subduction, collision and exhumation in the...
TRANSCRIPT
Subduction, collision and exhumation in the ultrahigh-pressureQinling - Dabie orogen
BRADLEY R. HACKER I, LOTHAR RATSCHBACHER2 & J. G. LIOU3IGeological Sciences, University of California, Santa Barbara, CA 93106, USA
2lnstitut fiir Geologie, Technische Universitiit Bergakademie Freiberg,Freiberg, D-09599, Germany
3Geological and Environmental Sciences, Stanford University,Stanford, CA 94305, USA
c':. Abstract: High-pressure metamorphism and ophiolite emplacement (Songshugou ophio-lite) attended suturing of the Yangtze craton to Rodinia during the c.l.O Ga Grenvillian oro-
. geny. The Qinling microcontinent then rifted from the Yangtze craton at c.750Ma. The.;~ Erlangping intraoceanic arc formed in the Early Ordovician, was emplaced onto the Qinling, microcontinent in the Ordovician-Silurian, and then both units were accreted to the Sino-
Korea craton before being stitched together by the c.400 Ma Andean-style Qinling arc.Subsequent subduction beneath the Qinling-Sino-Korean plate created a Devonian-Triassic accretionary wedge that includes eclogites, and formed a coeval volcano-plutonicarc that stretches from the Longmen Shan to Korea. In the Late Permian-Early Triassic,the northern edge of the South China Block was subducted to > 150 km depth, creating thediamond- and coesite-bearing eclogites of the Dabie and Sulu areas. Exhumation fromthe mantle by lithosphere-scale extension occurred between 245 and 195 Ma during clock-wise rotation of the craton. The Yangtze-Sino-Korea suture locally lies tens of km north ofthe exhumed UHP- HP part of the South China Block, implying perhaps that the very tip ofthe South China Block was not subducted, or that the UHP-HP rocks rose as a wedge thatpeeled the upper crust of the unsubducted South China Block from the lower crust. The Tan-Lu fault is an Early Cretaceous to Cenozoic feature. The apparent offset of the Dabie andSulu UHP terranes by the Tan-Lu fault is a result of this Cretaceous to Cenozoic faultingcombined with post-collisional extension north of Dabie.
The Sino-Korean craton and the Qinling micro- basement outcrops can be assigned either a Sino-3. continent colli~ed in the Ordovician-Silurian. Kore;an or Yangtze crat.on affini~y, where~s the~,., The North China Block (NCB) and the South affinIty of areally extensIve domaIns of sedImen-
~ China Block (SCB) collided in the Permo-Triassic. tary strata or of volcano-plutonic complexes can1,4 The orogenic belt associated with these collisions be ambiguous. 'North China Block' and 'South"f);' and intervening tectonism extends c.2000 km China Block' are used to refer to the continental
west-east through the Qinling, Tongbai, Dabie blocks north and south of the Qinling-Dabie-Shan and Sulu areas and into Korea (Fig. 1). It is Sulu suture.of special interest because it contains high-pressure The Sino- Korean craton is subdivided into(HP) rocks of four different ages: Grenvillian, three units: the western, eastern and centralDevonian, Carboniferous and Triassic. This paper blocks. The western and eastern blocks areaims to provide a review of the collision zone as Archean cratons linked by a central suture beltboth a summary of what conclusions have been that formed during collision at c.1.8 Ga (Zhaodrawn where and with which data, and as a guide et at. 2000). The U-Pb zircon ages from theto future reseal\;h. Sino-Korean craton cluster at c.3.8, 3.3, 3.0, 2.5
and 1.7-1.8Ga (Song et at. 1996; Yu et at.. 1996; Zhao et at. 2000). The craton consists of
Smo-Korean craton a basement of Archaean to Proterozoic meta-
In our usage, the Sino-Korean and Yangtze cra- morphic rock overlain by a relatively uninter-tons comprise Precambrian basement and cover rupted 4-8 km thick superjacent section ofas described below; in principle, all Precambrian Sinian (Late Proterozoic to Early Cambrian) to
From: MALPAS, J., FLETCHER, C. J. N., ALl, J. R. & AITCHISON, J. C. (eds) 2004. Aspects of the Tectonic Evolution ofChiua. Geological Society, London, Special Publications, 226, 157-175.0305-8719/04/$15 ((;) The Geological Society of London 2004.
1 ! ! ii , .
thrust fault
Lushi
Tan-
Lu fa
ult
J2
30o
113o
Xi'an
Lo-Nan F.
Lu Shan
Shanyang
Danfeng Shangnan
O
111o
35o113o
35o
115o
contact, depositional or intrusive
faultinferred contact
structural trend
antiformsynformhomocline
Triassic sedimentary rocks
post-Triassic rocks
Cretaceous plutons
Triassic plutons
Paleozoic plutons
33o
Queshan
Shiyan
Fangxia
T3
Shang-Dan F.
Shan-Feng F.
Wudang Shan
Wudang F.
Gonglu F.
Zhuqi F.
J2
J3
Huangling
Shennong
T1
S
T1
Wuhan
J3
Meishan Fm.
Xinyang
NanyangBasin
Erlangping
unit names are italicized
Qinling
Kuanping
Kuanping
Foziling
P
J1
J2
P2
T3J1
P2
Explanation
100 km
32¡
109¡
33o108o
31¡
111¡
Sino-Korean craton cover and basement; letter shows age of youngest rocks
Douling
Songshugou
Liuling
Wudang &Yaolinghe
Suixian &Yaolinghe
Xiaomoling
Heihe
Guandaokou
Xiong'er
Xiong'er
Taihua gneiss
Lu Shan fault
T
J1
T3
Dengfeng
Xinyang
N
Shagou F.Chenhe F.
