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SMOKE version 4.7 Recent Enhancements B.H. Baek University of North Carolina at Chapel Hill Alison Eyth U.S. EPA Office of Air Quality Planning and Standards 2

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Page 1: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

SMOKE version 47Recent Enhancements

BH BaekUniversity of North Carolina at Chapel Hill

Alison EythUS EPA Office of Air Quality Planning and Standards

2

Outline

1 Onroad Mobile Emissions Updates- Average Speed Fractions by Distribution (ASD)- NOx Humidity Corrections

2 New PostgreSQLPostGIS Surrogates Tool Development- Computationally optimized (Faster and Less memory usage)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 3

Creating Onroad Emissions using SMOKE-MOVES

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 4

Background on Speeds in MOVES and SMOKE-MOVES

bull Speed impacts emission rates and is relevant to MOVES rate-per-distance (RPD) processes

bull Vehicle-miles-traveled (VMT) are used for activity data

bull RPD emissions = RPD emission factor VMT

bull SMOKE-MOVES interpolates between two speed bin MOVES emission factors to estimate the factor for a specific speed value

bull Alternatively MOVES inventory mode uses average speed distributions (ASD) to compute emissions as a weighted sum across all speed bins

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 5

Speed Bin Min Speed Max Speed

1 0 25

2 25 75

3 75 125

4 125 175

5 175 225

6 225 275

7 275 325

8 325 375

9 375 425

10 425 475

11 475 525

12 525 575

13 575 625

14 625 675

15 675 725

16 725

Examples of Average Speed Distributions

bull Two counties ASD for weekdays at 400pm

bull Example 1 Spread-out ASD vs 2682mph bull MOVES inventory mode would apply emissions

rates from all speed bins and sum the emissionsbull SMOKE-MOVES would interpolate between

emissions factors from two speed binsbull Different emissions would be estimated due to

different number of bins involved

bull Example 2 Compact ASD with a peak at the same bins SMOKE-MOVES would used

bull Similar emissions would be estimated due to similar representation of speed bins

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 6

0010203040506070809

1

25 5 10 15 20 25 30 35 40 45 50 55 60 65

Frac

tion

Average Bin Speed

Example 1 4pm 2682mph

asd smspd

0010203040506070809

1

25 5 10 15 20 25 30 35 40 45 50 55 60 65

Frac

tion

Average Bin Speed

Example 2 4pm 60 mph

7International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

bull Atlanta Chicago Baltimore Dallas and Phoenix

bull Varies by hour vehicle amp city

bull Slower speed during rush hours and daytime

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 8

bull Restricted road speeds are typically higher than unrestricted road

bull Clear lower speed during the rush hours

Impact of Speed by Pollutant

and Vehicle Type

Fuel Gasoline

9

Impact of Speed by Pollutant

and Vehicle Type

Fuel Diesel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 10

Improved Representation of Speeds in SMOKE-MOVES

bull New Feature in SMOKE-MOVES Average Speed Fraction by Distance (ASD) Emissions estimated for each of 16 speed bins (SPD)

Traveled Distance (TD)spd = Speed (mph)spd ASFspd

ASDspd = TDspd Sums of TD

ASD is function of

int (FIPS SCC WeekdayWeekend Hour of day Speed)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 11

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 2: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Outline

1 Onroad Mobile Emissions Updates- Average Speed Fractions by Distribution (ASD)- NOx Humidity Corrections

2 New PostgreSQLPostGIS Surrogates Tool Development- Computationally optimized (Faster and Less memory usage)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 3

Creating Onroad Emissions using SMOKE-MOVES

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 4

Background on Speeds in MOVES and SMOKE-MOVES

bull Speed impacts emission rates and is relevant to MOVES rate-per-distance (RPD) processes

bull Vehicle-miles-traveled (VMT) are used for activity data

bull RPD emissions = RPD emission factor VMT

bull SMOKE-MOVES interpolates between two speed bin MOVES emission factors to estimate the factor for a specific speed value

bull Alternatively MOVES inventory mode uses average speed distributions (ASD) to compute emissions as a weighted sum across all speed bins

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 5

Speed Bin Min Speed Max Speed

1 0 25

2 25 75

3 75 125

4 125 175

5 175 225

6 225 275

7 275 325

8 325 375

9 375 425

10 425 475

11 475 525

12 525 575

13 575 625

14 625 675

15 675 725

16 725

Examples of Average Speed Distributions

bull Two counties ASD for weekdays at 400pm

bull Example 1 Spread-out ASD vs 2682mph bull MOVES inventory mode would apply emissions

rates from all speed bins and sum the emissionsbull SMOKE-MOVES would interpolate between

emissions factors from two speed binsbull Different emissions would be estimated due to

different number of bins involved

bull Example 2 Compact ASD with a peak at the same bins SMOKE-MOVES would used

bull Similar emissions would be estimated due to similar representation of speed bins

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 6

0010203040506070809

1

25 5 10 15 20 25 30 35 40 45 50 55 60 65

Frac

tion

Average Bin Speed

Example 1 4pm 2682mph

asd smspd

0010203040506070809

1

25 5 10 15 20 25 30 35 40 45 50 55 60 65

Frac

tion

Average Bin Speed

Example 2 4pm 60 mph

7International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

bull Atlanta Chicago Baltimore Dallas and Phoenix

bull Varies by hour vehicle amp city

bull Slower speed during rush hours and daytime

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 8

bull Restricted road speeds are typically higher than unrestricted road

bull Clear lower speed during the rush hours

Impact of Speed by Pollutant

and Vehicle Type

Fuel Gasoline

9

Impact of Speed by Pollutant

and Vehicle Type

Fuel Diesel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 10

Improved Representation of Speeds in SMOKE-MOVES

bull New Feature in SMOKE-MOVES Average Speed Fraction by Distance (ASD) Emissions estimated for each of 16 speed bins (SPD)

Traveled Distance (TD)spd = Speed (mph)spd ASFspd

ASDspd = TDspd Sums of TD

ASD is function of

int (FIPS SCC WeekdayWeekend Hour of day Speed)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 11

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 3: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Creating Onroad Emissions using SMOKE-MOVES

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 4

Background on Speeds in MOVES and SMOKE-MOVES

bull Speed impacts emission rates and is relevant to MOVES rate-per-distance (RPD) processes

bull Vehicle-miles-traveled (VMT) are used for activity data

bull RPD emissions = RPD emission factor VMT

bull SMOKE-MOVES interpolates between two speed bin MOVES emission factors to estimate the factor for a specific speed value

bull Alternatively MOVES inventory mode uses average speed distributions (ASD) to compute emissions as a weighted sum across all speed bins

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 5

Speed Bin Min Speed Max Speed

1 0 25

2 25 75

3 75 125

4 125 175

5 175 225

6 225 275

7 275 325

8 325 375

9 375 425

10 425 475

11 475 525

12 525 575

13 575 625

14 625 675

15 675 725

16 725

Examples of Average Speed Distributions

bull Two counties ASD for weekdays at 400pm

bull Example 1 Spread-out ASD vs 2682mph bull MOVES inventory mode would apply emissions

rates from all speed bins and sum the emissionsbull SMOKE-MOVES would interpolate between

emissions factors from two speed binsbull Different emissions would be estimated due to

different number of bins involved

bull Example 2 Compact ASD with a peak at the same bins SMOKE-MOVES would used

bull Similar emissions would be estimated due to similar representation of speed bins

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 6

0010203040506070809

1

25 5 10 15 20 25 30 35 40 45 50 55 60 65

Frac

tion

Average Bin Speed

Example 1 4pm 2682mph

asd smspd

0010203040506070809

1

25 5 10 15 20 25 30 35 40 45 50 55 60 65

Frac

tion

Average Bin Speed

Example 2 4pm 60 mph

7International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

bull Atlanta Chicago Baltimore Dallas and Phoenix

bull Varies by hour vehicle amp city

bull Slower speed during rush hours and daytime

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 8

bull Restricted road speeds are typically higher than unrestricted road

bull Clear lower speed during the rush hours

Impact of Speed by Pollutant

and Vehicle Type

Fuel Gasoline

9

Impact of Speed by Pollutant

and Vehicle Type

Fuel Diesel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 10

Improved Representation of Speeds in SMOKE-MOVES

bull New Feature in SMOKE-MOVES Average Speed Fraction by Distance (ASD) Emissions estimated for each of 16 speed bins (SPD)

Traveled Distance (TD)spd = Speed (mph)spd ASFspd

ASDspd = TDspd Sums of TD

ASD is function of

int (FIPS SCC WeekdayWeekend Hour of day Speed)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 11

