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Textile Effects TERASIL ® TC Excellent Right-first-time Performance for Polyester

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Page 1: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

Textile Effects

TERASIL® TCExcellent Right-first-time Performance for Polyester

Page 2: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

Exhaust dyeing on polyester

TERASIL® BLACK TCEconomical rapid dye with excellent shade reproducibility. Good all-round fastness.

Bla

ck T

C

UsesDyeing process

HT, standard

HT, rapid dyeing

HT, alkaline

CA —

CTA —

PES/WO —

Thermosol —

Direct printing —

Key:

very good good moderate — not recommended

PropertiesShade change under artificial light

Tungsten (A) TL 84 CWF

R R R

Energy level Medium

Chemical class Azo

Minimum dyeing temperature 125°C/257°F

pH-range

Sodium acetate + acetic acid 3.0–7.0

Ammonium sulfate + formic acid 3.0–7.0

Ammonium sulfate + soda ash 7.0–9.5

Stability to

Reduction very good

Fe-ions very good

Cu-ions good

Leveling very good

Coverage of barriness very good

SuitabilityExhaust dyeing

TERASIL®/SOLOPHENYL® One-bath method

TERASIL®/NOVACRON® LS One-bath method

TERASIL®/NOVACRON® Two bath method without intermediate clearing

TERASIL®/NOVASOL® One-bath method

Key:

very good good moderate — not recommended

2.0%

2.5%

3.0%

TerasilTC_insert_BLACK_250814534p_edited.indd 1 10/29/14 6:25 PM

TERASIL® TC Technology Competitive, cutting-edge disperse dyes for polyester

SYSTEMPARTNER

Page 3: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

1

Main Trichromatic dyes

Supplementary dyes

True to its name, TERASIL® TC is a Technology Competitive, cutting-edge disperse dye range for polyester. Designed to

offer outstanding economy and shade reproducibility for polyester, polyester/cotton, even microfiber and elastane blends.

• Robust, economical and comprehensive disperse dye range for exhaust dyeing of polyester

• Right-First-Time performance through excellent compatibility of the dyes and stability to reduction

• Highest level of productivity in exhaust dyeing through excellent shade reproducibility

• Fulfills Oekotex requirements, bluesign® certified and meets all major brand RSL requirements

a*

b*

• Good all round fastness performance

• Excellent stability to reduction

• Exceptional leveling properties

• Very good light fastness providing high shade durability

• Fast exhaustion at 130o C

• Wide pH stability

Yellow TC

Orange TC

Rubine TC

Blue TC

Dark Blue TC

Brilliant Red TC

Turquoise TC

Grey TC

Navy TC

Black TC

a*

b*

Yellow TC

Orange TC

Black TC

Grey TC

Navy TC

Dark Blue TC

Turquoise TC

Blue TC

Rubine TC

Brilliant Red TC

-40 -20 0 20 40

-40

-60

-20

0

20

40

60

80

100

Highlights

Range Benefits

Page 4: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

Operational and Economical excellence

Excellent right-first-time performance

Fulfills Oekotex requirements, bluesign® certified and meets all major brand RSL requirements

TERASIL® TCKey Benefits

Page 5: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

3Benefits of the TERASIL® TC range

Compatible dyes combination and uniform exhaustionThe similar shade on the fabric from the beginning to the end of the dyeing procedure ensures excellent leveling properties,

shade reproducibility and reliability. Coupled with the highest degree of exhaustion, TERASIL® TC dyes are the choice for

Operational and Economic excellence.

Operational and Economical Excellence

110o C 120o C 130o C 5 mins 130o C 60 mins Conventional CI dyes

Disperse Yellow 211

Disperse Red 73

Disperse Blue 165

Residual dye in the bath

110o C 120o C 130o C 5 mins 130o C 60 mins New state of the art technology

TERASIL® Orange TC

TERASIL® Rubine TC

TERASIL® Blue TC

Residual dye in the bath

Leveling properties and shade reproducibility

TERASIL® TC dyes provide the best lab to bulk reproducibility and levelness versus any conventional disperse dyes.

TERASIL® TC Trichromy Conventional CI Dyes

Very good levelness and correct shade Poor levelness and shade deviation

Page 6: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

Benefits of the TERASIL® TC range4

Stability to reduction

The cutting-edge technology in TERASIL® TC shows almost NO sensitivity to reduction during dyeing process.

Sensitivity to reduction of disperse dyes is the main cause of poor reproducibility. The main causes for reduction of

disperse dyes are:

• Fully flooded dyeing machines (in absence of air)

• Polyester blended fabrics may carry reductive chemicals in dyebath, like wool, viscose, greige cotton

• Economical dispersing agents (sulphonated lignin) have a reduction effect

100% Texturized PES

Fully-flooded dyeing machinewithout air

Dyeing machine which contains air

Fully-flooded dyeing machine + dispersing agent*

Conventional CI dyes

Disperse Yellow 211

Disperse Red 73

Disperse Blue 165

Very poor deviation

Industry benchmark dyes

Disperse Yellow Brown CC

Disperse Rubine CC

Disperse Blue CC

Slight deviation

New state of the art technology

TERASIL® Orange TC

TERASIL® Rubine TC

TERASIL® Blue TC

No deviation

*1 g/l dispersing agent based on sulphonated lignin.