C
coesiteeclogite
blueschist
blueschist
amphibolite
quartz eclogite
NorthernOrthogneissCretaceous Xiaotian-M
ozitan fault
Kuanping unit
Erlanping unit
Qinling unit
Songshugou ophiolite
Douling, Sujiahe (incl. Huwan), Luzhenguang unit
Liuling unit
Yangtze craton cover and basement; letter shows age of youngest rocks
Luzhenguang
Triassic high-pressure and ultrahigh-pressure rocks
coesite eclogite
quartz eclogite
eclogite → amphibolite
blueschist → greenschist
XinyangHuwan shear zone
eclogite
Songxian
Dengfenggreenstone
M301,247B297,264
K205±5Z404,780,1.0,1.545
H152 or K?45
B10145
K9545
K~1000→22045
H~100045 M806->75045
H23745
M232→15045
K100-105
2.814
Pb2.514
K55
H4347
H4337
H3167 H1357z746, 77612 H40113
m450,4339
H<498 K100, 6026
H4047
H400→222M22713M243,26613
B12013Z6562
Z2.02
Z1.52
b1213
b1243
b4303
b3893
b1353
b3413
b1403
b1353
Rb1058
KAr7188
Rb1434
Ar2144
Ar2174
Rb4184Z2004
Z7254 z1.7Sm1.9Sr422H83316
Srwr9919
M2321
B3141B327 M3481
rieb2161
KAr4072
KAr4852
KAr1312KAr1402
KAr1412
KAr3842H402K~20045
KAr3982
KAr8802
KAr3702
KAr1272KAr1002
KAr1032
KAr7952
Z7472
Z74515
0.9(15)
0.9(15)
Rb2.82
Rb2.62UPb2.42
Z2.62
z7625
z0.8,2.613
Z77826
Z77125
Luzh sed: Pb734-1.949Foziling granites: Z719-76649Foziling sed: Pb 2.5, 1.9-1.8 Ga, 1.0-0.7 Ga, 455 Ma49
K~1000→25045
Yang
tze
crat
on (S
CB
)Si
no-K
orea
n cr
aton
(NC
B)
reference
K205[c. 870]*
age (Ma)
K: 40Ar/39Ar K-feldsparB: 40Ar/39Ar biotiteM: 40Ar/39Ar K-white micaH: 40Ar/39Ar hornblendeb: K/Ar biotitem: K/Ar K-white micah: K/Ar hornblendeZ: U/Pb zirconRm: Rb/Sr whole-rock-K-white micaRb: Rb/Sr whole-rock-biotite
zircon core (if present)Geochronology Explanation
location
Sm2248
Z76125
Z~75044
M235,K20526
M220→25617
M20533
m186, 2289m196,2039
m2159
Z22732
~2.9, 2.9-3.3 (19)
Ar4218
Z3912
Z226,85422
M18028
K17133
M225, 22218
z470, 43513
Rb40210
coesite
coesite
eclogite
Huwan shear zone
Z77926
Z23221
M23018
M21318
M23617
M21417
M19518
M23323
Sm44643 M23017Z660,73526
M26317
M23133M22433
M21233
M2473324917
M23433
M196,22233
M23433
M20733M20533
K16933
m2079
M19017
m2329 b2269
m1979
m201,2059
M20118M19833
M19533
M19633 M23733
M~400x217Z312[~400]21
Z3072Z311,307[433]21
Z400H399?39Sm42240
Foziling
quartz eclogite
eclogite
Z73926
Z78126
Sm2448Sm23136
Sm22836
Z79825
Z67422
Z76825
Z1.329 Z2.129
Z6382277231
Z75729
Sm23842
Sm21048
Z229[707]46
M17926
B~197,M20826M2161
M196 K20424
B22724
M1951
M22124
m2109
M1787M19128
Z22425
K22025
M21825
M24226Z667,73926
H742,77026
K18026
m2139
m2259
m2029
b204, 2239
M20624
M210,19826
H28026
Z87025
coesite
Z21822
NorthernOrthogneiss
Sm20848
M185,H21427
Sm218-210 x6,Rm 223-19830
Rbb194,194,197,198,198M205,206,206,212B201,202,211,21035
Z218-240,K203,B199,216,M195,H195(?)24
Z21422Sm246,Rb24023H22524Z21829
Z223[1.8]41
Rm23623M19024K176,M183,19026Z238[1.9]mz223,20934Z233[2.5]Sm23135Sm226x2,Rbb169,171,173,174,18137
Z77231Sm22136Z227,B19022
M200B19024,B195,K19526
b182,216,2319 Z21829
Z230,mz20934
G
G B A IH
D A B I E
S H A N
O N G 'A N
T O N
QI
NIL
N
Songshugou
H42045Sm98347m4253
m3543
Ar4218
Rb3838
Rb6704
Rb4444
Rbwr4529
Rbwr4249 Rbwr9919
Rbwr7949Rbwr9739
Rb4864
KAr4012KAr3802
KAr4032
KAr3942
KAr4802
Z3912
H~400K22045
K23045 z488,4875
Z43720
b4323
KAr3702
coesite eclogite(Hu et al.,1995)
northern Liuling=Qinling(?)
z4805
Rbwr40211
Sm40038
m4203
KAr4022
H³386K27045
quartzeclogite
eclogite→amphibolite
Z78125
Dengfeng greenstoneTaihua gneiss
Xiong'er &GuandaokouGroups
2.5-2.8Ga
OrdovicianthruSinian
Silurianvolcanism
Lower CarboniferoustoUpper Ordovician
tectonichiatus
platform
PermianthruDevonian
Devonianclastics (partlydeep marine)
Lower Triassiccoal andphosphorite
shallow marine-lacustrine
4Ð8
km
basement
basement
MesozoicthruEarlyTriassic
continentalcontinental
unstable shelf
lacustrine to alluvial
middle Carboniferous-Early Permian andesites
+crustal derivedJurassic volcanics
Sino-Korean craton Kuanping: Sino-KoreanPr oterozoic-Silurian
passive margin/accr etionary wedge(?)
pre-EarlySilurianparagneissbasement
~638Madetrital zircon
PermianthruMiddleCarboniferous
amphibolite-greenschist~435 Mametamorphism
Erlangping-Danfeng-Heihe
intraoceanicarc
oceanicsediments
up to~420 Ma
pillowedvolcanics &sheeted dikes
older than~480 Ma
plutons490-470 Ma
~490-470 Maintraoceanic arc
~440-390 Ma Qinlingarc and arc metamorphism
=Kuanping(?)
Qinling: Sino-Koreancover, ophiolite andYangtze basement
subduction(~490-470 Ma)
435-470 Masubduction and collision(?)
subduction ³400 Mano collision
Grenville (~1 Ga)formation ofRodinia
South China Block
Devonian-Permian(?)flysch and molasse
=Qinling(?)
=Yangtze craton(?)
Southern Liuling:Paleozoic
flysch and molasse(?)
Northern Liuling: = Qinling(?)
