 2.4840 2.8253

10 12.13 31.816 6.74 24.12 2.305 2.8489 3.385020 10.22 32.061 6.90 24.65. 1.891 1.8668 2.243730 9.07 32.296 6.64 25.01 1.580 1.3732 2.169040 8.25 32.446 6.23 25.26 1.575 .76175 1.516345 7.85 32.526 6.12 25.38 1.601 .67819 1.284150 7.96 32.710 5.50 25.51 1.387 .78141 1.601255 8.42 32.920 5.33 25.60 1.241 .66866 1.472176 8.23 33.295 4.45 25.93 1.273 .69929 1.4729

100 7.96 33.746 3.58 26.32 .8150 .75193 1.4507125 7.50 33.866 3.34 26.48 .6236 1.5314 2.5022149 7.17 33.921 3.01 26.57 .75484 1.4370

Mc-44 0 10.75 32,249 6.50 24.69 .5742 3.1152 3.55093 10.75 32.244 6.53 24.70 2.7175 3.40016 10.77 32.244 6.53 24.70 .6781 2.8165 3.3277

10 10.62 32.239 6.50 24.72 2.624 2.7662 3.324520 7.97 32.583 5.83 25.5i 1,224 .78909 1.292725 7.80 32.651 5.60 25.48 1.490 .63325 1.245630 7.98 32.824 5.30 25.59 1.369 .77236 1.342240 8.09 33.082 4.46 25.78 1.507 .72838 1.399350 7.95 33.351 3.77 26.01 1.287 .77031 1.466475 7.51 33.790 3.27 26.42 .8228 .99621 1.6945

100 7.06 33.926 2.31 26.59 3.4608 5.2418MC-45 0 8.91 33.167 5.22 25.72 .6751 2.5423 3.6042

3 8,73 33.145 5.03 25.73 1.262 2.8211 3.04986 8.30 33.121 4.4 25.78 1.194 1.8236 2.6424

10 8.24 33.190 4.28 25.84 .8495 1.5472 2.36Q920 8.17 33.265 3.93 25.91 1.387 1.5687 2.689025 8.25 33.403 3.67 26.01 2,284 1.4417 2.228730 7.87 33.664 2.98 26.27 1.775 2.4123 3.8049

Page 37: The Columbia River as a source of marine light scattering particles

28

Table 1. (continued)

Z T S 02 Ni S45 S90

Stat. J (mi/i) j

MC-45 35 7.55 3.802 2.51 26.42 .9644 2.8036 4.645240 7,42 .843 2.38 26,147 .5970 4.0580 5.645245 7.39 33.853 2.40 26,49 3.9697 6.6340

!1c-46 0 9.17 33.058 5.61 25.58 2.209 3.5732 4,7347

3 8.92 33.175 4.99 25.73 1.746 3.0955 4.39116 8.32 33.175 4.18 25.82 1.282 3.3464 3,452710 8.56 33.311 4,37 2.89 1.380 2.5798 3.654420 8.60 33.558 4.16 26.08 1.550 3.0972 5.472430 7.85 33.723 2.69 26.32 .8172 2.7591 4.1708140 7.65 33.771 2,38 26.38 --- 3.0901 4.4724

MC-47 0 9.18 33.368 5.22 25.82 .7949 4.8038 7.5824

3. 9.18 33.376 5.16 25.94 .9157 5.7827 6.61256 9.12 33,392 5.11 25.87 1.290 4.7657 6.153910 8.95 33.451 5.00 25.914 1.761 4.4290 5.304820 7.97 33.653 2.92 26.25 .9028 3.5367 5.016530 7.79 33.727 2,50 26.33 .6561. 4.8452 6.237640 7.71 33.767 2.37 26.37 5.2754 7.0554

MC-48 0 9.30 32.991 5.35 25.51 3.061 3.9678

3 9,53 32,887 5.148 25.141 2.589 2.4727 3.08386 9.13 33.061 5.38 25,61 2.528 3.1165 4.049010 8.82 33.332 4.70 25.86 1.730 2.7165 3.855220 8.07 33.565 3.18 26.16 1.316 2.2288 3.256230 7.74 33.726 2.37 26.33 .8596 2.1849 3.4077140 7.62 33.798 2.21 26.141 .6659 2.5265 3.580950 7.49 33.829 1.87 26.45 5.1508 7.4803

MC-149 0 10.03 33.067 5.76 25.145 .7230 3.1185 4.2966

3 10.04 33.070 '.82 25.46 2.115 3,37914. 3,75146 9,140 33.104 5.47 25,60 2.114 3.1705 4.477710 8.84 33.228 5.13 25,78 1.422 3.1553 4.107820 8.62 33.441 4.46 25.98 1.096 3.3998 14.2645

30 8.50 33.573 3.99 26.10 1.512, 3.9Q81 4.936140 7.67 33.707 2.67 26.33 1.7778 24542

MC-60 0 11.86 33.143 9.06 2'.19 1.8140 4.7926 7.37433 8.93 33,147 8.93 25.29 2.409 6.6068. 6.81766 10.26 33.120 7.56 2r,47 2.994 4.8687 6,4585

10 7.95 33.124 3.78 2c.93 1.808 1.5154 2,12320 7.73 33.1+96 3.14 26.16 1.381 1.3705 2.037330 7.55 33,706 2.86 26.35 i.oi14 .98859 1.719640 7.43 33.815 2.36 26,45 .8109 1.0023 1.950450 7.32 33.877 2.06 26,1 1.9616 2.8742

MC-51 0 11.43 33.198 9.19 25.31 i.14414 6.6532 9.0619

3 11.08 33.191 9.17 2.38 1.999 6.5680 8.08046 10.35 33,178 7.66 25.50 1.377 7.1209 8.2337

10 9.89 33.202 6.65 C.J 2.642 6,1292 6,661220 7.84

7.5733.665 2.46

1.97 '6.140i.ii4 1.6225 2.5328

30 33.775 1.042 1.8307 3.039840 7.41 3.884 1.61 2(.50 2.6444 3.9727

MC-52 0 11.87 33.176 --- 6.00i6 8.86712 11.88 33.126 7.30 7.13 2.981 4.2739 5.1149

5 10.33 33.109 7,59 2,45 1,302 6.3556 6.7211

9 10.03 33.140 6.63 25.52 2.523 5.1232 5.6806

Page 38: The Columbia River as a source of marine light scattering particles

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Page 39: The Columbia River as a source of marine light scattering particles

30

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Figure 3. Salinity distribution on the sea surface.

Page 40: The Columbia River as a source of marine light scattering particles

[1

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S / S

0

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SI.

31

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Figure 4. Scattering particle distribution on the sea surface.

Page 41: The Columbia River as a source of marine light scattering particles

32

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32 3' 30 /29 28 .'.-.-,

AOM 26

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RT

44°N 32 33 -

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Figure 5. Salinity distribution on the 3m surface.

Page 42: The Columbia River as a source of marine light scattering particles

33

II I

I3(45)xIO2(m-str

4.0

S

50iWPORT

Figure 6. Scattering particle distribution on the 3m surface.

Page 43: The Columbia River as a source of marine light scattering particles

N

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0

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34

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)X32 33

32 31 n__/ 31

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Figure 7. Salinity distribution on the lOm surface.

Page 44: The Columbia River as a source of marine light scattering particles

35

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(45)xId2(m-Str1'

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45°N/ 1I

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Figure 8. Scattering particle distribution on the lOm surface.

Page 45: The Columbia River as a source of marine light scattering particles

II

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Figure 9. Salinity distribution on the 2Orn surface.

Page 46: The Columbia River as a source of marine light scattering particles

37

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4°N ..:

WPORT

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44°N ,/ ) 3.0

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F.- w U)

Figure 10. Scattering particle distribution on the Z0m surface.

Page 47: The Columbia River as a source of marine light scattering particles

38

S S S ,,

5;

o4!1S

-o?

