sustaining another decade of innovation...
TRANSCRIPT
AVS00_00
SUSTAINING ANOTHER DECADE OF INNOVATION INEQUIPMENT AND PROCESS DESIGN: NEEDS AND
CHALLENGES*
Mark J. KushnerUniversity of Illinois
Department of Electrical and Computer EngineeringUrbana, IL 61801
http://uigelz.ece.uiuc.edu →→ "Presentations" link
October 2000
* Work supported by NSF, SRC, DARPA/AFOSR
AGENDA
AVS00_AGENDA
University of Illinois Optical and Discharge Physics
• Reflection on 10 years past...
• ITRS Requirements
• Knowlegebase Generation
• The "challenge": Smart, Aware and Proactive Tools
• Examples of SAP Tools
• New systems and materials
• Concluding Remarks
37th AVS INTERNATIONAL SYMPOSIUMOctober 1990, Toronto, Canada
AVS00_30
University of Illinois Optical and Discharge Physics
Topics from papers appearing in Proceedings of 37th AVS InternationalSymposium
Plasma Sources:
Helicon 1 ECR 10RIE 8 Magnetron 1ICP 0 Ion Beam 1
Materials:
Polymer 2 SiGe 1Si3N4 1 p-Si/c-Si 3SiO2 2 GaAs 1
JVST A 9, 722 (1991)
AVS00_31
University of Illinois Optical and Discharge Physics
• Cl2 plasma
• Measurements of ion energies arriving at the substrate correlate with peakplasma potential, indicating collisionless acceleration through (pre)sheath.
AVS00_32
University of Illinois Optical and Discharge Physics
• Laser lightscattering frompatterned wafersis spatiallyanayzed as asensor forfeature shape.
Quantification of surface film formation effects in fluorocarbon plasmaetching of polysilicon
David C. Gray and Herbert H. SawinDepartment of Chemical Engineering, MIT, Cambridge Massachusetts 02139
Jeffrey W. ButterbaughIBM, General Technology Division, Essex Junction, Vermont 05452 JVST A 9, 779 (1991)
AVS00_33
University of Illinois Optical and Discharge Physics
• Radical/ion beams synthesize the plasma tool environment and show adecrease in p-Si etching with CF2/Ar+ ratio due to overlying polymerization.
CHALLENGES FOR < 100 nm BEYOND 2005
AVS00_01
University of Illinois Optical and Discharge Physics
• ITRS cites many "no known solutions" for interconnect to meet the 55 nmtechnology node by 2011.
CHALLENGES FOR < 100 nm BEYOND 2005
AVS00_01
University of Illinois Optical and Discharge Physics
• The challenges cited to meet the ITRS goals focus on new materials andstructures.
Int. Tech. Roadmap Semi.: Interconnect 1999
CHALLENGES FOR < 100 nm BEYOND 2005
AVS00_01
University of Illinois Optical and Discharge Physics
• Potential solutions foretch emphasize newmaterials, high plasmadensity sytems andcleans.
MARKETS AND APPLICATIONS
AVS00_29
University of Illinois Optical and Discharge Physics
• With the advent of high speed networks and parallel computing, pastspecialized markets for logic have collapsed to a single line.
• As processing becomes more critical (expensive) at <100 nm nodes andapplications return to centralized computing, the market may bifurcate.
HIGH-PERFORMANCE (MAINFRAMES)
MID-PERFORMANCE (MINI'S)
LOW-PERFORMANCE (MICRO'S)
COMMODITY (CONTROLLERS)
COMPOUND MAT'LS (LASERS)
EXTREME-PERFORMANCE (MAINFRAMES,
SERVERS)
HIGH-PERFORMANCE (DESKTOP)
COMPOUND MAT'LS (LASERS,
COMMUNICATION)
MEMS (SENSORS,
ACTUATORS)
SYSTEM ON CHIP, SMART WAFERS, SELF ASSEMBLY
THEN NOW TO COME
• MEMS, compoundmaterials (e.g.,Si/Ge) andorganics will join"conventional"silicon insensors, HBTs,actuators, SOCand opticalinterconnect.
"GENERIC" PLASMA PROCESSING REACTOR
AVS00_08
University of Illinois Optical and Discharge Physics
• For purposes of illustration during this talk, a "generic" plasmaprocessing reactor will be used to demonstrate principles.
