slides 1.5 heat capacity
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Capacidad Calorífica - Termodinámica.en el documento se exponen conceptos básicos relacionados con capacidades caloríficas a volumen y presión constantes, así como su deducción a partir de ecuaciones baseTRANSCRIPT
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Heat Capacity
Basic Physical Chemistry - Thermodynamics 1
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2 Basic Physical Chemistry - Thermodynamics
Heating Objects
Heat Capacity, C, is the heat energy required to
raise the temperature of an object by 1 °C or 1 K.
Low
Heat
Capacity
High
Heat
Capacity
C = q / DT [6]
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3 Basic Physical Chemistry - Thermodynamics
Definitions of Heat Capacity
Heat capacity is an extensive property.
Specific Heat Capacity, Cs = C / m units J K–1 kg–1
Molar Heat Capacity, Cm = C / n units J K–1 mol–1
Specific Heat capacity and Molar Heat Capacity
are intensive properties.
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130
140 390
440
710
710
1340 2000
2010
4 Basic Physical Chemistry - Thermodynamics
520
Specific heat capacities of substances / J K–1 kg–1
880
1670
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5 Basic Physical Chemistry - Thermodynamics
Isochoric and Isobaric Heat Capacities
Isochoric heat capacity is defined as:
CV = qV / DT = DU / DT [7]
Isobaric heat capacity is defined as:
Cp = qp / DT = DH / DT [8]
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Hm = Um + pVm
H = U + pV
For an ideal gas: pV = nRT
pVm = RT
6 Basic Physical Chemistry - Thermodynamics
RT = 8.314 J K–1 mol–1 × 298 K ~ 2.5 kJ mol–1
Hm = Um + RT
This is not negligible for a gas.
Cp,m & CV,m Relationship for an Ideal Gas
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For a change of temperature DT
Hm = Um + RT
DHm = DUm + RDT
DHm
DT=DUm
DT+ R
7 Basic Physical Chemistry - Thermodynamics
Cp,m = CV,m + R [9]
Cp,m & CV,m Relationship for an Ideal Gas
where R = 8.314 J K–1 mol–1
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