Excellent Right-first-time Performance

pH stability

The wide pH stability of TERASIL® TC ensures highest reproducibility and Right-first-time performance.

• Shade not influenced by pH

pH VariationsReference

pH 4.0RelativeDepth

da* db*

5.0 102 0.22 -0.07

New state of the art technology

TERASIL® Orange TC

TERASIL® Rubine TC

TERASIL® Blue TC

6.0 103 0.08 -0.12

7.0 103 0.23 -0.14

Page 7: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

TERASIL® TC Highest level of productivity even under severe dyeing conditions.

Page 8: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

6Further BenefitsSuperior Lightfastness Performance

Migration During Fabric Storage

The high lightfastness of TERASIL® TC ensures durability against fading, even on microfiber. Tested according to Xenonlight

ISO 105-B02 (blue scale) and Xenonlight AATCC 16E (gray scale).

ISO 105-B02 AATCC 16 E 20 AFU

TERASIL® Orange TC

TERASIL® Rubine TC

TERASIL® Blue TC

Xen

onlig

ht

1/12 SD 4–5 4–5

1/3 SD 4–5 4

1/1 SD 4–5 4

TERASIL® TC shows excellent fastness to storage due to outstanding fastness to dry heat.

Dry heat 30 seconds at 180°C Standard Ch PES CO

TERASIL® Yellow TC

TERASIL® Rubine TC

TERASIL® Blue TC

4 5

TERASIL® Orange TC

TERASIL® Rubine TC

TERASIL® Blue TC

4 5

Disperse Yellow CC

Disperse Rubine CC

Disperse Blue CC

3-4 4-5

Disperse Yellow 211

Disperse Red 73

Disperse Blue 165

3-4 4-5

Page 9: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

7

Standard HT method

°C

140

130

120

110

100

90

80

70

284

266

248

230

212

194

176

158

°F

1–2°C/min 20–60 min cool down or HT drop

0.3–0.8 g/l ALBAFLOW® UNI-01

0.5–1.0 g/l UNIVADINE® TOP / E3-DAP

3.0 g/l ALBATEX® RI

2.0–3.0 g/l ALBATEX® AB-45

x % TERASIL® dyes

pH 4.0

Dyeing at 130–135°C/266–275°F for 20–60 min

(depending on depth of shade)

Reduction clearing

4.0 ml/l caustic soda 36°Bé/66°Tw (40% w/v)

2.0 ml/l sodium hydrosulfite conc. powder

1.0 g/l ERIOPON® E3-SOP

10–20 min at 70°C/158°F

Rinse and neutralize.

ALBAFLOW® UNI-01

penetration accelerant

Versatile penetration accelerant with excellent deaerating, wetting and durable antifoam properties for

dyeing and pretreatment applications on natural and synthetic fibers. APEO-and solvent free. Nonionic.

ALBAFLUID® E3-DLM

lubricant

An excellent dye bath lubricant for wet finishing of any fiber at all stages, ALBAFLUID® E3-DLM is

particularly useful for fiber processing under difficult conditions including on short liquors, heavily loaded

jets and in delicate goods processing.

ALBATEX® AB-45

acid buffer

No pH setting needed. Excellent buffer capacity and therefore high reproducibility with pH sensitive

disperse dyes is assured. Anionic.

ALBATEX® RI

reduction inhibitor

ALBATEX® RI is a highly effective, halogen-free reduction inhibitor for dyeing of polyester fibers and their

blends with, e.g. cellulose or viscose rayon. It protects disperse dyes from yield loss during HT exhaust

dyeing processes.

ALBATEX® E3-DCC

protective colloid

An outstanding sequestering agent for reactive dyeing on cellulosic fiber and their blends, ALBATEX®

E3-DCC is equally effective as a protective colloid for the dyeing of greige stage cotton and polyester/

cotton blends. ALBATEX® E3-DCC is also a dyebath conditioner for cotton and a dye protectant for the

dyeing and finishing of polyester fabrics.

ERIOPON® E3-SOP

afterclearing agent

An excellent after-clearing agent for dyed and printed polyester goods produced with disperse dyes,

for polyester/cellulose blends with disperse/reactive dyes, for acetate and for polyester blends with

elastane and wool, ERIOPON® E3-SOP is an outstanding product for continuous washing off and

soaping for dyeing on open width washing machines, vat dye prints on all cellulosic goods and vat/

disperse dyes on polyester / cotton blends.