S . S IS

I1

,./

/

-,

S

/

I5°N I

S S S.

I32.5 32.5

/ wpo/i\ 33.0

I

S ' S IS S'SI/

SI33.5I

,I

4401,

/

,32.5-;.

Figure U. Salinity distribution on the 30m surface.

Page 48: The Columbia River as a source of marine light scattering particles

3.0 507.0 I

I

I3(45)xIO (rn-str

///$4°N

!O .:

/1 I

/ /

/ V (

I

r0

44°N

I I I

I.OZL9

Figure 12. Scattering particle distribution on the 30m surface.

Page 49: The Columbia River as a source of marine light scattering particles

25

50

=I.-

Iiic 7

100

125

150

20n.m. 40n.m.. - . a,' I A -,' -- -

:\.

I

1s (%)1

Figure 13. Salinity distribution on Section I. 0

Page 50: The Columbia River as a source of marine light scattering particles

=I-

a-wc

25

50

100

125

150

20n.m. 40n.m.IV1.f.J I IVI-'It I I

2..72.

Figure 14. Scattering particle distribution on Section I.

[ (5) x jo2 (m-str)1]

Page 51: The Columbia River as a source of marine light scattering particles

20n.m. 40n.m.'MC-25 MC-141 I I

MC-6° r I 6

¶:i iT\ HT7

Figure 15. Temperature distribution on Section I.

DB-40

[Temperature (°c)]

Page 52: The Columbia River as a source of marine light scattering particles

=I-0LLI

25

50

75

100

125

150

Figure 16. Sigma-t distribution on Section I.

Page 53: The Columbia River as a source of marine light scattering particles

'I

25

50

I-0Iii

a 75

100

125

1 5C

20fl.m. 40flmlit' IA IIA('_ flR4fl-I.--

-- 6. - - - -

-

7

4TNiiIIIJS

3

NFigure 17. Oxygen distribution on Section I.

S

[02 (mI/liter)]

Page 54: The Columbia River as a source of marine light scattering particles

0

25

5O

zI-0wc 75

100

125

150

MC-12 MC-13 MC-14 MC-15 MC-IG110n.m. zpn.m.

[S (%o)]

Figure 18. Salinity distribution on Section II.Ui

Page 55: The Columbia River as a source of marine light scattering particles

I-0wc

U

25

50

100

125

MC-12 MC-3 MC-14

I 0 B.

EEEEEEE

MC-15 MC-16

un.m.-I-

150[

Figure 19. Scattering particle distribution on Section II.

t (15) x iO (m-str)]

C'

Page 56: The Columbia River as a source of marine light scattering particles

-II

0tLI

c

25

50

100

125

MC-2 MC-13 MC-14 MC-15 MC-.t6

I un.m. 11.111.

I I

S. - .

1501

Figure 20. Temperature distribution on Section II.

\ '. IS

rnperature (°C)J

Page 57: The Columbia River as a source of marine light scattering particles

0

25

5o

I-0Luc 75

100

125

1 5C

MC-12 MC-13 MC-14 MC-15 MC-16ton.m.

2pn.m.

. '265

i

Figure 21. Sigrna-t distribution on Section II.

Page 58: The Columbia River as a source of marine light scattering particles

U

25

50

Ia-LU

75

100

125

150

MC-12 MC-13 MC-4

ii

MC-IStim. Z.On.m.

1w_I

iitH

[02 (m1/Jter)]

Figure 22. Oxygen distribution on Section II.

Page 59: The Columbia River as a source of marine light scattering particles

25

50

=I$ijcD 75

100

125

150

Figure 23. Scattering distribution on Section III. u-I

C

Page 60: The Columbia River as a source of marine light scattering particles

0

25

- 50

xI-0wci

100

125

150

I On.m. 20 n.m.

MC-5 MC-4

32

335

-[S (%)J

Figure 24. Salinity distribution on Section III. (B

Page 61: The Columbia River as a source of marine light scattering particles

2

I-0w

1

1

.Yf-.-.'.

3O.1.

0 .

S

S S

5.'\S

S 5

.

-15 -0 -25 -O -'fU 'vi'--'

-2.O

_-1.0S 1.0

S S

.. S

S S

S

I

S

S

S

S

S S

S

S

I (45) X 102 (m-str]

Figure 25. Scattering particle on Section IV.U.'

t\)

Page 62: The Columbia River as a source of marine light scattering particles

L

25

50

F-

0w

75

100

125

- -10 -? -0 - -iO -40 [1

32

S S S

1501

Figure Z6. Salinity distribution on Section IV.

S

[S (%o)]

Page 63: The Columbia River as a source of marine light scattering particles

a-w

1O(

1 2

1 5(

Figure 27. Scattering particle on Section V. U,

Page 64: The Columbia River as a source of marine light scattering particles

55

RESULTS

General Features of the 1968 Summer Columbia River Plume

The area distribution of the Columbia River plume observed

during the 6806C Cruise is presented in Figures 3 to 10 in terms of

salinity and particulate concentration. The Columbia River plume

in the summer is characterized by a tongue oflow salinity, high

temperature, and high particle concentration extending south or

southwest from the river mouth. The orientation of the plume is in

agreement with the general seasonal characteristics of the plume,

and its simple tongue-like shape clearly indicates the Columbia

River as the single source of the fresh water in the region.

One method of delineating the plume is to use some character-

istic isopleth as a boundary. Budinger et al, (1964) suggested that

the 32. 5 ppt isohaline is a suitable boundary for the Columbia River

plume. In the vertical section along the plume axis, the isohalines

(Figure 11) seem to suggest the 32.0 or 32.25 ppt isohaline may be

a better choice of the plume boundary in this case. The salinity vs.

depth curve of a station near the plume axis shown in Figure 28

clearly indicates that the boundary between the fresh river effluent

and the more saline ocean water is located at approximately ZOm

depth, which corresponds to the 32.25 ppt isohaline. The numerical

value of the salinity plume boundary may vary from year to year as

Page 65: The Columbia River as a source of marine light scattering particles

I.-0w

ST.

27 29 31 3314

35I6

Figure 28. Temperature and salinity vs. depth curves forstations MC-5 and MC-6.

56

Page 66: The Columbia River as a source of marine light scattering particles

57

flow conditions change.

The Columbia River plume as defined by the 32.25 ppt iso-

haline has a maximum width of about 110 nautical miles and extends

south or southwest to about 250 nautical miles from its source near

Astoria, Oregon, and is contained within the upper 30m of water.

The horizontal plume defined by 32. 25 ppt isohaline can be

very closely approximated by the isopleths of 24.0 sigma-t and 15°C

temperature in the 3m surface (Figures 29 and 30). The bottom

boundary of the plume can also be drawn approximately by the 25. 0

sigma-t and 11 to 12 degrees Centigrade isotherm which correspond

closely to the boundary set by salinity. The bottom boundary values

of sigma-t and temperature are noted to be different from those of

the edge boundary in the 3m surface. This is the result of the heat-

ing of the surface water by the solar radiation.

The particle concentration analyzed in the same method as the

other parameters shows the isopleth of particle concentration along

the outer plume boundary in the sea surface, 3 (45) = 1.0 x 10

(m-str)', is in fair agreement with the boundaries set by the other

parameters, but with considerable differences along the shore side

of the plume (Figure 4). The main reason for the differences ob-

served between the particle distribution and the salinity distribution

is that the coastal water acts as a disturbing source of particles

while the low salinity water has come only from the mouth of the

Page 67: The Columbia River as a source of marine light scattering particles

[1

SIGMA- T

.

N

.

0F.-

0wc,J

23 24 25

.I2

Figure 29. Sigma-t distribution on the 3m surface.

Page 68: The Columbia River as a source of marine light scattering particles

.

.

0

TEMPER

5 6

59

).HT. t

I5?% .;ç.

. S

6

/ //(PT/5/ I

/I

0IL)

cJ

Figure 30. Temperature distribution on the 3m surface.

