safety data sheet - nippon paint (nipsea)pc.nipponpaint.com/wp-content/uploads/hi-pon40-04... ·...

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SAFETY DATA SHEET

Version No: 003

1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THECOMPANY / UNDERTAKING

Product Name: HI-PON 40-04 EPOXY TOP COATIntended Use: Solvent-Based Protective PaintManufacturer: Nippon Paint (S) Co. Pte Ltd

No. 1 First Lok Yang RoadJurong Singapore 629728

Emergency Phone Number: (65) 6 265 5355Fax Numbers: (65) 6 264 1603

2. HAZARDS IDENTIFICATION

GHS Classification:

Physical HazardFlammable Hazard Category 3

Health HazardSkin corrosion/irritation Category 2Serious eye damage/irritation Category 2Skin sensitization Category 1Germ cell mutagenicity Category 1Carcinogenicity Category 1

Environmental HazardNot classified as an environmental hazard under GHS criteria

GHS Pictogram

Signal WordDanger

Hazard statementsH226: Flammable liquid and vapourH315: Causes skin irritationH317: May cause an allergic skin reactionH319: Causes serious eye irritationH340: May cause genetic defectsH350: May cause cancer

SDS Number: SDS-70010

HI-PON 40-04 EPOXY TOP COAT

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Precautionary statementsP201: Obtain special instructions before useP202: Do not handle until all safety precautions have been read and understoodP210: Keep away from heat/sparks/open flames/hot surfaces – No smokingP233: Keep container tightly closedP240: Ground/bond container and receiving equipmentP241: Use explosion-proof electrical/ventilating/light/equipmentP242: Use only non-sparking toolsP243: Take precautionary measures against static dischargeP261: Avoid breathing dust/fume/gas/mist/vapours/sprayP264: Wash hands thoroughly after handlingP272: Contaminated work clothing should not be allowed out of the workplaceP280: Wear protective gloves/protective clothing/eye protection/face protectionP281: Use personal protective equipment as required

ResponseP321: Specific treatment (see Section 4 of SDS)P362: Take off contaminated clothing and wash before reuseP363: Wash contaminated clothing before reuseP302+352: IF ON SKIN: Wash with soap and waterP308+313: IF exposed or concerned: Get medical advice/attentionP332+313: If skin irritation occurs: Get medical advice/attentionP333+313: If skin irritation or a rash occurs: Get medical advice/attentionP337+313: If eye irritation persists: Get medical advice/attentionP370+378: In case of fire: Use appropriate media for extinctionP303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.Rinse skin with water/showerP305+351+338: IF IN EYES: Rinse continuously with water for several minutes. Remove contactlenses if present and easy to do – continue rinsing

StorageP405: Store locked upP403+235: Store in a well ventilated place. Keep cool

DisposalP501: Dispose of contents/container to appropriate waste site or reclaimer in accordance with localor national regulations

3. COMPOSITION / INFORMATION ON INGREDIENTS

Substances CAS No. %Bisphenol-A type solid epoxy resin 25036-25-3 19-42Xylene 1330-20-7 7-16Diacetone alcohol 123-42-2 4-102-Butoxyethanol 111-76-2 4-10Substances determined to be non-hazardous - Balance

100%

4. FIRST-AID MEASURES

INHALATION


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Move person to fresh air and call for medical assistance immediately.If not breathing, give artificial respiration, if breathing is difficult, give oxygen. Keep at rest.

SKIN CONTACT

In case of contact, immediately flush skin with large amounts of water and soap whileremoving contaminated clothing and shoes.If irritation persists, get medical attention.

EYE CONTACT

Immediately flush eyes with large amounts of water until irritation subsides.Remove contact lens.Obtain medical attention, preferably by an ophthalmologist, immediately.

INGESTION

DO NOT induce vomiting unless directed to do so by a medical personnel. Never giveanything by mouth to an unconscious person. Keep at rest. Get medical attention immediately.

5. FIRE FIGHTING MEASURES

SUITABLE FIRE EXTINGUISHING MEDIA

Alcohol - resistant foam, Carbon dioxide, or dry chemical type.

SPECIFIC HAZARDS ARISING FROM THE CHEMICAL

Combustion products may include and are not limited to: Carbon monoxide and Carbondioxide.

SPECIAL PROTECTIVE ACTIONS FOR FIRE FIGHTERS

Wear full protective clothing and NIOSH - approved self - contained breathing apparatus.Use water spray to cool fire - exposed surfaces and to protect personnel. If a leak or spill hasnot ignited, use water spray to disperse the vapours.If possible, isolate product from heat, electrical equipments, sparks and open flames.Avoid spraying water directly into storage containers.Closed containers may explode when exposed to extreme heat.Avoid spreading burning liquid with water, isolate liquid.Do not allow runoff from fire fighting to enter drains or watercourses.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURE

Wear appropriate protective equipment, e.g. respirators, eye protection, gloves and safetyshoes.Avoid substance contact with eyes. Do not inhale vapours.Ensure supply of fresh air in enclosed rooms.

ENVIRONMENTAL PRECAUTIONS

Eliminate sources of ignition.Keep public away.Contain spilled liquid with sand or other non-combustible absorbent materials.Wash area and prevent runoff into drains and sewerage system.Advise authorities if substance has entered a watercourse or sewer or has contaminated soilor vegetation.


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METHODS AND MATERIALS FOR CONTAINMENTS AND CLEANING UP

Clean up all spills immediately.Absorb spill with absorbent and inert material, then place in container.Disposal in accordance to local/national regulations.

7. HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING

Use appropriate personal protective equipment.Keep out of reach of children.Handle containers with care. Open slowly in order to control possible pressure release.Do not pressurize containers.Do not ingest. Do not breathe in gas/fumes/vapour. Avoid contact with skin and eyes.For personal protection, see section 8.Use only in areas from which all naked lights and other sources of ignition have beenexcluded.Take precautionary measures against static discharge.Protect from frost and extremes of temperature.

CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILTIES

Keep containers tightly closed.Containers that are opened should be properly resealed and kept upright to prevent leakage.Store in cool, dry and well - ventilated place at temperature between 20°C to 40°C away fromheat and sources of ignition.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

CONTROL PARAMETERS/OCCUPATIONAL LIMITS

Substances ACGIH TLV-TWA OSHA PEL-TWAppm mg/m3 ppm mg/m3

Bisphenol-A type solid epoxy resin - - - -Xylene 100 434.00 - -Diacetone alcohol - - - -2-Butoxyethanol - - - -

APPROPRIATE ENGINEERING CONTROL MEASURES

Provide exhaust ventilation or other engineering controls to keep the airborne concentrationsof vapours below their respective occupational exposure limits.Ensure eyewash stations and safety showers are close to the workstation location.

PERSONAL PROTECTION

Respiratory Protection: Use of NIOSH - approved respirators with organic vapourcartridges is recommended.

Hand Protection: Use of solvent resistance type or chemical resistant type ofprotective gloves is recommended.

Eye Protection: Use of safety glasses or goggles with side shields isrecommended.

Skin / Body Protection: Wear chemical resistant clothes and safety shoes whenhandling product.


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9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : LiquidOdour : Aromatic hydrocarbon odourOdour threshold : Not availablepH : Not availableMelting point/freezing point : Not availableInitial boiling point and boiling range : Between 65 and 171 °CFlash point : 23 °CEvaporation rate : Not availableFlammability (solid, gas) : Not applicableLower flammability or explosive limit : 1.1 % by volUpper flammability or explosive limit : 7 % by volVapour pressure : Not availableVapour density : > 1.00 (Vapour is heavier than air)Relative density : Not availableSolubility : Not Miscible in waterPartition coefficient : Not availableAuto-ignition temperature : > 230 °CDecomposition temperature : Not availableViscosity : 76 - 80 KU

10. STABILITY AND REACTIVITY

REACTIVITY

No dangerous reaction known under condition of normal use.

CHEMICAL STABILITY

The product is stable under recommended storage and handling conditions. (see section 7)

POSSIBILITY OF HAZARDOUS REACTION

Under normal conditions of storage and use, hazardous reaction will not occur.

CONDITIONS TO AVOID

Keep away from oxidising agents, strongly alkaline and strongly acidic materials in order toavoid exothermic reactions. Avoid all possible sources of ignition (spark or flame). Do notpressurize, cut, weld, braze, drill, grind or expose containers to heat or sources of ignition.

HAZARDOUS DECOMPOSITION PRODUCTS

When exposed to high temperatures may produce hazardous decomposition products such ascarbon monoxide, carbon dioxide, oxides of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There is no data available on the product itself.Toxicological information of substances: Acute oral toxicityHarmful if swallowed


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Substances Oral LD50(Rat), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 4300Diacetone alcohol 25202-Butoxyethanol 1300 Acute dermal/skin toxicityMay be harmful if in contact with skin Substances Dermal LD50 (Rabbit), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 1700Diacetone alcohol 135002-Butoxyethanol 2000 Acute inhalation toxicityVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract, may cause headaches and dizziness, could be anesthetic and may have othercentral nervous system effects. Substances Inhalation Vapor LC50 (Rat), mg/L/4hrBisphenol-A type solid epoxy resin Data not availableXylene 5000Diacetone alcohol Data not available2-Butoxyethanol Data not available

Skin corrosion or irritationCauses skin irritation. Frequent or prolonged contact may dry the skin, leading to discomfort anddermatitis. Serious eye damage or irritationMay be an eye irritant Respiratory or skin sensitisationVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract Germ cell mutagenicityNo information available on the product CarcinogenicityTitanium DioxideThe International Agency for Research on Cancer (IARC) has classified Titanium Dioxide aspossibly carcinogenic to humans (Group 2B) based on inadequate evidence of carcinogenicity inhumans and sufficient evidence of carcinogenicity in experimental animals

Reproductive toxicityNo information available on the product Specific Target Organ Toxicity (STOT)-single exposureNo information available on the product Specific Target Organ Toxicity (STOT)-repeated exposureNo information available on the product


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Asphyxiation hazardMay be harmful if swallowed and enters airways

12. ECOLOGICAL INFORMATION

ToxicityAquatic toxicity -No data available Persistence and degradabilityBiodegradation -No data available Bioaccumulative potentialNo data available Mobility in soilNo data available Result of PBT and vPvB assessmentNo data available Other adverse effectsThere is no ecotoxicological test data available on the product itself.The product should not be allowed to enter drains or water courses.

13. DISPOSAL CONSIDERATIONS

The product should not be allowed to enter drains and watercourses.Preferred methods of waste disposal are incineration or biological treatment in federal/stateapproved facility. Empty containers should be recycled or disposed through an approved wastemanagement facility or licensed contractor.All federal, state and local environmental regulations shall be observed.

14. TRANSPORT INFORMATION

Transport to be in accordance with ADR/RID for road/rail, IMDG for sea and IATA for Air.

