solar cells and solar panels - solar navigator world electric navigation challenge

7/28/2019 Solar Cells and Solar Panels - Solar Navigator World Electric Navigation Challenge

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SOLAR CELLS

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It's incredible that we've come this far. We can catch the Sun's radiant light energyand convert it into electrical energy. It's nothing new of course. Nature has beencapturing the energy in light for millions of years. Each leaf is a form of solar cell,producing energy for plants and trees to grow in a chemical process known asPhotosynthesis.

Solar panels power satellites

SPACE AGE TECHNOLOGY - Solar cells, also known as Photo Voltaic Cells, were rapidlydeveloped to provide electrical energy for space missions. The beauty of solar cells isthat provided the Sun shines, they keep on producing free electricity. Well, sort of free. Solar panels are still expensive to manufacture. It is the high purchase priceand installation cost that effectively limits their use.

There are many types of solar cell. Polycrystaline (more than one crystal),monocrystaline and thin film. Monocrystaline is presently the most efficient atconverting light energy into electricity. Sometimes as high as 20% but more usually

15%. A monocrystaline cell is made from a thin slice cut from a single crystal of silicon. A grid of metal is then embedded over the wafer ending in the contacts andother layers added. Thin film cells are plated onto a plate of glass. They are muchcheaper to produce, but only around 5% efficient and heavy. Vehicle designers willnormally want to capture as much energy as possible for a given area and weight.

A single cell is not of much practical use, producing less than a volt. Several cells haveto be connected in a series of cells to produce a useable voltage. The voltage increasesproportionally. 10 cells connected in series will produce about 7.5 volts. 20 cells 15volts and so on. A number of cells (a battery) linked and mounted together is knownas a solar panel.

AR CELLS AND SOLAR PANELS - SOLAR NAVIGATOR WORL... http://www.solarnavigator.net/solar_

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HOW MUCH POWER - The Sun's energy reaching the surface of our planet is roughly1 kilowatt per square meter. Before entering our atmosphere it is about 20% more:1.2 kilowatts. That's why astronauts always look so bright. At 15% efficiency 10panels each measuring 1meter by 1 meter would power 1 1/2 bars on an electricheater. 20 panels would power an electric kettle. This of course assumes that the sunis shining. Just imagine how many panels Solar Navigator needs to cross an ocean?Why not try and guess the area of panels on Solar Navigator.

" T h e supp l y o f so l a r e ne r g y is b o t h w i t h o u t l im i t a n d co s t ;

s o l a r e ne r g y w i ll p o u r d ow n on u s l o n g a f t e r w e r u n ou t o f f o s s il f u e ls ."

Charles Fritts, 1886, inventor of the first selenium solar panel.

Example of commercially available products:

Solar Solar Kits Solar Gadgets SOLAR CELL MANUFACTURERS WORLDWIDE

Essentially, solar panels are devices that convert light into electricity. They are calledsolar after the sun or "Sol" because the sun is the most powerful source of the light touse. They are sometimes called photovoltaics which means "light-electricity". Solarcells or PV cells rely on the photovoltaic effect to absorb the energy of the sun andcause current to flow between two oppositely charge layers.

Solar cell

Photovoltaics

Photovoltaic (or PV) systems convert light energy into electricity. The term "photo" is a

stem from the Greek "phos," which means "light." "Volt" is named for Alessandro Volta(1745-1827), a pioneer in the study of electricity. "Photo-voltaics," then, could literallymean "light-electricity." Most commonly known as "solar cells," PV systems are alreadyan important part of our lives. The simplest systems power many of the smallcalculators and wrist watches we use every day. More complicated systems provideelectricity for pumping water, powering communications equipment, and even lightingour homes and running our appliances. In a surprising number of cases, PV power isthe cheapest form of electricity for performing these tasks. Photovoltaic cells convert light energy into electricity at the atomic level. Although firstdiscovered in 1839, the process of producing electric current in a solid material withthe aid of sunlight wasn't truly understood for more than a hundred years. Throughout


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the second half of the 20th century, the science has been refined and the process hasbeen more fully explained. As a result, the cost of these devices has put them into themainstream of modern energy producers. This was caused in part by advances in thetechnology, where PV conversion efficiencies have improved considerably.

