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Synoptic List of Precautions, Usage, and Health Effects of Selected Pesticides Information provided by product labels unless otherwise indicated 7/26/2007 For the LRC Katlego Matsila List ordered alphabetically

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Page 1: Synoptic List1

List ordered alphabetically

Synoptic List of Precautions, Usage, and Health Effects of Selected Pesticides Information provided by product labels unless otherwise indicated 7/26/2007 For the LRC Katlego Matsila

List ordered alphabetically

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List ordered alphabetically

1. Aqua-Rights by Ag-Chem Africa

a. Label Requirements

i. Precautions:

1. Avoid prolonged contact with concentrated product.

2. In the case of contact, wash affected area with soap and water.

3. In case of contact with eyes flush immediately with water for at

least 10 minutes.

4. Rinse empty container three times with a volume of water equal

to at least 10% that of the container and add the rinsings to the

contents of the spray tank before disposing of the container in

the prescribed manner.

5. Destroy empty container by perforation and flattening and

never use for any other purpose.

6. Prevent contamination of food, feeds, drinking water and eating

utensils.

ii. Handling and Personal Protection:

1. Ventilation system:

a. In general, dilution ventilation is a satisfactory health

hazard control for this substance. However, if

conditions of use create discomfort to the worker, a

local exhaust system should be considered.

2. Skin Protection:

a. Wear suitable personal protective equipment including

approved respiratory protection.

3. Hand Protection:

a. Wear appropriate hand gloves where necessary.

4. Eye Protection:

a. Use chemical safety goggles and/or full face shield

where splashing is possible. Maintain eye wash fountain

and quick-drench facilities in work area.

b. Hazards and other Effects on the Health

i. Direct Health Effects

1. Causes eye burns and irritation.

2. Harmful if swallowed or inhaled.

3. Causes irritation to skin and respiratory tract.

ii. Potential Health Effects

1. Inhalation:

a. Causes irritation to the mucous membranes of the

respiratory tract. May be absorbed from the mucous

membranes and depending on the amount of exposure

could result in the development of nausea, vomiting and

diarrhoea.

2. Ingestion:

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a. Symptoms parallel absorption via inhalation.

Aspiration into lungs may occur during swallowing or

vomiting, resulting in lung damage.

3. Skin Contact:

a. Causes skin irritation. Not significantly absorbed

through the intact skin. Readily absorbed through

damaged or burned skin.

4. Eye Contact:

a. Causes irritation, redness and pain.

5. Chronic Exposure:

a. No information found.

6. Aggravation of Pre-existing Conditions:

a. No information found.

2. Boziman by Ag-Chem Africa

a. Label Requirements

i. Handling and Personal Protection:

1. Ventilation system:

a. In general, dilution ventilation is a satisfactory health

hazard control for this substance. However, if

conditions of use create discomfort to the worker, a

local exhaust system should be considered.

2. Skin Protection:

a. Wear suitable personal protective equipment including

approved respiratory protection.

3. Hand Protection:

a. Wear appropriate hand gloves where necessary.

4. Eye Protection:

a. Use chemical safety goggles and/or full face shield

where splashing is possible. Maintain eye wash

fountain and quick-drench facilities in work area.

b. Hazards and other Effects on the Health

i. Direct Health Effects:

1. Harmful if swallowed or inhaled.

2. Causes irritation to skin and respiratory tract.

ii. Potential Health Effects:

1. Inhalation:

a. Causes irritation to the mucous membranes of the

respiratory tract. May be absorbed from the mucous

membranes and depending on the amount of exposure

could result in the development of nausea, vomiting,

diarrhoea and gastric distress.

2. Ingestion:

a. Symptoms parallel absorption via inhalation.

3. Skin Contact:

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a. Causes skin irritation. Not significantly absorbed

through the intact skin. Readily absorbed through

damaged or burned skin. Symptoms of skin absorption

parallel inhalation and ingestion.

4. Eye Contact:

a. Causes irritation, redness and pain.

5. Chronic Exposure:

a. Prolonged absorption causes weight loss, vomiting,

diarrhoea, skin rash, convulsions and anaemia. Liver

and particularly the kidneys may be susceptible. May

cause respiratory tract irritation, coughing and chest

discomfort.

6. Aggravation of Pre-existing Conditions:

a. Persons with pre-existing skin disorders or eye

problems, or impaired liver, kidney or respiratory

function may be more susceptible to the substance.