Douling: Yangtzebasement
Yangtze craton
Devonian-Permian(?)siliclastic &volcaniclasticrocks
amphibolite,marble, gneiss
~400Macontactmetamorphism ~310 &
400 Ma(?)eclogite
orthogneiss,acid todominantlyTi-richpillow basalt
0.7-0.8 Ga
Upper Sinianto Lower Triassicplatform carbonateson passive margin
Upper Triassicclastics
Lower-Middle Triassicevaporite,carbonate &breccia
pre-~435Maaccretionary wedgeor passive margin
amalgamated by 400 Ma
Yan
gtz
e ri
ftin
g
Yan
gtz
e ri
ftin
g
Mesozoic evolution sameas Sino-Korean craton
Triassic HP-UHP metamorphism(245-220 Ma)
paragneiss&hibolite
coesiteeclogite
2.1-2.6 Ga670-990 Ma
400 MaSongshugouophiolite
~1 Ga
marble,
Up
per
Qin
ling
Low
er Q
inlin
g
paragneiss,amphibolite
craton
relict eclogite
North South
(southern margin) (northern margin)
~12 km
suture
sutu
re
sub
duc
tion
zon
e
sub
duc
tion
zon
e
sutu
re
North China Block South China Block
Figure 3: Geologic units, tectono-thermal/sedimentary events, facies interpretation, radiometric ages, and tectonic interpretation of the Paleozoic-early Mesozoic Qinling orogenic belt. Formation of the intra-oceanic Erlangping arc between ~490-470 Ma was followed by accretion of the lower Qinling micro-continent to the intra-oceanic arc, and to the Sino-Korean craton. Subduction underneath the northernmost Liuling unit imprinted the ~400 Ma Qinling arc on the Sino-Korean + Qinling collage. A subduction signature is again evident during the mid-Carboniferous to Late Permian on the Sino-Korean craton, when the Paleo-Tethys was subducted northward, producing the andesitic magmatism on the Sino-Korean craton. In the Late Permian-Early Triassic, the leading edge of the Yangtze craton was subducted to >150 km and subsequently exhumed by crustal extension (after Ratschbacher et al. in press).
Tan-
Lu fa
ult
J2
30o
113o
Xi'an
LoÐNan F.
T
O
111o
35o113o
35o
115o
33o
T3
ShangÐDan F.
ShanÐFeng F.
Wudang F.
Zhuqi F.
J2
J3
T1
S
T1
Wuhan
J3
NanyangBasin
Foziling
P
J1
J2
P2
P2
32¡
109¡
33o108o
31¡
111¡
D a b i e S h a n
H o n g ' a n
T o n g b a i
Q i n l i n g
Douling
Liuling
Kuanping
Guandaokou
XiongÕer
XiongÕer
Taihua gneiss
Lu Shan fault
T
J1
T3
N
Shagou F.Chenhe F.
C
Cretaceous XiaotianÐMozitan fault
Luzhenguang
Xinyang Huwan shear zone
Figure 4: Major units and unit boundaries of the Qinling-Dabie orogen (see Figure 2 and its caption).
southern limit of NCB/northern limit of Yangtze affinity rockssouthern limit of Devonian tectonism
northern limit of Triassic metamorphism
northern limit of Triassic exhumation
southern limit of Sino-Korean cratonErlangping Intraoceanic Arc
Wudang ShanCore Complex
Hong'anHP-UHPTerrane
Dabie HP-UHPTerrane
Lower Yangtze fold-thrust belt
Yangtze craton basement and cover
Sino-Korean craton basement and cover
Qinling Microcontinent
. 1
162 B. R. HACKER ET AL
North China Block-South China Block suture in NCB (Yin & Nie 1993). This intra-oceanic arcthe Hong'an-Dabie areas. can be traced eastward as far as Hong'an,
High-pressure metagabbro, amphibolitized where it disappears beneath Cenozoic sediments~clogite and felsic granulite associated with (Figs 2 and 4). No such ophiolite is known fromc.l.0-l.2 Ga ophiolitic rocks were emplaced on Sulu or Korea, but there are several candidatestb the lower part of the Qinling unit in the Song- for Palaeozoic ophiolites in the Kunlun-Altynshugou area, following high-pressure meta- Tagh-Qaidam-Qilian area (Matte et al. 1996;morphism in an oceanic setting (Liu et al. Sobel & Arnaud 1999).1996; Song et al. 1998; Zhang 1999). The amphi-bolitized eclogite was derived from MORB, is in S"l. E I D . Q. I.fault contact with mantle peridotite and contains I unan- ar y evoman In mg arc
4ecompression textures common in many eclo- Following emplacement of the Early Ordoviciangites, including symplectites of plagioclase and Erlangping intra-oceanic arc, a continental mar-diopside derived from omphacite estimated to gin arc was built on the Kuanping, Erlangpinghave formed at pressures ~ 1.5 GPa (Zhang and Qinling units from c.438-395 Ma; this1999). A Sm-Nd mineral isochron of 983 Ma implies that the Erlangping and Qinling units'is taken to date later cooling. The high-P felsic were amalgamated with the Kuanping unit (andgranulite includes garnet + kyanite + micro- thus the Sino-Korean craton) prior to c.440 Maperthite + quartz + rutile assemblages formed (Fig. 3) (Ratschbacher et al. in press). Signifi- ;.at 800-900°C and 1.3-1.6GPa (Liu et al. cantly, none of these Silurian-Early Devonian1996). plutons crop out within the Liuling unit. How-
Palaeoclimatic, palaeobiogeographical and ever, the northern part of the Liuling unit,palaeomagnetic data imply that the North China which Ratschbacher et al. (in press) correlatedand South China blocks were close to or part of with the Qinling unit, experienced the regionalnear-equatorial East Gondwana through the contact metamorphism produced by this batho-Late Devonian, and that rifting of the NCB lith, and Silurian to Lower Devonian strata int1rom Gondwana took place after the Devonian the northern Liuling unit received metamorphic~hao et al. 1996; Huang et al. 2000). detritus (Mattauer et al. 1985) from the Qinlingi arc and c.780Ma and c.l.0Ga detrital zircons
(see above). We thus interpret the southernOphiolites and accretionary complexes NCB, and units as far south as the northern
