sample report (numerous attachments) · olc's to the hwi sample management office at (703)...

DATE PROMISED .23352ATTENTION : JOB NO.

(Red)ESTIMATED COST: TELEPHONE RESULTS

COMPANY NAME

ADDRESS

DATE

ITY, STATE, ZIP

TECHNICAL CONTACT^

P.O. NO.

_PHONE

BUpCEWS*YER

P.O. ENCLOSED SAMPLE ENCLOSED INSTRUCTION LETTER ENCLOSED

NO. PRICE/SAMPLE DISCOUNTenvironment, IIH*

EXTENSION Philadelphia

MS-D

MS-H

GC

LC

GC-MS

IR

AA

THERMAL

SAMP PREI

3/s

FOR REPORT

SAMPLE DESCRIPTION

LOT ANAL

Subtotal

Hrs Cons §$ /Hr

Hrs Sampling @$ /Hr

Mi @$.20/Mi

Sample PickupTTBI00233

Sample Return

REPORT DATE_

INVOICE NO._

SHIPPER N0._

DISPOSITION_

OUTSIDE LA"*

P.O.Box818, Alexandria, Viigirun223]3 70'-: LW 2490-ITS 5572490

ORGANICS LABORATORY CHRONICLE (EXTRACTIONS)Sample Number

Lab Name

Case No. _

Lab Sample ID No.

QC Report No. 1_>

QC REQUIREMENTS:

Designate below QCanalysis selected.

(If Applicable)

Duplicate

Matrix Spike

SAMPLE CONCENTRATION(Check OriQRJG fM i ^

f P ~ - i tLow Concentration ^^)Medium Concentration

SAMPLE MATRIX(Check One)

WaterSoil/Sediment

Description Technician Signature Detail Below Pertinent Information and/orDate/Time Extraction/Preparation Completed Problems Associated with Extraction/Preparatic

Extraction/Preparation(Base/Neutral)

Extraction/Preparation(Acid)

Extraction/Preparation(Pesticides)

Extraction/Preparation(Dioxins)

Preparation- (VGA)

Complete section below only if sample is to be used for duplicate or spike analyses.

Extraction/Preparation(Base/Neutral) QC

Extraction/Preparation(Acid)QC

Extraction/Preparation(Pesticides) QC

Extraction/Preparation(Dioxins) QC

'reparation(VOA)QC

6?!P02,ott

/ : ; , ;

U.S. ENVIRONMENTAL PROTECTION AGENCYHazardous Waste InvestigationSample Management OfficeP.O. Box 818*~ tandria, Virginia 22313

- ne: (703)

General Directions

1. Use only the materials provided to record sample information.

2. Familiarize yourself with all types of information requested of you, and fill in thisinformation completely for each sample taken.

3. Press firmly with ballpoint pen or pencil, and make sure all information is transferred tocarbon pages.:-:."

4. Where Organic Traffic Reports (OTR), Organics Laboratory Chronicle-Extractions (OCL-E)and/or Organics Laboratory Chronicle-Analysis (OLC-A) must be mailed, be sure that allsheets are sent to the correct addressee. . • . '

5. These instructions, as well as the address and phone number of the HWI Sample ManagementOffice (SMO) are reproduced for your convenience on the back of each page of the OTR's and OLC's.

6. Relate any problems and/or questions concerning SMO procedures or the use of OTR's orOLC's to the HWI Sample Management Office at (703) 557-2490.

Analysis Laboratory Directions

JU— Check condition of all samples and labels on arrival.

2. Verify that sample conforms to the information specified in Items 1 and 2 of the OrganicsTraffic Report (OTR). If there appears to be a discrepancy, immediately contact the HWISample Management Office.

3. Fill in information requested in Item 11 of the OTR and note comments regarding samplecondition in the space provided.

4. Send the top sheet of the OTR (white copy) to the HWI Sample Management Office andretain the remaining yellow copy for your files.

5. Transfer to the Sample Number box of an Organics Laboratory Chronicle-Extractions (OLC-E) and an Organics Laboratory .Chronicle-Analysis (OLC-A) the sample identification numberpreprinted on the Organics Traffic Report (OTR). For each sample received, that sample,an OTR, an OLC-E and an OLC-A must all be identified by a common HWI Sample Number.

6. Proceed with extraction/preparation, recording all pertinent information on the corres-ponding Organics Laboratory Chronicle-Extraction (OLC-E).

7. If a sample is used to fulfill QC requirements for Duplicate or Matrix Spike analysis,complete the appropriate sections on both the Extraction and Analysis Organics LaboratoryChronicles.

8. Upon completion of extraction/preparation, send the first two pages (white and pink copies)of the OLC-E to the HWI Sample Management Office, retaining the last page (yellow copy)'ir your files.

9. Proceed with analysis, recording all pertinent comments on the Organics LaboratoryChronicle-Analysis (OLC-A). If necessary, a more detailed discussion may be included in thenarrative section of your Weekly Report.

10. Upon completion of analysis, send the first two pages (white and pink copies) of the OLC-A

P.O.Box818, Alexandria,Virginia22313 -7C3 557 2490-FTS 5572490

ORGAN1CS LABORATORY CHRONICLE (EXTRACTIONS)Sample Numbe:

Lab Name

Case No. _

Lab Sample ID No.

QC Report No..!_

QC REQUIREMENTS:

Designate below QCanalysis selected.

(If Applicable)

Duplicate

Matrix Spike

SAMPLE CONCENTRATION(Check

Low ConcentrationMedium Concentration

SAMPLE MATRIX(Check One}

WaterSoil/Sediment

Description Technician Signature Detail Below Pertinent Information and/orDate/Time Extraction/Preparation Completed Problems Associated with Extraction/PreparatK

Extraction/Preparation(Base/Neutral)

Extraction/Preparation(Acid)

Extraction/Preparation(Pesticides)

Extraction/Preparation(Dioxins)

Preparation(VOA)

Complete section below only if sample is to be used for duplicate or spike analyses.

Extraction/Preparation(Base/Neutral) QC

Extraction/Preparation(Acid)QC

Extraction/Preparation(Pesticides) QC

Extraction/Preparation(Dioxins) QC

reparation(VOA)QC

A R I O O 236

U.S. ENVIRONMENTAL PROTECTION AGENCYHazardous Waste InvestigationSample Management OfficeRO. Box 818 ,, ,. (

xandria, Virginia 22313 ! ! ' « ! ' ' - ' i-Jin \ Y\M. .one: (703) 5 57-2490/FTS-8-5 57-2490 "

General Directions

1 . Use only the materials provided to record sample information.

2. Familiarize yourself with all types of information revested of you, and fill in thisinformation completely for each sample taken.

3. Press firmly with ball point pen or pencil, and make sure all information is transferred tocarbon pages.

4. Where Organic Traffic Reports (OTR), Organics Laboratory Chronicle-Extractions (OCL-E)and/or Organics Laboratory Chronicle- Analysis (OLC-A) must be mailed, be sure that allsheets are sent to the correct addressee.


6. Relate any problems and/or questions concerning SMO procedures or the use of OTR's orOLC's to the HWI Sample Management Office at (703) 557-2490.


-^ Check condition of all samples and labels on arrival.


3. Fill in information requested in Item 1 1 of the OTR and note comments regarding samplecondition in the space provided.


5. Transfer to the Sample Number box of an Organics Laboratory Chronicle-Extractions (OLC-E) and an Organics Laboratory Chronicle- Analysis (OLC-A) the sample identification numberpreprinted on the Organics Traffic Report (OTR). For each sample received, that sample,an OTR, an OLC-E and an OLC-A must all be identified by a common HWI Sample Number,

6. Proceed with extraction/preparation, recording all pertinent information on the corres-ponding Organics Laboratory Chronicle-Extraction (OLC-E).

7. If a sample is used to fulfill QC requirements for Duplicate or Matrix Spike analysis,complete the appropriate Sections on both the Extraction and Analysis Organics LaboratoryChronicles.

8. Upon completion of extraction/preparation, send the first two pages (white and pink copies). of the OLC-E to the HWI Sample Management Office, retaining the last page (yellow copy)

ror your files.

9. Proceed with analysis, recording all pertinent comments on the Organics LaboratoryChronicle- Analysis (OLC-A). If necessary, a more detailed discussion may be included in thenarrative section of your Weekly Report.


.», P.O. Box 818 Alexandra, Virginia 22313 -703 557 2490-ITS 5572490

ORGANICS LABORATORY CHRONICLE (ANALYSIS)Sample Number

Lab Name.

Case No. _

Lab Sample ID No.

QC Report No.l

QC REQUIREMENTS:

Designate below QCanalysis performed.

(If Applicable)

Duplicate

Matrix Spike

SAMPLE CONCENTRATION(Check Onel-

Low Concentration (Red)Medium Concentration '


WaterSoil/Sediment

Description Analyst SignatureDate/Time Analysis Completed

Detail Below Pertinent Information and/orProblems Associated with Analysis

Base/Neutral

Acid

Pesticides•• '- > / > " • 7

Dioxins

VOA

Complete section below only if sample is used for duplicate or spike analyses.