3. Citrex by BASF

a. Label Requirements

i. No Relevant Precautions found.

b. Hazards and other Effects on the Health

i. Direct and Potential Health Effects:

1. May cause skin and eye irritation.

2. Sign and Symptoms of Poisoning:

a. No cases of human acute intoxication have been

reported (irritation).

3. Skin Contact:

a. Moderately irritant to the, skin. Prolonged and repeated

exposure may cause chronic dermatitis. Wash

contaminated area with soap and water. If irritation

persists, seek medical attention.

4. Eye Contact:

a. Mildly irritant to the eye. Flush the eye with water. If

irritation persists seek medical attention.

5. Ingestion:

a. Accidental ingestion is an unlikely event. Special

measures are not indicated. Do not induce vomiting.

Give 1/4 litre of water to drink. Refer for medical

attention.

6. Inhalation:

a. Inhalation of concentrated oil mist may cause irritation

of upper respirators tract. Remove affected person to

fresh air. If rapid recovery does not occur refer for

medical attention.

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7. Emergency Antidote:

a. There is no specific antidote.

ii. Precautions:

1. Wash contaminated clothing daily.

2. Avoid contact with the eyes and/or skin, do not inhale the spray

mist.

3. Wash with soap and water after use or accidental skin contact.

4. Copsul 3 (Details below pretty much apply to Copsul as made by Universal Crop

Protection, Plaaskem, and Villa Crop through check with individual makers if further

details needed).

a. Label Requirements

i. Label:

ii. Handling:

1. Handle with care. Toxic when swallowed. May irritate skin and

eyes. Store away from food and feedstuffs in a cool, dry place.

Keep out of reach of children, animals and uninformed persons.

Toxic to fish and wildlife.

2. Handling in the Course of Employment and Protective

Equipment:

a. Clothing:

i. Employee must wear appropriate protective

(impervious) clothing, boots, hat and equipment

to prevent repeated or prolonged skin contact

with this substance. Do not wear leather

clothing.

b. Gloves:

i. Employee must wear appropriate chemical

resistant protective gloves to prevent contact

with this substance.

c. Eye protection:

i. The use of safety goggles is recommended.

d. Emergency eye wash:

i. Where there is any possibility that an

employee’s eyes may be exposed to this

substance, the employer should provide an eye

wash fountain or appropriate alternative within

the immediate work area for emergency use.

iii. Usage:

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1. Aerial application:

a. Notify all inhabitants of the immediate area to be

sprayed and issue the necessary warnings. Do not spray

over or allow drift to contaminate water and adjacent

areas.

2. Precautions when Using:

a. Do not inhale dust or spray mist. Wear protective

clothing, mask and rubber gloves while handling and

applying the product. Wash with soap and water after

use. Prevent drift onto other crops, grazing, rivers, dams

or areas not under treatment. Clean applicator after use

and dispose of wash water where it will not contaminate

food, grazing, rivers or dams. Destroy empty container

after emptying it thoroughly over the mixing tank. Do

not use empty container for any other purposes. Prevent

contamination of food, feed, drinking water and eating

utensils and do not eat, drink or smoke whilst applying

or mixing or before washing hands and face or changing

clothing.

b. Hazards and other Effects on the Health

i. Toxicological Information

1. Acute skin and eye irritation:

a. Skin and eye irritating.

2. Dermal sensitization:

a. No information currently available

3. Carcinogenicity:

a. Animal studies did not detect any carcinogenic activity.

4. No human data available.

a. Teratogenicity:

5. Animal studies did not detect any teratogenic effects. No

a. human data available.

6. Mutagenicity:

a. Not mutagenic

5. Demildex 3 by Delta Chemicals

a. Label Requirements

i. Aerial application:

1. Notify all inhabitants of the immediate area to be sprayed and

issue the necessary warnings. Do not spray over or allow drift

to contaminate water and adjacent areas.

ii. Precautions in Usage:

1. Do not inhale dust or spray mist. Wear protective clothing,

mask and rubber gloves while handling and applying the

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product. Wash with soap and water after use. Prevent drift onto

other crops, grazing, rivers, dams or areas not under treatment.

Clean applicator after use and dispose of wash water where it

will not contaminate food, grazing, rivers or dams

b. Hazards and other Effects on the Health

i. Direct and Potential Health Effects:

1. Inhalation: Dust will cause irritation and coughing.

2. Ingestion: The ingestion of a large quantity of Copper

Oxychloride is followed by nausea and vomiting. A metallic

taste and a burning sensation in the oesophagus and stomach.