PUMP PORT
DOME
GAS INJECTORS
BULK PLASMA
WAFER
30 30 0 RADIUS (cm)
HE
IGH
T (c
m)
0
26
sCOILS
s
rf BIASED SUBSTRATE
SOLENOID
POWER SUPPLY
POWER SUPPLY
INNOVATION REQUIRES MASTERY OF THE BASICS
AVS00_09
University of Illinois Optical and Discharge Physics
PUMP PORT
GAS INJECTORS (fluid dynamics)
BULK PLASMA (plasma hydrodynamics, kinetics,
chemistry, electrostatics,electromagnetics)
WAFER
30 30 0 RADIUS (cm)
HE
IGH
T (
cm)
0
26
sCOILS (electro-
magnetics)
s
rf BIASED SUBSTRATE
SOLENOID (magnetostatics)
DOME (suface chemistry, sputter physics)
POWER SUPPLY (circuitry)
POWER SUPPLY (circuitry)
POLYMER (surface chemistry, sputter physics)
M+ e
Secondary emission (beam physics)
WAFER
E-FIELD (sheath physics)
PROFILE EVOLUTION (surface chemistry,
sputter physics, electrostatics)
THE PROBLEM....
AVS00_38
University of Illinois Optical and Discharge Physics
• Uniformity and control of reactants becomes increasingly more difficult aswafer sizes increase and process chemistries become more complex.
• For example, non-uniformities in ion flux (sheath edge plasma density)across a wafer produce a change in sheath thickness and acommensurate change in ion energy-angular distributions.
RADIUS (cm)
SH
EA
TH
TH
ICK
NE
SS (
µ m)
SHEATHFLUX
ION
FLU
X (
1016
/cm
2 -s)
RADIUS (cm)
ION DENSITY
-12 120 -12 120ANGLE (deg)
EDGECENTER
ENERGY (eV)
0
100
200
THE PROBLEM....
AVS00_38
University of Illinois Optical and Discharge Physics
•• The end result is a loss in CD control (center-to-edge) which, tollerable atlarger feature sizes is intolerable at smaller feature sizes.
50 nm
0.00
0.05
0.10
0.15
0.20
0.25
0.30
50 100 150 200 250 300FEATURE SIZE (nm)
EDGE
CENTERF
RA
CT
ION
AL
LOS
S IN
CD
SMART, AWARE AND PROACTIVE TOOLS
AVS00_10
University of Illinois Optical and Discharge Physics
• In spite of tremendous progress in the design of plasma tools, most suchtools are passive or, at best, reactive to their own environment.
• The case is made that continuing innovation requires Smart, Aware andProactive (SAP) tools.
• SMART: mentally alert, knowledgeable, shrewd
• AWARE: having or showing realization, perception or knowledge
• PROACTIVE: involving modification by a factor which proceeds that which is being modified.
Webster's New Collegiate Dictionary
• A SAP tool is one that:
• Senses its internal reactive environment• Has access to a knowledge base which enables it to interpret these
observations• Changes its environment to meet specifications.
THE CASE FOR SAP TOOLS
AVS00_11
University of Illinois Optical and Discharge Physics
• The move towards foundries by even major chip producers implies that alarger variety of processes will be performed in a given tool over itslifetime; and that those processes will change more frequently.
• Tools must be "reconfigurable" rapidly.• Tool memory effects may be unavoidable and unpredictable.
• As new materials are developed (e.g., low-k, high-k) having more stringentCDs, recipes will likely become more complex.
• What is optimum for one mixture is not optimum for another.• More demanding requirements to widen process windows.
• As wafer sizes and die complexity increase, the value/wafer enablesexpenditures which now are discounted.
DOES The KNOWLEDGE BASE EXIST FOR SAP TOOLS(OR CAN IT BE GENERATED?)
AVS00_12
University of Illinois Optical and Discharge Physics
• Realizing SAP tools requires an intimate knowledge of the cause-and-effect relationship.
"If I observe A and do B, then C will result."
• This cause-and-effect knowledge base can be generated by a range ofmethods ranging from empirical to a priori.
• Empirical: Conventional DOE• A priori: Predict from first principles• Semi-Empirical/A priori: First principles bounded or normalized
by empiricism.
• At present the knowledge base does not exist for SAP tools, largelybecause the observables A are too far removed from the outcomes C.
• The methodology and technologies to realize SAP tools do, however, existor can be developed.