Liuling unit, as having been stitched togetherEarly Ordovician Erlangping Ophiolite, the by the 400 Ma magmatic-metamorphic event,Qinling Microcontinent and their and suggest that an Andean-type continental
... margin arc was built along the southern marginamalgamanon wIth the SIno-Korean Craton of the NCB at this time; we place the subduction
The distribution of ophiolites within the Qinling- zone producing the Silurian-Devonian arcDabie-Sulu orogen provides important infor- south of the northern Liuling unit (Ratschbachertpation about the (partial) closure of ocean et al. in press). The local absence of Upper "basins. The oldest Palaeozoic orogenic event in Ordovician (c.445 Ma) through Lower Carbon-~e Qinling orogen was the formation of the iferous (c.350 Ma) rocks from the NCB in the~rlangping intra-oceanic arc, which includes Qinling orogen probably reflects uplift related l'
the Heihe, Danfeng and Erlangping units to the formation of this Andean.style Qinling arc.(]Fig. 3). Sediments associated with the arc contain High-pressure rocks that may be associatedCambrian-Ordovician through Ludlovian- with the Qinling arc have been found by HuWenlockian (419-428 Ma) radiolaria, and tron- et al. (1995, 1996) in the northern Qinling areadjhemites, tonalites, gabbros, and rare pyroxenites (Fig. 2, offset). Hu et al. reported lenses andwith single-zircon PbjPb ages of 470-488 Ma blocks of eclogite, coesite-bearing eclogite andthat intrude a volcanic sequence (see summary retrogressed amphibolite within garnet-bearingin Ratschbacher et al. in press). Ratschbacher quartz and phengitic mica schist. While the indi-8t al. (in press) proposed south-directed emplace- vidual outcrops are no more than a few metresment of this arc on to the lower Qinling unit (the wide, the belt of eclogites eJ(tends more than~inling microcontinent) between c.470 and 10 km (Fig. 2). The eclogites c~nsist of garnet +435 Ma, based on the present geographical pos- omphacite + rutile + quartz + zoisite :t phengiteitions of the arc, the upper Qinling unit and the (3.5 Si atoms per formula utrit):t amphibole;lpwer Qinling unit. The Erlangping-Qinling col- many have been extensively retrogressed.lision may have been related to the collision of the Inclusions of coesite and its pseudomorphs inPamir-South Tarim-Qaidam continent with the garnet and omphacite were identified in a few
Ii
SUBDUCTION, COLUSION AND EXHUMATION 163
samples, based on optical properties and the of California (Ye et al. 1994; Liu et al. 1996).presence of radial fractures around the inclusions; They have yielded SHRIMP U - Pb zircon agesthis identification, however, should be confirmed of c.310 Ma (Sun et al. 2002), 400 Ma (Jianby Raman spectroscopy. Pressure-temperature et al. 1997), a Sm/Nd isochron of 422 Maestimates based on mineral composition range (Li et al. 1995), an amphibole 40 Ar /39 Ar age offrom 1.3 to 1.5GPa and 590 to 758°C; coesite 400Ma (Jian et al. 1997), and a muscoviteof course would indicate P> 2.6 GPa. A Sm- 4OAr/39Ar age of 400Ma (Xu et al. 2000a).Nd isochron for gamet, omphacite, rutile, amphi- Sun et al. (2002) directly tied their c.310 Mabole and whole rock is reportedly 400:t 16 Ma age to high-pressure recrystallization with laser(although we are unable to reproduce this age ICP-MS trace-element analyses that demon-from the reported isotopic ratios). strated zircon growth while garnet was stable
The Qinling continental arc can be traced east- and plagioclase was not stable.ward as far as Hong' an, where it disappears During and after the formation of the Qinlingbeneath Cenozoic sedimentary rocks (Figs 2 Andean-style volcano-plutonic arc, the southernand 4). No such arc is known from Sulu or margin of the NCB was dissected by sinistralKorea, but possible correlatives exist in the Kun- wrenching along the Lo-Nan and Shang-lun Mountains of northern Tibet (Matte et al. Dan shear systems at 420-380 Ma (Fig. 2)1996; Yang et al. 1996). (Ratschbacher et al. in press). We assume that
oblique subduction imposed these spectaculartransDressive wrench zones. Muscovite and bio-
Devonian- Carboniferous accretionary wedge tite 4t> Ar /39 Ar ages ranging from 348 to 314 Ma
A probable fossil accretionary complex, also with have been interpreted to reflect a continuationhigh-pressure rocks, lies south of the Silurian- of this strike-slip motion into the Permian (Mat-Earl~ Devonian arc in the Liuling and Sujiahe tauer et al. 1985). On a larger scale, the NCBunit$ (Fig. 3). The Liuling unit is a mixture of and SCB rifted from Gondwana in the Latesiliciclastic and volcaniclastic rocks, amphibolite Devonian-Early Carboniferous (Li & Powelland minor carbonate (You et al. 1993). Correla- 2001).tive rocks include the Xinyang Group in Tongbai-Hong'an and the Foziling unit in Dabie. . .. .pevpnian fossils in the Tongbai area (Du 1986; Devoman-Tnasslc volcano-plutonIc arcNiu' et al. 1993) have been used to infer a It is unclear whether the inferred Devonian-Per-Devpnian age for the entire Liuling; however, mian subduction beneath the NCB produced at:lu and Meng (1995) showed that several continental margin arc. Younger, Permian andconglomerate-bearing, volcaniclastic deposits, Triassic metaluminous, probably I-type plutonslocally containing metabasalts and metacarbo- with low Sri ratios (Xue et al. 1996a) intrudenates, have proven Upper Devonian and Lower the Kuanping, Erlangping, Qinling and LiulingCarboniferous and suspected Carboniferous to units as far east as Xi'an (Figs 2 and 4). CoevalPermian ages. The Sujiahe unit mainly contains intrusions pierce the western edge of the Yangtzevolcaniclastic rocks and 'melange' (Ratschba- Craton in the Xue Shan, Longmen Shan, thecher et al. in press). Songpan-Ganze flysch and the SCB cover
