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4th World Congress of Chemical Engineering STRATEGIES 2000 Karlsruhe/Germany 16-21 June 1991 Preprints IV Sessions 10.1 -13.4 .;j TECHMiCCHE

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4th World Congress of Chemical Engineering

S T R A T E G I E S 2 0 0 0

Karlsruhe/Germany 16-21 June 1991

P r e p r i n t s IV

Sessions 10.1 -13.4

. ; j

TECHMiCCHE

Session 10.1

Distillation

Workshop: Organised by the EFChE WP Distillation, Absorption and Extraction

MON 17. 6. Queens Hotel Saal Braunschweig

Chairman: J. Stichlmair, Essen/D

Oral Presentations

9.00 C. McGreavy, H.M.S. Lababidi, Leeds/UK 10.1 - 1Fuzzy synthesis of distillation sequences

9.30 J. Koehler, E. BlaB, Munchen/D 10.1 - 2Synthesizing distillation sequences via thereversible multicomponent distillation scheme

10.00 S. Farhat, L. Pibouleau, S. Domenech, 10.1 - 3Toulouse/FEffect of holdup on batch distillationoptimization

10.30 M. Gann, H. Schoenmakers, Ludwigshafen/D 10.1 - 4Optimization of an existing distillationprocess

11.30 Poster Discussion Nancy Halle

10.1 - 10 M. K. Abdul Aziz, N.A. Horad, Mohd. Suiong,Kuala Lumpur/MALExperimentation, modeling, simulation andoptimization of palm oils and oleochemicalsdistillation: the evolution of experiments andmodels to optimize the deacidification of crudepalm oils in plate and packed columns

10.1 - 11 A. Gorak, G. Wozny, L. Jeromin, Diisseldorf/DIndustrial application of the rate-basedapproach for multicomponent distillationsimulation

10.1 - 12 R. Sengupta, S.A. Puranik, Baroda/INDMass transfer coefficients in packed absorption columns:prediction by mathematical modeling

10.1 - 13 Z. Spekuljak, H. Monella, Santa Fe/RANew view in design concept of structuredpacking columns auxiliaries

10.1 - 14 Z. Olujic, F. Stoter, J. de Graauw, Delft/NLGas and liquid distribution in large diametercolumns containing structured packings

10.1 - 15 K. Mohammedi, R. Bressat, P. Moszkowicz,M. Otterbein, M. Prost, Lyon/FHydrodynamic behaviour of packed columns inreduced pressure distillation

10.1 - 16 Y. Hirose, M. Tsuda, H. Tachibana, Tokyo/JDistillation calculation with plate efficiencybased on Lewis model I.

10.1 - 17 M.J. Lockett, J.D. Augustyniak, Tonawanda, NY/USAExperimental determination of large diametersieve tray efficiency with and without liquidflow control

10.1 - 18 K.T. Yu, J. Huang, J.L. Li, H.H. Song,Tianjin/PRCTwo-dimensional eddy diffusivities and flowcharacteristics on a sieve tray

10.1 - 19 Xui-Lin Lu, Yu-An Li, Shanghai/PRCEffect of entrainment on distillation trayefficiency with vapor complete mixing andliquid partial mixing

10.1 - 20 S.J. Sykes, North Ryde; R.G.H. Prince, D.J. Casimir,Sydney/AUSThe design of spinning cone distillation columns

10.1 - 21 R. Billet, Bochum/DPerformance of thin film distillation and itsapplication

Session 10.1 (cont.)

MON 17. 6. Nancy Halle

16.30 Poster Presentations

10.1 - 22 M.S. Sivasubramanian, J.F. Boston, Cambridge, MA;J. M. Ryan, Wichita, KS/USAPrediction of misting effects in distillationusing a rate-based modeling approach

10.1 - 23 V.M. Mikelev, O.L. Dmitriev, A.A. Demyanov,R.B. Matatov, Karakh/USSRUsage of the complex columns in multi-componentsmixtures distillation processes

10.1 - 24 Fu Shen, Beijing/PRCFlexi-optimization for petro-processingwith highly fluctuating feed resources(case study on distillation process andequipments)

10.1 - 25 K.T. Yu, Z.C. Yang, B. Bai, Z.M. Mo,Tian'jin/PRCNovel strategy of multicomponent batchdistillation

10.1 - 26 H. Katayama, Koganei, Tokyo/JCorrelations of vapor-liquid equilibria on theethanol-toluene and ethylacetate-ethanol-toluenesystems

10.1 - 27 P. Rajniak, Bratislava/CSSimulation of stagewise separation columnsusing orthogonal collocation method

10.1 - 28 J. Lombira, P. Rajniak, Bratislava/CSUNIQUAC parameters from UNIFAC VLE data

10.1 - 29 J. Lombira, P. Rajniak, Bratislava/CSMathematical and experimental simulationof multicomponent batch rectification

10.1 - 30 M.R. Maldonado, A. Gomez-Munoz, Celaya/MEXOn the multiple solutions of the mesh equations-causes and effects

10.1 - 31 H.-J. Bart, J. Reidetschlager, Graz/ADistillation with chemical reaction in a continuouscounter-current bubble-cap-column

10.1 - 32 M. Mitrovic, M. Petkovska, Beograd/YUSimultaneous multiple separation

10.1 - 33 Q.Y. Sha, B.Q. Zhang, Z.Q. Shen, Dalian/PRC;B. H. Chen, Halifax/CDNAn inversely circulated thermosyphone evaporator

10.1 - 34 A.Y. Soetrisnanto, B. Schwarzer, B. Clauzade,P. Le Goff, Nancy/FA new falling film evaporator with spiral fins

Session 10.2

Advances in Membrane Operations

Workshop: Organised by the EFChE WP Membranes

WED 19.6. Stadthalle A. Hombert Saal

Chairmen: E. Drioli, Arcavacata di Rende/IE. L. Cussler, Minneapolis, MN/USA

Oral Presentations

9.00 E.L. Cussler, Minneapolis, MN/USA 10.2 - 1Facilitated transport in solid polymermembranes

9.30 H. Strathmann, H.J. Rapp, Stuttgart; 10.2 - 2C.-M. Bell, Hechingen/DNew bipolar membranes and their application inthe chemical process industry

10.00 R. Leysen, Ph. Vermeiren, W. Doyen, Mol/B 10.2 - 3The preparation and use of zirconium oxidebased composite membranes

10.30 H. Ohaya, S. Sato, Y. Negishi, K. Matsumoto, 10.2 - 4Yokohama/JThe separation of gaseous mixture compositemicroporous alumina membrane at high temperature

11.00 St. Schlosser, Bratislava/CS 10.2 - 5New type of hollow-fibre pertractor

11.30 N.N. 10.2 - 6The developments of the membrane cell forchloralkali production in the last ten yearsand the next ten years

Session 10.2 (cont.)

WED 19.6 Stadthalle A. Hombert Saal

Chairmen: S. Kimura, Tokyo/J

H. Strathmann, Stuttgart/D

Oral Presentations

14.00 S. Kimura, Tokyo/J 10.2 - 7New trends in membrane separation technology -Case study of ethanol-water seaparation

14.30 J. Neel, Q.-T. Nguyen, R. Clement, B. Wandelt, 10.2 - 8R. Gref, Nancy/FSome chemical engineering aspects ofpervaporation

15.00 R. Rautenbach, M. Franke, Aachen/D 10.2 - 9Cost comparison between pervaporation andazeotropic distillation for the dehydration ofbioethanol

15.30 I. Blume, M.H.V. Mulder, C.A. Smolders, 10.2 - 10Enschede/NLExperiments on the permeation, sorption anddiffusion of chlorinated hydrocarbons throughelastomers

16.00 V. Geraldes, M. Dina Afonso, M.N. de Pinho, 10.2 - 11Lisboa/PRemoval of organochlorinated compounds bynanofiltration

16.30 Yu. Dytnersky, Moscow/USSR 10.2 - 12Concentration polarization in membraneseparations

17.00 A. Da Costa, A. G. Fane, C.J.D. Fell, 10.2 - 13Kensington, NSW/AUSOptimal design of spacer-filled membranemodules for ultrafiltration

Session 10.2 (cont.)