GENERATION, APPLICATION AND EXTENSION OFKNOWLEDGE BASE: FEATURE EVOLUTION (D. B. Graves)
AVS00_02
University of Illinois Optical and Discharge Physics
• Advancing the knowledge base in feature evolution has required acombination of apriori, semi-empirical and empirical calculations andmeasurements, supported by validating experiments.
• The group/collaborators of D. B. Graves demonstrate this methodology.
• Sticking coefficients on evolvingsurfaces (CF3
+ on Si)• Reflection coefficients of ions
from surfaces (Cl2+ on Si)
GENERATION, APPLICATION AND EXTENSION OFKNOWLEDGE BASE: FEATURE EVOLUTION (D. B. Graves)
AVS00_02
University of Illinois Optical and Discharge Physics
• Equipment Scale Modeling (IonEnergy Distributions)
• Feature Scale Modeling (Sietching by Cl2/HBr)
GENERATION, APPLICATION AND EXTENSION OFKNOWLEDGE BASE: FEATURE EVOLUTION (D. B. Graves)
AVS00_02
University of Illinois Optical and Discharge Physics
• Validating data
• C.F. Abrams and D. B. Graves,JAP 86, 5938 (1999)
• M. Voyoda et al, JVSTB 18, 820(2000)
• B. Helmer and D. B. Graves,JVSTA 17, 2759 (1999)
ABC PRODUCT BUSINESS GROUPETCH PRODUCT BUSINESS GROUP
2
top grid (dc bias)
discriminator
collector
ion current I
repulsivevoltage V
+
0.1”
Examples of Plasma Diagnostic Tools Used inDevelopment of Etch Equipment
n Instrumented Wafers– Ion Current Flux– DC Bias– Ion Energy
Ion currentcollection disks
Ion currentcollection disks
WaferWafer
Ref: Peter K. Loewenhardt
ABC PRODUCT BUSINESS GROUPETCH PRODUCT BUSINESS GROUP
8
Position (in)
-4 -3 -2 -1 0 1 2 3 4
ICF
(m
A/c
m2 )
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Reference: ICF:European Semiconductor/Damage:P2ID
ICF ICF DamageDamage
2000W(4.6%)
1500W(3.8%)
1000W(3.4%)
500W(4.7%)
Cum
ulat
ive
Pro
babi
lity
1e-12 1e-11 1e-10
Leakage Current (Ig)
99
90
70
50
30
10
1
1800Watts
1000Watts
99
90
70
50
30
10
11e-12 1e-11 1e-10
Leakage Current (Ig)
Cum
ulat
ive
Pro
babi
lity
Source Power Window
Ref: Peter K. Loewenhardt
q A new diagnostic for detectingspecies and films formed on thereactor walls.
q What is formed on reactorwalls during etching? How doesit affect the plasma?
q Applications
Ø Detecting Fluorocarbonfilms on the walls
Ø SiOxCly films in Si etchingØ PECVD
Ø Monitoring reactor wallcleaning steps.
Ø Ref: Eray Aydil, UCSB,[email protected]
Multiple Total Internal Reflection Fourier Transform InfraredMultiple Total Internal Reflection Fourier Transform Infrared(MTIR-FTIR) surface probe(MTIR-FTIR) surface probe
From FTIRSpectrometer
To HgCdTe Detector
Chamber Wall
Internal Reflection Element
Plasma
In Situ Attenuated Total Reflection Fourier TransformInfrared (ATR-FTIR) Spectroscopy
RFQuartzWindow
Matching Network
HgCdTeDetector
Data AcquisitionGas Injection Ring
FTIR Spectrometer
KBr Windows
IR
ICP Source
RF bias
From IR Spectrometer To Detector
Ø Ref: Eray Aydil, UCSB,[email protected]
q During Cl2/O2 etching of Si, SiOxCly film deposits on the reactor walls.
q SiOxCly film must be etched from the reactor walls using F-containing plasma inbetween every wafer in a step referred to as Waferless Auto Clean (WAC).
q MTIR-FTIR probe help develop successful WAC in Lam’s TCP reactor for Si STIetching and improved productivity.