LAND TRANSPORT

Classified as Dangerous Goods by the criteria of the European Agreement concerning theinternational carriage of Dangerous Goods (ADR) by Road & Regulations concerning theinternational carriage of Dangerous goods (RID) by Rail.UN Number: 1263Proper shipping name: PAINT (including paint, lacquer, enamel , stain, shellac, varnish, polish,

liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL(including paint thinning or reducing compound)

Class: Class 3Packaging Group: III

SEA TRANSPORT

Classified as Dangerous Goods by the criteria of the International Maritime Dangerous GoodsCode (IMDG Code) for transport of Sea.UN Number: 1263


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Proper shipping name: PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish,liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL(including paint thinning or reducing compound)

Class: Class 3Packaging Group: IIIMarine Pollutant No

SEA (ANNEX II OF MARPOL 73/78 AND THE IBC CODE)

Not applicable

AIR TRANSPORT

Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA)Dangerous Goods Regulations for transport by AirUN Number: 1263Proper shipping name: PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish,



15. REGULATORY INFORMATION

Applicable national regulations:

Standards on Hazard communication for hazardous chemicals and dangerous goods- SS 586: Part 1: 2014-Transport and storage of dangerous goods- SS 586: Part 2: 2014-GHS of classification and labelling of chemicals- SS 586: Part 3: 2008(2014)-Preparation of safety data sheet

MOM: Workplace Safety and Health Act & Workplace Safety and Health (General Provisions)Regulations

- This product is subject to SDS, labelling, PEL and other requirements in theActs/Regulations.

NEA: Environmental Protection and Management Act & Environmental Protection andManagement (Hazardous Substances) Regulations

- This product is not subject to control under this Acts/Regulations.SCDF: Fire Safety Act & Fire Safety (Petroleum and Flammable Materials) Regulations

- This product is subject to the requirement of this Acts/Regulations.SPF: The Arms and Explosive Act, the Arms and Explosives (Explosives) Rules, and the Armsand Explosives (Explosive Precursors) Rules

- This product is not subject to the requirement of this Acts/Regulations.

16. OTHER INFORMATION

Revision date: 06-Apr-2016

AbbreviationACGIH American Conference of Governmental Industrial HygienistsTLV Threshold limit valueTWA Time-Weighted AverageOSHA Occupational Safety and Health AdministrationPEL Permissible Exposure LimitLD50 Lethal DoseLC50 Median lethal concentrationIACR International Agency for Research in Cancer


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DisclaimerTo the best of our knowledge, the information contained herein is accurate. However, theinformation is provided without any representation or warranty, expressed or implied, regarding itsaccuracy or completeness. Since the conditions of handling, storage, use and disposal are beyondour control and may be beyond our knowledge, for this and other reasons, we make no guaranteeof results and assume no liability for damages incurred by the use of this product. Please bereminded that all chemicals may present unknown health hazards and should be used with caution.

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SAFETY DATA SHEET

Version No: 003


Product Name: HI-PON 40-04 BASE 1Intended Use: Solvent-Based Protective PaintManufacturer: Nippon Paint (S) Co. Pte Ltd




GHS Classification:




GHS Pictogram

Signal WordDanger



HI-PON 40-04 BASE 1

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100%


INHALATION

HI-PON 40-04 BASE 1

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SKIN CONTACT


EYE CONTACT


INGESTION














HI-PON 40-04 BASE 1

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PERSONAL PROTECTION





HI-PON 40-04 BASE 1

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9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : LiquidOdour : Aromatic hydrocarbon odourOdour threshold : Not availablepH : Not availableMelting point/freezing point : Not availableInitial boiling point and boiling range : Between 65 and 171 °CFlash point : 23 °CEvaporation rate : Not availableFlammability (solid, gas) : Not applicableLower flammability or explosive limit : 1.1 % by volUpper flammability or explosive limit : 7 % by volVapour pressure : Not availableVapour density : > 1.00 (Vapour is heavier than air)Relative density : Not availableSolubility : Not Miscible in waterPartition coefficient : Not availableAuto-ignition temperature : > 230 °CDecomposition temperature : Not availableViscosity : 76 - 80 KU


REACTIVITY


CHEMICAL STABILITY




CONDITIONS TO AVOID






HI-PON 40-04 BASE 1

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Substances Oral LD50(Rat), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 4300Diacetone alcohol 25202-Butoxyethanol 1300 Acute dermal/skin toxicityMay be harmful if in contact with skin Substances Dermal LD50 (Rabbit), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 1700Diacetone alcohol 135002-Butoxyethanol 2000 Acute inhalation toxicityVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract, may cause headaches and dizziness, could be anesthetic and may have othercentral nervous system effects. Substances Inhalation Vapor LC50 (Rat), mg/L/4hrBisphenol-A type solid epoxy resin Data not availableXylene 5000Diacetone alcohol Data not available2-Butoxyethanol Data not available



HI-PON 40-04 BASE 1

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LAND TRANSPORT




SEA TRANSPORT


HI-PON 40-04 BASE 1

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Not applicable

AIR TRANSPORT
















HI-PON 40-04 BASE 1

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SAFETY DATA SHEET

Version No: 003






GHS Classification:


Health HazardSkin corrosion/irritation Category 2Serious eye damage/irritation Category 2Skin sensitization Category 1


GHS Pictogram

Signal WordWarning

Hazard statementsH226: Flammable liquid and vapourH315: Causes skin irritationH317: May cause an allergic skin reactionH319: Causes serious eye irritation

Precautionary statementsP210: Keep away from heat/sparks/open flames/hot surfaces – No smokingP233: Keep container tightly closed


HI-PON 40-04 BASE 2

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P240: Ground/bond container and receiving equipmentP241: Use explosion-proof electrical/ventilating/light/equipmentP242: Use only non-sparking toolsP243: Take precautionary measures against static dischargeP261: Avoid breathing dust/fume/gas/mist/vapours/sprayP264: Wash hands thoroughly after handlingP272: Contaminated work clothing should not be allowed out of the workplaceP280: Wear protective gloves/protective clothing/eye protection/face protection

ResponseP321: Specific treatment (see Section 4 of SDS)P362: Take off contaminated clothing and wash before reuseP363: Wash contaminated clothing before reuseP302+352: IF ON SKIN: Wash with soap and waterP332+313: If skin irritation occurs: Get medical advice/attentionP333+313: If skin irritation or a rash occurs: Get medical advice/attentionP337+313: If eye irritation persists: Get medical advice/attentionP370+378: In case of fire: Use appropriate media for extinctionP303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.Rinse skin with water/showerP305+351+338: IF IN EYES: Rinse continuously with water for several minutes. Remove contactlenses if present and easy to do – continue rinsing