Page 69: The Columbia River as a source of marine light scattering particles

Columbia River. The large particle concentration of the coastal

water on the shore side of the plume is primarily due to the high

biological productivity associated with coastal upwelling, and second-

arily due to the sediments disturbed by the water in shallow water.

This is due to the nearer proximity of the phytoplankton bloom, rela-

tively larger volume of the phytoplankton source, and more involved

process of transport and suspension of denser bottom sediments.

Consequently, the particle concentration contrast between the plume

and oceanic water on the shoreward edge of the plume decreases as

the downstream suspended load decreases and as the effect of the

coastal source increases.

The axis of the Columbia River plume in 3m depth as defined

by the different parameters used is presented in Figure 31. The

axes of the plume delineated by the different parameters nearly

coincide and the small deviations seem to be almost within the limits

of error. The plume axis defined by particle concentration, how-

ever, is shorter than that defined by salinity: the tongue-shaped

feature of the plume in particle concentration vanishes at about 100

nautical miles from the source (Figures 4 and 6).

The Columbia River plume is clearly identified and character-

ized by the high concentration of particles for about 100 nautical

miles downstream from its source in spite of the disturbing effects

from the nearshore water along the Oregon coast.

Page 70: The Columbia River as a source of marine light scattering particles

46

45

44

43

61

$27 $26 $25 24

SCATTERINGA TEMPERATURE

Alo SALINITY

' SIGMA-I0,

Al

QUINA

hi!

A/il

Figure 31. Columbia River plume axes defined by salinity,temperature, sigma- t, and scattering particleon the 3m surface.

Page 71: The Columbia River as a source of marine light scattering particles

62

In three cross sections, at the river mouth, at about 30 nm. from

the river mouth, and at about 60 nm. from the river mouth, the total

particle content was checked by the product of the cross-sectional

area of the plume defined by 32.25 ppt isobaline times the mean

particle concentration. The products for the three cross-sections

agree within five percent. The same computations for two more

cross-sections further downstream, one at 90 nm and the other 120

nm from the river mouth showed a marked decrease. Since the

particle distribution in the last cross-section, the one at 120 nm from

the river mouth, shown in Figure 27, unmistakably indicates no

plume particles, we may consider the product of the cross-sectional

area and the mean particle concentration computed for this section as

the value of the ambient water. Subtracting the value of the ambient

water from the values of the other cross-sections, the fourth cross-

section gave about 30 percent of the first three sections.

On the basis of the above estimates, the particle content of the

Columbia River plume is a conservative property of the plume water

over a distance of 60 nm and this distance corresponds to about ten

days if Frederick's (1967) 12 cm/sec surface current is assumed.

There is no indication in Figure 14 of a large number of sink-

ing particles in the water below the plume axis about 60 to 90 nm

downstream from the river mouth. The salinity distribution in the

10 and 20 meters (Figures 7 and 9) shows a low salinity center

Page 72: The Columbia River as a source of marine light scattering particles

63

located about 120 nm downstream from the river mouth. This ex-

tends the salinity plume along its axis in the downstream direction.

An examination of the particle distribution indicates that the low

salinity center mentioned above does not correspond with high

particle concentration. This fact suggests that the portion of the

plume water indicated by the low salinity center has gone through a

complicated history instead of a simple form of the plume shown in

the present data. If this is the case, then the particles contained in

the water at the low salinity center had been lost for some time and

consequently the water is considerably older than that at the termi-

nus of the tongue-shaped plume defined by the particle concentration.

The suspended particles in the plume water will slowly sink

down below the plume water, and in time particle concentration be-

comes non-conservative property. It was shown to be conservative

over a distance of 60 nm and a period of ten days. If a steady de-

crease of concentration is assumed, the particle concentration should

approximately be conservative for another three to five times 60 nm

and ten days, that is another 180 to 300 nm and 30 to 50 days.

Because of the seasonal variations of the wind system, the

plume delineated herein is in the transition from winter to summer

plume, and the plume will extend further south to southwest in time.

During the spring, before the northerly wind becomes predominant,

the Columbia River plume was flowing northward and a separate cell

Page 73: The Columbia River as a source of marine light scattering particles

64

of plume water was found at about 50 nautical miles north of the

Columbia River mouth during 8 to 24 May, 1961 (Budinger et al.,

1964). As the summer wind system developed, the pool was carried

downstream by the wind as a body of effluent. A surface salinity

distribution observed during the period of June 7 to 19, 1962, which

was seasonally about two weeks earlier than the observation herein,

is shown in Figure 32 (Budinger et al., 1964). It has a separate low

salinity cell located to the offshore side of the present fresh plume

axis, but it does not contribute to the extension of the present plume

length. When this '62 plume is compared with that of the '68 plume,

it is easy to see that the '68 plume could have resulted from a move-

ment of the low salinity center from the '62 position in the down-

stream direction. An estimate of the drifting speed of such a pool

was made using monthly mean wind at 45°N, 125°W taken from daily

surface weather map (Fisher, 1969), and geostrophic current at the

sea surface computed from hydrographic data taken from both the

NH-line and the DB-line each month. The method of computing drift

is given by Budinger et al, (1964), which provides an estimate of the

predicted plume position by adding the geostrophic current and

Ekman transport. The result of computation are listed in Table 2.

All the values of transport (drift) are north-south component. As

Budinger et al. (1964) noted, the use of monthly mean wind instead

of the actual wind in wind stress computation may introduce a

Page 74: The Columbia River as a source of marine light scattering particles

65

Page 75: The Columbia River as a source of marine light scattering particles

66

considerable error, and the error tends to cause the result too small,

It can be seen from Table 2 that the monthly total drift in April and

June is about one half of that in May. The total computed drift in

May and June is about the same as the distance from the river mouth

to the terminus of the plume determined by particle distribution,

The lowest value of drift in April may be interpreted as the period

when the pool was stagnant.

Table 2. Meridional components of geostrophic current and Ekmantrans port.

April May June

v-component of geo-strophic current,Vg (cm/sec) 0.8578 4.5246 2,4193

Monthly mean wind (m/sec),u - 3,04 - 1,44 - 0,645v 4,34 2,14 4.985

Ekman transport2(gm/(cm-sec)) x 10 45. 7515 10. 5495 9,2084

Ekman transport velocity,V (cm/sec) 1. 525 0,3515 0.307

Total velocity,Vg + Ve (cm/sec) 2.4828 4.8761 2.7263

Monthly total drift,nautical miles 33,332 68.2103 38.135

Page 76: The Columbia River as a source of marine light scattering particles

67

A thick layer of particle maximum is found on the offshore side

of the present plume axis below 30m depth (Figure Z3). Its thickness

increases down to deeper water as the distance from the plume axis

toward offshore direction increases. Thickness of this layer is about

50m at MC-4 and about 90m at MC-3.

Flows

The plume region, as described earlier, reveals a weak

southward surface flow. During the summer season a persistent

wind from the north contributes to a more steady southward surface

current. The plume orientation clearly results from these current

and wind conditions, This northerly wind also causes an upwelling

phenomena along the coast (Smith, 1964), The surface water under

the northerly wind stress is transported offshore and water from the

deeper layer upwells near the coast to replenish the transported

water.

The coastal upwelling is clearly indicated by the upward slope

of the isopleths of temperature, salinity, density, and particulate

concentration toward the shore in the vertical section across the

plume (Figures 18 to Z8). It is also noted by the band of cold water

Page 77: The Columbia River as a source of marine light scattering particles

along the coast. One of such distribution of cold temperature is

shown in Figure 30.