THU 20.6. Stadthalle A. Mortert Saal

Chairmen: V. Sanchez, Toulouse/F

C. A. Smolders, Enschede/NL

Oral Presentations

9.00 V. Sanchez, P. Aimar, Toulouse/F 10.2 - 14Prospects of macromolecules fraction usingsieving membranes

9.30 P. Paris, F. Wandelt, C. Cabassud, P. Aptel, 10.2 - 15Toulouse/FPressure drops in large bundles of ultra-filtration hollow fibers

10.00 S. Finnigan, J.A. Howell, S. X. Wu, M. Mackly, 10.2 - 16Y. Wang, Bath/UKComparison of experimental results and CFOsimulation on the use of pulsating flow forMicrofiltration applications

10.30 B.R. Viejo, L.J. Andres, R. Alvarez, J. Coca, 10.2 - 17Oviedo/EMass transfer during ultrafiltration ofcheese whey

11.00 J. E. Prenosil, K.-H. Yoon, J. Lang, Zurich/CH 10.2 - 18Characterization of a novel membrane tissueculture reactor using coffea arabica

11.30 E. Drioli, G. lorio, R. Molinari, A. Basile, 10.2 - 19G. Catapano, L. Giorno, Arcavacata di Rende;V. Violante, Frascati/ICatalytic membrane reactors

Session 10.2 (cont.)

THU 20.6 Nancy Halle

14.00 Poster Discussion

10.2 - 20 J. Kawasaki, R. Egashira, S. Oshima, Tokyo/JSeparation of aromatics from light re-circulatingoil by liquid membrane permeation

10.2 - 21 H. Matsuyama, M. Teramoto, Y. Miyake, Kyoto/JSeparation of rare earth metals by solvent extraction,supported liquid membrane method and Donnan dialysisin the presence of aqueous complexing agent

10.2 - 22 M. Teramoto, H. Matsuyama, Kyoto/JFunctionalization and design of supported liquidmembranes and their application to metal separation

10.2 - 23 D. Barba, F. Evangelista, Z. He, 0. Spera,L'Aquila/ITheoretical and experimental aspects of hindereddiffusion of biomolecules through microporousmembranes

10.2 - 24 - withdrawn -

10.2 - 25 T. Fujiwara, Kyoto; M. Tanaka, T. Furuichi,Y. Magara, Tokyo/JDevelopment of an expert system for faultdiagnosis of ultra filtration (UF) in nightsoil treatment plant

10.2 - 26 R. Rautenbach, R. Ahlers, Aachen;H. Paul, Stuttgart/DRecovery of organic solvents from air by membranes

10.2 - 27 S. Weiss, R. Arlt, S. Emeish, Merseburg/DLiquid membrane permeation in the recoveryof metallic ions from waste water

10.2 - 28 Chau-Jen Lee, Boa Ru Yang, Hsinchu/ROCThe extraction of europium by PC-88A carriercontaining supported liquid membrane system

10.2 - 29 M. Kim, K. Saito, S. Furusaki, Hongo, Tokyo;T. Sugo, I. Ishigaki, Takasaki, Gunma/JHydrophobic amino acid-containing porousaffinity membrane for bioseparations

10.2 - 30 M. Vico-Stevanovic, J. Savkovic-Stevanovic,M. Radeta, D. Bojovic, Belgrade/YUStudies on membrane separation of biologic activesubstances

10.2 - 31 H. Reisinger, R. Marr, Graz/ASeparation of fermented lactic acid by liquid-membrane-permeation with amines

10.2 - 32 S.B. Sawant, S.K. Sikdar, Boulder, CO/USAJ.B. Joshi, Bombay/INDAmmonia removal from mammalian cell culturemedium by ion exchange membranes

10.2 - 33 G. Daufin, F. Michel, A. Quemerais, Rennes;J.-P. Labbe, Paris/FUltrafiltration of defatted whey: improvingperformances

10.2 - 34 H.J. Bart, Ch. Ramaseder, R. Marr, Graz/AMass transfer and osmosis in the liquid membranetechnique

10.2 - 35 H.J. Bart, N. Ramaseder, C. Ramaseder,R. Marr, Graz/AModeling of mass transfer of phenol throughliquid membranes

10.2 - 36 T. Tatsuguchi, K. Sakai, Tokyo/JStructure and permeability of drawn hollow-fiber dialysis membranes of regeneratedcellulose

10.2 - 37 K. Yoshizuka, K. Inoue, Saga/JControlled-release system of physiological activesubstances with phase transition behavior ofliquid crystal-chitosan blend membrane

10.2 - 38 C. Dutta, R. Singh, Dehradun/INDDesign of polymer-membrane and activatedcarbon based biooxidation system andhydroclones - an emerging technology forwaste water handling

10.2 - 39 R. Ben Aim, Compiegne/F, S. Vigneswaran, Bangkok,TV. Mi 1 isic, Foulayronnes /FMembranes: a clean unit operation for cleanerprocesses

10.2 - 40 M. Hlavacek, J.F. Remy, B. Smail, J. Granger,J.A. Dodds, Nancy /FCake instabilities and non-uniformitiesin cross flow microfiltration

10.2 - 41 P. Ding, C. Jallut, J. Lenoir, C. Bardot,J. Lieto, Villeurbanne/FApplication of chemical engineering methodsfor physical and chemical characteristicsdetermination of charged ultrafiltrationmembranes

10.2 - 42 S.N. Gaeta, E. Petrochi, C. Sartori, E. Drioli,Arcavacata di Rende/IEffect of preparation parameters upon structureand transport properties of polysulphone membranes

10.2 - 43 A. Basile, Cosenza; E. Drioli, Arcavacata di Rende;V. Violante, Frascati/ICatalytic membrane reactor: Prototype study forhydrogen isotopes recovery

10.2 - 44 M. Nystrbm, N. Ehsani, Lappeenranta/SF;H. Ojamo, Espoo/SFUse of modified ultrafiltration membranes infractionation of enzymes

10.2 - 45 Ray Y. K. Yang, Ch. J.Layton, Morgantown,WV/USAEnzymatic hydrolysis of cellulose in membranereactors

10.2 - 46 E. Park, S.M. Barnett, Kingston, RI/USAOil water separation by nanofiltration membranes

Session 10.3

Supercritical Fluid Separations and Reactions

Workshop: Organised by M. Perrut, Champigneulles/F

MON 17.6. Queens Hotel Saal Braunschweig

Chairmen: M. Perrut, Champigneulles/FG. Brunner, Hamburg/D

Keynote Lecture

14.00 M. Perrut, Champigneulles/F 10.3 - 1Supercritical fluid applications in the 90's

Oral Presentations

14.45 U. Muller, Quakenbruck/D 10.3 - 2Application of C02-supercritical-fluid extractionfor microbial products in food Industry

15.15 Jin-Chu Chen, Lei Jin, Y.T. Shah, 10.3 - 3M.A. Abraham, Tulsa, OK/USAA determination of rate parameters duringheterogeneous catalysis in supercritical fluids

15.45 T. Adschiri, K. Kanazawa, K. Aral, Sendai/J 10.3 - 4Chemical supercritical fluid deposition

16.15 Chin Ge, Y. Zhang, J.-Z. Tian, Jie Wang, 10.3 - 5Shenyang/PRCConcentration of gamma-1inolenic acidfrom vaccinium uliginosum oil with super-critical fluid using inclusion separation method

17.15 Poster Discussion Nancy Halle

10.3 - 10 G. Di Giacomo, V. Brandani, G. Del ReMonteluco di Roio, L'Aquila; P.P. Boattini,San Salvo, Chieti/I;Solubility of metallorganic compounds insupercritical carbon dioxide

10.3 - 11 W.E. Leyers, Greenville, SC; D.A. Linnig,Irvine/CA; R. A. Novak, Allentown, PA/USAThe design and economics of a plant to decaffeinatecoffee by supercritical extraction

