system optimization and selection of lignite coal drying process for coal mines
TRANSCRIPT
Solutions for Coal Drying
System optimization and selection of lignite coal drying process for coal mines
Lignite Coal Misture and Ash
Lignite Coal Production
Country or area Year Quantity,thousand ton
United States 2011 503890
China 2011 450000
Germany 2011 160210
Australia 2012 109730
Russian 2011 75410
Poland 2011 61800
Turkey 2011 60670
Greece 2011 59860
Serbia 2011 39480
Czech Republic 2011 39260
Romania 2011 36920
Country or area Year Quantity,thousand ton
Canada 2011 36660
Bulgaria 2011 35230
India 2011 32060
Thailand 2011 17160
Mexico 2011 15590
Estonia 2011 14390
Other Asia 2011 13080
Bosnia and
Herzegovina 2011 11790
Philippines 2011 10960
Hungary 2011 9500
Indonesia 2011 8000
1801650
Lignite coal for power
generation
Country or area Year Quantity,thousand ton
United States 2011 503890
Germany 2011 160210
Australia 2011 109730
China 2012 100000
Russian 2011 75410
Poland 2011 61800
Turkey 2011 60670
Greece 2011 59860
Serbia 2011 39480
Czech Republic 2011 39260
Romania 2011 36920
Country or area Year Quantity,thousand ton
Canada 2011 36660
Bulgaria 2011 35230
India 2011 32060
Thailand 2011 17160
Mexico 2011 15590
Estonia 2011 14390
Other Asia 2011 13080
Bosnia and
Herzegovina 2011 11790
Philippines 2011 10960
Hungary 2011 9500
Indonesia 2011 8000
1451710
Benefits and issue with
lignite coal drying
• Benefits with lignite coal drying
Reduce moisture
Reduce ash
Increase heating value
Reduce transportation cost
• Issues with lignite coal drying
Spontaneous combustion
Coal dust during handling
Benefits and issue with
lignite coal drying
• Spontaneous combustion of lignite coal
Mechanism of spontaneous combustion of lignite coal
Lignite coal has a large surface area and therefore has a strong ability to absorb oxygen due to its porous structure;
When lignite coal contacting with air, oxygen physisorption of coal occurs first, and physisorption heat is released;
Chemical absorption and chemical reaction happens and chemical reaction and chemical adsorption heat are released afterwards;
It will cause self-heating if heat produced cannot be carried away immediately and coal temperature rises constantly with heat buildup inside coal;
Coal temperature rising causes the oxidation reaction more intensive; intensive reaction would release more heat; and speed of coal temperature rising accelerates further and vicious circle accelerates, spontaneous combustion occurs when coal temperature reaches its ignition temperature.
• Coal dust issue during handling
According to study, coal dust problem is mainly caused by fine coal less than 0.6mm. Solution:
Selecting grinding equipment with minimum fine coal
Separation of fine coal from coarse coal: fine coal can be used as fuel for drying process; the remaining fine coal can be sold nearby; and fine coal briquetting.
Benefits and issue with
lignite coal drying
• Mechanism of inhibition of spontaneous combustion of lignite
By destroying or reducing the structure with lower activation energy;
Coal surface is inerted by covering with binders to reduce contacting chance between coal and oxygen;
By water spraying on the surface of coal pile to absorb heat and reduce heating speed;
• Measures of inhibition of spontaneous combustion of lignite
Dried lignite coal briquetting can destroy or reduce structure with lower activation energy. Many attempts, but no successive story in industry;
Coal pile surface inerted treatment by covering with airtight cloth or scaring formed by binder spraying to prevent contacting between coal and oxygen;
Water spraying on surface of coal pile to cool down. This is widely used in industry;
• Fine coal briquetting (Binderless Coal Briquetting, BCB process; Hot briquetting process, HBP):
(1), Fine coal collection fine coal is collected by cyclone after dryer. Fine coal dusting issue is mainly caused by fines 150 mesh or less; 150 mesh or less fines only accounts for 35% or so from cyclone;
(2), Fine heating Fined coal is heated close to its softening point with vertical indirect heating
(3), Fines screening Fine coal is then screened after heating. According to the mechanism of pressing granulation, occupied state and void ratio of fines are determined by its size distribution; larger bonding interface between fines are necessary for fine briquetting and finer coal would have higher strength of product. Screening before briquetting is necessary: the amount of fines to briquetting process is reduced; strength of product is increased, which is particularly important for lignite coal as it will experience multi loading and unloading for long distance transportation;
(4), Fine briquetting: Fine coal passed screen is briquetted after screening with roll compactor;
Features of BCB / Hot briquetting
Binderless and low cost
Fines are heated up to close its softening temperature and therefore power consumption for briquetting can be reduced to minimum;
Benefits and issue with lignite coal drying
Selection of lignite coal pre-drying technologies
Available drying technologies for lignite coal
Flue gas
fluidized
bed dryer
Flue gas
rotary
dryer
Flue gas
flash
dryer
Superheated
steam fluidized
bed dryer
Steam
rotary
dryer
Microwave
dryer