Blocks of eclogitic rocks and retrograde south of the Qinling mountains (Fig. 1, Regionalamphibolites occur in a shear zone 1-3 km Geological Survey of Gansu 1989, Regionalwide near the southern edge of the Sujiahe unit Geological Survey of Shaanxi 1989). The plutons5 - 20 km northwest of Tongbai. The eclogites intruding the SCB cover raise an important pro-con~ain gamet, omphacite, quartz, rutile, phen- blem, as they appear to be south of the inferred~iteand barroisitic amphibole, and have yielded north-dipping subduction zone. East of Xi'anP-T estimates of 480-550 °C and 1.3-1.8 GPa this arc may end, disappear under Cenozoic sedi-twe~ et al. 1999). Ye et al. (1994) reported Sm- mentary rocks, or be covered by younger thrustNd tnineral/rock isochrons of 533 :t 13 Ma and slices. Middle Carboniferous to Early Permian$44114 Ma and a 40 Ar /39 Ar barroisite age of andesites form a NE-trending belt across the east-
399:it4 Ma. This belt of HP rocks in the Sujiahe em half of the NCB (Fig. 1) (Zhang 1997), butunit extends as far east as the Xiongdian area of the belt is surprisingly far north of and obliqueHong' an, where eclogite lenses or layers crop to the inferred NCB-SCB suture.put jn quartzite and felsic gneiss. These eclogites We suggest that the pre-collisional, Permo-con~ain minor glaucophane and phengite in Carboniferous NE trend of the NCB-SCB sutureaddition to gamet, omphacite and rutile, and in Tongbai-Hong'an-Dabie and the suture-arcfonned at Po::: 1.3-1.5 GPa, To::: 590-680°C, distance were modified by the Triassic, syn-similar to tectonic blocks in the Franciscan Complex collisional clockwise rotation of the SCB
-
SUBDUCTION, COLLISION AND EXHUMATION 165
(Wei et at. 1998; Tsai & Liou 2000; Xu et at. only 400-800 MPa at 350-450 DC (Eide & Liou2000b; Zhou et at. 2000; Liu et at. 2001); (3) 2000). While most of the evidence of UHPthe Zhangbaling and Bengbu areas, a mostly derives from eclogites, the paragneiss also con-blueschist-facies extensional complex (our obser- tains local unambiguous indications of meta-vations); and (4) the Sulu area (Wallis et at. morphism at similar pressure and temperature,1999) (Fig. 1). such that the eclogites clearly were metamor-
The evidence of Triassic HP and UHP meta- phosed in situ (Liou et at. 1996), the same maymorphism comes chiefly from a few per cent of not hold true for ultramafic blocks, some ofeclogite and garnet peridotite boudins that are which record recrystallization pressures >4 GPahosted by paragneiss plus less granodioritic- (Okay 1994; Hacker et at. 1997; Liou & Zhangtonalitic orthogneiss (Fig. 6) (Cong 1996; Liou 1998). The spatial distribution and metamorphicet at. 2000). The highest temperatures and press- conditions of these: HP through UHP rocksures attained in the coesite- and, locally, diamond- indicate subduction~zone metamorphism on abearing Dabie eclogites were 825-850 DC and regional scale.3.3-4.0 GPa (Carswell et at. 1997). The coesite- The age of UHP metamorphism in the Dabie
~ free eclogites reached somewhat lower peak Shan is now well constrained to be Middle-
conditions of 625-700 DC and 2.2-2.4 GPa in Late Triassic (e.g. Hacker et at, 2000). Thethe Dabie Shan (Okay 1993; Liou et at. 1996; most recent data indicate that UHP recrystalliza-
~ Carswell et at. 1997), and have been divided tion may have begun as early as 245 Ma andinto kyanite-bearing and kyanite-absent eclogites extended through c.225-230 Ma (Okay 1993;in Hong'an, with estimated physical conditions of Hacker et at. 1998; Hacker et at. 2000; Li et at.550-650 DC, 1.6-2.5 GPa and 450-550 DC, 2000; Chavagnac et at. 2001; Ayers et at.0.8~1.2GPa, respectively (Eide & Liou 2000). 2002). High-pressure rocks in Hong'an (theThe amphibolite unit is a hornblende-rich orthog- area least affected by Cretaceous reheating) indi-neiss; peak pressure and temperature estimated cate that the regional amphibolite-facies over-from one locality are > 1.0 GPa and :::: 650 DC (Liu print at 500-650 DC and 0.8 GPa occurred during& Liou 1995). Blueschists reached conditions of the 195 - 225 Ma time span (40 Ar /39 Ar phengite
I!,i
i, Eclogites Garnet peridotites8 7Dable -5ulu te"ane , Dabie-5ulu terrane
I. Eastern Dable ,II. Central Dabie " @Mantle-derIVed spinelIII. Yangkou Beach, 5ulu, @peridotlte (5) and ' , "IV. Weihai 5ulu ' 6 G garnet peridotite (G) ,, , G
5 NQ: North Qinling ,'UHP . Crustal maflc-ultramsfic b
HW H ' complex c~: uwan .,. , ~"" ~ej,. , ,%0" ~'(',- 5 ~"~,- 4 ov, ,/~ - ~, DryEC
tV '-Q. ,.
. ,(!) Lw-EC ,--, 4 'GI' """, ,~ 3 ' "
, m,' "/j GI '... 3,'-
I Q. ,i ,,' ~\e
2 " "
2 .j,"I ~<;,-" ~o\\\8
~ II1
0 0200 400 600 600 1000 200 400 600 1000 1200 1400
Temperature °C km-1
Fig. 6. Metamorphic pressures and temperatures for eclogites and peridotites of the Qinling-Dabie-Sulu orogen(modified after Liou et ai. 1999; Zhang et ai. 2001).
,h
L _I l" "...