10.3 - 12 A.K. Sunol, D. Ward, Tampa, FL/USASupercritical fluid aided wood compositemanufacture

10.3 - 13 J.M.L. Penninger, Hengelo/NLHydrocarbon-type reactions in supercritical water

10.3 - 14 L. Bernad, A. Keller, D. Barth, Nancy; M. Perrut,Champigneulles/FSeparation of ethanol from aqueous solutions bysupercritical carbon dioxide: Comparison betweensimulation and experiment

10.3 - 15 H.Z. Li, M. Perrut, Champigneulles/FFlash discharge of high pressure gas and super-critical fluid to atmospheric pressure: Experimentalresults and modelisation

10.3 - 16 L. Doguet, G. Fuchs, Nancy; M. Perrut, Champigneulles;A. Tambute, Vert-le-Petit/FSeparation of enantiomers by preparative supercriticalfluid chromatography

10.3 - 16 A L. Doguet, Nancy; M. Perrut, R. M. Nicoud, Champigneulles/FFlow modelisation in preparative supercritical fluidchromatography columns

10.3 - 17 T. Dumont, D. Barth, Nancy; M. Perrut, Champigneulles/FContinuous synthesis of ethyl myristate by enzymaticreaction in supercritical carbon dioxide

10.3 - 18 G. Hotier, Rueil Malmaison/FSupercritical solvent deasphalting: new improvementto a conventional process

10.3 - 19 M.L. Viriot, M.C. Carre, H. Aziz, J. C. Andre, Nancy/FSupercritical fluids as solvents for fine photochemistry

10.3 - 20 M. Carles, J. Fra, C. Perre, G. Delestre,Pierrelatte/FHigh performance pilots for supercritical extraction

10.3 - 21 P. Subra, R. Tufeu, Y. Garrabos, B. Boissinot,Vi1letaneuse/FSupercritical fluid extraction from a Mediterraneanbrown alga

Session 10.4

E x t r a c t i o n

TUE 18. 6. Nancy Halle

14.00 Poster Presentations

10.4 - 1 I. Penchev, E. Ivanova, I. Seikova, Sofia/BGFluid dynamics in liquid-liquid extractioncolumns

10.4 - 2 B. Grinbaum, J. Gai, Haifa/ILSimulation of liquid-liquid extraction processesin inorganic industry

10.4 - 3 Shin Tanaka, A. Matsuura, Chiba; S. Furusaki,Tokyo/JSolvent extraction of indole using B-cyclodextrin

10.4 - 4 M.I. Zaretsky, S.Z. Taits, V.V. Semenov,Moscow/USSRRecovery of benzothiophene and indole fromcoal-tar fractions by liquid extraction method

10.4 - 5 H. Rauscher, E. BlaB, Munchen/DMass transfer in a pulsed sieve-plateextraction column operated with an extreme phaseflow ratio

10.4 - 6 H. Hufnagl, M. Mclntyre, E. BlaB, Munchen/DDynamic behaviour and simulation of a liquid-liquid extraction column

10.4 - 7 W. Ronmel, E. BlaB, Munchen/DSeparation of liquid-liquid dispersions:Methods and equipment

10.4 - 8 J.T. Leu, A. Vogelpohl, Clausthal-Zel lerfeld/DFluid dynamics of pulsed extraction columns withstructured packings

10.4 - 9 H.-J. Bart, R. Marr, B. Wachter, Graz/AApparatus selection in solvent extraction

10.4 -10 P.I. Alvarez, H.A. Massaldi, J. A. Maymo,Santiago/RCHEfficiency of solid-liquid extraction in fixed bedsof biporous particles: theoretical and numerical solution

10.4 - 11 Zhou Li, Ch.-M. Yan, Gao-Yao She, Beijing/PRCResearch on the extraction kinetics of nickel IIcobalt II with extractant 5709

10.4 - 12 Ting-Chia Huang, Dong-Hwang Chen, Shiuh-Dong Huang;Tainan; Ching-Tsven Huang, Mu-Chang Shieh,Lung-Tan/ROCKinetic study on the extraction of uranyl nitratewith polyurethane foam

10.4 - 13 D.E. Hadjiev, Y. Aurelle, Sofia/BGSeparation processes based on phaseinversion

10.4 - 14 D. Hadjiev, L. Peneva, Sofia/BGNew type of mixer-settler unit

10.4 - 15 A.A. Abbas, Baghdad/IQScale-up of mixer settler

10.4 - 16 Yu Qian, J. Wang, Beijing/PRC or Trondheim/NModeling of mass transfer in extraction columnswith drop forward-mixing and coalescense-redispersion

10.4 - 17 K. Ethirajulu, S.B. Thakore, Baroda/INDNear critical fluid extraction of ethyleneglycol from water

10.4 - 18 P. Muhl, K. Gloe, Dresden/DLiquid-liquid extraction of metal ions -unit process for metal recovery, recycling andenvironmental protection

10.4 - 19 J. Hartl, R. Marr, Graz/AThe salting-out-process in reactive extractionsystems

10.4 - 20 W. Backer, J.P. Schafer, J. Schrbter, Leverkusen/DStructured packing in liquid-liquid-extractioncolumns

Session 10.5

A d s o r p t i o n

TUE 18. 6. Queens Hotel Saal Miinster

Chairmen: R. Leyva-Ramos, San Luis Potosi, S.L.P/MEXK. Unger, Mainz/D

Keynote Lecture

14.00 K. Knoblauch, K. Krabieil, Essen/D 10.5 - 1Environment 2000: Task and challenge foradsorption technology

15.00 Poster Discussion Nancy Halle

10.5 - 10 S.H.Kang, T.J. Lee, H.K. Ahn, Y.K.Kim,Gyongsan/ROKAdsorption of chlorofluoro-carbons byzeolites and active carbons

10.5 - 11 K. Chihara, M. Inoue, Y. Takeuchi, Kawasaki/JControl of gas adsorption rate by chemicalvapor deposition

10.5 - 12 J.U. Keller, W. Michels, Siegen/DElectro-gravimetric measurements of binarycoadsorption equilibria

10.5 - 13 M. Van de Voorde, W. Feng, H. Verelst, Brussels/BMicropore diffusion in zeolite adsorbents forair separation

10.5 - 14 A. Recnik, J. Levee, Ljubljana/YUSelective adsorption of methanol by molecularsieves

10.5 - 15 K.T. Chue, G. Grevillot, D. Tondeur, Nancy/FPotential-swing adsorption of o-nitrophenolon activated carbon in flow-through fixed bed

10.5 - 16 L.N. Rachkovskaya, S.Yu. Burylin,N.D. Topolniak, I.I. Frolova, Novosibirsk/USSRThe preparation and properties of carbon -mineral sorbents

10.5 - 17 F. Karavias, A.L. Myers, Philadelphia, PA/USASingle and binary gas adsorption in zeolitecavities: computer simulations and thermo-dynamic theories

10.5 - 18 F. Watanabe, J. Ozaki, M. Kumita, M. Hasatani,Nagoya/JPreparation of molecular sieving carbon fromlow quality carbonaceous materials

10.5 - 19 R. Leyva-Ramos, San Luis Potosi, SLP/MEXAdsorption of nitrate on several types ofcommercial activated carbons

10.5 - 20 K. Hashimoto, Y. Shirai, S. Adachi, Kyoto;M. Morishita, Wakayama/JContinuous separation of two componentsconcentrated by a simulated moving bed adsorber

10.5 - 21 Y. Nakano, Y. Seida, T. Kato, K. Suzuki,Hamamatsu/JStructure of micropores and diffusion of nitrogenand oxygen in a molecular sieving carbon

10.5 - 22 D. Bobok, P. Zhorelecky, Bratislava/CSDiffusion of chlorinated hydrocarbons inparticles of activated carbon

10.5 - 23 S. Nakamura, Y. Ito, M. Shirakashi, M. Kanno,Niigata/JDevelopment of circulating fluidized bed adsorberand its application to recovery of uranium fromseawater