LD50 value = 1 667mg/Kg.

3. Skin and eye contact: Powder is irritating to skin.

4. Dust is irritating to eyes.

5. Chronic Toxicity: Frequent persistent contact with the skin can

cause skin irritation.

6. Carcinogenicity: Not Applicable.

7. Mutagenicity: Not Applicable.

8. Reproductive hazards: Unknown.

9. The ingestion of a large quantity is followed by nausea and

vomiting. A metallic taste and a burning sensation in the

oesophagus and stomach.

10. Flammability: Non-flammable.

11. Chemical Hazard: None, if powder is kept dry. Wet powder is

corrosive to most metals.

12. Biological Hazard: None.

13. Reproduction Hazard: None.

ii. Precautions and Directions for Accidental Exposure:

1. Personal Precautions: Avoid breathing dust, wear dust mask if

necessary.

2. Avoid contact with eyes wear goggles if necessary.

3. Avoid contact with skin; wear rubber gloves and long sleeved

shirt and trousers.

4. Environmental Precautions: Do not allow to enter drains,

sewers or watercourses.

5. Small Spills: Sweep spills up, place in clean container and

remove to chemical waste site.

6. Large Spills: Sweep spills up, place in clean container and

remove to chemical waste site.

6. Dicarzol 1b by Bayer CropScience

a. Label Requirements

i. Label:

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b. Precautions:

i. Handle with extreme care.

ii. Poisonous when swallowed, inhaled or through skin contact.

iii. Toxic to fish, bees and wildlife. Do not apply when bees are actively

visiting treated areas.

iv. Store under lock and key in a cool, dry place, away from food and

feed.

v. Keep out of reach of children, uninformed persons and animals.

vi. Do not expose product to humidity. Because of the hygroscopicity of

the product, the container should be tightly sealed if any product is left

after use.

vii. In case of poisoning - CALL A DOCTOR AND MAKE THIS LABEL

AVAILABLE TO HIM.

c. General Usage:

i. Do not inhale fumes or spray mist.

ii. Wear protective clothing (overall, boots, rubber gloves, respirator, face

shield) when handling or applying the product.

iii. Wash contaminated clothing daily.

iv. Wash immediately with soap and cold water after use or accidental

skin contact.

v. In case of eye contact, flush immediately with plenty of water for at

least 15 minutes.

vi. Do not eat, drink or smoke whilst mixing or applying or before

washing hands and face and changing clothes.

vii. Prevent contamination of food, eating utensils, feed and drinking

water.

viii. Clean applicators thoroughly before re-using with other material and

do not pollute the environment with wash water.

ix. When empty, rinse the container three times with a volume of water

equal to at least one tenth of that of the container and add the rinsings

to the contents of the spray tank. Destroy the container by puncturing

and burying or burning it. Do not use the container for any other

purpose.

d. Re-entry, Aerial Application, and Drift:

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i. Re-entry – Do not enter treated area within 2 days after treatment

unless wearing protective clothing.

ii. Aerial application - notify all inhabitants of the immediate area to be

sprayed and issue the necessary warnings. Do not spray over or allow

drift to contaminate adjacent areas or water.

iii. Prevent spray drift onto other crops, grazing, rivers, dams or other

areas not under treatment.

e. Hazards and other Effects on the Health

i. Symptoms of Poisoning with High Toxicity Carbamate Compounds.

1. Headache, fatigue, faintness, giddiness, excessive sweating,

nausea, abdominal pain, vomiting, blurred vision, muscle

twitching, usually small pupils, respiratory distress, coma.

ii. Symptoms of Poisoning with High Toxicity Carbamate Compounds

(from an independent source).

1. High Toxicity Carbamate Pesticides:

a. Malaise, muscle weakness, dizziness, and sweating.

b. Headache, salivation, nausea, vomiting, abdominal pain,

and diarrhoea.

c. Miosis with blurred vision, incoordination, muscle

twitching and slurred speech.

d. In more severe cases: Central nervous system

depression (coma, seizures and hypotonicity),

hypertension and cardiorespiratory depression. Also

dyspnea, bronchospasms and bronchorrhea with

eventual pulmonary edema.