'I IiI\ill I,
166 B. R. HACKER ET ALI,: ages). ~ost o.f the ~-f:ldsrar 40 Ar/~9 Ar spectra exten.sional exhumation of the HP- UHP rocksi have mflectIons mdicatmg cooling below remams unclear.I c.200 °C near 170 Ma, although some rocks were The HP to UHP rocks of Dabie- Hong' an are
this cool as early as 200 Ma. Such P- T paths, mostly a structural homocline with SE-dippingwith concomitant decompression and cooling are foliation, SE-plunging lineation, and overall
.. only possible if exhumation was rapid or the slab top-to-NW flow that includes significant coaxialwas refrigerated by deeper level subduction stretching (Fig. 7). In northern Hong' an, how-(Hacker & Peacock 1995; Ernst & Peacock ever, the S-oriented structures rollover through1996). The exhumation rate is only crudely con- horizontal into a 5-km-thick zone of N(W)-dip-strained to c.3-l5 mm/year. ping foliations, N(W)-plunging lineations, and a
" Geochronology shows that the Middle-Late N(W)-directed sense of shear. This, the HuwanTriassic thermal event associated with the UHP shear zone (Webb et at. 2001), effectively strad-metamorphism in the eastern Dabie Shan and dIes the Triassic suture. It developed out of theHong'an areas extended as far north as the high-strain gneisses of typical Yangtze affinity
i Erlangping unit in the Qinling area, the Xinyang in northern Hong'an, contains strongly retro-, 6 unit in the Tongbai and Hong'an areas, and the gressed eclogite boudins of pre-Triassic age ini .. Foziling and Luzhenguang units in the Dabie the Sujiahe complex (see above), and dies out
r Shan (Hacker et at. 1.998; Hacker et at. 2000). northward in the phyllitic quartzites typical ofThe absence of HP metamorphism means that the southern Liuling unit. The Huwan shearthese northernmost units were not subducted zone can be followed - with interruptions by Cre-during the collision, but the Late Triassic meta- taceous plutons - into northern Dabie, where it ismorphism is certainly related to the collision. truncated by a large Cretaceous pluton. The pseu-
dostratigraphy of the Hong'an area also defines aseries of kID-scale NW -trending synforms and
t . .. antiforms that are overturned to the north in cen-Co uslonal defonnatlon tral Hong'an, and are upright to south facing in
The Triassic NCB-SCB collision produced a southern Hong'an. The coesite-bearing eclogitedistinct set of structures throughout the Qinling- unit forms the core of the northernmost antiform;Dabie orogen: NW-SE to N-S contraction by the lowest pressure rocks, blueschist, are presentfolding and thrusting Ithroughout the belt, sub- only on the south limb of this orogen-scale fold.horizontal NW -SE to N -S extension within The westward decrease in peak metamorphiccore complexes along the northern margin of pressures reveals that the antiform plungesthe South China Block, and dextral transpressive west. This antiform extends eastward intoreactivation of existing shear zones in the Qinling Dabie where it is partially overprinted by thearea (Fig. 5). dominantly Cretaceous intrusions and structures
The UHP rocks in both Dabie-Hong'an of the Northern Orthogneiss (Ratschbacher et at.(Faure et at. 1999; Hacker et at. 2000) and Sulu 2000), and then terminates against the Tan-Lu(Wallis et at. 1999; Faure et at. 2001) form the fault. ..
cores of structural d\)mes, exhibit a top-NW The large-scale Wudang Shan dome (Fig. 4)sense of shear and are overlain by extensional that lies west of the UHP Hong'an-Dabie areafaults that exhumed die UHP rocks. At least in is an extensional core complex overprinted byHong'an-Dabie, the entire crystalline core of foreland folding and thrusting. Deformation in "the orogen constitutes a normal-sense shear the Wudang Shan began with an early unre-zone c.15 km thick; *e Huwan shear zone, a solved, but possibly contractional deformation,normal-sense detachment that reactivated the was followed by sub-vertical contraction andplate suture, tops the ~xtensional allochthon in sub-horizontal N -S extension during blues-Hong'an (Hacker et I at. 2000; Webb et at. chist-greenschist-facies metamorphism of the2001). Associated Triassic metamorphic core basement and basement-cover contact zone;complexes in the northern part of the SCB 40 Ar /39 Ar dating of syn- to post-kinematic horn-i.clude the Wudang Shan (Ratschbacher et at. blende and muscovite puts the extension at, orin press) and Zhangbaling-Bengbu (our unpub- prior to, 230-235 Ma. Subsequent folding andlished data); whether the Lu Shan (Lin et at. thrusting of the basement and Palaeozoic cover2000), Wugong Shan (Faure et at. 1996), sequence occurred during N-S contraction.Dongling (Grimmer et at. in press), and Jiuling The northern limit of the Triassic extensionalShan (Lin et at. 2001) basement uplifts within deformation (Fig. 4) is located at differentthe foreland SCB fold-thrust belt south and east positions along the Qinling orogen. In theof Hong'an-Dabie, which show a Triassic to Qinling mountains, the northern limit of exten-Cretaceous extensional overprint, are related to sion is the Wudang basement; the Douling unit
II
i
1_-
I li8lm'c "if' c
I 'I' f
blueschist
fold & thrust belt
Yangtzebasement
Yangtzebasement
10 km
N blueschist
Foziling GpXinyang Gp
Qinling Gp
Sujiahe Gp
blueschist
Qinling Gp
Meishan Gp Luzhenguang Gp
amphibolite
Ceno
zoic
Ta
nÐLu
Fau
lt
C retace
ous XiaotianÐMozitang Fault
quartz eclogite
quartz eclogite
Northern Orthogneiss
suture
fold & thrust belt
coesite eclogite
coesite eclogite
Yangtzebasement
Erlan-ping Gp
Northern Dabie Shan
shear bands & shear zones shear bands & shear zonesshear bands & shear zones
lineation, showing sense of motion of upper plate
Northern Hong'an
Southeastern Dabie Shan
shear bands & shear zones
SouthernHong'an
SE-NW trend
SSW trend
Central Eastern Dabie Shan
Southwestern Dabie Shan1
3
2
1
B 23
1
3
2B
1
2
3Sf
S0
S0
L
B
Eastern foreland
D287
D285
D284
D283
D287
D285
D284
D283
S1
foliation (¥) & lineation ( )
L1
S1
L1
L1
shear bands & shear zonesshear bands & shear zones
L2L1
foliation (¥) & lineation ( ) foliation (¥) & lineation ( )
foliation (¥) & lineation ( )foliation (¥) & lineation ( )foliation (¥) & lineation ( )
brittle stretch direction
115oE
30oN
Eocene sedimentsNeogene sediments
synform, antiformfault/shear zone
eclogite
coesite absentcoesite
metamorphic boundaries
Early Cretaceous volcanicsLower Cretaceous sediments
125-137 Ma syenite to tonalitepre-Cretaceous cratonal cover sequence
Figure 7: Structural overview of the Dabie-Hong'an area (after Schmid et al. 1999; Hacker et al. 2000; Ratschbacher et al. 2000; Webb et al. 2001). Areas disturbed by Cretaceous plutons are not included in the synoptic stereonets. Stereonets from eastern foreland show dominantly brittle faults: (1), (2), and (3) indicate principal stress directions; B, fold axis; S0, bedding; and Sf, foliation.
