SUPPLEMENTARY INFORMATIONdoi: 10.1038/ngeo1114

nature geoscience | www.nature.com/naturegeoscience 1

Strong elemental fractionation of Zr-Hf and Nb-Ta across the Pacific Ocean

M. Lutfi Firdaus, Tomoharu Minami, Kazuhiro Norisuye and Yoshiki Sohrin

Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan

1. Analytical Methods

Seawater samples were collected during two cruises of KH-04-5 (December 2004–

March 2005; stations SX) and KH-05-2 (August–September 2005; stations ST) of R/V

Hakuho Maru (Supplementary Fig. S1). The details of sampling, pretreatment and analysis

were published elsewhere1. Clean technique was adopted throughout the procedure. A CTD

Carousel equipped with 12 liter Niskin-X samplers was submerged using a titanium armed

cable to collect seawater samples. Seawater was transferred from the sampler to low-density

polyethylene bottles (Nalge Nunc) on deck using a silicon tube and filling bell to avoid

contamination by airborne particles. Samples were immediately brought into a clean room

laboratory (class 100) on the vessel, passed through a 0.2 m Nuclepore filter (Costar) using

a closed filtration system, and acidified to pH 2.2 with HCl and HF. These samples were

stored at ambient temperature until analysis. Zr, Hf, Nb and Ta were preconcentrated in 1 M

HNO3 with a concentration factor of 50, through solid-phase preconcentration using chelating

resin immobilized-8-hydroxyquinoline and evaporation. The four elements were

quantitatively recovered; the recovery of spiked metals was 100±4%. Concentrations of Zr,

Hf, Nb and Ta in the final solution were determined by HR-ICP-MS (Element II, Thermo

Fischer). Measured isotopes were 90Zr, 91Zr, 177Hf, 178Hf, 93Nb and 181Ta. Standard solutions

were used for calibration. Detection limit was 0.084, 0.006, 0.072 and 0.006 pmol/kg for Zr,

Hf, Nb and Ta, respectively. Procedure blank was 0.25, 0.008, 0.078 and 0.009 pmol/kg,

respectively. The precision was about 5% for each element.

The seawater samples for dissolved Mn and Fe were obtained from the same samplers,

filtered as described above, and acidified to pH 2.2 with HCl. Mn and Fe were

preconcentrated using a column of Nobias Chelate-PA1 resin (Hitachi High-Technologies)

and determined by a calibration curve method using an ELAN DRC II ICP-mass

spectrometer (Perkin Elmer)2.

Present address: Department of Chemistry, Bengkulu University, Jl. Raya Kandang Limun, Bengkulu 38371, Indonesia. E-mail: ml.firdaus@gmail.com

1

2. Calculation of the Oceanic Residence Time

The residence time () of HFSEs in the ocean can be calculated from:

Csw Msw

Ftotal

Csw Msw

Friverine Fatmospheric Fhydrothermal

where Csw is the concentration of the element in seawater, Msw is the total mass of seawater

(1.35 1021 kg), and Ftotal, Friverine, Fatmospheric and Fhydrothermal are total, riverine, atmospheric

and hydrothermal flux of the element, respectively3. The results are given in Supplementary

Table S2. Csw of HFSEs used here is the average concentration of 163 deep water samples

(>1,000 m) on the Pacific section. Friverine can be calculated from:

Friverine Criverwater Friver f

where Criver is the concentration of the element in river water, waterFriver is the total river

discharge (3.74 1016 kg/year), and f is the fraction of riverine element that is not removed

from the water column within estuaries and is added to the deep ocean basins. Criver is taken

from Gaillardet et al4 for Zr and Nb. Criver of Hf and Ta is the concentration determined by

ourselves in a river water reference material SLRS-3 (Ottawa River, Canada)5. These

concentrations are 15% and 23% of the proposed world average4. The concentrations of Zr

and Hf in the Hudson River reported recently6 are comparable with the adopted Criver. In the

Hudson River estuary, there was ~50% removal of Zr and Hf. It is, however, assumed that f =

1, because we do not know enough details of estuarine removal for each element. Fatmospheric

consists of wet and dry deposition. The wet deposition flux is obtained by multiplying the

concentration in rain water (Crain) and the rain water flux (waterFrain = 3.60 1017 kg/year).

Because of scarcity of data, the concentration in rain water collected in Japan5 is used for Crain.

Since there is high dust supply from the Asian Continent to Japan, it is possible that the used

Crain is higher than the global average, resulting in overestimation of the flux. On the other

hand, the dry deposition flux is not considered here, because there are not enough data.

Fhydrothermal is assumed to be negligible on the basis of our observation.

The resulting of HFSEs is comparable with or slightly longer than the oceanic

mixing time of 500–1,000 years, and shorter than of silicate3. The that has been estimated

from scavenging models is 800–5,600 years for Zr and 650–1,300 years for Hf7. The that

has been estimated from riverine input is 5,000 years for Zr and 1,500 years for Hf8. On the

data from the Hudson River estuary, of Hf is estimated between 1,500 and 7,500 years6.

Using a weighted average river concentration of 33 pmol/l and variable f, it was argued that

of Hf is in a range of 435–1,500 years9. On the other hand, it has been proposed that of Hf

2

is only a few hundred years, because Hf does not increase along the deep ocean conveyer10.

Thus, our estimates of for Zr and Hf seem to be acceptable. No other data of for Nb and

Ta are available.

Supplementary Figure S1. Location of sampling stations. Locations of stations SA-12 and 34°41’N, 139°54’E, where the vertical profiles of REEs were observed11,12, are also shown. The map was made using ODV (http://www.awi-bremerhaven.de/GEO/ODV).

3

Supplementary Figure S2. Plot of silicate vs. HFSEs for all data on the Pacific section.

Supplementary Figure S3. Vertical profiles of the mole ratio of dissolved metals. (a) Zr/Hf at SX20 (30°S, 170°W) and ST09 (30°N, 160°W), (b) La/Lu at SA-12 (27°S, 175°E)12 and 34°41’N, 139°54’E11.

4

Supplementary Figure S4. Sectional distribution of dissolved Nb/Ta mole ratio in the Pacific Ocean along 170°W and 160°W. Water masses indicated are Western South Pacific Central Water (WSPCW) and Eastern North Pacific Central Water (ENPCW).

References used in Supplementary Information: 1 Firdaus, M. L. et al., Preconcentration of Zr, Hf, Nb, Ta and W in seawater using solid-

phase extraction on TSK-8-hydroxyquinoline resin and determination by inductively coupled plasma-mass spectrometry. Anal. Chim. Acta 583, 296-302 (2007).

2 Sohrin, Y. et al., Multielemental Determination of GEOTRACES Key Trace Metals in Seawater by ICP-MS after Preconcentration Using an Ethylenediaminetriacetic Acid Chelating Resin. Anal. Chem. 80, 6267-6273 (2008).

3 Sarmiento, J. L. & Gruber, N., Ocean Biogeochemical Dynamics. (Princeton University Press, Princeton, 2006).

4 Gaillardet, J., Viers, J. & Dupré, B., in Surface and Ground Water, Weathering, and Soils, edited by Henry Elderfield (Elsevier-Pergamon, Oxford, 2003), pp. 225-272.

5 Firdaus, M. L. et al., Dissolved and labile particulate Zr, Hf, Nb, Ta, Mo and W in the western North Pacific Ocean. J. Oceanogr. 64, 247-257 (2008).

6 Godfrey, L. V., Field, M. P. & Sherrell, R. M., Estuarine distributions of Zr, Hf, and Ag in the Hudson River and the implications for their continental and anthropogenic sources to seawater. Geochem. Geophys. Geosyst. 9, Q12007 (2008).

7 Orians, K. J. & Merrin, C. L., in Encyclopedia of Ocean Sciences, edited by John H. Steele, Steve A. Thorpe, and Karl K. Turekian (Academic Press, San Diego, 2001), Vol. 4, pp. 2387-2399.

8 Godfrey, L. V., White, W. M. & Salters, V. J. M., Dissolved Zirconium and Hafnium Distributions across a Shelf Break in the Northeastern Atlantic Ocean. Geochim. Cosmochim. Acta 60, 3995-4006 (1996).

9 Zimmermann, B. et al., The hafnium isotope composition of Pacific Ocean water. Geochim. Cosmochim. Acta 73, 91-101 (2009).

10 Rickli, J., Frank, M. & Halliday, A. N., The hafnium-neodymium isotopic composition of Atlantic seawater. Earth Planet. Sci. Lett. 280, 118-127 (2009).

11 Alibo, D. S. & Nozaki, Y., Rare earth elements in seawater: particle association, shale-normalization, and Ce oxidation. Geochim. Cosmochim. Acta 63, 363-372 (1999).

12 Zhang, J. & Nozaki, Y., Rare earth elements and yttrium in seawater: ICP-MS determinations in the East Caroline, Coral Sea, and South Fiji basins of the western South Pacific Ocean. Geochim. Cosmochim. Acta 60, 4631-4644 (1996).

