safety data sheeting).pdf · supplier company : dyteks boya ve kimya san. ve tic. ltd. Şti....

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SAFETY DATA SHEET DYDIRECT YELLOW RL

(R.G.13/12/2014- 29204) on the Safety Data Sheets for Hazardous Substances and Mixtures.

Preparation Date: 13.04.2018

New Regulation Date / Revision No:02

SDS No : GBF01.12.08 Form No : DR326

Authorized Name/Surname: MERVE ATMACA

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/DISTRIBUTOR

1.1 Identification of the substance/mixture

Trade Name : DYDIRECT YELLOW RL Area of use : Organic dye for industrial use.

1.2 Identified uses and non-recommended uses of substance or mixture

Attention: Avoid contact with food.

1.3 Details of the supplier of the safety data sheet Company

Supplier Company : Dyteks Boya ve Kimya San. Ve Tic. Ltd. Şti.

Telephone : +90(212) 438 75 18

Fax : +90(212) 438 75 19

Address : İkitelli OSB. Çevre Sanayi Sitesi 10.Blok No : 36 İkitelli / İstanbul .

E-mail : [email protected]

1.4 Emergency telephone number

National Poison Information Center Telephone : 114

For company emergency telephone : +90 532 236 94 44

2. HAZARD IDENTIFICATION

2.1 Classification of the substance or mixture.

Have not been classified as harmful according to '' Regulation on Safety Data Sheets for Hazardous Substances and Mixtures '' (R.G.13 / 12 / 2014-29204). 2.2 Label Elements

Labelling (28848 T.C)

Danger Sign GHS07 Warning Word

Attention

mailto:[email protected]

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2.3 Other Hazards.

None.

PHYSICAL / CHEMICAL HAZARDS: - HEALTH HAZARDS: May cause sensitization by skin contact or inhalation. May cause itching on skin and eye. Repeated exposure may cause skin dryness or cracking. Avoid contact with eyes, skin and hands, inhalation of its dust.

ENVIRONMENTAL HAZARDS: Avoid giving installed amount to the environment.

3.COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Description: Mixture.

Phrases of Harmfulness H302+H312 Harmful if swallowed or in contact with skin. H319 Serious eye irritation.

Phrases of Precaution Precaution– Intervention – Extermination P264 Wash thoroughly after handling. P280 Wear protective gloves / protective clothing /

eye protection. P302+P352 IF CONTACT WITH LEATHER: Wash with plenty

of soap and water. P305 + P351 + P338 IF CONTACT WITH EYE: Rinse carefully with

water for a few minutes. If it is put in and easy to do, remove contact lenses and continue rinsing.

P337+P313 If eye irritation is persistent, get medical help/care.

P312 If you don’t feel well, Call 114 NATIONAL POISON CENTER or doctor / physician at the NATIONAL POISON ADVISORY CENTER.

P501 Dispose of contents / container in accordance with international regulations.

Ingredients; Component 1, Sodium Sulphate

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3.2. Contained Substances:

CONTAINED CHEMICAL

SUBSTANCE NAMES

EINECS NO

CAS NO

%

Concentration

SEA

Class ,

H statements*

COMPONENT 1

COMMERCIAL SECRET

%60-70

--

SODIUM SULPHATE 231-820-9

7757-82-6

%4

--

*H full disclosure of the phrases is given in Chapter 16.

4.FIRST AID MEASURES 4.1 Description of first aid measures

IN CASE OF INHALATION

Go out for fresh air. In case of respiratory difficulties, consult a doctor.

IN CASE OF SKIN CONTACT

Wash contact areas with soap and water for at least 15 minutes. Remove contaminated clothes.

In the event of such a complication consult your doctor.

IN CASE OF EYES CONTACT

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

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IN CASE OF INGESTION

If swallowed, seek medical advice immediately. Rinse mouth thoroughly with water. Do not try

to vomit. If symptoms persist, seek medical advice.

4.2 Rapid and Delayed Significant Signs and Effects

No information available.

4.3 First signs for medical intervention and special treatment

No specific treatment was offered. Treat according to symptoms.

5. FIREFIGHTING MEASURES

5.1 Fire Extinguisher

Suitable extinguishing media: To extinguish fire; use dry chemical substances (DCP: Dry Chemical Powder), water and foam.

Incompatible Extinguishing Media: Carbon dioxide (CO2) and full water jet.

5.2 Special hazards arising from the substance or mixture

Harmful Combustion Products: In case of burning; carbon, sulfur and oxides of nitrogen can be formed.

5.3 Advice for firefighters

FIRE EXTINGUISHING

Firefighting Instructions: Cool the packages at the fire place with water and take the personnel to a safe area. Avoid contaminating the environment by overusing a fire extinguisher. Fire fighting residues must not be allowed to reach sewage and groundwater.

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Unusual Fire Hazards: Firefighters must use the protective equipment described in Section 8.

