sustainable energy mod.1: fuel cells & distributed ... · effectiveness or regeneration rate...
TRANSCRIPT
A.A. 2011-2012
Sustainable Energy
Mod.1: Fuel Cells & Distributed
Generation Systems
Thermochemical Power Group (TPG) - DiMSET – University of Genoa, Italy
Dr. Ing. Mario L. Ferrari
A.A. 2011-2012
Lesson XVII
Lesson XVII: Gas Turbines
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Simple cycle (1/4)
Lesson XVII
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Simple cycle (2/4)
Lesson XVII
�Ideal Brayton cycle: efficiency
�Ideal Brayton cycle: maximum specific work
It is possible to demonstrate (first order derivative = 0) that the expression
has a maximum for:
β
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Simple cycle (3/4)
Lesson XVII
�Real Brayton cycle: efficiency (1/2)
l: limit (real fluid)
i: internal (real cycle)
r: real
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Simple cycle (4/4)
Lesson XVII
�Real Brayton cycle: efficiency (2/2)
β
η
•In the case of real cycle efficiency curve
shows a maximum value
•The compression ratio for maximum
efficiency is higher than the compression
ratio for maximum specific work
•The designer has to decide if optimising
the turbine for maximum efficiency or
maximum specific work
•Usually aeroengines (and aeroderivative
turbines) are optimized for ηmax typically
with high β (e.g. 30) and heavy-duty
turbines for Wmax with lower β values
(e.g. 17).
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Recuperated Cycle (1/2)
Lesson XVII
Effectiveness or regeneration rate
•Efficiency increase
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Recuperated cycle (2/2)
Lesson XVII
•Efficiency:
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Intercooled Cycle
Lesson XVII
•Specific work increase
•Efficiency decrease (if ideal cycle)
•Efficiency increase possible (if real cycle)
•More efficiency benefit if recuperator is includes
•Example: LMS100 GE machine (P=100 MW, η=46%)
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Reheated Cycle
Lesson XVII
•Specific work increase
•Efficiency decrease
•Increase of heat content at turbine outlet (useful aspect for combined cycles or
recuperated cycles
•Essential for recuperator application in high β cycles
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Ericsson Cycle
Lesson XVII
•Not real cycle because too many exchangers and machines
•Efficiency equal to Carnot cycle if cycle with R=1 (recuperated)
H
←Q
HL
L
3 4
52
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Mixed Cycles: STIG (or Cheng) Cycle
Lesson XVII
•Efficiency increase (up to 46% in simple cycle), power increase
•Low cost in comparison with combined cycles
•Disadvantages: large water consumption, power limitation and surge risks
Examples: Allison/General Motors, 4/6 MWe; Kawasaki, 2/4 Mwe, GE LM5000)
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Mixed Cycles: RWI Cycle
Lesson XVII
•Efficiency increase (up to 52%), power increase (lower than STIG)
•Disadvantages: large water consumption, power limitation and surge risks, large
dimension heat exchanger
•No commercial application because it is no too cheap in comparison with CC
Water inlet
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Mixed Cycles: HAT Cycle
Lesson XVII
•Efficiency increase (up to 55%), power increase
•Disadvantages: large water consumption, power limitation and surge risks,
saturator is critical
•No commercial application, but prototype developments
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Gas Turbine Emissions
Lesson XVII
�Chemical pollution:
�CO emission are not significant (high air excess): <15-20 ppm
�HC emission are not significant (high air excess and natural gas – no
benzene based composites)
�NOx (to be reduced with apt devices)
�SOx (not significant if natural gas, low if kerosene): < 2-4 ppm (n.g.)
�Carbon particulate (not present if natural gas)
�Thermal pollution:
�CO2 emission (low if natural gas)
Emission content depends on turbine type, combustor geometry, operating
conditions (temperature), maintenance type, fuel composition.
Zeldovich reactions
(significant if T > 1600 K)
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Gas Turbine Emissions Abatement
Lesson XVII
Different approaches are considered:
�Low temperature operation (not efficient)
�Steam injection at combustor level
�Selective catalytic reduction devices
�Dry low NOx combustors (premixed flames)
Steam injection:
�Steam injection in STIG cycles is useful to have more uniform
temperatures in combustors (50% reduction in Nox)
Premixed flames (emissions < 15-20 ppm):
�With premixed flows (upstream of combustor inlet) it is possible to have
uniform combustion and no peak temperature (<1600 K) avoiding
significant thermal NOx formation.