QC(Base/Neutral)

QC(Acid)QC(Pesticides)

QC(Dioxins)

QC(VOA)

LAB FILE COPY

U.S. ENVIRONMENTAL PROTECTION AGENCYHazardous Waste InvestigationSample Management OfficeP.O. Box 818Av" ndria, Virginia 22313Pi 3: (703) 557-2490/FTS-8-557-2490 c r 7 H fl I H \1

. ; , , j , r Q O C/ VJ U

': . iGeneral Directions


2. Familiarize yourself with all types of information requested of you, and fall in thisinformation completely for each sample taken.

3. Press firmly with ball point pen or pencil, and make sure all information is transferred tocarbon pages.

4. Where Organic Traffic Reports (OTR), Organics Laboratory Chronicle-Extractions (OCL-E)and/or Organics Laboratory Chronicle-Analysis (OLC-A) must be mailed, be suie that allsheets are sent to the correct addressee.


-5. Relate any problems and/or Questions concerning SMO procedures or the use of OTR's orOLC's to the HWI Sample Management Office at (703) 557-2490.


1. ^-^heck condition of all samples and labels on arrival.


3. Fill in information requested in Item 11 of the OTR and note comments regarding samplecondition in the space provided.


3. Transfer to the Sample Number box of an Organics Laboratory Chronicle-Extractions (OLC-E) and an Organics Laboratory Chronicle-Analysis (OLC-A) the sample identification numberprepnnted on the Organics Traffic Report (OTR). For each sample received, that sample,an OTR, an OLC-E and an OLC-A must all be identified by a common HWI Sample Number.

o. Proceed with extraction/preparation, recording all pertinent information on the corres-ponding Organics Laboratory Chronicle-Extraction (OLC-E).

7. If a sample is used to fulfill QC requirements for Duplicate or Matnx Spike analysis,complete the appropriate sections on both the Extraction and Analysis Organics LaboratoryChronicles.

3. Upon completion of extraction/preparation, send the first two pages (white and pink copies)of the OLC-E to the HWI Sample Management Office, retaining the last page (yellow copy)

• your files.

). Proceed with analysis, recording all pertinent comments on the Organics LaboratoryChronicle-Analysis (OLC-A). If necessary, a more detailed discussion may be included in thenarrative section of your Weekly Report.


P.O.Box818 Alexandria,Viiginia22313-703;5572490-nS 557'X49C

ORGAN1CS LABORATORY CHRONICLE (ANALYSIS)Sample Number

Lab Name \ - '• v-_ ._ r-\ - !Case No. __

Lab Sample

QC Report No.

QC REQUIREMENTS:

Designate below QCanalysis performed.

(If Applicable)

Duplicate

Matrix Spike

SAMPLE CONCENTRATION(Check One)

O R I G I N A LLow Concentration (Red)Medium Concentration


WaterSoil/Sediment

Description Analyst SignatureDate/Time Analysis Completed

Detail Below Pertinent Information anoVorProblems Associated with Analysis

Base/Neutral

Acid

Pesticides

Dioxins

VOA

Complete section below only if sample is used for/duplicate or spike analyses.

QC(Base/Neutral)

QC(Acid)QC(Pesticides)

QC(Dioxins)

QC(VOA)

U.S. ENVIRONMENTAL PROTECTION AGENCYHazardous Waste InvestigationSample Management OfficeP.O. Box 818/' andria, Virginia 22313I. ue: (703) 557-2490/FTS-8-557-2490 _, , i- *i 7 fl fl I H \j

General Directions


2. Familiarize yourself with all types of information requested of you, and fill in thisinformation completely for each sample taken.

3. Press firmly with ball point pen or pencil, and make sure aD information is transferred tocarbon pages.

4. Where Organic Traffic Reports (OTRJ, Organics Laboratory Chronicle-Extractions (OCL-E)and/or Organics Laboratory Chronicle-Analysis (OLC-A) must be mailed, be sure that allsheets are sent to the correct addressee.


5. Relate any problems and/or questions concerning SMO procedures or the use of OTR's orOLC's to the HWI Sample Management Office at {703} 557-2490.


1 -""^heck condition of all samples and labels on arrival.

2. Verify that sample conforms to the- information specified in Items I and 2 of the OrganicsTraffic Report (OTR). If there appears to be a discrepancy, immediately contact the HWISample Management Office.

3. Fill in information requested in Item 11 of the QTR and note comments regarding samplecondition in the space provided.


5. Transfer to the Sample Number box of an Organics Laboratory Chronicle-Extractions (OLC-E) and an Organics Laboratory Chronicle-Analysis (OLC-A) the sample identification numberpreprinted on the Organics Traffic Report (OTR). For each sample received, that sample,an OTR, an OLC-E and an OLC-A must all be identified by a common HWI Sample Number.

6. Proceed with extraction/preparation, lecording all pertinent information on the corres-ponding Organics Laboratory Chronicle-Extraction (OLC-E).

7. If a sample is used to fulfill QC requirements for Duplicate or Matrix Spike analysis,complete the appropriate sections on both the Extraction and Analysis Organics LaboratoryChronicles.

3. Upon completion of ex traction/preparation, send the first two pages (white and pink copies)...of the OLC-E to the HWI Sample Management Office, retaining the last page (yellow copy)

r your files.

3. Proceed with analysis, recording all pertinent comments on the Organics LaboratoryChronicle-Analysis (OLC-A). If necessary, a more detailed discussion may be included in thenarrative section of your Weekly Report.

1 Upon completion of analysis, send the first two pages (white and pink copies) of the OLC-A

WCTS Extract Log-In Sheet

ORIGIN^(Red;

WCTS JNContract #SMO Case #

Date/Time ReceivedSample TypeRequired Turn-around

Custody Seals - On Ice Chests

Intact

Samples Received - ColdIntact

Sample Tags - Present

Chain of Custody - Received

Present Yes r NoProperly Placed .Yes K No

SampleH

V G A ' sso-i,

Vfc

Yes K No

On SamplesPresent Yes __ NoProperly Placed Yes __ NoIntact Yes No

YesYes

NONo

Yes __ !No x

Yes v: No

Date/Time Concentration Completed_____J C C o m b , ~ KBNA.TCDD Pest.PCB Florisiled

I - ^ ,(Red)' '

KX

^AiiW^tCk-AjeS^X-Ox—»

C*n **><*. JBVo ^RM-o4^>v Qjer -orv^v^

.^^XO^

B/NA/UPP

O R I G I N A L(Red)

- \11

C

(Red)

TT

ejert-^^

SHIPPER'S CERTIFICATION FOR RESTRJCTED ARTICLES(excluding radioactive materials)

Two completed end signed copies of this certification shall be handed to the carrier. (Use block letters)

WARNING: Failure to comply in all respects with the applicable regulations of the Department ofTransportation, 49-CFR, CAB 82 and, for international shipments, the IATA Restricted Articles Regulations maybea breach of the applicable law, subject to legal penalties. This certification shall in no circumstance be signed

- by.an IATA Cargo Agent or a consolidates for international shipments.__:___,—:—'•• ——————:——————————'•————————————————————.———.——————————————————————————————This shipment is within the limitations prescribed for: (mark one)

XKPC passenger aircraft ' " D cargo-only aircraft , ,

l^.a--.J Number

1 °f]MV-',i

'- - ."!*.. '

* *. Article>" Number"^

(Int'l onlySee Section

IV IATA RAR)

"•n." - ' ' "Cil : . .- L •

. ^ ..;V " '"

Proper Shipping Name of Articles, as"*hown in Title 49 CFR, CAB 82 Tariff 6-D, .

and (for int'l shipments) the IATARestricted Articles Regulations. Specifyeach article separately. Technical namemust follow in parenthesis, the propershipping name for N.O.S. items.- - -

.• •- .'-:' ' •*•- . .. .', ,- -

Methyl ene Chloride ^ •( 1 im1 ted quanti ty)

Hexane -(limited quantity)

Methyl Alcohol(limited quantity)

Class

ORM-AUN! 593

Fl amtnaLiquidUN1208

FlammaLiquidUN1230

IATAPackingNote NoApplied

(Int'tonly)

.x 'f

. "

>le

>le

!

" NetQuantityof EachPackage

less th2 oz.

less th2 oz.

less th2 oz.

Flash Point(closed cup)

For FlammableLiquids I

•c.

in

in

in

Ii

Special Handling Information:

laboratory samples for analysisI hereby certify that the contents of this consignment are fully and accurately described above by Proper

.Shipping Name and are classified, packed, marked, labelled and in proper condition for carriage by airaccording to applicable national governmental regulations, and for International Shipments, the current IATARestricted Articles Regulations. • 'Name and full address of Shipper

Fred C. Hart Associates, Inc.NEIC/Reyulaled Lab

Name and title of person signing Certification

".Diana Hudson

Denver Federal CenterBldg 53r Box'25227Denver. CO .00225—~-

-Administrative Assistant

.,"-—(303)'234-2683 .Date

3-25 82Signature of the Shipper (see WARNING above)

Air Waybill No.'