Incomplete Cleaning Step Optimized Cleaning Step
Application of MTIR-FTIR surface probe: reactor wall cleaningApplication of MTIR-FTIR surface probe: reactor wall cleaning
Ø Ref: Eray Aydil, UCSB,[email protected]
600 800 1000 1200 1400
0.0
0.2
0.4
0.6
0.8
1.0
1.2
After Cl 2/O2
etching of Si
Abs
orba
nce
Wavenumbers (cm-1)
After SF6/O2
plasma cleaning
600 800 1000 1200 1400
After Cl2/O2
etching of Si
Abs
orba
nce
Wavenumbers (cm -1)
After SF6/O2
plasma cleaning
0.0
0.2
0.4
0.6
0.8
MEMS (MICRO-ELECTRO-MECHANICAL SYSTEMS)MICROSENSORS FOR SMART WAFERS
AVS00_05
University of Illinois Optical and Discharge Physics
• The development of MEMS technologies provide the opportunity toimplement intra-tool sensors and, ultimately, on-wafer sensors resulting inthe wafer analogue of the smart-tool: the Smart Wafer
• MEMS sensors enable measurements of, for example, reactive fluxes to bemade at or near the wafer surface.
• Provides data directly relevant to process control
• Eliminates need to disengage complex relationships betweenmeasurements of, for example, OES and desired quantities such asflux.
• Smart Wafers may have unique sensors for individual processes, therebyeliminating the need for over-functionality to be built into the tool.
SUB-MICRON RETARDING FIELD ENERGY ANALYZER(M. BLAIN, Sandia National Labs)
AVS00_04
University of Illinois Optical and Discharge Physics
• Leveraging MEMS technologies, Blain et al have developed sub-micron ionenergy anlyzers which provide the means for non-perturbing, in-situ, on-wafer measurements.
• Micro-Ion Energy Analyzer fabricated using MEMS technologies
SUB-MICRON RETARDING FIELD ENERGY ANALYZER(M. BLAIN, Sandia National Labs)
AVS00_04
University of Illinois Optical and Discharge Physics
0 10 20 30 40 50
0.0
4.0x10-8
8.0x10-8
1.2x10-7
1.6x10-7100 sccm Ar
10 mT200 Ws
Energy (eV)
f(v)
Bias Power: 0 Wb
25 Wb
50 Wb
• Ion energydistributionsobtained on rf-biased substrate inICP-GECRC
• With multiplesensors acrosswafer, real-timeassessments ofquality anduniformity of ionfluxes are possible.
VIRTUAL PLASMA EQUIPMENT MODEL (VPEM)
MURI9920
UNIVERSITY OF ILLINOISOPTICAL AND DISCHARGE PHYSICS
l The Virtual Plasma Equipment Model (VPEM) is a “shell” which supplies sensors, controllers and actuators to the HPEM.
HPEM
CONTROLLERMODULE
INITIAL AND OPERATING CONDITIONS
SENSOR POINTS AND ACTUATORS
SENSORMODULE
ACTUATORMODULE
SENSOROPERATING
POINTS
“DISTURBANCE”
PID CONTROLLER
AVS9908
University of Illinois Optical and Discharge Physics
•• A Proportional-Integral-Differential (PID) controller has been implementedin the VPEM.
• Proportional:
( ) SignalErrorSSSSS
gAA o =−=∆∆
⋅⋅=∆ ,
• PID
odi
Adt
SSdt
SS
SS
gA +
∫
∆
+∆
+∆
⋅= ττ1
where:
oSSS ,,∆ Error, current value and setpoint of sensor
g Gain of Controller
oAAA ,,∆ Change, current value and setpoint of actuator
id ττ , Differential and integraltime constants
PROCESS VARYING WALL CONDITIONS
AVS00_13
University of Illinois Optical and Discharge Physics
• During a process recipe, deposition on reactor side walls (or changes inprocess conditions) results in changes in reactive-sticking coefficients,producing both intra-run and run-to-run variations in performance.
• Chamber cleans are, in large part, necessary to "reset" the reactor to"initial conditions".
• Particle formation concerns aside, the difficulty in using real-time-controlto compensate for evolving wall conditions is the uncertainty in correlatingobservables (e.g., OES, actinometry) with fluxes to wafer surface.
• SATs and SAWs eliminate this uncertainty, by directly measuring processrelevant parameters.
• Example: Cl →→ Cl2 sticking coefficient increasing during process.
Cl →→ Cl2 STICKING COEFFICIENT
AVS00_14
University of Illinois Optical and Discharge Physics
• During a process, the sticking coefficient on chamber walls increases from0.01 to 0.4 due to deposition of etch products.