10.5 - 24 M. Petkovska, M. Mitrovic, Belgrad/YUMicroscopic modeling of electrothermaldesorption

10.5 - 25 L.M. Sun, F. Meunier, Orsay/FFlow of multi-adsorbate systems through afixed adsorbent bed

10.5 - 26 E. Furuya, K. Shirasu, H. Yokomura, Kawasaki;S. Yamashita, Tokyo/J; K.E. Noll, Chicago, IL/USAComparison of intraparticle diffusion onto MRsynthetic resins and activated carbons

10.5 - 27 V. Viard, M.-L. Lameloise, Massy/FParameter evaluation for predictive modelingof the chromatographic separation of glucoseand fructose

10.5 - 28 I. Plazl, T. Kjlojni, Ljubljana/YUKinetics of NA -H ion exchange in buffersolutions

10.5 - 29 R. Leyva-Ramos, San Luis Potosi, SLP/MEX;C.J. Geankoplis, Minneapolis, MN/USAEffect of solvent on diffusion of phenol inliquid-filled pores of activated carbon

10.5 - 30 J.H. Petropoulos, J.K. Petrou, Athens/GRA.I. Liapis, Rolla, MO/USACapillary network model of gas transport innon-random bidisperse porous adsorbents

10.5-31 - withdrawn -

10.5 - 32 T. Kataoka, A. Muto, Sakai, Osaka/JMass transfer in mixed bed

10.5 - 33 J. Tobis, Warsaw/PL; D. Vortmeyer, Munchen/DThe mathematical modelling of channelling effectsin adsorption columns

10.5 - 34 S. Yamashita, Tokyo; E. Furuya, Y. Takeuchi,Kawasaki/JAmount adsorbed of organic solvent vapors on MRsynthetic resins and activated carbons

10.5 - 35 St.E. Scholl, A.B. Mersmann, Munchen/DOn the intraparticle total pressure changeduring gas phase ad- and desorption

10.5 - 36 E. Molga, S. Wronski, Warsaw/PLThe effect of particle size distribution on theefficiency of separation and purificationprocesses performed in fixed beds and slurryvessels

10.5 - 37 J.P. Crawshaw, J.H. Hills, Nottingham/UKCorn grits as a selective adsorbent forethanol/water separation

10.5 - 38 R. Lewandowski, M.L. Lameloise, Massy/FA predictive model for purification ofmolasses by ion-exclusion chromatographyusing a simulated moving bed adsorber

Session 10.6

Precipitation

Workshop: Organised by the EFChE WP Mixing

WED. 19.6. Queens Hotel Saal Braunschweig

Chairmen: A. Hackl, Wien/AA. Mersmann, Miinchen/D

Oral Presentations

9.00 D.F. Scofield, C.J. Martin, Wilmington, DE; 10.6 - 1M.A. Pivovarov, Washington, D.C./USAMeasurement and analysis of mixing in abalanced double-jet precipitator

9.30 R. David, B. Marcant, Nancy/F 10.6 - 2Interaction of micromixing withprecipitation processes

10.00 I. Hirasawa, K. Toyokura, Tokyo/J; 10.6 - 3I. Stavek, Praha/CSControlled double-jet precipitation ofsparingly soluble salts - an approach to highadded value materials

10.30 D. Hasson, A. Cornel, Haifa/IL 10.6 - 4Adsorption kinetics of a precipitationinhibitor

11.00 H. Desplanches, Y. Gaston-Bonhomme, 10.6 - 5R. Arnaud, J.L. Chevalier, Marseille/FHeat transfer efficiency in gas-Newtonian ornon-Newtonian liquid systems agitated bypitched blade turbines

Session 10.6 (cont.)

Precipitation

Workshop: Organised by the EFChE WP Crystallization

WED 19. 6. Queens Hotel Saal Braunschweig

Chairmen: A. Hack!, Wien/AW. Wohlk, Dusseldorf/D

Oral Presentations

14.00 J. Stavek, Praha/CS; I. Hirasawa, K. Muraoka, 10.6 - 6K. Toyokura, Tokyo/JControlled double-jet precipitation of lead,barium, and strontium sulfates

14.30 - withdrawn - 10.6 - 7

15.00 J.W. Mullin, J.D. Murphy, G. Spoors, 10.6 - 8London/UKMagnesium hydroxide precipitation

15.30 K.T. Jung, Y.G. Shul, Seoul/ROK 10.6 - 9Synthesis of potassium titanate powdersby sol-gel method

16.00 - withdrawn - 10.6 - 10

16.30 A. Tulke, H. Offermann, Aachen/D 10.6 - 11"On-line"-measurement of crystal sizedistribution with the help of an imageanalysing-system

Session 10.7

Crystallisation

THU 20. 6. Konferenz-Haus Saal 2

Chairmen: R. W. Rousseau, Atlanta, GA/USAJ. Ulrich, Bremen/D

Keynote Lecture

9.00 H. Vivier, M.-N. Pons, L. Le Bee, Nancy/F 10.7 - 1Application of quantitative image analysis tocrystallization

10.00 Poster Discussion Nancy Halle

10.7 - 10 I. Hirasawa, S. Imada, Y. Irie, K. Toyokura, Tokyo/JThe purity of benzene crystal from benzene-cyclohexane melt

10.7 - 11 T. Muraoka, A. Shiroishi, Toyama/JDevelopment of three-stage crystallizationprocess by connecting MSMPR type crystallizersin series

10.7 - 12 M. Matsuoka, M. Kiyomura, 0. Sakai, Tokyo/JConcentration profiles in a column crystallizerfor binary solid solution systems

10.7 - 13 K. Toyokura, K. Yamada, T. Kajiwara, J. Sato,I. Hirasawa, Tokyo; M. Moritoki, N. Nishiguchi,Kobe/JEffect of sweating operation in high pressurecrystallization

10.7 - 14 M. Yokota, T. Oguchi, K. Toyokura, Ch. Inoue,H. Naijyo, Tokyo/JEffect of suspended fines on the growth rateof L-SCMC crystals

10.7 - 15 A. Chianese, S. Di Cave, B. Mazzarotta, Roma/IGrowth rate of pentaerythritol crystals in aqueoussolutions

10.7 - 16 V.D. Luniov, S.P. Fedorov, Leningrad/USSRAanalyis od a feedback crystallizers cascadeperformance

10.7 - 17 S.P. Fedorov, Leningrad/USSRSolution of inverse problem of the kinetics ofpolydisperse systems mass crystallization

10.7 - 18 B.A. Kasimbekov, A.T. Meyerbekov, Chimkent/USSRIntensification of the substances purificationprocess by fractional crystallization

1 0 . 7 - 1 9 K. Nagahama, K. Maeda, Tokyo/JCrystallization separation of organic mixturesusing liquefied gas

10.7 - 20 K. Gramlich, H. Wenzlau, U. Gansel, A. Meyer,Kothen/DImprovements in modeling of the secondarynucleation rate

10.7 - 21 S.K. Myasnikov, Yu, L. Kuzmenko, Moscow/USSRMass transfer in countercurrent columncrystallization

10.7 - 22 J. Ulrich, Bremen/D; A. Kuszilk, S.J. Jancic,Buchs/CHA comparison of static and dynamic meltcrystallization processes

10.7 - 23 R. Riesen, A. Aichert, Greifensee/CHNew method: Crystallization process optimizedby reaction calorimetry

10.7 - 24 J. A. Budz, Rochester, NY/USAJ. Mydlarz, East Lansing, MI/USAAverage properties from number density distributionfor size-dependent crystal growth

10.7 - 25 Jing-Kang Wang, Jan Jun Jian, Qiang ZangTianjing/PRCMelt crystallization in a falling liquid film

10.7 - 26 C. Frances, B. Biscans, C. Laguerie, Toulouse/FEffect of ionic impurities and surfactantson the crystallization of tetrahydrate sodiumperborate

10.7 - 27 A. Viksna, Olaine/Latvian; G. Nosov, Y. Chernyaev,Moscow/USSRResolution of stereoisomers by preferentialcrystallization procedure

