synthesis and characterization of triphenylethylene derivatives with aggregation induced emission...
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Synthesis and Characterization of TriphenylethyleneDerivatives with Aggregation-Induced EmissionCharacteristics
Presented by : Muhammad Faisal 10060607-084
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INTRODUCTION
• Aggregation Induced Emission (AIE) Property
• Organic luminescent materials with AIE properties
• Applications of AIE in the areas of
– Electroluminescence devices
– Chemosensors
• Limited in number due to complicated and difficult preparation.
• Triphenylethylene carbazole and triphenylethylene derivatives
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EXPERIMENTAL
• SYNTHESIS:– The derivatives were easily prepared by a three-step reaction, including
the Suzuki and Wittig–Horner reactions.
• CHARACTERIZATION:– Structural Identification– Thermal Properties– Photopysical and Electrochemical Properties– Aggregation Induced Emission Properties
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RESULTS & DISCUSSION
Thermal properties:
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RESULTS & DISCUSSION
Photophysical and Electrochemical Properties:
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RESULTS & DISCUSSION
Aggrigation Induced Emission Properties:
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CONCLUSION• We have developed New class of AIE compounds……
• Blue light emitters
• Maximum fluorescence emission wavelength 443-461
nm.
• Glass transition temperature range, 86-129 °C…..
• Decomposition temperature, 432-534 °C…..
• HOMO levels are between5.61-5.66 eV….
• ΔEg values range is 3.18-3.22 eV….
• The compounds (BN)2Bt and (BB)2Bt exhibited vibronic
fine-structure PL spectra when the water fraction was less
than 70%