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 4: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Background on Speeds in MOVES and SMOKE-MOVES

bull Speed impacts emission rates and is relevant to MOVES rate-per-distance (RPD) processes

bull Vehicle-miles-traveled (VMT) are used for activity data

bull RPD emissions = RPD emission factor VMT

bull SMOKE-MOVES interpolates between two speed bin MOVES emission factors to estimate the factor for a specific speed value

bull Alternatively MOVES inventory mode uses average speed distributions (ASD) to compute emissions as a weighted sum across all speed bins

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 5

Speed Bin Min Speed Max Speed

1 0 25

2 25 75

3 75 125

4 125 175

5 175 225

6 225 275

7 275 325

8 325 375

9 375 425

10 425 475

11 475 525

12 525 575

13 575 625

14 625 675

15 675 725

16 725

Examples of Average Speed Distributions

bull Two counties ASD for weekdays at 400pm

bull Example 1 Spread-out ASD vs 2682mph bull MOVES inventory mode would apply emissions

rates from all speed bins and sum the emissionsbull SMOKE-MOVES would interpolate between

emissions factors from two speed binsbull Different emissions would be estimated due to

different number of bins involved

bull Example 2 Compact ASD with a peak at the same bins SMOKE-MOVES would used

bull Similar emissions would be estimated due to similar representation of speed bins

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 6

0010203040506070809

1

25 5 10 15 20 25 30 35 40 45 50 55 60 65

Frac

tion

Average Bin Speed

Example 1 4pm 2682mph

asd smspd

0010203040506070809

1

25 5 10 15 20 25 30 35 40 45 50 55 60 65

Frac

tion

Average Bin Speed

Example 2 4pm 60 mph

7International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

bull Atlanta Chicago Baltimore Dallas and Phoenix

bull Varies by hour vehicle amp city

bull Slower speed during rush hours and daytime

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 8

bull Restricted road speeds are typically higher than unrestricted road

bull Clear lower speed during the rush hours

Impact of Speed by Pollutant

and Vehicle Type

Fuel Gasoline

9

Impact of Speed by Pollutant

and Vehicle Type

Fuel Diesel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 10

Improved Representation of Speeds in SMOKE-MOVES

bull New Feature in SMOKE-MOVES Average Speed Fraction by Distance (ASD) Emissions estimated for each of 16 speed bins (SPD)

Traveled Distance (TD)spd = Speed (mph)spd ASFspd

ASDspd = TDspd Sums of TD

ASD is function of

int (FIPS SCC WeekdayWeekend Hour of day Speed)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 11

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 5: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Examples of Average Speed Distributions

bull Two counties ASD for weekdays at 400pm

bull Example 1 Spread-out ASD vs 2682mph bull MOVES inventory mode would apply emissions

rates from all speed bins and sum the emissionsbull SMOKE-MOVES would interpolate between

emissions factors from two speed binsbull Different emissions would be estimated due to

different number of bins involved

bull Example 2 Compact ASD with a peak at the same bins SMOKE-MOVES would used

bull Similar emissions would be estimated due to similar representation of speed bins

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 6

0010203040506070809

1

25 5 10 15 20 25 30 35 40 45 50 55 60 65

Frac

tion

Average Bin Speed

Example 1 4pm 2682mph

asd smspd

0010203040506070809

1

25 5 10 15 20 25 30 35 40 45 50 55 60 65

Frac

tion

Average Bin Speed

Example 2 4pm 60 mph

7International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

bull Atlanta Chicago Baltimore Dallas and Phoenix

bull Varies by hour vehicle amp city

bull Slower speed during rush hours and daytime

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 8

bull Restricted road speeds are typically higher than unrestricted road

bull Clear lower speed during the rush hours

Impact of Speed by Pollutant

and Vehicle Type

Fuel Gasoline

9

Impact of Speed by Pollutant

and Vehicle Type

Fuel Diesel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 10

Improved Representation of Speeds in SMOKE-MOVES

bull New Feature in SMOKE-MOVES Average Speed Fraction by Distance (ASD) Emissions estimated for each of 16 speed bins (SPD)

Traveled Distance (TD)spd = Speed (mph)spd ASFspd

ASDspd = TDspd Sums of TD

ASD is function of

int (FIPS SCC WeekdayWeekend Hour of day Speed)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 11

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 6: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

7International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

bull Atlanta Chicago Baltimore Dallas and Phoenix

bull Varies by hour vehicle amp city

bull Slower speed during rush hours and daytime

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 8

bull Restricted road speeds are typically higher than unrestricted road

bull Clear lower speed during the rush hours

Impact of Speed by Pollutant

and Vehicle Type

Fuel Gasoline

9

Impact of Speed by Pollutant

and Vehicle Type

Fuel Diesel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 10

Improved Representation of Speeds in SMOKE-MOVES

bull New Feature in SMOKE-MOVES Average Speed Fraction by Distance (ASD) Emissions estimated for each of 16 speed bins (SPD)

Traveled Distance (TD)spd = Speed (mph)spd ASFspd

ASDspd = TDspd Sums of TD

ASD is function of

int (FIPS SCC WeekdayWeekend Hour of day Speed)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 11

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 7: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 8

bull Restricted road speeds are typically higher than unrestricted road

bull Clear lower speed during the rush hours

Impact of Speed by Pollutant

and Vehicle Type

Fuel Gasoline

9

Impact of Speed by Pollutant

and Vehicle Type

Fuel Diesel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 10

Improved Representation of Speeds in SMOKE-MOVES

bull New Feature in SMOKE-MOVES Average Speed Fraction by Distance (ASD) Emissions estimated for each of 16 speed bins (SPD)

Traveled Distance (TD)spd = Speed (mph)spd ASFspd

ASDspd = TDspd Sums of TD

ASD is function of

int (FIPS SCC WeekdayWeekend Hour of day Speed)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 11

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 8: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Impact of Speed by Pollutant

and Vehicle Type

Fuel Gasoline

9

Impact of Speed by Pollutant

and Vehicle Type

Fuel Diesel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 10

Improved Representation of Speeds in SMOKE-MOVES

bull New Feature in SMOKE-MOVES Average Speed Fraction by Distance (ASD) Emissions estimated for each of 16 speed bins (SPD)

Traveled Distance (TD)spd = Speed (mph)spd ASFspd

ASDspd = TDspd Sums of TD

ASD is function of

int (FIPS SCC WeekdayWeekend Hour of day Speed)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 11

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 9: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Impact of Speed by Pollutant

and Vehicle Type

Fuel Diesel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 10

Improved Representation of Speeds in SMOKE-MOVES

bull New Feature in SMOKE-MOVES Average Speed Fraction by Distance (ASD) Emissions estimated for each of 16 speed bins (SPD)

Traveled Distance (TD)spd = Speed (mph)spd ASFspd

ASDspd = TDspd Sums of TD

ASD is function of

int (FIPS SCC WeekdayWeekend Hour of day Speed)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 11

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 10: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Improved Representation of Speeds in SMOKE-MOVES

bull New Feature in SMOKE-MOVES Average Speed Fraction by Distance (ASD) Emissions estimated for each of 16 speed bins (SPD)

Traveled Distance (TD)spd = Speed (mph)spd ASFspd

ASDspd = TDspd Sums of TD

ASD is function of

int (FIPS SCC WeekdayWeekend Hour of day Speed)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 11

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 11: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Difference in July NOx

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 12

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 12: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Difference in July PM25

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 13

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 13: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Difference in July VOC

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 14

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 14: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Comparison between Interpolation vs ASD

bull July Monthly Total Emissions Comparison

Percent Difference [] (ASD ndash ORG)ORG 100

bull PM10 and PM25 Model Species Reduction -2 ~ -10

bull Gas Model Species All Increases ranging from 0 to 7

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 15

RPD_ORG_domain_daily_total7

RPD_Full_ASD_domain_daily_total

RPD_Gasoline_ASD

Full_AvgSpeedFrac_Org_compariso

1

2

3

4

5

6

7

A

B

CO

Original

150101341

ASD (Gasoline)

1571406723

ASD (All Fuels)