UNIVADINE® E3-DAP

diffusion accelerant

A diffusion accelerant for HT dyeing of polyester fibres and microfiber blends at all stages in jets

processing and circulating liquor machines, UNIVADINE® E3-DAP is excellent for dyeing polyester fibres

in tightly wound or high-density package.

UNIVADINE® TOP

leveling and dispersing agent

Excellent leveling and dispersing effects. Good stability to electrolytes, preventing dye agglomeration.

Good rubbing fastness. No dye retention. Reduces staining of cellulosic fabric. Anionic.

ProcessesExhaust Dyeing

Dyeing Auxiliaries

Page 10: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

TERASIL® TC Technology competitive disperse dyes for PolyesterComplies with OEKO-Tex 100 (inc. Class I) • Meets European standards bluesign® approved – Meets requirements of brand RSL’s (Restricted Substance Lists)

SYSTEMPARTNER

Page 11: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

Learn more about TERASIL® TC.

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Page 12: Textile Effects TERASIL TC - Huntsman Corporation Library/global/files/213001e... · Textile Effects TERASIL® TC Excellent Right-first-time Performance for Polyester. Exhaust dyeing

HeadquartersHuntsman (Singapore) Pte LtdTextile Effects Division152 Beach Road#29-00 Gateway EastSingapore 189721Telephone +65 6297 3363Fax +65 6298 [email protected]

Europe RegionHuntsman Advanced Materials(Switzerland) GmbH, Textile EffectsKlybeckstrasse 2004057 Basel, SwitzerlandTelephone +41 61 299 11 11Fax +41 61 299 11 [email protected]

Americas RegionHuntsman International LLCTextile Effects3400 Westinghouse Blvd,Charlotte, NC 28273, USATelephone +1 704-587-5000Fax +1 [email protected]

Asia RegionHuntsman Textile Effects(China) Co. Ltd.Flying Geese Mountain Industrial ParkShilou Town, Panyu District, Guangzhou511447, PR ChinaTelephone +86 20 3937 7000Fax +86 20 8484 [email protected]

(Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers)

www.huntsman.com/textile_effects213001e – October 2014, Printed in Singapore.

Edition 2014Copyright© 2014 Huntsman. All rights reserved.All product trademarks mentioned are registered trademarks of Huntsman Corporation or an affiliate thereof in one or more, but not all countries.

Chemical products carrying the bluesign® approved label meet the strict ecological and toxicological requirements of the bluesign® criteria. Properly applied they allow the production of bluesign® approved textiles and accessories with a minimum impact on people and the environment.

For more information visit www.bluesign.com

IMPORTANT: The following supersedes Buyer’s documents. Sales of the product described herein (“Product”) are subject to the general terms and conditions of sale of either Huntsman Advanced Materials LLC, or its appropriate affiliate. Huntsman warrants that at the time and place of delivery all Products sold to Buyer shall conform to the specifications provided to Buyer by Huntsman.

While the information and recommendations included in this publication are, to the best of Huntsman’s knowledge, accurate as of the date of publication, NOTHING CONTAINED HEREIN (EXCEPT AS SET FORTH ABOVE REGARDING CONFORMANCE WITH SPECIFICATIONS PROVIDED TO BUYER BY HUNTSMAN) IS TO BE CONSTRUED AS A REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, NONINFRINGEMENT OF ANY INTELLECTUAL PROPERTY RIGHTS, OR WARRANTIES AS TO QUALITY OR CORRESPONDENCE WITH PRIOR DESCRIPTION OR SAMPLE, AND THE BUYER ASSUMES ALL RISK AND LIABILITY WHATSOEVER RESULTING FROM THE USE OF SUCH PRODUCT, WHETHER USED SINGLY OR IN COMBINATION WITH OTHER SUBSTANCES.

No statements or recommendations made herein are to be construed as a representation about the suitability of any Product for the particular application of Buyer or user or as an inducement to infringe any patent or other intellectual property right. Buyer is responsible to determine the applicability of such information and recommendations and the suitability of any Product for its own particular purpose, and to ensure that its intended use of the Product does not infringe any intellectual property rights. The Product may be or become hazardous. The Buyer should obtain Material Safety Data Sheets and Technical Data Sheets from Huntsman containing detailed information on Product hazards and toxicity, together with proper shipping, handling and storage procedures for the Product, and should comply with all applicable governmental laws, regulations and standards relating to the handling, use, storage, distribution and disposal of, and exposure to the Product. Buyer shall also take all steps necessary to adequately inform, warn and familiarize its employees, agents, direct and indirect customers and contractors who may handle or be exposed to the Product of all hazards pertaining to and proper procedures for safe handling, use, storage, transportation and disposal of and exposure to the Product, and the containers or equipment in which the Product may be handled, shipped or stored.

Please note that products may differ from country to country. If you have any queries, kindly contact your local Huntsman representative.

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SYSTEMPARTNER