In a previous paper (Pak, Beardsley and Smith), an off-

shore subsurface flow was discussed in connection with a tempera-

ture inversion and a tongue of high particle concentration under up-

welling conditions. In the above discussion, the temperature in-

version and the corresponding scatterance maximum and minimum

transmittance was interpreted as the result of a flow along the slant-

ed permanent pycnocline. The water which flows along the perma-

nent pycnocline was formed from the dense upwelled water, modi-

fied by the solar heating, mixed with the warmer and less saline

surface water, and supplemented with particles of phytoplankton

products. The upwelled water originating from a depth below the

permanent pycnocline undergoes these modifying processes, and the

resulting water becomes similar in density to that at the bottom of

the permanent pycnocline. As this water is carried offshore by the

northerly wind, it tends to flow along the slanted pycnocline since it

is denser than its neighboring water.

Another subsurface offshore flow is likely to occur from a

consideration of the continuity of upwelling and the existence of the

plume. The process of the formation of this source water is entire-

ly analogous to that of the offshore flow along the permanent pycno-

dine except that the final density of the offshore flow is smaller than

Page 78: The Columbia River as a source of marine light scattering particles

that of the permanent pycnocline. Thus the water does not sink to

the permanent pycnocline, but stays near the surface until it meets

with the Columbia River plume. Then it dives under the plume. The

pronounced pycnocline at the bottom of the plume, sloping downward

offshore, acts like a barrier for the denser water moving offshore.

The particle concentration plotted against temperature on

Section II is presented in Figure 33, showing that a tongue of water

of high particle concentration is associated with 11°C temperature.

The 11°C isotherm in Figure 20 corresponds to the particle maxi-

mum located at the lower part of the plume in Figure 19. This

layer is also associated with an oxygen maximum slightly below the

particle maximum. The difference in the depth between the particle

and oxygen maximum may partly be explained by the fact that the

oxygen maximum is controlled by both the nutrients associated with

the particle maximum and an optimum amount of sunlight.

The particle distribution to the north of the Columbia River

mouth at the 30m surface (Figure 12) under the southward flowing

surface layer, indicates that the large particles which sank quickly

from the river plume are flowing northward, which conforms with

the current measurements of Collins et al. (1968). The evidence of

the northward flow in the deep layer is also found in the distribution

of sediments originating from the Columbia River. Gross and

Nelson (1958), by means of a radioactive tracer method, found that

Page 79: The Columbia River as a source of marine light scattering particles

oc

15

Li'

5

MC-13 MC-14 MC-15 MC-I6

8 9 10 1099__j/

4

-r

Figure 33. Temperature vs. scattering particle on Section II.

2

-.1C

Page 80: The Columbia River as a source of marine light scattering particles

71

Columbia River originated sediments are distributed to the north

and west of the Columbia River mouth, Duncan et al, (1968) showed

that the Group I clay minerals (Figure 34), which were derived from

the lower Columbia and Snake River sub-basins are found primarily

north and west of the Columbia River mouth.

In addition to the coastal upwelling driven by the wind system,

it is also conceivable that the entrainment process suggested by

Tully (1958) exists, In that case upwelling of the deep water occurs

under the fast moving plume especially around the river mouth. The

entrainment of deep water by fast moving surface water seems to be

analogous to the upwelling of deep water resulting from the offshore

transport of surface water driven by the wind except for the difference

in the driving force, The present data near the river mouth shows

the upwelling effects but wind driven coastal upwelling cannot be dif-

ferentiated from that by the entrainment,

The offshoreward subsurface flows discussed above may be

performing an important role of biological interest. The existence

of the Columbia River plume is essentially blocking any direct

transport of upwelled nutrients into the surface layer, and the region

offshore side of the Columbia River plume could not have a high

nutrient supply without the subsurface offshore flow discussed above.

The distribution of the upwelled nutrients beyond the Columbia River

plume must be ascribed to the subsurface offshore flows along the

Page 81: The Columbia River as a source of marine light scattering particles

130° 128° 1260

IY460GROUPI /'

I

wI °; °ASTORIA I

is .'

rAcCADIA CHANNL GROJP2 o'- (GROUP /1 '

"J/'k., 4. -''

I:)

I

.1

p.'

.',

C)

I

1/°C2_L_______.t /130° 128°

Figure 34. Distribution of Holocene clay-mineral groups.

72

124°

4 COL1$JS/A

c\.46°

'CAPEOLANCO

ROGUERIvER

ORE.

i

124°

440

Page 82: The Columbia River as a source of marine light scattering particles

73

permanent pycnocline and the pycnocline under the plume.

Model Plume

The Columbia River effluent is the major source of light

scattering particles in the plume region. A model has been devel-

oped to describe the general pattern of paths and processes by which

the river particles are distributed to ocean water masses. It was

assumed that the bottom slope of the plume region is such that the

plume water has little influence from the bottom sediment. Thus it

is valid when the plume is in deep water immediately off the river

mouth.

Particles with a wide range of sizes, densities, and indices of

refraction are carried down the estuary by the Columbia River. The

high density particles that were carried by the river effluent will

sink rapidly into deep water below the plume within a few miles from

the river mouth. These particles are permanently lost from the

river plume.

The less dense particles tend to stay in the plume for a long

time. The sinking of these light particles is so slow that they may

be considered as conserved in the plume. For such a tendency of

conservativeness in the plume, the concentration of the less dense

particles serve as an indicator of the plume position and mixing

processes.

Page 83: The Columbia River as a source of marine light scattering particles

74

While the light particles are kept in the plume, they settle

internally to form one or two layers of particle maximum within the

plume. In general, the bottom of plumes are identified by a marked

density gradient, which is associated with a large salinity gradient.

One layer of particle maximum occurs at this level. Because of

solar radiation a thermocline is eventually created even if there

were no thermocline across the lower boundary of the effluent

leaving the estuary. If the vertical gradients of salinity and tempera-

ture are located at two separate levels, then two layers of particle

maxima will be observed as shown in Figures 35 and 36. As the

plume continues its flow and spreading, the solar radiation maintains

the thermocline despite mixing and diffusion, but the salinity gradient

weakens continuously. Thus the particle maximum associated with

the halocline eventually disappears as the plume diffuses and only

one layer of particle maximum remains.

Page 84: The Columbia River as a source of marine light scattering particles

Ia-wc

0

25

50

100

125

150

/60 NM-- bU 100 /20

32.2 ISOALINE

Figure 35. Plume model on a section along the plume axis.-J'SI

Page 85: The Columbia River as a source of marine light scattering particles

0

25

;50

0w

75

100

'In --MV DV

32,5 ISOHAIjNE

125

150

Figure 36. Plume model on a section across the plume axis.-.1

0'

Page 86: The Columbia River as a source of marine light scattering particles

77

DISCUSSION

The Columbia River effluent had the simple form of a plume

extending south to southwest under the persistent north to north-

easterly wind as described in the previous section. Because of the

coastal upwelling along the Oregon and California coasts, the plume

was kept away from the coast.

The horizontal spreading of the plume is clear evidence of

horizontal diffusion, but the vertical diffusion is limited by the

presence of the vertical gradient of the density at the bottom of the

plume. Tully (1958) and Budinger et al. (1964) concluded that the

vertical mixing of the fresh water plume takes place in the form of

entrainment of the sea water below the plume into the fresh water.

Thus the vertical exchange is only in one way, that is upward trans-

port of heavy sea water into the plume water, and as a result the

plume tends to maintain its lower boundary at the same level or lift

upward, and glides over the heavy sea water resulting in horizontal

spreading.

The Columbia River effluent carries particles of all sizes.

The large particles quickly sink into the ocean water below the

stratified plume within a few miles from the river mouth. These

large particles, after they leave the plume water, keep sinking and

are also carried away by the flow of deep water. The water below

Page 87: The Columbia River as a source of marine light scattering particles

rI1

the plume is generally slow and tends to flow in the opposite direc-

tion from the surface flow due to the upwelling caused by the wind and

entrainment effect resulting in a restriction of the spreading of these

large particles. In the case of the Columbia River, the deep water

flows northward with an onshore component, and the large particles

are carried northward within a few miles from the coast (Figure 12).

