supportinginformation kolano · 2008. 7. 29. · title: microsoft word -...

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1 Supporting Information Synthesis, characterization and applicability of three isotope labeled azobenzene photoswitches Rolf Pfister, a Janne Ihalainen, a Peter Hamm* a and Christoph Kolano* a a Physikalisch-Chemisches Institut,Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland. Fax:+41 4463 56838; E-mail: [email protected] , [email protected] Table of contents NMR spectra ( 1 H and/or 13 C) for all compounds reported in the manuscript 2-21 Supplementary Material (ESI) for Organic & Biomolecular Chemistry This journal is (c) The Royal Society of Chemistry 2008

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Page 1: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

1

Supporting Information

Synthesis, characterization and applicability of three isotope labeled azobenzene photoswitches

Rolf Pfister,a Janne Ihalainen,a Peter Hamm*a and Christoph Kolano*a

a Physikalisch-Chemisches Institut,Universität Zürich, Winterthurerstrasse 190,

CH-8057 Zürich, Switzerland. Fax:+41 4463 56838;

E-mail: [email protected], [email protected]

Table of contents NMR spectra (1H and/or 13C) for all compounds reported in the manuscript 2-21

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 2: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

2

Compound 1

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 3: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

3

Compound 2

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 4: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 3

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 5: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 3a

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 6: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 5

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 7: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 6

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 8: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 8

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 9: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 9

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 10: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 12a

Compound 12b

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 11: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 12c

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 12: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 12d

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 13: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 12e

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 14: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 12f

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 15: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 12h

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 16: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 13a

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 17: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 13b

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 18: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 14a

Compound 14b

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 19: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 14c

Compound 14d

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 20: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 15a

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008

Page 21: SupportingInformation Kolano · 2008. 7. 29. · Title: Microsoft Word - SupportingInformation_Kolano.doc Author: c.kolano Created Date: 6/24/2008 11:55:09 AM

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Compound 15b

Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2008