French physicist Edmond Becquerel first described the photovoltaic (PV) effect in 1839,but it remained a curiosity of science for the next three quarters of a century. At only19, Becquerel found that certain materials would produce small amounts of electriccurrent when exposed to light. The effect was first studied in solids, such as selenium,by Heinrich Hertz in the 1870s. Soon afterward, selenium PV cells were convertinglight to electricity at 1% to 2% efficiency. As a result, selenium was quickly adopted inthe emerging field of photography for use in light-measuring devices. Major steps toward commercializing PV were taken in the 1940s and early 1950s,when the Czochralski process was developed for producing highly pure crystallinesilicon. In 1954, scientists at Bell Laboratories depended on the Czochralski process todevelop the first crystalline silicon photovoltaic cell, which had an efficiency of 4%.

Solar Cells

A solar cell is any device that directly converts the energy in light into electricalenergy through the process of photovoltaics. The development of solar cell technologybegins with the 1839 research of French physicist Antoine-César Becquerel. Becquerelobserved the photovoltaic effect while experimenting with a solid electrode in anelectrolyte solution when he saw a voltage develope when light fell upon the electrode.

"What is often considered the first genuine solar cell was built around 1883 byCharles Fritts, who used junctions formed by coating selenium (a semiconductor)with an extremely thin layer of gold... These early solar cells, however, still hadenergy-conversion efficiencies of less than 1 percent. This impasse was finallyovercome with the development of the silicon solar cell by Russell Ohl in 1941.Thirteen years later three other American researchers, G.L. Pearson, Daryl

Chapin, and Calvin Fuller, demonstrated a silicon solar cell capable of a 6-percentenergy-conversion efficiency when used in direct sunlight." - EncyclopediaBritannica

Solar Panels

A solar panel or battery converts the sun's energy to electricity. Gerald Pearson, CalvinFuller and Daryl Chapin invented the first sun energy battery in 1954. The inventorscreated an array of several strips of silicon (each about the size of a razorblade),placed them in sunlight, captured the free electrons and turned them into electricalcurrent. Bell Laboratories in New York announced the prototype manufacture of a new

solar battery. Bell had funded the research. The first public service trial of the BellSolar Battery began with a telephone carrier system (Americus, Georgia) on October 41955.

Sun Energy Battery - In 1954, G.L. Pearson, C.S. Fuller, and D.M. Chapin invented thefirst solar panel battery.


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Solar panel array on Solar Navigator development model

Solar Panels in Space

Extract: Nasa Jet Propulsion Laboratory ReporCrystalline silicon and gallium arsenideare typical choices of materials for solar panels for deep-space missions. Galliumarsenide crystals are grown especially for photovoltaic use, but silicon crystals areavailable in less-expensive standard ingots, which are produced mainly forconsumption in the microelectronics industry. When exposed to direct sunlight at 1 AU, a 6-centimeter diameter silicon cell canproduce a current of about 0.5 ampere at 0.5 volt. Gallium arsenide is more efficient.Crystalline ingots are sliced into wafer-thin disks, polished to remove slicing damage,dopants are introduced into the wafers, and metallic conductors are deposited onto

each surface: a thin grid on the sun-facing side and usually a flat sheet on the other.Spacecraft solar panels are constructed of these cells cut into appropriate shapes,protected from radiation and handling damage on the front surface by bonding on acover glass, and cemented onto a substrate (either a rigid panel or a flexible blanket),and electrical connections are made in series-parallel to determine total outputvoltage. The cement and the substrate must be thermally conductive, because in flightthe cells tend to heat up from absorbing infrared energy that is not converted toelectricity. Since cell heating reduces the operating efficiency it is desirable tominimize the heating. The substrate is supported on a deployable structuralframework. The resulting assemblies are called solar panels or solar arrays.

A solar panel is a collection of solar cells. Although each solar cell provides a relatively

small amount of power, many solar cells spread over a large area can provide enoughpower to be useful. To get the most power, solar panels have to be pointed directly atthe Sun. Spacecraft are built so that the solar panels can be pivoted as the spacecraftmoves. Thus, they can always stay in the direct path of the light rays no matter howthe spacecraft is pointed. Spacecraft are usually designed with solar panels that canalways be pointed at the Sun, even as the rest of the body of the spacecraft movesaround, much as a tank turret can be aimed independently of where the tank is going.A tracking mechanism is often incorporated into the solar arrays to keep the arraypointed towards the sun.

