safety data sheets · 2014-03-03 · company telephone telefax : chemetall ltd denbigh road...

APPENDIX 1 Safety Data Sheets

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;AFETY DATA SHEET ccording to Regulation (EC) No. 1907/2006

;ardacid P 4309 Revision Date 17.05.201 1 Print Date 31.05.201 1 ersion 3.0

. Identification of the substancelmixture and of the companylundertaking

.I Product identifier

Trade name : Gardacid P 4309

.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Sub- StancelMixture Recommended restrictions : None known. on use

: Acid pickling agent for metal surfaces.

.3 Details of the supplier of the safety data sheet

Company

Telephone Telefax

: Chemetall Ltd Denbigh Road Bletchley Milton Keynes MKI 1 PB

: 01908 649333 : 01908 373939

Contact person product safety Telephone : +49(0)6971652292 E-mail address : [email protected]

.4 Emergency telephone number

Emergency telephone : 01908 649333 number

I. Hazards identification

'.I Classification of the substance or mixture

Classification (REGULATION (EC) No 127212008)

I Skin corrosion, Category 1A H314: Causes severe skin burns and eye damage.

Classification (67/548/EEC, 1999/45/EC)

Corrosive R35: Causes severe burns.

1.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms

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mailto:[email protected]

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jAFETY DATA SHEET ccording to Regulation (EC) No. 190712006

Sardacid P 4309 'ersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 1

Signal word

iazard statements

'recautionary statements

Danger

H314 Causes severe skin burns and eye damage.

Prevention: P262 P280

Response: P301 + P330 + P331

P303 + P361 + P353

Do not get in eyes, on skin, or on clothing. Wear protective gloves1 protective clothing1 eye protection1 face protection.

IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water1 shower.

P305 + P35

P312

Disposal: P501

+ P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor1 physician if you feel unwell.

Dispose of contents1 container to an ap- proved waste disposal plant.

iazardous components which must be listed on the label: 7664-93-9 Sulphuric acid

Additional Labelling:

EUH208 Contains: DiethylthioureaMay produce an allergic reaction.

Labelling according to EC Directives (1999/45/EC)

Hazard pictograms

Corrosive

R-phrase( s) : R35 Causes severe burns.

S-phrase(s) : s24125 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immedi-

ately with plenty of water and seek medical advice. Never add water to this product. Wear suitable protective clothing, gloves and eyelface protection.

S30 S36137139

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SAFETY DATA SHEET iccording to Regulation (EC) No. 190712006

231 -639-5

105-55-5 203-308-5

Sardacid P 4309

Nota B

Xn; Carc.Cat.3; R40

Xn; R22

Xi; R37-R41

R43

/ersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 1

s45

S60

In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste.

Hazardous components which must be listed on the label: 7664-93-9 Sulphuric acid

Special labelling of certain mixtures detergents:

: Ingredients according to Regulation (EC) No.648/2004 on

Sensitising components : Diethylthiourea May produce an allergic reaction.

!.3 Other hazards

The information required is contained in this Material Safety Data Sheet.

1. Compositionlinformation on ingredients

1.1 Substances

1.2 Mixtures Identification: Gardacid P 4309

Chemical nature : Aqueous solution inorganic acids

Hazardous components

Chemical Name

Sulphuric acid

Diethylthiourea

EC-NO. (67/548/EEC) Registration num-

ber I 7664-93-9 I C: R35

Classification (REG U LATl ON

(EC) No

H314

~

Care. 2; H351

Acute Tox. 4; H302

STOT SE 3; H335

Eye Dam. 1; H318

Concentration [%I

>= 65 - < 80

>= 0.1 - < 1

3 / 1 3 .--- - EN

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SAFETY DATA SHEET iccording to Regulation (EC) No. 1907/2006

Sardacid P 4309 /ersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 1

Skin Sens. 1; H317

For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. For the full text of the Notas mentioned in this Section, see Section 16.

1. First aid measures

1.1 Description of first aid measures

General advice

If inhaled

: Take off contaminated clothing and shoes immediately. First-aid crew: Ensure self-protection. Move out of dangerous area.

Move to fresh air. If symptoms persist, call a physician.

In case of skin contact : Wash off immediately with plenty of water for at least 15 min- Utes. Call a physician immediately.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately.

If swallowed : Rinse mouth with water. Immediately give large quantities of water to drink. Do NOT induce vomiting. Call a physician immediately.

1.2 Most important symptoms and effects, both acute and delayed

Symptoms : Erythema Blistering Pain

Risks : corrosive effects

1.3 Indication of any immediate medical attention and special treatment needed

Treatment : Treat symptomatically. For specialist advice physicians should contact the Poisons Information Service.

5. Fire-fighting measures

5.1 Extinguishing media

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EPA Export 03-03-2014:23:31:02

AFETY DATA SHEET :cording to Regulation (EC) No. 1907/2006

iardacid P 4309 m i o n 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 1

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing : High volume water jet media

Specific hazards during fire fighting

Special protective equipment for fire-fighters Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

2 Special hazards arising from the substance or mixture

: May form toxic gases on heating or in case of fire.

3 Advice for firefighters

: In the event of fire, wear self-contained breathing apparatus.

, Accidental release measures

1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Ensure adequate ventilation. Wear personal protective equipment. Evacuate personnel to safe areas.

2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.

3 Methods and materials for containment and cleaning up

Methods for cleaning up : Ensure adequate ventilation. Soak up with liquid binder (sand, kieselguhr, acid binder, universal binder). Sweep up and shovel into suitable containers for disposal.

4 Reference to other sections

See chapter 8 and 13

Handling and storage

1 Precautions for safe handling

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms. Have eye wash bottle or eye rinse ready at the work place. Avoid contact with skin and eyes. When diluting, always add the product to water. Never add water to the product.

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according to Regulation (EC) No. 1907/2006

(Gardacid P 4309 IVersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 1

Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Store at room temperature in the original container. Keep container tightly closed in a dry and well-ventilated place.

Further information on stor- : Avoid contact with metals. age conditions

7.3 Specific end uses

Specific use(s) : Acid pickling agent for metal surfaces.

8. Exposure controlslpersonal protection

8.1 Control parameters

Basis Components CAS-No. Value Update Control parameters

Sulphuric 7664-93-9 TWA 0.05 mgIrn3 2009-12-19 2009/161/EU acid

Further information

: (8): When selecting an appropriate exposure monitoring method, account should be taken of potential limitations and interferences that may arise in the presence of other sulphur com- pounds. Indicative

8.2 Exposure controls

Engineering measures

Ensure adequate ventilation, especially in confined areas.

Personal protective equipment

Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Recommended Filter type: B-P2

Hand protection Viton (R) Protective gloves complying with EN 374. The exact break through time can be obtained from the protective glove producer and this has to be observed. Protective gloves have to be replaced at the first sign of deterioration.