The small particles are contained in the plume and carried

along with the plume. The plume is oriented towards the south to

southwest responding to the prevailing wind. The plume is bounded

by cold and saline water upwelled from deep water on the coast side,

and cold and saline ocean water on the oceanic side.

The length of the plume depicted in the horizontal plane is

approximately 100 nautical miles on the 3m surface. Using the sur-

face velocity of 12 cm/sec determined by Chromium activity

(Frederick, 1967), the time required for the plume to reach a point

100 nautical miles downstream from the river mouth is about 20

days. On the basis of conservation of particle content to the extent

discussed in the previous section, the length of the model plume

should not be limited to that of the present data. It is more likely to

extend beyond ZOO nautical miles (about three times the length of the

present plume axis) under a steady wind condition. This figure is,

of course, a first approximation since it will vary with the cb3rac-

teristics of the effluent, stability structure, and extent of mixing.

Page 88: The Columbia River as a source of marine light scattering particles

79

The particle concentration in the Columbia River plume region

can conveniently be described by three distinctive layers: the first

and second layers in the plume water itself, and the third layer in the

water below the plume.

The Columbia River effluent was warmer than the ambient sea

water (Figure 30). This plume water was heated by the solar radia-

tion at the surface. The net result was a strong vertical tempera-

ture gradient, the thermocline, at the lower part of the plume water.

The entrainment of cold sea water and the solar radiation heating at

the surface of the plume water cause a strong thermocline and also

a strong halocline,

The particles contained in the plume water showed a tendency

to settle down slowly within the plume water. As they settled down,

they were trapped at the level where the vertical density gradient

was a maximum. Two layers of particle maximum, the first and

second layers, were observed at the maximum density gradient

levels which are associated with the maximum stability (Figures 37

and 38), The Brunt Vàisàlâ frequency is used as the stability para-

meter. The two layers of particle maxima were not observed at the

edge of the plume and near the river mouth of the plume (Figures

39 and 40). Along the edges, mixing is extensive so that the halo-

dine becomes quite weak and the first layer does not exist. In the

vicinity of the river mouth, the upwelling ofdeep water due to the

Page 89: The Columbia River as a source of marine light scattering particles

2

0Ui

FigUre 37. Scatt ng particle profile at

Page 90: The Columbia River as a source of marine light scattering particles

I'

Page 91: The Columbia River as a source of marine light scattering particles

=Ia-LLI

-2 -I

Figure 39. Profilesof stability and scattering particles atMC-25, near the river mouth.

Page 92: The Columbia River as a source of marine light scattering particles

LU

50

Ni]

M

-2 -I

Figure 40. Profiles of stability and scattering particles atMC-33, at the edge of the plume.

Page 93: The Columbia River as a source of marine light scattering particles

wind and also the entrainment causes the river effluent to be kept in

the upper 10 to 15 meters depth, so that the temperature and salinity

gradients are unable to be separated.

The third layer is difficult to simplify in the model, because it

is not uniformly distributed and its cause may be diverse too. It

could have been formed by the process(es) of (1) sinking of the parti-

des from the plume when the plume stagnated for a long period of

time, 2) erosion of particles trapped at the bottom of the plume by

the subsurface offshore flow, 3) transport of particles from the sur-

face layer by the subsurface offshore flow, and 4) in situ biological

production.

The particles in the third layer could have been derived by any

one of the processes introduced above, or any combinations. The

sinking of particles will take place all the time but their quantitative

treatment is difficult. The subsurface offshore flow is evident from

the temperature inversion (Figure 20), bulges in particle concentra-

tionfrom shore to offshore in 20 and 30 meters surfaces (Figures

10 and 12), and also the correlation of temperature and particle con-

centration (Figure 33), A super-saturated oxygen concentration

layer is found under the plume axis, implying that the photosynthetic

production is active. At the stations, MC-5 and MC-15, the third

layers is found as a 30 meters thick layer and centered at about 55m

depth. The stability of the water column (Figure 41) is high at 75 to

Page 94: The Columbia River as a source of marine light scattering particles

;50

I-0w

I.

-2N

-I

7/1/

o MC-15

L MC-5

Figure 41. Stability profiles at MC-5 and MC-15.

85

Page 95: The Columbia River as a source of marine light scattering particles

90 meters, and a low stability exists at 55m depth at MC-5. This

must be an indication of the fact that the sinking is not the major

process responsible for the third layer.

The particulate substances that the Columbia River introduces

into the oceanic region off the Oregon coast during the summer sea-

son under the predominant northerly wind may be considered under

the following three processes: 1) the heavy particles sinking from

the plume water immediately off the river mouth, Z) erosion of

particles (particles settled to the bottom of the plume) by the sub-

surface offshore flow along the bottom of the plume, and 3) the

sinking of small particles which have been contained in the plume

water. By the first process, large particles are introduced into the

oceanic region but confined within a narrow zone along the coast due

to their high rate of sinking and the deep water circulation northward

with onshore component. These particles must be studied more

closely since there were too few stations near the river mouth.

The second process is a direct consequence of the upwelling

and its downstream (offshore) extent is not known, but it may be re-

lated to the intensity of the upwelling. From Figures 10 and 12, it

can be noted that the offshore subsurface flow is associated with the

bulges of particle concentration, and this implies that the subsurface

offshore flow is patchy instead of uniform along the coast. This

subsurface flow should be closely related with water of high biological

Page 96: The Columbia River as a source of marine light scattering particles

productivity since it consists of upwelled water and passes through

lighted depths of water. This flow will pick up some particles as it

moves along the bottom of the plume water.

The third process is the process which was ignored in the

model plume. The Columbia River plume data suggest that the

plume could be traced a much longer distance by the particle concen-

tration later in the season, The model tacitly assumes that the small

particles are nearly conserved over the length of the plume. Thus

particles will eventually sink from the plume water which is distri-

buted over a large area, approximately over ZOO nautical miles

downstream, and the plume is acting as a broad plane source of

particles.

The study of the Columbia River plume was motivated by the

need of understanding the process by which particles carried by the

river effluent are distributed to the ocean water. The application of

the optical method to the oceanographic problem is directly related

with this knowledge. The model describes the basic process of de-

livering particles: 1) large particles sink immediately within a few

miles of the river mouth, and Z) small particles are contained in the

plume water, which spreads out, responding to the general circula-

tion of the sea surface, over the ocean water as a layer of about 30m

thick. The river effluent, mainly because of its density relative to

the ocean water, effectively converts a point source of particles,

Page 97: The Columbia River as a source of marine light scattering particles

river mouth, into a surface source of particles. The size of this sur-

face is a function of spreading causes, i.e., currents and wind field,

and residence time of the particles in the plume water, This resi-

dence time is estimated as 30 to 50 days.

It is useful to consider the results of Ketchum and Shonting

(1958) in light of the present model. In order to show that the parti-

des found in the Cariaco Trench originate in the Orinoco River it is

necessary to establish: 1) that the plume reaches the trench; 2) that

the particles are retained in the plume until the trench is reached; and

3) that the density structure of the plume changes in the vicinity of the

trench so that the particles can fall to the observed depth of 100 to

220 meters.

In the absence of data on the temperature and salinity of the

water at and upstream to the Cariaco Trench it is impossible to es-

tablish either the path of the plume or the stability of the water

column, The particle distribution in the Cariaco Trench does not

show any indication of river plume in the surface layer. The time of

travel between the river mouth and trench appears long in comparison

to the residence time of particles in the Columbia River plume. Thus

none of the conditions required is shown to be true for the Orinoco-

Cariaco system.

Since the water over the trench must pass over a sill with the

maximum depth of 24 meters immediately at the upstream edge of

I

Page 98: The Columbia River as a source of marine light scattering particles

the trench, it seems much simpler to attribute the observed particle

distribution to the topographic effect (Jerlov, 1968),

Page 99: The Columbia River as a source of marine light scattering particles

BIBLIOGRAPHY

Anderson, C. C. 1964. The seasonal and geographic distribution ofprimary productivity off the Washington and Oregon coasts.Limnology and Oceanography 9:284-302.

