supplementary data meristematic cells of …supplementary data biotransformation of...

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Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata Electronic Supplementary Material (ESI) for RSC Advances. This journal is © The Royal Society of Chemistry 2019

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Page 1: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Supplementary Data

Biotransformation of 4-methylcoumarins by cambial

meristematic cells of Camptotheca acuminata

Electronic Supplementary Material (ESI) for RSC Advances.This journal is © The Royal Society of Chemistry 2019

Page 2: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S1. HR-ESI-MS spectrum of I-1 in CH3OH.

Page 3: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S2. 13C NMR spectrum (125 MHz) of I-1 in DMSO-d6.

Page 4: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S3. 1H NMR spectrum (500 MHz) of I-1 in DMSO-d6.

Page 5: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S4. HMBC spectrum of I-1 in DMSO-d6.

Page 6: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S5. HSQC spectrum of I-1 in DMSO-d6.

Page 7: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S6. IR spectrum of I-1.

Page 8: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S7. HR-ESI-MS spectrum of II-1 in CH3OH.

Page 9: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S8. 13C NMR spectrum (125 MHz) of II-1 in DMSO-d6.

Page 10: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S9. 1H NMR spectrum (500 MHz) of II-1 in DMSO-d6.

Page 11: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S10. HMBC spectrum of II-1 in DMSO-d6.

Page 12: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S11. HSQC spectrum of II-1 in DMSO-d6.

Page 13: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S12. IR spectrum of II-1.

Page 14: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S13. HR-ESI-MS spectrum of IV-1 in CH3OH.

Page 15: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S14. 13C NMR spectrum (125 MHz) of IV-1 in DMSO-d6.

Page 16: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S15. 1H NMR spectrum (500 MHz) of IV-1 in DMSO-d6.

Page 17: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S16. HMBC spectrum of IV-1 in DMSO-d6.

Page 18: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S17. HSQC spectrum of IV-1 in DMSO-d6.

Page 19: Supplementary Data meristematic cells of …Supplementary Data Biotransformation of 4-methylcoumarins by cambial meristematic cells of Camptotheca acuminata 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO

Fig. S18. IR spectrum of IV-1.