STICKING COEF. INCREASES
PERTURBED
UNPERTURBED
UNPERTURBED
Cl DENSITY
Cl2 DENSITY
5 1017
6 1017
7 1017
8 1017
9 1017
0.0
0.2
0.4
0.6
0.8
1.0
40 60 80 100 120ITERATION
UNPERTURBED
PERTURBED
Cl > Cl2STICKING
COEF.
Cl S
TIC
KIN
G C
OE
FF
ICIE
NT
ION
FLU
EN
CE
(1/
s)
Cl, Cl2 Densites with/without Perturbation Ion Fluence, Sticking Coef.
• Cl densities decrease, Cl2 densities increases, resulting in a decrease inthe ion flux to the on-wafer sensor.
• Ar/Cl2 = 70/30, 20 mTorr, 500 W, 200 sccm
Cl →→ Cl2 STICKING COEFFICIENT: ION FLUENCE-POWER RTC
AVS00_15
University of Illinois Optical and Discharge Physics
• A simple proportional controller with a wafer-level ion flux sensor is used.The desired ion fluence, perturbed by the change in Cl sticking coefficient,is largely recouped.
5 1017
6 1017
7 1017
8 1017
9 1017
450
500
550
600
650
40 60 80 100 120ITERATION
ION
FLU
EN
CE
(1/
s)
ICP
PO
WE
R
POWER
PERTURBED
CONTROLLEDTARGET
START RTC
• Ar/Cl2 = 70/30, 20 mTorr, 500 W, 200 sccm
CHOICE OF SENSOR FOR TRANSIENTS: ACTINOMETRY
GECA9909
University of Illinois Optical and Discharge Physics
•• The proper choice of sensor is critical to controlling through transients.
• Sensors which are adequate for perturbations to the steady state may failduring a transient.
• Example: Impulsively change the coefficient for Cl →→ Cl2 on walls whilekeeping the input flow rate and pressure constant.
Cl
Cl,
Cl 2
DE
NS
ITY
(10
13 c
m-3
)
Cl2 Ar
Ar
(101
2 cm
-3)
Startup Transient
Quasi-steadystate
[ Cl WALL Cl2 ] x 4• Sensor:
Actinometry ofCl*: S = [Cl*]/[Ar**]
• The decrease inoutflow resultingfrom morerecombinationincreases the Ardensity.
• 10 mTorr, 120sccm, Cl2/Ar =95/5, 500 W
CHOICE OF SENSOR FOR TRANSIENTS: ACTINOMETRY
GECA9909
University of Illinois Optical and Discharge Physics
• As a result of the absolute increase in Ar density (and Ar* signal) resultingfrom the change in mole fractions, the actinometry signal decreasesrelative to the actual Cl density.
Cl DENSITY
ACTINOMETRY
Cl D
EN
SIT
Y (
1013
cm
-3)
AC
TIN
OM
ET
RY
[Cl*
/Ar*
*] • Transients whichchange the molefraction of thereference willcomplicate use ofactinometry.
SMART WAFER: ION FLUX AND UNIFORMITY
AVS00_16
University of Illinois Optical and Discharge Physics
• Intra-process seasoning of walls changing reactive sticking coefficientsproduces changes in both magnitudes and uniformity of fluxes.
• Smart wafer techniques will be applied to control against changes in ionflux and uniformity following a change in sticking coefficient for Cl →→ Cl2.
TIME (µs) [accelerated]
Cl DENSITY
Cl2 DENSITY
PERTURBED
Cl > Cl2 : 0.05 > 0.4
ION FLUX UNIFORMITY ION FLUX
MAGNITUDE
ICP POWER (MAGNITUDE)
MAGNETIC FIELD (UNIFORMITY)
• Ar/Cl2 = 50/50, 20 mTorr, 500 W, 200 sccm
ION SOURCE AND FLUXES
AVS00_17
University of Illinois Optical and Discharge Physics
• Due to the increase in Cl2 resulting from the increase in Cl →→ Cl2 on wallsion sources are confined closer to the coils.
• The ion flux decreases and becomes more edge high.