Size mm 0-50 0-50 0-6 0-6 0-6 0-50
Heating source Flue gas Flue gas Flue gas Steam Steam Electricity
Energy consumption
kw
1 1.25 1.25 1.5 0.8 2
Drying & de-ashing
integrated
Y N N N N N
Water evaporation /
unit
500 30 30 100 30 NA
Investment 1 1,5 1.5 2 2 NA
Selection of lignite coal pre-drying technologies
DDT high temperature flue gas fluidized bed dryer process •High temp flue gas fluidized bed dryer has been developed based on conventional low to medium temp (650 C and below ) to utilize high temp flue gas (900 C to 1000 C ) ; •The inlet flue gas temp was only about 450 C in the original design in the early stage, and it was gradually increased with the increase of production. The highest inlet flue gas was reached 750 C in operation nowadays; •DDT has developed air distribution with independent Intellectual Property Rights which made it possible to increase inlet flue gas to 1000 C;
Selection of lignite coal pre-drying technologies
Features of high temperature flue gas fluidized bed dryer
•Inlet flue gas temperature can be as high as 950C;
•Small equipment dimension, low capital investment and low energy consumption due to higher inlet flue gas temperature;
•Larger capacity: up to 500t/h water evaporation per unit;
•Coarse coal (up to 50mm) can be dried;
•Drying and de-ashing can be integrated;
•Can be designed and operated in slight positive system pressure, oxygen concentration can be controlled to 2.5% or less, which makes sure that drying system is free of coal dust explosion and it is also ideal for coal gasification(for higher yield of tar oil)
•Fine can be separated from coarse coal
•Fine coal can be used as dryer fuel; sold nearby or briquetting for long distance transportation
Flow sheet for high temperature flue gas fluidized bed dryer ( Drying & de-ashing integrated)
Selection of lignite coal pre-drying technologies
LFC process
•Lignite coal is still hydrophilic with drying treatment only, water absorption and spontaneous combustion issues still remain due to no change in structure and property.
•Lignite coal is changed from hydrophilic to hydrophobic with mild pyrolysis treatment, no issue with water absorption and spontaneous combustion as its structure and property are changed.
•LFC is a mild pyrolysis or carbonization process ( moderate temperature and atmospheric pressure):
•The first step is to remove most of water in rotary grate dryer (3% or so);
•The second step is a mild pyrolysis process to remove the remaining water and portion of volatile; to upgrade lignite coal to high-quality solid fuel (Process Derived Fuel, PDF, namely semi-coke) with stable physical and chemical properties. By product, the liquid (Coal Derived Liquid, CDL, namely coal tar), is also produced.
•The third step is purification of the solid product to decrease its activity by passivation treatment.
•For the fines produced in LFC process is briquetted with binder.
Modified LFC process
Drawbacks for LFC process
•Rotary grate dryer and pyrolysis in LFC process are poor in mass and heat transfer;
•Coal to pyrolysis is 3% moisture and at lower temperature requires larger amount of process air flow, which leads to more heating loss and lower heating value of fuel gas from LFC process;
•Briquetting process increases production cost;
Modified LFC process
Modified LFC process
Major modifications
Replacement of rotary grate dryer and pyrolyzer with high temp fluidized bed dryer and pyrolyzer due to fluidized bed dryer and pyrolyzer are excellent in heat and mass transfer.
Fluidized bed dryer can be designed as two layers ( drying and heating are integrated ) due to high inlet temp flue gas. Coal to pyrolyzer can dried to 0% moisture and heated up to close its reaction temperature.
Amount of process air flow can be reduced to minimum and loss due to process air can be minumum and heating value of fuel gas from LFC process can be maximum;
Fine briquetting is hot briquetting (Binderless Coal Briquetting, BCB) and production coat can be reduced.
Modified LFC process
Advantages of modified LFC process over LFC process:
Double layer fluidized bed dryer (drying & heating) vs Rotary grate dryer;
High inlet flue gas temperature (950C) vs low inlet flue gas temperature (455C for dryer and 725C for pyrolyzer);
Low outlet exhaust temperature (75C) vs high outlet exhaust temperature (200C for dryer only, same for pyrolyzer);
Smaller amount of process air flow (1 & 1) vs Larger amount of process air flow 4.5 & 3 ;
Smaller fluidized bed area (2m2& 1m2) vs Larger rotary grate cross area (2m2 & 1m2);
High system energy utilization efficiency vs Low system energy utilization efficiency ;
De-ashing integrated vs no de-ashing integrated ;
Larger capacity per unit (40000t/d) vs Smaller capacity per unit (2000t/d) ;
Low capital investment vs High capital investment
BCB process for fines vs Briquetting process with binder
High tar oil yield due to fast heating speed of coal vs Low tar oil yield due to slow heating speed of coal
High fuel heating value 3 vs Low fuel heating value 1
Modified LFC process
Factors should be considered for LFC process
•Tar oil ratio from raw coal;
•Tar oil market and price;
•Solid fuel market and price;
Modified LFC process
Modified LFC process
Modified LFC process
Modified LFC process
Modified LFC process