1575032492

5

Gasoline ASD

5

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
Original 15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
ASD (Gasoline) 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
ASD (All Fuels) 1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
5 3 4 3 7 2 -15 -4 -5 -6 -3 -13 -15 -3 -17 -13 -13 -4 -4 -2 -4 -4 -14 -5 -13 2 -0 -1 3 0 1 -0 1 -0 1 1 -1 6 0 1 -1 -1 1 1 1 1 1 -0 -0 -1 0 -0 -1 2 3 7
Gasoline ASD 5 2 3 2 6 2 -12 -1 -2 -2 -0 -10 -13 -1 -14 -11 -10 -0 -1 1 -1 -1 -11 -2 -10 3 0 0 3 1 1 0 1 0 1 2 0 6 1 1 0 0 1 1 1 1 1 0 0 0 0 0 -1 1 3 6
0
Diff (Full-Gasoline) 0 1 1 1 0 0 -3 -3 -3 -4 -3 -3 -3 -3 -3 -2 -3 -4 -3 -2 -4 -3 -3 -3 -3 -0 -1 -1 -1 -0 -0 -0 0 -1 -0 -1 -1 -0 -0 -0 -1 -1 -0 0 -0 -0 -0 -1 -1 -1 -0 -1 -0 0 -1
CO NOx NH3 SO2 TOG PM25 PM10
(tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth) (tonsmonth)
Original 150101341 32731036 866532 243010 16933473 1137931 2299143
ASD (Gasoline) 157140672 33152895 915495 245314 16968671 1104651 2119854
ASD (All Fuels) 157503249 33872540 922994 247160 17029036 1088181 2080859
CO NOx NH3 SO2 TOG PM25 PM10
ASD (Gasoline) 469 129 565 095 021 -292 -780
ASD (Others) 024 220 087 076 036 -145 -170
ASD (All Fuels) 493 349 652 171 056 -437 -949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550228438 106327295 12410016 978376 3097526 85524 3692358 05828 32164 09439 1982122 60979 03982 01755 41794 00553 261122 0305 274533 36658 1258 1265575 4634 129277 02059 25658 338348 175479 1023254 2244247 512582 857433 1360711 624383 725661 13351 16641 19963 120452 12423053 171219 06304 3162733 0 177475 28598484 4002465 645216 624374 338349 43329 8035 7617 34333 5168692 1023382
183 537367266 107724248 12543879 99099 3086094 853578 3744655 05947 32867 09677 2037892 61899 04033 01794 42427 0056 265664 03135 280343 3735 12907 1293568 4721 132473 02095 25534 34151 178267 1025632 2260251 511359 861772 1335793 633489 71717 13467 170305 19717 1206267 12340176 173879 0646 3123234 0 175384 28436658 3965202 640552 63348 341511 44099 80049 77084 344469 51792735 1025761
184 524232656 108102021 12573835 994349 3108055 85305 3767189 05994 33115 0974 2056552 62309 04057 01808 4266 00563 267326 03158 282457 37673 12996 1303459 47485 133593 02108 2553 342449 178968 1026431 2265315 511591 863441 1307699 635817 706542 13426 171203 19604 1205115 12236018 174441 06495 3088286 0 172944 28236355 3940969 639273 635808 34245 44287 80072 77332 346535 51760745 1026559
185 437339414 70771494 8430392 65261 2554665 652835 2392714 03426 18156 04714 1041036 39547 02628 00995 26535 0037 159446 01477 156552 2268 06248 708848 27222 71044 01251 19986 220149 103124 716232 1503063 390475 594014 1100178 373981 558361 08258 8558 1646 856388 9494965 101737 03162 25514 0 13759 21687227 3218595 520092 373975 220149 24651 62911 47591 266073 371353675 716321
186 460356602 75525146 89922 696409 2660844 68376 2451797 0365 19389 05116 1124364 40572 02684 01066 26904 0038 164732 01612 167406 24129 06793 760597 28117 76034 01292 20873 232237 110239 760722 158538 405862 6223 113102 399241 579222 0885 93215 1735 896304 9833908 108414 03457 2628309 0 142595 22488223 3317278 536958 399235 232238 26484 6489 50509 269704 391283325 760819
187 466285391 69133882 8308881 638114 2586251 657368 220898 03192 16728 04223 9228 36568 02434 00921 24083 00347 145739 01304 145002 21461 05594 65467 24551 63994 01141 20251 212738 97384 716428 1467955 390705 581838 1133723 355243 570318 08076 78022 17219 848486 957288 96154 02862 2602307 0 140342 21817073 3261166 525695 355238 212738 2311 62861 45632 256768 36921515 716518
188 523764766 97053799 11373191 893421 2940655 804798 3429014 05337 29384 08549 1746069 56685 03711 01602 38916 00516 241472 02737 250839 33684 11389 1154287 4276 115886 01903 24235 312337 160363 957381 2080614 482827 797937 129134 571776 685173 1228 150133 19081 1124692 11702819 156628 05675 3002134 0 167319 2691479 3796972 612161 571769 312338 39463 75852 70045 324192 48103885 9575
189 54623043 106160977 12384537 976795 3097526 854208 3691883 05815 32109 09435 198159 60909 03982 01752 41788 00553 260946 03049 274107 36551 12569 1263441 46327 129164 02058 25616 338089 175413 102192 2242275 51188 856629 1352776 624083 722837 13327 16641 19913 1202703 12386981 171119 06304 3151343 0 176756 28521094 3992025 644018 624074 33809 43316 80265 76124 34333 5160629 1022047
190 53116543 107262646 12483198 986686 3086095 850342 3744031 05931 32794 09672 2037195 61808 04033 01789 4242 0056 265435 03133 279785 37211 12893 1290781 47193 132327 02094 25466 341191 17815 1023214 2257188 510354 860625 1320786 63301 710484 13409 170276 19584 1203064 12255844 173637 06459 3099321 0 17389 28269585 3943754 638108 633001 341192 44074 79908 77012 344469 5163537 102334
191 524891445 107753467 12531854 991131 3108055 851594 3766466 05976 33031 09734 2055744 62203 04057 01803 42652 00563 26706 03155 28181 37512 12979 1300229 47466 133431 02106 25532 342724 179051 1026228 2266327 511873 863958 131055 636117 706522 13422 171276 19552 120584 12230721 174438 06498 3089009 0 173104 282377 3940945 638909 636108 342725 44306 80112 7737 346535 51751545 1026356
192 570737461 107609492 12598414 99049 3272643 884648 373492 05831 32006 09243 1928432 61791 0404 01748 42185 00563 262281 02969 273462 36967 12319 1257919 4629 127207 02067 26783 343146 175214 1048995 2285464 533653 878332 1418767 625027 751191 13372 163166 2095 1237579 12870654 171085 06161 330876 0 183909 29619866 4194125 677781 625019 343147 43058 84065 76737 358219 52801195 1049125
193 506663906 80068726 9548708 738433 2806584 728293 2598916 03819 20323 05392 1183345 42814 02848 01116 28563 00403 174125 01697 175577 25164 07141 79695 29787 79926 01366 22255 247046 117042 809808 1686847 432682 662495 12392 424055 630282 09495 98729 18585 958029 10611713 115231 0366 2843806 0 154956 24225735 356597 573795 424049 247047 28102 69231 53682 285878 4170426 809909
194 480171445 69576348 8370623 642269 2586251 661832 220862 03183 16686 0422 922399 36515 02434 00919 24079 00347 145607 01303 144681 21381 05585 653064 24542 63909 0114 20405 213856 97785 721438 1476366 393351 585182 1162833 356827 582865 08181 78215 17426 856089 9723127 96615 02868 2647387 0 143289 22132053 3302294 530364 356822 213857 23198 63291 45854 256768 37170735 721527
195 514098984 96871152 11344727 891681 2940655 801348 3429763 05357 29471 08556 1746906 56795 03711 01608 38924 00516 241747 02739 251509 33851 11406 1157638 42779 116054 01905 24134 311534 160058 9539 2074731 481044 795604 1273647 570586 677541 12208 149956 1894 1119731 1160986 15629 05669 2974876 0 165547 26719587 3771461 609554 570578 311535 39394 75588 69885 324192 47869235 954016
196 505305156 104993555 12215374 965783 3097526 838421 369431 05878 3239 09455 1984311 61266 03982 01769 41816 00553 26184 03057 276279 37093 12625 1274303 46391 12972 02064 25168 334701 174157 1006782 2217034 504093 846615 1269295 619169 68661 13013 16574 19309 1180321 11954337 169739 06282 3022668 0 168233 27613621 3874032 631053 61916 334702 43036 79021 75446 34333 50636745 1006907
197 487192578 106198789 1231932 976569 3086095 83293 3746575 05997 33089 09693 2040039 62181 04033 01807 42449 0056 266369 03141 282057 37778 12951 1302141 47259 132919 02101 24983 337616 176823 1006779 2230274 502062 850018 1239024 627797 674126 13093 169571 18953 1179805 11821744 172253 06436 2970399 0 165316 2735584 3823971 6243 627789 337617 43776 78581 76293 344469 5057890 1006904