UNPERTURBED (LOW Cl2) PERTURBED (HIGH Cl2)ION SOURCE FLUX VECTORS
• Ar/Cl2 = 50/50, 20 mTorr, 500 W, 200 sccm
ION FLUENCE MAGNITUDE AND UNIFORMITY
AVS00_18
University of Illinois Optical and Discharge Physics
• The shift in ion source to larger radius increases the ion flux at largeradius thereby making uniformity more edge-high.
• Larger rates of attachment and higher wall losses decrease the ion flux.
• These trends will be corrected using ICP power and B-field as actuators.
0 100
1 1017
2 1017
3 1017
4 1017
5 1017
6 1017
7 1017
0 500 1000 1500 2000 2500
[Points are sensor readings]
UNPERTURBED
PERTURBED
TIME (µs) [accelerated]
-0.20
-0.15
-0.10
-0.05
0.00
0 500 1000 1500 2000 2500
[Points are sensor readings]
UNPERTURBED
PERTURBED
UNIFORM
TIME (µs) [accelerated]
EDGE-HIGH
CENTER-HIGH
ION FLUENCE (1/s) UNIFORMITY
• Ar/Cl2 = 50/50, 20 mTorr, 500 W, 200 sccm
MAGNETIC FIELD AS AN ACTUATOR
AVS00_20
University of Illinois Optical and Discharge Physics
• By applying moderate solenoidalmagnetic fields (a few - 10s G), radialand axial components of the inductivelycoupled field are generated.
• This results in shifts in the powerdeposition, and can be used as anactuator for ion flux uniformity.
• Ar/Cl2 = 70/30, 20 mTorr, 500 W, 200 sccm
0 GAUSS POWER DEPOSITION
5 GAUSS
5 GAUSS POWER DEPOSITION
CONTROLLED ION FLUX MAGNITUDE AND UNIFORMITY
AVS00_19
University of Illinois Optical and Discharge Physics
• Using proportional controllers with moderately high gain (0.5), uniformityand ion flux are restored to their target values.
• The use of on-wafer sensors insures target values directly correlate withdesired reactant properties.
0 500 1000 1500 2000 2500
[Points are sensor readings]
CONTROLLED
PERTURBED
TARGET
TIME (µs) [accelerated]
450
500
550
600
650
700
750
800
POWER
PO
WE
R (
W)
0
2
3
1
4
5
6
-0.20
-0.15
-0.10
-0.05
0.00
0 500 1000 1500 2000 2500
CONTROLLED
PERTURBED
UNIFORMEDGE-HIGH
CENTER-HIGH
TIME (µs) [accelerated]
0
4
8
12
[Points are sensorreadings]
B-FIELD
B-F
IELD
(G
auss
)
ION FLUENCE (1017/s) UNIFORMITY
• Ar/Cl2 = 50/50, 20 mTorr, 500 W, 200 sccm
TAPERING AND BOWING OF PROFILES
AVS00_23
University of Illinois Optical and Discharge Physics
• Feature profiles in fluorocarbon plasma etching of SiO2 often have bowedor tapered profiles.
SiO2
PR
BOWED TAPERED
C Cui (AMAT)
• Control of profile CD (and selectivity) ultimatelydepends on control of not only uniformity andmagnitude of reactants, but also flux composition.
• For example, bowing and tapering have beencorrelated with the ratio of polymerizing radicalfluxes to ion fluxes.
• On wafer measurements of species resolved,neutral and ion resolved fluxes are beyond the stateof the art.
• However, innovating such sensors may be the keyto maintaining CDs to 0.08 nm and beyond.
CORRELATION OF PROFILE WITH REACTANT FLUX RATIOS
AVS00_24
University of Illinois Optical and Discharge Physics
• Results from integrated plasma equipment and feature profile modelinghave shown that SiO2 feature profiles can be correlated with the ratio ofthe passivating neutral flux to the ion flux.
8.4 10.2 12
Photoresist
SiO2
Φn/Φion = 6
Wb
/ Wt
Dep
th (
µm)
Wb / Wt
Depth
Φn / Φion
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0.0
0.5
1.0
1.5
2.0
2.5
3.0
7 8 9 10 11 12
ΦΦnΦΦ/ion : Passivating Neutral/Ion flux Wb/Wt: Bottom Width / Top Width
• Quantitative knowledge of these trends, coupled with measurement ofcomposition of reactive flux, provide the means ot control profile CD.
