silane

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Silquest A-1100* silane

Version 10.0 Print Date 28.12.2012 Revision date 13.08.2012 OSI000000006

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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier

Trade name : Silquest A-1100* silane CAS : 919-30-2 REACH Registration No. : 01-2119480479-24-XXXX

1.2 Relevant identified uses of the substance or mixture and uses advised against

1.2.1 Usage : ES 1: Production On-site Industrial use ES 2: Intermediate Downstream industrial site ES 3: monomer Downstream industrial site ES 4: Formulation of: Coatings Downstream industrial site ES 5: Coatings Industrial use ES 6: Coatings Industrial use ES 7: Coatings Professional use Consumer use ES 8: Formulation Non-metal Surface treatment Industrial use ES 9: Non-metal Surface treatment In situ treatment ES 10: Formulation of: Sealants ES 11: Sealants Industrial use ES 12: Sealants Professional use Consumer use ES 13: Laboratory chemical

1.2.2 Uses advised against : None known.

1.3 Details of the supplier of the safety data sheet

Company: : Momentive Performance Materials GmbH Chempark Leverkusen Gebaeude V7 DE - 51368 Leverkusen

Telephone : + 40 213044229 Information contact: : [email protected]

1.4 Emergency telephone

24 Hour Emergency Telephone : Europe, Israel & All other: +44 (0) 1235239670; Middle East:+44 (0) 1235239671

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:

Classification according to Regulation (EC) No 1272/2008 as amended

Acute toxicity Category 4; Oral; H302; Skin corrosion/irritation Category 1B; H314; Skin sensitizer Category 1; H317;




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Classification according to Directive 67/548/EEC or 1999/45/EC as amended:

Corrosive; C; R34; Harmful; Xn; R22; SENSITIZER; Xi; R43;

2.2 Label elements

GHS-Labelling Regulation (EC) No. 1272/2008:

Hazard pictograms

Signal words: danger

Hazard statements H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction.

Precautionary Statement - Prevention: P260 Do not breathe dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary Statement - Response: P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P303+P361+P353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.

Precautionary Statement - Disposal: P501 Dispose of contents/container to an approved incineration

Labelling according to EC Directives

Hazardous components which must be listed on the label:

gamma-Aminopropyltriethoxysilane Symbol(s) : C Corrosive R-phrase(s) : R22 Harmful if swallowed.

R34 Causes burns. R43 May cause sensitisation by skin contact.

S-phrase(s) : S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.




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S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

S60 This material and its container must be disposed of as hazardous waste.

2.3 Other hazards

None known.

Not fulfilling PBT (persistent/bioaccumulative/toxic) criteria Not fulfilling vPvB (very persistent/very bioaccummulative) criteria

3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture Substances

Hazardous Component(s)

Chemical name CAS-No.; EC No.; REACH

Registration No.

Concentration %

EU Classification

Regulation (EC) No. 1272/2008

gamma-Aminopropyltriethoxysilane

919-30-2; 213-048-4; 01-2119480479-24-XXXX;

>= 99,000 C;R34, R22, R43;

Category 4; Acute Tox.; H302;

Category 1B; Skin Corr.; H314;

Category 1; Skin Sens.; H317;

4. FIRST AID MEASURES

4.1 Description of first aid measures

Inhalation : Move the exposed person to fresh air at once.

Skin contact : Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water. Wash contaminated clothing before reuse.

Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist.

Ingestion : If conscious, drink plenty of water. Do NOT induce vomiting.




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4.2 Most important symptoms and effects, both acute and delayed

This material reacts immediately with water in the acid contents of the stomach to produce ethanol.

4.3 Indication of any immediate medical attention and special treatment needed

DO NOT induce vomiting. Get medical attention immediately. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water.

5. FIRE-FIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

: Alcohol resistant foam. Carbon dioxide Dry chemical.

Unsuitable extinguishing media

: None known.

5.2 Special hazards arising from the substance or mixture:

Material reacts with water.

5.3 Advice for firefighters:

Wear self-contained breathing apparatus and protective clothing. Do not use water jet as an extinguisher, as this will spread the fire. Use water spray to keep fire-exposed containers cool.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:

Avoid contact with eyes, skin, and clothing. Avoid contact with liquid and vapors. Use personal protective equipment.

6.2 Environmental precautions:

Avoid release to the environment.

6.3 Methods and material for containment and cleaning up:

Absorb spillage with suitable absorbent material. Shovel up and place in a container for salvage or disposal.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Handling : Do not taste or swallow. Avoid contact with eyes, skin, and




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clothing. Avoid breathing mists or vapors. Wash hands after handling.