198 49923582 10749124 12476774 988517 3108055 841884 3768441 06027 3326 09751 2057948 62493 04057 01816 42675 00563 267785 03161 283573 37952 13025 1309041 47517 133893 02112 25249 340489 178235 1016675 2250172 506967 857609 1261692 632913 686379 1324 170809 19214 119222 11993381 17364 06482 3016465 0 168195 27726475 3874357 631441 632904 34049 44121 7932 76933 346535 5112771 1016801
199 530396289 106727471 12464324 982121 3272643 870772 3736779 0588 32221 09259 1930509 62063 0404 0176 42206 00563 262964 02974 27512 37381 12362 1266209 46338 127645 02072 26335 339601 173908 1034275 2259677 525723 868034 1339966 619951 717345 13083 16245 20408 1215419 12466929 169747 06138 3186974 0 175815 28761121 4081381 66499 619942 339602 42766 8276 76037 358219 51954275 1034404
200 455425312 78334146 9306249 722142 2806584 711532 2600539 03861 2051 05405 1185156 43051 02848 01127 28582 00403 174719 01702 177024 25525 07179 804181 29829 80305 01371 21691 242846 115519 791115 1655562 422963 650108 1145003 418067 589438 09145 97945 17882 931288 10120993 113626 03634 2696019 0 145283 23184473 3428287 557758 41806 242847 27762 67661 52849 285878 407508375 791213
201 443417891 68103125 8172311 628496 2586251 649292 2209629 03209 16803 04228 923525 36663 02434 00926 24091 00347 145977 01306 145581 21605 05609 657565 24568 64147 01143 20002 210893 96718 707931 1454214 386455 576435 1094107 352618 553628 07924 77675 16906 837111 9370323 95442 02851 2541038 0 136387 21383855 3203644 518849 352613 210894 2296 6216 45267 256768 3648849 708018
202 506275586 96245244 11268118 885893 2940655 797535 3430027 05363 29501 08558 1747201 56833 03711 01609 38927 00516 241844 0274 251742 33909 11412 1158805 42786 116122 01906 24043 310858 159801 950886 2069569 479431 793521 1258334 569606 670326 12145 149826 18808 111526 11521637 155989 05664 2949321 0 163923 26536577 3747289 606176 569598 310859 39338 7527 69745 324192 47705325 951005
203 547338828 105760361 12340909 973134 3097526 853094 369194 05817 32116 09435 1981656 60918 03982 01753 41789 00553 260968 03049 274159 36564 1257 1263701 46329 129181 02058 25622 338164 175419 1022066 224258 511993 85675 135402 624142 72237 13323 166408 19892 1202858 12380164 171091 06304 3150869 0 176772 28513777 3991186 643451 624133 338165 43318 80226 7613 34333 5161853 1022192
204 53254207 10704957 12460326 984739 3086095 850888 3744009 0593 32792 09672 2037167 61804 04033 01789 42419 0056 265426 03133 279763 37206 12892 1290673 47193 132324 02093 25481 34127 17818 1023754 2257865 510541 860838 1328636 633131 713306 13433 170296 1962 1204137 12288119 173712 0646 3109189 0 174584 28334482 3951195 638384 633122 341271 44081 79921 77028 344469 51686245 1023881
205 515619609 107627998 12512426 989937 3108055 848181 3767542 06004 33156 09743 2056946 62361 04057 0181 42664 00563 267455 03159 282771 37751 13004 130503 47494 133682 02109 25435 341849 178736 1022957 2260354 510072 861558 1295969 634886 701008 13366 171084 19456 1201267 12165701 174167 06491 3068333 0 17172 28089741 3921216 636421 634877 34185 44235 79825 77205 346535 51523755 1023086
206 559155352 107678438 12602854 991097 3272643 881082 373616 05864 32149 09254 1929816 61972 0404 01756 42199 00563 262735 02972 274566 37243 12348 1263435 46322 127496 0207 26663 3421 174831 1045125 2278138 531379 875306 1398521 623552 742421 13296 162955 20818 1231437 12767202 170731 06154 3277265 0 181828 29396121 416439 674231 623543 342101 42974 837 76534 358219 52570925 1045256
207 506870938 80356079 9587531 741122 2806584 728165 2599178 03826 20353 05394 1183638 42852 02848 01118 28566 00403 174221 01697 175811 25222 07147 798117 29794 79988 01367 22261 247053 117049 809886 1687054 432752 662563 1241587 424082 631846 09503 98727 18603 958509 10630759 115263 0366 2848736 0 155291 24260281 3570318 574108 424077 247054 28103 69235 53687 285878 41704265 809987
208 476776602 69695103 8385077 643367 2586251 660413 2208886 0319 16717 04222 922697 36554 02434 00921 24082 00347 145705 01304 144919 2144 05592 654254 24549 63971 01141 20373 213595 97696 720109 1474549 392821 584509 1161592 356457 583248 0817 78156 17397 855266 9725438 96542 02866 2647238 0 143323 22128208 3301278 530069 356452 213596 23177 63218 45806 256768 3708495 720199
209 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
210 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
211 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
212 493745391 96688506 11308368 889876 2940655 793568 343124 05395 29641 08568 1748555 57011 03711 01618 38941 00516 242288 02744 252824 34179 1144 1164216 42818 116393 01909 23916 309889 15948 94636 2062661 477301 790863 1235473 568271 66247 12067 149656 18673 1109513 11431154 155698 05659 2919634 0 161868 26332725 3720984 603803 568263 30989 39264 75008 69566 324192 47369275 946479
total 15714067229 2942955836 34523952 27094175 91549482 24531355 101520281 157712 861844 246051 51741275 1680449 109977 47109 1142159 15352 7089862 78889 7372724 1005657 327875 33865345 124571 3421284 55828 741228 9317945 4721529 28775363 62283709 14706694 23988876 39068661 1687309 206461 362124 4353162 586302 33867757 354224062 4615621 164092 91435955 0 5059242 814519902 116029701 18778919 16872852 9317974 1157574 2320375 2078251 990182 14559761825 28778949
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 550345586 107608145 12502397 989691 310828 856831 3567357 05658 31135 09072 1925412 59006 03847 01701 40203 00538 251843 0293 265952 35758 12101 1225573 44545 124863 01985 25582 336239 174088 1017571 2232628 511447 853645 1360904 619321 724954 13268 164723 19963 1200083 12409099 169924 06238 3161849 0 177483 28549587 4000557 64479 619313 33624 42945 802 7563 343193 51868765 1017698
183 537438633 109041016 12638774 100262 3097112 855209 3615965 05772 31804 09299 1979617 59866 03894 01738 40789 00544 256102 03011 271484 36421 12412 1252267 45359 12793 02019 25454 339312 176817 1019732 2248136 510174 857823 1335979 628221 716431 13381 168547 19717 120164 12325565 17253 06391 3122314 0 175391 28385635 396321 640107 628212 339313 43698 79893 76522 344328 51979475 1019861
184 524297539 109431494 12669756 1006093 3119112 854717 3637993 05818 32046 0936 1998384 60268 03917 01752 41016 00547 257721 03033 273546 36738 12498 126191 45626 129037 02032 2545 340238 17751 102049 2253131 510399 859472 1307884 630517 705801 13339 169436 19604 1200464 12221405 173084 06426 3087361 0 172953 28185151 3938969 638826 630508 340239 43884 79915 76767 346394 51951515 1020616
185 437773125 71651963 8499877 660438 2559784 654214 234319 03353 17714 04555 102468 38765 02574 00972 25916 00364 155698 01427 152824 22287 0604 691445 26498 69363 01221 19958 219436 10265 714026 1499196 390105 592737 1100361 372201 558199 08232 8501 1646 854921 9492202 101298 0314 2551174 0 13766 21673279 3218082 51996 372195 219437 24518 62861 47403 266018 372933275 714115
186 460812227 7647417 9068168 704854 2666135 685308 2398465 03567 18889 04935 1114379 3971 02625 0104 26224 00373 160574 01558 163208 23682 06556 74093 27313 74439 01259 20839 231264 109585 758062 1579993 405349 620526 1131224 396854 578962 08812 92423 1735 894257 982927 107805 03426 2627979 0 142668 22467942 3316533 536773 396848 231265 26303 6482 50254 269624 39305575 758156
187 466855312 69961797 8376148 645492 2590594 658759 2169618 0313 16352 04086 917595 35933 0239 00901 23586 00342 142659 01264 141828 21123 05415 639808 23956 62852 01117 20227 212105 96954 714576 1464468 39038 580678 1133938 353649 570182 08052 77503 17219 84716 9570711 95755 02842 2602123 0 14042 21804966 326074 525581 353644 212105 2299 62815 45462 25671 37080305 714664