.- ; 154721210Airport of Departure* ,

DEN/APA.Airport of Destination*

wets "Your Full Service Chemistry Laboratory"/ West Coast Technical Service Inc.17605 Fabrica Way/Cerritos, California 90701 /(213) 921-9831_or (714) 523-9200•' i' f ["fri f ""IjTnJii'f- m'rn' r'li'iTVrf -TiV iF--'-'i'-i=''' "ir-t'illktPfctiifliiTi ffiiiilttt

ReportORIGINAL

(Red)

Prepared For Date

U.S. Environmental Protection Agency .Curtis Building 6th & Walnut St., 35A-30Philadelphia, PA 19106

Attn: .Jeffrey Hass

April 22, 1982

Date Received PJD.NO. Job No.

3-26-82 6502 23352Description of Samples

Enclosed is the data for EPA Samples numbers C5047, C5048. Casenumber 904. Chain of Custody was received. At the time of theanalyses, Decafluorobiphenyl (surrogate) was not available for thestandard solutions, therefore it was not quantitated in the reporteddata. Phenol D5 (surrogate) was not detected in the samples analyzed,but it was noted to be spiked at 400,000ug/kg.

We would appreciate a telephone call if you have any questions regarding this report Page 1 of pages.

I certify that Ihis report truly represents Ifie findings of work performed byor under my direct supervision.

Richard AmanoSenior Chemist

Reviewed and Approved.

D.J. Northington, Ph.D,Technical Director

This ft poll periams only lo me samples investigated and does not necessarily apply to olher apparently identical or similar materials. Trus report is submitted for the enclusrve use of the client lo whom it is iddiessedAny reproduction ol Ihis report or use of this Laboratory's name lor advertising 01 publicity purposes without written aulhornalion is prohibited

"Your Full Service Chemistry Laboratory"/ West Coast Technical Service Inc.17605 Fabrica Way/Cerritos, California90701 /(213) 921-9831 or (714) 523-9200^^,...^\:^^^^^^^^^&^^^^^m^^ A:-.J v- . - . . . - . . . . ,

ORIGINALr-i ^ (Red)Report

Pie pared for Date

USEPA EMSL, QADExecutive Center Rm 226944 So. Harmon Ave.Las Vegas, NEV 89109Attn: George H. Brills

Apri l 22, 1982

Date Received P.O. No. Job No.

3-26-82 6502 23352Description of Sampta

Enclosed is the data for ERA Samples numbers C5047, C5048. Casenumber 904. - Chain of Custody was received. At the time of theanalyses, Oecafluorobiphenyl (surrogate) was not available for thestandard solutions, threfore it was not quantitated in the reporteddata. Phenol 05 (surrogate) was not detected in the samples analyzed,but it was opted to be spiked at 400,000ug/kg.

We would appreciate a telephone call if you have any questions regarding this report Page 1 of pages.

t certify thai this report truly represents the findings of work performed by me,or under my direct supervision.

AR1002149

Richard AnanoSenior Chemist

Reviewed and Approved,

D.J. Northington, Ph.D,Technical Director

This report pertains only lo the samples investigated and does not neces&aiily apply to oinei apparently identical or sJmilai materials. This report is submitted for Ihe exclusive use o< the clienl to «*wn il ts addressedAny reproduction of this repor! or use oi Ihis laboratory's name lor advertising or publicity purposes without written automation is prohibited

70

±L r*

fD

fD

CO

ro

O O JO3 —' C

BHT m

X

X

X

Ul

X

N/

A Total Metals

B Acid ExtractableMetals

C Total MercuryP Strong

Acid AnionsH Volatile Organics

Base/NeutralAcid, TCOD

ir Comb. Base/NeutralL Acid, TCDDK Pesticides, PCB

L Other

CO

r*

mX

PO

-HCO

TO

70mo

CD

-o;om

o

33OOc:CO

CO

mx

O

OcrCO— 1o

m<r>o^3O

Sample Phase No.

oIS3m:2— iCO

\i\ff" I*, : . . : . - < f & •-] -W-<:£fc* "Your Full Service Chemistry Laboratory"/ West Coast Technical Service IncVwWi LZy,;;^ :'HJ & S p S F a ^avMaB^^

ReportORIGINAL

(Red)Prepared For Date

U.S. Environmental Protection AgencyHazardous Waste Site InvestigationSample Mgmt. Office, 112N. Columbus St.Alexandria, VA 22313

Attn:. Marian Bernd

April 22, 1982

Date Received P.O. No. Job No.

3-26-82 6502 23352Description of Samples

Enclosed is the data for ERA Samples numbers C5047, C5048. Casenumber 904. Chain of Custody was received. At the time of theanalyses, Decafluorobiphenyl (surrogate) was not available for thestandard solutions, therefore it was not quantitated in the reporteddata. Phenol D5 (surrogate) was not detected in the samples analyzed,but it was,noted to be spiked at 400,000ug/kg.

We would appreciate a telephone call if you have any questions regarding this report Page 1 of J pages.

I certify that this report truly represents the findings of work performed by me.or under my direct supervision.

A R I 0 0 2 5aiRichard AmanoSenior Chemist

Reviewed and Approved

0.0. Northington, Ph.DTechnical Director

This report pertains only lo IM samples inveslioaled and does nol necessarily apply lo Other apparenlly identical of similoi malenels This report is submitted *o> the ««chjsive use of Ihe client lo whom it is aOOiessedAny leproduclion of this leport 01 use of this Laboreloiy's name for advertising en publicity purposes without written aulhornation is prohibited

4, r^O.

Lib

ORIGIN' 1 ,(Re::;

INITIALJOT

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00255

196e

QUPINTJTATION REPORT FILE: 6NAP047

BNAF047.T!04/18/82 12:27:00SAMPLE: 50UG/ML. 6502 FUSED SILICA STANDARD

INSTRUMENT: 4021ANALYST: DP #592

ORIGINAL(Red)

: FSCCJRMULA: SENS213

^"SUBMITTED SY: BNAP047WEIGHT: 0.080ACCT. NO.: FC112581

flMOUNT«AREA * REF.AMNT/CF-EF.AREA* RESP.FACT)

NO123456?89

101112131415161718192021

2526272829303132333435363738394941424344454647

NflME2,4,6-FHENOL D3 (INTERNAL STANDARD)188 BIS (2-CHLOROETHYL) ETHER24ft 2-CHLOROPHENOL278 1,4-DICHLOROBENZENEU2-DICHLOROBEHZENE428 BIS (2-CHLOROISOPROPYL) ETHER128 HEXACKLQRQETHflNEPHENOLPHENOL D-5 CSUPROGPlTE)PYRIDINE D6 (SURROGATE)NAPHTHALENE DG CINTERNAL STANDftRD)63B N-NITROSO-DI-H-PROPYLAMINENITROBENZENEISOPHORONE57A 2-NITROPHENOL

2,4-DIMETHYLFHENOLBIS C2-CHLOROETHOXY) METHAHE2,4-DICHLOROPHENOL

34fl43 B3lfl88 1,2,4-TRICHLORODENZENE55B MnPHTHALENE528 HEXACHLOROBUTADIENE22A 4-CHLORO-M-CRESDL538 HEXACHLOROCYCLOPENTADIENE21A 2,4,6-TRICHl.OKQPHENOL208 2-CHLDRONAPHTHALENE778 ACENAPHTHALENE7.1 B DIMETHYLPHThftLftTE368 2,6-DINITROTOLUENENITPOBENZENE D-5 (SURROGATE)2-FLUCRBIPHEMYL (SURROGATE;PHEMANTHRENE D10 (INTERNAL STANDARD)IB ACENAPHTHENE

53A 2,4-DINITROPHENOL358 2,4-DINITRDTOLUEHE4-NITROFHENOL8BB FLUORENE408 4-CHLOROPHENYLPHENYL ETHER70B DIETHYLPHTHALATE6GA 4,6-DINITRQ-O-CRESOL62Q N-NITROSODIPHEHMfiMINE378 1,2-DIPHENYLHY3RAZINE41B 4-BRnriOPHEr'OXYbEHZeNE98 HEXfiCHLO^OBEKZENE64A PEHTftCHLOROPHENOL818 PHF.MAhlTHRF.NE7EB ftNTHRnCEME6E3 DI-N-BUTYLFHTK^LATE

ARI00256

5758 67B59 2RB60 66861 693

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NO1234567B91011121314151617IB192021

tl/E97931281461467711794NOT561361301238213912293162180128225

SCAN387303304400419443454454

FOUND227549453460466506529535543545552579

TIME7:067:017:027:287:418:078:198:19

4:1010:048:243:358:333:179:429:409:549:5910:07IB: 37

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2849.37212.2111.10629.31201.11497.39812.51158.29955.39447 .1(16435.15690.

