table of content page no · 2014-08-14 · table of content page no 1h nmr and 13c nmr spectra of...

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1 Supplementary Data Palladium and Copper catalyzed one-pot Sonogashira reaction of 2 nitroiodobenzenes with aryl acetylenes and subsequent regioselective hydration in water: Synthesis of 2-(2-nitrophenyl)-1-aryl ethanones Sabir Ahammed, Raju Dey, Brindaban C. Ranu* Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2

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Page 1: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

1

Supplementary Data

Palladium and Copper catalyzed one-pot Sonogashira reaction of 2

nitroiodobenzenes with aryl acetylenes and subsequent regioselective

hydration in water: Synthesis of 2-(2-nitrophenyl)-1-aryl ethanones

Sabir Ahammed, Raju Dey, Brindaban C. Ranu*

Table of Content Page No

1H NMR and 13C NMR spectra of all products listed 2-13

in Table 2

Page 2: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

2

ONO2

Table 2, entry 1

CDCl3, 300 MHz

ONO2

Table 2, entry 1

CDCl3, 75 MHz

Page 3: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

3

ONO2

Table 2, entry 2

CDCl3, 500 MHz

ONO2

Table 2, entry 2

CDCl3, 125 MHz

Page 4: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

4

ONO2

Table 2, entry 3

CDCl3, 500 MHz

ONO2

Table 2, entry 3

CDCl3, 125 MHz

Page 5: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

5

ONO2

OMe

Table 2, entry 4

CDCl3, 400 MHz

ONO2

OMe

Table 2, entry 4

CDCl3, 100 MHz

Page 6: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

6

ONO2

Cl

Table 2, entry 5

CDCl3, 300 MHz

ONO2

Cl

Table 2, entry 5

CDCl3, 75 MHz

Page 7: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

7

ONO2

nPentyl

Table 2, entry 6

CDCl3, 500 MHz

ONO2

nPentyl

Table 2, entry 6

CDCl3, 125 MHz

Page 8: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

8

ONO2

F

Table 2, entry 7

CDCl3, 300 MHz

ONO2

F

Table 2, entry 7

CDCl3, 75 MHz

Page 9: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

9

ONO2

S

Table 2, entry 8

CDCl3, 300 MHz

ONO2

S

Table 2, entry 8

CDCl3, 75 MHz

Page 10: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

10

ONO2

Table 2, entry 9

CDCl3, 500 MHz

ONO2

Table 2, entry 9

CDCl3, 125 MHz

Page 11: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

11

ONO2

Table 2, entry 10

CDCl3, 500 MHz

ONO2

Table 2, entry10

CDCl3, 125 MHz

Page 12: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

12

ONO2

Table 2, entry 11

CDCl3, 500 MHz

ONO2

Table 2, entry 11

CDCl3,125 MHz

Page 13: Table of Content Page No · 2014-08-14 · Table of Content Page No 1H NMR and 13C NMR spectra of all products listed 2-13 in Table 2 . 2 O NO 2 Table 2, entry 1 CDCl 3, 30 0 MHz

13

ONO2

S

Table 2, entry 12

CDCl3, 500 MHz

ONO2

S

Table 2, entry 12

CDCl3,125 MHz