5

Supplementary Table S1. Trace elements, nutrients and physical properties

Cruise Station Longitude Latitude Depth (m) Temp (C) Salinity O2 (ml/l) Phosphate (umol/l) Silicate (umol/l) Chl a (ug/l) Zr (pmol/kg ) Hf (pmol/kg ) Nb (pmol/kg ) Ta (pmol/kg )KH-04-5 SX10 -172.648 -67.2192 3 -0.643 33.444 8.36 1.49 56.3 1.89 41 0.11 1.55 0.027KH-04-5 SX10 -172.648 -67.2192 10 -0.626 33.448 8.41 1.49 56.1 2.01 43 0.10 1.62 0.019KH-04-5 SX10 -172.648 -67.2192 20 -0.480 33.635 8.29 1.64 54.9 1.67 40 0.08 1.56 0.022KH-04-5 SX10 -172.648 -67.2192 30 -0.574 33.690 8.23 1.69 56.7 2.12 45 0.11 1.68 0.019KH-04-5 SX10 -172.648 -67.2192 50 -1.704 33.636 7.18 2.12 69.6 0.58 39 0.09 1.57 0.023KH-04-5 SX10 -172.648 -67.2192 75 -1.754 33.690 6.89 2.10 71.5 0.30 50 0.09 1.6 0.032KH-04-5 SX10 -172.648 -67.2192 100 -1.326 34.110 6.62 2.15 73.0 0.15 56 0.11 1.74 0.027KH-04-5 SX10 -172.648 -67.2192 124 -0.409 34.182 5.79 2.20 79.4 0.07KH-04-5 SX10 -172.648 -67.2192 148 0.364 34.244 5.17 2.24 82.3 0.03 61 0.10 1.82 0.031KH-04-5 SX10 -172.648 -67.2192 198 1.153 34.411 4.63 2.26 86.2 0.02 54 0.11 1.86 0.028KH-04-5 SX10 -172.648 -67.2192 296 1.445 34.540 4.52 2.20 89.9 60 0.12 2.25 0.033KH-04-5 SX10 -172.648 -67.2192 395 1.310 34.646 4.59 2.20 92.4KH-04-5 SX10 -172.648 -67.2192 495 1.270 34.717 4.60 2.20 95.7 57 0.12 2.31 0.044KH-04-5 SX10 -172.648 -67.2192 593 1.241 34.723 4.63 2.21 98.9KH-04-5 SX10 -172.648 -67.2192 790 1.165 34.728 4.61 2.20 105.4 71 0.13 2.55 0.053KH-04-5 SX10 -172.648 -67.2192 987 1.015 34.722 4.68 2.22 111.3 79 0.14 2.31 0.062KH-04-5 SX10 -172.648 -67.2192 1233 0.862 34.717 4.70 2.23 118.0KH-04-5 SX10 -172.648 -67.2192 1480 0.708 34.711 4.81 2.24 121.4 82 0.18 2.52 0.069KH-04-5 SX10 -172.648 -67.2192 1726 0.596 34.705 4.81 2.25 123.2KH-04-5 SX10 -172.648 -67.2192 1971 0.489 34.701 4.84 2.26 124.7 98 0.21 2.64 0.065KH-04-5 SX10 -172.648 -67.2192 2216 0.407 34.701 4.87 2.27 127.1KH-04-5 SX10 -172.648 -67.2192 2461 0.328 4.92 2.26 126.5 99 0.24 2.79 0.061KH-04-5 SX10 -172.648 -67.2192 2706 0.270 34.697 4.97 2.26 126.2KH-04-5 SX10 -172.648 -67.2192 2950 0.228 34.695 5.02 2.26 125.3 109 0.24 2.92 0.073KH-04-5 SX10 -172.648 -67.2192 3194 0.194 34.693 5.06 2.26 123.3KH-04-5 SX10 -172.648 -67.2192 3400 0.187 34.693 5.08 2.25 122.7 124 0.27 2.83 0.069KH-04-5 SX10 -172.648 -67.2192 3621 0.194 34.693 5.12 2.26 122.6 130 0.27 2.76 0.075KH-04-5 SX10 -172.648 -67.2192 3669 0.196 34.693 5.11 2.26 121.7KH-04-5 SX10 -172.648 -67.2192 3716 0.200 34.696 5.10 2.25 121.7 132 0.27 2.88 0.077KH-04-5 SX12 -169.98 -59.3712 3 4.501 33.933 7.24 1.50 0.0 0.44 35 0.09 1.58 0.017KH-04-5 SX12 -169.98 -59.3712 10 4.506 33.930 7.23 1.50 0.0 0.51 32 0.09 1.75 0.015KH-04-5 SX12 -169.98 -59.3712 21 4.520 33.932 7.22 1.49 0.0 0.49 37 0.09 1.51 0.019KH-04-5 SX12 -169.98 -59.3712 30 4.537 33.931 7.23 1.51 0.0 0.48 32 0.12 1.69 0.022KH-04-5 SX12 -169.98 -59.3712 50 4.505 33.930 7.25 1.52 0.0 0.51 31 0.10 1.68 0.015KH-04-5 SX12 -169.98 -59.3712 61 3.493KH-04-5 SX12 -169.98 -59.3712 75 2.537 33.945 7.28 1.89 10.3 0.34 39 0.12 1.72 0.031KH-04-5 SX12 -169.98 -59.3712 100 2.369 33.942 7.29 1.88 12.4 0.23 47 0.11 1.7 0.04KH-04-5 SX12 -169.98 -59.3712 123 2.312 33.955 7.23 1.85 13.0 0.14KH-04-5 SX12 -169.98 -59.3712 148 1.858 33.918 7.41 1.84 14.4 0.11 38 0.11 1.76 0.037KH-04-5 SX12 -169.98 -59.3712 198 1.774 33.930 7.39 1.87 15.4 0.06 52 0.13 1.91 0.039

KH-04-5 SX12 -169.98 -59.3712 297 2.594 34.121 6.11 2.09 27.7 57 0.13 2.07 0.049KH-04-5 SX12 -169.98 -59.3712 396 2.121 34.172 5.79 2.19 37.4KH-04-5 SX12 -169.98 -59.3712 495 2.546 34.319 4.78 2.34 50.0 55 0.11 2.28 0.048KH-04-5 SX12 -169.98 -59.3712 594 2.574 34.416 4.33 2.41 59.8KH-04-5 SX12 -169.98 -59.3712 791 2.440 34.545 3.98 2.40 71.3 63 0.13 2.28 0.049KH-04-5 SX12 -169.98 -59.3712 990 2.357 34.631 3.99 2.32 76.6 72 0.16 2.26 0.063KH-04-5 SX12 -169.98 -59.3712 1235 2.228 34.691 4.19 2.25 80.8KH-04-5 SX12 -169.98 -59.3712 1480 2.059 34.727 4.32 2.18 85.6 70 0.19 2.69 0.075KH-04-5 SX12 -169.98 -59.3712 1727 1.904 34.741 4.40 2.15 90.2KH-04-5 SX12 -169.98 -59.3712 1973 1.703 34.743 4.49 2.15 96.0 84 0.23 2.55 0.073KH-04-5 SX12 -169.98 -59.3712 2217 1.494 34.742 4.57 2.17 102.3KH-04-5 SX12 -169.98 -59.3712 2462 1.308 34.732 4.66 2.18 108.8 95 0.25 2.93 0.07KH-04-5 SX12 -169.98 -59.3712 2707 1.167 34.726 4.68 2.21 113.6KH-04-5 SX12 -169.98 -59.3712 2952 1.056 34.721 4.71 2.23 116.5 110 0.26 2.73 0.074KH-04-5 SX12 -169.98 -59.3712 3193 0.963 34.716 4.83 2.24 120.1KH-04-5 SX12 -169.98 -59.3712 3439 0.877 34.713 4.82 2.26 123.6 118 0.27 2.91 0.079KH-04-5 SX12 -169.98 -59.3712 3683 0.849 34.709 4.79 2.26 125.8KH-04-5 SX12 -169.98 -59.3712 3926 0.849 34.711 4.82 2.27 127.6KH-04-5 SX12 -169.98 -59.3712 4170 0.867 34.712 4.88 2.27 128.5KH-04-5 SX12 -169.98 -59.3712 4410 0.892 34.710 4.80 2.25 128.7 130 0.31 3.12 0.088KH-04-5 SX12 -169.98 -59.3712 4892 0.950 34.706 4.81 2.26 128.4 138 0.35 2.9 0.086KH-04-5 SX12 -169.98 -59.3712 4941 0.956 34.708 4.84 2.26 128.2KH-04-5 SX14 -169.996 -50.0165 3 11.136 34.347 6.40 0.81 0.0 0.27 24 0.08 1.5 0.017KH-04-5 SX14 -169.996 -50.0165 10 11.016 34.342 6.44 0.79 0.0 0.25 27 0.08 1.52 0.02KH-04-5 SX14 -169.996 -50.0165 20 10.974 34.338 6.43 0.80 0.0 0.30 30 0.08 1.49 0.018KH-04-5 SX14 -169.996 -50.0165 30 10.934 34.340 6.47 0.79 0.0 0.28 25 0.08 1.53 0.021KH-04-5 SX14 -169.996 -50.0165 50 9.417 34.743 6.72 0.87 0.0 0.39 24 0.09 1.55 0.017KH-04-5 SX14 -169.996 -50.0165 64 8.665KH-04-5 SX14 -169.996 -50.0165 75 8.229 34.436 6.33 1.16 2.2 0.55 23 0.08 1.45 0.015KH-04-5 SX14 -169.996 -50.0165 100 7.979 34.440 6.28 1.17 2.4 0.06 27 0.10 1.45 0.023KH-04-5 SX14 -169.996 -50.0165 123 7.934 34.448 6.28 1.18 2.8 0.04KH-04-5 SX14 -169.996 -50.0165 148 7.712 34.420 6.36 1.19 2.7 0.03 30 0.09 1.85 0.03KH-04-5 SX14 -169.996 -50.0165 199 7.541 34.411 6.28 1.26 3.1 0.01 37 0.11 1.77 0.037KH-04-5 SX14 -169.996 -50.0165 298 7.234 34.393 6.05 1.39 5.2 37 0.10 2 0.035KH-04-5 SX14 -169.996 -50.0165 396 6.650 34.333 5.94 1.51 6.6KH-04-5 SX14 -169.996 -50.0165 495 6.188 34.317 5.62 1.67 10.2 45 0.11 2.12 0.054KH-04-5 SX14 -169.996 -50.0165 594 5.652 34.312 5.29 1.82 15.9KH-04-5 SX14 -169.996 -50.0165 790 4.573 34.331 4.84 2.07 29.1 57 0.14 2.57 0.058KH-04-5 SX14 -169.996 -50.0165 989 3.708 34.383 4.53 2.25 44.6 68 0.16 2.6 0.08KH-04-5 SX14 -169.996 -50.0165 1235 3.066 34.472 4.14 2.36 61.8KH-04-5 SX14 -169.996 -50.0165 1482 2.649 34.548 4.01 2.38 71.7 76 0.18 2.63 0.092KH-04-5 SX14 -169.996 -50.0165 1728 2.439 34.628 3.99 2.34 79.7KH-04-5 SX14 -169.996 -50.0165 1973 2.286 34.687 4.12 2.26 81.2 93 0.20 2.83 0.083KH-04-5 SX14 -169.996 -50.0165 2219 2.147 34.721 4.25 2.21 85.0