StorageP403+235: Store in a well ventilated place. Keep cool




100%


INHALATION


SKIN CONTACT


EYE CONTACT

HI-PON 40-04 BASE 2

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INGESTION

















HI-PON 40-04 BASE 2

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PERSONAL PROTECTION





9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : LiquidOdour : Aromatic hydrocarbon odourOdour threshold : Not availablepH : Not availableMelting point/freezing point : Not available

HI-PON 40-04 BASE 2

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Initial boiling point and boiling range : Between 65 and 171 °CFlash point : 23 °CEvaporation rate : Not availableFlammability (solid, gas) : Not applicableLower flammability or explosive limit : 1.1 % by volUpper flammability or explosive limit : 7 % by volVapour pressure : Not availableVapour density : > 1.00 (Vapour is heavier than air)Relative density : Not availableSolubility : Not Miscible in waterPartition coefficient : Not availableAuto-ignition temperature : > 230 °CDecomposition temperature : Not availableViscosity : 73 - 77 KU


REACTIVITY


CHEMICAL STABILITY




CONDITIONS TO AVOID





There is no data available on the product itself.Toxicological information of substances: Acute oral toxicityHarmful if swallowed Substances Oral LD50(Rat), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 4300Diacetone alcohol 25202-Butoxyethanol 1300 Acute dermal/skin toxicityMay be harmful if in contact with skin

HI-PON 40-04 BASE 2

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Substances Dermal LD50 (Rabbit), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 1700Diacetone alcohol 135002-Butoxyethanol 2000 Acute inhalation toxicityVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract, may cause headaches and dizziness, could be anesthetic and may have othercentral nervous system effects. Substances Inhalation Vapor LC50 (Rat), mg/L/4hrBisphenol-A type solid epoxy resin Data not availableXylene 5000Diacetone alcohol Data not available2-Butoxyethanol Data not available


Reproductive toxicityNo information available on the product Specific Target Organ Toxicity (STOT)-single exposureNo information available on the product Specific Target Organ Toxicity (STOT)-repeated exposureNo information available on the product Asphyxiation hazardMay be harmful if swallowed and enters airways


ToxicityAquatic toxicity -No data available

HI-PON 40-04 BASE 2

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Persistence and degradabilityBiodegradation -No data available Bioaccumulative potentialNo data available Mobility in soilNo data available Result of PBT and vPvB assessmentNo data available Other adverse effectsThere is no ecotoxicological test data available on the product itself.The product should not be allowed to enter drains or water courses.





LAND TRANSPORT




SEA TRANSPORT

Classified as Dangerous Goods by the criteria of the International Maritime Dangerous GoodsCode (IMDG Code) for transport of Sea.UN Number: 1263Proper shipping name: PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish,




Not applicable

AIR TRANSPORT

HI-PON 40-04 BASE 2

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AbbreviationACGIH American Conference of Governmental Industrial HygienistsTLV Threshold limit valueTWA Time-Weighted AverageOSHA Occupational Safety and Health AdministrationPEL Permissible Exposure LimitLD50 Lethal DoseLC50 Median lethal concentrationIACR International Agency for Research in Cancer DisclaimerTo the best of our knowledge, the information contained herein is accurate. However, theinformation is provided without any representation or warranty, expressed or implied, regarding itsaccuracy or completeness. Since the conditions of handling, storage, use and disposal are beyondour control and may be beyond our knowledge, for this and other reasons, we make no guaranteeof results and assume no liability for damages incurred by the use of this product. Please bereminded that all chemicals may present unknown health hazards and should be used with caution.

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SAFETY DATA SHEET

Version No: 003






GHS Classification:




GHS Pictogram

Signal WordWarning




HI-PON 40-04 BASE 3

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100%


INHALATION


SKIN CONTACT


EYE CONTACT

HI-PON 40-04 BASE 3

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INGESTION

















HI-PON 40-04 BASE 3

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PERSONAL PROTECTION






HI-PON 40-04 BASE 3

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REACTIVITY


CHEMICAL STABILITY




CONDITIONS TO AVOID






HI-PON 40-04 BASE 3

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HI-PON 40-04 BASE 3

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LAND TRANSPORT




SEA TRANSPORT





Not applicable

AIR TRANSPORT

HI-PON 40-04 BASE 3

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SAFETY DATA SHEET

Version No: 003






GHS Classification:




GHS Pictogram

Signal WordWarning




HI-PON 40-04 BASE 4

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100%


INHALATION


SKIN CONTACT


EYE CONTACT

HI-PON 40-04 BASE 4

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INGESTION

















HI-PON 40-04 BASE 4

Page 4 of 8











PERSONAL PROTECTION






HI-PON 40-04 BASE 4

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REACTIVITY


CHEMICAL STABILITY




CONDITIONS TO AVOID






HI-PON 40-04 BASE 4

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HI-PON 40-04 BASE 4

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LAND TRANSPORT




SEA TRANSPORT





Not applicable

AIR TRANSPORT

HI-PON 40-04 BASE 4

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SAFETY DATA SHEET

Version No: 003


Product Name: HI-PON 40-04 BASE REDIntended Use: Solvent-Based Protective PaintManufacturer: Nippon Paint (S) Co. Pte Ltd




GHS Classification:


Health HazardSkin corrosion/Irritation Category 2Serious eye damage/irritation Category 1Skin sensitization Category 1Germ cell mutagenicity Category 1Carcinogenicity Category 1

Environment HazardNot classified as an environmental hazard under GHS criteria

GHS Pictogram

Signal WordDanger

Hazard statementsH226: Flammable liquid and vapourH315: Causes skin irritationH317: May cause an allergic skin reactionH318: Causes serious eye damageH340: May cause genetic defectsH350: May cause cancer