10.7 - 28 B. Ratsimba, C. Laguerie, Toulouse/FGrowth of potassium bitartrate crystalsin model solutions: comparison of theresults obtained in a fluidized bed and ina stirred vessel

10.7 - 29 I. Hirasawa, K. Noguchi, T. Niimi, T. Morita,S. Yamaguchi, K. Toyokura, Tokyo/JGrowth rate of flat plate borax crystal in asupersaturated solution with fines

Session 10.8Special Mechanical Separation Processes

THU 20. 6. 14.00 Nancy Halle

14.00 Poster Presentations

10.8 - 10 H. Biittner, Kaiserslautern/DParticle separation in cyclones

10.8 - 11 J. P. Glarner, Lenzburg/CHRemarkable progress in wet dust, dioxine andheavy metal gas scrubbing

10.8 - 12 - withdrawn -

10.8 - 13 I. Penchev, J. Hristov, G. Gouvalyas, Sofia/BGAerosol filtration in magnetically stabilizedbed filters

10.8 - 14 L. Gmachowski, Warsaw/PLEfficiency of flocculation

10.8 - 15 Y. Adachi, M. Kamiko, Ibaragi/JSedimentation of permeable floe

10.8 - 16 Th. Langeloh, Karlsruhe/DLimits of solids dewatering in centrifuges

10.8 - 17 Yeong-Lin Chen, Pou-Sen Liu, Hsin-Tsai Ho,Taoyuan /ROCBatch filtration of a crystal solution withfilter aids

10.8 - 18 R. Bott, Karlsruhe/DVersions of the continuous pressure filtration

10.8 - 19 H. Bennoit, Frankfurt am Main-Hochst/DDevelopment and application of dissolvedair flotation in the chemical industry

10.8 - 20 A. Mroz, P. Pietraszek, Warszaw/PLApparatus for dynamic classification ofsuspensions of solid bodies in liquids

10.8 - 21 J. Hristov, Sofia/BSedimentation of fibre suspensions- batch tests

Session 11.1

Interfacial Phenomena

TUE 18 6. Konferenz-Haus Saal 2

Chairman: W. Nitsch, Garching/D

Keynote Lecture

9.00 L.M. Rabinovich, Moscow/USSR 11.1 - 1Interfacial instability and mass transfer inreaction processes. Theory and intensificationmethods

10.00 Poster Discussion Nancy Halle

11.1 - 10 Jin-Gu Kim, Jong-Duk Kim, Cheongryang, Seoul/ROKThe effects of the structures of nonionic surfactants,poly(oxyethylene)n alkyl ethers on the solubilization ofphosphatidylcholine vesicles

11.1 - 11 K. Okada, Y. Akagi, N. Yoshioka, Okayama/JAnalysis of small particle trajectories aroundbubble in flotation when the particles andbubbles are both charged

11.1 - 12 M.C. Amiri, M.S. Nehzat, Isfahan/IRA new approach to colloidal gas aphron

11.1 - 13 Li-Jen Chen, Meng-Chung Hsu, Taiwan/ROCWetting transition of four-component surfactantsystems

11.1 - 14 R.S. Miao, K.T. Yu, S.Y. Wang, Tianjin/PRCStudy on the hydrodynamic and mass transfermicro behaviors near the interface of a risingbubble by laser techniques

11.1 - 15 A.A. Golovin, Moscow/USSRThe influence of the Marangoni effect on thehydrodynamics and mass transfer at extractionin moving droplet

11.1 - 16 I. Seikova, Sofia/BUL; C. Gourdon, G. Casamatta,Toulouse/FInfluence of mass transfer on drop breakage ina Kiihni column

11.1 - 17 C. Gourdon, G. Casamatta, Toulouse;G. Muratet, Paris/FRole of coalescence on the hydrodynamicbehaviour of a pulsed column: influence of masstransfer direction

11.1 - 18 P. Plucinski, W. Nitsch, Garching/DReversed micelles: Kinetic studies on theextraction of metal ions and amino acids intoan AOT/isooctane phase

11.1 - 19 Cheng-Ann Yu, Chau-Jen Lee, Hsinchu /ROCPreparation and properties of perfluorochemical(PFC) emulsions

Session 11.2

Surface and Interface Phenomena

WED 19. 6 Nancy Halle

11.00 Poster Presentations

11.2 - 10 L.N. Braginsky, Leningrad/USSRThe drop break-up in the turbulent flow inagitated vessels. The model and the method fordrop size calculation

11.2 - 11 H. Roques, Y. Aurelle, Toulouse/FOil-water separation - oil recovery and oilywastewater treatment

11.2 - 12 T. Hirose, Y. Tominaga, Kumamoto/JEffects of adsorption heat on performance ofpressure swing adsorption

11.2 - 13 E.G. Rakov, Moscow/USSRThe chemical etching of monocristalline oxide materialsby liquid flourides

11.2 - 14 K. Nahm, D.B. Chang, Chonju/ROKThe mechanism of GaAs etching reactionin aqueous solutions

11.2 - 15 J.F. Cambra, B. Guemez, P.M. Uria,P.L. Arias, Bilbao/ECommercial feedstocks hydrodesulfurizationusing Co-Mo-catalysts with fluorinated aluminaas support

Session 12.1

Process Dynamics and Control

Workshop: Organised by Members of the AIChE

WED 19.6 Konferenz-Haus Saal 3

Chairmen: V. N. Schrodt, Tuscallosa, AL/USAR Hermann, Darmstadt/D

Keynote Lecture

14.00 M. Brisk, East Melbourne, W.A. Walker, 12.1 - 1Melbourne,VIC/AUSThe economic benefits of advanced process control

Ora1-Presentat i ons

14.30 F. Panetsos, J.M. Zaldivar, Ispra/I 12.1 - 2Batch chemical reactors control and malfunctiondiagnosis using neural networks

15.00 X. Lin, R.B. Newell, St.Lucia; M.0. Tade, 12.1 - 3Perth/AUSDevelopment of structural systems for thesynthesis of control structures for largescale processes

15.30 M.0. Tade; Perth; X. Lin, R.B. Newell, 12.1 - 4M.L. Forthergill, St. Lucia/AUSComparison of interaction measures for thesynthesis of control structures for chemicalprocesses

16.00 J. Sefcik, J. Sefcik, V. Bales, Bratislava/CS 12.1 - 5Airlift reactor modelling

Session 12.1

Part 1: Process Control

WED 19.6 Nancy Halle

16.30 Poster Presnetations

12.1 - 10 P. Guiraud, J. Bertrand, J. Costes, Toulouse/FNumerical prediction of local velocities andconcentration within chemical reactors.Application to an axisymmetric jet-stirred reactor

12.1 - 11 J. Meszaros, Budapest/H; Z. Fonyo, Ziirich/CHComputer modeling of parastillation process

12.1 - 12 J.S.J. van Deventer, Stellenbosch/ZARecent developments in the dynamic simulationof adsorbent-in-pulp systems

12.1 - 13 S. Damronglerd, K. Pruksathorn, Bangkok/TMicrocomputer control on coal combustionin fluidized bed

12.1 - 14 S. SchlUter, A. Steiff, P.-M. Weinspach,Dortmund/DModeling and simulation of bubble column reactors

12.1 - 15 G.P. Rangaiah, P.R. Krishnaswamy, Singapore/SGPSet-point weighting for two recent digital controlalgorithms

12.1 - 16 Chun-Yu Chen, Chang-Chuen Sun, Tashi/ROCCritical condition detection and model-basedcontrol for packed-bed reactors

12.1 - 17 Jan-Chen Hong, Pei-Jean Young, Taipei/ROCDesign and stepwise set-point optimization formultistage adiabatic fixed-beds with catalystdecay and interstage cooling

12.1 - 18 N. Jabr, I. Alatiqi, Kuwait/KTControllability and switchability of petroleumfractionators using steady state models

12.1 - 19 K. Sakuma, K. Hashimoto, Kitakyushu City/JComputer control of column crystallizer

