the behaviour to weathering of the hyblean limestone in the ...the beds used as carving and...

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The behaviour to weathering of the Hyblean limestone in the Baroque architecture of the Val di Noto (SE Sicily): An experimental study on the ‘‘calcare a lumachella’’ stone M.F. La Russa a , C.M. Belfiore b,, G.V. Fichera b , R. Maniscalco b , C. Calabrò b , S.A. Ruffolo a , A. Pezzino b a Dipartimento di Biologia, Ecologia e Scienze della Terra (DIBEST), Università della Calabria, Via Pietro Bucci, 87036 Arcavacata di Rende (Cs), Italy b Dipartimento di Scienze Biologiche, Geologiche e Ambientali – Sezione di Scienze della Terra, Università di Catania, Corso Italia 57, 95129 Catania, Italy highlights Characterisation of a carbonate building stone used in the Val di Noto (SE Sicily). The calcare a lumachella stone shows higher durability than other local limestones. Its intrinsic features are responsible for the high resistance to decay. article info Article history: Received 30 May 2014 Received in revised form 13 October 2014 Accepted 27 November 2014 Available online 30 December 2014 Keywords: Limestone Baroque architecture SE Sicily Durability abstract This work focuses on the study of the ‘‘calcare a lumachella’’ stone (Mt. Carrubba Fm.), a carbonate rock widely used as building and decorative material in the Baroque architecture of the Val di Noto (south- eastern Sicily). Among all types of limestone outcropping in the area, this lithotype shows higher resistance to weathering. In such a context, the main goal of this study is to correlate the mineralogical– petrographic and physical-mechanical features of the ‘‘calcare a lumachella’’ stone with its excellent response to weathering. For such a purpose, all obtained data were also compared with those from liter- ature concerning other local limestones whose behaviour with respect to weathering is rather different. Ó 2014 Elsevier Ltd. All rights reserved. 1. Introduction and geological setting The Hyblean Plateau of southeastern Sicily is composed of sev- eral hundred metres thick succession mostly of Miocene age. This succession can be divided into an eastern and a western facies association [1,2]. The eastern Miocene succession consists of massive to thick-bedded carbonates and overlying reefal to lagoo- nal limestones with intercalated pyroclastic rocks (Mt. Climiti, Palazzolo and Mt. Carrubba Fms., Fig. 1). The western part of the plateau is characterised by well-exposed upper Oligocene–Mio- cene limestone and marl deposited on a carbonate ramp under neritic to pelagic conditions (Ragusa and Tellaro Fms., Fig. 1). Plio–Pleistocene near-shore carbonates are widespread along the margins of the plateau, at places intercalated with mafic volcanics. The Hyblean carbonates have been the subject of several detailed geological, lithological and sedimentological studies [3–5] and their value is enhanced by the large use as building, carving and ornamental stones [e.g., 6–17]. The present paper is part of a wider research project aimed at the characterisation of different typologies of carbonate rocks used in the Baroque architecture of the Val di Noto area (eastern Sicily) and their decay processes [9–19]. After the severe earthquake of 1693, which devastated the entire eastern part of Sicily, the cities were affected by an intense reconstruction activity. In the Hyblean area (Fig. 1), the peculiarity of such a reconstruction in a Baroque style was the wide use of local stones which characterised and defined the urban planning and the architecture of the cities with their whitish colour [20]. Indeed, their easy workability has deter- mined disparate use, both as structural (walls, arches, piers, vaults) and decorative (gargoyles, capitals, balustrades, fountains, stairs) elements. In this paper, attention has been paid on the ‘‘calcare a lumach- ella’’ stone, so far still poorly studied though extensively employed in eastern Sicily during the 17 th and 18 th centuries. This stone, as well as the ‘‘calcare oolitico’’, belong to the Monte Carrubba http://dx.doi.org/10.1016/j.conbuildmat.2014.11.073 0950-0618/Ó 2014 Elsevier Ltd. All rights reserved. Corresponding author. Tel.: +39 095 7195736; fax: +39 095 7195760. E-mail address: cbelfi[email protected] (C.M. Belfiore). Construction and Building Materials 77 (2015) 7–19 Contents lists available at ScienceDirect Construction and Building Materials journal homepage: www.elsevier.com/locate/conbuildmat

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Page 1: The behaviour to weathering of the Hyblean limestone in the ...the beds used as carving and ornamental stones (‘‘pietra d’inta-glio’’, [20]), were the ‘‘calcare a lumachella’’

The behaviour to weathering of the Hyblean limestone in the Baroquearchitecture of the Val di Noto (SE Sicily): An experimental study on the‘‘calcare a lumachella’’ stone

M.F. La Russa a, C.M. Belfiore b,⇑, G.V. Fichera b, R. Maniscalco b, C. Calabrò b, S.A. Ruffolo a, A. Pezzino b

a Dipartimento di Biologia, Ecologia e Scienze della Terra (DIBEST), Università della Calabria, Via Pietro Bucci, 87036 Arcavacata di Rende (Cs), Italyb Dipartimento di Scienze Biologiche, Geologiche e Ambientali – Sezione di Scienze della Terra, Università di Catania, Corso Italia 57, 95129 Catania, Italy

h i g h l i g h t s

� Characterisation of a carbonate building stone used in the Val di Noto (SE Sicily).� The calcare a lumachella stone shows higher durability than other local limestones.� Its intrinsic features are responsible for the high resistance to decay.