SMART WAFER: ION FLUX AND ION/NEUTRAL RATIO
AVS00_25
University of Illinois Optical and Discharge Physics
• Intra-process seasoning of walls changing reactive sticking coefficientsproduces changes in both magnitudes and ratio of fluxes.
• Smart wafer techniques will be used to control changes in ion flux andneutral/ion flux ratio following a change in sticking coefficient for CF2.
NEUTRAL POLYMERIZING FLUX
TIME (µs) [accelerated]
PO
LYM
ER
IZIN
G /
ION
FLU
X
POLYMER / ION FLUX
INCREASE IN CF2 STICKING COEF.
0
5
10
15
20
25
0 200 400 600 800 1000 1200
PO
LYM
ER
IZIN
G F
LUX
(10
17/c
m2 -
s)
0
0.5
1.0
1.5
2.0
2.5
PERTURBED
• An increase in CF2 stickingcoefficient on wallsdecreases thepolymerizing flux (mostlyCF2 and CF).
• The ion flux remains nearlyconstant, producing alarge decrease in theneutral/ion flux ratio.
• Ar/C2F6= 60/40, 15 mTorr, 500 W, 200 sccm
Ar/C2F6 ION FLUX AND NEUTRAL/ION RATIO vs PRESSURE
AVS00_26
University of Illinois Optical and Discharge Physics
• To determine process variables to control, computational (or experimental)DOEs are performed.
• Power (to control ion flux) and pressure (to control ineutral/ion flux ratio)are chosen.
ION FLUX
NEUTRAL FLUX
RATIO
FLU
X (
1016
/cm
2 -s)
NE
UT
RA
L / I
ON
FLU
X
0.0
0.5
1.0
1.5
2.0
2.5
0
1
2
3
4
5
0 10 20 30 40PRESSURE (mTorr)
ION FLUX MAGNITUDE
ICP POWER (ION FLUX)
GAS FLOW RATE- PRESSURE (RATIO)
NEUTRAL POLYMER FLUX MAGNITUDE
• Ar/C2F6= 60/40, 500 W, 200 sccm
Ar/C2F6 NEUTRAL/ION RATIO CONTROLLED
AVS00_27
University of Illinois Optical and Discharge Physics
• Using power and pressure as actuators, the on wafer flux sensors directincreases in both values to maintain flux ratios and power constant.
TIME (µs) [accelerated]P
RE
SS
UR
E (
mT
orr)
PRESSURE
NE
UT
RA
L / I
ON
FLU
X
RATIO
PERTURBED
UNPERTURBED
CONTROLLED
CONTROL
STICKING
0
4
8
12
16
20
0
10
20
30
40
50
0 200 400 600 800 1000 1200
TARGET
• With on wafersensors, profile CDcontrol is directlycorrelated tomeasurements.
• Ar/C2F6= 60/40, 200sccm
CONFLUENCE OF MICROELECTRONICS-AND-MEMS:SYSTEMS ON-A-CHIP
AVS00_06
University of Illinois Optical and Discharge Physics
• The plasma processing community has been slow to recognize andpotential of combining microelectronics with MEMS to create systems-on-a-chip.
• The ITRS lists examples of future SOCs, and cites cost as the presentlimiting factor in developing such systems.
Int. Tech. Roadmap Semi.: System-on-Chip 1999
• Never-the-less, market forces will drive this integration, and so theknowledge base to implement it should be addressed now.
[MEMS at DARPA 3.ppt] Slide 25Microsystems Technology Office
DARPADARPA
MTOMTO
Approved for Public Release - Distribution Unlimited
MEMS Actuators for Data StorageMEMS Actuators for Data Storage
Areal density: 1-100 Gb/cm2
Transfer Rates: 0.1-10 Mb/sSize: 0.5 cm3
Power consumption: <1W
Parallel atomic force imaging with MEMS to exceed densities of conventional magnetic and optical storage
[MEMS at DARPA 3.ppt] Slide 29Microsystems Technology Office
DARPADARPA
MTOMTO
Approved for Public Release - Distribution Unlimited
Advanced Digital Receiver (ATO)Advanced Digital Receiver (ATO)Digital IF w/ Bandpass Sampling
SiGe ASIC
C6x DSP
VCSELInterconnect
High SpeedADCs
FilterTo
Modem
Filter
DSP
RF MEMS
FilterFilterRF
Input
Frequency Synthesis
A/D
COMBINING ORGANIC LEDs WITH CMOS
AVS00_34
University of Illinois Optical and Discharge Physics
• Combining organic light-emitting-diodes with CMOS provides a means forSi-based optical interconnects for inter/intra-die communication.