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13.20.31.30.35.28.52.56.43.54.40.47.

030974578193916249219021

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TIME11 : 4312:1612:3912:5113:5014:0314:068:3312:4917:4614:1614:3714:5915:1215:2915:4215:4715:5716:0215:5716:5017:0517:3917:5017:5619:4720:4721:1616:5417:4018:1419:0320:4121:1324:2121:2423:2924:3225:0326:3421:5421:5322:4523:2721:2423:2422: IS22:3127:2924:3224:3229:5223:5230:154:037:11

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228 1326 24:19 56 0.998 A BB228 1331 24:24 55 1.002 A BB

RETCL)7:007:127:137:287:518:128:268:268:384:139:558:318:488:389:209:509:549:59

10:0310:1010:3811:4912:1912:3212:5213:4714:0314:078:37

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RATIO1.010.970.970.980.980.990.990.99

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100.00

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J.271.591.48

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104.26.

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699.185.

15.16.77.

7144.460.189.309.

1433.189.

19.199.244.73.

817.164.93.24.10.

665.65.17.

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fl: 23352F1.TI ORIGINAL04/18/82 19:43:09 0SAMPLE: C05047CONDS.: EXT 4/14/82 0.25G TO 5MLSF^MULft: SENS213 INSTRUMENT: 4021 HEIGHT: 0.000

IITTED BY: DNAP047 ANALYST: RA #592 ACCT. NO.: FC112581

AMQUNT-flREfl * REF.AMNT/CREF.AREA* RESP.FflCT)

NO HfiME1 2,4,6-PHENOL D3 (INTERNAL STANDARD)2 61B N-NITROSO-DIMETHYLAMINE3 18B BIS (2-CHLQRQETHYL) ETHER4 24ft 2-CHLOROPHENOL5 26B 1,3-DICHLOROBENZENE6 27B 1,4-DICHLOROBENZENE7 1,2-DICHLOROBENZENE8 428 BIS <2-CHLOROISOPROPYL) ETHER9 12B HEXACHLOROETHflNE10 PHENOL11 PHENOL D-5 (SURROGATE)12 2-FLUOROPHENOL (SURROGATE)13 PYRIDINE B6 (SURROGATE)14 NAPHTHALENE D8 (INTERNAL STANDARD)15 63B N-NITROSO-DI-N-PROPYLAMINE16 NITROBENZENE17 ISOPHORONE18 57A 2-NITROPHENOL19 34A 2,4-DIMETHYLPHENOL20 438 BIS (2-CHLOROETHOXY) METHANE21 31ft 2,4-DICHLQRQPHENOL22 8B 1,2,4-TRICHLOROBENZENE2^ 55B NAPHTHALENE

52B HEXACHLOROBUTADIENE** 22A 4-CHLORO-M-CRESOL26 53B HEXACHLORQCYCLOPENTftDIENE27 21ft 2,4,6-TRICHLOROPHENOL26 208 2-CHLORONfiPHTHALENE29 77B ACENftPHTHALENE3D 7 IB D IM^TI-lYLPHTHflLftTE31 36B 2,£-DI!: ITPOTCLUENE32 NITROBENeENE D-5 (SURROGATE)33 2-FLUOR&IPHEHYL (SURROGATE)34 PHEMOKTHRENE D10 (INTERNAL STANDARD)35 IB flCFhSPHTHEME36 59A 2, /i-D ! N1 TROr-HF'HGL37 35D 2, -i- PIK ITKnTOLUF.NE38 4-K77ROPI-!>:nL39 808 i"LUGr;Ei:f:43 408 4-CHLORGPh!EKYLFHirNYL ETHER41 70S DhTTHYLPHTHALflTE42 60A 4,6-DIIUTRO-O-CRESOL43 62E N-NITRDSOPIPHENYLflMINE44 37B 1,2-DIPHENYLHYDRftZINE45 41B 4-EROmPHENOXYBENZENE46 93 HEXflCHLOaOBENZENIE47 64ft PENTfiCHLOROPHENOL

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M/E SCAN TIME REF RRT METH97 352 6:27 1 1.080 A B8

NCT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUtUL,77 f4 p 7:54 1 1.224 A BB

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RETCL) RATIO7:00 0.924:217:127:137:287:267:518:12 0.968:268:268:38 0.955:24 0.934:139:55 8.998:318:408:38 0.989:209:509:549:5918:0310:10 0.9810:3811:4912:1912:3212:5213:4714:8314:878:3712:4617:35 1.0814:1614:3314:5915:0915:2915:3915:43 1.0015:5516:0215:5516:4917:0017:3517:51 0.9917:57 0.9919:4G 0.9920:44

TIME REIF RRT

RRTCL) RATIO1.000 1.000.5970.9900.9321.8251.0251.0781.126 1.091.1591.1591.18G 1.078.720 1.080.5901.088 1.000.8420.8570.853 1.010.9220.9710.9780.9870.9931.085 1.011.051 *1.1681.2171.2391.2721.3621 . 3b81.3950.B551.2651.000 1.000.8040.8200.8440.8530.8738.8320.885 1.800.8970.9040.8970.9460.9580.9911.006 1.001.011 0.991.114 0.991.168-

METH

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AMOUNT

R.FAC R.FACCL)1.000 1.300

0.4111.1300.9600.8281.0780.S9E)

0.014 0.2880.6D40.232

0.005 1.3240.018 0.765

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J.GS 1.1971.00 1.0300 . 99 0 . 0761.00 0.362

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R.FflC R.FACCL) RATIO

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1.303

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ORIGINAL(Red)

0.541.000.010.31

0.480.33

1.00

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RIC ) DATA: 23352F1 ttl04/18/82 19:43:08 CALI: FC112581 ttSAMPLE• C05047RAHGEi 'G 1,1799 LABEL: N 9, 4.9 QUAN: A 0. 1.0 BASE: U 20, 3

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8 42B BIS (2-CHLORGISOPROPYL) ETHER9 12B HEXnCHLOROETHflNE

10 PHENOL11 PHENOL P-5 (El.rrc] ' 2-FLU5ROFHEt-'C._ C-i 6 FviT; ii'tii-Jt" 'r. r,*''j'14 N":~i-"T"l-!rLri-!1 I'."1 •is G'"" ;-;-:' ; ' '>>•'

IT !;•, ':/•: ' • ' ,IB 5}'. :--. "'^-'--1^1IP 34fl 2.4--, i, .-,;-';.f-;-i-:iL2& 43EJ ?IS (2-u-:(_u?on>!0>^Y) METHRME

22! RE1 1,?. <<-"(: laf.OOTjrM'ENc

24 52? HEXACHLOROBIITHDIENE25 22fi 4-CHLORO-M-CRESOL26 525 HEX-OLOSQCYCLOPENTflDlENE27 21 il 2,4,6-TRI CHLOuOPHEHOL26 20B 2-CHLuRONHFHTHftl.ENE29 77B flCEHAPHTHflLEMET30 719 IlhETHYLPHTKAL.ATE31 3fB 2,£-DINITSOTOLUENE32 NITROCENZENE D-5 (SURROGATE)33 2-Fl.UGSHPIJRJYL <SUF!RPEATE)34 PHENAHTHREKE DID (INTERNAL STANDARD)35 IB AOLUfiPKTHENE3G 59A 2,4-DINITROr'HCNOL37 35B 2,4-DINITROTOLUENE3B 4-NITROPHENOL39 B0B FLUOREHE40 40E 4-CHLQROPHENYLPHENY'L. ETHER41 70B DIETHYLPHTHALATE42 6aft 4, S-DINITRO-D-CRESOL45 62B N-NITR030DIPHENYLPMINE44 378 l,?:-riPHcNYLHYDR^INE4? 4 IB 4-E*;j 92 H^;47 64A PEKTfiCHLOROPHUNOL

A R I 0 0 3 2 8

NO-49495051

1-..35455565758596061626364656667686570717273747576777879

^

"NOi234567B9

1C11i:* T

1415If17

\32021

NAME8'lfe PHENANTKRENE788 ANTHRACENE688 D I-N-BUTYLPHTHALATE39B FLUORftNTHENE648 PYRENEALPHA BHCGfiMMP 8. BETA BHCDELTA-BKCHEPTACHLORALDRINPYRENE D18 (SURROGATE)CHRYSENE D12 (INTERNAL STANDARD)

5B BENZIDINE678 BUTYLBENZYLPHTHALATE728 BENZO (A) ANTHRACENE76B CHRYSENE2BB 3,3'-DICHL030BENZIDINE66E BIS C2-ETHYLHEXYL) PHTHALATE69B D I-N-OCTYLPHTHALATE4, 4' -DDEDIELDRIM4,4'-DPD4,4*-DDTBETA ENDOSULFANEMDOSULFAN SULFATEENDRINALFH3 ENSQSULFflNBEKZO CA) FYRENE D-!2 (INTERNAL STANDARD)74B BEKZO CE) FLUORRNTHENE73B BENZfj (ft) PYRENE8^6 IMO!0-1,2,3 (C,P) PYRENEB2B r/ieciszo CA,H) ANTHRACENE79B BENSO (G,H,I) PERYLENE

M/E SCAN TIME RPF RRT METH9? 373 6:5G 1 J.OOB A 8B

NOT FOU1DNOT FOUNDNOT FOUSDHOT FOUNDHOT FOUMi?NOT FOUNDNOT FOUNDLOT FOUNDMOT FOUND99 458 8:24 1 1.212 A BB

112 27\ 4:5B 1 0.717 # BVNOT FOUND13G 541 9:55 14 1.003 # BVNOT FOl"IDt-'OT FOUND

FZ 45? 8:24 14 0.847 # BV

i-iuV FOU;'DNOT FOUIJPNOT FOUfID

AREA14515

21149912

43507

4SB73

AMOUNT20.090 UG/L

KTCT4.23

0.220 UG^B9.949 UG/L

20.080 UG/L

is!0i4.23

11.