12.1 - 20 M. Ghoul, C. Fonteix, M. Dardenne, A. Marc, Nancy/FControl and optimization of fed-batch Hybridomacultures based on mathematical estimators

12.1 - 21 P.I. Alvarez, F. Cubillos M., Santiago/RCHStatic and dynamic simulation of a direct rotary dryer

Session 12.1 (cont.)Part 2: Measurement Techniques

WED 19.6 Nancy Halle

16.00 Poster Presentations

12.1 - 22 M. Grandclaudon, G. Wild, J.-C. Andre,N. Midoux, J.-C. Charpentier, Nancy/FInvestigation of variations of the local gas/liquidmass transfer coefficient by means of a chemi-luminescent reaction

12.1 - 23 E. G. Chatzi, C. Boutris, C. Kiparissides,Thessaloniki/GROn-line monitoring of drop size distributionsin agitated reactor vessels

12.1 - 24 S. Rode, M.A. Latifi, N. Midoux, A. Storck,Nancy/FThe use of micro-electrodes in the study offlow patterns in a trickle-bed reactor

12.1 - 25 M.-N. Pons, H. Vivier, Nancy/FStudy of extrusion by image analysis

1 2 . 1 - 2 6 V. Rothacker, K. Stephan, Stuttgart/DSpatially resolved tunable diode-laser infraredabsorption measurements using optimal Stark shifting

12.1-27 S.V. Mishchenko, S.V. Ponomarev, Tambov/USSRMethods and devices for measuring the thermo-physical properties in laminar flow of liquid

12.1 - 28 Ph. Verneau, Ph. Essel, J. Lieto, Saint-Fons/FA new approach of liquid-vapor equilibrium determination:measurement, modelling and identification

12.1 - 29 N. Eisenreich, H. Kull, T. Messer, Pfinztal/DAcousto-optic tunable filters: a spectroscopictool in the near infrared to control fast chemicalreactions

12.1 - 30 S.G. Poryvayev, V.M. Bondareva, T.V. Andrushkevich,Novosibirsk/USSRThe Raman apparatus for the in-situ investigationsof high-temperature physical-chemical processes

12.1 - 31 N.G. Triantafillopoulos, Kalamazoo, MI/;C.K. Aidun, Atlanta, GA/USADynamics of flow in a high-speed coaterwith contact application

12.1 - 32 V.A. Bernshtan, A. M. Manson, I.M.Manson,• E.V. Muravjov, D. A. Shalunov, V.I. Toshinsky,

Kharkov/USSRThe device to control the content of liquidin a gas stream

Session 12.2

Process Analysis and Synthesis

Workshop: Organised by Members of the AIChE

TUE 18. 6. Konferenz-Haus Saal 3

9.00 V. Schrodt, Tuscaloosa,AL/USAIntroduction

16.30 Conclusion and Genral Discussion

9.30 Poster Discussion Nancy HallPart 1: Design, Synthesis and Methods of Solution

12.2 - 1 Y. Tanaka, M. Tanaka, Y. Tomisaka,Kobe, Hyogo/JImprovement of thermal efficiency in airseparation systems

12.2 - 2 M. Nemecek, Neratovice/CSImprovements in chemical plant as a resultof process synthesis

12.2 - 3 S.C. Bikos, J.R. Flower, Leeds/UKSynthesis and design of energy-efficientevaporator cascades

12.2 - 4 Th. Braun, H. Schoenmakers, Ludwigshafen/DOptimization in process design

12.2 - 5 F. Friedler, K. Tarjan, Veszprem/HY.W. Huang, L.T. Fan, Manhattan, KS/USAProcess synthesis by exploiting the combinatorialproperties of feasible process structures

12.2 - 6 D. W. Kirmse, Gainesville,FL; P.K. BhattacharjeeFt. Meade, FL/USAPhosphoric acid technology selection descisionsupport

12.2 - 7 J.D. Seader, K. Gritton, Salt Lake City, UT/USAM. Kuno, Nagoya-shi/JComputing all solutions to general systems ofnonlinear equations arising in process designand simulation

Session 12.2 (cont.)

11.00 Part 2: Expert Systems. Neural Nets, Search Methods

Rapporteur: L.T. Fan, Manhattan, KS/USA

12.2 - 8 J. Corel la, E. Frances, Zaragoza/EA model for the riser of a FCC unit to predictthe product distribution based in chemicalreaction engineering principles

12.2 - 9 F. Friedler, K. Tarjan, Veszprem/HY.W. Huang, L.T. Fan, Manhattan, KA/USAAn accelerated branch and bound methodfor process synthesis

12.2 - 10 E. von Westerholt, S.S. Melsheimer, N. J. Beard;Clemson, SC/USANeural net modeling and analysis of process systems

12.2 - 11 R. Berksun, T. Giirkan, C. Ozgen, Ankara/TRDrysel: An expert system for dryer selection

12.2 - 12 S.N. Sautin, A.E. Punin, Leningrad/USSRIntegrated expert systems for design ofchemical processes

12.2 - 13 Y.L. Huang, Y.W. Huang, L.T. Fan, Manhattan, KS/USAA neural network for guiding stream matching insynthesizing a highly controllable heat exchangernetwork

Session 12.2 (cont.)

14.00 Part 3: Reliability. Uncertainty, Fuzzy Sets

Rapporteur: C.A. Floudas, Princeton, NJ/USA

12.2 - 14 G. Bloch, D. Mielcarek, Vandoeuvre;J.-P. Dubus, Saint-Avoid /FPresentation of two new multivariableidentification methods. Applications to achemical process

12.2 - 15 T. K. Zhelev, Sofia/BGReliability controlled heat exchangernetwork retrofit

12.2 - 16 A. Kraslawski, Lodz/PL; C. Gourdon,G. Casamatta, Toulouse/FOrder-of-magnitude reasoning based on fuzzyrelations

12.2 - 17 0. Sens, J.P. Caire, J.C. Delachaume,P. Ozil, Saint-Martin d'Heres/FApplication of fuzzy sets for chemical processsimulation

12.2-18 L. Badea, Bucharest/ROOverdesign of a chemical process subsystemunder conditions of uncertainty and reliability

12.2 - 19 V. Manousiouthakis, Los Angeles, CA/USATotal annualized cost minimization for heat/massexchange networks

12.2 - 20 C.A. Floudas, V. Visweswaran, Princeton, NJ/USAA global optimization algotrithm (GOP):theory and computational results

15.30 Poster Presentations Nancy Hall

12.2 - 21 Y.L. Huang, L.T. Fan, Manhattan, KS/USASynthesizing a robust controller with decoup-ling capability for a multivariable controlsystem

12.2 - 22 —

12.2 - 23 J. Krope, D. Goricanec, Maribor/YUOptimal incorporation of pumps in a pipenetwork using mixed integer separableprogramming

12.2 - 24 P. Winter, Cambridge/UKIntegrated process simulation for designand manufacturing

Session 12.3

Model supported Control in Chemical Processes

Workshop: Organised by I.D. Landau, Grenoble/F

MON 17. 6 Konferenz-Haus Saal 3

Chairmen: M.M'Saad, Saint-Martin d'Heres/FG. Eigenberger,Stuttgart/D

Oral Presentations

9.00 M.M.'Saad, I.D.Landau, Saint-Martin-D'Heres/F 12.3 - 1Model supported control in chemical processes

9.30 J. Savkovic-Stevanovic, S. Jezdic 12.3 - 2Belgrad/YUAn adaptive control system for reactiondistillation column

10.00 Wen Xu, Jixin Qian, Youxian Sun, Hangzhou/PRC 12.3 - 3Model algorithmic control and its applicationto a paper-making process

10.30 Jianhua Ge, Youxian Sun, Chunhui Zhou, 12.3 - 4Hangzhou/PRCA new hierarchical computer control system andits application in a fluidized bed reactor

11.00 Xiaoming Luo, Youxian Sun, Chunhui Zhou, 12.3 - 5Hangzhou/PRCPredictive control based on state space modeland its application in paper-making processcontrol

11.30 Poster Discussion Nancy Halle

Session 12.3 (cont.)