Beardsley, C. F., Jr. 1966. The polarization of the near asympto-tic light field in sea water. Ph.D. thesis. Cambridge,Massachusetts Institute of Technology. 119 numb. leaves.

Budinger, T. F., L. K. Coachman and C. A. Barnes. 1964.Columbia River effluent in the northeast Pacific Ocean, 1961,1962: Selected aspects of physical oceanography. Seattle,University of Washington, Dept. of Oceanography. 'ISp.(Technical Report no. 99)

Burt, W. V. and B. McAlister. 1959. Recent studies in the hydro-graphy of Oregon estuaries. Research Briefs of the Fish Com-mission of Oregon 7: 14-27.

Burt, W. V. and B. Wyatt. 1964. Drift bottle observations of theDavidson Current off Oregon. In: Studies on oceanography,ed. by Kozo Yoshida. Tokyo, Japan, University of Tokyo.p. 156-165.

Cissell, M. C. 1969. Chemical features of the Columbia Riverplume off Oregon. Master's thesis. Corvallis, Oregon StateUniversity. 45 numb, leaves.

Collins, C. A. 1964. Structure and kinematics of the permanentoceanic front off the Oregon coast. Master's thesis.Corvallis, Oregon State University. 53 numb, leaves.

Collins, C. A., C. N. K. Mooers, M. R. Stevenson, R. L. Smithand J, C. Pattullo. 1968. Direct current measurements inthe frontal zone of a coastal upwelling region. Journal of theOceanographical Society of Japan. (In press)

Duncan, J, R., L. D. KulmandG. B. Griggs. 1968. Clay-mineral composition of late Pleistocene and Holocene sedi-ments of Cascadia Basin, Northeastern Pacific Ocean.(Submitted to the Journal of Geology)

Duxbury, A. C. 1965. The union of the Columbia River and thePacific Ocean, In: Ocean Science and Ocean Engineering,

Page 100: The Columbia River as a source of marine light scattering particles

91

1965: Transactions of the Joint Conference of the MarineTechnology Society and American Society of Limnology andOceanography, 1965. Washington, D. C. p. 914-922.

Fisher, C. W. 1969. A statistical study of winds and sea watertemperature during Oregon coastal upwellings. Master'sthesis, Corvallis, Oregon State University. 67 numb. leaves.

Frederick, L. C. 1967. Dispersion of the Columbia River plumebased on radioactivity measurements. Ph.D. thesis.Corvallis, Oregon State University. 134 numb, leaves.

Gross, M. G. and J. L. Nelson. 1958. Sediment movement of thecontinental shelf near Washington and Oregon. Science 154:879 -881.

Hickson, R. E. and F. W. Rodolf. 1951. History of the ColumbiaRiver jetties. In: Proceedings of the First Conference onCoastal Engineering, Long Beach, 1950. Berkeley, Councilon Wave Research. p. 283-298.

Jerlov, N. G. 1953a. Influence of suspended and dissolved matteron the transparency of sea water. Tellus 5: 306-307.

Jerlov, N. G. 1953b. Particle distribution in the ocean. In: Re-ports of the Swedish Deep-Sea Expedition, 1947-1948, ed. byHans Petterson. Vol. 3. Physics and chemistry. Goteborg.Elanders Boktryckeri Aktiebolag. p. 73-9 7.

Jerlov, N. G. 1955, The particulate matter in the sea as deter-mined by means of the Tyndall meter. Tellus 7:218-225.

Jerlov, N. G. 1958, Distribution of suspended material in theAdriatic Sea. Archivio di Oceanografia e Limnologia 11:227-250.

Jerlov, N. G. 1959. Maxima in the vertical distribution of particlesin the sea. Deep-Sea Research 5: 178-184.

Jerlov, N. G. 1968. Optical oceanography. Elsevier, Amsterdam.l94p.

Jerlov, N. G. and B. Kullenberg. 1953. The Tyndall effect of uni-form minerogenic suspensions. Tellus 5: 306-307.

Page 101: The Columbia River as a source of marine light scattering particles

92

Ketchum, B. H. and D. H. Shonting. 1958. Optical studies ofparticulate matter in the sea. Woods Hole, Massachusetts.28p. (Woods Hole Oceanographic Institute. Reference no.58-15)

Morse, B. A. and N. McGary. 1965. Graphic representation of thesalinity distribution near the Columbia River mouth. In:Ocean Science and Ocean Engineering, 1965: Transactions ofthe Joint Conference of the Marine Technology Society andAmerican Society of Limnology and Oceanography, 1965.Washington, D. C. p. 923-942.

Neal, V. T. 1965. A calculation of flushing times and pollutiondistribution for the Columbia River estuary. Ph.D. thesis.Corvallis, Oregon State University. 82 numb. leaves.

Osterberg, C., N, Cutshall and J. T. Cronin. 1965. Chromium-51 as a radioactive tracer of Columbia River water at sea.Science 150: 1585-1587,

Osterberg, C., J. Pattullo and W. Pearcy. 1964. Zinc-65 ineuphausiids as related to Columbia River water off the Oregoncoast. Limnology and Oceanography 9:249-257.

Pak, H., G. F. Beardsley, Jr. and R. L. Smith. 1969. An opticaland hydrographic study of a temperature inversion off Oregonduring upwelling. (Submitted to the Journal of GeophysicalResearch)

Park, K. 1966. Columbia River plume identification by specificalkalinity. Lirnnology and Oceanography 2: 118-120.

Rosenburg, D. H. 1962. Characteristics and distribution of watermasses off the Oregon coast. Master's thesis. Corvallis,Oregon State University. 45 numb. leaves.

Sasaki, T., N. Okami, G. Oshiba and S. Watanabe. 1962. Studieson suspended particles in deep sea water. Scientific papers ofthe Institute of Physical and Chemical Research (Tokyo) 56:77-83.

Smith, R. L. 1964. An investigation of upwelling along the Oregoncoast. Ph.D. thesis. Corvallis, Oregon State University.83 numb, leaves.

Page 102: The Columbia River as a source of marine light scattering particles

Spilhaus, A. F. 1965. Observation of light scattering in sea water.Ph.D. thesis. Cambridge, Massachusetts Institute of Techno-logy. 24Z numb. leaves,

Stefanson, U. and F. A. Richards, 1963, Process contributing tothe nutrient distribution of the Columbia River and the Straitof Juan de Fuca, Limnology and Oceanography 8:394-410.

Tully, J. P. 1958, On structure, entrainment, and transport inestuarian embayments. Journal of Marine Research 17: 5Z3-535,

U. S. Bureau of Reclamation. 1947, The Columbia River: Acomprehensive report on the development of the water re-sources of the Columbia River Basin. Washington, D. C.393p.

Page 103: The Columbia River as a source of marine light scattering particles

APPENDICES

Page 104: The Columbia River as a source of marine light scattering particles

94

APPENDIX I

COLUMBIA RIVER AND ITS ESTUARY

The Columbia River is carrying the bulk of fresh water into

the northeastern part of the Pacific Ocean through its estuary located

at the border of Oregon and Washington States (Figure 42). Its total

length is approximately 1220 statute miles (Hickson and Rodolf,

1951). The drainage basin (U,S Bureau of Reclamation, 1947),which

covers 670, 000 Km2 with 85 percent of this area within the United

States, includes nearly all of Idaho, most of Washington, Oregon

and western Montana, and small areas in Wyoming, Nevada and

Utah. The watershed of the Columbia River constitutes about seven

percent of the nation's area.

There is considerable seasonal variation in the mass transport

of the Columbia River. Maximum discharge occurs during May to

July due to melting snow at the head waters, whereas the maxima

for the small coastal streams south to the Rogue River normally

occurs during the wet period from November through February.