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iAFETY DATA SHEET :cording to Regulation (EC) No. 1907/2006

iardacid P 4309 ersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 '

Eye protection : Tightly fitting safety goggles Eye protection (EN 166)

Skin and body protection : Chemical resistant protective clothing according to DIN EN 13034 (Type 6)

Hygiene measures Do not breathe spray. Take off contaminated clothing and shoes immediately. Avoid contact with the skin and the eyes. Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and immediately after handling the product .

Protective measures : Handle in accordance with good industrial hygiene and safety practice. Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower.

Environmental exposure controls

General advice : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.

1. Physical and chemical properties

.I Information on basic physical and chemical properties

Appearance : liquid

Colour : light yellow to beige

Odour : stinging

Flash point : not applicable

Ignition temperature : not applicable

Autoignition temperature : not applicable

PH < 2 at 20 "C (undiluted)

Solidification tempera- : <-14°C turehange

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SAFETY DATA SHEET according to Regulation (EC) No. I90712006

(Gardacid P 4309 IVersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 1

Boiling point/boiling range : no data available

Vapour pressure : no data available

Density : 1.66 - 1.7 gkm3 at 20 "C Method: DIN 51757

Water solubility : completely miscible

Flow time ca.20 s at 23 "C 4 mm Method: IS0 2431

9.2 Other information

Explosivity : no explosion risk

10. Stability and reactivity

10.1 Reactivity

Potential for exothermic hazard, Reacts violently with water.

10.2 Chemical stability

10.3 Possibility of hazardous reactions Stable under recommended storage conditions.

Hazardous reactions : Gives off hydrogen by reaction with metals.

10.4 Conditions to avoid

Conditions to avoid : To avoid thermal decomposition, do not overheat.

10.5 Incompatible materials

Materials to avoid : When diluting, always add the acid to the water, never the other way round. Incompatible with bases. Organic materials

10.6 Hazardous decomposition products

Risk of decomposition. : No decomposition if used as directed.

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3ardacid P 4309 fersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 1

1. Toxicological information

1 .I Information on toxicological effects

Acute toxicity

Acute oral toxicity : LD50: 2,150 mg/kg Species: rat CAS NO. 7664-93-9

Acute oral toxicity Sulphuric acid LD50: 2,140 mg/kg

Species: rat

Diethylthiourea : LD50: 316.0 mglkg Species: rat

Skin corrosionlirritation

Skin irritation : Causes severe burns.

Serious eye damageleye irritation

Eye irritation : Causes serious eye damage.

Respiratory or skin sensitization

Sensitisation : Contains one or more substance(s) classified as sensitising.

Human experience : If swallowed, severe burns in the oral cavity and throat as well as danger of perforation of the digestive tract and stomach.

2. Ecological information

2.1 Toxicity

Toxicity to fish

Toxicity to fish Sulphuric acid

no data available

: LC50: 42 mg/l

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SAFETY DATA SHEET according to Regulation (EC) No. 190712006

Sardacid P 4309 Jersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 1

Exposure time: 96 h Species: Gambusia affinis (Mosquito fish)

LC50: 82 mg/l Exposure time: 24 h Species: Danio rerio (zebra fish)

12.2 Persistence and degradability

Biodegradability : no data available

12.3 Bioaccumulative potential

Bioaccumulation

12.4 Mobility in soil

: no data available

Mobility : no data available

12.5 Results of PBT and VPVB assessment

no data available

12.6 Other adverse effects

Additional ecological informa- : slightly water endangering tion

: Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.

13. Disposal considerations

13.1 Waste treatment methods

Product : Dispose of as hazardous waste in compliance with local and national regulations.

Contaminated packaging : Dispose of as hazardous waste in compliance with local and national regulations.

Waste Code Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

14. Transport information

ADR

10 I 1 3 - Er

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3ardacid P 4309 lersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 ’

UN number UN proper shipping name Transport hazard class(es) Packing group Classification Code Hazard identification No Packing instruction (LQ) Labels Tunnel restriction code Environmentally hazardous

IATA UN number Description of the goods Class Packing group Labels

Packing instruction (cargo aircraft) IATA-C Environmentally hazardous

Packing instruction (passen- ger aircraft) IATA-P Environmentally hazardous

IMDG UN number Description of the goods Class Packing group Labels Ems Number 1 Ems Number 2 Marine pollutant

RID UN number Description of the goods Transport hazard class(es) Packing group Classification Code Hazard identification No Labels Environmentally hazardous

: 1830 : SULPHURIC ACID with more than 51% acid : 8 : II : c1 : 80 : LQ22 : 8 : (E), : no

: 1830 : SULPHURIC ACID with more than 51% acid : 8 : II : 8

: 855

: no

: 851

no

1830 SULPHURIC ACID with more than 51% acid 8 II 8 F-A S-B no

1830 SULPHURIC ACID with more than 51% acid 8 II 1 80 8 no

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3ardacid P 4309 fersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 ’

15. Regulatory information

15.1 Safety, health and environmental regulationsllegislation specific for the substance or mixture

Water contaminating class : WGK 1 slightly water endangering (Germany) WVVWS A4

Other regulations The product is classified and labelled in accordance with EC directives or respective national laws. Regional or national implementations of GHS may not imple- ment all hazard classes and categories.

15.2 Chemical Safety Assessment A Chemical Safety Assessment is not required for this substance.

16. Other information

Full text of R-phrases referred to under sections 2 and 3

R22 R35 R37 R40 R4 1 R43

Harmful if swallowed. Causes severe burns. Irritating to respiratory system. Limited evidence of a carcinogenic effect. Risk of serious damage to eyes. May cause sensitization by skin contact.

Full text of H-Statements referred to under sections 2 and 3.

H302 H314 H317 H318 H335 H351

Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Causes serious eye damage. May cause respiratory irritation. Suspected of causing cancer.

Full text of Notas referred to under section 3

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;ardacid P 4309 ‘ersion 3.0 Revision Date 17.05.201 1 Print Date 31.05.201 1

Nota B Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solutions require different labelling since the hazards vary at different concentrations. In Annex I entries with Note B have a general designation of the following type: nitric acid .... %. In this case the manufacturer or any other person who markets such a substance in aqueous solution must state the percentage concentration of the solution on the label. Example: nitric acid 45 %. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weighvweight basis. The use of additional data (e.g. specific gravity, degrees Baume) or descriptive phrases (e.g. fuming or glacial) is permissible.

Further information

The information provided is based on our current knowledge and experience and apply to the producl as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety datasheet does not free the recipient of the product from his own responsibility to follow the relevant rules and regulations concerning this product.