MON 17.6 Konferenz-Haus Saal 3

Chairmen: M.M'Saad, Saint-Martin d'Heres/FG. Eigenberger,Stuttgart/D

14.00 P. Jarupintusophon, A.M. Gaudy, M. Cabassud, 12.3 - 6M.V. Le Lann, G. Casamatta, Toulouse/FModel supported control of a semi-batch reactor

14.30 Biao Zou, Youxian Sun, Hangzhou/PRC 12.3 - 7The design of H°° multivariable decouplingcontroller and its application to paper-making process

15.00 B. Grandjean, J. Thibault, A. Normandin, 12.3 - 8Sainte-Foy, Quebec/ CDNProspective uses of neural network modelsin chemical engineering

15.30 Ping Li, Youxian Sun, Yiqun Ying, 12.3.- 9ChunhuiZhou, Hangzhou/PRCDevelopment of the mathematical model forfourdrinier paper-making process

16.00 Yan Xong, Jixin Qian, Youxian Sun, 12.3 -10Hangzhou/PRCThe modeling of fluidized bed reactor asan approach of pattern recognization

16.30 Kejin Huang, Jixin Qian, Youxian Sun, 12.3 -11Chunhui Zhou, Hangzhou/PRCModeling and simulation of extractivedistillation tower

Session 12.3 (cont.)

Discussed Poster Nancy Halle

12.3 - 12 V.I. Konovalov, A.G. Posternak, E.N. Tugolukov,L.V. Prudnik, V.N. Zatona, Tambov, USSRProblems of all-round optimizing of cooling andskrinking processes for extruded rubber andplastic products

12.3 - 13 C. Uys, M. Harmse, H.R. Vorster, Sasolburg/ZAAdvanced adaptive control algorithm fordry bottom gasifiers

12.3 - 14 Shuanghua Yang, Jicheng Wang, Hangzhou/PRCSynthesis of complex control structuresfor chemical processes

12.3 - 15 Wei-Mao Chang, Y. C. Liu, C. Y. Lee,P.Z. Gee, Hsinchu/ROCOn-line monitoring and control of cellconcentration in glutamic acid fermentation

12.3 - 16 Jianhua Ge, Youxian Sun, Chunhui Zhou, Hangzhou/PRCA study of fault-tolerant control in chemical process

12.3 - 17 Hui Wang, Jixin Qian, Youxian Sun, Chunhui Zhou,Hangzhou/PRCApplied fuzzy controller into paper-making process

12.3 - 18 Jianli Lu, Youxian Sun, Deming Wang, Hangzhou/PRCOptical fiber method of detecting local holdupof three-phase reactor

12.3 - 19 H. Nishitani, E. Kunugita, Osaka/JStructuring of on-line multi-periodoptimization

12.3 - 20 K. Fiaty, A. Accary, C. Jallut, Villeurbanne/FThermal modeling of batch reactors.Temperature error evolution connected withmodel reduction

12.3 - 21 Kwang-Soon Lee, Jinwon Cho, Tae Yoon Kim,M.K. Cho, Seoul/ROKControl of a batch reactor using iterativelearning operation

Session 13.1

Trends in Chemical Reaction Engineering

Workshop: Organised by the EFChE WP Chemical Reaction Engineering

TUE 18.6 Konferenz-Haus Saal 2

Chairmen: P. Trambouze, Vernaison/FM. Baerns, Bochum/D

Keynote Lecture

14.00 G. Eigenberger, Stuttgart/D 13.1 - 1Tasks and trends in chemical reactionengineering

Oral Presentations

14.45 Yu.Sh. Matros, A.S. Noskov, G.A. Bunimovich, 13.1 - 2Novosibirsk/USSRCatalytic reverse process for selective reductionof nitrogen oxides by ammonia and oxidation ofsulphur dioxide

15.15 K.O. Okpala, K. Littlewood, Sheffield/UK 13.1 - 3The synthesis of hydrogen cyanide and acetylenefrom methane in a nitrogen plasma jet

15.45 -^withdrawn - 13.1 - 4

16.15 Ming Rao, Edmonton.AL/CDN 13.1 - 5Challenges and opportunities for intelligentprocess control

17.00 Poster Discussion Nancy HallePoster No. 13.1 - 11 - No. 13.1 - 16

Session 13.1 (cont.)

TUE 18. 6. Nancy Halle

Discussed Posters

13.1 - 11 M.G. Makarenko, Yu.Sh. Matros, Novosibirsk/USSRTheory and practice of methanol oxidation toformaldehyde in reactors with adiabatic oxidecatalyst beds

13.1 - 12 R. G. Pigeon, A. Varma, A.E. Miller,Notre Dame, IN/USADirect synthesis of reaction-bonded densesilicon nitride

13.1 - 13 G. Flamant, A. Bamrim, G. Vallbona,Odeillo Font-Romeu/FSpouting of particles with thermal plasma a solutionfor solid conversion at high temperature

13.1 - 14 C. Roizard, F. Mokrani, 0. Korn, N. Midoux, Nancy/FThe gas-liquid centrifugal reactor: study ofhydrodynamics

13.1 - 15 P.N. Tsybuljov, V.A. Pop, P.N. Voronin,V.D. Parkhomenko,S.F. Tikhov, O.N. Kimkhai, V.A. Sadykov, E.A. Pack,L.M. Plyasova, A.G. Ziborov, G.N. Kustova, V.P. Ivanov,V.N. Kolomichuk, G.N. Krjukova, Novosibirsk/USSRNew way for oxide catalysts preparation: synthesisin plasma. Physico-chemical and catalytical propertiesof the oxide catalysts of environmental control

13.1 - 16 M. Yano, K. Nishikawa, N. Kakutani, Osaka;Y. Harano, Hiroshima/jPreparation of thin film type catalyticreactor by CVD

Session 13.1 (cont.)

WED 19.6 Konferenz Haus Saal 2

Chairmen: P. Trainbouze, Vernaison/FM. Baerns, Bochum/D

Oral Presentations

9.00 P. Trambouze, Vernaison/FReview of the presented posters

10.00 M. Crine, P.Marchot, M. Schlitz, B. Lekhlif, 13.1 - 6G. L'Homme, Liege/BLiquid spreading in trickle flow columns

10.30 F. Chiampo, R. Conti, S. Sicardi, Torino/I 13.1 - 7Recirculation reactor for the study of multiphase kinetics

11.00 Y.A. Saleh, Jeddah, Saudi Arabia 13.1 - 8P.L. Silveston, R.R. Hudgins, Waterloo,ONT/CDNActivity and selectivity enhancement in partialoxidation of propylene via forced compositionmodulation

11.30 General Discusssion

14.00 Poster Discussion Nancy Halle

13.1 - 17 G. Fevotte, Lyon; J.P. Klein, Villeurbanne/FEstimation and control of multi purpose batchevaporative crystallizers

13.1 - 18 F. Lagenier, J.M. Le Lann, X. Joulia,B. Koehret, Toulouse/FA simultaneous modular approach to dynamicprocess simulation and control

13.1 - 19 T. Kaghazchi, Tehran/IRUsing a laminar jet to determine the overallrate of liquid-liquid reactions

13.1 - 20 E. Waldmann, J.L. Schenk, G. Staudinger,R. Wutti, Graz/AA mathematical model for calculation ofsimultaneous heat and mass transfer in combi-nation with gas-solid reactions in a porousparticle

13.1 - 21 A.F.Y. Al-Shammary, I.T. Caga, I.R. Harris,A.Y. Tata, J.M. Winterbottom, Birmingham/UK1,3-butadiene hydrogenation by Pd-basedmembrane reactor catalysis

13.1 - 22 U. Nieken, G. Kolios, G. Eigenberger,Stuttgart/DAutothermal operation of fixed-bed reactorswith integrated heat-exchange

13.1 - 23 D. C. Koopman, Hong H. Lee, Gainesville, FL/USASimultaneous reaction and separation

Session 13.1 (cont.)