KH-04-5 SX14 -169.996 -50.0165 2464 1.966 34.737 4.38 2.18 89.9 109 0.26 2.73 0.08KH-04-5 SX14 -169.996 -50.0165 2709 1.772 34.741 4.47 2.19 96.2KH-04-5 SX14 -169.996 -50.0165 2953 1.575 34.740 4.56 2.20 102.0 112 0.26 2.68 0.081KH-04-5 SX14 -169.996 -50.0165 3197 1.409 34.736 4.60 2.22 107.6KH-04-5 SX14 -169.996 -50.0165 3442 1.260 34.729 4.66 2.22 112.0 123 0.28 3.11 0.083KH-04-5 SX14 -169.996 -50.0165 3687 1.135 34.727 4.73 2.24 115.9KH-04-5 SX14 -169.996 -50.0165 3929 1.029 34.719 4.76 2.25 119.6 122 0.28 2.87 0.095KH-04-5 SX14 -169.996 -50.0165 4172 0.971 34.715 4.82 2.26 122.7KH-04-5 SX14 -169.996 -50.0165 4415 0.944 34.712 4.79 2.26 124.6 124 0.31 2.88 0.098KH-04-5 SX14 -169.996 -50.0165 4658 0.948 34.711 4.80 2.26 125.4KH-04-5 SX14 -169.996 -50.0165 4901 0.965 34.713 4.80 2.26 125.8 135 0.35 3.04 0.093KH-04-5 SX14 -169.996 -50.0165 5358 1.020 34.713 4.83 2.28 125.8 140 0.38 2.99 0.095KH-04-5 SX17 -169.995 -39.998 2 16.396 35.025 5.63 0.19 0.0 0.11 21 0.07 1.43 0.015KH-04-5 SX17 -169.995 -39.998 10 16.400 35.021 5.59 0.18 0.0 0.13 25 0.07 1.45 0.014KH-04-5 SX17 -169.995 -39.998 20 16.395 35.019 5.60 0.18 0.0 0.12 29 0.07 1.47 0.017KH-04-5 SX17 -169.995 -39.998 29 16.319 35.019 5.64 0.18 0.0 0.08 23 0.08 1.5 0.019KH-04-5 SX17 -169.995 -39.998 40 15.067KH-04-5 SX17 -169.995 -39.998 50 14.329 35.053 5.80 0.24 0.0 0.19 23 0.07 1.46 0.021KH-04-5 SX17 -169.995 -39.998 74 12.187 34.947 5.74 0.54 0.0 0.13 28 0.10 1.57 0.012KH-04-5 SX17 -169.995 -39.998 99 11.939 34.976 5.61 0.61 0.0 0.12 27 0.08 1.78 0.018KH-04-5 SX17 -169.995 -39.998 124 11.593 34.932 5.61 0.67 0.0 0.03KH-04-5 SX17 -169.995 -39.998 149 11.324 34.905 5.57 0.72 0.0 0.01 38 0.09 1.89 0.029KH-04-5 SX17 -169.995 -39.998 199 10.812 34.830 5.33 0.89 0.0 0.00 45 0.09 1.84 0.042KH-04-5 SX17 -169.995 -39.998 298 9.540 34.680 5.04 1.20 2.4 47 0.11 2.16 0.042KH-04-5 SX17 -169.995 -39.998 397 8.566 34.572 5.07 1.37 5.7KH-04-5 SX17 -169.995 -39.998 495 7.972 34.517 5.06 1.49 7.7 52 0.13 2.07 0.041KH-04-5 SX17 -169.995 -39.998 595 7.407 5.05 1.61 9.3KH-04-5 SX17 -169.995 -39.998 792 6.371 34.407 4.83 1.82 15.8 69 0.15 2.29 0.048KH-04-5 SX17 -169.995 -39.998 990 5.228 34.408 4.47 2.06 31.4 80 0.18 2.45 0.066KH-04-5 SX17 -169.995 -39.998 1237 4.101 34.479 4.02 2.30 57.3KH-04-5 SX17 -169.995 -39.998 1483 3.226 34.542 3.75 2.44 89.4 96 0.22 2.35 0.064KH-04-5 SX17 -169.995 -39.998 1729 2.691 3.57 2.40 89.2KH-04-5 SX17 -169.995 -39.998 1975 2.374 34.627 3.51 2.46 108.9 120 0.24 2.63 0.061KH-04-5 SX17 -169.995 -39.998 2221 2.187 34.649 3.52 2.48 114.4KH-04-5 SX17 -169.995 -39.998 2466 2.019 34.673 3.70 132 0.26 2.73 0.066KH-04-5 SX17 -169.995 -39.998 2711 1.867 34.706 4.01 2.43 113.4KH-04-5 SX17 -169.995 -39.998 2956 1.691 34.722 4.28 2.31 107.2KH-04-5 SX17 -169.995 -39.998 3201 1.508 34.723 4.30 2.24 105.6KH-04-5 SX17 -169.995 -39.998 3445 1.330 34.731 4.60 2.31 110.9 128 0.30 2.92 0.072KH-04-5 SX17 -169.995 -39.998 3688 1.160 34.723 4.64 2.31 115.9KH-04-5 SX17 -169.995 -39.998 3933 1.020 34.716 4.72 2.32 120.1 138 0.33 3.08 0.078KH-04-5 SX17 -169.995 -39.998 4176 0.956 34.713 4.75 2.32 122.9KH-04-5 SX17 -169.995 -39.998 4418 0.943 34.712 4.75 2.31 124.7KH-04-5 SX17 -169.995 -39.998 4571 0.950 34.714 4.77 2.31 125.3 140 0.34 3.02 0.095

KH-04-5 SX17 -169.995 -39.998 4619 0.953 34.715 4.75 2.29 125.4 146 0.35 3.24 0.092KH-04-5 SX19 -170.003 -35.0038 2 19.589 35.214 5.33 0.14 0.0 0.06 25 0.09 1.37 0.009KH-04-5 SX19 -170.003 -35.0038 10 19.578 35.210 5.38 0.13 0.0 0.06 26 0.08 1.35 0.012KH-04-5 SX19 -170.003 -35.0038 20 19.539 35.207 5.33 0.13 0.0 0.06 22 0.09 1.33 0.011KH-04-5 SX19 -170.003 -35.0038 29 19.454 35.196 5.43 0.13 0.0 0.07 20 0.07 1.4 0.013KH-04-5 SX19 -170.003 -35.0038 50 17.411 35.123 5.67 0.14 0.0 0.10 25 0.09 1.38 0.012KH-04-5 SX19 -170.003 -35.0038 74 15.115 35.135 6.06 0.17 0.0 0.16 27 0.10 1.35 0.011KH-04-5 SX19 -170.003 -35.0038 100 13.889 35.138 5.76 0.30 0.0 0.33 21 0.08 1.45 0.029KH-04-5 SX19 -170.003 -35.0038 125 13.250 35.097 5.60 0.42 0.0 0.28KH-04-5 SX19 -170.003 -35.0038 149 12.851 35.122 5.32 0.58 1.1 0.14 30 0.10 1.65 0.044KH-04-5 SX19 -170.003 -35.0038 198 12.326 35.059 5.16 0.74 1.3 0.01 42 0.11 1.59 0.036KH-04-5 SX19 -170.003 -35.0038 298 9.924 34.722 4.95 1.17 4.1 35 0.13 1.93 0.053KH-04-5 SX19 -170.003 -35.0038 397 8.536 34.540 5.24 1.33 4.2KH-04-5 SX19 -170.003 -35.0038 496 7.738 34.465 5.42 1.44 5.1 41 0.15 2.01 0.058KH-04-5 SX19 -170.003 -35.0038 595 7.234 34.422 5.37 1.55 6.4KH-04-5 SX19 -170.003 -35.0038 793 6.397 34.385 5.05 1.78 12.9 49 0.18 2.51 0.057KH-04-5 SX19 -170.003 -35.0038 991 5.252 34.362 4.64 2.05 25.4 60 0.17 2.75 0.058KH-04-5 SX19 -170.003 -35.0038 1238 3.813 34.414 4.20 2.31 49.7KH-04-5 SX19 -170.003 -35.0038 1484 3.023 34.513 3.82 2.44 74.7 87 0.20 2.75 0.074KH-04-5 SX19 -170.003 -35.0038 1730 2.626 34.588 3.58 2.50 96.2KH-04-5 SX19 -170.003 -35.0038 1976 2.375 34.622 3.48 2.53 109.7 100 0.21 2.78 0.067KH-04-5 SX19 -170.003 -35.0038 2222 2.208 34.638 3.43 2.55 117.6KH-04-5 SX19 -170.003 -35.0038 2468 2.067 34.651 3.45 2.56 123.2 116 0.25 2.82 0.079KH-04-5 SX19 -170.003 -35.0038 2713 1.938 34.665 3.46 2.55 127.8KH-04-5 SX19 -170.003 -35.0038 2958 1.822 34.679 3.62 2.51 126.6 130 0.28 3.04 0.086KH-04-5 SX19 -170.003 -35.0038 3201 1.723 34.704 4.03 2.38 116.8KH-04-5 SX19 -170.003 -35.0038 3447 1.581 34.720 4.35 2.29 111.2 140 0.29 3.01 0.082KH-04-5 SX19 -170.003 -35.0038 3690 1.401 34.723 4.53 2.24 112.6KH-04-5 SX19 -170.003 -35.0038 3934 1.226 34.717 4.65 2.25 116.6 139 0.31 2.98 0.084KH-04-5 SX19 -170.003 -35.0038 4178 1.089 34.716 4.75 2.25 120.5KH-04-5 SX19 -170.003 -35.0038 4421 1.031 34.713 4.79 2.27 122.7 147 0.32 3.06 0.082KH-04-5 SX19 -170.003 -35.0038 4663 1.016 34.711 4.79 2.27 124.2KH-04-5 SX19 -170.003 -35.0038 4906 1.028 34.709 4.77 2.26 124.6 147 0.36 3.39 0.091KH-04-5 SX19 -170.003 -35.0038 5175 1.057 34.710 4.77 2.27 125.2 152 0.37 3.36 0.092KH-04-5 SX20 -170 -30.0005 2 23.751 35.696 4.90 0.02 0.0 0.12 19 0.06 1.44 0.015KH-04-5 SX20 -170 -30.0005 10 23.737 35.693 4.92 N.D. 0.0 0.12 19 0.07 1.35 0.017KH-04-5 SX20 -170 -30.0005 19 23.738 35.692 4.91 0.02 0.0 0.13 15 0.09 1.48 0.014KH-04-5 SX20 -170 -30.0005 30 23.736 35.692 4.93 0.01 0.0 0.14 20 0.09 1.38 0.016KH-04-5 SX20 -170 -30.0005 49 23.674 35.710 5.10 0.02 0.0 0.16 21 0.07 1.47 0.012KH-04-5 SX20 -170 -30.0005 72 19.769 35.668 5.48 0.06 0.0 0.22 22 0.07 1.45 0.012KH-04-5 SX20 -170 -30.0005 100 18.183 35.639 5.50 0.08 0.0 0.33 18 0.08 1.82 0.011KH-04-5 SX20 -170 -30.0005 125 17.372 35.604 5.25 0.13 0.0 0.29 21 0.08 1.89 0.012KH-04-5 SX20 -170 -30.0005 149 16.869 35.565 4.89 0.28 0.0 0.23 26 0.09 2.07 0.015KH-04-5 SX20 -170 -30.0005 201 16.041 35.475 4.72 0.42 0.0 0.05 30 0.08 1.78 0.027