Solar panels need to have a lot of surface area that can be pointed towards the Sun asthe spacecraft moves. More exposed surface area means more electricity can be


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converted from light energy from the Sun. Sometimes, satellite scientists purposefullyorient the solar panels to "off point," or out of direct alignment from the Sun. Thishappens if the batteries are completely charged and the amount of electricity needed islower than the amount of electricity made. The extra power will just be vented by ashunt into space as heat.

Solar panels are very hardy. Compared to alternative power sources, they wear outvery slowly. The principal factor affecting the loss in power with time is the Spaceradiation environment. For low radiation environments, such as low Earth orbiting,their effectiveness decreases around 1 to 2 percent a year. This means after a five yearmission the solar panels will still be making more than 90% of what they made at thebeginning of the mission (as long as they haven't gotten farther away from the Sun).In contrast, for missions in higher radiation environments, such as mid altitude Earthorbit (2000 to 10000 kilometers), arrays can lose half their power within 1 year. Thatis one reason few missions fly in this orbital range.

Photovoltaic concentrator solar arrays for primary spacecraft power are devices, whichintensify the sunlight on the photovoltaics. This design uses lenses, called Fresnel*lenses, which take a large area of sunlight and direct it towards a specific spot bybending the rays of light and focusing them. Some people use the same principle whenthey use a magnifying lens to focus the Sun's rays on a pile of kindling or paper to

start fires.

Solar concentrators put one of these lenses over every solar cell. This focuses lightfrom the large concentrator area down to the smaller cell area. This allows thequantity of expensive solar cells to be reduced by the amount of concentration.Concentrators work best when there is a single source of light and the concentratorcan be pointed right at it. This is ideal in space, where the Sun is a single light source.Solar cells are the most expensive part of solar arrays, and arrays are often a veryexpensive part of the spacecraft. This technology allows costs to be cut significantlydue to the utilization of less material.

*Fresnel lenses have been around since Augustin Jean Fresnel invented them in 1822.

Theaters use them for spotlights and lighthouses use them to make their lights visibleat greater distances.


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SOLAR CELL MANUFACTURERS WORLD WIDE A-Z

A solar, or photovoltaic cell, is a semiconductor device consisting of a large-area p-n junction diode, which, in the presence of sunlight is capable of generating usableelectrical energy. This conversion is called the photovoltaic effect. The field of researchrelated to solar cells is known as photovoltaics.

Solar cells have many applications. They are particularly well suited to, and historicallyused in situations where electrical power from the grid is unavailable, such as inremote area power systems, Earth orbiting satellites, handheld calculators, remoteradiotelephones, water pumping applications, etc. Solar cells (in the form of modulesor solar panels) are appearing on building roofs where they are connected through aninverter to the electricity grid in a net metering arrangement.

The term "photovoltaic" comes from the Greek photos meaning light and the name of the Italian physicist Volta, after whom the volt (and consequently voltage) are named.It means literally of light and electricity .

INVENTOR MODERN SOLAR CELL

Russell Ohl is generally recognized for patenting the modern solar cell in 1946US2402662, "Light sensitive device"). Sven Ason Berglund had a prior patentconcerning methods of increasing the capacity of photosensitive cells.


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Materials and efficiency

Various materials have been investigated for solar cells. There are two main criteria -efficiency and cost. Efficiency is a ratio of the electric power output to the light powerinput. Ideally, near the equator at noon on a clear day, the solar radiation isapproximately 1000 W/m². So a 10% efficient module of 1 square meter can power a100 W light bulb. Costs and efficiencies of the materials vary greatly. By far the mostcommon material for solar cells (and all other semiconductor devices) is crystallinesilicon. Crystalline silicon solar cells come in three primary categories:

Single crystal or monocrystalline wafers made using the Czochralskiprocess. Most commercial monocrystalline cells have efficiencies on the order of 14%; the SunPower cells have high efficiencies around 20%. Single crystal cellstend to be expensive, and because they are cut from cylindrical ingots, theycannot completely cover a module without a substantial waste of refined silicon.Most monocrystalline panels have uncovered gaps at the corners of four cells.Sunpower and Shell Solar are among the main manufacturers of this type of cells.Poly or multi crystalline made from cast ingots - large crucibles of moltensilicon carefully cooled and solidified. These cells are cheaper than single crystalcells, but also somewhat less efficient. However, they can easily be formed intosquare shapes that cover a greater fraction of a panel than monocrystalline cells,and this compensates for their lower efficiencies. See GT Solar HEM Furnace, BPSolar, Sharp Solar and Kyocera Solar.Ribbon silicon formed by drawing flat thin films from molten silicon and has amulticrystalline structure. These cells are typically the least efficient, but there isa cost savings since there is very little silicon waste since this approach does notrequire sawing from ingots. See Evergreen Solar, and RWE Schott Solar.


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Sun powered solar tracking panel array

These technologies are wafer based manufacturing. In other words, in each of theabove approaches, self supporting wafers of ~300 micrometres thick are fabricated andthen soldered together to form a module. Thin film approaches are module based. Theentire module substrate is coated with the desired layers and a laser scribe is thenused to delineate individual cells. Two main thin film approaches are amorphous siliconand CIS:

Amorphous silicon films are fabricated using chemical vapor depositiontechniques, typically plasma enhanced (PE-CVD). These cells have lowefficiencies around 8%.CIS stands for general chalcogenide films of Cu(InxGa1-x)(SexS1-x)2. Whilethese films can achieve 11% efficiency, their costs are still too high.

There are additional materials and approaches. For example, Sanyo has pioneered theHIT cell. In this technology, amorphous silicon films are deposited onto crystallinesilicon wafers.The chart below illustrates the various commercial large area module efficiencies andthe best laboratory efficiencies obtained for various materials and technologies.

Interconnection and modules

Usually, solar cells are electrically connected, and combined into "modules", or solar


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panels. Solar panels have a sheet of glass on the front, and a resin encapsulationbehind to keep the semiconductor wafers safe from the elements (rain, hail, etc). Solarcells are usually connected in series in modules, so that their voltages add.

THEORY

In order to understand how a solar cell works, a little background theory in

semiconductor physics is required. For simplicity, the description here will be limited todescribing the workings of single crystalline silicon solar cells.

Silicon is a group 14 (formerly, group IV) atom. This means that each Si atom has 4valence electrons in its outer shell. Silicon atoms can covalently bond to other siliconatoms to form a solid. There are two basic types of solid silicon, amorphous (having nolong range order) and crystalline (where the atoms are arranged in an ordered threedimensional array). There are various other terms for the crystalline structure of silicon; poly-crystalline, micro-crystalline, nano-crystalline etc, and these refer to thesize of the crystal "grains" which make up the solid. Solar cells can be, and are madefrom each of these types of silicon, the most common being poly-crystalline.

Silicon is a semiconductor. This means that in solid sil icon, there are certain bands of energies which the electrons are allowed to have, and other energies between thesebands which are forbidden. These forbidden energies are called the "band gap". Theallowed and forbidden bands of energy are explained by the theory of quantummechanics.

At room temperature, pure silicon is a poor electrical conductor. In quantummechanics, this is explained by the fact that the Fermi level lies in the forbiddenband-gap. To make silicon a better conductor, it is "doped" with very small amounts of atoms from either group 13 (III) or group 15 (V) of the periodic table. These "dopant"atoms take the place of the silicon atoms in the crystal lattice, and bond with theirneighbouring Si atoms in almost the same way as other Si atoms do. However, becausegroup 13 atoms have only 3 valence electrons, and group 15 atoms have 5 valence

electrons, there is either one too few, or one too many electrons to satisfy the fourcovalent bonds around each atom. Since these extra electrons, or lack of electrons(known as "holes") are not involved in the covalent bonds of the crystal lattice, theyare free to move around within the solid. Silicon which is doped with group 13 atoms(aluminium, gallium) is known as p-type silicon because the majority charge carriers(holes) carry a positive charge, whilst silicon doped with group 15 atoms (phosphorus,arsenic) is known as n-type silicon because the majority charge carriers (electrons) arenegative. It should be noted that both n-type and p-type silcion are electricallyneutral, i.e. they have the same numbers of positive and negative charges, it is justthat in n-type silicon, some of the negative charges are free to move around, while theconverse is true for p-type silicon.