I
168 B. R. HACKER ET AL.
is non-mylonitic and lacks significant Triassic sedimentation (Huang & Opdyke 2000) ormetamorphism. In northern Hong' an, the unconfonnable deposition of coarse carbonateHuwan shear zone constitutes a lithosphere- breccias (Breitkreuz et al. 1994). Yin & Niescale reactivation of the Devonian-Triassic (1993) proposed that the transition from marinesubduction complex. In Dabie, the Huwan to continental sedimentation was diachronous:detachment cannot be mapped, as Cretaceous Early Permian in Shandong and Korea, Lower/tectonism has obliterated earlier fabrics, but the Upper : Permian south of Sulu, Lower/Middlenorthern limit of extension must be south of Triassic SE of Dabie.the Foziling and Luzhenguang units, which Nie ~t al. (1994) and Zhou & Graham (1996)have clear Yangtze craton affinity and were proposed that detritus eroded from the activeunaffected by HP metamorphism, very likely Qinling - Dabie mountain range was channeledcoinciding with the Early Cretaceous Xiaotian- westward and deposited to fonn the Songpan-Mozitang crustal-scale shear zone (Hacker et al. Ganze flysch from the Anisian through the2000; Ratschbacher et al. 2000). Norian (c. 240-2 10 Ma). Bruguier et al. (1997)
Much of the area shown in Figure 2 has found detrital zircons with U /Pb ages of 233WNW-trending folds and craton-directed thrusts and 231 Ma within the Songpan-Ganze flysch .of millimeter to kilometre scale that fonned during that m~tch the ages of zircons found in Dabiethe collision (Mattauer et al. 1985; Regional Geo- (Hacker et al. 2000).logical Survey of Henan 1989; Regional Geological Post-collisional, Jurassic, continental clasticSurvey of Shaanxi 1989; Regional Geological sedimentation on both cratons was accompaniedSurvey of Hubei 1990). On the NCB, the north- by deposition of up to 5 km of calc-alkaline, crus-directed Lu Shan thrust, placing crystalline base- tal-derived, intennediate-composition volcanicment over Palaeozoic cover, was active in the rocks: tuff, volcanogenic sandstone, and someMiddle Triassic and Late Jurassic (Huang & lava in the Late Jurassic (Regional Geological Sur-Wu 1992). Huang and Wu (1992) also identified vey of Anhui 1987; Regional Geological Survey ofa series of Mesozoic S-directed thrusts imbricating Henan J989; Regional Geological Survey of Hubeithe Sino-Korean basement, Kuanping, Qinling, 1990). Gneiss cobbles, presumably derived fromErlangping and Douling units. The fold-thrust the Dabie Mountains, first appeared in the Zhujibelt along the Lower Yangtze river began to Fonnation on the northern slope of the Dabiedevelop through NW -SE contraction in the Mountains in Middle Jurassic time (Ma 1991).Middle Triassic and continued through the Middle Jurassic sedimentary rocks in the LowerEarly Jurassic, by which time the shortening Yangtze fold-thrust belt show clear evidence ofdirection had rotated to NNE-SSW (Schmid erosion of the Dabie UHP core, including Triassic-et al. 1999). Jurassiq detrital micas with high-Si contents and
The Early Palaeozoic core of the Qinling oro- zircon grains as young as c.218 Ma (Grimmergen was reactivated during the relatively early et al. ~ press) their oldest mica ages indicate thatstages of the NCB-SCB collision by overall exhum~ion in Hong'an-Dabie might have startedtop-south imbrication during a change from at 240 t 5 Ma.NW -SE (dextral transpression) to NE-SW .shortening. Ratschbacher et al. (in press) docu- . .mented c.200-250 Ma low-grade metamorphism Plate-scale collision modeland dextral transpression along the Lo-Nan, While there is still much that we do not know,Shang-Xian and Shang-Dan faults, and N-S some key structural observations constrain theshortening within the Liuling and Douling units. exhum~tion mechanism of the UHP rocks
(Hacker et al. 2000):
Syn- to post-collisional overlap assemblage (I) Unfolding the 'Hong' an antifonn' - the
Changes in sedimentation patterns are often orogen-scale fold trending NW -SE acrossamong the best guides to collisional timing. Hpng'an-Dabie - yields aN-dippingDepositional facies up through the Permian lithospheric slab with coesite eclogite intrend E- W in the southern NCB, and NNE in the north and lower pressure rocks progress-the northern SCB (Han et al. 1989; Sun et al. ively farther south and closer to the interior1989; Wang et al. 1989; Zhang et al. 1989). of the SCB. The upper boundary of the slabAlthough collision-related (?) shortening began is: the Huwan shear zone, which encom-on the SCB in the Early to Middle Triassic, p~sses the suture between the NCB andthe major sedimentological change occurred t~ SCB, implying that it is essentially ain the Middle Triassic, which was marked plate boundary reactivated as a litho-locally by either a depositional hiatus, continental sphere-scale, nonnal-sense shear zone.
. : j J : 'C :