KH-04-5 SX20 -170 -30.0005 295 14.157 35.225 4.61 0.67 1.6 31 0.10 2.45 0.024KH-04-5 SX20 -170 -30.0005 399 10.720 34.762 4.60 1.13 3.2KH-04-5 SX20 -170 -30.0005 497 8.796 34.578 4.90 1.35 4.6 52 0.13 2.35 0.037KH-04-5 SX20 -170 -30.0005 598 7.445 34.445 5.19 1.52 6.0KH-04-5 SX20 -170 -30.0005 796 6.272 34.359 5.16 1.75 11.0 47 0.15 2.71 0.057KH-04-5 SX20 -170 -30.0005 991 4.986 34.342 4.65 2.08 25.4 55 0.18 2.47 0.049KH-04-5 SX20 -170 -30.0005 1237 3.664 34.411 4.15 2.36 50.8KH-04-5 SX20 -170 -30.0005 1484 2.882 34.527 3.79 2.47 78.5 85 0.22 2.37 0.069KH-04-5 SX20 -170 -30.0005 1731 2.482 34.596 3.57 2.51 101.3KH-04-5 SX20 -170 -30.0005 1977 2.259 34.627 3.41 2.57 114.1 106 0.22 2.68 0.068KH-04-5 SX20 -170 -30.0005 2223 2.111 34.645 3.36 2.59 121.6KH-04-5 SX20 -170 -30.0005 2469 2.000 34.651 3.37 2.59 126.3 128 0.26 2.86 0.064KH-04-5 SX20 -170 -30.0005 2714 1.894 34.663 3.41 2.59 129.9KH-04-5 SX20 -170 -30.0005 2959 1.769 34.674 3.50 2.55 131.9 130 0.29 2.96 0.078KH-04-5 SX20 -170 -30.0005 3203 1.659 34.697 3.97 2.41 121.1KH-04-5 SX20 -170 -30.0005 3448 1.533 34.712 4.31 2.30 113.2 134 0.30 3.03 0.088KH-04-5 SX20 -170 -30.0005 3691 1.371 34.719 4.53 2.25 112.7KH-04-5 SX20 -170 -30.0005 3935 1.215 34.718 4.64 2.25 116.2 135 0.32 2.78 0.092KH-04-5 SX20 -170 -30.0005 4180 1.100 34.715 4.69 2.26 119.5KH-04-5 SX20 -170 -30.0005 4472 1.028 34.711 4.73 2.27 121.7 143 0.35 3.5 0.098KH-04-5 SX20 -170 -30.0005 4665 1.022 34.708 4.75 2.26 122.6KH-04-5 SX20 -170 -30.0005 4908 1.031 34.708 4.75 2.27 123.7 151 0.36 3.36 0.108KH-04-5 SX20 -170 -30.0005 5150 1.055 34.708 4.77 2.27 124.2KH-04-5 SX20 -170 -30.0005 5390 1.085 34.706 4.76 2.26 124.4 155 0.38 3.28 0.11KH-04-5 SX21 -169.999 -25.0003 2 26.190 35.189 4.64 0.02 0.0 0.11 14 0.09 1.45 0.012KH-04-5 SX21 -169.999 -25.0003 12 26.183 35.178 4.65 N.D. 0.0 0.12 15 0.10 1.36 0.015KH-04-5 SX21 -169.999 -25.0003 20 26.161 35.182 4.65 N.D. 0.0 0.12 18 0.08 1.42 0.021KH-04-5 SX21 -169.999 -25.0003 31 25.830 35.272 4.75 N.D. 0.0 0.14 21 0.09 1.37 0.01KH-04-5 SX21 -169.999 -25.0003 50 23.374 35.485 5.02 0.04 0.0 0.15 17 0.08 1.45 0.011KH-04-5 SX21 -169.999 -25.0003 76 22.047 35.574 4.80 0.06 0.0 0.18 12 0.10 1.59 0.027KH-04-5 SX21 -169.999 -25.0003 101 21.469 35.600 4.72 0.09 0.0 0.16 19 0.08 1.75 0.034KH-04-5 SX21 -169.999 -25.0003 125 20.683 35.633 4.67 0.13 0.0 0.06KH-04-5 SX21 -169.999 -25.0003 151 19.976 35.633 4.31 0.24 0.0 0.04 18 0.10 1.62 0.015KH-04-5 SX21 -169.999 -25.0003 199 18.731 35.601 4.39 0.31 0.0 0.01 37 0.11 2.08 0.04KH-04-5 SX21 -169.999 -25.0003 300 16.294 35.408 4.49 0.45 0.0 45 0.11 1.83 0.041KH-04-5 SX21 -169.999 -25.0003 397 12.949 35.000 4.47 0.87 1.6KH-04-5 SX21 -169.999 -25.0003 496 10.346 34.709 4.56 1.22 3.6 37 0.12 2.21 0.052KH-04-5 SX21 -169.999 -25.0003 595 7.996 34.470 5.07 1.47 5.0KH-04-5 SX21 -169.999 -25.0003 794 5.881 34.329 5.01 1.86 13.5 50 0.15 2.33 0.064KH-04-5 SX21 -169.999 -25.0003 991 4.748 34.363 4.21 2.24 33.4 63 0.19 2.21 0.063KH-04-5 SX21 -169.999 -25.0003 1238 3.362 34.459 3.84 2.44 65.1KH-04-5 SX21 -169.999 -25.0003 1485 2.644 34.571 3.57 2.50 92.8 88 0.21 2.29 0.077KH-04-5 SX21 -169.999 -25.0003 1733 2.419 34.604 3.41 2.55 108.4KH-04-5 SX21 -169.999 -25.0003 1977 2.257 34.627 3.37 2.58 117.5 115 0.25 2.58 0.073

KH-04-5 SX21 -169.999 -25.0003 2223 2.100 34.645 3.34 2.59 123.2KH-04-5 SX21 -169.999 -25.0003 2469 1.962 34.655 3.38 2.59 128.8 118 0.27 3.03 0.084KH-04-5 SX21 -169.999 -25.0003 2715 1.865 34.672 3.42 2.59 132.7KH-04-5 SX21 -169.999 -25.0003 2960 1.747 34.674 3.45 2.58 135.1 130 0.30 2.8 0.074KH-04-5 SX21 -169.999 -25.0003 3203 1.638 34.687 3.71 2.49 130.5KH-04-5 SX21 -169.999 -25.0003 3449 1.536 34.707 4.17 2.37 118.0 122 0.29 3.35 0.076KH-04-5 SX21 -169.999 -25.0003 3693 1.418 34.718 4.44 2.28 113.5KH-04-5 SX21 -169.999 -25.0003 3937 1.279 34.722 4.62 2.26 114.4 132 0.31 2.89 0.091KH-04-5 SX21 -169.999 -25.0003 4180 1.155 34.720 4.66 2.27 118.1KH-04-5 SX21 -169.999 -25.0003 4360 1.084 34.714 4.76 2.27 119.8 137 0.33 3.34 0.083KH-04-5 SX21 -169.999 -25.0003 4667 1.054 34.705 4.76 2.28 121.2KH-04-5 SX21 -169.999 -25.0003 4911 1.053 34.711 4.77 2.28 122.0 140 0.37 3.41 0.094KH-04-5 SX21 -169.999 -25.0003 5152 1.067 34.703 4.76 2.28 122.9KH-04-5 SX21 -169.999 -25.0003 5395 1.093 No Data 4.75 2.27 123.1 152 0.39 3.38 0.094KH-04-5 SX21 -169.999 -25.0003 5594 1.118 34.710 4.73 2.27 123.2 158 0.39 3.25 0.097KH-04-5 SX22 -170 -20 2 28.554 35.132 4.49 0.09 0.0 0.09 19 0.13 1.46 0.017KH-04-5 SX22 -170 -20 11 28.528 35.131 4.55 0.10 0.0 0.09 25 0.12 1.35 0.019KH-04-5 SX22 -170 -20 21 28.435 35.149 4.53 0.09 0.0 0.12 21 0.13 1.39 0.02KH-04-5 SX22 -170 -20 31 28.445 35.231 4.51 0.10 0.0 0.08 22 0.12 1.45 0.021KH-04-5 SX22 -170 -20 52 26.707 35.419 4.85 0.08 0.0 0.13 19 0.13 1.62 0.023KH-04-5 SX22 -170 -20 76 25.877 35.558 4.62 0.13 0.0 0.16 20 0.13 1.73 0.019KH-04-5 SX22 -170 -20 100 24.501 35.523 4.61 0.11 0.0 0.26 18 0.12 2.1 0.015KH-04-5 SX22 -170 -20 125 23.643 35.598 4.41 0.17 0.0 0.19KH-04-5 SX22 -170 -20 150 22.655 35.620 4.12 0.20 0.0 0.06 21 0.13 1.78 0.03KH-04-5 SX22 -170 -20 199 21.075 35.648 4.22 0.25 0.0 0.02 31 0.12 1.69 0.034KH-04-5 SX22 -170 -20 298 17.657 35.460 4.18 0.49 0.0 45 0.13 2.16 0.042KH-04-5 SX22 -170 -20 397 13.474 34.988 4.19 0.94 2.4KH-04-5 SX22 -170 -20 497 9.437 34.594 4.36 1.45 6.1 39 0.15 2.31 0.055KH-04-5 SX22 -170 -20 596 7.313 34.413 4.84 1.67 8.4KH-04-5 SX22 -170 -20 793 5.398 34.374 4.18 2.16 26.9 51 0.17 2.68 0.059KH-04-5 SX22 -170 -20 991 3.949 34.434 3.76 2.42 54.5 69 0.21 2.62 0.071KH-04-5 SX22 -170 -20 1239 3.002 34.523 3.63 2.50 80.5KH-04-5 SX22 -170 -20 1486 2.590 34.590 3.42 2.56 101.4 83 0.23 2.58 0.085KH-04-5 SX22 -170 -20 1732 2.395 34.617 3.35 2.58 112.0KH-04-5 SX22 -170 -20 1978 2.209 34.635 3.33 2.58 119.0 105 0.27 2.83 0.081KH-04-5 SX22 -170 -20 2225 2.066 34.646 3.35 2.59 124.1KH-04-5 SX22 -170 -20 2470 1.947 34.656 3.35 2.60 129.1 116 0.28 2.67 0.078KH-04-5 SX22 -170 -20 2715 1.834 34.661 3.37 2.59 133.1KH-04-5 SX22 -170 -20 2960 1.740 34.673 3.43 2.58 135.4 123 0.30 3.05 0.085KH-04-5 SX22 -170 -20 3206 1.629 34.682 3.58 2.54 134.9KH-04-5 SX22 -170 -20 3451 1.531 34.695 3.91 2.44 127.6 134 0.30 3.23 0.086KH-04-5 SX22 -170 -20 3694 1.398 34.715 4.40 2.30 115.5KH-04-5 SX22 -170 -20 3939 1.232 34.719 4.63 2.26 115.0 147 0.33 2.95 0.097KH-04-5 SX22 -170 -20 4181 1.114 34.715 4.70 2.26 118.1