7. Dichlorvaros by Universal Crop Protection

a. Label Requirements

i. Label:

ii. General Usage and Precautions:

1. Do not inhale spray mist or fumes.

2. Wear protective clothing, suitable mask, rubber gloves and

boots. Wash contaminated clothing daily.

3. Wash with soap and water after use.

4. Prevent contamination of food, feed, drinking water and eating

utensils and do not eat, drink or smoke while applying, mixing

or before washing hands and face and changing clothing.

iii. Drift, Re-entry, and Aerial Application

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1. Drift: Prevent drift onto other crops, grazing, rivers, dams or

areas not under treatment.

2. Re-entry: Keep treated buildings closed for about 12 hours and

ventilate well before re-entry.

3. Aerial Application: Notify all inhabitants of the area to be

sprayed and issue the necessary warnings. Do not spray over or

allow drift to contaminate adjacent areas or water.

b. Hazards and other Effects on the Health

i. Direct and Potential Health Effects:

1. Toxicity class:

a. WHO Ib, EPA I: Dichlorvos is a compound which

inhibits cholinesterase enzyme activity in the nervous

tissue. It is of very high toxicity. Contact with skin,

inhalation of dust or spray, or swallowing may be fatal.

Slightly toxic to fish and birds and toxic to bees.

2. Likely routes of exposure:

a. May be absorbed from the gastrointestinal tract, through

the intact skin, and through inhalation of fine spray mist

or dust.

3. Eye contact:

a. Highly toxic. Mildly irritating to eyes.

4. Skin contact:

a. Highly toxic, due to possible absorption. Mildly

irritating to skin.

5. Ingestion:

a. Highly toxic by ingestion. See point 4 for symptoms.

6. Inhalation:

a. Highly toxic by inhalation, depends on volatility of

compound. See point 4 for symptoms.

ii. Symptoms of Poisoning:

1. Nausea, headache, tiredness, giddiness, blurred vision and

papillary constriction, vomiting, abdominal pain, diarrhoea,

sweating and salivation. Confusion, ataxia, slurred speech, loss

of reflexes are some of the central nervous system effects

which may lead to misdiagnosis of acute alcoholism.

2. After inhalation of vapours effects appear within minutes:

ocular and respiratory effects. These include marked miosis,

ocular pain, conjuctival congestion, diminish vision, ciliary

apasm and brow ache. With acute systemic absorption:

rhinorrhea, hyperemia of upper respiratory tract, tightness in

the chest and wheezing respiration.

iii. Symptoms of Severe Intoxication:

1. Salivation, involuntary defecation and urination, sweating,

lacrimation, penile erection, bradycardia and hypotension.

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iv. Other noted Symptoms:

1. Overexposure effects:

a. After inhalation of vapours or aerosols effects appear

within minutes: ocular and respiratory effects generally

appear first. This include marked miosis, ocular pain,

conjunctival congestion, diminished vision, ciliary

spasm and brow ache.

2. With acute systemic absorption:

a. Miosis may not be evident due to sympathetic discharge

in response to the hypotension. In addition to rhinorrhea

and hyperemia of the upper respiratory tract, respiratory

effects consist of “tightness” in the chest and wheezing

respiration, caused by the combination of broncho-

constriction and increased bronchial secretion.

3. Gastrointestinal symptoms occur earliest after ingestion, and

include anorexia, nausea and vomiting, abdominal cramps, and

diarrhoea.

4. With percutaneous absorption of liquid, localised sweating and

muscular fasciculation in the immediate vicinity are generally

the earliest manifestations.

8. Dithane by Dow AgroSciences

a. Label Requirements

i. Label:

ii. Usage and Precautions:

1. Precautions:

a. Avoid contact with the skin, eyes and clothes, as well as

inhalation of dust and spray mist.

b. Wear face mask and rubber gloves when mixing

product.

c. Wash thoroughly with soap and water after application

and in case of eye contamination, rinse the eyes

thoroughly with plenty of cold water and obtain medical

aid if necessary.

d. Wash contaminated clothing.

e. Prevent contamination of food, feeds, drinking water

and eating utensils.

f. Clean application equipment after use and dispose of

wash water where it will not contaminate crops,

pastures, rivers, dams or other water sources.

