spin and the exclusion principle modern ch.7, physical systems, 20.feb.2003 ejz review hydrogen...
Post on 21-Dec-2015
213 views
TRANSCRIPT
Spin and the Exclusion PrincipleModern Ch.7, Physical Systems, 20.Feb.2003 EJZ
Review Hydrogen atom, orbital angular momentum L
Electron spin s
Total angular momentum J = S + L= Spin + orbit
Applications: 21 cm line, Zeeman effect
Good QN and allowed transitions
Pauli exclusion principle
Periodic Table
Lasers
Hydrogen atom : Bohr model
We found rn = n2 r1, En = E1/n2, where the “principle quantum number” n labels the allowed energy levels.
Discrete orbits match observed energy spectrum
Hydrogen atom: Schrödinger solutions depend on new angular momentum quantum numbers
Quantization of angular momentum direction for l=2
Magnetic field splits l level in (2l+1) values of ml = 0, ±1, ± 2, … ± l
1
12
( 1) 0,1,2,..., 1
cosz l
l l where l n
L m
EE where E Bohr ground state
n l
L
L
Hydrogen atom plus L+S coupling:
• Hydrogen atom so far: 3D spherical solution to Schrödinger equation yields 3 new quantum numbers:
l = orbital quantum number
ml = magnetic quantum number = 0, ±1, ±2, …, ±l
ms = spin = ±1/2
• Next step toward refining the H-atom model:
Spin with
Total angular momentum J=L+s
with j=l+s, l+s-1, …, |l-s|
( 1)l l L
1 12 2( 1)s 1
2z ss m
( 1)j j J
Total angular momentum:
• Multi-electron atoms: J = S+L where S = vector sum of spins, L = vector sum of angular momenta
Spectroscopic notation: L=0 1 2 3 S P D F
Allowed transitions (emitting or absorbing a photon of spin 1)
ΔJ = 0, ±1 (not J=0 to J=0) ΔL = 0, ±1
Δmj = 0, ±1 (not 0 to 0 if ΔJ=0) ΔS = 0 Δl = ±1
2 1SJL
Magnetic moment of electron
Magnetic moment: Bohr magneton models e- as spinning ball (or loop) of charge
We expect but Stern-Gerlach experiment shows that where g = 2.0023…=gyromagnetic ratio(electron is not quite a spinning ball of charge).
arg.
2
2 2 2Be e
ch e evI area where I
time revr eL e
Showthatm m
z B sm
z B sg m
Application of Zeeman effect: 21-cm line
Electron feels magnetic field due to proton magnetic moment (hyperfine splitting).
2 BE B
Pauli Exclusion principle
Identical fermions have antisymmetric wavefunctions, so electrons cannot share the same energy state.
Fill energy levels in up-down pairs:
1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
…
( , ') ( ', )x x x x
LASER = Light Amplification by Stimulated Emission of Radiation
Pump electrons up into metastable excited state.
One transition down stimulates cascade of emissions.
Monochromatic: all photons have same wavelength
Coherent: in phase, therefore intensity ~ N2