188 523926797 98123252 11448221 90285 2950578 806024 3314088 05186 28463 08223 1691687 54876 03587 01554 37449 00502 233009 02629 243179 32884 10962 1118634 41122 111822 01836 24168 310455 159117 952362 2070222 481815 794547 1291528 567256 684523 12206 148622 19081 1120711 11689817 155469 05615 3001324 0 167308 26870459 3795227 611778 567248 310456 39119 75718 69562 324067 48243285 952481
189 546350859 107439736 12476725 988092 310828 855801 3566882 05646 31079 09068 1924878 58935 03847 01698 40197 00538 251668 02929 265526 35652 1209 1223441 44532 124751 01984 2554 335979 17402 1016236 2230646 510745 85284 1352971 619018 72213 13245 164722 19913 1198262 12373021 169823 06238 3150458 0 176764 28472209 3990119 643592 619009 33598 42931 80115 75583 343193 51788525 1016362
190 531243477 108574492 12577657 998272 3097112 851977 3615337 05756 31731 09294 197892 59775 03894 01734 40781 00544 255873 03009 270926 36282 12398 124948 45343 127785 02017 25387 338992 176701 1017314 2245073 50917 856676 1320973 62774 709745 13323 168518 19584 1198439 12241244 172288 0639 3098398 0 173897 28218577 3941761 637662 627731 338993 43673 79751 7645 344328 5182256 1017441
191 524970508 109080293 12627539 1002852 3119112 853268 3637274 058 31962 09354 1997575 60162 03917 01747 41007 00547 257455 03031 272899 36577 12481 1258679 45607 128874 0203 25452 340515 177595 1020288 2254155 510683 859993 1310739 630823 705782 13336 16951 19552 1201195 12216127 173083 06428 3088084 0 173114 28186562 3938949 638463 630814 340516 43904 79955 76805 346394 5194325 1020416
192 570961172 108849863 12687565 1001446 3283233 886188 3613413 05669 3102 08893 1873324 59876 03909 01696 40637 00548 253301 02854 265248 36109 11861 1219671 44552 122947 01995 26711 341175 173911 1043625 2274608 532595 874787 141898 620277 750536 13295 161587 2095 1233427 12857703 169873 06099 3307937 0 183919 29574299 4192343 677384 620268 341176 42698 83924 76231 358088 5297687 1043756
193 507163867 81065264 9628386 7473 2812204 729916 25425 03732 19798 05202 1172352 41903 02785 01089 27844 00396 169738 0164 171168 24694 06892 776299 28939 78231 01331 22219 246034 116361 807032 1681241 432148 660647 1239423 421569 630014 09456 97905 18585 955898 1060692 114598 03627 2843462 0 155034 24204695 3565198 573603 421563 246035 27913 69158 53417 285795 418902575 807132
194 48075875 704079 8438246 649678 2590594 663229 216926 03121 1631 04083 917194 3588 0239 00899 23581 00342 142527 01263 141507 21043 05406 638202 23947 62767 01116 20381 213227 97358 71959 1472901 393028 584029 1163052 355241 582733 08157 77699 17426 854771 9721018 96218 02848 2647207 0 143368 22120122 3301873 530251 355236 213228 23079 63245 45685 25671 373304375 719679
195 514250234 97938555 11419491 901091 2950577 802572 3314836 05205 2855 08229 1692527 54985 03587 01559 37458 00502 233285 02631 243849 33051 10979 1121986 41142 11199 01838 24067 309651 158812 948876 2064328 480031 79221 1273831 566062 67689 12134 148445 1894 1115749 11596826 155129 05609 2974066 0 165536 26675222 3769716 609171 566054 309652 3905 75454 69402 324067 48008575 948992
196 505387695 106259365 12306235 97696 310828 840006 3569312 05709 31361 09089 1927599 59292 03847 01715 40225 00538 252561 02937 267698 36194 12146 1234302 44595 125307 0199 25091 332582 17276 1001081 2205363 502953 842812 1269477 614087 685899 1293 164046 19309 1175865 11940255 168439 06216 3021779 0 16824 27564502 3872111 630624 614079 332583 42649 7887 74904 343193 5081793 1001204
197 487229883 107500098 12412637 988061 3097112 834552 3617882 05822 32026 09315 1981765 60148 03894 01751 40811 00544 256807 03017 273199 36849 12456 1260839 45409 128377 02024 24903 335408 175368 1000858 2218107 500871 846053 1239199 622508 673382 13007 167806 18953 117516 11807014 170898 06367 2969467 0 16532 27304531 3821966 623853 622499 335409 43374 78424 75728 344328 50764745 1000983
198 499280117 108814004 12571898 1000199 3119112 84354 3639248 05851 32191 09371 199978 60451 03917 0176 4103 00547 25818 03037 274662 37017 12527 1267492 45659 129337 02035 25169 338273 176774 101072 2237961 505773 853631 1261871 627602 685635 13154 169038 19214 1187561 11978667 17228 06413 3015536 0 168202 27675078 3872352 630993 627593 338274 43717 79163 76367 346394 51317375 1010846
199 530561562 107957803 12552368 992981 3283233 87229 3615271 05717 31235 08908 1875401 60148 03909 01709 40658 00548 253982 02859 266907 36522 11904 1227961 446 123384 02 26262 337616 172598 1028883 2248752 524659 864469 1340166 615175 716681 13005 160862 20408 1211242 12453776 168528 06075 3186141 0 175822 28715171 4079582 664589 615166 337618 42404 82619 75528 358088 5212733 1029012
200 455853828 7931667 93846 730882 2812204 71313 2544122 03774 19985 05216 1174162 4214 02785 011 27863 00396 170332 01645 172614 25055 0693 783529 28981 78611 01336 21654 24182 11483 788314 1649881 422421 648239 1145206 415553 58916 09106 97111 17882 92913 10116039 112985 03602 2695664 0 145357 2316293 3427494 557562 415548 24182 27572 67587 52581 285795 40933975 788412
201 443959492 68923154 8238903 635802 2590594 650676 2170269 03147 16427 04092 918321 36028 0239 00906 23593 00342 142897 01266 142407 21267 0543 642702 23973 63005 01118 19979 210256 96286 706068 1450708 386127 575268 1094315 351016 55349 079 77153 16906 835777 9368105 95041 0283 2540853 0 136464 21371643 3203213 518734 351012 210257 2284 62113 45097 25671 366466925 706156
202 506423203 97306289 11342378 895246 2950578 79876 33151 05212 2858 08231 1692819 55024 03587 01561 37461 00502 233381 02632 244082 3311 10985 1123153 41149 112058 01838 23976 308973 158553 94586 2059155 478417 790123 1258522 565078 669674 1207 148313 18808 1111272 11508597 154828 05605 2948513 0 163911 26492124 3745542 605793 56507 308974 38993 75136 69262 324067 47844705 945979
203 547465781 107036797 12432935 984409 310828 854689 3566939 05647 31086 09069 1924944 58944 03847 01699 40198 00538 251689 02929 265577 35665 12091 1223699 44534 124767 01984 25546 336056 174028 1016385 2230966 510859 852962 1354217 619082 721664 1324 164722 19892 1198422 12366207 169797 06238 3149984 0 176781 28464958 3989279 643025 619074 336057 42933 80076 7559 343193 51800855 1016511
204 532626055 108359941 1255475 996315 3097112 852527 3615315 05755 31729 09294 1978892 59771 03894 01733 40781 00544 255864 03009 270904 36277 12397 1249371 45342 127781 02017 25402 339072 176731 1017856 2245757 509357 856891 1328824 627864 712568 13347 168539 1962 1199515 12273542 172364 06391 3108267 0 174592 28283545 3949206 637939 627856 339073 43681 79765 76466 344328 5187411 1017984
205 515687812 108950957 12607778 1001624 3119112 849856 3638351 05828 32087 09363 1998777 6032 03917 01754 4102 00547 25785 03034 27386 36817 12506 1263481 45635 129125 02033 25355 339638 177278 1017015 224817 50888 857588 1296155 629587 700267 1328 169317 19456 1196616 12151095 172811 06422 3067405 0 17173 28038574 3919215 635975 629578 339639 43832 79668 76639 346394 5171572 1017142
206 559365742 108920059 12692112 1002062 3283233 882623 3614648 05701 31163 08903 1874705 60057 03909 01704 40651 00548 253754 02857 266352 36384 11889 1225186 44584 123236 01998 26592 340126 173526 1039753 2267264 53032 871758 1398732 618797 741763 13219 161374 20818 1227278 12754191 169517 06092 327644 0 181838 29350454 416261 673834 618788 340127 42613 8356 76027 358088 5274666 1039882
207 507372734 8135666 9667616 750024 2812204 729794 2542762 03739 19828 05205 1172643 41941 02785 0109 27847 00396 169834 01641 171401 24753 06898 777465 28946 78294 01332 22225 246041 116369 80711 1681456 432219 660718 1241812 421599 631578 09464 97904 18603 956381 10625994 114631 03627 2848392 0 155368 24239277 3569548 573916 421593 246042 27915 69161 53422 285795 418907975 807211