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Photons absorb into electron-hole pairs, which diffuse to contacts

Light generation of carriers

When a photon of light hits a piece of silicon, one of two things can happen. The first isthat the photon can pass straight through the silicon. This (generally) happens whenthe energy of the photon is lower than the bandgap energy of the silicon

semiconductor. The second thing that can happen is that the photon is absorbed by thesilicon. This (generally) happens if the photon energy is greater than the bandgapenergy of silicon. When a photon is absorbed, its energy is given to an electron in thecrystal lattice. Usually this electron is in the valence band, and is tightly bound incovalent bonds between neighbouring atoms, and hence unable to move far. Theenergy given to it by the photon "excites" it into the conduction band, where it is freeto move around within the semiconductor. The covalent bond that the electron waspreviously a part of now has one less electron - this is known as a hole. The presenceof a missing covalent bond allows the bonded electrons of neighboring atoms to moveinto the "hole," leaving another hole behind, and in this way a hole can move throughthe lattice. Thus, it can be said that photons absorbed in the semiconductor createmobile electron-hole pairs.

A photon only needs to have energy greater than the band gap energy to excite anelectron from the valence band into the conduction band. However, the solar frequencyspectrum approximates a black body spectrum at ~6000 K, and as such, much of thesolar radiation reaching the Earth is composed of photons with energies greater thanthe band gap of silicon. These higher energy photons will be absorbed by the solar cell,but the difference in energy between these photons and the silicon band gap isconverted into heat (via lattice vibrations - called phonons) rather than into usableelectrical energy.

The p-n junction

A solar cell is a large-area semiconductor p-n junction. To understand the workings of a p-n junction it is convenient to imagine what happens when a piece of n-type siliconis brought into contact with a piece of p-type silicon. In practice, however, the p-n

junctions of solar cells are not made in this way, but rather, usually, by diffusing ann-type dopant into one side of a p-type wafer.


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A truly solar powered house - zero carbon emissions

If we imagine what happens when a piece of p-type silicon is placed in intimate contactwith a piece of n-type silicon, then what occurs is a diffusion of electrons from theregion of high electron concentration - the n-type side of the junction, into the regionof low electron concentration - p-type side of the junction. When the electrons diffuseacross the p-n junction, they recombine with holes on the p-type side. This diffusion of carriers does not happen indefinitely however, because of the electric field which iscreated by the imbalance of charge immediately either side of the junction which thisdiffusion creates. Electrons from donor atoms on the n-type side of the junction arecrossing into the p-type side, leaving behind the (extra) positively charged nuclei of the group 15 donor atoms, leaving an excess of positive charge on the n-type side of the junction. At the same time, these electrons are filling in holes on the p-type side of

the junction, becoming involved in covalent bonds around the group 13 acceptoratoms, making an excess of negative charge on the p-type side of the junction. Thisimbalance of charge across the p-n junction sets up an electric field which opposesfurther diffusion of charge carriers across the junction.

This region where electrons have diffused across the junction is called the depletionregion because it no longer contains any mobile charge carriers. It is also known as the"space charge region".

The electric field which is set up across the p-n junction creates a diode, allowingcurrent to flow in only one direction across the junction. Electrons may pass from then-type side into the p-type side, and holes may pass from the p-type side to the n-type

side. But since the sign of the charge on electrons and holes is opposite, conventionalcurrent may only flow in one direction.

Separation of carriers by the p-n junction

Once the electron-hole pair has been created by the absorption of a photon, theelectron and hole are both free to move off independently within the silicon latttice. If they are created within a minority carrier diffusion length of the junction, then,depending on which side of the junction the electron-hole pair is created, the electricfield at the junction will either sweep the electron to the n-type side, or the hole to the


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p-type side.