KH-04-5 SX22 -170 -20 4426 1.050 34.713 4.73 2.24 120.8 145 0.34 3.39 0.1KH-04-5 SX22 -170 -20 4669 1.025 34.711 4.75 2.27 122.6KH-04-5 SX22 -170 -20 4912 1.038 34.705 4.70 2.28 123.0 155 0.38 3.32 0.104KH-04-5 SX22 -170 -20 5287 1.077 34.710 4.75 2.27 123.7 162 0.38 3.38 0.105KH-04-5 SX24 -169.997 -14.9948 1 29.422 35.567 4.41 0.16 0.0 0.02 34 0.14 1.44 0.023KH-04-5 SX24 -169.997 -14.9948 4 29.405 0.31 0.0 29 0.13 1.47 0.019KH-04-5 SX24 -169.997 -14.9948 10 10.349 25 0.16 1.51 0.027KH-04-5 SX24 -169.997 -14.9948 30 29.076 35.557 4.42 0.16 0.0 0.03 33 0.15 1.39 0.025KH-04-5 SX24 -169.997 -14.9948 50 27.539 35.556 4.40 0.11 0.0 0.03 30 0.13 1.35 0.031KH-04-5 SX24 -169.997 -14.9948 51 27.462 35.565 4.45 0.16 0.0 0.03KH-04-5 SX24 -169.997 -14.9948 100 25.430 ?35.800 4.68 0.15 0.0 0.05KH-04-5 SX24 -169.997 -14.9948 100 25.424 35.721 4.73 0.15 0.0 0.06 31 0.13 1.48 0.028KH-04-5 SX24 -169.997 -14.9948 133 23.886 35.749 4.58 0.15 0.0 0.09KH-04-5 SX24 -169.997 -14.9948 150 22.920 35.895 4.25 0.21 0.0 0.13 28 0.12 1.72 0.037KH-04-5 SX24 -169.997 -14.9948 200 20.317 35.923 3.82 0.39 0.0 0.10KH-04-5 SX24 -169.997 -14.9948 298 14.990 35.748 3.95 0.51 0.0 0.01KH-04-5 SX24 -169.997 -14.9948 398 10.275 35.128 3.94 0.87 2.6 41 0.15 1.86 0.044KH-04-5 SX24 -169.997 -14.9948 447 8.772 34.661 2.96 1.80 13.4KH-04-5 SX24 -169.997 -14.9948 496 7.877 34.528 3.31 2.03 22.2 48 0.16 2.1 0.042KH-04-5 SX24 -169.997 -14.9948 598 6.236 34.454 3.69 2.15 29.5KH-04-5 SX24 -169.997 -14.9948 794 4.991 34.472 3.37 2.40 50.7 54 0.18 2.4 0.049KH-04-5 SX24 -169.997 -14.9948 992 4.030 ?34.710 4.70 2.26 121.7 77 0.21 2.35 0.062KH-04-5 SX24 -169.997 -14.9948 1238 3.296 34.558 3.10 2.62 90.2KH-04-5 SX24 -169.997 -14.9948 1486 2.785 34.589 3.19 2.60 101.8 89 0.26 2.76 0.069KH-04-5 SX24 -169.997 -14.9948 1733 2.389 34.617 3.31 2.57 111.5KH-04-5 SX24 -169.997 -14.9948 1979 2.140KH-04-5 SX24 -169.997 -14.9948 1978 2.140 34.637 3.36 2.58 119.4 112 0.27 2.99 0.068KH-04-5 SX24 -169.997 -14.9948 2225 1.965 34.652 3.39 2.56 125.1KH-04-5 SX24 -169.997 -14.9948 2471 1.844 34.664 3.41 2.56 129.7 125 0.31 3.16 0.074KH-04-5 SX24 -169.997 -14.9948 2715 1.760 34.671 3.52 2.54 131.8KH-04-5 SX24 -169.997 -14.9948 2961 1.678 34.677 3.58 2.53 133.6 134 0.31 3.16 0.073KH-04-5 SX24 -169.997 -14.9948 3205 1.609 34.681 3.67 2.51 133.9KH-04-5 SX24 -169.997 -14.9948 3450 1.530 34.682 3.75 2.49 133.2 146 0.34 3.03 0.082KH-04-5 SX24 -169.997 -14.9948 3695 1.413 34.704 4.13 2.37 124.5KH-04-5 SX24 -169.997 -14.9948 3939 1.242 34.715 4.54 2.27 116.8 156 0.37 3.3 0.086KH-04-5 SX24 -169.997 -14.9948 4183 1.088 34.715 4.66 2.25 119.7KH-04-5 SX24 -169.997 -14.9948 4426 1.031 34.710 4.71 2.26 121.8KH-04-5 SX24 -169.997 -14.9948 4670 1.039 34.704 4.71 2.27 122.6KH-04-5 SX24 -169.997 -14.9948 4764 1.045 34.711 4.71 2.27 122.9 164 0.38 3.31 0.092KH-04-5 SX24 -169.997 -14.9948 4812 1.050 34.711 4.72 2.27 122.8 170 0.39 3.47 0.098KH-04-5 SX25 -169.997 -10.0007 3 29.159 35.253 4.45 0.16 0.0 0.05 19 0.12 1.52 0.039KH-04-5 SX25 -169.997 -10.0007 10 29.160 35.245 4.47 0.16 0.0 0.06 18 0.13 1.52 0.026KH-04-5 SX25 -169.997 -10.0007 21 29.165 35.245 4.46 0.16 0.0 0.05 22 0.12 1.44 0.028KH-04-5 SX25 -169.997 -10.0007 31 29.166 35.260 4.45 0.16 0.0 0.06 25 0.11 1.36 0.037

KH-04-5 SX25 -169.997 -10.0007 50 28.387 35.945 4.26 0.27 0.0 0.20 20 0.10 1.56 0.023KH-04-5 SX25 -169.997 -10.0007 75 27.258 36.246 4.08 0.31 0.0 0.21 19 0.09 1.38 0.029KH-04-5 SX25 -169.997 -10.0007 99 26.040 36.362 3.67 0.49 0.0 0.18 28 0.10 1.82 0.036KH-04-5 SX25 -169.997 -10.0007 124 24.387 36.331 3.42 0.63 0.0 0.11KH-04-5 SX25 -169.997 -10.0007 149 22.779 36.162 3.46 0.65 0.0 0.06 36 0.11 2.03 0.032KH-04-5 SX25 -169.997 -10.0007 199 18.945 35.653 3.19 0.91 2.3 0.01 33 0.13 2.32 0.029KH-04-5 SX25 -169.997 -10.0007 299 12.731 34.912 2.35 1.72 12.5 42 0.13 2.44 0.043KH-04-5 SX25 -169.997 -10.0007 498 7.797 34.586 2.84 2.19 28.6 50 0.16 2.59 0.055KH-04-5 SX25 -169.997 -10.0007 596 6.619 34.531 2.79 2.38 38.4KH-04-5 SX25 -169.997 -10.0007 796 5.210 34.523 2.41 2.70 59.1 69 0.18 2.73 0.068KH-04-5 SX25 -169.997 -10.0007 993 4.308 34.529 2.68 2.70 75.4 86 0.22 2.43 0.069KH-04-5 SX25 -169.997 -10.0007 1239 3.554 34.562 2.80 2.72 92.7KH-04-5 SX25 -169.997 -10.0007 1487 3.004 34.587 2.94 2.68 105.3 111 0.25 2.93 0.082KH-04-5 SX25 -169.997 -10.0007 1734 2.554 34.606 3.21 2.61 111.2KH-04-5 SX25 -169.997 -10.0007 1981 2.213 34.630 3.24 2.62 122.1 131 0.26 3.14 0.074KH-04-5 SX25 -169.997 -10.0007 2225 2.021 34.650 3.22 2.63 130.5KH-04-5 SX25 -169.997 -10.0007 2473 1.884 34.658 3.22 2.62 135.5 141 0.28 2.97 0.092KH-04-5 SX25 -169.997 -10.0007 2717 1.772 34.666 3.32 2.60 137.9KH-04-5 SX25 -169.997 -10.0007 2961 1.685 34.674 3.43 2.58 137.6 157 0.31 2.86 0.083KH-04-5 SX25 -169.997 -10.0007 3206 1.626 34.678 3.56 2.54 137.5KH-04-5 SX25 -169.997 -10.0007 3452 1.565 34.684 3.67 2.52 136.8 166 0.30 3.37 0.092KH-04-5 SX25 -169.997 -10.0007 3696 1.539 34.686 3.73 2.51 136.8KH-04-5 SX25 -169.997 -10.0007 3940 1.442 34.693 3.92 2.45 133.5 169 0.36 3.27 0.089KH-04-5 SX25 -169.997 -10.0007 4184 1.229 34.710 4.51 2.30 120.4KH-04-5 SX25 -169.997 -10.0007 4428 1.096 34.708 4.71 2.27 120.1 177 0.36 3.61 0.098KH-04-5 SX25 -169.997 -10.0007 4670 1.066 34.711 4.73 2.27 121.2KH-04-5 SX25 -169.997 -10.0007 4915 1.087 34.710 4.73 2.27 121.8 175 0.40 3.58 0.102KH-04-5 SX25 -169.997 -10.0007 4991 1.092 34.711 4.74 2.27 121.7 178 0.39 3.64 0.118KH-04-5 SX25 -169.997 -10.0007 5039 1.097 34.704 4.73 2.28 121.2KH-04-5 SX26 -170.011 -4.911 2 29.050 34.433 4.49 0.19 0.0 0.11 30 0.15 1.68 0.025KH-04-5 SX26 -170.011 -4.911 10 29.060 34.451 4.45 0.18 0.0 0.11 28 0.13 1.45 0.022KH-04-5 SX26 -170.011 -4.911 20 29.245 34.647 4.46 0.18 0.0 0.11 26 0.13 1.58 0.023KH-04-5 SX26 -170.011 -4.911 30 29.334 34.767 4.54 0.17 0.0 0.12 31 0.14 1.45 0.017KH-04-5 SX26 -170.011 -4.911 51 29.258 34.759 4.49 0.18 0.0 0.15 28 0.13 1.36 0.026KH-04-5 SX26 -170.011 -4.911 76 29.243 34.782 4.43 0.18 0.0 0.20 36 0.12 1.59 0.022KH-04-5 SX26 -170.011 -4.911 100 29.515 35.155 4.16 0.24 0.0 0.13 29 0.11 1.73 0.039KH-04-5 SX26 -170.011 -4.911 124 28.987 35.572 4.39 0.44 0.0 0.22KH-04-5 SX26 -170.011 -4.911 150 28.167 35.786 3.73 0.56 0.0 0.10 32 0.13 1.86 0.045KH-04-5 SX26 -170.011 -4.911 199 20.865 35.918 3.18 0.83 1.1 0.02 39 0.11 1.95 0.06KH-04-5 SX26 -170.011 -4.911 299 12.054 34.910 1.85 1.96 17.7 45 0.15 2.29 0.068KH-04-5 SX26 -170.011 -4.911 398 9.962 34.738 2.05 2.12 24.1KH-04-5 SX26 -170.011 -4.911 497 8.907 34.669 1.82 2.35 29.5 61 0.17 2.25 0.085KH-04-5 SX26 -170.011 -4.911 596 7.709 34.605 1.47 2.66 39.6KH-04-5 SX26 -170.011 -4.911 795 6.108 34.543 2.18 2.66 49.9 69 0.21 2.63 0.083