6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures

WARNING METHODS: In case of insufficient ventilation, wear suitable respiratory equipment. See section 8 for personal protection.

PROTECTIVE MEASURES: See Section 5 for information on fire fighting. For hazards see section "Hazard identification". See Section 4 for Recommendations on First Aid. In case of contact with eyes, it is recommended to wear suitable glasses. 6.2 Environmental Precautions

Large Spills: Draw a set away from the spill. Keep out of reach of water channels, sewers, basements or enclosures. Prevent spread to the environment.

6.3 Environmental Precautions

SPILTH/SPILLAGE MANAGEMENT

Spilling to Soil : Dispose of the mixed material according to Article 13. Do not walk over the spilled material. Keep out of reach of water channels, sewers, basements or enclosures.

Spilling to Water: If there is no risk for you, stop the leak.

6.4 Other Sections See Section 8 for personal protection. See Section 11 for additional information on health hazards. See Section 13 for waste disposal.

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7.HANDLING AND STORAGE

7.1 Precautions for safe handling Try not to spill, avoid contact with skin and eyes. 7.2 Conditions for Safe Storage, including any incompatibilities

Protect from sources of ignition - do not smoke. Store tightly closed in original packaging and in a dry and cool place. Store in original container. Containers should be completely covered. Prevent dust accumulation. Protect from temperatures of 60 ° C or higher. Keep the storage temperature in a cool place in the sealed container between 5-35°C.

7.3 Specific End Uses: None.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Control Parameters Exposure Limits / Standards There are no current occupational exposure limit values for product components. Note: Information about the recommended monitoring procedures can be obtained from the institution (s) concerned: Ministry of Labor and Social Security, General Directorate of Occupational Health and Safety - İSGÜM.

8.2 Exposure Controls

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8.2.1 Personal Protective Equipment Information on the selection of protective equipment that can be used with this substance, as

defined below, is intended for normal use conditions.

Protection of the respiratory system: Avoid breathing product. Half face mask or full face mask can be used. In all cases where a breathing apparatus must be used at the workplace, the Respiratory Protection Program must be followed to comply with OSHA 1910.134 and ANSI Z88.2 balanced practices. Also; Half-face filter respirator; Type A filter material, EN 136, 140 and 405 respiratory masks from the European Standards Committee (CEN) standards; It gives recommendations on EN 149 and 143 filters.

Protection of hands: All specific information regarding the use of gloves is based on published literature and glove manufacturer data. Depending on the specific use conditions, glove suitability and the permeability time differs. For glove selection and permeability time appropriate to the conditions of use, contact the manufacturer of gloves to inform them. Examine gloves and replace worn or damaged gloves with new ones. The use of chemical resistant gloves is recommended.

Eye Protection: Use safety glasses with side shields. Skin and Body Protection: Wear clothing that will prevent any contact with skin. Special Hygiene Precautions: Always make sure that appropriate personal hygiene measures are taken after handling the substance and washing hands before eating, drinking and / or smoking. Wash work clothing and protective equipment regularly to remove contaminants. Carry out hygiene measures that must be observed at work. ENVIRONMENTAL CONTROLS Follow the necessary regulations that limit the discharge to the ground, air and water. Protect the environment by using the necessary control mechanisms to prevent or minimize emissions.

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9.PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Physical State Powder

Color Dark Yellow

Odor Odorless

pH (10g/l H2O) 8 – 9 (20°C ) Flash Point N/A Explosion Limit N/A Density (20°C ) N/A

Viscosity N/A

Solubility 30 g/L ( 70°C in water)

Melting Point 150°C

9.2 Other Informations: None

10.STABILITY AND REACTIVITY 10.1.Reactivity

It does not react under normal conditions. 10.2.Chemical Stability Stable under normal conditions.

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10.3.Possibility of hazardous reactions. Under normal conditions do not give harmful reaction. However; Keep away from strong oxidants. 10.4.Conditions to Avoid Keep away from sunlight, strong oxidants, temperature and humidity.

10.5.Items to Avoid Strong oxidizing agents (nitrogen oxides, sulfur oxides), carbon monoxide, carbon dioxide. Oxidation and reduction agents.

10.6.Hazardous Decomposition Products

This material does not degrade at ambient temperature. If exposed to fire; burning may cause producing of carbon, nitrogen and sulfur, chromium oxides.

11.TOXICOLOGICAL INFORMATION 11.1.Information on Toxic Effects

ACUTE TOXICITY

Structurally similar substances are based on test data.

Acute oral toxicity: LD50 >2000 mg/kg (Rat)

Acute dermal toxicity: LD50 > 2000 mg/kg (Rat)

Skin Irritation (Tested in rabbits) Irritant. Eye Irritation (Tested in rabbits) Irritant.

Cancinogenicity: No data.

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CHRONIC/ OTHER EFFECTS: None.

12.ECOLOGICAL INFORMATION

12.1.Toxicity / Ecotoxicity

The information given is based on the knowledge of the components and the ecotoxicology of similar products. Unless otherwise stated, the data given is representative of the product as a whole, rather than the individual component (s).