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;ardobond R 2600 A ‘ersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

. Identification of the substancelmixture and of the companylundertaking

.I Product identifier

Trade name : Gardobond R 2600 A

.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Sub- : Phosphating solution for metal surfaces. stance/Mixture Recommended restrictions : None known. on use

.3 Details of the supplier of the safety data sheet

Company : Chemetall Ltd Denbigh Road Bletchley Milton Keynes MKI 1 PB

Lead Organisation Contact person Telephone : 01908 649333 Telefax : 01908 373939

Product safety Telephone E-mail address

: +49(0)6971652292 : [email protected]

.4 Emergency telephone number

Emergency telephone : 01908 649333 number

I. Hazards identification

.I Classification of the substance or mixture

Classification (67/548/EEC, 19991451EC)

Carcinogenic Category 1 toxic

Toxic to Reproduction Category 2 Corrosive R34: Causes burns. Mutagenic Category 3 Sensitising

Dangerous for the environment

R49: May cause cancer by inhalation. R48/23: Toxic: danger of serious damage to health by prolonged exposure through inhalation. R61: May cause harm to the unborn child.

R68: Possible risk of irreversible effects. R42/43: May cause sensitization by inhalation and skin contact. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environ-

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;ardobond R 2600 A Revision Date 20.10.201 0 Print Date 03.02.201 1 'ersion 6.0

ment.

.2 Label elements

Labelling according to EC Directives (19991451EC)

Hazard pictograms

Toxic Dangerous for the environment

R-phrase( s)

S-phrase( s)

: R49 R61 R48/23

R34 R68 R42/43

R51/53

: s53

S23 s24/25 S26

S36/37/39

s45

S60

S61

May cause cancer by inhalation. May cause harm to the unborn child. Also toxic: danger of serious damage to health by prolonged exposure through inhalation. Causes burns. Possible risk of irreversible effects. May cause sensitization by inhalation and skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Avoid exposure - obtain special instructions before use. Do not breathe spray. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eyelface protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ Safety data sheets.

Hazardous components which must be listed on the label: 0 13138-45-9 Nickel(l1) nitrate

Special labelling of certain : Restricted to professional users. mixtures

!.3 Other hazards 2 / 2 6 --

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SAFETY DATA SHEET xcording to Regulation (EC) No. 1907/2006

Gardobond R 2600 A dersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

The information required is contained in this Material Safety Data Sheet.

3. Compositionlinformation on ingredients

3.1 Substances

3.2 Mixtures Identification: Gardobond R 2600 A

Chemical nature : Aqueous solution of inorganic salts.


Chemical Name

Zinc bis (dihydrogen Dhosphate)

3rthophosphoric acid

Vickel(l1) nitrate

CAS-NO. EC-NO.

Registration number

13598-37-3 237-067-2 01-21 19485974- 19-0000 01-21 19485974- 19-0001 01 -21 19485974- 19-0002 01-21 19485974- 19-0003

7664-38-2 231 -633-2

1 31 38-45-9 236-068-5

Classification (67/548/E EC)

Xn; R22

N; R50

C; R34

Nota B

0; R 8

Carc.Cat.1; R49

Repr.Cat.2; R61

Mut.Cat.3; R68

T; R48/23

Xn; R20122

Xi; R38-R41

R42/43

N; R50-R53

Classification (REGULATION

(EC) No 1272/2008)

Aquatic Acute 1; H400

Acute Tox. 4; H302

Skin Corr. IB ; H314

ox. Sol. 2; H272

Carc. IA ; H350i

Muta. 2; H341

Repr. IB ; H360D

STOT RE 1; H372

Acute Tox. 4; H332

Acute Tox. 4; H302

Concentration ["/I

>= 2.5 - 10

> = 5 - < 1 0

> = 5 - < 1 0

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SAFETY DATA SHEET iccording to Regulation (EC) No. I90712006

Sardobond R 2600 A lersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

Io ta E Skin Irrit. 2; H315

Eye Dam. 1; H318

Resp. Sens. 1; H334

Skin Sens. 1; H317

Aquatic Acute 1; H400

Aquatic Chronic 1; H410

WEL substance : Manganese 1871 8-07-5 Not a hazard- >= 2.5 - < 10 bis(dihydrogen phos- 242-520-2 ous substance phate) or mixture ac-

cording to Regulation (EC) No. 127212008.

For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. For the full text of the Notas mentioned in this Section, see Section 16.

1. First aid measures

..1 Description of first aid measures

General advice Take off contaminated clothing and shoes immediately. First-aid crew: Ensure self-protection. Move out of dangerous area.

If inhaled Move to fresh air. If symptoms persist, call a physician.

In case of skin contact : Wash off immediately with plenty of water for at least 15 min- Utes. Call a physician immediately.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately.

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jAFETY DATA SHEET ccording to Regulation (EC) No. 190712006

3ardobond R 2600 A ‘ersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 ’

If swallowed Rinse mouth with water. Immediately give large quantities of water to drink. Do NOT induce vomiting. Call a physician immediately.

..2 Most important symptoms and effects, both acute and delayed

Symptoms : Erythema Blistering Pain

Risks : corrosive effects

..3 Indication of any immediate medical attention and special treatment needed

Treatment : Treat symptomatically. For specialist advice physicians should contact the Poisons Information Service.

i. Fire-fighting measures

i.1 Extinguishing media

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing : High volume water jet media

i.2 Special hazards arising from the substance or mixture

Specific hazards during fire : Combustion may cause: fighting nitrogen oxides (NOx)

i.3 Advice for firefighters

Special protective equipment for fire-fighters Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

: In the event of fire, wear self-contained breathing apparatus.

5. Accidental release measures

;.I Personal precautions, protective equipment and emergency procedures

Personal precautions : Wear personal protective equipment.

5.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.

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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

IGardobond R 2600 A IVersion 6.0 Revision Date 20.10.201 0 Print Date 03.02.201

Avoid subsoil penetration.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Ensure adequate ventilation. Soak up with liquid binder (sand, kieselguhr, acid binder, universal binder). Sweep up and shovel into suitable containers for disposal.

6.4 Reference to other sections

See chapter 8 and 13

7. Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms. Have eye wash bottle or eye rinse ready at the work place. Avoid contact with skin and eyes. Do not breathe vapours, aerosols.

: Normal measures for preventive fire protection. Advice on protection against fire and explosion

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Store at room temperature in the original container. Keep container tightly closed in a dry and well-ventilated place.