Advice on protection against fire and explosion

: All equipment used when handling the product must be grounded.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Keep container tightly closed. Keep away from sources of ignition - No smoking.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Occupational exposure limits

Contains no substances with occupational exposure limit values.

DNEL-Values: GAMMA-AMINOPROPYLTRIETHOXYSILANE

Area of use Value

workers; Dermal; Acute, Systemic Toxicity 8,3 mg/kg bw/day

workers; Inhalation; Acute, Systemic Toxicity 59 mg/m3

workers; Dermal; long term, Systemic Toxicity 8,3 mg/kg bw/day

workers; Inhalation; long term, Systemic Toxicity 59 mg/m3

PNEC-Values: GAMMA-AMINOPROPYLTRIETHOXYSILANE

Area of use Value

Water 0,33 mg/l

Seawater 0,033 mg/l

Intermittent release 3,3 mg/l

Sediment Derived from PNEC(freshwater) using the equilibrium partitioning method.

0,26 mg/kg

Soil Derived from PNEC(freshwater) using the equilibrium partitioning method.

0,04 mg/kg

Sewage treatment plant 13 mg/l

8.2 Exposure controls

Appropriate engineering controls

Provide eyewash station and safety shower. General (mechanical) room ventilation is expected to be satisfactory if handled at low temperatures or in covered equipment.




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Personal protective equipment (ppe)

Respiratory Protection : Respiratory protection mask with Filtertype ABEK

Hand protection : Advice: This recommendation is valid only for our Product as delivered. If this product will be mixed with other substances you need to contact a supplier of CE approved protective gloves (e.g. KCL GmbH, D-36124 Eichenzell, Tel. 0049 (0) 6659 87300, Fax. 0049 (0) 6659 87155, email: [email protected]). Material: 730 Camatril Minimum break through time: 480 min Glove thickness: 0,4 mm Producer: KCL GmbH, D-36124 Eichenzell, Tel. 0049 (0) 6659 87300, Fax. 0049 (0) 6659 87155, email: [email protected].

Eye protection : Face shield

Safety glasses with side-shields conforming to EN166

Skin and Body Protection : Safety shoes Wear suitable protective clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance : Liquid Colorless

Odor : amine like

Odor Threshold : No data available.

pH : 10,5 at100 g/lConcentration: 100 g/l

Melting Point : <-70 °C

Boiling point/boiling range : 220 °C at 1.013 hPa

Flash Point : 93 °C Method: ASTM D 93

Evaporation Rate : <1

Lower explosion limit : Not applicable

Upper explosion limit : Not applicable

Vapour pressure : 0,02 hPa at 20 °C




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Vapor Density : >1

Density : 0,9500 g/cm3 at 25 °C (1,013 hPa)

Solubility(ies) No data available. Partition Coefficient: n-octanol/water

: Log Pow (n-Octanol/Water Partition Coefficient): 1,7 at: 20 °C Method: Calculated

Autoignition Temperature : 270 °C at 1.010 hPa

Thermal decomposition : Note: No decomposition if stored and applied as directed.

Viscosity, dynamic : 2 mPa.s at 20 °C

Viscosity, kinematic : No data available.

Explosive properties : Not classified

Oxidizing properties : Not applicable

10. STABILITY AND REACTIVITY

10.1 Reactivity:

Material is stable under normal conditions.

10.2 Chemical stability:

Water reactive material.

10.3 Possibility of hazardous reactions:

Hazardous polymerisation does not occur. No dangerous reaction if used as recommended.

10.4 Conditions to avoid:

Avoid contact with: Moisture. Water

10.5 Incompatible materials:Reaction with water or other aqueous media is rapid and exothermic. The addition of small amounts of water (in the range of 2-15%) can produce an exothermic reaction which generates alcohol to the extent that the resulting solution can reach a temperature which




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exceeds the flash point of the new solution. If a water solution is desired, add the product to water, and not vice versa.

10.6 Hazardous decomposition products:Carbon oxides, Nitrogen Oxides, Oxides of silicon.

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute oral toxicity : LD50 Rat males Dose: 2.830 mg/kg

: LD50 Rat female Dose: 1.570 mg/kg

Acute inhalation toxicity : LC50 Rat males Result: 5 ppm Exposure time: 6 h Method: OECD Test Guideline 403

: LC50 Rat female Result: 16 ppm Exposure time: 6 h Method: OECD Test Guideline 403

Acute dermal toxicity : LD50 Rabbit male and female Dose: 4.290 mg/kg

Skin irritation. : Rabbit Result: Corrosive Classification: Corrosive Method: OECD-Guideline 404 (Acute Dermal Irritation/Corrosion)

Eye irritation : Rabbit Result: Strongly irritating. Method: OECD-Guideline 405 (Acute Eye Irritation/Corrosion)

Sensitization : Guinea Pig Result: positive Classification: SENSITIZER

Repeated dose toxicity : Oral Rat Dose: Daily dosage Exposure time: 90 d NOAEL: 200 mg/kg




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: Oral Rat

Dose: Daily dosage Exposure time: 90 d LOAEL: 600 mg/kg

Genetic Toxicity in vitro : Test type: Ames-Test Result: negative

: Test type: Chinese Hamster Ovary (CHO) Result: negative

: Test type: Chromosomal aberration Result: negative

12. ECOLOGICAL INFORMATION

12.1 Toxicity

The product degrades through hydrolysis into alcohols and silanol- and/or siloxanol compounds.