II
170 B. R. HACKER ET An.
two plates as the result of Late Pennian-Early ed~e of the SCB. In Dabie, it lies south ofTriassic indentation of the NCB by the SCB; th(j Luzhenguang unit. This implies thatthey rationalized that the active margin of the the Douling, Luzhenguang and other unitsNCB should have been relatively straight and (i) represent the leading edge of the SCBthat the passive margin of the SCB could have but were not subducted; (ii) were originallybeen relatively complex. Gilder et al. (1999) cri- south of the HP- UHP rocks and ended upticized this idea because of a 'lack of significant in their present position as a result of exhu-folding of Phanerozoic rocks. . . north of the Sulu mation of the HP- UHP rocks; or (iii) arebelt', and proposed instead that the older NCB part of the NCB (although of Yangtze affi-acted as a rigid indentor to deform the SCB in nity, like the Qinling unit), but are nowthe Early to Middle Jurassic - leading to the mysteriously south of the Liuling, Xinyangpalaeomagnetically recorded bending of the an(l Foziling units and escaped intrusion byLower Yangtze fold-thrust belt (Gilder et al. the Qinling arc.1999), formation of the Tan-Lu fault, and 600 (4) A weakness of the exhumation model out-of relative rotation between the NCB and SCB lined in the previous section is that we(Zhao & Coe 1987). While there is structural have not identified a sole thrust along theand thermochronological evidence of Late Cre- southern and eastern edges of Dabie- .taceous and Cenozoic strike-slip and normal Hong' an. SE-directed extrusion of thefaulting (Ratschbacher et al. 2000; e.g. Grimmer w~dge of UHP-HP rocks should haveet al. 2002), no well-documented structural data induced equivalent shortening at the tip ofdemonstrate sinistral Triassic or Jurassic motion thcr extruding wedge, but one of the charac-along the Tan-Lu fault. However, Mid-Triassic tetjistics of the Triassic/Jurassic forelandNW -SE contraction and Late Triassic-Early de~rmation east of Dabie is upright foldingJurassic N -S contraction in the eastern Dabie an afo~land (Schmi~ et al. 1999) .implies ~at if the c? bination o.f hin~erland-. and foreland-Tan-Lu fault eXIsted at that time then It would di cted thrusting WIth relatively moderatehave been sinistral. Note that the age of Triassic shprtening (Schmid et al. 1999; Grimmermetamorphism in the Qinling area is similar to et i al. in press). To explain the apparentthat in Dabie; the proposed younging and west- laqk of the mega-thrust and the distinctiveward migration of collision (e.g. Zhao & Coe stljuctural style, we can envision at least1987; Yin & Nie 1993; Zhang 1997) is not sup- thtee scenarios. (i) The leading edge ofported by extant geochronology (Hacker & th~ UHP-HP rocks forms a wedge that isWang 1995). buried beneath the cover strata of the fore-
land. This implies that the crust of the fore-.. land was detached at middle to upper
Problems and possible solutions c~stal levels and thrust northwestward onThe preceding sections have outlined a number tol the crystalline core. (ii) The UHP-HPof important problems within the Qinling - rocks were exhumed by buoyancy into!Dabie orogen. the middle/lower crust, and the overlying "! rocks were removed by extension and ero-1(1) The boundary between rocks of Sino-Kor- sil1>n. A plate rotation model proposes that
ean and Yangtze affinity appears to be a af(er initial collision in the eastern part of thesuture of Ordovician-Silurian age. This ott>gen, continued closure of the 'Songpan- "interpretation could benefit from further G~ze Sea' by subduction of oceanic litho-analysis of the tectonic histories of key sphere caused the SCB to rotate 60 0 clock-
units in the Qinling orogen. wise (required by palaeomagnetic data),1 (2) Devonian-Triassic rocks of the Liuling, pulling parts of the subducted SCB back
Xinyang, and Foziling units separate the toward the surface.NCB from the SCB. These relatively mono-tonous units thus potentially experiencedquite a varied history. Can this history beread from these rocks?
1 (3) The northern boundary of Triassic exhuma- Summarytion is generally south of the northern edge Grenvillian orogeny, involving oceanic subduc-of the SCB. In the Qinling mountains, it lies tion ~ith HP metamorphism and ophiolitesouth of the Douling unit and south of the emplacpment (Songshugou ophiolite), assembledYangtze craton cover. In Tongbai and the Ya1)gtze craton, including the Qinling micro-Hong'an it coincides with the northern contint1lit, into Rodinia. Rifting at c. 750 Ma
I '] -
SUBDUCTION, COLLISION AND ~ATION 171
separated the Qinling microcontinent from the CAO, R. ~ ZHU, S. 1995. The Dabieshan coesite-bear-Yangtze craton. Intra-oceanic arc formation ing eqlogite terrain - a neo-Archean ultra-high(Erlangping-Danfeng-Heihe) between c.490- press~ metamorphic belt. Acta Geologica Sinica,470 Ma was followed by the accretion of the 69, 2~2-242.lower Qinling unit to the intra-oceanic arc and CARSWE~, D. A., O'BRIEN, P. J., WILSON: R. N.. &
the North China Block. Oceanward (northward ZHAI~M. ~997. The~obarometIJ°fphenglte-~ngin present coordinates) subduction beneath the eclogites m the Dable. MountanIs of central China.rth L . 1. ... Jounl41 of Metamolphlc Geology, 15, 239-252.
no em ill mg urnt. lmpnnted the c.400 Ma CHAVAGNAC, V. & JAHN, B.-M. 1996. Coesite-bearingAn~ean-type mag.matlc arc o~ t~ the North eclogites from the Bixiling Complex, Dabie Moun-Chma Block. OblIque ~ubductlon Imposed the tains, China; Sm-Nd ages, geochemical character-spectacular Early Devornan left-lateral transpres- istics£d tectonic implications. Chemical Geology,sive wrench zones. A subduction signature is 133, 9-51.again evident during the mid-Carboniferous to CHAVAG AC, V., JAHN, B.-M. VILLA, I. M.,Late Pennian on the North China Block, when WHIT~HOUSE, M. & LIU, D. 2001. Mu1tichrono-the Palaeo-Tethys was subducted northward, pro- ~etriq evidence for an in. situ origin of the ultra-
" ducing the andesitic magmatism on the North hig.h-pressure metamorphic terrane of Dabieshan,fhina Bloc~. In the Late Pennian-E~ly Trias- Chinaf Journal of Geology, 109, 633-646.SIC the leadmg edge of the South China Block CHEN, D'i Wu, Y., WANG, Y.-J., ZHI: X., ~A, Q. &
was subducted to >150km and subse uentl ~~Nt J' 1998. .Age~, Nd and S~ IS.otOpl~ compo-
. . q. y sItton of the JIaozlyan gabbrolc mtruslon from
exhu.med by crustal extensIon dunng clockwIse the n rthern Dabie terrain. Scientia GeologicarotatIon of the craton. Sinic ,7,29-35.
CHEN,J., E,Z.,LIU, S.,LI,X. &FOLAND,K.A.1995.Thanks to Yongjun Yue, Stanford, for assistance with COOl~ g age of Dabie orogen, China, determinedChinese publi~ations; Shuwen Dong, Yueqiao Zhang and ?y 40 _39 ~ and fission track techniques. Science
many other Chinese colleagues for field guidance and discus- m Ch na, Senes B, 38, 749-757.sions; our colleagues J. C. Grimmer, L. Franz, R. Schmid, CHEN, ~., RAN, Y., You, Z. & SUN, M. 1992.E. Enkelmann and R. Oberhiinsli for discussions; and Whoi-rock Sm-Nd, Rb-Sr and zircon Ph-PhC. Blake, P. Robinson and C. Fletcher for useful criticism. datin of the metamorphic complex in the inte-Funded by projects Ra442/14, 19 of the Deutsche For- rior f Qinling orogenic belt, western Henan,schungsgemeinschaft and NSF grants EAR-9796119, and~eir im.plications with regard to crustalEAR-9725667 and EAR-<XXJ3568. evolu on. Chinese Journal of Geochemistry, 11,
168- 77.CHEN, .-S., You, Z.-D., Suo, S.-T., YANG, Y. &
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