Connection to an external load

If Ohmic metal-semiconductor contacts are made to both the n-type and p-type sidesof the solar cell, and the electrodes connected to an external load, then electronswhich are created on the n-type side, or have been "collected" by the junction and

swept onto the n-type side may travel through the wire, power the load, and continuethrough the wire until they reach the p-type semiconductor-metal contact where theyrecombine with a hole which was either created as an electron-hole pair on the p-typeside of the solar cell, or swept across the junction from the n-type side after beingcreated there.

Equivalent circuit of a solar cell

To understand the electronic behaviour of a solar cell, it is useful to create a modelwhich is electrically equivalent, and is based on discrete electrical components whosebehaviour is well known. An ideal solar cell may be modelled by a current source inparallel with a diode. In practice no solar cell is ideal, so a shunt resistance and a

series resistance component are added to the model. The result is the "equivalentcircuit of a solar cell" shown on the left. Also shown on the right, is the schematicrepresentation of a solar cell for use in circuit diagrams.

Manufacture and devices

Because solar cells are semiconductor devices, they share many of the sameprocessing and manufacturing techniques as other semiconductor devices such ascomputer and memory chips. However, the stringent requirements for cleanliness andquality control of semiconductor fabrication are a little more relaxed for solar cells.

Most large-scale commercial solar cell factories today make screen printedpoly-crystalline silicon solar cells. Single crystalline wafers which are used in thesemiconductor industry can be made in to excellent high efficiency solar cells, but theyare generally considered to be too expensive for large-scale mass production.

Poly-crystalline silicon wafers are made by wire-sawing block-cast silicon ingots intovery thin (250 to 350 micrometre) slices or wafers. The wafers are usually lightlyp-type doped.To make a solar cell from the wafer, an n-type diffusion is performed on the front sideof the wafer, forming a p-n junction a few hundred nanometres below the surface.


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Antireflection coatings, which increase the amount of light coupled into the solar cell,are typically applied next. Over the past decade, silicon nitride has gradually replacedtitanium dioxide as the antireflection coating of choice because of its excellent surfacepassivation qualities (i.e., it prevents carrier recombination at the surface of the solarcell). It is typically applied in a layer several hundred nanometers thick using plasma-enhanced chemical vapor deposition (PECVD).

The wafer is then metallised, whereby a full area metal contact is made on the backsurface, and a grid-like metal contact made up of fine "fingers" and larger "busbars" isscreen-printed onto the front surface using a silver paste. The rear contact is alsoformed by screen-printing a metal paste, typically aluminum. Usually this contactcovers the entire rear side of the cell, though in some cell designs it is printed in a gridpattern. The metal electrodes will then require some kind of heat treatment or"sintering" to make Ohmic contact with the silicon.

After the metal contacts are made, the solar cells are interconnected in series (and/orparallel) by flat wires or metal ribbons, and assembled into modules or "solar panels".Solar panels have a sheet of tempered glass on the front, and a polymer encapsulationon the back.

Some solar cells have textured front surfaces that, like antireflection coatings, serve to

increase the amount of light coupled into the cell. Such surfaces can usually only beformed on single-crystal silicon, though in recent years methods of forming them onmulticrystalline silicon have been developed.

Energy conversion efficiency

Typical module efficiencies for commercially available screen printed multicrystallinesolar cells are around 12%. A solar module's energy conversion efficiency, (or justefficiency) is the ratio of the maximum output electrical power divided by the inputlight power under "standard" test conditions. The "standard" solar radiation (known asthe "air mass 1.5 spectrum") has a power density of 1000 watts per square metre.Thus, a typical 1 m² solar panel in direct sunlight will produce approximately 120 watts


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of peak power.

Applications and implementations

See the article solar panel for information about applications and implementations of solar cells and panels.

Cost analysis

The US retail module costs are in the $3.50 to $5.00/Wp range. Additional installationcosts for a residential rooftop retrofit in California (CA) is around $3.50/Wp or more.So on the low side, installed system costs are about $7.00/Wp in CA, and probablyhigher in places with less experience. Federal, state, utility, and other subsidiescombined pay about half the cost. So CA rule of thumb is that the installed system PVwill cost you at the low end, $3.50/Wp.