Ecotoxicity effects

Toxicity to fish : static test LC50 Species: Brachydanio rerio Dose: > 934 mg/l Exposure time: 96 h Method: OECD Test Guideline 203

Toxicity to other organisms : static test EC50 Species: Daphnia magna Dose: 331 mg/l Exposure time: 48 h Method: OECD-Guideline 202

Toxicity to algae : static test EC50 Species: Desmodesmus subspicatus (green algae) Dose: > 1.000 mg/l Exposure time: 72 h

: static test NOEC Species: Desmodesmus subspicatus (green algae) Dose: 1,3 mg/l Exposure time: 72 h

Toxicity to microorganisms : static test EC10 Species: Pseudomonas putida Dose: 13 mg/l Exposure time: 5,75 h

: static test EC50 Species: Pseudomonas putida




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Dose: 43 mg/l Exposure time: 5,75 h

12.2 Persistence and degradability

Elimination information (persistence and degradability)

Persistence and degradability

: Exposure time: 28 d 67 % Not readily degradable. hydrolyses

12.3 Bioaccumulation

: Species: Cyprinus carpio Bioconcentration factor (BCF): 3,4 Method: Measured The product is not bioaccumulating.

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

Not fulfilling PBT (persistent/bioaccumulative/toxic) criteria Not fulfilling vPvB (very persistent/very bioaccummulative) criteria

12.6 Other adverse effects

None known.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product : Can be incinerated when in compliance with local regulations. Contaminated packaging : Dispose of as unused product.

14. TRANSPORT INFORMATION

Land transport

ADR: UN-Number 3267 Class 8 Packing group II Classification Code C7 Hazard identification No 80 ADR/RID-Labels 8 Proper Shipping Name CORROSIVE LIQUID, BASIC, ORGANIC,

N.O.S. Contains gamma-Aminopropyltriethoxysilane




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RID Class No.:

UN-Number 3267

Class 8 Packing group II Classification Code C7 Hazard identification No 80 ADR/RID-Labels 8 Proper Shipping Name CORROSIVE LIQUID, BASIC, ORGANIC,


Inland waterway transport

ADNR: UN-Number 3267 Class 8 Packing group II Classification Code C7 Hazard identification No 80 ADNR-Labels 8 Proper Shipping Name CORROSIVE LIQUID, BASIC, ORGANIC,


Sea transport

IMDG: UN-Number 3267 Class 8 Packing group II IMDG-Labels 8 EmS F-A, S-B Proper Shipping Name CORROSIVE LIQUID, BASIC, ORGANIC,


Air transport

ICAO/IATA: UN-Number 3267 Class 8 Packing group II ICAO-Labels 8 Proper Shipping Name Corrosive liquid, basic, organic, n.o.s. Contains gamma-Aminopropyltriethoxysilane

Further Information : Keep away from food, drink and animal feedingstuffs.

Protect from moisture.




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15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

None known.

15.2 Chemical safety assessment

A Chemical Safety Assessment has been performed on this substance.

Inventories

Australia Inventory of Chemical Substances (AICS)

y (positive listing)

EU list of existing chemical substances


Japan Inventory of Existing & New Chemical Substances (ENCS)


China Inventory of Existing Chemical Substances


Korea Existing Chemicals Inventory (KECI)


Canada DSL Inventory y (positive listing) Canada NDSL Inventory n (Negative listing) New Zealand Inventory of Chemicals


Philippines Inventory of Chemicals and Chemical Substances (PICCS)


TSCA list y (positive listing) For inventories that are marked as quantity restricted or special cases, please contact Momentive.

16. OTHER INFORMATION

Wording of the R-phrases and H-statements in section 2 and 3

H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction. H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction.




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R22 Harmful if swallowed. R34 Causes burns. R43 May cause sensitisation by skin contact.

Momentive Products are intended for industrial application only. They are not intended for specific medical applications, neither for long-lasting (> 30 days) implantation into the human body, injected or directly ingested, nor for the manufacture of multiple usable contraceptives.

Further Information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

silane

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