KH-04-5 SX26 -170.011 -4.911 992 4.756 2.08 2.86 74.7 79 0.23 2.93 0.077KH-04-5 SX26 -170.011 -4.911 1242 3.773 34.569 2.32 2.85 96.2KH-04-5 SX26 -170.011 -4.911 1487 3.022 34.592 2.64 2.77 111.4 108 0.25 2.53 0.082KH-04-5 SX26 -170.011 -4.911 1735 2.538 34.618 2.89 2.72 121.9KH-04-5 SX26 -170.011 -4.911 1980 2.199 34.638 2.91 2.71 132.9 125 0.28 3.07 0.08KH-04-5 SX26 -170.011 -4.911 2226 2.009 34.649 2.86 2.72 141.0KH-04-5 SX26 -170.011 -4.911 2471 1.874 34.660 3.05 2.68 141.7 135 0.28 2.98 0.091KH-04-5 SX26 -170.011 -4.911 2717 1.763 34.667 3.25 2.64 141.7KH-04-5 SX26 -170.011 -4.911 2962 1.685 34.673 3.31 2.60 142.6 150 0.31 3.15 0.091KH-04-5 SX26 -170.011 -4.911 3207 1.578 34.675 3.50 2.56 141.3KH-04-5 SX26 -170.011 -4.911 3452 1.497 34.687 3.73 2.52 139.9KH-04-5 SX26 -170.011 -4.911 3696 1.451 34.685 3.78 2.49 139.6KH-04-5 SX26 -170.011 -4.911 3940 1.397 34.692 3.93 2.47 138.9KH-04-5 SX26 -170.011 -4.911 4185 1.343 34.688 4.07 2.43 135.2KH-04-5 SX26 -170.011 -4.911 4427 1.282 34.702 4.26 2.38 131.3 175 0.37 3.56 0.107KH-04-5 SX26 -170.011 -4.911 4671 1.202 34.701 4.49 2.33 125.1KH-04-5 SX26 -170.011 -4.911 4914 1.205 34.705 4.57 2.31 124.2 181 0.40 3.49 0.11KH-04-5 SX26 -170.011 -4.911 5159 1.229 34.707 4.58 2.31 124.5 187 0.41 3.57 0.112KH-04-5 SX26 -170.011 -4.911 5345 1.254 34.707 4.59 2.31 124.8KH-04-5 SX26 -170.011 -4.911 5407 1.262 34.706 4.57 2.31 125.0KH-04-5 SX27 -170.01 0.0865 2 28.491 36.367 4.52 0.38 0.0 0.20 16 0.10 1.54 0.021KH-04-5 SX27 -170.01 0.0865 3 28.491KH-04-5 SX27 -170.01 0.0865 11 28.526 35.330 4.54 0.36 0.0 0.27 22 0.08 1.62 0.019KH-04-5 SX27 -170.01 0.0865 19 28.490 35.351 4.54 0.36 0.0 0.27 20 0.10 1.47 0.022KH-04-5 SX27 -170.01 0.0865 32 28.482 35.374 4.51 0.37 0.0 0.32 23 0.10 1.76 0.012KH-04-5 SX27 -170.01 0.0865 49 28.372 35.384 4.54 0.39 0.0 0.34 18 0.09 1.34 0.022KH-04-5 SX27 -170.01 0.0865 54 28.235 0.42 0.0KH-04-5 SX27 -170.01 0.0865 75 28.070 35.419 4.37 0.48 0.0 0.22 23 0.10 1.92 0.032KH-04-5 SX27 -170.01 0.0865 99 27.739 35.344 4.36 0.48 0.0 0.17 32 0.13 1.7 0.031KH-04-5 SX27 -170.01 0.0865 124 27.537 35.382 4.41 0.50 0.0 0.10KH-04-5 SX27 -170.01 0.0865 149 26.105 35.402 3.72 0.65 1.0 0.03 39 0.12 2.14 0.027KH-04-5 SX27 -170.01 0.0865 199 15.599 35.081 3.14 1.17 10.1 0.01KH-04-5 SX27 -170.01 0.0865 298 12.216 34.881 2.37 1.75 18.4 51 0.13 2.22 0.053KH-04-5 SX27 -170.01 0.0865 398 10.307 34.746 2.61 2.22 27.0KH-04-5 SX27 -170.01 0.0865 498 8.227 34.612 1.96 2.38 35.7 70 0.16 2.6 0.074KH-04-5 SX27 -170.01 0.0865 595 6.916 34.576 1.88 2.78 50.0KH-04-5 SX27 -170.01 0.0865 794 5.605 34.543 1.88 2.81 65.0 88 0.21 2.56 0.087KH-04-5 SX27 -170.01 0.0865 992 4.473 34.553 3.42 2.83 85.9 100 0.23 2.68 0.093KH-04-5 SX27 -170.01 0.0865 1240 3.541 34.583 2.15 2.89 108.1KH-04-5 SX27 -170.01 0.0865 1486 3.002 34.600 2.20 2.91 122.7 109 0.27 2.86 0.089KH-04-5 SX27 -170.01 0.0865 1733 2.556 34.620 2.39 2.86 133.5KH-04-5 SX27 -170.01 0.0865 1980 2.204 34.639 2.59 2.81 141.1KH-04-5 SX27 -170.01 0.0865 2226 2.001 34.653 2.75 2.77 144.8KH-04-5 SX27 -170.01 0.0865 2470 1.818 34.661 2.90 2.71 148.4

KH-04-5 SX27 -170.01 0.0865 2717 1.737 34.664 3.05 2.69 148.2KH-04-5 SX27 -170.01 0.0865 2962 1.654 34.673 3.16 2.64 147.1 145 0.34 3.19 0.089KH-04-5 SX27 -170.01 0.0865 3207 1.554 34.680 3.38 2.60 147.0KH-04-5 SX27 -170.01 0.0865 3452 1.505 34.680 3.51 2.57 144.9 153 0.32 3.25 0.089KH-04-5 SX27 -170.01 0.0865 3697 1.460 34.688 3.64 2.54 143.3KH-04-5 SX27 -170.01 0.0865 3941 1.382 34.694 3.87 2.49 139.5 161 0.37 3.38 0.091KH-04-5 SX27 -170.01 0.0865 4185 1.309 34.698 4.08 2.43 135.5KH-04-5 SX27 -170.01 0.0865 4429 1.267 34.702 4.27 2.39 131.0KH-04-5 SX27 -170.01 0.0865 4673 1.244 34.704 4.37 2.36 128.4KH-04-5 SX27 -170.01 0.0865 4915 1.256 34.705 4.40 2.35 128.5 195 0.40 3.47 0.096KH-04-5 SX27 -170.01 0.0865 5451 1.321 34.706 4.44 2.35 127.5 199 0.43 3.71 0.098KH-04-5 SX27 -170.01 0.0865 5499 1.328 34.705 4.42 2.34 127.8KH-04-5 SX28 -170 5.1035 3 28.700 34.709 4.43 0.19 0.0 0.23 10 0.07 1.52 0.017KH-04-5 SX28 -170 5.1035 11 28.749 34.724 4.38 0.19 0.0 0.24 11 0.08 1.54 0.028KH-04-5 SX28 -170 5.1035 20 28.779 34.760 4.41 0.18 0.0 0.22KH-04-5 SX28 -170 5.1035 30 28.798 34.776 4.39 0.18 0.0 0.22 14 0.08 1.45 0.018KH-04-5 SX28 -170 5.1035 51 28.811 34.805 4.37 0.17 0.0 0.23 9 0.06 1.37 0.023KH-04-5 SX28 -170 5.1035 76 28.808 34.820 4.28 0.20 0.0 0.21 16 0.09 1.16 0.027KH-04-5 SX28 -170 5.1035 78 28.808 0.20 0.0KH-04-5 SX28 -170 5.1035 99 27.201 34.765 3.49 0.41 1.9 0.08 14 0.06 1.44 0.038KH-04-5 SX28 -170 5.1035 151 20.881 34.885 3.11 0.70 5.4 0.03 11 0.10 1.46 0.054KH-04-5 SX28 -170 5.1035 200 13.809 ?34.592 1.79 1.71 18.5 0.01 20 0.12 1.67 0.057KH-04-5 SX28 -170 5.1035 299 11.146 34.651 1.49 2.29 32.8KH-04-5 SX28 -170 5.1035 495 8.168 34.543 1.15 2.86 52.7 66 0.13 2.31 0.063KH-04-5 SX28 -170 5.1035 793 5.546 34.544 1.15 3.00 74.2KH-04-5 SX28 -170 5.1035 993 4.635 34.551 1.43 3.03 90.2 108 0.19 2.63 0.071KH-04-5 SX28 -170 5.1035 1239 3.736 34.571 1.60 3.02 110.6KH-04-5 SX28 -170 5.1035 1487 3.130 34.575 1.87 2.97 124.4 162 0.25 2.48 0.077KH-04-5 SX28 -170 5.1035 1734 2.619 ?34.617 2.16 2.88 135.3KH-04-5 SX28 -170 5.1035 1979 2.289 34.619 2.30 2.86 143.6 173 0.29 2.88 0.072KH-04-5 SX28 -170 5.1035 2225 2.008 34.634 2.55 2.79 149.8KH-04-5 SX28 -170 5.1035 2470 1.870 34.648 2.65 2.75 152.1 191 0.30 3.23 0.077KH-04-5 SX28 -170 5.1035 2714 1.774 ?34.640 2.81 2.74 153.7KH-04-5 SX28 -170 5.1035 2962 1.673 34.665 2.99 2.67 151.3 195 0.33 3.27 0.077KH-04-5 SX28 -170 5.1035 3208 1.594 34.667 3.15 2.62 149.9KH-04-5 SX28 -170 5.1035 3452 1.531 34.667 3.38 2.59 148.7 198 0.30 3.42 0.08KH-04-5 SX28 -170 5.1035 3695 1.476 34.683 3.48 2.57 145.9KH-04-5 SX28 -170 5.1035 3942 1.381 34.690 3.76 2.50 141.6 205 0.30 3.29 0.078KH-04-5 SX28 -170 5.1035 4185 1.325 34.695 3.94 2.45 137.5KH-04-5 SX28 -170 5.1035 4429 1.265 34.697 4.14 2.39 132.6 206 0.33 3.48 0.075KH-04-5 SX28 -170 5.1035 4672 1.256 ?34.684 4.25 2.37 130.6KH-04-5 SX28 -170 5.1035 4914 1.273 34.697 4.27 2.36 129.8 203 0.36 3.46 0.08KH-04-5 SX28 -170 5.1035 5158 1.295 ?34.687 4.32 2.36 129.3KH-04-5 SX28 -170 5.1035 5400 1.323 34.703 4.31 2.35 128.8 205 0.37 3.6 0.089