HI-PON 40-04 BASE RED

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ResponseP310: Immediately call a POISON CENTER or doctor/physicianP321: Specific treatment (see Section 4 of SDS)P362: Take off contaminated clothing and wash before reuseP363: Wash contaminated clothing before reuseP302+352: IF ON SKIN: Wash with soap and waterP308+313: IF exposed or concerned: Get medical advice/attentionP332+313: If skin irritation occurs: Get medical advice/attentionP333+313: If skin irritation or a rash occurs: Get medical advice/attentionP370+378: In case of fire: Use appropriate media for extinctionP303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.Rinse skin with water/showerP305+351+338: IF IN EYES: Rinse continuously with water for several minutes. Remove contactlenses if present and easy to do – continue rinsing



3. COMPOSITION / INFORMATION ON INGREDIENTSSubstances CAS No. %Bisphenol-A type solid epoxy resin 25036-25-3 21.17-46.57Xylene 1330-20-7 14.03-30.86Azo pigment Not

available3.90-8.57

Diacetone alcohol 123-42-2 3.39-7.462-Methyl-1-propanol 78-83-1 2.26-4.982-Butoxyethanol 111-76-2 1.92-4.22Amino resin Not

available0.84-1.84



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INHALATION


SKIN CONTACT


EYE CONTACT


INGESTION













Eliminate sources of ignition.Keep public away.Contain spilled liquid with sand or other non-combustible absorbent materials.Wash area and prevent runoff into drains and sewerage system.Advise authorities if substance has entered a watercourse or sewer or has contaminated soil


Page 4 of 9

or vegetation.







Keep containers tightly closed.Containers that are opened should be properly resealed and kept upright to prevent leakage.Store in cool, dry and well - ventilated place at temperature between 20oC to 40oC away fromheat and sources of ignition.




Bisphenol-A type solid epoxy resin - - - -Xylene 100.00000 434 - -Azo pigment - - - -Diacetone alcohol - - - -2-Methyl-1-propanol - - - -2-Butoxyethanol - - - -Amino resin - - - -



PERSONAL PROTECTION




Page 5 of 9



9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : LiquidOdour : Aromatic hydrocarbon odourOdour threshold : Not availablepH : Not availableMelting point/freezing point : Not availableInitial boiling point and boiling range : Between 137 and 143 °CFlash point : 23 °CEvaporation rate : Not availableFlammability (solid, gas) : Not applicableLower flammability or explosive limit : 1.1 % by volUpper flammability or explosive limit : 11.2 % by volVapour pressure : Not availableVapour density : > 1.00 (Vapour is heavier than air)Relative density : Not availableSolubility : Not Miscible in waterPartition coefficient : Not availableAuto-ignition temperature : > 230 °CDecomposition temperature : Not availableViscosity : 68 - 72 KU


REACTIVITY


CHEMICAL STABILITY




CONDITIONS TO AVOID


HAZARDOURS DECOMPOSITION PRODUCTS




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There is no data available on the product itself.Toxicological information of substances: Acute Oral toxicityHarmful if swallowed Substances Oral LD50(Rat), mg/kgBisphenol-A type solid epoxyresin

2001

Xylene 4300Azo pigment 5000Diacetone alcohol 25202-Methyl-1-propanol 24602-Butoxyethanol 1300Amino resin Data not available Acute dermal/skin toxicityMay be harmful if in contact with skin

Substances Dermal LD50 (Rabbit),mg/kg

Bisphenol-A type solid epoxyresin

2001

Xylene 1700Azo pigment Data not availableDiacetone alcohol 135002-Methyl-1-propanol 34002-Butoxyethanol 2000Amino resin Data not available Acute inhalation toxicityVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract, may cause headaches and dizziness, could be anesthetic and may have othercentral nervous system effects.

Substances Inhalation Vapor LC50(Rat), mg/L/4hr


Data not available

Xylene 5000Azo pigment Data not availableDiacetone alcohol Data not available2-Methyl-1-propanol 80002-Butoxyethanol 4.9Amino resin Data not available

Skin corrosion or irritationCauses skin irritation. Frequent or prolonged contact may dry the skin, leading to discomfort anddermatitis. Serious eye damage or irritationMay be an eye irritant


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Respiratory or skin sensitisationVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract Germ cell mutagenicityNo information available on the product CarcinogenicityNo information available on the product









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LAND TRANSPORT




SEA TRANSPORT





Not applicable

AIR TRANSPORT






Standards on Hazard communication for hazardous chemicals and dangerous goods- SS 586: Part 1: 2014-Transport and storage of dangerous goods- SS 586: Part 2: 2014-GHS of classification and labelling of chemicals- SS 586: Part 3: 2008-Preparation of safety data sheet





- This product is subject to the requirement of this Acts/Regulations.SPF: The Arms and Explosive Act, the Arms and Explosives (Explosives) Rules, and the Arms


Page 9 of 9

and Explosives (Explosive Precursors) Rules- This product is not subject to the requirement of this Acts/Regulations.


Revision date: 27-Feb-2015


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SAFETY DATA SHEET

Version No: 003


Product Name: HI-PON 40-04 BASE YELLOWIntended Use: Solvent-Based Protective PaintManufacturer: Nippon Paint (S) Co. Pte Ltd




GHS Classification:




GHS Pictogram

Signal WordDanger



HI-PON 40-04 BASE YELLOW

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3. COMPOSITION / INFORMATION ON INGREDIENTSSubstances CAS No. %Bisphenol-A type solid epoxy resin 25036-25-3 20.84-45.86Xylene 1330-20-7 13.62-29.97Azo pigment Not

available4.31-9.47

Diacetone alcohol 123-42-2 3.27-7.202-Methyl-1-propanol 78-83-1 2.18-4.802-Butoxyethanol 111-76-2 1.85-4.07Amino resin Not

available0.89-1.96



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INHALATION


SKIN CONTACT


EYE CONTACT


INGESTION













Eliminate sources of ignition.Keep public away.Contain spilled liquid with sand or other non-combustible absorbent materials.Wash area and prevent runoff into drains and sewerage system.Advise authorities if substance has entered a watercourse or sewer or has contaminated soil


Page 4 of 9

or vegetation.