2. Drift, Aerial Treatment, and Re-entry:

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a. Do not spray over water or allow spray drift onto water

or adjacent areas not under treatment.

b. Re-entry: Do not enter treated field/orchard until spray

deposit has dried unless wearing protective clothing.

c. Aerial Application: Notify all inhabitants of the

immediate area to be sprayed and issue the necessary

warnings. Do not spray over or allow drift to

contaminate water or adjacent areas.

b. Hazards and other Effects on the Health

i. Direct and Potential Health Effects

1. May cause sensitization of the skin and irritation of eyes and air

passages.

ii. Direct and Potential Health Effects (Independent Source)

1. Symptoms of Poisoning

a. Irritation of skin, eyes and respiratory tract.

b. Skin sensitization.

c. Chronic skin disease has been observed in

occupationally exposed workers.

2. Other Reactions to Exposure:

a. Inhalation: Cough. Sore throat.

b. Skin: Redness.

c. Eyes: Redness, Pain.

d. Ingestion Diarrhoea: Nausea, Vomiting.

9. Dursban 480 EC by Dow AgroSciences

a. Label Requirements:

i. Label

ii. Usage and Precautions:

1. Wear protective clothing whilst mixing and applying –

protective gloves and face shield. Wash with soap and water

after use or accidental skin contact.

2. Avoid contamination of food, feedstuffs, drinking water and

eating utensils.

iii. Mist Drift, Aerial Application, and Re-entry:

1. Avoid inhalation of spray mist.

2. Re-entry period: Do not enter treated fields/orchards within 1

day after application unless wearing protective clothing.

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3. Aerial Application: Notify all inhabitants of the immediate area

to be sprayed and issue the necessary warnings. Do not spray

over or allow drift to contaminate water or adjacent areas.

b. Hazards and other Effects on the Health

i. Symptoms of Human Poisoning:

1. Headaches, fatigue, faintness, giddiness, excessive sweating,

nausea, abdominal pains, vomiting, diarrhoea, tightness of

chest, anxiety, blurred vision, muscle twitching beginning in

eyelids and tongue, usually small pupils, respiratory distress,

convulsions, coma.

ii. Notice to Physician:

1. This material contains both a cholinesterase inhibitor and a

solvent. Atropine, only by injection, is the preferable antidote.

Oximes, such as 2-PAM/protopam, may be therapeutic if used

early; however, use only in conjunction with atropine. If lavage

is performed, suggest endotracheal and/or oesophageal control.

Danger from lung aspiration must be weighed against toxicity

when considering emptying the stomach. Supportive care.

Treatment based on judgement of physician in response to

symptoms of patient.

10. Folpan – Label Not Found

11. Flint by Bayer CropScience

a. Label Requirements

i. Label

ii. Usage and Precautions

1. Wear an overall, rubber gloves and boots, face mask and shield

when preparing spray mixture and overall and rubber boots

when spraying.

2. Do not inhale product dust or spray mist.

3. Avoid contact of skin, eyes and clothing with product or spray

mist.

4. Wash hands and entire body with soap and water after use.

5. Wash contaminated clothing after use.

iii. Drift and Re-entry:

1. Avoid drift of spray onto other crops, grazing, rivers, dams,

boreholes and areas not under treatment.

2. Re-entry: Do not enter treated area until spray deposit has dried

unless wearing protective clothing

b. Hazards and other Effects on the Health

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i. Direct and Potential Effect on Health:

1. May cause sensitization by skin contact.

2. Poisonous if swallowed, inhaled or absorbed through the skin.

3. Very toxic to fish and other aquatic organisms.

4. Slight skin irritation on rabbit. No skin sensitization on guinea

pigs.

5. Irritant to the mucus membrane of the rabbit.

12. Glucomag by AG Chem Africa

a. Label Requirements

i. Relevant Data Not Fount

b. Hazards and other Effects on the Health

i. Direct Health Effects:

1. Causes eye burns and mild irritation.

2. Mildly harmful if swallowed.

3. Causes mild irritation to skin.

ii. Potential Health Effects

1. Inhalation: Not harmful if inhaled.

2. Ingestion: Mildly harmful if swallowed.

3. Skin Contact: Causes mild skin irritation. Not significantly

absorbed through the intact skin.

4. Eye Contact: Causes mild irritation to eyes.

5. Chronic Exposure: No information found.

6. Aggravation of Pre-existing Conditions: No information found.

13. Legend 250 SC by Dow AgroSciences

a. Label Requirements

i. Label:

ii. Usage and Precautions:

1. Avoid contact with eyes, skin and inhalation of fumes and

spray mist.