Under net metering, one offsets regular retail utility rate which for CA is about 11cents/kWh. Knowing installed system costs, amount of sunshine, and the util ity rates,

one can figure out the years till payback with or without financing costs. Assuming nofinancing costs and a $6/Wp installed system cost (lower than current $7), one cantake sunshine and utility rate information from around the globe and come up with apayback graph such as shown below. The addition of subsidies brings down the years topayback proportionately. For example, if the years to payback were 24 years at $6/Wp,and subsidies brought that down to $3/Wp, the years to payback would be 12.

Current research

There are currently many research groups active in the field of photovoltaics atuniversities and research institutions around the world.

Much of the research is focussed on making solar cells cheaper and/or more efficient,so that they can more effectively compete with other energy sources, including fossilenergy. One way of doing this is to develop cheaper methods of obtaining silicon that issufficiently pure. Silicon is a very common element, but is normally bound in silicasand. Another approach is to significantly reduce the amount of raw material used inthe manufacture of solar cells. The various thin-film technologies currently beingdeveloped make use of this approach to reducing the cost of electricity from solar cells.

The invention of conductive polymers, (for which Alan Heeger was awarded a Nobelprize) may lead to the development of much cheaper cells that are based oninexpensive plastics, rather than semiconductor grade silicon. However, all organicsolar cells made to date suffer from degradation upon exposure to UV light, and hence

have lifetimes which are far too short to be viable.


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Silicon monocrystaline solar panels

Thin-film solar cells

The next step in reducing the cost of solar cells and panels seems certain to come fromthin-film technology. Thin-film solar cells use less than 1% of the raw material (silicon)

compared to wafer based solar cells, leading to a significant price drop per kWh. Thereare many research groups around the world actively researching different thin-filmapproaches and/or materials.

Thin Film solar cells are mainly deposited by PECVD from silane gas and hydrogen.This process produces a material without crystalline orientation : amorphous silicon.Depending on the deposition's parameters nanocrystalline silicon can also be obtained.These types of silicon present dandling and twisted bonds, which results in theaparition of deep defects (energy levels in the bandgap) as well as in the deformationof the valence and conduction bands (band tails). This contributes to reduce theefficiency of Thin-Film solar cells by reducing the number of collected electron-holepair by incident photon.

Amorphous silicon (a-Si) has a higher bandgap (1.7 eV) than crystalline Silicon (c-Si)(1.1 eV), which means it is more efficient to absorb the visible part of the solarspectrum, but it fails to collect an important part of the spectrum : the infrared. Asnano crystalline Si has about the same bandgap as c-Si, the two material can becombined by depositing to diodes on top of each other : the tandem cell. The top cell ina-Si absorbs the visible light and leaves the infrared part of the spectrum for thebottom cell in nanocrystalline Si.

One particularly promising technology is crystalline silicon thin-films on glasssubstrates. This technology makes use of the advantages of crystalline silicon as asolar cell material, with the cost savings of using a thin-film approach. From the Pacific


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Solar website:

"Crystalline Silicon on Glass (CSG) [is] the photovoltaic technology developed byPacific Solar that is now being commercialised by CSG Solar. A very thin layer of silicon, less than two micrometres thick, is deposited directly onto a glass sheetwhose surface has been roughened by applying a layer of tiny glass beads. Thesilicon is not crystalline when first deposited, but becomes so after heattreatment in an oven. The resulting layer is processed using lasers and ink-jetprinting techniques to form the electrical contacts needed to get the solar-produced electricity out of the thin silicon film."

In 2005, a full-scale production factory is being built in Germany to commercialise thistechnology. CSG Solar expects to release its first product for sale in 2006. Each solarmodule will have a rated power exceeding 100 watts and will be cheaper thancompeting solar panels.Another interesting aspect of thin-film solar cells is the possibility to deposit the cellson all kind of materials, including flexible substrates (PET for example), which opens anew dimension for new applications.

Exotic materials

For special applications, such as Deep Space 1, high-efficiency cells can be made fromgallium arsenide by molecular beam epitaxy. Such cells have many diodes in series,each with a different band gap energy so that it absorbs its share of theelectromagnetic spectrum with very high efficiency. Triple junction solar cell have (asthe name suggest) 3 diodes layered on top of each other, each absorbing a differentspectrum of light, efficiency as high as 28% have been achieved. The multiple junctionsolar cells may be very efficient, but are prohibitively expensive to make.Cost-effective use of these cells could be achieved with concentrating optics so thatless of the array consists of actual semiconductor devices.