Bisphenol-A type solid epoxy resin - - - -Xylene 100.00000 434 - -Azo pigment - - - -Diacetone alcohol - - - -2-Methyl-1-propanol - - - -2-Butoxyethanol - - - -Amino resin - - - -



PERSONAL PROTECTION




Page 5 of 9





REACTIVITY


CHEMICAL STABILITY




CONDITIONS TO AVOID






Page 6 of 9

There is no data available on the product itself.Toxicological information of substances: Acute Oral toxicityHarmful if swallowed Substances Oral LD50(Rat), mg/kgBisphenol-A type solid epoxyresin

2001

Xylene 4300Azo pigment 5000Diacetone alcohol 25202-Methyl-1-propanol 24602-Butoxyethanol 1300Amino resin Data not available Acute dermal/skin toxicityMay be harmful if in contact with skin

Substances Dermal LD50 (Rabbit),mg/kg


2001

Xylene 1700Azo pigment Data not availableDiacetone alcohol 135002-Methyl-1-propanol 34002-Butoxyethanol 2000Amino resin Data not available Acute inhalation toxicityVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract, may cause headaches and dizziness, could be anesthetic and may have othercentral nervous system effects.

Substances Inhalation Vapor LC50(Rat), mg/L/4hr


Data not available

Xylene 5000Azo pigment Data not availableDiacetone alcohol Data not available2-Methyl-1-propanol 80002-Butoxyethanol 4.9Amino resin Data not available

Skin corrosion or irritationCauses skin irritation. Frequent or prolonged contact may dry the skin, leading to discomfort anddermatitis. Serious eye damage or irritationMay be an eye irritant


Page 7 of 9

Respiratory or skin sensitisationVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract Germ cell mutagenicityNo information available on the product CarcinogenicityTitanium DioxideThe International Agency for Research on Cancer (IARC) has classified Titanium Dioxide aspossibly carcinogenic to humans (Group 2B) based on inadequate evidence of carcinogenicity inhumans and sufficient evidence of carcinogenicity in experimental animals







Page 8 of 9



LAND TRANSPORT




SEA TRANSPORT





Not applicable

AIR TRANSPORT










- This product is not subject to control under this Acts/Regulations.


Page 9 of 9

SCDF: Fire Safety Act & Fire Safety (Petroleum and Flammable Materials) Regulations- This product is subject to the requirement of this Acts/Regulations.

SPF: The Arms and Explosive Act, the Arms and Explosives (Explosives) Rules, and the Armsand Explosives (Explosive Precursors) Rules



Revision date: 27-Feb-2015


of 9

SAFETY DATA SHEET

Version No: 003


Product Name: HI-PON 40-04 BLACKIntended Use: Solvent-Based Protective PaintManufacturer: Nippon Paint (S) Co. Pte Ltd




GHS Classification:




GHS Pictogram

Signal WordDanger



HI-PON 40-04 BLACK

Page 2 of 9





3. COMPOSITION / INFORMATION ON INGREDIENTSSubstances CAS No. %Bisphenol-A type solid epoxy resin 25036-25-3 22.73-50.00Xylene 1330-20-7 14.96-32.91Diacetone alcohol 123-42-2 3.43-7.55Carbon black 1333-86-4 2.75-6.052-Methyl-1-propanol 78-83-1 2.29-5.032-Butoxyethanol 111-76-2 1.94-4.27Amino resin Not

available0.95-2.09


INHALATION

HI-PON 40-04 BLACK

Page 3 of 9


SKIN CONTACT


EYE CONTACT


INGESTION














HI-PON 40-04 BLACK

Page 4 of 9











Bisphenol-A type solid epoxy resin - - - -Xylene 100.00000 434 - -Diacetone alcohol - - - -Carbon black - 3.5 - 3.52-Methyl-1-propanol - - - -2-Butoxyethanol - - - -Amino resin - - - -



PERSONAL PROTECTION




HI-PON 40-04 BLACK

Page 5 of 9


9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : LiquidOdour : Aromatic hydrocarbon odourOdour threshold : Not availablepH : Not availableMelting point/freezing point : Not availableInitial boiling point and boiling range : Between 21.2 and 171 °CFlash point : 21 °CEvaporation rate : Not availableFlammability (solid, gas) : Not applicableLower flammability or explosive limit : 1.1 % by volUpper flammability or explosive limit : 13.1 % by volVapour pressure : Not availableVapour density : > 1.00 (Vapour is heavier than air)Relative density : Not availableSolubility : Not Miscible in waterPartition coefficient : Not availableAuto-ignition temperature : > 140 °CDecomposition temperature : Not availableViscosity : 75 - 79 KU


REACTIVITY


CHEMICAL STABILITY




CONDITIONS TO AVOID





There is no data available on the product itself.