2. Wear protective clothes and face shield when preparing the

spray mixture and during spraying.

3. In case of direct contact with skin, wash with soap and water.

4. In case of direct eye contact, rinse for several minutes with

clean water.

5. Wash contaminated clothing daily.

6. Prevent contamination of food, feed, drinking water and eating

utensils.

iii. Drift and Re-entry:

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1. Re-entry: Do not enter treated area until spray deposit has dried

unless wearing protective clothing.

2. Avoid drift of spraymist onto other crops, grazing, rivers, dams

and other areas not under treatment.

b. Hazards and other Effects on the Health

i. Direct and Potential Health Effects:

1. Harmful if swallowed.

2. May cause skin sensitivity.

3. Very poisonous for aquatic organisms and algae.

ii. Direct and Potential Health Effects(Independent Source):

1. Inhalation: Cough, Nausea. Vomiting. Laboured breathing.

Shortness of breath. Weakness.

2. Skin: May be absorbed! Redness. Pain Skin burns. (Further see

Inhalation).

3. Eyes: Redness. Pain. Blurred vision.

4. Ingestion: Cough. Nausea. Vomiting. Laboured breathing.

Shortness of breath. Weakness.

14. Melody Duo 69 WG by Bayer CropScience

a. Label Requirements

i. Label:

ii. Precautions and Usage:

1. Do not inhale dust or spraymist.

2. Wash contaminated clothing daily.

3. Wash with soap and water after use.

4. Do not eat, drink or smoke during application before washing

hands and face.

5. Prevent contamination of food, feed, drinking water and eating

utensils.

iii. Re-entry, Aerial Treatment, and Drift:

1. Prevent spray drift towards and contamination of water

supplies, rivers, dams and other crops not being treated.

2. Aerial Application: Notify all inhabitants of the immediate area

to be sprayed and issue the necessary warnings. Do not spray

over or allow drift to contaminate adjacent areas or water.

Please refer to the SANS Code of Practice for the aerial

application of agricultural chemicals.

3. Re-entry: Do not enter treated area until spray deposit has dried

unless wearing protective clothing.

b. Hazards and other Effects on the Health

i. Direct and Potential Effects on Health

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1. No particular hazards known.

15. Milraz 4

a. Label Requirements

b. Hazards and other Effects on the Health

16. Prospur 500 EC by Bayer CropScience

a. Label Requirements

i. Label:

ii. Precautions and General Usage:

1. Do not inhale fumes or spraymist.

2. Wear rubber gloves and boots and a face shield when preparing

spray mixture and rubber gloves and face shield when spraying.

3. Wash contaminated clothing daily.

4. Wash with soap and water after use.

5. Prevent contamination of food, feed, drinking water and eating

utensils.

iii. Aerial, Re-entry, and Drift:

1. Re-entry: Do not enter treated area within 1 day after treatment

unless wearing protective clothing.

2. Aerial Application: Notify all inhabitants of the immediate area

to be sprayed and issue the necessary warnings. Do not spray

over or allow drift to contaminate adjacent areas or water.

3. Avoid drift of spraymist to other crops, grazing, rivers, dams

and areas that will not be treated.

b. Hazards and other Effects on the Health

i. Direct and Potential Health Effects:

1. Poisonous when swallowed. Toxic to fish and wild life.

2. Prosper 500 EC is irritating to the eyes, skin and mucous

membranes.

3. Harmful by inhalation, in contact with skin and if swallowed.

Irritating to skin. Risk of serious damage to eyes. Very toxic to

aquatic organisms, may cause long-term adverse effect in the

aquatic environment

4. Health Effects on Skin: Irritant

5. Health Effects on Ingestion: Harmful if Swallowed

6. Effects on Eyes: Damaging

17. Round-up by Monsanto Europe S.A.

a. Label Requirements

i. Precautions and General Usage:

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1. Engineering controls - Have eye wash facilities immediately

available at locations where eye contact can occur.

2. Eye protection - Wear chemical goggles.

3. Skin protection - If repeated or prolonged contact: Wear

chemical resistant gloves.

4. Respiratory protection - No special requirement when used as

recommended

5. When recommended, consult manufacturer of personal

protective equipment for the appropriate type of equipment for

a given application.

b. Hazards and other Effects on the Health

i. Potential Heath Effects:

1. Likely routes of exposure - Skin contact, eye contact

2. Eye contact, short term - Risk of serious damage to eyes.

3. Skin contact, short term - Not expected to produce significant

adverse effects when recommended use instructions are

followed.

