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    SP Logging

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    In sand A- Rw is less than Rmf; which means

    that formation water is saltier than the mud

    filtrate. In sand B- the SP deflection is less than in sand

    A and thus a fresher formation water is

    indicated.

    In sand C- the SP is reversed, indicating thatformation water is fresher than the mud

    filtrate and thus Rw is greater than Rmf.

    Somewhere in the region of 7000 feet it may

    be guessed that Rmf and Rw are equal.

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    SPLiquid Junction Potential

    Two mechanisms cause SP

    Electrokinetic (very small)

    Electrochemical

    i. Liquid Junction

    ii. Membrane Potential

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    SPMembrane Potential

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    Static SP (SSP)

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    SP as a permeability or shale indicator

    Since invasion can only occur in

    permeable formations,

    deflections of SP can be used toidentify permeable formations.

    The vertical resolution of SP is

    poor, and often the permeable

    bed must be 30 ft or more to

    achieve a static (flat baseline) SP

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    Rw from SSP

    Under certain circumstances Rw can

    be estimated from SP.

    The SP value remains constant for

    at least 30 feet.

    The area where the SP is constant

    must correspond to a very clean

    sandstone. The value of Rmf must remain

    constant across this same interval.

    These conditions are rare, and

    large errors in the Rw estimatemay occur.

    2._:,

    24.065

    133.061

    10

    log

    SPChartRR

    CTcK

    FTcK

    k

    SSP

    mfeq

    weq

    weq

    mfeqc

    mfeqweq

    c

    R

    R

    RRKSSP

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    Rmfeq from Rmf or Rw from Rweq

    If Rmf @ 75degF > 0.1

    Ohmm then Rmfeq=0.85

    Rmf @ BHT

    If Rmf @ 75 degF < 0.1

    Ohmm then Rmfeq from

    chart sp2,

    Same with Rw

    Chart SP-2

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    SP as Rw indicator

    Rmf < Rw

    Saline mud

    Rmf > Rw

    Fresh mudRmf = Rw

    SP is more often used

    qualitatively to predict

    whether Rw > Rmf or not.

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    SP for correlation

    -ve SPdeflectio

    n

    +ve SPdeflectio

    n

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    SP for correlation

    Keep in mind that SP deflection is Rmf dependent and never an absolute value

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    SP log

    Rmf > Rw?Where is Sand?

    Where is Shale?

    What is Vsh?

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    The Electrochemical Component

    The electro-chemical component Ec consists of the liquid junction

    potential (Ej) and the membrane potential (Em). These potentials

    create a current that flows at the shale / reservoir interface. When a

    reference electrode is moved across this interface a difference in

    potential is measured.

    Liquid Junction Potential

    SP is affected by formation water salinity. When solutions of

    differing concentration are brought into contact, ions from the

    solution with a higher concentration tend to migrate toward the

    solution of lower concentration until equilibrium occurs

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    However, with sodium chloride (NaCl) solutions, the Cl- anions move faster

    than Na+ cations, so a conventional current (or potential) flows from the less

    concentrated solution to the more concentrated solution. The electrical

    potential that results from the combined sodium and chlorine ion movement is

    known as the liquid junction potential(Elj). In terms of the solutions present in a formation, mud filtrate can be substituted

    for the less concentrated solution and formation water will be the more

    concentrated solution. Borehole mud-weight is usually higher than the

    formation fluid pressure. This produces an over-pressure at the face of the

    reservoir exposed to the borehole, and causes mud filtrate to invade thereservoir. A mud cake is subsequently formed and the invasion process slows

    down. An invasion profile as shown, Liquid Junction Potential is formed which

    separates, in this case, a high saline formation water and the low salinity mud

    filtrate

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    The liquid junction potential Ejis created at the interface between the invaded

    zone and the uncontaminated zone due to a salinity difference between mud

    filtrate and formation water. Since the negative Cl-anions (assuming an NaCl

    solution) have a greater mobility than the positive Na+cations, the net result is a

    flow of negative charges (Cl-ions) from the moreconcentrated solution to the less

    concentrated solution. This mechanism, which is driven by the conductivity

    difference the mud filtrate and formation water is also shown by the above Liquid

    Junction Potentialgraphic. The greater the contrast in salinitybetween mud

    filtrate and formation water, the largerthis potential

    M b P i l

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    Membrane Potential

    Another "battery" found in the formation arises from the molecular constructionof shale beds. Shale can act as an ionic sieveor membrane. This means that shalecan be permeable for one type of ion while acting as a barrier for another type.This property is called ionic perm-selectivity, and the result is that the shale-

    membrane can preferentially prevent the movement of negative ions. In thiscase, shales are permeable to Na+ ions, but not so permeable to C1- ions.