Further information on stor- : Avoid contact with metals. age conditions

7.3 Specific end uses

Specific use(s) : Phosphating solution for metal surfaces

8. Exposure controlslpersonal protection

8.1 Control parameters

Components CAS-No. Value Update Basis Control parameters

Orthophos- 7664-38-2 TWA 1 mg/m3 2000-06-1 6 2000/39/EC phoric acid

Further informa- Indicative tron

STEL 2mglm3 2000-06-1 6 2000/39/EC

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Indicative

SAFETY DATA SHEET jccording to Regulation (EC) No. 1907/2006

TWA

STEL

Sardobond R 2600 A

1 rng/rn3 2005-04-06 GB EH40

2rng/rn3 2005-04-06 GB EH40

Jersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

1871 8-07- 5


TWA 0.5 rnglrn3 As 2006-09-01 GB EH40 Mn

Manganese bis(dihydroge n phosphate)


:

Nickel(l1) nitrate

2: Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used

As Mn


: 68: Substances that can cause occupational asthma (also known as asthmagens and respiratory sensitisers) can induce a state of specific airway hyper-responsiveness via an immunologi- cal, irritant or other mechanisms. Once the airways have become hyper-responsive, further exposure to the substance, sometimes even to tiny quantities, may cause respiratory symptoms. These symptoms can range in severity from a runny nose to asthma. Not all workers who are exposed to a sensitiser will become hyper-responsive and it is impossible to identify in advance those who are likely to become hyper-responsive. . Substances that can cause occupational asthma are classified under the "Chemicals (Hazard information and Packaging for

9 1 Nickel

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;ardobond R.2600 A ‘ersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

Nickel

DNEL/DMEL Zinc bis (dihydrogen phos- : End Use: DNEL, Workers

phate) Exposure routes: Skin contact Potential health effects: Chronic effects, Local effects 8.3 mg/kg The result refers to Zn - ion. End Use: DNEL, Workers Exposure routes: Ingestion Potential health effects: Chronic effects, Local effects 0.83 mgkg

The result refers to Zn - ion.

PNEC Zinc bis (dihydrogen phos- : Fresh water phate) Value: 20.6 mg/l

The result refers to Zn - ion.

Marine water Value: 6.1 mg/l The result refers to Zn - ion.

Fresh water sediment Value: 117.8 mglkg The result refers to Zn - ion.

Marine sediment Value: 56.5 mgkg The result refers to Zn - ion.

Behaviour in waste water treatment plants Value: 0.052 mg/l The result refers to Zn - ion.

1.2 Exposure controls

Engineering measures

Ensure adequate ventilation, especially in confined areas.


Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Recommended Filter type: NO-P3

Hand protection : Neoprene

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Sardobond R 2600 A fersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

Eye protection

Skin and body protecti

Hygiene measures

Protective measures

n

Protective gloves complying with EN 374. The exact break through time can be obtained from the protective glove producer and this has to be observed. Protective gloves have to be replaced at the first sign of deterioration.

Tightly fitting safety goggles Eye protection (EN 166)

Chemical resistant protective clothing according to DIN EN 13034 (Type 6)

Do not breathe spray, vapour. Take off contaminated clothing and shoes immediately. Avoid contact with skin and eyes. Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and immediately after handling the product.

Handle in accordance with good industrial hygiene and safety practice. Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower.

Environmental exposure controls

General advice Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.

j. Physical and chemical properties

).I Information on basic physical and chemical properties

Appearance : liquid

Colour : green

Odour : odourless

Flash point : not applicable

Lower explosion limit : no explosion risk

Autoignition temperature : not auto-flammable

PH : < 2 at 20 "C

(undiluted)

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Sardobond R 2600 A Iersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

Solidification tempera- turehange

Boiling point/boiling range

Vapour pressure

Density

Water solubility

Flow time

1.2 Other information

Corrosion

Explosivity

: <O"C

: no data available

: no data available

: 1.39 - 1.43 g/cm3 at 20 "C Method: DIN 51 757

: completely miscible

: c a . 1 5 ~ at 23 "C 4 mm Method: IS0 2431

: Corrosive to metals

: no explosion risk

IO. Stability and reactivity

0.1 Reactivity

No decomposition if stored and applied as directed.

0.2 Chemical stability

0.3 Possibility of hazardous reactions Stable under recommended storage conditions.

Hazardous reactions : Gives off hydrogen by reaction with metals.

0.4 Conditions to avoid

Conditions to avoid : To avoid thermal decomposition, do not overheat.

10.5 Incompatible materials

Materials to avoid : Contact with organic substances or other reducing agents can form mixed nitrous gases (toxic).

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SAFETY DATA SHEET ccording to Regulation (EC) No. 1907/2006

3ardobond R 2600 A 'ersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 '

Incompatible with bases.

0.6 Hazardous decomposition products

Risk of decomposition. : nitrogen oxides (NOx)

1. Toxicological information

1.1 Information on toxicological effects

Acute toxicity

Acute oral toxicity

Acute oral toxicity Zinc bis (dihydrogen phosphate)

Orthophosphoric acid

Nickel(l1) nitrate

Acute inhalation toxicity Orthophosphoric acid

Acute dermal toxicity Zinc bis (dihydrogen phosphate)

Orthophosphoric acid

Skin corrosionlirritation

Skin irritation

: no data available

: LD50: > 300 - 2,000 mg/kg Species: rat Method: OECD Test Guideline 423 GLP: yes

: LD50: 1,530 mg/kg Species: rat

: Acute toxicity estimate: 500 mg/kg Method: Converted acute toxicity point estimate

: LC50: 100 - 1,000 mg/l Exposure time: 96 h Species: rat

LD50: > 2,000 mg/kg Species: rat Method: OECD Test Guideline 402 GLP: yes Test substance: Similar substance

: LD50: 2,740 mg/kg Species: rabbit

: Causes burns.

Serious eye damageleye irritation 11 /26

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3ardobond R 2600 A lersion 6.0 Revision Date 20.10.201 0 Print Date 03.02.201 1

Eye irritation : Causes burns.

Respiratory or skin sensitization

Sensitisation

Germ cell mutagenicity Zinc bis (dihydrogen phosphate)

Human experience

May cause sensitization by inhalation and skin contact.

Ames test Result: negative Method: Mutagenicity (Escherichia coli - reverse mutation assay) GLP: yes

If swallowed, severe burns in the oral cavity and throat as well as danger of perforation of the digestive tract and stomach.

Target Organ Systemic Toxicant - Repeated exposure

Zinc bis (dihydrogen phos- : Species: rat phate) Application Route: Oral

Exposure time: (90 d) NOAEL: 53.5 mg/kg Method: OECD Test Guideline 408 GLP: yes The result refers to Zn - ion.

Further information : May cause cancer by inhalation. May cause harm to the unborn child. Possible risk of irreversible effects. Also toxic: danger of serious damage to health by prolonged exposure through inhalation.

