si–c shock activation of green mixtures for shs production of si–c composites sergey skiba, gh....

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Shock activation of green mixtures for SHS production of Si–C Si–C composites Sergey Skiba, Gh. Sergey Skiba, Gh. G. Pak G. Pak XII International symposium on explosive production of new materials: science, technology, business and innovations (EPNM-2014) Cracow 2014

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1 –electrical detonator; 2 – charge of ES; 3 – plate-piston; 4 – activated powder; 5 – container of conservation; 6 – plate-basic; 7 - ground; 8 –elements for fixation weld gap. Parameters 1234 Тhickness of plates- foundation, мм 12 Height of ES, мм Height weld gap, мм Detonation velosity, м/s 3600 Percussion velosityдарения, м/s Share of the reflected wave, % 20 Progress of SHS process --++ Shock-wave activation

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Page 1: Si–C Shock activation of green mixtures for SHS production of Si–C composites Sergey Skiba, Gh. G. Pak XII International symposium on explosive production

Shock activation of green mixtures for SHS production

of Si–CSi–C composites

Sergey Skiba, Gh. G. PakSergey Skiba, Gh. G. Pak

XII International symposium on explosive production of new materials: science, technology, business and innovations

(EPNM-2014)

Cracow 2014

Page 2: Si–C Shock activation of green mixtures for SHS production of Si–C composites Sergey Skiba, Gh. G. Pak XII International symposium on explosive production

Si + C = SiC+Q

System Q, кДж/кg Tad, К,

Ti + B 2770 25005Ti + 3Si 1790 2350

Ti + C 2990 3070Tа + C 670 2550Si + C 73 1800

Methods of increase reactionary ability of Si-C system

SHS in additional electric field

SHS systems Si-C in the environment of nitrogen

Chemical activation of SHS process

Mechanical activation of initial mix

SHS with preliminary heating of a reactionary layer

Heat and combustion temperature for some SHS sytems

Increase of reaction ability

Page 3: Si–C Shock activation of green mixtures for SHS production of Si–C composites Sergey Skiba, Gh. G. Pak XII International symposium on explosive production

1 –electrical detonator; 2 – charge of ES; 3 – plate-piston; 4 – activated powder; 5 – container of conservation; 6 – plate-basic; 7 - ground; 8 –elements for fixation weld gap.

Parameters 1 2 3 4Тhickness of plates-foundation, мм 12

Height of ES, мм 60 60 65 65Height weld gap, мм 2 3

23

Detonation velosity, м/s

3600

Percussion velosityдарения, м/s

600 670 700 750

Share of the reflected wave, % 20

Progress of SHS process

- - + +

SShock-wave activationhock-wave activation

Page 4: Si–C Shock activation of green mixtures for SHS production of Si–C composites Sergey Skiba, Gh. G. Pak XII International symposium on explosive production

Before activation

Microstructure of Si-C powder

After activation

Page 5: Si–C Shock activation of green mixtures for SHS production of Si–C composites Sergey Skiba, Gh. G. Pak XII International symposium on explosive production

E-mail: [email protected]

Тел./fax. : 8 (8412) 38 84 93

XII International symposium on explosive production of new materials: science, technology, business and innovations

(EPNM-2014)

Thank you for your attentionThank you for your attention!!