Experimental non-silicon solar panels can be made of carbon nanotubes or quantum


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dots embedded in a special plastic. These have only one-tenth the efficiency of siliconpanels but could be manufactured in ordinary factories, not clean rooms which shouldlower the cost. While conventional solar cells only generate electricity from the visiblelight spectrum, experimental cells have been made that use the infrared spectrum. Byvarying the size of the quantum dots, the cells can be tuned to absorb differentwavelengths. If panels that absorb both visible and infrared spectrums are able to bemanufactured, the panels may be able to achieve up to 30 percent efficiency.

Some of the most efficient solar cell materials are cadmium telluride (CdTe) and copperindium gallium selenide (CIGS). Unlike the basic silicon solar cell, which can bemodelled as a simple p-n junction (see under semiconductor), these cells are bestdescribed by a more complex heterojunction model. The best efficiency of a bare solarcell as of April 2003 was 16.5% [Dr IM Dharmadasa, Sheffield Hallam University, UK].Higher efficiencies (around 30%) can be obtained by using optics to concentrate theincident light.

Polymer or organic solar cells are built from ultra thin layers (typically 100 nm) of organic semiconductors such as polyphenylene vinylene and fullerene. The p/n

junction model is only a crude description of the functioning of such cells, as electronhopping and other processes also play a crucial role. They are potentially cheaper tomanufacture than silicon or inorganic cells, but efficiencies achieved to date are low

and cells are highly sensitive to air and moisture, making commercial applicationsdifficult. In the reverse mode, the technology has however already successfully beencommercialised in organic LEDs and organic displays, also called polymer displays.

Graetzel cells (sometimes called photoelectrochemical cells) have been around for twodecades or so. A p/n junction is used here too in the form of a doped solid (normallytitanium dioxide) in contact with a solid or liquid electrolyte (for example CuI). Incontrast to the classical solar cell not the semiconductor but a dye placed at the p/ninterface is used for absorption of radiation, mimicking the process of photosynthesis.As a result, this type of cell allows a more flexible use of materials. Like organic solarcells, Graetzel cells can be manufactured under "dirty" conditions. Commercialapplications have failed to appear due to the fast degradation occurring in Graetzel

cells.

Solar cells and energy payback

There is a common but mistaken notion that solar cells never produce more energythan it takes to make them. While the expected working lifetime is on the order of 40years, the energy payback time of a solar panel is anywhere on the order of 2 to 30years depending on the type and where it is used, see Net energy gain.


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Use of solar cells in Kenya and Uganda, in AfricaPennicott, Katie, "Solar cell edges towards endless energy ". 7 December 2001.Dye Sensitized Solar Cells (DYSC) based on Nanocrystalline Oxide SemiconductorFilmsNews searching: Solar Cell, PhotovoltaicHistorical: Photovoltaic Solar Energy Conversion: An UpdateWladek Walukiewicz, Materials Sciences Division, Berkeley Lab.: Full Solar SpectrumPhotovoltaic Materials Identified. Quote: "... Maximum, theoretically predictedefficiencies increase to 50%, 56%, and 72% for stacks of 2, 3, and 36 junctions with


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appropriately optimized energy gaps, respectively...."CNET: 5/12/03 SunPower Announces World's Most Efficient, Low-Cost Silicon Solar CellQuote: "...The National Renewable Energy Laboratory (NREL) has verified 20.4 percentconversion efficiency for the A-300...."SunPower A-300 (pdf), SunPower29 March 2002, Scientists Create New Solar Cell Quote: "...semiconducting plasticmaterial known as P3HT... 1.7 percent for sunlight..."15 February 03, 'Denim' solar panels to clothe future buildings Quote: "... Unlikeconventional solar cells, the new, cheap material has no rigid silicon base..."Residential Solar Power Systems - Photo GalleryExamples of Photovoltaic SystemsHow Solar Cells Workazonano.com: Carbon Nanotube Structures Could Provide More Efficient Solar Powerfor Soldiers 28 February 2005Solar energy timelineTimeline of Photovoltics How A Photovoltic Cell Works

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