208 477357266 70527383 845277 650783 2590594 661812 2169527 03128 16341 04085 917493 35919 0239 00901 23585 00342 142625 01263 141745 21102 05412 639393 23954 62828 01116 2035 212966 97268 718259 1471079 392498 583355 116181 354871 583115 08146 7764 17397 853948 9723323 96145 02846 264706 0 143402 22116257 3300857 529956 354866 212966 23057 63172 45638 25671 37244745 71835
209 493879023 97750146 11382499 899234 2950577 794794 3316314 05244 28721 08241 1694174 55201 03587 01569 37475 00502 233825 02636 245164 3338 11013 1128563 4118 11233 01842 23848 308 158231 941328 2052231 476285 787461 1235654 563737 661815 11993 148141 18673 110552 11418068 154535 05599 2918821 0 161856 26288225 3719234 603418 563729 308001 38919 74874 69082 324067 4750861 941445
210 501601797 106766592 12363163 98161 310828 837056 3570248 05733 31469 09097 1928644 59429 03847 01721 40236 00538 252905 0294 268534 36402 12168 1238481 4462 125539 01993 25052 332394 172695 999385 2203632 502447 842257 1266022 613797 684529 1291 164011 19257 1174648 11926206 168402 06215 3017098 0 167892 27530923 3867845 629654 613788 332395 42633 78788 74864 343193 50673465 999509
211 499065391 1080754 12491169 993448 3097112 838422 3617741 05818 32009 09314 1981601 60127 03894 0175 40809 00544 256754 03017 273069 36816 12453 1260192 45405 128356 02024 25033 336342 175714 1005075 2225249 503128 848925 1262951 62386 684556 13092 167969 19123 1181768 1194052 171272 06372 3008639 0 16793 27580256 3858219 627769 623851 336343 4345 78764 75918 344328 5101658 1005201
212 510059453 108986191 1260348 1001878 3119112 847428 3638601 05834 32116 09365 1999056 60356 03917 01756 41023 00547 257942 03035 274084 36873 12512 1264602 45642 129189 02033 25287 339179 1771 1014762 2244555 507774 85619 1282462 628914 693614 1323 169223 19361 1193048 12073188 172611 06419 3044861 0 170169 27880522 3899013 633856 628905 33918 43792 79466 76542 346394 5157857 1014889
1575032492 3008455449 351116241 27682287 92299436 24715968 99267828 155072 845207 239811 512493 1645236 107479 46259 1111954 1509 6922635 76963 7235403 992784 319808 33228736 1212689 3359175 54493 743159 9349364 4737588 28828492 62511012 14763057 2407931 39179182 16921876 20706272 363329 4367819 588024 33990128 355575715 4631961 164646 91728656 0 5080389 817447675 116450563 18849431 16921638 9349393 1161079 232903 2084828 9959974 14719855875 28832085
Day CO NO NO2 HONO NH3 SO2 PMC PAL PCA PCL PEC PFE PH2O PK PMG PMN PMOTHR PNA PNCOM PNH4 PNO3 POC PSI PSO4 PTI ACET ALD2 ALDX CH4 ETH ETHA ETHY ETOH FORM IOLE ISOP KET MEOH OLE PAR PRPA TERP TOL UNK UNR VOC_INV XYL BENZ FORM_PRIMARY ALD2_PRIMARY ACROLEIN BUTADIENE13 NAPHTHALENE N2O_INV CO2_INV CH4_INV
UNIT (tonday)
182 527521289 104187705 12096017 95816 2916008 843671 4167513 05895 3271 09609 1985614 67723 04539 01768 48289 00617 288101 03065 278758 36556 1268 1275076 51515 131479 02273 25075 337565 175434 993582 2229801 50918 856529 1353648 623222 720678 13149 166413 18945 119824 12369397 171206 06304 3144352 0 176114 28465674 3984323 641234 623213 337566 43272 80196 76002 347433 51099815 993707
183 516131016 10563458 12237189 971244 2904136 842359 4225359 06016 33424 0985 2041453 68736 04596 01806 49006 00624 292997 0315 284641 37257 13009 1303341 52451 134711 02313 2499 340949 178289 997305 2247655 508591 861603 1329856 632622 712877 13274 170318 18739 1201132 12297847 173919 0646 3108173 0 174193 28330491 3951694 637453 632614 34095 44055 79982 7696 348596 51223245 997429
184 503450664 106042188 12271257 974882 2924994 841786 425044 06064 33675 09914 2060127 69181 04623 0182 49274 00628 2948 03173 286774 37578 13098 1313258 52754 135841 02327 24987 341892 17899 998159 2252749 508832 863277 1302012 634953 702371 13233 171216 18626 1200029 12194872 174479 06495 3073632 0 171785 28132668 3927747 63619 634944 341893 44243 80006 77209 35068 51189375 998281
185 412640312 68845259 8147964 634411 2409311 641414 2740057 03459 18482 04837 1043001 44355 03036 01 31243 00417 178836 01486 15917 22469 06307 71325 30963 72514 01405 19276 218121 102629 684281 1479467 383548 588276 1089621 37107 55067 0805 85518 15417 843984 9385507 101387 03162 2517846 0 135598 21423406 3175189 511009 371065 218121 2451 62264 47169 269326 3656006 684366
186 433033164 73375015 867765 676099 2507971 671238 281798 03669 19663 05239 1125698 45582 03115 01067 31891 00429 18506 01619 169581 23769 06841 762396 3207 7744 01454 20091 229999 109689 725827 1559375 398227 615963 1119706 396025 570644 0862 93147 16195 882599 971358 108043 03457 2591316 0 140381 22197629 3269388 526941 396019 229999 26328 64165 50043 273629 38495705 725918
187 436329062 66922847 7985676 617234 2439078 644435 2547927 03206 16962 04337 923902 41163 02833 00921 2868 00392 164437 01311 146909 21092 05635 65571 28191 65259 0129 19397 210028 96685 679347 1438193 381735 573865 1120289 351393 560384 07834 77932 16007 832386 9428972 95666 02862 2558507 0 137795 21471216 3203411 513796 351388 210028 22924 61948 45072 260426 362687875 679432
188 501372383 95002676 11072416 874043 2768458 793734 3877832 054 29896 08711 1749341 63047 04237 01614 45048 00576 266934 02751 254808 33581 11483 116314 47645 117959 02106 23658 311449 160278 928444 2065771 479206 796619 1284231 57049 680104 12084 15013 18094 1118042 11645947 156587 05675 2982958 0 165942 26774353 3777099 60786 570481 31145 39399 75651 69859 328078 4754195 928561
189 523637695 104034453 12072527 956702 2916008 842744 4167044 05883 32656 09606 1985091 67655 04539 01764 48284 00617 287929 03064 27834 36452 12669 1272988 51503 131369 02272 25034 337313 175369 992318 2227886 508499 855748 1345992 62293 717929 13127 166414 18898 119647 12334379 171111 06304 3133279 0 175412 28390537 3974153 640067 622921 337314 43259 80114 75957 347433 51024665 992444
190 510116523 105199639 12180325 967191 2904136 839198 4224749 06001 33353 09845 2040769 68646 04596 01802 48999 00624 292772 03148 284094 3712 12995 1300601 52435 134568 02311 24926 340637 178174 995043 2244696 507615 860476 1315009 632154 706271 13217 170289 18612 1197995 12214474 173678 06459 3084567 0 172719 28165559 3930524 635055 632145 340638 44031 79843 76889 348596 5106909 995166
191 503891562 105700977 12230387 971735 2924994 840322 4249734 06046 33593 09908 2059337 69077 04623 01816 49265 00628 29454 0317 286142 3742 13082 1310098 52735 135682 02325 24989 342152 17907 997955 2253701 509089 863755 1304632 635239 702278 1323 171288 18576 1200693 12188588 174473 06498 3074044 0 171926 28131846 3927404 635797 63523 342154 44262 80042 77244 35068 51178825 998079
192 544858086 105312734 12261509 968791 3082353 871822 4221925 05895 3254 09418 1931802 68663 04611 01759 48831 00628 289827 02983 277625 36816 12417 1266768 51581 129416 02285 26099 341898 175032 1015488 2266757 528848 875917 1409757 623227 74485 13146 163151 19814 1228818 1279431 170967 06161 3283715 0 182207 29432878 4166435 671874 623218 341899 4297 83736 76476 362433 52152005 1015614
193 476778438 77749429 9209822 71653 2644341 714915 2986949 0384 20618 05523 1184799 4813 03304 01118 3385 00455 195686 01705 177915 24792 07193 799032 33978 81425 01538 21429 244699 116469 772873 1659478 424661 655869 1226457 42068 620931 09251 98658 17364 943539 1048174 11484 0366 2803787 0 152545 23913462 3514915 563255 420673 2447 27938 68472 53193 289938 4102799 77297
194 449196914 6732082 8041113 620969 2439078 64876 2547578 03197 16921 04334 923512 41112 02833 00919 28676 00392 164308 01309 146596 21014 05627 654148 28182 65177 01289 1954 211103 97073 683947 1446197 384249 577074 1148655 352918 572572 07935 78124 16201 839693 9574733 96115 02868 2602206 0 140654 21776494 3243127 51826 352913 211104 2301 62359 45286 260426 36511305 684033