A R I 0 0 3 2 9

NO' 22232425262722233031323334353637383943414243444545474H495051525354555657585960616?.f.ri.465£667eo6P7071727374757677

IVE SCPN TIMENOT FOUNDIi8 544 9:58NOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FCUNDNOT FOUKD12B 4"3 8:24NOT FOUND1PC 963 17:39NOT FO'JHDHOT FCUNDNOT Fniri?NOT FOUNDNOT FOUNDNOT FDJJWL149 £4£/ 15:32NOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDHOT FOUNDNOT FCiJJbilL149 Q073X 19:46NOT FOUNDNOT FOUNDNOT FCUNDNOT FCUNDNOT FOUNDNOT FOUNDNOT FOUND212 11^3 21:0324Q !'<.'-. 24:11184 ii^ 21:0314D 1ZT5 23:22NOT Fni'hT<HOT FOl.'V'h.CT Fj -O.1.,:; Cl 24:54\<.:- UO^ 2C:18NOT FOUNDNDT FOUKDNOT FOUNDIS'" FOUNDNuV FOUNDNOT FOUNDNOT FOUNDNOT FOUND264 14B9 27:18NOT FOUNDNOT FOUND

REF RRT METH

14 1.006 P BB

14 0.847 P BB

34 1.000 P BB

34 0.880 * VB

34 1.119 * VB

34 1.192 P BB59 1.003 * V359 0.873 ft BB59 0.96? # VB

59 1.030 * W59 1.088 * VV

75 1.000 P BB

PREP

220

PMOUNT

• 0,097 UC.1.

19344.

32493.

37110

18138, UU/L

19203,17515,

69,38648,

32129.28194.

28.225 UG/L20.099 UG/L•O.T21 UG/L

UG-^L

11398 40.000 UG/L

XTOT

0.02

64.438 UG/L 13.62

20.000 UG/L 4.23

5.45

1.55

5.964.230.158.52

5.253.24

8.45

ORIGINAL(Red)

54x0,000

A R I 0 0 3 3 0

.NO767960

23456789131112131415161718192321222324252G27

B31323334353537383940414243444546474849SB5!

M/E SCANNOJ FOUNDNOT FOUNDNOT FOUND

RETCL) RATIO7:00 3.994:217:127:137:287:287:516:128:268:268:38 0.975:24 3.924:139:55 1.638:318:436:3R 0.979:209:509:549:5913:0310:10 fc.SS10:361 1 :-<912:1912:3212:5213:4714:0314:070:37 0.97\2:t£17:35 1.6014: 1G14:3314:5915:0915:2i)15:3315:43 0.9915:5516:0215:5516:4917:E017:3517:5117:5719:4S 1.0020:44

TIME REF RRT

RRT(L) RATIO1.000 1.000.5973.9933.9921.3251.6251.0781.1261.1591.1591.186 1.020.720 1.000.590l.BOS 1.00Q.G4?B . fsti/0.853 0.990.92?3. 5710.97H0.S870.933l.GPLj 1.631.0511 . It'31.2171.233i.2721.3621.39G1.3950.655 3.991 . 265I.L->:~ i.ooO.f:u4o.c?o0 . 0-140.8536 . £733.6820.B35 0.993.6970.9540.6570 . 945C . 9560.99]1.6361.0111.114 1.B11.16R

METH

AMNT20.00

0.2289.95

20.00

55.89

0.10

64.44

20.08

25.78

7.35

flREA

PMNT(L)20.0050.0050.0050.0350. BB50. 8050.0050.0050.0350.0050.0050.0350.0020.08se.oo50.00so. ea50.0053.0053.0050.0050.0050.0059.0050.6350 . 0059.0059.0053.cn50. G350.0050.0059.0020. GO50 . 0350 . GO50.005'j.ca50.0950.0050.00SO . 00

5L .0053.0050.0050 . 0050.0050.0050.00

AMOUNT XTOT

R.FAC R.FAC(L) RATIO1.000 1.333 1.03

3.4111.1300.9680.8281.3780.8933.2880.6040.232

0.336 1.324 3.331.375 0.765 1.80

8.3691.099 1. f.'0F.J 1.03

0.0238.110

0.449 C.4&2 1.120.1440.3390.4780.3020.379

0.002 1.340 0.000. 1650.2760.1080.2000.6760.5730.6120.194

0.178 0.138 1.290.322

1.030 1.000 1.0e0.5860.0200.1420.0670.7190.394

3.457 3.666 B.52

0.2110.0110.213

0.1230.93;?0.934

0.223 1.516 0.150.971

A R I 0 0 3 3

NO525354555657535960616263646566676869( ''j~t i

RETCL)21*1516:5117:3518:8919:0520:3921:1524:1121:1923:2524:1924:2324:2625:8126:2921:5421:5222:4223:25?: i • ;: i

RATIO RRT(L)1.1970.9490.9911.0231.075

0.991.000.991.00

B.990.99

1.1631.1971.0630.8760.9620.9991.6021.0661.029I. BBS0.9010.8?98.9330.952G.PVti

RftTIO

1.001.000.991.00

1.061.00

flMNT

2B.20.0.40.

24.15.

23007234

8634

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.00

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.69

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.60

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R.FftC R.FfiC(L)1 . 02E)0.1570.1270.0960.118

B.2361.6000.0026.883

0.734B.644

0.0230.4191.000O.ME)1.0940.9340.0666.31!.1.4762.6996.3396 . 3950.5120 . 40P0.03(1

Ratio

0.561.000.010,B1

0.500.31

777379B6

5?

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3e:l

t '.tC. '&.;_....

1.0S31.103

1.00 48.00

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t-tC/>OW^ y>- ft* c:re iT N. >y^&i-r-r-'coi; i • -'i '**-. r*I-: • • - <r>.- -t.i rco-w to...; .-> ».4.V)..- WO'

C"'" '•""»-*ni©m

otrj

.OS

jTur*F—-^

—'.71 —

£!W•"(.0

N.i

11'tT-j : r

SArl?LE ^'-l

i

nn UT :L£ FK <:

-'

FIT

C4.H10»•'• in UT t., i

B PK €?SANK :>HI 2.,FIT &.

0-i'CS/::> 13:03:00 + 5:35SAKPi".: i::7AG2« BLAtiK 63(c 15? 2,: or/

C5.H1211n '.'T >

& PK <KM1X>fl 12:FIT &

DATA: 23252V3 C 108CALI: FCi12331 J

BASE ti/E: -53EIC: 9231

.,CO

in

CDO

or.

129

UiiKAllY SfcAi-CH04/08,02 S3:03:00 + 0:53SAMPLE E?AGEHT BUIIK C33-261

L—• IS 15B 2H OT)

PATA: 23352V3 f 172CAIS: FC112581 J 1

BASE EBIC: 12751

1VK^< ' V

SAMPLE J

C5.H10.C1ft -i

M UT IB PK ttRANK iIN 29 '•'.FIT 9L,

C4.H6.C210i- ' "1

U UT tGB PK 43BANK ?IN 22C .FIT 9^.

C4.H6.f?10-r • -1

n UT * oD FK <3BAtIK 3IN 11 'FIT a.,:.

r

;

r • • • • | — '-

P

, . . . ! - , —— 1-

r

, —————— , —— U

r

1

i ij , . , , . ( . . . . . . . . ( . . . . , . . . . , i . . . i . , . . , . . . . , . .

UDi

COCDCD-

cc,—— i ——— | ——— . ——— . ——— r--, ——— I ——— . ——— . ——— I ——— . ——— 1 ——— . ———— -, ——— . ——— ] ——— . ——— r—— , ——— -, ——— . —— , ——— . ——— . ——— , ——— 1 —— - ——— , ——— , ——— i —— . ——— , ——— , —— ——— , ——— , ——— , —— ~«5-t —— —— 1 ——— ' ——— «

2-3-EUTAflED-CIE

J | ^ , ... | , , I . ,——,--, , , p.-^ , ,-,.-,--. , , , .-., , , . ^ , ,—— . ——— ,- , ,—— , -n —— , ,-,.-.--1 ——— , ——— , ——— J

IVE -

c

257 J

63. H

328 _

i00.8-i

322 _

mn russ04/19/32 21:25:88SAHPLE: C5648-BIOXINBANGE: G 1, 8 LABEL: N 3, 4.8

DATA: 23352D2 ft174CALI: FCI12581 fil

A 1, 1.8 BASE: U 59, 3

SCANS 158 TO

1752:37

1882:42

1852:46

187

5376.