12. Ecological information

12.1 Toxicity

Toxicity to fish : no data available

Toxicity to fish Zinc bis (dihydrogen phos- : flow-through test NOEC: 0.199 mg/l phate) Exposure time: 30 d

Species: Oncorhynchus mykiss (rainbow trout) Test substance: Similar substance

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SAFETY DATA SHEET lccording to Regulation (EC) No. 1907/2006

3ardobond R 2600 A lersion 6.0 Revision Date 20.10.201 0 Print Date 03.02.201 1

Method: OECD Test Guideline 21 5 GLP: yes

Toxicity to daphnia and other aquatic invertebrates. Zinc bis (dihydrogen phos- : Immobilization EC50: 9.04 mg/l phate) Exposure time: 48 h

Species: Daphnia magna (Water flea) Method: OECD Test Guideline 202 GLP: yes

Immobilization NOEC: 3.13 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Method: OECD Test Guideline 202 GLP: yes

Toxicity to algae Zinc bis (dihydrogen phos- : Growth inhibition ErC50: 0.37 mgll phate) Exposure time: 72 h

Species: Pseudokirchneriella subcapitata (green algae Method: OECD Test Guideline 201 GLP: yes

Growth inhibition LOEC: 0.32 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae) Method: OECD Test Guideline 201 GLP: yes

Growth inhibition NOEC: 0.18 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae) Method: OECD Test Guideline 201 GLP: yes

Nickel(l1) nitrate : M-Factor:

12.2 Persistence and degradability

Biodegradability : no data available

12.3 Bioaccumulative potential

Bioaccumulation

12.4 Mobility in soil

no data available

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jAFETY DATA SHEET iccording to Regulation (EC) No. 1907/2006

-

Sardobond R 2600 A lersion 6.0 Revision Date 20.10.201 0 Print Date 03.02.201 1

Mobility : no data available

2.5 Results of PBT and VPVB assessment

no data available

2.6 Other adverse effects

Additional ecological informa- : highly water endangering tion

: Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Even leakage of small amounts in the subsoil can contaminate drinking water. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

13. Disposal considerations

13.1 Waste treatment methods

Product : Dispose of as hazardous waste in compliance with local and national regulations.

Contaminated packaging : Dispose of as hazardous waste in compliance with local and national regulations.

Waste Code : Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

14. Transport information

ADR UN number UN proper shipping name

Transport hazard class(es) Packing group Classification Code Hazard identification No Packing instruction (LQ) Labels Tunnel restriction code Environmentally hazardous

: 3264 : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Ortho-

phosphoric acid, Nickel(l1) nitrate : 8 : Ill : c 1 : 80 : LQ19 : 8 : (E), : yes

IATA UN number : 3264 Description of the goods : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Ortho-

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Class Packing group Labels

Packing instruction (cargo aircraft) IATA-C Environmentally hazardous

Packing instruction (passen- ger aircraft) IATA-P Environmentally hazardous

IMDG UN number Description of the goods

Class Packing group Labels Ems Number 1 Ems Number 2 Marine pollutant

RID UN number Description of the goods

Transport hazard class(es) Packing group Classification Code Hazard identification No Labels Packing instruction (LQ) Environmentally hazardous

phosphoric acid : 8 : Ill : 8

: 820

no

: 818

: no


phosphoric acid, Nickel dinitrate : 8 : Ill : 8 : F-A : S-B : no


phosphoric acid , Nickel(l1) nitrate : 8 : Ill : c1 : 80 : 8 : LQ19 : yes

5. Regulatory information

5.1 Safety, health and environmental regulationsllegislation specific for the substance or mixture

Water contaminating class : WGK 3 highly water endangering (Germany) WVWVS A4

Other regulations German regulation: Soluble nickel salts are carcinogenic substances, category 1.

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IAFETY DATA SHEET :cording to Regulation (EC) No. I90712006 e iardobond R 2600 A ersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

: The product is classified and labelled in accordance with EC directives or respective national laws. Regional or national implementations of GHS may not imple- ment all hazard classes and categories.

5.2 Chemical Safety Assessment A Chemical Safety Assessment has been carried out for one or more substances in this product.

6. Other information

Full text of R-phrases referred to under sections 2 and 3

R 8 R20122 R22 R34 R38 R4 1 R42143 R48123

R49 R50 R51 153

R53 R61 R68

Contact with combustible material may cause fire. Harmful by inhalation and if swallowed. Harmful if swallowed. Causes burns. Irritating to skin. Risk of serious damage to eyes. May cause sensitization by inhalation and skin contact. Toxic: danger of serious damage to health by prolonged exposure through inhalation. May cause cancer by inhalation. Very toxic to aquatic organisms. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May cause long-term adverse effects in the aquatic environment. May cause harm to the unborn child. Possible risk of irreversible effects.

Full text of H-Statements referred to under sections 2 and 3.

H272 H302 H314 H315 H317 H318 H332 H334

H341 H350i H360D H372

H400 H410

May intensify fire; oxidiser. Harmful if swallowed. Causes severe skin burns and eye damage. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing genetic defects. May cause cancer by inhalation. May damage the unborn child. Causes damage to organs through prolonged or repeated exposure if inhaled. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Full text of Notas referred to under section 3

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Zardobond R 2600 A lersion 6.0 Revision Date 20.10.201 0 Print Date 03.02.201 1

Nota B

Nota E

Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solutions require different labelling since the hazards vary at different concentrations. In Annex I entries with Note B have a general designation of the following type: nitric acid .... %. In this case the manufacturer or any other person who markets such a substance in aqueous solution must state the percentage concentration of the solution on the label. Example: nitric acid 45 %. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weight/weight basis. The use of additional data (e.g. specific gravity, degrees Baume) or descriptive phrases (e.g. fuming or glacial) is permissible. Substances with specific effects on human health (see Chapter 4 of Annex VI) that are classified as carcinogenic, mutagenic and/or toxic for reproduction in categories 1 or 2 are ascribed Note E if they are also classified as very toxic (T+), toxic (T) or harmful (Xn). For these substances, the risk phrases,R 20, R 21, R 22, R 23, R 24, R 25, R 26, R 27, R 28, R 39, R68 (harmful), R 48 and R 65 and all combinations of these risk phrases shall be preceded by the word "Also". Examples: R 45-23 "May cause cancer. Also toxic by inhalation". R 46-27/28 "May cause heritable genetic damage. Also very toxic in contact with skin and if swallowed".

Further information

The information provided is based on our current knowledge and experience and apply to the product as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety datasheet does not free the recipient of the product from his own responsibility to follow the relevant rules and regulations concerning this product.

17 I 2 6 - EN

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SAFETY DATA SHEET iccording to Regulation (EC) No. 190712006

Sardobond R 2600 A /ersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

. Short title of Exposure Scenario: GES Zn(H2P04)2 andlor Zn(N03)2-7 : Industrial and pro- essional use of surface treatment products containing Zn(H2P04)2 and/or Zn(NO3)P

Main User Groups

'roduct Category

3rocess category

Environmental Release Category

Activity

SU 3: Industrial uses: Uses of substances as such or in preparations at industrial sites

PC1 4: Metal surface treatment products, including galvanic and electroplating products

PROC: 2 Use in closed, continuous process with occasional controlled exposure PROC: 3 Use in closed batch process (synthesis or formulation) PROC: 4 Use in batch and other process (syn-thesis) where opportunity for exposure arises PROC: 7 Industrial spraying PROC: 8a Transfer of substance or preparation (chargingldischarging) from/to vesselsllarge containers at non- dedicated facilities PROC: 8b Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC: 9 Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC: 10 Roller application or brushing PROC: 13 Treatment of articles by dipping and pouring PROC: 23 Open processing and transfer operations with min- erals/metals at elevated temperature PROC: 24 High (mechanical) energy work-up of substances bound in materials and/or articles

ERC4: Industrial use of processing aids in processes and products, not becoming part of articles

Use at workplace

!.l Contributing scenario controlling environmental exposure for: ERC4: Industrial use of wocessing aids in processes and products, not becoming part of articles

'roduct characteristics Concentration of the Substance in MixturelArticle the MSDS.