195 492119414 94837139 11046455 872464 2768458 790245 3878569 05419 29981 08717 1750161 63155 04237 01619 45056 00576 267203 02753 255463 33744 115 1166415 47664 118123 02108 23562 310663 159977 925157 2060046 477474 794333 1266519 569321 672527 12013 149954 17957 111318 11553611 156247 05669 2955917 0 164188 26580769 3751902 605308 569313 310664 39332 75391 69701 328078 47305865 925272
196 484653867 10296874 11918015 946649 2916008 826995 4169432 05945 32932 09625 198776 68005 04539 01781 48312 00617 288806 03071 280473 36984 12725 1283649 51565 131915 02279 24608 334006 174135 978106 2203459 500962 84597 1263255 618126 682209 12818 165747 1832 1174615 11907894 169742 06282 3006566 0 167021 27497097 3858349 627449 618117 334007 42983 789 75296 347433 5005759 978228
197 468224805 104244414 12032341 958103 2904137 821897 422726 06066 33644 09866 2043577 69014 04596 01819 49028 00624 293694 03156 286336 37679 13053 1311811 52501 135152 02318 24466 337149 17687 979621 2218662 499595 850125 1234175 62706 670483 12907 169587 18011 1175305 11787462 172309 06436 2957863 0 16429 27267686 3813175 621633 627051 33715 43739 7855 76188 348596 5001863 979742
198 479718555 105501494 12184573 969713 2924994 830722 4251681 06096 33818 09924 2061509 69362 04623 01829 49288 00628 295254 03177 287877 37853 13127 1318775 52786 136138 0233 24722 339983 17827 989069 223816 504376 857595 1256544 632121 682547 13052 170824 18256 1187483 11956486 173687 06482 3003143 0 167123 27632395 3862603 628598 632112 339984 44081 79275 7682 35068 50560935 989193
199 507036484 104535312 12142426 961406 3082353 858174 4223745 05942 3275 09433 1933838 6893 04611 01771 48852 00628 290496 02989 279251 37221 12459 1274894 51628 129845 0229 25677 338464 173757 100186 2242014 521251 865957 1332349 6183 711733 12865 162439 19304 1207363 12399872 169653 06138 3164822 0 174296 28594998 4056819 659559 618291 338465 42685 82476 75798 362433 51316645 1001985
200 4291425 76164351 8988975 701649 2644341 69841 2988514 03881 208 05536 1186551 48359 03304 01128 33869 00455 196261 0171 179314 25141 07229 806025 34018 81792 01542 20903 240651 114987 755704 1629651 415406 643947 1134162 414897 581117 08912 97879 16707 917784 10004016 113266 03634 2660045 0 143129 22901084 3381587 547889 414891 240652 27609 6696 5239 289938 40087695 755798
201 414913398 65957471 7858538 608232 2439078 636319 2548572 03223 17036 04342 924622 41258 02833 00925 28687 00392 164673 01313 147484 21235 0565 658584 28208 65411 01292 19164 208241 96034 671511 1425056 37767 568637 108115 348847 544025 07686 77587 15712 821387 923062 94962 02851 2498573 0 133927 21047625 3147417 507205 348842 208242 22779 61267 4472 260426 358340475 671595
202 484641602 94245527 10974386 866995 2768458 786479 3878844 05426 30012 08719 1750471 63195 04237 01621 45059 00576 267304 02754 255709 33806 11506 1167649 47671 118194 02108 23475 310002 159724 922319 2055047 47591 792294 1251418 568361 665434 11951 149825 17832 110881 11466925 155951 05664 2930829 0 162593 26401084 3728215 602018 568353 310003 39276 75082 69565 328078 4714359 922434
203 524579883 103643984 12030052 953135 2916008 841569 4167108 05885 32664 09606 1985165 67664 04539 01765 48285 00617 287954 03064 278399 36466 12671 127328 51504 131387 02272 2504 337379 175373 992427 222814 50859 855841 1346991 622978 717404 13121 166412 18877 119658 1232666 171078 06304 3132526 0 175415 2838125 3973052 63948 622969 33738 4326 80072 75962 347433 51032785 992551
204 511148203 104983652 12156962 96522 2904136 83969 4224742 06 33352 09845 2040759 68645 04596 01802 48999 00624 29277 03148 284088 37119 12995 1300573 52435 134568 02311 24937 340702 1782 995457 2245244 507761 860647 1322636 632255 708996 1324 170309 18644 1198981 12245485 17375 0646 3094034 0 17339 28227639 3937558 635277 632246 340703 44037 79851 76903 348596 51117265 995579
205 494995859 105593164 12213384 970708 2924994 836909 4250807 06073 33717 09917 2060536 69234 04623 01823 49278 00628 294934 03174 287099 37659 13107 1314885 52763 135933 02328 24896 341294 178758 994849 2247889 507336 861401 1290197 63403 696845 13174 171097 18484 1196221 12124623 174204 06491 3053715 0 170566 27986409 3908074 633372 634021 341295 44191 7976 77082 35068 5095164 994974
206 533839492 105399277 12268152 969559 3082353 868282 4223143 05927 32681 09428 1933169 68842 04611 01767 48845 00628 290276 02987 278716 37088 12445 1272224 51613 129701 02289 25984 340876 174655 1011827 2259645 526642 872963 1389777 621783 73623 13072 16294 19688 1222822 1269275 170617 06154 325282 0 180165 29213418 4137359 668422 621774 340877 42887 8338 76277 362433 51923385 1011953
207 476864883 78021787 9246307 719074 264434 714709 29872 03847 20648 05525 1185081 48167 03304 01119 33853 00455 195779 01706 178141 24848 07199 800158 33984 81486 01538 21434 244698 116473 772916 1659636 424712 655914 1228626 420697 622412 09258 98655 17381 943971 10499733 114868 0366 2808427 0 152862 23945813 3518981 563534 420692 244699 27939 68471 53196 289938 410243825 773013
208 445999766 67436274 8055095 622036 2439078 647313 2547833 03203 16951 04336 923798 41149 02833 0092 28679 00392 164402 0131 146825 21071 05632 655291 28189 65236 0129 19511 210848 96985 682725 144446 383743 576418 1147303 352557 572922 07924 78064 16174 8389 957679 96043 02866 2601999 0 140683 21772288 324213 517981 352552 210848 22989 62288 45239 260426 36424665 68281
209 472785469 94697012 11016262 871061 2768458 782554 3880029 05457 3015 08729 1751794 63369 04237 01629 45073 00576 267739 02758 256767 3407 11533 1172938 47702 118459 02112 23355 309061 15941 918105 2048412 473864 789717 1228873 567064 657733 11875 149655 17703 1103238 11378469 155665 05659 29018 0 160579 26201936 370263 599743 567056 309062 39205 74827 69392 328078 46811125 918219
210 481044219 103465703 11973818 951203 2916008 82403 4170384 0597 33042 09633 198882 68144 04539 01787 48323 00617 289155 03074 281319 37195 12746 1287882 51589 132149 02281 24572 33382 17407 976532 2201805 500478 845425 1259823 61784 680867 12798 165711 18271 1173432 11894218 169705 06281 3002022 0 166683 27464414 3854222 626511 617832 333821 42967 78818 75257 347433 49911685 976655
211 479501172 104780957 12105438 963125 2904136 825715 4227133 06062 33629 09865 2043438 68995 04596 01818 49026 00624 293649 03156 286225 37652 1305 1311259 52498 135136 02317 2459 338057 177207 983584 2225571 501779 852924 1257601 628373 681487 12991 169748 18172 1181753 11918835 172677 06441 2996377 0 166857 2753863 3848744 625447 628365 338058 43813 78881 76372 348596 5026754 983707
212 489967422 105643008 12211602 971102 2924994 834542 4251039 0608 33744 09919 2060797 69268 04623 01824 4928 00628 29502 03175 287309 37711 13112 1315934 52769 135992 02328 24834 340863 178589 992845 2244516 506305 860082 1276818 633396 69037 13126 171006 18396 1192815 12048998 174011 06488 3031837 0 169049 27833271 3888593 631364 633387 340864 44153 79569 76991 35068 50818255 992968
15010134101 2907447588 338906633 26749425 86653198 24300952 116121122 161073 886044 254096 52666292 1887825 126966 47921 1339128 17312 7931596 80409 7568148 1010458 334775 34482032 140709 3529457 62521 725221 9364562 4766655 28009183 62249139 14646134 24095161 38918082 16994929 205379 358933 4410037 555377 3383826 353637793 4660906 166325 91011697 0 5030087 813094019 115656819 18679581 16994688 936459 1168126 2322596 2090508 10087629 14479505425 28012676
Page 15: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Findings on Using ASD