HI-PON 40-04 BLACK

Page 6 of 9

Toxicological information of substances: Acute Oral toxicityHarmful if swallowed Substances Oral LD50(Rat), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 4300Diacetone alcohol 2520Carbon black 80002-Methyl-1-propanol 24602-Butoxyethanol 1300Amino resin Data not available Acute dermal/skin toxicityMay be harmful if in contact with skin Substances Dermal LD50 (Rabbit), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 1700Diacetone alcohol 13500Carbon black Data not available2-Methyl-1-propanol 34002-Butoxyethanol 2000Amino resin Data not available Acute inhalation toxicityVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract, may cause headaches and dizziness, could be anesthetic and may have othercentral nervous system effects. Substances Inhalation Vapor LC50 (Rat), mg/L/4hrBisphenol-A type solid epoxy resin Data not availableXylene 5000Diacetone alcohol Data not availableCarbon black Data not available2-Methyl-1-propanol 80002-Butoxyethanol Data not availableAmino resin Data not available

Skin corrosion or irritationCauses skin irritation. Frequent or prolonged contact may dry the skin, leading to discomfort anddermatitis. Serious eye damage or irritationMay be an eye irritant Respiratory or skin sensitisationVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract Germ cell mutagenicityNo information available on the product

HI-PON 40-04 BLACK

Page 7 of 9

CarcinogenicityNo information available on the product








LAND TRANSPORT

Classified as Dangerous Goods by the criteria of the European Agreement concerning theinternational carriage of Dangerous Goods (ADR) by Road & Regulations concerning theinternational carriage of Dangerous goods (RID) by Rail.UN Number: 1263

HI-PON 40-04 BLACK

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Proper shipping name: PAINT (including paint, lacquer, enamel , stain, shellac, varnish, polish,liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL(including paint thinning or reducing compound)


SEA TRANSPORT





Not applicable

AIR TRANSPORT














HI-PON 40-04 BLACK

Page 9 of 9



of 8

SAFETY DATA SHEET

Version No: 003


Product Name: HI-PON 40-04 CLEARIntended Use: Solvent-Based Protective PaintManufacturer: Nippon Paint (S) Co. Pte Ltd




GHS Classification:




GHS Pictogram

Signal WordWarning




HI-PON 40-04 CLEAR

Page 2 of 8






Substances CAS No. %Bisphenol-A type solid epoxy resin 25036-25-3 29-63Xylene 1330-20-7 10-222-Butoxyethanol 111-76-2 5-12Diacetone alcohol 123-42-2 5-12Substances determined to be non-hazardous - Balance

100%


INHALATION


SKIN CONTACT


EYE CONTACT

HI-PON 40-04 CLEAR

Page 3 of 8


INGESTION

















HI-PON 40-04 CLEAR

Page 4 of 8








Bisphenol-A type solid epoxy resin - - - -Xylene 100 434.00 - -2-Butoxyethanol - - - -Diacetone alcohol - - - -



PERSONAL PROTECTION






HI-PON 40-04 CLEAR

Page 5 of 8

Initial boiling point and boiling range : Between 137 and 143°CFlash point : 23 °CEvaporation rate : Not availableFlammability (solid, gas) : Not applicableLower flammability or explosive limit : 1.1 % by volUpper flammability or explosive limit : 11.2 % by volVapour pressure : Not availableVapour density : > 1.00 (Vapour is heavier than air)Relative density : Not availableSolubility : Not Miscible in waterPartition coefficient : Not availableAuto-ignition temperature : > 230 °CDecomposition temperature : Not availableViscosity : 72 - 78 KU


REACTIVITY


CHEMICAL STABILITY




CONDITIONS TO AVOID





There is no data available on the product itself.Toxicological information of substances: Acute oral toxicityHarmful if swallowed Substances Oral LD50(Rat), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 43002-Butoxyethanol 1300Diacetone alcohol 2520 Acute dermal/skin toxicityMay be harmful if in contact with skin

HI-PON 40-04 CLEAR

Page 6 of 8

Substances Dermal LD50 (Rabbit), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 17002-Butoxyethanol 2000Diacetone alcohol 13500 Acute inhalation toxicityVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract, may cause headaches and dizziness, could be anesthetic and may have othercentral nervous system effects. Substances Inhalation Vapor LC50 (Rat), mg/L/4hrBisphenol-A type solid epoxy resin Data not availableXylene 50002-Butoxyethanol Data not availableDiacetone alcohol Data not available

Skin corrosion or irritationCauses skin irritation. Frequent or prolonged contact may dry the skin, leading to discomfort anddermatitis. Serious eye damage or irritationMay be an eye irritant Respiratory or skin sensitisationVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract Germ cell mutagenicityNo information available on the product CarcinogenicityNo information available on the product



ToxicityAquatic toxicity -No data available Persistence and degradabilityBiodegradation -No data available Bioaccumulative potential

HI-PON 40-04 CLEAR

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No data available Mobility in soilNo data available Result of PBT and vPvB assessmentNo data available Other adverse effectsThere is no ecotoxicological test data available on the product itself.The product should not be allowed to enter drains or water courses.





LAND TRANSPORT




SEA TRANSPORT





Not applicable

AIR TRANSPORT

Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA)Dangerous Goods Regulations for transport by AirUN Number: 1263

HI-PON 40-04 CLEAR

Page 8 of 8















of 8

SAFETY DATA SHEET

Version No: 003


Product Name: HI-PON 40-04 HARDENERIntended Use: Hardener for PaintManufacturer: Nippon Paint (S) Co. Pte Ltd




GHS Classification:


Health HazardSkin corrosion/irritation Category 1Serious eye damage/irritation Category 1Skin sensitization Category 1Specific target organ toxicity:- Single exposure Category 3


GHS Pictogram

Signal WordDanger

Hazard statementsH226: Flammable liquid and vapourH314: Causes severe skin burns and eye damageH317: May cause an allergic skin reactionH318: Causes serious eye damageH335: May cause respiratory irritationH336: May cause drowsiness or dizziness


HI-PON 40-04 HARDENER

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Precautionary statementsP210: Keep away from heat/sparks/open flames/hot surfaces – No smokingP233: Keep container tightly closedP240: Ground/bond container and receiving equipmentP241: Use explosion-proof electrical/ventilating/light/equipmentP242: Use only non-sparking toolsP243: Take precautionary measures against static dischargeP260: Do not breathe dust/fume/gas/mist/vapours/sprayP261: Avoid breathing dust/fume/gas/mist/vapours/sprayP264: Wash hands thoroughly after handlingP271: Use only outdoors or in a well-ventilated areaP272: Contaminated work clothing should not be allowed out of the workplaceP280: Wear protective gloves/protective clothing/eye protection/face protection