: Information on the concentration may be found in chapter 3 of

imount used Amount of substance in the prod- : 100,000 kg uct per year. Amount of the substance which : 400,000 kg

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3ardobond R 2600 A /ersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

may be safely used within the limits of the exposure scenario. (Msafe)

3wironment factors not influenced by risk management Flow rate : 18,000 m3/d

Remarks Dilution Factor (River) : 10

: Calculated worst case river - this may be adapted using scaling criteria to the local receiving environment.

Xher given operational conditions affecting environmental exposure Emission to aqueous environment. Number of emission days per year : 365 Emission or Release Factor: Air : 0 O/O

Emission or Release Factor: Water : 100 % Emission or Release Factor: Soil : 0 % Remarks : All process and non-process waters should be recycled inter-

nally as much as possible. Even when no process waters are produced, some non-process water containing zinc can be generated (e.g. from cleaning). In industrial and professional settings, all processes are per- formed in a contained area. All residues containing zinc are recycled, or treated as hazardous wastes.

:onditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant Flow rate of sewage treatment : 2,000 m3/d plant effluent

Percentage removed from waste : 99.8 YO eater Sludge Treatment Procedures to limit air emissions : Not relevant from Sewage Treatment Plant

: Chemical precipitation and public sewage-treatment plant.

Effectiveness (of a measure) : 99.8 Yo

: Use sludge treatment techniques for disposal or recovery.

:onditions and measures related to external treatment of waste for disposal : All contaminated waste water must be processed in an indus-

trial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.

: Can be landfilled after chemical and physical treatment, when in compliance with local regulations. (Effectiveness: 99 %)

Waste treatment

Disposal methods

!.2 Contributing scenario controlling worker exposure for: PROC: 2 Use in closed, continu- )us process with occasional controlled exposure 'ROC: 3 Use in closed batch process (synthesis or formulation) 'ROC: 4 Use in batch and other process (synthesis) where opportunity for exposure arises 'ROC: 8a Transfer of substance or preparation (charging/discharging) fromlto vessels/large :ontainers at non-dedicated facilities

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;AFETY DATA SHEET ccording to Regulation (EC) No. 190712006

Sardobond R 2600 A 'ersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

'ROC: 8b Transfer of substance or preparation (chargingldischarging) from/to vesseldlarge ontainers at dedicated facilities 'ROC: 9 Transfer of substance or preparation into small containers (dedicated filling line, in- luding weighing) 'ROC: 10 Roller application or brushing 'ROC: 13 Treatment of articles by dipping and pouring 'ROC: 23 Open processing and transfer operations with mineralshetals at elevated tempera- Jre 'ROC: 24 High (mechanical) energy work-up of substances bound in materials and/or articles

ctivity : Use at workplace

'roduct characteristics Concentration of the Substance in Mixture/Article the MSDS. Physical Form (at time of use) : Liquid mixture

Information on the concentration may be found in chapter 3 of

imou n t used Used amount per day : 50 kg

Amount of the substance which : 50,000 kg may be safely used within the limits of the exposure scenario.

'requency and duration of use Frequency of use : 8 hourslday

luman factors not influenced by risk management Exposed skin area : Uncovered body parts: (potentially) face

Hher operational conditions affecting workers exposure Outdoor / Indoor : Indoor Remarks : Room temperature, room size and air exchange rate are not

relevant for this exposure scenario.

'echnical conditions and measures In industrial and professional settings the following applies: Process enclosures where relevant and possible local exhaust ventilation on furnaces and other work areas with potential dust generation. Dust capturing and removal techniques are applied. Containment of liquid volumes in sumps to collectlprevent accidental spillage.

Irganisational measures to prevent /limit releases, dispersion and exposure In general, emissions are controlled and prevented by implementing an appropriate management system. This would involve: informing and training workers, regular cleaning of equipment and floors, procedures for process control and maintenance, treatment and monitoring of releases to outside air and exhaust gas streams, according to national regulations. SEVESO 2 compliance, if applicable.

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:onditions and measures related to personal protection, hygiene and health evaluation For personal protection see section 8.

1.3 Contributing scenario controlling worker exposure for: PROC7: Industrial spraying

ictivity

'roduct characteristics Concentration of the Substance in Mixture/Article Physical Form (at time of use) Process Temperature Remarks

imount used Used amount per day

Amount of the substance which may be safely used within the limits of the exposure scenario.

kequency and duration of use Workers Frequency of use

: Spraying

Information on the concentration may be found in chapter 3 of the MSDS.

: Liquid mixture : 25°C : During use, aerosols are formed.

: 1,500 kg

: M-Safe has not been derived.

: 620 min : 5days/week

iuman factors not influenced by ris.. management Exposed skin area : Uncovered body parts: (potentially) face

: 0.3 mg/d

Ither operational conditions affecting workers exposure Outdoor / Indoor : Indoor Temperature : 25°C

Remarks : Engineering controls, e.g. exhaust ventilation, general ventila- Ventilation rate per hour : 10

tion; specify effectiveness of measure

Industrial /professional: Local exhaust ventilation systems and process enclosures are generally applied Cyclones/filters (for minimizing dust emissions): efficiency 70%-90% (cyclones); dust filters (50-80%) LEV in work area: efficiency 84% (generic LEV)

Dermal exposure, Inhalation exposure

'echnical conditions and measures In industrial and professional settings the following applies:

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ERC5

3ardobond R 2600 A lersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201

~ ~ ~ ~ ~

(ater TPEC r 5.lpg/L 1 0.25 ~

Ecetoc TRA Standard parameters where used

Process enclosures where relevant and possible local exhaust ventilation on furnaces and other work areas with potential dust generation. Dust capturing and removal techniques are applied. Containment of liquid volumes in sumps to collect/prevent accidental spillage.

Irganisational measures to prevent /limit releases, dispersion and exposure In general, emissions are controlled and prevented by implementing an appropriate management system. This would involve: informing and training workers, regular cleaning of equipment and floors, procedures for process control and maintenance, treatment and monitoring of releases to outside air and exhaust gas streams, according to national regulations. SEVESO 2 compliance, if applicable.