KH-04-5 SX28 -170 5.1035 5619 1.352 34.682 4.30 2.36 129.2KH-04-5 SX28 -170 5.1035 5668 1.359 34.705 4.30 2.36 128.7 207 0.39 3.65 0.099KH-05-2 ST01 -160.287 -10.1603 0 29.000 35.667 4.49 <0.2 0.07KH-05-2 ST01 -160.287 -10.1603 5 28.952 35.662 4.48 <0.2 0.07KH-05-2 ST01 -160.287 -10.1603 11 28.973 35.662 4.48 <0.2 0.07 18 0.08 1.52 0.027KH-05-2 ST01 -160.287 -10.1603 20 28.866 35.660 4.47 <0.2 0.07 12 0.07 1.49 0.021KH-05-2 ST01 -160.287 -10.1603 30 28.856 35.659 4.49 <0.2 0.08 11 0.08 1.48 0.021KH-05-2 ST01 -160.287 -10.1603 42 28.853 35.659 4.47 <0.2 0.08KH-05-2 ST01 -160.287 -10.1603 51 28.852 35.662 4.47 <0.2 0.08 20 0.11 1.58 0.026KH-05-2 ST01 -160.287 -10.1603 75 28.851 35.663 4.50 <02 0.09 19 0.13 1.67 0.034KH-05-2 ST01 -160.287 -10.1603 100 28.816 35.674 4.48 <0.2 0.14 17 0.15 1.77 0.052KH-05-2 ST01 -160.287 -10.1603 148 25.497 36.383 3.80 <0.2 0.13 24 0.17 1.98 0.049KH-05-2 ST01 -160.287 -10.1603 200 22.834 36.175 3.64 0.3 0.04 27 0.15 2.16 0.066KH-05-2 ST01 -160.287 -10.1603 248 17.575 35.395 3.40 2.7 NDKH-05-2 ST01 -160.287 -10.1603 298 13.759 34.942 2.62 8.9 ND 29 0.19 2.2 0.076KH-05-2 ST01 -160.287 -10.1603 398 9.513 34.670 2.28 24.2KH-05-2 ST01 -160.287 -10.1603 498 7.668 34.584 2.58 33.6 51 0.19 2.6 0.084KH-05-2 ST01 -160.287 -10.1603 596 6.808 34.551 2.34 42.7KH-05-2 ST01 -160.287 -10.1603 793 5.506 34.525 2.18 61.7 62 0.23 2.9 0.1KH-05-2 ST01 -160.287 -10.1603 992 4.322 34.540 2.43 84.5 70 0.25 2.94 0.101KH-05-2 ST01 -160.287 -10.1603 1470 2.964 34.583 2.86 117.0 99 0.30 2.85 0.09KH-05-2 ST01 -160.287 -10.1603 1980 2.176 34.630 3.40 128.0 120 0.31 3.22 0.085KH-05-2 ST01 -160.287 -10.1603 2472 1.859 34.660 3.51 140.0 145 0.35 2.94 0.087KH-05-2 ST01 -160.287 -10.1603 2962 1.645 34.675 3.65 144.0 148 0.37 3.17 0.09KH-05-2 ST01 -160.287 -10.1603 3453 1.526 34.688 3.93 141.0 159 0.38 3.28 0.085KH-05-2 ST01 -160.287 -10.1603 3940 1.378 34.690 4.20 137.0 171 0.37 2.89 0.096KH-05-2 ST01 -160.287 -10.1603 4425 1.263 4.51 133.0 170 0.39 3.28 0.108KH-05-2 ST01 -160.287 -10.1603 4689 1.279 34.701 4.49 132.0 173 0.40 3.37 0.102KH-05-2 ST01 -160.287 -10.1603 4691 1.279 4.52 132.0KH-05-2 ST03 -160.224 0.00633 0 27.500 35.458 4.41 1.2 0.34KH-05-2 ST03 -160.224 0.00633 4 27.263 35.449 4.41 1.2 0.34KH-05-2 ST03 -160.224 0.00633 9 27.268 35.446 4.40 1.1 0.33 12 0.11 1.62 0.031KH-05-2 ST03 -160.224 0.00633 20 27.271 35.447 4.39 1.2 0.34 10 0.10 1.59 0.024KH-05-2 ST03 -160.224 0.00633 29 27.254 35.444 4.37 1.1 0.14 17 0.09 1.55 0.028KH-05-2 ST03 -160.224 0.00633 39 27.200 35.435 4.33 1.0 0.34KH-05-2 ST03 -160.224 0.00633 50 27.133 35.420 4.24 1.1 0.32 12 0.11 1.79 0.026KH-05-2 ST03 -160.224 0.00633 75 26.744 35.390 4.02 1.5 0.24 20 0.11 1.88 0.037KH-05-2 ST03 -160.224 0.00633 100 24.631 35.470 3.15 2.8 0.06 28 0.13 1.92 0.033KH-05-2 ST03 -160.224 0.00633 149 20.571 5.0 0.02 32 0.12 1.86 0.052KH-05-2 ST03 -160.224 0.00633 199 14.713 35.039 3.00 11.9 40 0.15 2.04 0.067KH-05-2 ST03 -160.224 0.00633 249 12.622 34.901 2.65 16.8KH-05-2 ST03 -160.224 0.00633 299 11.467 34.827 1.48 23.4 59 0.17 2.32 0.079KH-05-2 ST03 -160.224 0.00633 398 9.865 34.705 1.25 30.7KH-05-2 ST03 -160.224 0.00633 497 8.166 34.624 1.12 40.2 67 0.19 2.47 0.076

KH-05-2 ST03 -160.224 0.00633 596 7.740 34.611 1.12 43.8KH-05-2 ST03 -160.224 0.00633 795 5.856 34.550 1.74 62.5 85 0.23 2.85 0.073KH-05-2 ST03 -160.224 0.00633 992 4.699 34.553 1.93 84.3 98 0.25 2.66 0.078KH-05-2 ST03 -160.224 0.00633 1486 3.119 34.599 2.12 127.0 125 0.30 3.15 0.079KH-05-2 ST03 -160.224 0.00633 1979 2.301 34.641 2.45 151.0 141 0.34 3.06 0.085KH-05-2 ST03 -160.224 0.00633 2471 1.845 34.666 2.85 160.0KH-05-2 ST03 -160.224 0.00633 2962 1.672 34.675 3.17 159.0 161 0.38 3.34 0.099KH-05-2 ST03 -160.224 0.00633 3451 1.508 34.687 3.47 156.0 174 0.38 3.23 0.092KH-05-2 ST03 -160.224 0.00633 3941 1.400 34.691 3.79 152.0 192 0.37 3.12 0.099KH-05-2 ST03 -160.224 0.00633 4429 1.307 34.702 4.15 143.0 187 0.40 3.38 0.101KH-05-2 ST03 -160.224 0.00633 4900 1.243 34.705 4.40 136.0 192 0.41 3.22 0.104KH-05-2 ST03 -160.224 0.00633 4916 1.243 135.0 195 0.42 3.45 0.108KH-05-2 ST05 -160.007 10.0648 0 27.900 34.447 4.59 0.6 0.05KH-05-2 ST05 -160.007 10.0648 4 27.709 34.429 4.54 0.6 0.04KH-05-2 ST05 -160.007 10.0648 10 27.691 34.438 4.54 0.6 0.05 18 0.10 1.62 0.027KH-05-2 ST05 -160.007 10.0648 20 27.674 34.441 4.54 0.6 0.05 13 0.10 1.75 0.019KH-05-2 ST05 -160.007 10.0648 30 27.578 34.484 4.58 0.5 0.06 10 0.11 1.56 0.024KH-05-2 ST05 -160.007 10.0648 40 27.303 34.514 4.59 0.7 0.07KH-05-2 ST05 -160.007 10.0648 49 27.061 34.513 4.63 0.5 0.08 20 0.13 1.55 0.024KH-05-2 ST05 -160.007 10.0648 75 24.252 34.923 4.92 0.6 0.14 24 0.12 1.42 0.023KH-05-2 ST05 -160.007 10.0648 100 21.093 - 4.52 1.7 0.22 16 0.12 1.79 0.042KH-05-2 ST05 -160.007 10.0648 149 12.314 34.575 0.63 26.0 0.02 38 0.17 1.83 0.045KH-05-2 ST05 -160.007 10.0648 200 11.287 34.691 0.22 30.8 61 0.18 1.98 0.077KH-05-2 ST05 -160.007 10.0648 249 10.669 34.687 0.49 32.7KH-05-2 ST05 -160.007 10.0648 298 10.114 34.671 0.37 35.5 73 0.19 2.28 0.065KH-05-2 ST05 -160.007 10.0648 397 9.033 34.620 0.35 42.7KH-05-2 ST05 -160.007 10.0648 497 8.006 34.568 0.45 53.0 96 0.21 2.64 0.079KH-05-2 ST05 -160.007 10.0648 597 6.982 34.530 0.50 64.9KH-05-2 ST05 -160.007 10.0648 650 5.567 34.533 0.74 85.1 116 0.26 2.91 0.076KH-05-2 ST05 -160.007 10.0648 940 4.444 34.547 1.07 108.0 133 0.26 2.98 0.095KH-05-2 ST05 -160.007 10.0648 1486 2.993 34.603 1.84 145.0 165 0.30 3.21 0.103KH-05-2 ST05 -160.007 10.0648 1979 2.154 34.643 2.27 170.0 182 0.33 2.87 0.094KH-05-2 ST05 -160.007 10.0648 2471 1.844 34.664 2.61 179.0 187 0.38 3.27 0.095KH-05-2 ST05 -160.007 10.0648 2962 1.683 34.674 2.87 180.0 197 0.38 3.32 0.096KH-05-2 ST05 -160.007 10.0648 3452 1.514 34.685 3.26 177.0 195 0.40 3.27 0.099KH-05-2 ST05 -160.007 10.0648 3860 1.399 34.695 3.70 164.0 207 0.39 3.51 0.097KH-05-2 ST05 -160.007 10.0648 4380 1.363 34.696 3.94 157.0 210 0.41 3.44 0.106KH-05-2 ST05 -160.007 10.0648 4915 1.374 34.699 4.06 153.0 214 0.40 3.43 0.109KH-05-2 ST05 -160.007 10.0648 4916 1.374 34.700 4.08 153.0KH-05-2 ST07 -160.005 19.9978 0 27.000 35.033 4.62 0.8 0.08KH-05-2 ST07 -160.005 19.9978 5 26.916 35.023 4.62 0.6 0.08KH-05-2 ST07 -160.005 19.9978 10 26.904 35.023 4.66 0.8 0.08 27 0.13 1.64 0.034KH-05-2 ST07 -160.005 19.9978 20 26.848 35.025 4.69 0.6 0.08 25 0.14 1.77 0.037KH-05-2 ST07 -160.005 19.9978 30 26.623 35.044 4.80 0.9 0.09 26 0.13 1.78 0.031