ResponseP310: Immediately call a POISON CENTER or doctor/physicianP312: Call a POISON CENTER or doctor/physician if you feel unwellP321: Specific treatment (see Section 4 of SDS)P363: Wash contaminated clothing before reuseP302+352: IF ON SKIN: Wash with soap and waterP304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathingP333+313: If skin irritation or a rash occurs: Get medical advice/attentionP370+378: In case of fire: Use appropriate media for extinctionP301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomitingP303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.Rinse skin with water/showerP305+351+338: IF IN EYES: Rinse continuously with water for several minutes. Remove contactlenses if present and easy to do – continue rinsing

StorageP405: Store locked upP403+233: Store in a well ventilated place. Keep container tightly closedP403+235: Store in a well ventilated place. Keep cool



Substances CAS No. %1-Butanol 71-36-3 13-28Xylene 1330-20-7 13-28Diethylenetriamine 111-40-0 3-6Substances determined to be non-hazardous - Balance

100%


INHALATION

Move person to fresh air and call for medical assistance immediately.


Page 3 of 8

If not breathing, give artificial respiration, if breathing is difficult, give oxygen. Keep at rest.

SKIN CONTACT


EYE CONTACT


INGESTION
















Page 4 of 8










1-Butanol - - - -Xylene 100 434.00 - -Diethylenetriamine - - - -



PERSONAL PROTECTION





9. PHYSICAL AND CHEMICAL PROPERTIES


Page 5 of 8

Appearance : LiquidOdour : Aromatic hydrocarbon odourOdour threshold : Not availablepH : Not availableMelting point/freezing point : Not availableInitial boiling point and boiling range : Between 117 and 199 °CFlash point : 23 °CEvaporation rate : Not availableFlammability (solid, gas) : Not applicableLower flammability or explosive limit : 1.1 % by volUpper flammability or explosive limit : 11.2 % by volVapour pressure : Not availableVapour density : > 1.00 (Vapour is heavier than air)Relative density : Not availableSolubility : Not Miscible in waterPartition coefficient : Not availableAuto-ignition temperature : > 527 °CDecomposition temperature : Not availableViscosity : Not available


REACTIVITY


CHEMICAL STABILITY




CONDITIONS TO AVOID





There is no data available on the product itself.Toxicological information of substances: Acute oral toxicityHarmful if swallowed Substances Oral LD50(Rat), mg/kg1-Butanol 790


Page 6 of 8

Substances Oral LD50(Rat), mg/kgXylene 4300Diethylenetriamine Data not available Acute dermal/skin toxicityMay be harmful if in contact with skin Substances Dermal LD50 (Rabbit), mg/kg1-Butanol 3400Xylene 1700Diethylenetriamine Data not available Acute inhalation toxicityVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract, may cause headaches and dizziness, could be anesthetic and may have othercentral nervous system effects. Substances Inhalation Vapor LC50 (Rat), mg/L/4hr1-Butanol 8000Xylene 5000Diethylenetriamine Data not available

Skin corrosion or irritationCauses skin irritation. Frequent or prolonged contact may dry the skin, leading to discomfort anddermatitis. Serious eye damage or irritationMay be an eye irritant Respiratory or skin sensitisationVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract Germ cell mutagenicityNo information available on the product CarcinogenicityNo information available on the product





Page 7 of 8






LAND TRANSPORT




SEA TRANSPORT





Not applicable

AIR TRANSPORT


Page 8 of 8
















of 9

SAFETY DATA SHEET

Version No: 003


Product Name: HI-PON 40-04 WHITEIntended Use: Solvent-Based Protective PaintManufacturer: Nippon Paint (S) Co. Pte Ltd




GHS Classification:




GHS Pictogram

Signal WordDanger



HI-PON 40-04 WHITE

Page 2 of 9






Substances CAS No. %Bisphenol-A type solid epoxy resin 25036-25-3 19-41Xylene 1330-20-7 7-162-Butoxyethanol 111-76-2 4-10Diacetone alcohol 123-42-2 4-10Substances determined to be non-hazardous - Balance

100%


INHALATION

HI-PON 40-04 WHITE

Page 3 of 9


SKIN CONTACT


EYE CONTACT


INGESTION














HI-PON 40-04 WHITE

Page 4 of 9











Bisphenol-A type solid epoxy resin - - - -Xylene 100 434.00 - -2-Butoxyethanol - - - -Diacetone alcohol - - - -



PERSONAL PROTECTION





HI-PON 40-04 WHITE

Page 5 of 9



REACTIVITY


CHEMICAL STABILITY




CONDITIONS TO AVOID






HI-PON 40-04 WHITE

Page 6 of 9

Substances Oral LD50(Rat), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 43002-Butoxyethanol 1300Diacetone alcohol 2520 Acute dermal/skin toxicityMay be harmful if in contact with skin Substances Dermal LD50 (Rabbit), mg/kgBisphenol-A type solid epoxy resin 2001Xylene 17002-Butoxyethanol 2000Diacetone alcohol 13500 Acute inhalation toxicityVapour concentrations above the recommended exposure levels may be irritating to the eyes andthe respiratory tract, may cause headaches and dizziness, could be anesthetic and may have othercentral nervous system effects. Substances Inhalation Vapor LC50 (Rat), mg/L/4hrBisphenol-A type solid epoxy resin Data not availableXylene 50002-Butoxyethanol Data not availableDiacetone alcohol Data not available



HI-PON 40-04 WHITE

Page 7 of 9








LAND TRANSPORT




SEA TRANSPORT


HI-PON 40-04 WHITE

Page 8 of 9




Not applicable

AIR TRANSPORT
















HI-PON 40-04 WHITE

Page 9 of 9


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