4. Inhalation, short term - Not expected to produce significant

adverse effects when recommended use instructions are

followed.

ii. Experience with Human Exposure:

1. Ingestion, excessive, intentional misuse:

a. Respiratory effects: pneumonitis (aspiration)

b. Gastro-intestinal effects: nausea/vomiting, diarrhea,

abdominal pain, bloody vomiting (haematemesis)

c. Cardiovascular effects: abnormal heart rhythm (cardiac

dysrhythmia), decreased heart output (myocardial

depression)

2. General/systemic effects: disturbances of fluid and electrolyte

regulation, abnormally decreased blood volume

(hypovolaemia), elevated serum amylase, fluid loss

(haemoconcentration), no cholinesterase inhibition.

3. Laboratory effects - blood chemistry: elevated serum

transaminases, mild acidosis.

iii. Eye contact, short term, epidemiological:

1. Note: No cases of irreversible eye effects could be attributed to

glyphosate formulations in an extensive epidemiological survey

of reported accidental eye contact with these formulations.

iv. Direct and Potential Health Effects of Active Ingredient

Isopropylamine (Independent Source)

1. Irritation of skin, eyes and respiratory tract.

2. Inhalation may cause burning sensation in nasopharynx and

chest, coughing, and/or dizziness.

3. Headache, vomiting, diarrhea.

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4. Confusion, bizarre or aggressive behavior.

5. Kidney failure, increased heart rate.

6. Metabolic acidosis resulting in peculiar odor on breath.

18. Rubigan by Klub M5 CC

a. Label Requirements

b. Hazards and other Effects on the Health

19. Roval Aqua 4

a. Label Requirements

i. Precautions and General Usage

1. No not inhale spray mist.

2. Wear rubber gloves, rubber boots and face shield when

preparing mixture, and rubber gloves when applying.

3. Wash contaminated clothing after use.

4. Wash any contamination off skin and eyes immediately.

5. Prevent contamination of food, feeds, drinking water and eating

utensils.

ii. Drift

1. Avoid spray drift onto other crops, grazing, rivers, dams and

areas not intended for treatment.

2.

b. Hazards and other Effects on the Health

i. Direct and Potential Health Effects:

1. Poisonous when swallowed or inhaled.

2. May cause severe irritation with corneal injury, resulting in

permanent vision impairment or blindness.

3. May cause skin irritation with short single exposures and

severe skin irritation with prolonged or repeated exposure.

4. Excess inhalation may cause irritation to upper respiratory tract

(nose and throat) and lungs.

20. Storby WG by BASF

a. Label Requirements

i. Label:

ii. Precautions and General Usage:

1. Avoid prolonged contact with skin and protect eyes.

2. Do not inhale spray mist or dust.

3. Wash with soap and water after handling of product.

4. Do not eat, drink or smoke whilst mixing and applying or

before washing hands and face.

5. Destroy empty containers and never use for any other purpose.

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6. Prevent contamination of food, feed, drinking water and eating

utensils.

iii. Drift

1. Prevent spray drift onto other crops, grazing, rivers and dams.

b. Hazards and other Effects on the Health

i. Direct and Potential Health Effects:

1. Limited evidence of a carcinogenic effect.

2. Very toxic to aquatic organisms, may cause long-term adverse

effects in the aquatic environment.

21. Teldor by Bayer CropScience

a. Label Requirements

i. Label

ii. Precautions and General Usage

1. Do not inhale fumes or spraymist.

2. Wash contaminated clothing daily.

3. Wash with soap and water after use.

4. Clean applicator after use, dispose of wash water where it will

not contaminate crops, grazing, rivers and dams.

5. Prevent contamination of food, feeds, drinking water and eating

utensils.

iii. Re-entry, Drift

1. Re-entry: Do not enter treated area until spray deposit has dried

unless wearing protective clothing.

2. Avoid drift of spray on to other crops, grazing, rivers, dams and

areas not under treatment.

b. Hazards and other Effects on the Health

i. Direct and Potential Health Effects:

1. Harmful when swallowed.

22. Thioflo SC by Bayer CropScience

a. Label Requirements

i. Label

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ii. Precautions and General Usage

1. Do not inhale fumes or spray mist.

2. Wear protective clothing (overall, boots, rubber gloves,

respirator and face shield) when handling or applying the

product. Wash contaminated clothing daily.