bull Why are NOx emissions increased with ASD application

bull More lower speed bins are included when computing emissions with the ASD approach

bull Why are PM25 emissions decreased with ASD in cities while increased in highwaysbull The single NEI average speed assigned for urban roads was relatively lower than used in ASDbull The single NEI average speed assigned for rural roads was relatively higher than ASD

bull Why do VOC emissions show different patterns between Dallas and Phoenixbull Most of metro cities show relatively lower estimated VOC while Dallas TX and Phoenix AZ show

increasesbull Higher average speed for urban unrestricted roads from Dallas and Phoenixbull Higher contribution of urban unrestricted roads from Dallas and Phoenix bull Contributions of road and vehicle types by region andor average speed played a key role

ASD approach is a better representation of actual driving patterns by road type

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 16

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 16: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

NOx Humidity Correction

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 17

Humidity impacts NOx emissionsbull Spark-Ignition engines

bull Compression Ignition Diesel

The NOx Humidity Correction Equation differs by fuel Type

1 Gasoline Ethanol and CNG2 Diesel

Compute the Correction Using1 MOVES Model (Month-humiditycounty)

2 SMOKE-MOVES Integration ToolThe humidity correction equation has been coded into the latest version of SMOKE-MOVES thus allowing the adjustment to be applied according to hourly changes in humidity instead of seasonal averages

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 17: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Percent Change on RPD NO2

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

January 1 2014 July 1 2014

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 18

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 18: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Percent Change in Monthly Total NOx(January and July)

19International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019)

January July

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 19: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

New Jersey NOx Correction Sensitivity Runs

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 20

To assess the true impacts of NOx humidity correction perform the sensitivity runs based on the following MOVES EFs

1 MOVES Native MOVES EFs without NOx Correction

2 MOVES-NOx MOVES EFs with NOx Correction applied by MOVES

3 SMOKE-MOVES MOVES EFs with NOx Correction applied by SMOKE-MOVES

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 20: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 21

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 21: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

NJ Monthly Total NOx Changes between the Methods

RPD MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 3590 4701 31 4252 18July 4517 4961 10 4354 -4

RPV MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 1127 1115 -1 1390 23July 870 866 0 832 -4

RPH MOVES(tonsmonth)

MOVES-NOx(tonsmonth)

MOVES-NOx Perc Diff ()

SMOKE-MOVES(tonsmonth)

SMOKE-MOVES Perc Diff ()

January 100 114 14 115 15July 128 128 -1 124 -3

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 22

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 22: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Findings from the NJ NOx Humidity Adjustment

bull Significant Impacts to NOx emissions for RPD RPV and RPH processesbull US western regions with lower humidity will see an increase of NOxbull US eastern regions with higher humidity will see a decrease in NOxbull The Winter drier season (January) shows the significant increases of

NOx from all processesbull Summer season (July) shows up to 4 decrease of NOx from all

processesbull RPD NOx MOVES-NOx case shows higher impacts compared to

SMOKE-MOVES casebull These findings are limited to New Jersey stateInternational Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 23

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 23: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Spatial Allocation using Spatial Surrogates

bull Spatial allocation is the process of mapping county-level emissions inventory data to modeling grid cells

bull We do this using spatial surrogates - each has a unique code (ID)bull There are more than 60 surrogates currently used ndash eg Population (100) Total agriculture

(310) Railroad Density (261) Offshore shipping (806) Urban unrestricted daily VMT (222) Gas well count (698)

bull Surrogates have been created using the Surrogate Tool (from wwwcmascenterorg)

bull Value = sum of attribute in grid cellsum of attribute in county

bull Values sum to 1 for each county province

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 24

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 24: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

New Postgres Spatial Surrogate Tool

bull Written in the PostgreSQL and PostGIS database languagebull Released on June 30 2019 bull Download from CMAS Center Spatial Allocator Github Repository

httpsgithubcomCMASCenterSpatial-Allocator

bull PostgreSQL uses a 3-tier hierarchy for data storage database schema and table A single query can access multiple tables and multiple schemas but only one database

bull Requires ReadCreateUpdateInsert access for databasesbull Supports multicore-Processing for Multiple Jobs running in parallel

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 25

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 25: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Steps performed in the PG Surrogate Tool

Create a modeling domain table and insert it into the PostgreSQL Database

Load the geographic boundaries data shapefile and then reproject them to match the output modeling domain

Overlay with geographic boundaries and then calculate the attribute value in the county (ie surrogate denominator)

Overlay grid modeling domain and compute the gridded surrogate weight (ie the numerator)

Generate Surrogates using the Surrogate Tool input files

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 26

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 26: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

SMOKE v47 Public Release

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 27

bull Plan to release in 2019

bull Average Speed Distribution

bull NOx Humidity Correction

bull A few bug fixes and minor updates

bull Future Updatesbull New Rate-Per-Start (RPS) Process

bull New Off-network Idling (ONI) Process

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 27: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Acknowledgement

International Emissions Inventory Conference at Dallas TX (July 29 ndash August 2 2019) 28

bull US EPA Office of Air Quality Planning and Standard (OAQPS)bull US EPA Office of Transportation Air Quality (OTAQ)bull US EPA Office of Research Development (ORD)

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 28: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Road Types Distribution by Region

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 29: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Average Speed by Road type

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)
Page 30: SMOKE version 4.7 Recent Enhancements€¦ · • Higher average speed for urban unrestricted roads from Dallas and Phoenix • Higher contribution of urban unrestricted roads from

Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)

  • SMOKE version 47Recent Enhancements
  • Outline
  • Slide Number 3
  • Background on Speeds in MOVES and SMOKE-MOVES
  • Examples of Average Speed Distributions
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Unrestricted)
  • Current 24-hours Speed Profiles by MOVES source type (Gasoline-Urban Restricted)
  • Impact of Speed by Pollutant and Vehicle TypeFuel Gasoline
  • Impact of Speed by Pollutant and Vehicle TypeFuel Diesel
  • Improved Representation of Speeds in SMOKE-MOVES
  • Difference in July NOx
  • Difference in July PM25
  • Difference in July VOC
  • Comparison between Interpolation vs ASD
  • Findings on Using ASD
  • NOx Humidity Correction
  • Percent Change on RPD NO2
  • Percent Change in Monthly Total NOx(January and July)
  • New Jersey NOx Correction Sensitivity Runs
  • New Jersey NOx Adjustment Sensitivity(MOVES ndash SMOKE-MOVES)
  • NJ Monthly Total NOx Changes between the Methods
  • Findings from the NJ NOx Humidity Adjustment
  • Spatial Allocation using Spatial Surrogates
  • New Postgres Spatial Surrogate Tool
  • Steps performed in the PG Surrogate Tool
  • SMOKE v47 Public Release
  • Acknowledgement
  • Road Types Distribution by Region
  • Slide Number 29
  • Urban Unrestricted ASD by SCC (Weekday=5 Hour =18)