WED 19.6. Konferenz-Haus Saal 2

Chairman: J. Villermaux, Nancy/F

Oral Presentations

16.00 B. Jager, T. Shingles, Sasolburg/ZA 13.1 - 9A novel, cost effective commercial reactorfor Fischer-Tropsch synthesis

16.30 B. Strobel, Essen; R. Ldring, Bochum/D 13.1 - 10Advanced coal liquefaction technology:the IGOR process

17.00 General Discussion

Session 13.2Thermodynamic Challenges for Chemical Processes

Workshop: Organised by H. Renon, Paris/F

MON 17.6 Konferenz-Haus Saal 2

Chairmen: : H. Renon, Paris/F

U. Onken, Dortmund/D

Keynote Lecture

9.00 H. Renon, Paris 13.2 - 1Frontiers in thermodynamicsOral Presentations

9.45 P. Davoine, J.P. Lorand, P. Scauflaire, 13.2 - 2Bruxelles/BModelling of Solvay s bicarbonate column

10.15 D. Arnaud, S. Macaudiere, L. Niveau, 13.2 - 3S. Wosonski, Paris/FThermophysical properties of HFA 134a,comparative performances with CFC 12

10.45 G. Maurer, H. Hasse, Y. Liu, B. Rumpf, 13.2 - 4Kaiserslautern/DAdvances in modeling phase equilibria incomplex fluid systems

11.15 R. Solimando, E. Neau, A. Peneloux, 13.2 - 5Marseille; M. Rogalski, Nancy/FSimple equation of state for near criticalfluids

11.45 C.A. Hwang, J.C. Holste, K.R. Hall, College 13.2 - 6Station, TX; G.A. Mansoori, Chicago, IL/USAA simple relation to predict or to correlate theexcess functions of multicomponent mixtures

14.00 G. B.Lekhowa, Swerdlowsk/USSR 13.2 - 7The UNIFAC model for the complete VLEdiagrams restoration and for the distillationprocesses calculations in the multicomponentsystems from coal and pyrolysis tars

14.30 J.Y. Wu, G.J. Chen, K.T. Yu, Tianjin/PRC 13.2 - 8The prediction of vapor-liquid equilibriaof fluids

15.00 F. Aguirre-Ode, Valparaiso/RCH; 13.2 - 9F.J. Aguirre, Reno, NV/USAEvaluation of the unified models of associatedsolutions for the representation of excessenthalpies

15.30 J. L. Chevalier, A.M. Siouffi, F. Charbit, 13.2 - 10B. Ribero, Marseille/FDiffusion coefficients in solvent mixtures

16.00 F.-Y. Jou, F.D. Otto, A.E. Mather, 13.2 - 11Edmonton/CDNPhase equilibria in the system propane +methyldiethanollamine solution

16.30 S. Michel, S. Schulz, Dortmund/D 13.2 - 12Mutual solubilities of water and hydrocarbonsfrom an equation of state in theregion 20 - 200°C

17.00 N.A. Ovchinnikov, B.A. Grigoryev, E.V.Kovalski, 13.2 - 13N.V. Shevchenko, Grozny/USSRLiquid and saturated density predictions fordeep petroleum refining products based on originalexperimental data obtained at the pressure rangefrom 0,1 to 60 MPa

17.30 R.P. Stateva, St.G. Tsvetkov, Sofia/BG; 13.2 - 14R. Stryjek, Warsaw/PLMultiphase behaviour in the nitrogen-methane-ethane-system at low temperatures

Session 13.3

Multiphase Reaction

THU 20.6. Konferenz-Haus Saal 3

Chairman: A. Vogelpohl, Clausthal-Zellerfeld/D

Keynote Lecture

10.00 A. Vogelpohl, Clausthal-Zellerfeld/D 13.3 - 1Flow in multiphase reactors

11.00 Poster Discussion Nancy Halle

13.3 - 10 V.A. Kirillov, A.N. Glukhikh, V.M. Chanaev,Novosibirsk/USSRScale-up and liquid distribution in tricle bedreactor

13.3 - 11 I. Ziolkowska, M. Krajewska, D. Ziolkowski,Warsaw/PLRelation between packed bed structure and gasflow characteristics in tubular apparatus

13.3 - 12 J. Drahos, J. Zahradnik, F. Bradka, Praha/CSExperimental verification of liquid circula-tion pattern in bubble columns

13.3 - 13 S. Berg, A. Steiff, P.-M. Weinspach, Dortmund/DGas phase backmixing in bubble columnswith internals

13.3 - 14 P. Mitschka, V. Sobolik, 0. Wein, K. Wichterle,Praha/CSElectrodiffusion diagnostics of complexfluid flow

13.3 - 15 M. Perpar, I. Zun, I. Kljenak, Ljubljana/YUVoid fraction fluctuations and flow patterns incocurrent down-flow trickle-bed reactors

13.3 - 16 J.-W. Tzeng, H.T. Bi. L.-S. Fan, Columbus, OH/USAGas distributor effects on flow characteristicsin a slurry bubble column

13.3 - 17 K. Koide, H. Okano, K. Yamanaka, K. Shibata,K. Ohtaguchi, Tokyo/JGas holdup and volumetric liquid-phase masstransfer coefficient in gel particle suspendedbubble column

13.3 - 18 M. Nakamura, Y. Adachi, K. Kitao, F. Hori,S. Toyama, Nagoya/JMeasurement of two-phase flow in trickle bedby x-ray computed tomography method

13.3 - 19 R. Andreozzi, C. Caprio, M.G. D'Amore,A. Insola, C. Tufano, Napoli/IMathematical modeling of gas-liquid reactions:The ozonation of 2-hydroxypyridine in aqueoussolutions

13.3 - 20 W. Pippel, Hj. Oelmann, Dresden/DA new liquid phase reactor with a system of dynamicmixing elements providing low axial and effectiveradial dispersion

13.3 - 21 V.A. Kaminskii, E. B. Brun, Moscow/USSRModeling of radical polymerization batchreactor: isothermal and nonisothermal process

13.3 - 22 K. Uebo, K. Sakuma, R. Yamazaki, K. Yoshida,Tokyo/JMechanism of calcium carbonate powderformation in a three-phase reactor

13.3 - 23 A. Tsutsumi, K. Yoshida, Tokyo/JA wake shedding model for prediction ofaxial mixing in three-phase reactors

13.3 - 24 E.F. Stefoglo, O.P. Zhukova, V.M. Sonnikov,Kemerovo/USSRExperimental and mathematical simulation ofgas-liquid processes in stirred reactors withsuspended catalyst. Dynamics and study-state analysis

13.3 - 25 M.A. Zarraa, Alexandria/ETEffect of wetting agents on the rate of masstransfer during metal powder dissolution in acidicsolutions in stirred vessels

13.3 - 26 A.P. Boyes, X.X. Lu, S. Raymahasay,M.W. Tilston, M. Winterbottom, Birmingham/UKThe cocurrent downflow contactor (CDC) -A novel reactor for gas-liquid-solid reactions

13.3 - 27 S. Ledakowicz, M. Stelmachowski, A. Chacuk, Lodz/PL;W. von Wedel, W.-D. Deckwer, Braunschweig/DMethanol synthesis in surry phase reactors

Session 13.4Computer Aided Process Engineering

Workshop: Organised by the EFChE WP Computer Aided Process Engineering

THU 20. 6. Konferenz-Haus Saal 2

Chairman: S. Pierucci, Milano/I

Oral Presentations

14.00 D. Depeyre, Chatenay-Malaby/F 13.4 - 1Process system engineering

14.30 D. Rippin, Ziirich/CH 13.4 - 2Future of process operations I.

15.00 E. D. Gilles, Stuttgart/D 13.4 - 3Future of process operations II.

16.00 J.W. Ponton, Edinburgh/UK 13.4 - 4Future of process design I.

16.30 K. Lien, Trondheim/N 13.4 - 5Future of process design II.

17.00 J. Clark, London/UK 13.4 - 6Needs and opportunities in processengineering

17.30 P.K. Nair, F.B. Canfield, Houston,TX/USA 13.4 - 7Chemical engineering: The key to CIM inthe process industries