    Shales are cation exchangers; they are electro-negative, and therefore repelanions. This phenomenon occurs as a result of the crystalline structure of clayminerals. Their exterior surfaces exchange sites where positively charged cationscling temporarily. In most instances, the shales are 100% effective and thereforerepel all chlorine (negatively charged) ions. The positive sodium ions move towardthe lower salinity mud in the borehole, but the chlorine ions cannot follow thismovement.

    Since Na+ ions effectively manage to penetrate through the shale from the salineformation water to the less saline mud column, a positive potential is generatedtoward the low-concentration NaCl solution of the mud column. This potential isknown as themembrane potential(Em). Figure 8 indicates the process.

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    The currents created by this series of potentials flow through

    5 different media, each with its own resistivity:

    borehole filled with mud (Rm),

    mudcake (Rmc),

    invaded zone filled with mud filtrate (Rxo),

    virgin zone filled with uncontaminated fluids (Rt)

    surrounding shales (Rsh).

    In each medium the potential along a line of current flow (I)

    drops in proportion to the resistance that is encountered.

    Etotal = I. Rm

    mud

    + I. Rmc

    mudcake

    + I. Rxo

    flushed zone

    + I.R t

    virgin zone

    + I.

    Rshadjacent shale

    The motor providing the potential (Etotal) can therefore be expressed as:

    [E-6]

    kshkmcjmtotal EEEEE

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    SHALE VOLUME CALCULATION

    The presence of shale in art otherwise "clean" sand tends to supress the SP. This effect can beused in estimating the shale content of a formation. If SPlog is the value of the SP curve at thedesired measurement point on the log, and SPsand is the value observed in a clean, water-bearing sand and SPshale is the value observed in a shale, then any intermediate value of the SP

    may be converted into a value for the shale volume (Vsh) by the relationship

    sandshale

    sand

    SPsh

    SPSP

    SPSPV

    )()(

    )()(

    log

    This concept is illustrated in Figure 3:Shale Volume Calculation Example Using theSP.

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    GEOLOGICAL INFORMATION

    FACTORS AFFECTING THE SP

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    FACTORS AFFECTING THE SP

    SP readings are usually accurately and easily measured. However, there are some

    circumstances where SP readings need careful consideration.

    Oil-base muds completely lack an electrical path through the mud column,

    hence no SP can be generated. Shaly formations suppresses the measured SP. This phenomenon permits

    the formation shaliness to be determined if a clean sand with the same water

    salinity is available for a legitimate comparison.

    Hydrocarbon saturation suppresses SP deflections. Thus, only water-bearing

    sands should be selected for Rwdetermination from the SP. Unbalanced mud columns, with differential pressure into the formation, can

    cause "streaming" potentials that augment the SP. This effect, known as

    electrokinetic SP, is noticeable in depleted reservoirs, and is impossible to

    compensate quantitatively.

    Resistivities may be very high in hard formations, except in permeable zonesor shales. These high resistivities affect the distribution of the SP currents, hence

    the shape of the SP curve. As illustrated in Figure 1: Schematic Representation of

    the SP in Highly Resistive Formations, the SP currents flowing from shale bed Shl

    toward permeable bed P2 are largely confined to the borehole between Shl and

    P2 because of the very high resistivity of the formation in this interval.

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    Accordingly, the intensity of the SP current in the borehole in this interval

    remains constant. Assuming the hole diameter is constant, the potential drop

    per foot is constant and the SP curve is a straight line.

    In high resistivity formations, SP current can leave or enter the borehole only

    opposite permeable beds or shales. This causes the SP curve to show a

    succession of straight portions with a change of slope opposite every

    permeable interval (with the concave side of the SP curve toward the shale

    line) and opposite every shale bed (with the convex side of the SP curve toward

    the shale line). The boundaries of the permeable beds cannot be located with

    accuracy by use of the SP in such highly resistive formations.

    Bed thickness can affect the SP measurement quite dramatically. In thin beds,

    the SP does not fully develop. Figure 2: Factors Affecting SP Reduction

    illustrates the factors which produce this effect.