Zonditions and measures related to personal protection, hygiene and health evaluation For personal protection see section 8. (Effectiveness: > 75 YO)

Exposure estimation and reference to its source

Invironment

Contributing Scenario

Exposure Assessment

Method

Specific conditions Com- part- ment

Type: Level of Exposure

Risk charac- terisa-

tion ratio

(PEC/P NEC):

Contributing Scenario

2.2

Exposure Assessment

Method

Specific conditions

MEASE MEASE parameters were set as follows: aqueous solution; Content in preparation: 525%; Process category (PROC): as indicated; Process T: 25°C; Scale of operation: professional; Duration of exposure: >240 minutes; Pattern of use: wide dispersive; Patter of exposure control: direct handling; Contact level: extensive; Implemented RMMs: LEVgeneric (indoor); no RMM (outdoor);Efficiency based on: median estimate; No RPE, unless indicated otherwise; Use of gloves: prop- erly designed

Type:

Total systemic exposure

(mg/d)

Level of Exposure

< 0.4 mgld

Risk c h a rac- terisa-

tion ratio

(PECIP NEC):

< 0.04

22 I 2 6 - El

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Gardobond R 2600 A Version 6.0 Revision Date 20.10.201 0 Print Date 03.02.201

2.3 MEASE MEASE parameters were set as follows: aqueous solution; Content in preparation: 5-25%; Process category (PROC): as indicated; Process T: 25°C; Scale of operation: professional; Duration of exposure: >240 minutes; Pattern of use: wide dispersive; Patter of exposure control: direct handling; Contact level: extensive; Implemented RMMs: LEV generic (indoor); no RMM (outdoor);Efkiency based on: median estimate; No RPE, unless indicated otherwise; Use of gloves: prop- erly designed

Total systemic exposure

(mgW

ERC5: Industrial use resulting in inclusion into or onto a matrix

Uses with a risk characterisation ratio (RCR) 1 are considered to be safe uses.

4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure Scenario

If your uses are within the limits of the provided exposure scenario, you may use scaling options to adapt the exposure scenario to your local conditions.

For further information on safe use, ask our technical specialists.

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SAFETY DATA SHEET iccording to Regulation (EC) No. 1907l2006 11 3ardobond R 2600 A lersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 1

. Short title of Exposure Scenario: GES Zn(H2P04)2 andlor Zn(N03)2-7 : Industrial and pro- essional use of surface treatment products containing Zn(H2P04)Z and/or Zn(N03)2

Main User Groups : SU 3: Industrial uses: Uses of substances as such or in preparations at industrial sites

: ERC5: Industrial use resulting in inclusion into or onto a matrix Environmental Release Category

Activity : Corrosion inhibitors

!.I Contributing scenario controlling environmental exposure for: ERC4: Industrial use of wocessing aids in processes and products, not becoming part of articles

'roduct characteristics Concentration of the Substance in MixturelArticle the MSDS.

: Information on the concentration may be found in chapter 3 of

imount used Amount of substance in the prod- : 200,000 kg uct per year. Amount of the substance which : 200,000 kg may be safely used within the limits of the exposure scenario. (Msafe)

kvironment factors not influenced by risk management Flow rate : 18,000 m3ld

Remarks Dilution Factor (River) : 10

: Calculated worst case river - this may be adapted using scaling criteria to the local receiving environment.

Ither given operational conditions affecting environmental exposure Emission to aqueous environment. Number of emission days per year : 350 Emission or Release Factor: Air : 0 % Emission or Release Factor: Water : 100 YO Emission or Release Factor: Soil : 0 YO Remarks : All process and non-process waters should be recycled inter-

nally as much as possible. Even when no process waters are produced, some non-process water containing zinc can be generated (e.g. from cleaning). In industrial and professional settings, all processes are per- formed in a contained area. All residues containing zinc are recycled, or treated as hazardous wastes.

24 I 2 6 - EN

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IAFETY DATA SHEET :cording to Regulation (EC) No. 1907/2006

iardobond R 2600 A ersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201 ’

onditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant Flow rate of sewage treatment : 2,000 m3/d plant effluent

Percentage removed from waste : 99.1 % eater Sludge Treatment Procedures to limit air emissions : Not relevant from Sewage Treatment Plant

onditions and measures related to external treatment of waste for disposal Waste treatment

: Chemical precipitation and public sewage-treatment plant.

Effectiveness (of a measure) : 99.1 %

: Use sludge treatment techniques for disposal or recovery.

: All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.

: Dispose of as hazardous waste in compliance with local and national regulations.

Disposal methods

~ _ _ _ _ _ _ ~ ~

, Exposure estimation and reference to its source

nvironment

Sontributing Exposure Specific conditions Scenario Assessment

Method

E RC5 Chemetall pre-

treatment calculation

tool

General Input Data : Modifiers; Produc- tion rate: 100 units I h; Average body surface: 100 m2; Production: 22 hours I day; Production: 350 days I year; Con- ductivity in Phosphate tank: 20000 pSIcm; Conductivity in final rinse tank: 50 pS/crn; Drag out (standard = 100mUm2): 100 mum’; Number of rinse stages: 3

~~

Com- I Type: 1 Eve1 of

RC5: Industrial use resulting in inclusion into or onto a matrix

kes with a risk characterisation ratio (RCR) < 1 are considered to be safe uses.

Risk charac- terisa-

tion ratio

(PEC/P NEC):

0.0006

. Guidance to Downstream User to evaluate whether he works inside the boundaries et by the Exposure Scenario

‘ou may get the Chemetall pretreatment uses calculation tool on our homepage,

25 / 26 M

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SAFETY DATA SHEET according to Regulation (EC) No. 190712006

(Gardobond R 2600 A IVersion 6.0 Revision Date 20.10.2010 Print Date 03.02.201

from your technical contact to assess your local installation.

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sAFE7-Y DATA SHEET carding to Regulation (EC) No. 1907/2006

Sardobond R 2604E 'ersion: 3 22.03.201 0

. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANYlUNDERTAKlNG

English Product information

Commercial Product Name Recommended use: Phosphating solution for metal surfaces.

Gardobond R 2604E

Company: Chemetall plc Denbigh Road Bletchley Milton Keynes MK

Lead Organisation: Contact person: Telephone: 01908649333 Telefax: 01908373939

Product safety: Telephone: E-mail address:

+44(0)1908 649333 [email protected]

Emergency telephone: 01 908 649333

1 PB

~ ~

I. HAZARDS IDENTIFICATION

Risk advice to man and the environment

Classification: Carcinogenic Category 1 R49 May cause cancer by inhalation.

toxic R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation.

Toxic to Reproduction Category 2

Corrosive R34 Causes burns.

R61 May cause harm to the unborn child. ,

Mutagenic Category 3

Sensitising

R68 Possible risk of irreversible effects.

R42143 May cause sensitization by inhalation and skin contact.