257.877

328.8968.588

6338.

322.896± 8.588.

3872.

324.8978.588

SCAM

eesi . i .

=0

CDCDCO

00

. I . I . I • I . I . I . I . I . I . I

15 I8KI13J :I1V3SSVU fT!U

> •i ;

^O^i^- '2c.

3INA:ed)

P. E. PEST, HIXF'HS 200ISO 62 RPR 013 11:26:420

CHRNNEL 4 RUN 5 FILE 7 METHOD 5

INDEX 1 CRLIBRflTION

NflME CONC RT RP.EFl KF

123

fl-BHCG-BHCB-BHCHEPTD-BHCflLDRIN1011

HEPT-EPOXfl-ENDOODEDIELDRINENDRIN17

DDD-B-ENODOTEND-flLDEND-'SULF22

METHOXV

TDTfiLB

• 4v

. 2

. 87

. 2

. 51• c.

. 2

. 424

. 2

. 2

. 51-?

i 57. 23

1. 11

1

86105117134166188202218242281309358448510540654710777930

1030124015101743

626626353491

1853481294091730411067651485679594676104790

10587473066

101062121034126056

199813051914773935525

22585510750109694

S\••_Ii11_,1i1L_*I^_,1L1jS<•_

926700647000193900533800291300479700

529300172200505300605200247200

435100259200371600203500

109700

6. 922 2103040

MEW FILE

NflME

R-BHCG-BHCB-BHCHEPTD-BHCRLDRINHEPT-EPOXfl-ENDODDEDIELDRINENDRINDDD-B-EHDDDTEND-RLDEND-SULFMETHOXV

RT

133166188202217242357447509540653776928

102812401741

KF

926700647000198900533300291300479700529300172300505300605200247200435100259200371800£03500109700

GT'GfNA

L50B

741

P. E. PEST, MIXPHS 200ISO

CHftHHEL 4 RUH 6

INDEX 2

NflME CONC

12

fl-BHCG-BHCB-BHCHEPT0-BHCflLDRIH

910

HEPT-EPOKfl-ENDODDEDIELDRINEHDRIH

16DPO-B-EHDDDTEND-RLD

£2 RPR 013 12:09:3:30

FILE 7 METHOD 5

RT RREfi KF

20119484S199507197

196416194193521

296534227

86104133166188201

. 2172432803093574475085406527107?59281028

65902542

18589612553B1685871062631478159438474124671

10368071746979371166521288632109

12SS89138446S4485

SS_l111_l111L_>1_»_j1L1_i

9267006470001989005338002913:00479700

5293:00172300505300605200247200

435100259200371800

f l f i !0035l

EMC-SULF21

METHOXV

TOTflLS

1. 1

. 985

6. 806

124115061741

22384011335108027

2065757

S 203500^•v 109700

ORlGi r 'L(Red)

^&^

219

P443

510566

622

802

OOT>

SI6977

L090

L197

fl.417

L657

LB30

flfi/00352

P.E-PEST,MIXPHS 2DOISO

CHflNHEL 4 RUN 7

B2 RPR 013 12:27:010

FILE 7 METHOD 5

79

920

L062

L400

L517

/L6GO

i.

ORIGINAL

P. E. PEST, MIXPHS 200ISO

CHRHNEL 4

INDEX 8

NRME

1fl-EHCG-BHCB-BHC

RUN 12

CONC

. 002

. 005

. 05?

82 flPR 013 14:52:100

FILE 7 METHOD 5

RT

106

fiREfi

167ISO

KF

1857 S1983 S 9267DO2081 < 64700011261 •-_ 198900

ARI00353

V

CHRHHEL A

INDEX 10

NHME

1fl-BHCG-BHCB-BHCflLORIH ,HEPT-EPOX,EHO-SULF .METHOXV

TOTfiLS

RUN 15

COHC

FILE

RT

METHODORIGINAL

(Red)

RREfl KF

005008059009002034078

IDS13616617B26039111971660

117550725090117654518101569448526

\S 926700< 647000. 19B900479700

L 529300203500

.. 109700

. 196 44105

712

800

1197

L413

L56D

L66D

L813

P. E. PEST, WIXPHS 200ISO

CHHNNEL 4 RUH 16

INDEX 11

HOME CONC

12

fi-BHCG-BHCB-BHCflLDRINHEPT-EPOXENt>-flLDHETHOXV

62 RPR 013 16 05:540

FILE 7 METHOD 5

V ,

RT RREH KF

023017201004002003033

10612513416617826038B10671660

1667141912177411351399331808122711343603

11 fl P Jj 9 2 67-0 Ui 647000S 19B900i 479700529300

i 371800•«, 109700

00351*

TOTftLS .284 101692

I N D E X

HftflE

1

TOTflLS

crCOHC RT

12

f lREfi

1117 L

1117

C 110536

260

37391

04

530

so;

g s~?-Ifa

1197

1410

leeo

6 U

ARI00355

P.E.PEST,MIXPHS 200ISO 82 RPR 013 15:40:440

to.870

E-PEST,MIXPHS 200ISO 82 flPR 013 16:20:470

IRHNEL

1DEX 12

WE

1-BHC-BHC-BHC.DRIH67

IPT-EPOX9

JDRIN•D-E-EHOID-flLD131D-SULF15:THOXVJTfiLS

ff*f-f ' ' '

J==}230L309

4 RUN 17 FILE 7

CONC

. 559

. 099

. 016

. 055

.021

. 006

. 004

. 007

. 023

. 252

1. 043

<S-TQ df

1U4i

RT

1081 8178210261230329366336712762

10631130119713631667

T3 —————

eil ('

flREfl

1695415184631971247792658656162962

11226610014051626259630345795103627676

808163

f

METHOD 5

1S\S1L111iL11S\S

Ki

926700198900291300479700

529300

247200435100371800

203500

109700

"5'

'00356.02

240

L510

ORIGINAL(Red)

'1743

P.E.PEST,MIXPHS 200ISOCHRNNEL 4 RUN 18

INDEX 13

NRME

122

R-BHCG-BHCB-BHCHEPTP-BHCRLC'RIM1011

HEPT-EPOXfl-EHDODDEDIELDRINENDRIM17

DDD-B-ENDDOTEMD-RLDEND-SULF

22METHOXV

TQTRLS

COHC

62 flPR 013 16:55:470FILE 7 METHOD 5

RT RREft KF

.

.

.

.

.

.

.

.

.

.

.

.

.

.1.•

6.

211204891193556205

2044241932527

30954922311

965

973

86105117134166188202217243230309357447510540654710777920

1027124015101743

671327272946

1956471320751772221032441619333820713693904

10326173090100152121234130334

13091344571423818471722578510434105S31

2125027

S\S_,11i-J11i_,-11-J_,1LILS<'-

92670064700019B900533800291300479700

529300172300505300605200247200

435100259200371800203500

109700

wes; TECHNICAL SERVICE INC. iNDUSTRl t6ORY.CHiGlNAL

SAMPLE ID Lr\e> B>L\ LAB ID / 2BSSZV I

DATE INJECTED 4tb

ANK SAMPLE ID MlSTHOO e»l-*OK ^PpH^LAB

$2_ DATESTD ID "BPSOOS" VDLd)2_3> DATECONC.. FACTOR ~

'•-'.'• • ' . "'V:- '

Volatiles2V ,3V

acroletnacrylonitrile

ID \ f&\C£ "K-

EXTRACTEDINJECTED 4-

2.^,a

<£>

P,lfs-

ez-

STD ID TfeA^lt* 2J^25^CONC . FACTOR O.Oc

ug/kg Pesticides5OO U 89P

4V benzene6V7V10V11V13V14V15V16V17V

'19V£3V'29V

• 30V

carbon tetrachloridechlorobenzene1 , 2-dichloroethane1,1, 1-trichloroethane1 , 1-dichloroethane1,1, 2-trichloroethane1 , 1 ,2, 2-tetrachloroethanechloroethanebis(chloromethyl) ether2-chloroethyl vinylchloroform

ether

1 , 1-dichloroethylene1,2-trans-dichloroethylene

'. 32V^> 1,2-dichloropropane*3Q.T" - 1, 3"jdichlorbpropylene';38V -ethylbenzene

-'45V •:46v

47V48V

- 4 9 V50V51V-85V

-86V87V88V

methylene chloridemethyl chloridemethyl bromidebromoform

90P91P92P93P94P95P96P97P98P99P100P101P102P103P

aldrindieldrinchlordane4,4'-DDT4,4'-DDE4,4 ( -DDD

(F- \Orr>\

ug/kg

* .

alpha-endosulfanbeta-endosulfanendosulfan sulfateendrinendr in aldehydeheptachlorheptachlor epoxidealpha-BHCbeta-BHC

.

