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    Set IV

    Section A

    1. Which of the following organic compounds undergoes addition reaction?

    A. Propane B. Propene C. Propan-1-ol D. Propanoic acidb

    2. Which of the following is the chemical name for common salt?

    A. Sodium sulphate B. Sodium carbonate C. Sodium chloride

    D. Sodium bromide c

    3. What is the systematic name for the following organic compound?

    H H H H

    HCC==CCCH

    H H H

    HCH

    HCH

    H

    A. 2-ethylpent-2-ene B. 3-methylhex-3-ene

    C. 3-methylhex-4-ene D. 4-ethylpen-2-ene b

    4. A sequence of reactions involving ethene is as follows.

    Reaction I Reaction II

    C2H4 C2H5OH CH 3COOH

    Which of the following represents Reaction I and Reaction II?

    Reaction I Reaction II

    A. Esterification Oxidation

    B. Hydration Reduction

    C. Dehydration Oxidation

    D. Hydration Oxidation d

    5. Isomers of an organic compound have similarI physical properties

    II chemical properties

    III structural formula

    IV relative molecular mass

    A. I and III only B. II and IV only C. I, II, and III only

    D. II, III, and IV only b

    6. Which of the following ions does not produce a white precipitate when sodium hydroxide solution is added in

    excess?

    I Zn 2+

    II Al 3+

    III Pb 2+

    IV NH4+

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    A. I and III only B. II and IV only C. I, II, and III only

    D. I, II, III, and IV d

    7. The figure below shows the cooling curve of acetamide.

    temperature/oC

    80

    70

    60

    50

    40

    t1 t2 t3 t4 t5 time/s

    Which of the following is the correct conclusion?

    A. The melting point of acetamide is 80 oC

    B. The volume of acetamide increases from t4 to t5.

    C. Both solid and liquid exist between t2 and t4.

    D. Heat is absorbed from the surrounding between t1 and t2. c

    8.

    X is a mono atomic inert gas The electron configuration of Y is 2.8.8

    Which of the following statements is true?

    A. X and Y have octet electron configuration

    B. X and Y can form a covalent bond C. Size of X is bigger than that of Y

    D. Y is more reactive than X. a

    9. The electron configuration of two elements are shown below.

    Element Electron configuration

    J 2.8.2

    Z 2.8.7

    Which of the following formula and the type of bonding of the compound formed between J and Z?

    Formula Type of bond

    A. JZ ionic

    B. J2Z covalent

    C. JZ2 ionic

    D. JZ2 covalent c

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    10. A chemical equation is shown below.

    2R + CuSO4 R2SO4 + CuWhat is the volume of copper(II) sulphate 1 mol dm 3 that is required to react completely 1.95 g of R? [relative

    atomic mass: R = 39]

    A. 25 cm 3 B. 30 cm 3 C. 35 cm 3 D. 40 cm 3 a

    11. An electrolytic cell is shown below.

    ammeter

    carbon electrodes

    Glacial ethanoic acid

    Which of the following would result in a flow of current through the electrolyte?

    A. Tetrachoromethane is added to the glacial ethanoic acid

    B. The carbon electrodes are moved closer to each other

    C. Water is added to the glacial ethanoic acid D. A more powerful battery is used. c

    12. The figure below shows a syringe containing X g of sulphur dioxide at room temperature and pressure.

    X g of sulphur dioxide

    20 40 60 80 100 120

    Which of the following values represent X? [relative atomic mass: S = 32; O = 16; 1 mol of gas occupies 24 dm 3 at

    room temperature and pressure.]

    A. 0.32 g B. 0.64 g C. 0.96 g D. 1.28 g a

    13. The proton numbers of two elements R and J are shown below.

    Element Proton number

    R 19

    J 8

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    What is the relative molecular mass of the compound formed between R and J?

    [relative atomic mass: R = 39 ; J = 16]

    A. 55 B. 71 C. 94 D. 110 c

    14. Some information on particles P, Q, R, and S is shown below.

    Particle Proton number Nucleon number Number of electrons

    P 12 24 10

    Q 12 24 12

    R 17 35 17

    S 17 37 17

    Based on the above information, which of the following statements is true?

    I P is positively charged

    II R and S are isotopes of the same element

    III Q reacts with S to form an ionic compound

    IV Q is a neutral particle

    A. I and III only B. II and IV only C. I, II, and III onlyD. I, II, III, and IV d

    15. Which of the following shows that iron is a transition metal?

    I Iron(II) hydroxide is green in colour

    II Iron forms two chlorides, iron(II) chloride and iron(III) chloride

    III Iron(II) oxide is soluble in dilute hydrochloric acid

    IV A compound containing iron is potassium hexacyanoferrate(IV)

    A. I and III only B. II and IV only C. I, II, and IV only

    D. I, II, III, and IV c

    Section B

    1. The table below shows the proton number of a few elements.

    Element Sodium Magnesium Aluminium Sulphur Chlorine

    Protonnumber

    11 12 13 16 17

    Based on the above table, answer the following questions.

    (a) Name (i) a metal and a non metal. [1]

    (b) Name (i) the group which chlorine belong in the Periodic Table. [1]

    (ii) another element in the same group as chlorine. [1]

    (c) Write the electron configuration of sulphur. [1]

    (d) (i) Arrangement the elements in order of increasing atomic size. [1]

    (ii) Explain your answer in (d) (i) above. [1]

    (e) In a simple experiment, magnesium ribbon is burnt in excess of chlorine.

    (i) State one observation obtained. [1]

    (ii) Write an equation for the reaction occurred. [1]

    (iii) State one physical of the product formed above. [1]

    (f) State the period of the elements in the above table. [1]

    2.

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    ammeter

    Carbon electrode X carbon electrode Y

    U-tube

    concentrated

    copper(II)

    chloride

    The electrolysis of concentrated copper(II) chloride solution using carbon electrodes is shown above.

    (a) (i) Write the formulae of all ions present in concentrated copper(II) chloride solution. [1]

    (ii) Explain why copper(II) chloride solution conducts electricity. [1]

    (b) State the observation at

    (i) electrode X

    (ii) electrode Y [2]

    (c) (i) Write the equation for the half-reaction at

    (i) electrode X

    (ii) electrode Y [2]

    (d) Some product at electrode X is collected and passed into an aqueous solution of potassium iodide, a chemical

    reaction takes place.

    (i) Name the product formed. [1]

    (ii) Name the type of reaction occurred. [1]

    (iii) Write an equation to represent the chemical reaction occurred. [1]

    (e) If both the carbon electrodes are replaced by copper electrodes, explain what happens to electrode X.

    [1]

    Section C

    6. (a) With the aid of a labeled diagram, describe how you would electroplate an iron key with silver. State the

    materials required and any precautions taken. [8]

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    (b) The figure below shows the arrangement of a simple chemical cell to measure the potential difference between two

    different metals.

    voltmeter

    Metal electrode Metal electrode

    U-tube

    electrolyte

    The potential difference between two metals is shown in the following table.

    Pairs of metal electrodes Potential difference /V Negative terminal

    Copper and zinc

    zinc and magnesium

    silver and copper

    1.10

    2.90

    0.46

    zinc

    magnesium

    copper

    (i) Arrange the metals copper, zinc, magnesium and silver in descending order of the tendency to donate electrons.

    Explain your answer. [6]

    (ii) If a chemical cell is set up by using silver and zinc and the same electrolyte, what would be the potential

    difference? Name the negative electrode. [2]

    (c) The symbol of an element X is shown below.

    37

    X17

    Describe how element X can react with sodium. [4]