3. Wash with soap and cold water immediately after accidental

skin contact.

4. Do not eat, drink or smoke whilst mixing or applying or before

washing hands and face and changing clothes.

5. Prevent contamination of food, eating utensils, feed and

drinking water.

6. Clean applicator/aircraft thoroughly after use and do not pollute

the environment with wash water.

7. Do not calibrate aircraft or clear hopper over grazing, crops not

under treatment or water sources.

iii. Protective Measures and Equipment:

1. Do not inhale aerosols

2. Hygiene measures

a. Do not eat, drink or smoke during work time.

b. Remove soiled clothing immediately.

c. Clean hands and face at work intervals and after work.

3. Hand protection: Chemical resistant gloves

4. Eye protection: Safety glasses

5. Skin protection: Protective clothing

iv. Re-entry, Aerial Application, and Drift

1. Re-entry - Avoid skin contact with treated crops in glasshouses

or tunnels for a minimum of 24 hours following application by

wearing protective rubber gloves, long-sleeved shirts, long

trousers and rubber boots. Do not enter treated area within two

days after treatment unless wearing protective clothing. In case

of poisoning - CALL A DOCTOR AND MAKE THIS LABEL

AVAILABLE TO HIM.

2. Aerial application - notify all inhabitants of the immediate area

to be sprayed and issue the necessary warnings.

3. Do not spray over or allow drift to contaminate adjacent areas

or water. Prevent spray drift onto other crops, grazing, rivers,

dams or other areas not under treatment.

b. Hazards and other Effects on the Health

i. Direct Health Effects

1. Poisonous when swallowed, inhaled or by skin contact.

2. Symptoms:

a. Symptoms of Poisoning:

i. Headaches, vertigo, nausea, possibly coupled

with diarrhoea, anaesthesia of the tongue,

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cerebral and cervical tremor and tremor of the

extremeties, tonic and clonic cramps, perhaps

with unconsciousness.

b. Information to the Physician:

i. Administer phenobarbital (e.g., "Luminal") to

control convulsions. Loss of water and salt

should be corrected by the infusion of IN

physiological saline solution. The use of

adrenaline and foods or purgatives containing fat

or oil should be avoided. Pay special attention to

respiratory failure and cardio-vascular collapse.

23. Thiovit Jet by Syngenta

a. Label Requirements

i. Label:

ii. Precautions and General Usage:

1. Do not inhale dust or spray mist.

2. Wear rubber gloves and face mask when handling granules.

3. Wash with soap and water after use.

4. Wash contaminated clothing after use.

5. Do not eat, drink or smoke while mixing or applying the

product or before washing hands and face.

6. Prevent contamination of food, feed, drinking water and eating

7. utensils.

iii. Re-entry and Drift:

1. Re-entry: Do not enter treated areas until spray deposit has

dried unless wearing protective clothing.

2. Avoid drift of spray onto other crops, grazing, rivers, dams,

boreholes and areas not under treatment.

b. Hazards and other Effects on the Health

i. Direct and Potential Health Effects (Independent Source):

1. Symptoms by Route of Exposure:

a. Inhalation: Burning sensation. Cough. Sore throat.

b. Skin: Redness.

c. Eyes: Redness. Pain. Blurred vision.

d. Ingestion: Burning sensation. Diarrhoea.

24. Tracer 480 SC by DowAgroSciences

a. Label Requirements

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i. Label:

ii. Precautions and General Usage:

1. Avoid inhalation of spray mist.

2. Wash with soap and water after use or accidental skin contact.

3. Wear gloves and face shield when handling.

4. Avoid contamination of skin and eyes. In case of accidental

contact with eyes, wash with running water for at least 15

minutes. Get medical attention if irritation persists.

5. Do not eat, drink or smoke whilst mixing or applying.

6. Wash hands and face before eating, drinking, smoking or using

the toilet

7. Prevent contamination of food, feedstuffs, drinking water and

eating utensils by handling, storage or diposal.

iii. Re-entry and Drift:

1. Avoid spray drift onto adjacent crops, grazing, rivers and dams.

2. Re-entry interval: Do not enter treated area until spray deposit

has dried unless wearing protective clothing.

b. Hazards and other Effects on the Health

i. Potential Health Effects:

1. May cause slight eye irritation