«,•* i '

•104P gamma-BHC105P106P

107P-76C 108PGCOU 109P

dichlorpbromomethanetrichlorofluoromethanedichlorodifluoromethanechlorodibromomethanetetrachloroethylenetoluenetrichloroethylenevinyl chloride »

HOPHIP112P113P

U -*;-

** _.

delta-BHC

PCB-1242PCB-1254PCB-1221PCB-1232PCB-1248PCB-1260PCB-1016toxaphene

> r."ifcf f 4 '

- ; • ' . •" •>.

\

v •, ;

sF"-

-

Analyzed for but not detectedDetected below quantitationlimit ;Not confirmed by GCMS

A R I 0 0 3 5 8Fahrira Wau Quite D r»rritn«; California 90701 913/9?l-9B3l

Q.C. Report No:

tLhMiCALStKVlCt INC. li\DLj^, KiAL CATEGORY

ORGANICS ANALYSIS. DATA SHEET - Page'3ageORIGINAL(Red)

Samole Number

A. SURROGATE SPIKE RESULTS -' ." -

- ,\f.,r COMPOUND '•_ . -f*s ly^T-I^Lchlorobenzene ,D4

Benzene. b6: ' . ' ' • ' • . . / '

E.thylbenzenfi DID'Phenol' D52- Fluoropheno^lNitrobenzene D5Pyrene D10Decaf luorobiphenyl

. 1,2,3,4-TCDD . '

Frac t ion

VOA

VOA

VOA

BMA

BNA

BNA

BNA

BNA

TCDD

Cone. (ug/kg)

ZH^OOO2-M>c>oazs}Ooo

NAv '

'

(Surrogates Only)S p i k e . . ,

Added ( u g / kg) »2.5,000 : *2.€",COQ——— — ——— ———— —— ' —— ;

Z-SjOOOM*\

•i: ———— : ———

• » - ' * 4 1 " -'-Recovery,"' f "eft ' ' - V' 9fc

100 . . . - .r^

•!

*

'

B. TENTATIVELY IDENTIFIED COMPOUNDS•

1.2.-3.4.5.6..7.8.9.10,11..12.13.14.is:16.

H'

CONC.(ug/kg)

*

-.

, *

COMPOUND NAME FRACTION

—————————————— fr?I0035

% Maximum Score Attained 'Mass Matching Routine: FIT

(specify)•- ! ' ;

' '

. :'•

J

W6S eCHNICAl SERVICE INC. INDUSTR .ORY.

SAMPLE ID Cs£)H~l SAMPLE ID GSO<t~7 CRIGl i' LAB ID "'• z-J&'S'Z.v *4 LABDATE INJECTED 4 U/&7- DATESTD ID ' ?>FftO£>£5 SOL.O2.S DATE

ID ~n2Ace^ Z.U54, êc

EXTRACTED 4) 12. 82.INJECTED Hll^'/ftZ^

i , / l/ N. " ':. CONC. FACTOR \.Q6r - IO^\ ( Yso OvumoaJBTD ID t EJSCê* Z40Zf\".. . • . ' ' ; - . ,V. ' !;;"A!' ; . -• -• . - " "CONC . FACTOR l.O^r — \O^^ •

-' Volatiles ucj/'kg Pesticides ucr/kav2V acrolein ' 6OOO 89P

3V acrylonitrile• 4V ^ benzene

6V 'carbon tetrachloride7V chlorobenzene ^

90P91P92P93P

iOV 1,2-dichloroethane lôOÔOO 94P11V l,ljl-trichloroethane SOOLJ 95P13V 1,1-dichloroethane14V 1,1,2-trichloroethane15V 1, 1,2,2-tetrachloroethane16V chloroethane17V bis(chloromethyl) ether19V 2-chloroethylvinyl ether

. 23V '"chloroform, 29V- • T.l-dichloroethylene..30.V 1, 2-trans-dichloroethylene• 32V 1,2-dichloropropane• 33V 1,3-dichloropropylene ^

96P97P98P99P100P101P102P103P104P105P106P

38V ethylbenzene 2CQO 107P44V methylene chloride }"^>OC> 108P

. 45V methyl chloride 6CX>(J 109P46V methyl bromide.47V bromoform

^%8V--,. dichlorobromomethane^fe -.; ..43 • . —— — ————————————^49V .':^ trfchlorofluoromethane'..50V dichlorodifluoromethane51V chlorodibromomethane

.85V -êtrachloroethylene

110PHIP112P113P

U -L_ J t f -

86V 'toluene 2. 0 D: 87V trichloroethylene 22.OOO ** "

88V vinyl chloride ^>60L?

aldrin . \OQ(dieldrinchlordane *4,4'-DDT '4,4'-DDE4,4'-DDDalpha-endosulfanb«ta-endosulfanendosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxidealpha-BHCbeta-BHCgamma-BHCdelta-BHCPCB-1242

PCB-1254PCB-1221PCB-1232PCB-1248 tf .*'• -PCB-1260 - I/.

PCB-1016 •.. .. *^j 3 Mltbxaphene * - - ' \ ' «"' '-^^:

Analyzed for but not detectedDetected below quantitation * •limit . . ;, •

Not confirmed by GCMS * . • .-

17605 Fabrica Way, Suite D Cerritos, California )7D1 4l7/

SAMPLE IDLAB ID

WEST COAST TECHNICAL SGRVIC6 INC. INDUSTRIAL CATEGORY

r. SVAT___-__:_

DATE EXTRACTEDDATE JNJECTED__STD IDCONC FACTOR Q,2s6: Tt> 5~MLS-

.Acid Compounds21A 2,4,6-trichlorophenol22A • p-chloro-m-cresol24A 2-chlorophenol

ug/kg

31 A 2 , 4-dlchlorophenol34A 2 ( 4-dimethylphenol57A 2-nitrophenol58A 4-nitrophenol59A 2,4-dinitrophenol60A 4,6-dinitro-o-cresol64A pentachlorophenol65A- phenol

'Base/Neutral Compounds

IB acenaphthene 20. OOP U.5B8B

benzidine1 ,2,4-trichlorobenzene

9B ' hexachlorobenzene12B hexach.loroethaneU.8ff ,^5f2-chloroethyl)ether'20o '2-cTiloronapthalene25B • 1 , 2-dichlorobenzene26B 1,3-dichlorobenzene27B28B35B36B37 B

39B40B

1 , 4-dichlorobenzene3,3'-dichlorobenzidine2 , 4-dinitrotoluene2,6-dinitrotoluene1 ,2-diphenylhydrazine(as azobenzene)

fluoranthene / .4-chlorophfiuwl. p/Wi>y^ ether v

SAMPLE ID^LAB IDDATE EXTRACTEDDATE INJECTED^STD ID

(Red)

CONC FACTOR

Base/Neutral Compounds ug/kg41B42B43B52B53B54B55B56B61B62B63B66B67B68B69B70B71B72B73B74B75B76B77B78B79BSOB81B82B83B84 B

4-bromophenyl phenyl ether ZOOOOlbis(2-chlorolsopropyl) etherbis ( 2-chloroethoxy ) methanehexachlorobutadiene ' •hexachlorocyclopentadieneisophoronenaphthalenenitrobenzeneN-nitrosodimethylamineN-nitrosodiphenylamineN-nitrosodi-n-propylaminebis (2-ethylhexyl) phthalatebutyl benzyl phthala tedi-n-butyl phthalatedi-n-octyl phthalatediethyl phthalatedimethyl phthalatebenzo(a ) anthracenebenzo(a)pyrene

•

f

". • . 'V';. . _/

v ...

* . <

3,4-benzoflUoranthene*^.- - ^ »„>,benzo{k)fluoranthene " *** '/'':^vchryseneacenaphthyleneanthracene /benzo(ghi)perylene •-fluorenephenanthrenedibenzot a, h) anthraceneindeno(1.2.3-cd)pyrene

IB^F'• '^-^;

'?

i. ,pyrene

129B 2,3,7,8-tetrachlorodibenzo-p-dioxin____________

17605 Fabrics Way, Suite D Cerritos. California 90701* SEE SURROGATE SPIKE

213/921-9831

1^' WGbT COAST TECHNICAL S6RVIC6 INC INDUSTRIAL CATEGORY.

