supporting information performance investigation cobalt … · carlos m. granadeiro,a* mohamed...
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![Page 1: SUPPORTING INFORMATION Performance Investigation Cobalt … · Carlos M. Granadeiro,a* Mohamed Karmaoui,b Eva Correia,a Diana Julião,a Vitor S. Amaral,b Nuno J.O. Silva,b Luís Cunha-Silvaa](https://reader034.vdocuments.us/reader034/viewer/2022050218/5f63bd283230cc5ea36c8b27/html5/thumbnails/1.jpg)
SUPPORTING INFORMATION
Cobalt Aluminate Nanoparticles Supported on MIL-101 Structure: Catalytic Performance Investigation
Carlos M. Granadeiro,a* Mohamed Karmaoui,b Eva Correia,a Diana Julião,a Vitor S. Amaral,b Nuno J.O. Silva,b Luís Cunha-Silvaa and Salete S. Balulaa*
a REQUIMTE & Department of Chemistry and Biochemistry , Faculty of Sciences,
University of Porto, 4169-007 Porto, Portugalb CICECO & Department of Physics, University of Aveiro, 3810-193 Aveiro, Portugal
Corresponding authors: Dr Carlos M. Granadeiro and Dr. Salete S. Balula; e-mail: [email protected],
[email protected]; Tel.: +351 220402576; Fax: +351 220402659
Figure S1. FT-IR spectra of CoAl2O4 nanoparticles, the solid support MIL-101 and the CoAl-2@MIL(Cr) composite.
Electronic Supplementary Material (ESI) for RSC Advances.This journal is © The Royal Society of Chemistry 2014
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Figure S2. FT-Raman spectra of CoAl2O4 nanoparticles, the solid support MIL-101 and the CoAl-2@MIL(Cr)
composite.
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Figure S3. Powder XRD patterns of CoAl2O4 nanoparticles, the solid support MIL-101 and the CoAl-2@MIL(Cr)
composite in the 3-23° range.
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Figure S4. SEM image of the CoAl-1@MIL(Cr) (left) and CoAl-2@MIL(Cr) (right) composite materials.
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Figure S5. EDX spectra of the CoAl-1@MIL(Cr) composite (a) before and (b) after catalysis.
(a) (b)
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Figure S6. Kinetic profiles for the oxidation of thioanisole using the isolated nanoparticles and the corresponding
composite materials.
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Figure S7. Kinetic profiles for the oxidation of styrene using the isolated CoAl-1 nanoparticles and the
corresponding CoAl-1@MIL(Cr) composite material.
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Figure S8. SEM image and elemental mapping images for CoAl-1@MIL(Cr)-ac (ac stands for after catalysis).