KH-05-2 ST07 -160.005 19.9978 40 25.775 35.094 4.89 0.7 0.11KH-05-2 ST07 -160.005 19.9978 50 24.396 35.136 4.97 0.7 0.14 22 0.12 1.62 0.039KH-05-2 ST07 -160.005 19.9978 75 23.029 35.204 4.97 0.8 0.17 24 0.13 1.71 0.033KH-05-2 ST07 -160.005 19.9978 99 22.210 35.203 4.83 0.7 0.22 22 0.11 1.79 0.058KH-05-2 ST07 -160.005 19.9978 149 19.958 35.025 4.55 1.6 0.09 35 0.15 2.11 0.045KH-05-2 ST07 -160.005 19.9978 199 16.977 34.662 4.37 3.7 0.01 59 0.17 1.98 0.073KH-05-2 ST07 -160.005 19.9978 248 13.624 34.268 4.37 8.4KH-05-2 ST07 -160.005 19.9978 299 10.797 34.138 4.18 17.7 81 0.19 2.28 0.068KH-05-2 ST07 -160.005 19.9978 397 8.128 34.138 2.52 40.9KH-05-2 ST07 -160.005 19.9978 496 6.278 34.132 1.53 67.0 100 0.21 2.64 0.072KH-05-2 ST07 -160.005 19.9978 595 5.503 34.297 1.03 86.2KH-05-2 ST07 -160.005 19.9978 794 4.877 34.440 1.11 98.5 142 0.25 3.01 0.078KH-05-2 ST07 -160.005 19.9978 991 4.171 34.520 1.24 113.0 155 0.26 2.98 0.085KH-05-2 ST07 -160.005 19.9978 1485 2.800 34.579 1.68 148.0 178 0.30 3.14 0.088KH-05-2 ST07 -160.005 19.9978 1978 2.122 34.616 2.27 164.0 188 0.34 3.09 0.076KH-05-2 ST07 -160.005 19.9978 2470 1.741 34.648 2.65 172.0 190 0.37 3.29 0.089KH-05-2 ST07 -160.005 19.9978 2961 1.580 34.670 2.93 174.0 195 0.39 3.37 0.086KH-05-2 ST07 -160.005 19.9978 3410 1.491 34.677 3.21 172.0 208 0.40 3.29 0.092KH-05-2 ST07 -160.005 19.9978 3938 1.464 34.683 3.46 166.0 216 0.41 3.46 0.097KH-05-2 ST07 -160.005 19.9978 4425 1.449 34.692 3.67 160.0 220 0.42 3.55 0.105KH-05-2 ST09 -159.998 30.004 0 26.600 35.109 4.69 2.9 0.06KH-05-2 ST09 -159.998 30.004 6 26.572 35.090 4.65 3.0 0.06KH-05-2 ST09 -159.998 30.004 10 26.564 35.090 4.68 3.2 0.06 16 0.11 1.68 0.023KH-05-2 ST09 -159.998 30.004 20 26.300 34.982 4.96 3.3 0.08 11 0.10 1.67 0.026KH-05-2 ST09 -159.998 30.004 30 21.590 34.549 5.85 3.8 0.10 19 0.11 1.79 0.031KH-05-2 ST09 -159.998 30.004 40 19.200 34.506 6.07 3.9 0.13KH-05-2 ST09 -159.998 30.004 50 17.338 34.493 6.18 4.4 0.16 13 0.12 1.68 0.028KH-05-2 ST09 -159.998 30.004 74 15.186 34.514 6.02 5.1 0.37 12 0.12 1.69 0.046KH-05-2 ST09 -159.998 30.004 99 14.050 34.481 5.29 7.3 0.15 20 0.14 1.75 0.048KH-05-2 ST09 -159.998 30.004 149 13.269 34.399 5.16 9.2 0.01 21 0.18 2.12 0.054KH-05-2 ST09 -159.998 30.004 199 12.840 34.397 5.23 10.1 25 0.19 2.16 0.062KH-05-2 ST09 -159.998 30.004 247 12.066 34.326 5.17 12.6KH-05-2 ST09 -159.998 30.004 298 11.035 34.229 4.97 16.7 34 0.19 2.43 0.065KH-05-2 ST09 -159.998 30.004 398 9.469 34.137 4.66 25.1KH-05-2 ST09 -159.998 30.004 450 7.411 34.032 3.51 46.9 48 0.21 2.64 0.068KH-05-2 ST09 -159.998 30.004 596 5.576 34.009 2.31 74.8KH-05-2 ST09 -159.998 30.004 795 4.116 34.174 0.61 121.0 84 0.25 3 0.074KH-05-2 ST09 -159.998 30.004 991 3.557 34.347 0.27 147.0 95 0.26 3.13 0.077KH-05-2 ST09 -159.998 30.004 1450 2.606 34.551 1.24 173.0 148 0.30 3.14 0.082KH-05-2 ST09 -159.998 30.004 1977 2.028 34.605 1.91 188.0 163 0.34 3.1 0.081KH-05-2 ST09 -159.998 30.004 2468 1.723 34.640 2.38 195.0 188 0.36 3.21 0.087KH-05-2 ST09 -159.998 30.004 2959 1.570 34.663 2.80 193.0KH-05-2 ST09 -159.998 30.004 3447 1.505 34.672 3.12 190.0 190 0.39 3.32 0.091KH-05-2 ST09 -159.998 30.004 3990 1.482 34.682 3.29 186.0 200 0.39 3.37 0.096

KH-05-2 ST09 -159.998 30.004 4423 1.495 34.687 3.47 181.0 202 0.41 3.48 0.098KH-05-2 ST09 -159.998 30.004 4930 1.530 34.687 3.61 176.0 212 0.41 3.46 0.106KH-05-2 ST09 -159.998 30.004 5420 1.581 34.691 3.64 172.0 227 0.41 3.57 0.109KH-05-2 ST11 -159.998 40.0015 0 20.200 33.616 5.24 0.9 0.07KH-05-2 ST11 -159.998 40.0015 5 21.137 33.604 5.22 1.1 0.08KH-05-2 ST11 -159.998 40.0015 10 21.058 33.576 5.32 1.0 0.08 18 0.11 1.66 0.027KH-05-2 ST11 -159.998 40.0015 19 20.311 33.613 6.45 0.8 0.16 21 0.11 1.59 0.022KH-05-2 ST11 -159.998 40.0015 29 14.411 33.694 7.14 <0.2 0.24 14 0.12 1.72 0.031KH-05-2 ST11 -159.998 40.0015 40 12.819 33.697 7.02 0.3 0.41KH-05-2 ST11 -159.998 40.0015 50 11.986 33.671 6.62 1.5 0.67 17 0.11 1.73 0.029KH-05-2 ST11 -159.998 40.0015 74 10.326 33.666 5.92 8.2 0.16 20 0.13 1.65 0.048KH-05-2 ST11 -159.998 40.0015 99 10.456 33.889 5.75 8.9 0.03 23 0.12 1.56 0.052KH-05-2 ST11 -159.998 40.0015 149 10.193 34.108 5.32 15.1 31 0.14 1.82 0.043KH-05-2 ST11 -159.998 40.0015 198 9.650 34.111 5.14 20.0 33 0.16 2.16 0.038KH-05-2 ST11 -159.998 40.0015 249 9.044 34.071 5.00 24.1 0.01KH-05-2 ST11 -159.998 40.0015 297 8.204 34.016 4.71 30.4 51 0.18 2.23 0.048KH-05-2 ST11 -159.998 40.0015 397 6.789 33.974 3.77 47.7KH-05-2 ST11 -159.998 40.0015 495 5.597 33.989 2.64 70.7 77 0.20 2.48 0.055KH-05-2 ST11 -159.998 40.0015 594 4.686 34.058 1.76 96.5KH-05-2 ST11 -159.998 40.0015 792 3.897 34.200 0.87 128.0 93 0.24 2.67 0.044KH-05-2 ST11 -159.998 40.0015 990 3.287 34.321 0.47 156.0 110 0.27 2.56 0.057KH-05-2 ST11 -159.998 40.0015 1483 2.443 34.493 0.42 194.0 158 0.30 2.78 0.062KH-05-2 ST11 -159.998 40.0015 1976 2.010 34.588 1.15 207.0 177 0.34 2.97 0.068KH-05-2 ST11 -159.998 40.0015 2466 1.721 34.634 1.91 208.0 193 0.37 3.05 0.078KH-05-2 ST11 -159.998 40.0015 2956 1.563 34.662 2.59 198.0 203 0.39 3.14 0.064KH-05-2 ST11 -159.998 40.0015 3445 1.486 34.677 3.06 192.0 208 0.39 3.48 0.089KH-05-2 ST11 -159.998 40.0015 3932 1.474 34.685 3.28 190.0 215 0.41 3.35 0.079KH-05-2 ST11 -159.998 40.0015 4419 1.506 34.688 3.31 195.0 222 0.42 3.44 0.088KH-05-2 ST11 -159.998 40.0015 4903 1.565 34.690 3.34 193.0 227 0.44 3.51 0.095KH-05-2 ST11 -159.998 40.0015 5389 1.630 34.689 3.34 193.0 232 0.45 3.68 0.102KH-05-2 ST13 -159.983 50.005 0 12.600 32.256 6.15 20.9 0.26KH-05-2 ST13 -159.983 50.005 3 12.557 32.264 6.15 20.8 0.28KH-05-2 ST13 -159.983 50.005 11 12.555 32.289 6.19 20.9 0.28 28 0.16 1.88 0.029KH-05-2 ST13 -159.983 50.005 22 12.522 32.323 6.14 20.9 0.27 30 0.14 1.97 0.026KH-05-2 ST13 -159.983 50.005 31 12.413 32.342 6.17 21.3 0.30 25 0.14 1.95 0.027KH-05-2 ST13 -159.983 50.005 40 7.506 32.522 7.03 26.2 0.32KH-05-2 ST13 -159.983 50.005 50 5.897 32.593 7.01 28.6 0.28 27 0.14 2.01 0.031KH-05-2 ST13 -159.983 50.005 75 4.566 32.838 6.03 36.7 0.38 20 0.12 2.26 0.043KH-05-2 ST13 -159.983 50.005 100 4.109 33.499 3.51 61.9 42 0.13 2.52 0.044KH-05-2 ST13 -159.983 50.005 149 3.958 33.787 1.95 80.7 0.02 59 0.16 2.02 0.047KH-05-2 ST13 -159.983 50.005 197 3.941 33.899 1.05 93.4 66 0.16 2.68 0.057KH-05-2 ST13 -159.983 50.005 247 3.913 33.966 0.75 101.0KH-05-2 ST13 -159.983 50.005 298 3.879 34.027 0.54 108.0 87 0.19 2.96 0.058KH-05-2 ST13 -159.983 50.005 397 3.709 34.109 0.62 117.0

KH-05-2 ST13 -159.983 50.005 495 3.529 34.195 0.40 131.0 102 0.21 2.78 0.056KH-05-2 ST13 -159.983 50.005 594 3.324 34.254 0.44 140.0KH-05-2 ST13 -159.983 50.005 793 2.984 34.342 0.47 154.0 127 0.25 3.01 0.052KH-05-2 ST13 -159.983 50.005 990 2.708 34.407 0.57 164.0 154 0.29 2.84 0.065KH-05-2 ST13 -159.983 50.005 1483 2.219 34.522 0.91 182.0 176 0.32 3.16 0.071KH-05-2 ST13 -159.983 50.005 1975 1.914 34.591 1.36 190.0 192 0.36 3.35 0.074KH-05-2 ST13 -159.983 50.005 2464 1.712 34.631 1.95 188.0 204 0.39 3.27 0.062KH-05-2 ST13 -159.983 50.005 2953 1.576 34.655 2.54 185.0 221 0.41 3.34 0.075KH-05-2 ST13 -159.983 50.005 3442 1.506 34.672 2.98 179.0 227 0.40 3.57 0.092KH-05-2 ST13 -159.983 50.005 3930 1.491 34.680 3.20 179.0 227 0.44 3.48 0.089KH-05-2 ST13 -159.983 50.005 4414 1.516 34.683 3.34 181.0 240 0.45 3.62 0.108KH-05-2 ST13 -159.983 50.005 4940 1.563 34.686 3.45 186.0 249 0.47 3.52 0.114

Supplementary Table S2. Residence time of HFSEs in the ocean

Elements Seawater Concentration Budget River Concentration River Flux Rain Concentration Rain Flux Hydrothemal Flux Residence Time(pmol/kg) (mol) (pmol/kg) (mol/y) (pmol/kg) (mol/y) (mol/y) (y)

Zr 155 2.1E+11 4.3E+02 1.6E+07 1.1E+02 4.1E+07 0.0E+00 3.7E+03Hf 0.33 4.5E+08 4.9E+00 1.8E+05 9.1E-01 3.3E+05 0.0E+00 8.7E+02Nb 3.1 4.2E+09 1.8E+01 6.7E+05 2.5E+00 9.0E+05 0.0E+00 2.7E+03Ta 0.087 1.2E+08 1.4E+00 5.2E+04 1.1E-01 4.0E+04 0.0E+00 1.3E+03

Si* 1.1E+17 5.6E+12 5.0E+11 6.0E+11 1.6E+04

*Data taken from Sarmiento & Gruber (2006).