ORGANICS ANALYSIS DATA SHEET - Page'3

Q.C. Report No: ORIGINALSamole Number

' • • • ' • j f — HlCyH TPtiP - p b YVWTKuc iiotL^.1 -

' ' . - " . - . " A . SURROGATE SPIKE RESULTS ' ' . ~ *

COMPOUND

1 , 2T-Dichlorobenzene ,D4———— jL ————————— ————————————————

Benzene D6Ethylbenzene DIDPhenol D52- Fluorophenol

.Nitrobenzene D5Pyfene DIGDecaf luorobiphenyl

'', .i;2,3,4-TCDD

Fraction

VGA

VOA

VOA

BNA

BNA

BNA

BNA

BNA

TCDD •

Cone. (ug/kg)

L^jOoc*Z-^ÔCO

2&} OOO-Zôoou

1,4 40,0001,4^0,000

540,000N / RIHcu

(Surrogates Only)Sp ike

Added (ug/ kq)

2-5, OCOZSftoo/.2.5,000A CO, OOO

Zy^ 00,000•£,400,000

' 400,000

40QOOO

Hci>0 _ •

'% . •Recovery .

2(o^ ^^b^0o

; • Uiolo l——— *** — T-^

ISS'N / 9

' 0-

B. TENTATIVELY IDENTIFIED COMPOUNDS4

•

1.

2V3., '4,-

5 . '6.

7.8.9.10.11..12.13.14.15,16.17

CONC.

(ug/kg)

l,oa0,OOO

| «p£0 ; '

''..-.y-'1 ~

•

COMPOUND NAHE

6H~rS.S-jj/MFm^Hejo i/oe.

f lR;

FRACTION

6/Mfl^79S

B/wMÎI^S

0036?- — .

% Maximum ScooeftAttained*\ .

Mass Matching Routine: FIT. (specify)-

987 , '937 ' • ' r " - '-'-f *'t^

•.v»

•'->:/..!;

•

', 1!' '

WEST COAST TECHNICAL SERVICE INC INDUSTRIAL CATEGORY.

SAMPLE ID."LAB uDATE EXTRACTEDDATE INJECTED^'STD ID

4-i4-fcz '

SMflPoa-7

CONC FACTOR O.OO- TO SfUS

SAMPLE IDLAB ID

COMBl/on> re^c.TiONJ

DATE EXTRACTEDDATE INJECTED^STD ID

*'

CONC FACTOR

Acid Compounds ug/kg21A22A24 A31A34A. .57A58A59A60A64A65A

2,4, 6-trichlorophenol *ZO. OOOUp-chloro-m-cresol2-chlorophenol2 , 4-dichlorophenol2 , 4-dimethylphenol2-nitrophenol4-nitrophenol2,4-dinitrophenol4,6-dinitro-o-cresolpentachlorophenolphenol \i/

Base/Neutral Compounds ug/kg

Base/Neutral Comounds

IB acenaphthene 2OOOO U.5B8B•9B12Bi&e20B25B26B

,27B28B

benzidine (1,2,4-trichlorobenzenehexachlorobenzenehexachloroethanebis (2-chloroethyl) ether2-chloronapthalene1,2-dichlorobenzenel,3-:dichlorobenzene1 , 4-dichlorobenzene3,3'-dichlorobenzidine

".35^ 2,4-dinitrotoluene^§BB ,2,6-dinitrotoluene37B

39B40B

1 ,2-diphenylhydrazine(as azobenzene)

fluoranthene

1

4-chlorophenyl phenyl etherVf lR I00363

41B42B43B52B53B54B55B56B61B62B63B66B67B68B69B70B71B72B73B74B75B76B77B78B79BSOB81B82B83B84 B

4-bromophenyl phenyl ether t£>>OOCbis(2-chlorolsopropyl) etherbis (2-chloroethoxy) methanehexachlorobutadienehexachlorocyclopentadieneisophoronenaphthalenenitrobenzeneN-nitrosodimethylamineN-nitrosodiphenylamineN-nitrosodi-n-propylaminebis (2-ethylhexyl) phthalatebutyl benzyl phthalatedi-n-butyl phthalatedi-n-octyl phthalatediethyl phthalatedimethyl phthalate . 'benzo(a) anthracene v

benzo(a)pyrene 13,4-benzofluoranthene ;benzo(k)fluoranthene !

chryseneacenaphthylene * ianthracene ( •'•"benzo(chi)perylene

* ' * •''fluorene * >, . i Aphenanthrene *" rdibenzo( a, h) anthraceneindeno(l ,2 f3-cd)pyrenepyrene v

129B 2,3,7, 8-tetrachlorodibenzo-p-dioxin

17605 Fabrics Way. Suite D Cerritos. California 90701* SEE SURROGATE SPIKE

213/921-9831

INC. INDUSTR. ORY

SAMPLE ID CbOHfe SAMPLE ID CSOMft /pLAB ID 2.3^>£>2_V3> LAB ID T£^£_e*: ^ 2-fc>3»7

• DATE INJECTED ^j/^ S>2_ DATE EXTRACTED 4|i2.|&-2_STD ID BFB<Z>(£5~' VOi__$2_S DATE INJECTED 4/r5/ft3l

CONC. FACTOR O.O6- — I0rv\) ( Vfe pic.. ) STD ID TfeA^e * Z6-.33rf, r . . _ "CONC. FACTOR o.Oc, -• iom-\ * ji'

1 "^ . r » _ ' - ' *' /' ' *

JJolaUiies ug/kg Pesticides - v .. ug#kis^Ij^c^lein^' •- •*- fbOOO 89P aldrin >•.> -^ "•? A|V'3V, : : acrylonitrile

4V> benzene>£y ''''carbon tetrachloride

7V chlorobenzene.10V 1,2-dichloroethane11V 1, 1,1-trichloroethane13V 1,1-dichloroethane14V 1 , 1 ,2-trichloroethane15V 1,1,2,2-tetrachloroethane16V chloroethane

•17V bis(chloromethyl) ether19V 2-chloroethylvinyl ether23V chloroform29V 1 , 1-dichloroethylene30V 1 , 2-trans-dichloroethylene32V 1 , 2-dichloropropane33V 1 , 3-dichloropropylene

90P dieldrin " :" :

91P chlordane92P 4, 4 '-DOT93P 4, 4 '-DDE94P 4,4'-DDD95P alpha-endosulfan96P beta-endosulfan97P endosulfan sulfate98P endrin99P endrin aldehyde100P heptachlor101P heptachlor epoxide102P alpha-BHC103P beta-BHC104P gamma-BHC105P delta-BHC106P PCB-1242

38V ethylbcnzene ZOOO 107P PCB-125444V methylene chloride I\ ,OCO 108P PCB-1221— . —————— J. ————— — ————————— —— ————————————————————— , —————45V methyl chloride 5OOO 109P PCB-123246V methyl bromide47V bromoform48V dichlorobromomethane49V trichlorofluoromethane

:'56V ' ."dichlorodinuoromethane'51V ' .chlorodibromomethane

85V tetrachloroethylene86V toluene

^87V-. -trichloroethylene88V vinyl chloride

HOP PCB-1248111P PCB-1260112P PCB-1016113P toxaphene ,

TI _ A n a l y ^ ^ f l fr»r fcit* n^t flf>+e>r*:

W - Detprteri below qnantitationlimit

** - Not confirmed by GCMS

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A R I 0 0 3 6 1 *17605 Fabrica Way. Suite D Cerritos, Calilornia 90701 213/921-9831

WtS!' COAST TECHNICAL SERVICE INC. INDUSTRIAL CATEGORY

ORGANICS ANALYSIS DATA SHEET - Page'3Q.C; Report No:___________ ORIGINAL-.. - , -.5*.,. . - -(Red) .-

Samole Number

'• ' ' A. SURROGATE SPIKE RESULTS . ' .

. ' " : COMPOUND

1 , 2^Dichiorbbenzene ,D4Benzene "D6

^ . . . • * * . '

'Ethylbenzene DIDPhenol D5 •2- FluorophenolNitrobenzene D5Pyrene DIDDecaf luorobiphenyl1,2,3,4-TCDD . '

Fraction

VGA

VOA

VOA

BNA

BNA

BNA

BNA

BNA

TCDD

Cone. (ug/kg)

ZHjDOOZb.OfcO—— ~ — st^ ——— . — _„zs^oo

-ZO.QOO CL ",

1,800,000

1,28^,0005^0, ODD

M ftS(oO

( Surrogates. Only") ' •Spike

Added (ug/ kg)

2,6,000Z5jOCO-2. 000£00,000

tAob.QQOZ.,400,000.• Aoo.ooo. 400,000

1HOO

" X • ' - . " - - ; -Recovery .

- qW •IOO/ooo

. -?5"S'S—————— '^^•M i n,|

140K»^

-HO.,B. TENTATIVELY IDENTIFIED COMPOUNDS

1.

2..3.

4.5. .

6.

7.8.9.10. i

**'-•12.13 .i14.15.16.17.

CONC.

(ug/kg)

*^ ' •";f * ^ :;

. • . '- ' -ii'i

..* "

COMPOUND NAME FRACTION

/ Rinn.? _

% Maximum Score Attained ' =Mass Matching Routine: FIT

(specify)j• ,;• ...

. ' ' ' ' • ( .. .. . . >

,

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sample report (numerous attachments) · olc's to the hwi sample management office at (703)...

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