LC, 96 hours, fishes (mg / l):> 100 EC, 48 hours, crustaceans (mg / l):> 100 IC, 72 saat, algae (mg / l): N / A Biochemical Oxygen Demand (BOD): 2mg / l (100ppm - Standby time 5 days) Absorbable organic bound halogens (AOX): 3.86%

12.2.Persistence and degradability Biodegradation and Elimination: 10-20% Chemical Oxygen Demand (COD): 86mg / l (100ppm)

12.3 Bioaccumulative potential Undetermined. 12.4 Mobility in Soil Not available.

12.5 Results of PBT and PvB evaluation

The product is not classified as PBT or vPvB.

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12.6 Other adverse effects

None.

13.DISPOSAL INFORMATION

Disposal considerations shall be based on the material provided. Disposal must be carried out in accordance with the laws and regulations already in force and the properties of the substance at the time of disposal.

Additional Information: Used packaging must be disposed of as chemical waste after it is completely emptied.

13.1. Waste Processing Methods and Disposal Methods

Do not drain into sewers. Dispose of waste according to national regulations. Dispose of waste packaging in accordance with national regulations.

14.TRANSPORT INFORMATION ROAD (ADR/RID): No special transport requirements. INLAND WATER WAYS (ADNR/ADN): No special transport requirements. SEA (IMDG): No special transport requirements. AIR (IATA): No special transport requirements.

14.1 UN Number : N/A 14.2 Proper Shipping Name: N/A 14.3 Transport hazard class (es): N/A

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14.4 Packing Group: N/A 14.5 Environmental Hazards: Avoid giving to the environment. 14.6 Special Precautions for user: Avoid respiratory, skin and eye contact.

14.7 Castings according to Annex II of MARPOL 73/78 and the IBC Code Transport: Not applicable.

15.REGULATORY INFORMATION 15.1. Matter and Matter Specificity Safety, Health and Environment Legislation

REGULATION ON HEALTH AND SAFETY IN WORKING WITH CHEMICAL COMPOUNDS.

REGULATION ON CONTROL OF LARGE INDUSTRIAL ACCIDENTS.

16. OTHER INFORMATIONS

Revision Changes: Hazardous ingredients and mixture conditions have been revised according to the Regulation on Safety Data Sheets (R.G. 13/12 / 2014-29204).

Abbreviations:

CAS - Chemical Theory Service

EC numbers - EINECS (European Inventory of Existing Commercial Chemical Substances),

ELINCS (List of Notified Chemical Substances) or NLP (Residual Non-Polymeric Substance)

LD50 - lethal dose, 50%

LC50 - lethal concentration, 50%

EC50 - effective concentration, 50%

IC50 - inhibitor concentration, 50%

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PBT - persistent, bioaccumulative and toxic,

vPvB - very persistent and very bioaccumulative

BCF - bioconcentration factor

COD - chemical oxygen demand BOD - biochemical oxygen demand

ADR - European Agreement on International Carriage of Dangerous Goods by Road

RID - Regulations on International Carriage of Dangerous Goods by Rail

IMDG - International Maritime Dangerous Goods Code

IATA - International Air Transport Association

Reference Sources: Regulations

Revision Change: 1.2 Information of the Safety Data Sheet Supplier has been revised.

All of the Hazard Statements:

H302+H312 Harmful if swallowed or in contact with skin.

H319 Serious eye irritation.

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Authorized Name/Surname: MERVE ATMACA All of the Precautionary statements:

Preparing SDS

Name-Surname : Merve ATMACA

Address: İSTANBUL

Qualification Certificate Date : 20.01.2018

Certificate Number : GBF01.12.08

The information in this SDS is based on reliable sources. However, no warranty is given for the accuracy of this information. The handling, storage or disposal conditions may be outside of our control or our knowledge. For this and other reasons, we do not take any responsibility in case of any damage, loss or expense according to handling, storage, use or disposal.

This GBF is intended for this product and should only be used for this product. If the product is used as a component in another application, the information herein may not be applicable.

This Safety Data Sheet was prepared based on the manufacturer's information.

Phrases of Precaution Precaution– Intervention – Extermination P264 Wash thoroughly after handling.

P280 Wear protective gloves / protective clothing / eye protection.

P302+P352 IF CONTACT WITH LEATHER: Wash with plenty of soap and water.

P305 + P351 + P338 IF CONTACT WITH EYE: Rinse carefully with water for a few minutes. If it is put in and easy to do, remove contact lenses and continue rinsing.

P337+P313 If eye irritation is persistent. Get medical help/care.

P312 If you don’t feel well, Call 114 NATIONAL POISON CENTER or doctor / physician at the NATIONAL POISON ADVISORY CENTER.

P501 Dispose of contents / container in accordance with international regulations.

safety data sheeting).pdf · supplier company : dyteks boya ve kimya san. ve tic. ltd. Şti....

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