8 x 8 OLED with CMOS Circuitry Laser Focus, September 2000, p.38
MEMS FABRICATION BRING NEW CHALLENGES
AVS00_35
University of Illinois Optical and Discharge Physics
• Although MEMS dimensions are now large by microelectronics standards,extreme aspect ratios push the state of the art. As MEMS dimensionsshrink, these HAR features will rapidly exceed the state-of-the-art.
J. MEMS 8, 403 (1999)
Accelerometer fabricated with Deep RIE
JVST B 18, 1890 (2000)
AVS00_36
University of Illinois Optical and Discharge Physics
• Extreme HAR etching using Cl2and SF6/O2 chemistries (l) 5 hr Cl2 ICP etch with (r) 10 min
widening process
A Microfabricated Inductively CoupledPlasma Generator
Jeffrey A. Hopwood
J MEMS9, 309 (2000)
AVS00_37
University of Illinois Optical and Discharge Physics
• Innovative SAP tools may use real-time-control with sensor equippedsmart wafers to guide arrays of plasma sources fabricated using MEMStechniques.
HUMAN RESOURCES: THE SOURCE OF INNOVATION
AVS00_07
University of Illinois Optical and Discharge Physics
• Ultimately, our ability to sustain innovation in our field relies on the talentof our human resources.
• Our field is perhaps unique is that innovations are generally produced bybroadly educated scientists and engineers, as opposed to narrowlydefined specialists.
• As a result, the "yield" from science and engineering college graduates istypically not high.
• To maintain and increase our progress, we must continue to capture thebest and brightest of our college graduates.
HUMAN RESOURCES: THE SOURCE OF INNOVATION
AVS00_07
University of Illinois Optical and Discharge Physics
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• Although the totalnumber of BS andgraduate degreescontinues toincrease, thefractions inEngineering andPhysical Sciencesare decreasing.
Ref: NSF00-3100 S&E Degrees 1966-97
HUMAN RESOURCES: THE SOURCE OF INNOVATION
AVS00_07
University of Illinois Optical and Discharge Physics
• Although a single field in a given industry cannot change reverse thesetrends, the health of our field requires pro-active measures on our parts.
• Mentoring programs• University collaborations• Internships• Scholarships and Fellowships• Grammar and secondary school outreach.
• Student attitudes towards science and engineering, particularly for under-represented groups, are typically unchangeable after junior high. Outreachprograms must also target these younger prospects.
GENERATING THE KNOWLEDGEBASE
AVS00_28
University of Illinois Optical and Discharge Physics
• Generating the knowledge base required tofulfill this challenge is as large a challenge asimplementing the solutions.
• Collaborations are clearly the most viableoption to achieve these goals.
• Looking ahead 10 years, one must also reflecton how well industry wide collaborations haveserved us during the past 10 years.
• SRC, Sematech, DARPA, NSF Initiatives haveall served in this capacity with varying degreesof success.
• The emphasis on pre-competitive,collaborative research (industry-university-national lab) has, however, declined of late. Areassessment of that strategy is necessary.
FOR MORE INFORMATION
AVS00_21
University of Illinois Optical and Discharge Physics
•• Copy of today's presentation:
http://uigelz.ece.uiuc.edu →→ "Presentations" link at top of page
• PS-TuM7 [next paper], R.L. Kinder, "Electron Transport and PowerDeposition in Magnetically Enhanced Inductively Coupled Plasmas"
• PS2-ThA4, D. Zhang, "Reaction Mechanisms and SiO2 Profile Evolution inFluorocarbon Plasmas: Bowing and Tapering"
• PS1+MS-WeA7, E.A. Edelberg, "Productivity Solutions for EliminatingWithin-Wafer and Wafer-to-Wafer Variability in a Silicon Etch Processthrough Plasma and Surface Diagnostics"
• PS2-ThM8, M.J. Sowa, "Electron Temperature and Ion EnergyMeasurements with A High-resolution, Sub-micron, Retarding FieldAnalyzer"
• PS2-TuA2, H. Singh, "Comprehensive Measurements of Neutral and IonNumber Densities, Neutral Temperature, and EEDF in a CF4 ICP"