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17 17.5

18 18.5

19 19.5

20 20.5

21 21.5

22

7.1 7.2 7.3 7.4

cAM

P (p

mol

/mL

)

pH

b

a a

b

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-500 0 500 1000 1500 2000 2500 3000 3500 4000-240

-235

-230

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-195

2 mM2 mMsssss

Calibration solution

E, m

V

time, sec

Calibration solution

2 mM

1 mM

9 mM

s

s-Serumsample

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