a r t i c l e i n f o

Article history:Received 30 May 2014Received in revised form 13 October 2014Accepted 27 November 2014Available online 30 December 2014

Keywords:LimestoneBaroque architectureSE SicilyDurability

a b s t r a c t

This work focuses on the study of the ‘‘calcare a lumachella’’ stone (Mt. Carrubba Fm.), a carbonate rockwidely used as building and decorative material in the Baroque architecture of the Val di Noto (south-eastern Sicily). Among all types of limestone outcropping in the area, this lithotype shows higherresistance to weathering. In such a context, the main goal of this study is to correlate the mineralogical–petrographic and physical-mechanical features of the ‘‘calcare a lumachella’’ stone with its excellentresponse to weathering. For such a purpose, all obtained data were also compared with those from liter-ature concerning other local limestones whose behaviour with respect to weathering is rather different.

� 2014 Elsevier Ltd. All rights reserved.

1. Introduction and geological setting

The Hyblean Plateau of southeastern Sicily is composed of sev-eral hundred metres thick succession mostly of Miocene age. Thissuccession can be divided into an eastern and a western faciesassociation [1,2]. The eastern Miocene succession consists ofmassive to thick-bedded carbonates and overlying reefal to lagoo-nal limestones with intercalated pyroclastic rocks (Mt. Climiti,Palazzolo and Mt. Carrubba Fms., Fig. 1). The western part of theplateau is characterised by well-exposed upper Oligocene–Mio-cene limestone and marl deposited on a carbonate ramp underneritic to pelagic conditions (Ragusa and Tellaro Fms., Fig. 1).Plio–Pleistocene near-shore carbonates are widespread along themargins of the plateau, at places intercalated with mafic volcanics.The Hyblean carbonates have been the subject of several detailedgeological, lithological and sedimentological studies [3–5] and

their value is enhanced by the large use as building, carving andornamental stones [e.g., 6–17].

The present paper is part of a wider research project aimed atthe characterisation of different typologies of carbonate rocks usedin the Baroque architecture of the Val di Noto area (eastern Sicily)and their decay processes [9–19]. After the severe earthquake of1693, which devastated the entire eastern part of Sicily, the citieswere affected by an intense reconstruction activity. In the Hybleanarea (Fig. 1), the peculiarity of such a reconstruction in a Baroquestyle was the wide use of local stones which characterised anddefined the urban planning and the architecture of the cities withtheir whitish colour [20]. Indeed, their easy workability has deter-mined disparate use, both as structural (walls, arches, piers, vaults)and decorative (gargoyles, capitals, balustrades, fountains, stairs)elements.

In this paper, attention has been paid on the ‘‘calcare a lumach-ella’’ stone, so far still poorly studied though extensively employedin eastern Sicily during the 17th and 18th centuries. This stone, aswell as the ‘‘calcare oolitico’’, belong to the Monte Carrubba

http://dx.doi.org/10.1016/j.conbuildmat.2014.11.0730950-0618/� 2014 Elsevier Ltd. All rights reserved.

⇑ Corresponding author. Tel.: +39 095 7195736; fax: +39 095 7195760.E-mail address: [email protected] (C.M. Belfiore).

Construction and Building Materials 77 (2015) 7–19

Contents lists available at ScienceDirect

Construction and Building Materials

journal homepage: www.elsevier .com/locate /conbui ldmat

Page 2: The behaviour to weathering of the Hyblean limestone in the ...the beds used as carving and ornamental stones (‘‘pietra d’inta-glio’’, [20]), were the ‘‘calcare a lumachella’’

Formation (late Tortonian–early Messinian in age), extensivelyexposed in the peninsula areas in the vicinity of Syracuse andAugusta (Ortygia, Maddalena Peninsula, Capo S. Croce, Faro S.Croce, Ognina) (Fig. 1). The large number of deep undergroundlimestone quarries in Syracuse, known as ‘‘latomie’’ (Fig. 2), explainthe huge amount of material used as building stone. In particular,the beds selected for building (‘‘pietra da murare’’, [20]), due totheir low workability, were the ‘‘calcare oolitico’’ levels, obtainedfrom quarrying activity in the deep latomie in Ortygia. Conversely,the beds used as carving and ornamental stones (‘‘pietra d’inta-glio’’, [20]), were the ‘‘calcare a lumachella’’ exploited from quar-ries located in Maddalena Peninsula and Capo S. Croce. Due to itspeculiar features, the latter stone was too expensive and thereforemainly used for decorative motives or for the construction of edi-fices of great importance, such as the façade of the Cathedral ofSyracuse.

Actually, the ‘‘calcare a lumachella’’ stone was employed notonly near the exploiting areas in the Syracuse province but alsoin churches and private buildings of the Catania province. Indeed,as known from literature [20], abundant calcareous rocks from

Fig. 1. Lithostratigraphic map of south-eastern Sicily showing the distribution of Mt. Carrubba Formation.

Fig. 2. Historic underground quarry (latomia) of the ‘‘calcare a lumachella’’ stone(Maddalena Peninsula, Syracuse).

8 M.F. La Russa et al. / Construction and Building Materials 77 (2015) 7–19