Average flow in the period of maximum and minimum discharge is

about 660, 000 and 70, 000 cubic feet per second (Hickson and Rodolf,

1951). Total flow represents approximately 14 percent of the total

annual discharge from continental United States.

Seasonal variation in precpitation shows more precipitation in

Page 105: The Columbia River as a source of marine light scattering particles

N

95

Tzo IIo

150W

Figure 42. Columbia River basin.

Page 106: The Columbia River as a source of marine light scattering particles

winter than in summer, A quick run-off of winter rain on the west

side of the Cascade Range controls the coastal stream discharges to

create a seasonal variation opposite to that of the Columbia River.

There is a winter peak flow in the Columbia River depending on

coastal precipitation (Duxbury, 1965). The winter discharge may

deviate considerably from its mean value,

Using Pritchard's classification (1955), the Columbia River

estuary at Astoria, Oregon, belongs to type B (partially mixed type)

during high discharge period and type D (well mixed) during low

river period (Neal, 1965), Upstream the estuary is type B except

for high river flow when it becomes type A (Stratified).

The tide at the river mouth of the estuary has a mean range

of 6. 5 feet and the tide itself is the typical mixed semi-diurnal tide

of Northeastern Pacific Ocean (Neal, 1965).

The salinity intrusion ranges from ZO to 15 nautical miles up-

stream from the river mouth depending on whether type B or type D

conditions exist (Burt and McAlister, 1959),

Further physical and hydrological details of the Columbia

River were discussed by Budinger et al, (1964) and Neal (1965),

Page 107: The Columbia River as a source of marine light scattering particles

97APPENDIX II

REVIEW OF REGIONAL OCEANOGRAPHIC CONDITIONSOFF THE OREGON-WASHINGTON COAST

The oceanic region off the Oregon and Washington coast is

characterized by a weak and poorly defined current, the Eastern

boundary current, The North Pacific west wind drift diverges into

northern and southern branches, The northern branch feeds into a

gyre in the Gulf of Alaska, and the southern branch forms a broad

California Current,

Seasonal patterns in wind produce distinctive seasonal varia-

tions in near-shore current systems. During October and through

March or April, south or southwest winds prevail and result in a

northerly surface current, called Davidson Current (Burt and Wyatt,

1964), and during the rest of the year, north to northwest winds pre-

vail to cause coastal upwelling (Smith, 1964).

In the Northeast Pacific Ocean, precipitation and fresh water

drainage from adjacent land masses exceeds the evaporation so that

the area is a region of net dilution (Budinger et al., 1964), The

oceanic region subject to the influence of the Columbia River plume

is contained within 40 to 50 degrees North, and 1Z4 to 132 degrees

West (Budinger et al., 1964).

Rosenburg (1962), Collins (1964), Pattullo and Denner (1965),

and others discussed the water mass characteristics of the region in

Page 108: The Columbia River as a source of marine light scattering particles

detail. The water mass above lOOm depth, according to them, con-

sists largely of Subarctic water mixed with a small amount of Pacific

Equatorial water.

The Columbia River plume shows a large seasonal variation in

its position due to the prevailing surface current which is driven by

the prevailing wind, During the summer, prevailing wind drives

the surface water southward with offshore component causing deep

water to upwell. A band of high salinity and low temperature water

along the coast in summer is the direct consequence of the upwelling.

A zone exists parallel to the coast between upwelled water near

shore and non-upwelled water offshore. This zone is referred to as

a front because there exist a large density, temperature, and

salinity gradients across this zone (Collins, 1964).

The Columbia River effluent is the major source of fresh

water drainage in the Northeast Pacific Ocean, and is the primary

cause of the low salinity water near the shore of Oregon. Yet,

during some period of the year, primarily the winter, the Columbia

River effluent becomes less distinguishable from that of the other

coastal streams once it becomes part of the marine environment.

During the summer, the Columbia River plume is often kept

intact as a shallow lens of water, over the dense sea water due to

the calm sea and large river discharge (Budinger et al., 1964).

Tully (1958), and Budinger et al. (1964) explained that the mixing

Page 109: The Columbia River as a source of marine light scattering particles

occurs in such a way that the salty sea water mixes vertically upward

into the plume, and little fresh water is lost through the halocline.

Buoyancy of fresh water keeps it above the sea water. Tully (1958)

attributed this phenomena to the lower coefficient of vertical eddy

viscosity near the pycnocline than in the water above it.

Budinger et al. (1964) delineated the Columbia River plume by

3Z. 5 ppt isohaline, which they found consistently corresponds to 30

to 40 meters depth in the vertical and about 760 Km downstream

during late summer.

During the winter, the plume turns northward and lies closely

along the Washington coast. High run-off from the coastal streams

and low Columbia River discharge in the winter complicate the

Columbia River plume determination (Budinger et al., 1964; and

Duxbury, 1965).

The Columbia River plume has been studied by salinity

(Budinger et al., 1964; Duxbury, 1965; Morse and McGary, 1965,

and others), by plant nutrients (Stefanson and Richards, 1963),

Chlorophyl (Anderson, 1964), Alkalinity (Park, 1966), and by radio-

active tracers (Osterberg, 1964; Osterberg, 1965; and Frederick,

1967).

Page 110: The Columbia River as a source of marine light scattering particles

100

APPENDIX III

BRICE PHOENIX LIGHT SCATTERING PHOTOMETER

Introduction

The B rice Phoenix light scattering photometer, which was used

to measure the intensity of scattered light, is a laboratory type in-

strument, It measures the intensity of light scattered from water

samples contained in the Pyrex-glass scattering cell and placed in

the path of the light beam. Thus it requires samples taken by means

of the sampling device. The scattering intensity is measured at

angles between 300 and 1350 measured from the direction of the beam,

and the limits are imposed by the geometry of the system. The volume

scattering function is deduced from the intensity by formula (1).

The light source is provided by an 85 watt mercury arc lamp,

and the output of the photomultiplier detector is recorded on a re-

corder. In order to keep the input to the photomultiplier detector in

the linear range of the system, a set of four neutral density filters

are used in the light source to control the intensity of the light source.

Interference filters are used to control the wavelength of the light

beam.

The details of the instrument are described by Spilhaus (1965)

and they are not repeated here.

Page 111: The Columbia River as a source of marine light scattering particles

101

Calibration of the B rice Phoenix Light Scattering Photometer

The calibration of the Brice Phoenix light scattering photometer

was done basia1ly by the working standard method of Tomimatsu and

Palmer (1963), but by an entirely dependent derivation of the rela-

tions.

The volume scattering function defined in equation (1) can be

expressed in terms of radiance and recorder output voltage. The

radiant intensity falling on the detector in the direction of 0 is,

J(0) = N AS S

(5)

where N is scattered radiance and A is the area of the scatteringS 5

volume defined by the distance between the scattering volume and the

detector, and the solid angle £2D. The radiance, N, N, and ND

representing the incident, scattered, and detected radiance respec-

tively, is a function of £2, and d, assuming the time dependence is

negligible. The voltage output recorded, V0, may be expressed by

V (0) = k N A % Tg (1 - R) (6)D sD

where k is a constant conversion factor (volts/flux), T and R are

transmissivity and reflectivity of the Pyrex glass scattering cell,

From equation (1) and (5), the scattered radiance is expressed by

N = 1(0) N £2 T (1 - R) (7)00 g

Page 112: The Columbia River as a source of marine light scattering particles

102

recalling that the incident irradiance, H = N £2 , and the scattering00volume, V = A 1(0), where 1(0) is the path of sight. The path of

sight is t sinO, when t is the width of the light beam. Then equation

(6) with equation (7) substituted in for N becomes

VD(e) = k (0)l(0)N £2 A £2 T 2(1 - R)2 (8)ooDDg

The voltage output at 0 0, VD (0), is written as

V (0) = kuN £2 £2 A T 2(1 - R)2

D ooDDg

where a is the working standard constant. The ratio of VD(e) to

VD(0) is

p(e)l(o)VD(0) a

(6) ta sine (9)

The ratio of voltage outputs, V and V isw op

V kN2a2Aw 00 D D a

V kN2T2A fop oo oDD o

where V and V are voltage outputs when the working standardw op

and opal standard were placed in the beam respectively, T is the

transmissivity of the opal standard.

Page 113: The Columbia River as a source of marine light scattering particles

103

The working standard constant, a, is

Vw

a T (10)V 0

op

From equation (8), the volume scattering function is written by

VD(0) V T= sinO

VD(0) V top

Thus the calibration constant K is expressed by

Y T

V top

(1Z)

T is provided with the instrument by the manufacturer, and t can

easily be determined.

Operational Procedures

The operational procedure includes the sampling of water,

operation of the B rice Phoenix scattering photometer, and reduction

of the recorded data into the volume scattering function.

Water samples were drawn from the desired depth by Nansen-

bottles hung on regular hydro-wire. The inside of the Nansen-bottles

were coated with teflon. The water samples were transferred to

plastic nutrient bottles. The nutrient bottles were rinsed carefully

Page 114: The Columbia River as a source of marine light scattering particles

104

to avoid contamination. Since there are always some possibilities of

contamination from the transferring of the samples to nutrient

bottles, a direct transfer of samples from the Nansen-bottle to the

scattering cell is desirable.

The estimated time of storage in the nutrient bottle ranges

from ten to thirty minutes. According to Spilbaus (1965), the error

that might occur by the storage of less than one hour is negligible.

The operation of the Brice Phoenix light scattering photometer

starts with warming up the light source and photomultiplier. The

power was put on as soon as the instrument is installed, and left on

for the entire cruise. On the power source a voltage regulator was

used to prevent any fluctuation of voltage. It was convenient to make

a log on the recorder chart before the measurement about the cruise,

station, date, and other things that might be needed later on.

A semi-hexagonal pyrex-glass scattering cell was used, and

this cell enabled measurement of the scattered light at 45, 90, and

135 degrees. The scattering cell was cleaned before the first sta-

tion and clean double distilled water was filled in, and also whenever

the instrument was idle the scattering cell was filled with the same

double distilled water, After the sample was poured into the

scattering cell, the cell was seated on the cell base in the light tight

Page 115: The Columbia River as a source of marine light scattering particles

1 ('1. U.

compartment. The alignment of the scattering cell was checked by

watching the reflected light beam from the scattering cell back to the

slit through which the light beam emanates. The cap of the light tight

compartment was closed. At this time another log for the sample in

the instrument was made. This log included the depth of the water

sample, color of the light, time of measurement, etc.

The 00 reading was made first. Using the neutral density fil-

ters attached near the light source, the output was kept near 4 to 5

my. The output decreases as the angle increases, and the neutral

density filters become unnecessary. The output of open ocean water

at 90° is usually less than 4 my without using any neutral density fil-

ter.

As the output is recorded, the angle of measurement and

neutral density filters used must be recorded. The output often

shows some fluctuations. The record was made long enough, some-

times as long as one minute, to record the minimum reading. The

higher values are from the motes, which are very difficult to treat

uniformly, and the effects of the motes are avoided by taking the

minimum readings for all the measurements.

The data read from the chart was processed by a CDC3300

computer to deduce the volume scattering functions corresponding to

angles of measurements. The formula for the volume scattering

Page 116: The Columbia River as a source of marine light scattering particles

function is given in equation (7).

The data processing includes 1) take account of the neutral

density filters used, Z) normalize to the NO), 3) take account of the

scattering volume, 4) take the calibration constant into account, and

5) make correction for reflections. These processes are discussed

by Spilhaus (1965) and the complete computer program is presented

here without repeating explanations on steps.

Error Analysis

Spilhaus (1965) determined the precision of measurements of

the B rice Phoenix light scatterometer from an experimental measure-

ment made on pairs of samples drawn simultaneously. The measure-

ment itself could not be made simultaneously. By the deviation of

J(0) from its mean at each angle, the standard error was ± 0. 034.

He also analyzed the error caused by the aging of the sample

by repeating the measurement of the same sample with various

storage time intervals. He did not find a pattern of changes as a

function of time.

Beardsley (1966) discussed the precision of the same instru-

ment. He found a standard deviation of four percent for the drift

of the electro-optical system by taking time average of a large num-

ber of one second period readings. He also found that the repeata-

bility of the calibration can be determined with a precision of two

Page 117: The Columbia River as a source of marine light scattering particles

107

310') TPil S1 iFPS1J 1 . 12/?3/ 14tprAt SCAT 4C"N 'W (10) N 1 (1 RO) , IF7 (1 k'l) N(. 3(1 Mo I , iF+ C I Fl I

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Page 118: The Columbia River as a source of marine light scattering particles

p e r C e nt.

To test the repeatability of the instrument, an experiment was

made with a sample prepared by adding 10.5 micron diameter Latax

spheres into cleau sea water. The sea water was prepared by fil-

tering through 0.8 micron Millipore filters many times. The clean-

liness of this filtered water was checked by scattering measurements

aLId also by Coulter-Counter measurements. The number of Latax

spheres added was determined by the Coulter-Counter method. The

sample prepared in this way was measured by the Brice Phoenix

light scatterometer at angles of 0, 45, 90, and 135 degrees using

blue and green light. Two days later, the same procedure was re-

peated by a different person. The results are presented in Table 3.

Table 3. Results of error analysis.

Color 0 A5 B C5 D(xlO )

(xlO

Blue 45 0.0176 0.44% 0.0062 0.15%90 0. 0129 4.98% 0.0045 1. 73%

135 0.0408 14.4% 0.0144 5,08%

Green 45 0,0354 1,28% 0.0125 0.45%90 0.0040 2,43% 0.0014 0.85%

135 0. 0180 9.7 % 0. 0063 3.39%

A=N1 N2

N1B = A x 100

C = Standard Deviation

D = (Stand. Dev,/p(0)1)x 100

Page 119: The Columbia River as a source of marine light scattering particles

109

The errors are larger at the larger angles than at 45 degrees.

These errors include that of the Coulter-Counter and all the opera-

tional errors such as electro-optical drift, cleanliness of the scat-

tering cell, human error, etc. The experiments were made aboard

the R/V Yaquina during a cruise on the open ocean.

The errors due to the storage time of samples discussed by

Spilhaus (1965) will be much smaller in this work since samples are

measured much more quickly by measuring at only three angles,

while Spilhaus took readings at 5 degree intervals from 30 to 135

degrees.

The recording pen often drifts to give a wide range of value.

This is due to the motes of the particles in the scattering volume,

especially large particles like swimming zooplanktons. It is diffi-

cult to account for the effects of this non-homogenous state. We

considered the scattering from a sample of water as a sum of basic

scattering and anomalous scattering from a few foreign particles

(from large particles that cause the large variations). The effects

of such anomalous scattering are eliminated by taking long records,

as long as one minute, and taking the minimum value.

Another set of experiments was made to determine whether or

not the Nansen-bottles contaminated the water samples as compared

to newer plastic sampling bottles, and the experimental errors.

The experiment included sampling and light scattering

Page 120: The Columbia River as a source of marine light scattering particles

110

measurements. Seven Teflon coated Nansen-bottles were tested

against four Niskin bottles, one Van Dorn bottle, and two NI0 bottles.

The Nansen-bottles and plastic bottles were placed in alternating

order on the hydro-wire with two meters spacing. The choice of

each individual bottle was made randomly. The bottles were

lowered to Z50 meters depth, well below the thermocline, and water

samples were taken, The scattering measurements at 450 were

made in random order until each sample was measured twice.

The result of this experiment shows that the Nansen-bottles

are no different from the newer plastic bottles, and the mean error

of the same sample and the mean of the same type bottles were

approximately five percent each.