Dangerous for the environment

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

1. COMPOSlTlONllNFORMATlON ON INGREDIENTS Hazardous components

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;AFEP/ DATA SHEET ccording to Regulation (EC) No. 1907/2006

3ardobond R 2604E fersion: 3 22.03.2010

Nickelill) nitrate 5.00 - 10.00 YO

Classification: 0; R 8 Carc.Cat.1; R49 Repr.Cat.2; R61 Mut.Cat.3; R68 T; R48/23 Xn; R20122 Xi; R38, R41 R42/43 N; R50, R53

CAS-NO.: 131 38-45-9 EINECS-NO.: 236-068-5

Orthophosphoric acid 2.50 - 5.00 YO CAS-NO.: 7664-38-2 EINECS-NO.: 231 -633-2 Classification: C; R34

Manqanese fluoroborate 1 .OO - 2.50 YO CAS-NO.: 30744-82-2 El NECS-NO.: 250-320-1 Classification: C; R34

WEL substance: Manqanese biddihvdroqen Dhosphatel 25.00 - 50.00 YO CAS-NO.: 1871 8-07-5 EINECS-NO.: 242-520-2

1. FIRST AID MEASURES

General advice: Take off contaminated clothing and shoes immediately. First-aid crew: Ensure self-protection. Move out of dangerous area. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately. Skin contact: Wash off immediately with plenty of water for at least 15 minutes. Call a physician immediately. Inhalation: Move to fresh air. If symptoms persist, call a physician. Ingestion: Rinse mouth with water. Immediately give large quantities of water to drink. Do NOT induce vomiting. Call a physician immediately.

i. FIRE-FIGHTING MEASURES

Specific hazards during fire fighting: Combustion may cause: nitrogen oxides (NOx) Special protective equipment for fire-fighters: In the event of fire, wear self-contained breathing apparatus. Suitable extinguishing media: Carbon dioxide (C02), Dry powder, Water spray jet, Alcohol-resistant foam Further information: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

i. ACCIDENTAL RELEASE MEASURES

Personal precautions: Wear personal protective equipment.

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3ardobond R 2604E lersion: 3 22.03.2010

Environmental precautions: Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Methods for cleaning up: Ensure adequate ventilation. Soak up with liquid binder (sand, kieselguhr, acid binder, universal binder). Sweep up and shovel into suitable containers for disposal.

'. HANDLING AND STORAGE

Handling

Safe handling advice: Provide sufficient air exchange and/or exhaust in work rooms. Have eye wash bottle or eye rinse ready at the work place. Avoid contact with skin and eyes. Advice on protection against fire and explosion: No special protective measures against fire required.

Storage

Requirements for storage areas and containers: Store at room temperature in the original container. Keep container tightly closed in a dry and well-ventilated place. Further information: Avoid contact with metals.

I. EXPOSURE CONTROLSlPERSONAL PROTECTION

Components with workplace control parameters

Manganese bis(dihydrogen phosphate) 1871 8-07-5

TWA 0.50 mglm3 As Mn 2006-09-01 GB EH40

Nickel(l1) nitrate 131 38-45-9

TWA 0.10 mg/m3 Nickel 2007-08-01 GB EH40

2007-08-01 GB EH40

Value Update Basis

Value Update Basis 1

Orthophosphoric acid 7664-38-2

TWA 1 .OO mg/m3 2000-06-1 6 2000/39/EC STEL 2.00 mglm3 2000-06-1 6 2000/39/EC TWA 1 .OO mg/m3 2005-04-06 GB EH40 STEL 2.00 mg/m3 2005-04-06 GB EH40

Manganese fluoroborate 30744-82-2

TWA 0.50 mglm3 As Mn 2006-09-01 GB EH40

TWA 2.50 mg/m3 2000-06-1 6 2000/39/EC


Value Update Basis

Value Update Basis

Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Recommended Filter type: NO-P3

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Sardobond R 2604E Iersion: 3 22.03.2010

Hand protection: Material: Neoprene General advice: Protective gloves complying with EN 374., The exact break through time can be obtained from the protective glove producer and this has to be observed., Protective gloves have to be replaced at the first sign of deterioration.

Eye protection: Tightly fitting safety goggles Skin and body protection: Chemical resistant protective clothing according to DIN EN 13034 Hvcliene measures: Take off contaminated clothing and shoes immediately. Avoid contact with skin and eyes. Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and immediately after handling the product. Protective measures: Handle in accordance with good industrial hygiene and safety practice. Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower.

1. PHYSICAL AND CHEMICAL PROPERTIES

Form : Colour: Odour:

Solidification temperaturekange:

Boiling point/boiling range:

Flash point:

Density:

Solubilitylqualitative:

pH:

liquid green none

< -10 "C

110 "C

not applicable

1.53 glcm3

completely miscible

1.5 (undiluted)

IO. STABILITY AND REACTIVITY

Conditions to avoid:

To avoid thermal decomposition, do not overheat.

Materials to avoid:

Contact with organic substances or other reducing agents can form mixed nitrous gases (toxic)., Incompatible with bases.

Hazardous decomposition products:

nitrogen oxides (NOx)

Hazardous reactions: Gives off hydrogen by reaction with metals.

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Zardobond R 2604E lersion: 3 22.03.2010

Thermal decomposition: > 320 "C

11. TOXICOLOGICAL INFORMATION

Skin irritation: Causes burns.

Eye irritation: Causes burns.

Sensitisation: May cause sensitization by inhalation and skin contact.

Further toxicological information: May cause cancer by inhalation., May cause harm to the unborn child., Possible risk of irreversible effects., Also toxic: danger of serious damage to health by prolonged exposure through inhalation.

-

12. ECOLOGICAL INFORMATION

Elimination information (persistence and degradability):

Chemical Oxygen Demand (COD): 0 mg/l

Further information: Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. highly water endangering

13. DISPOSAL CONSIDERATIONS

Waste key for the unused product: 11 01 06 acids not otherwise specified

Product: Dispose of as hazardous waste in compliance with local and national regulations.

Contaminated packaging: Dispose of as hazardous waste in compliance with local and national regulations.

14. TRANSPORT INFORMATION

Regulation : ADR UN/ID No.: 3264 Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Orthophosphoric acid, Nickel(l1) nitrate Packaging group: 111 Class: a

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3ardobond R 2604E lersion: 3 22.03.2010

ADWRID-Labels: 8

Regulation : RID UN/ID No.: 3264 Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Orthophosphoric acid, Nickel( II) nitrate Packaging group: Ill Class: 8 ADWRID-Labels: 8

Regulation : IMDG UN/ID No.: 3264 Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Orthophosphoric acid, Nickel dinitrate Packaging group: Ill Class: 8 Ems: F-A S-B Environmentally Hazardous

Regulation : IATA-C UN/ID No.: 3264 Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Orthophosphoric acid Packaging group: Ill Class: 8

Regulation : IATA-P UN/ID No.: 3264 Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Orthophosphoric acid Packaging group: Ill Class: 8

5. REGULATORY INFORMATION

Hazardous components which must be listed on the label: 0 Nickel(l1) nitrate

La be II i ng :

(81 Toxic Dangerous for the environment M

R49 R6 1 R48123

R34 Causes burns. R68 R42143

R51 153

May cause cancer by inhalation. May cause harm to the unborn child. Also toxic: danger of serious damage to health by prolonged exposure through inhalation.

Possible risk of irreversible effects. May cause sensitization by inhalation and skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

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0

4)


Sardobond R 2604E /ersion: 3 22.03.2010

S-phrase( s): s53

S23 S26

s35

S36137139

s45

Avoid exposure - obtain special instructions before use. Do not breathe gaslfumeslvapourlspray. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. This material and its container must be disposed of in a safe way. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Special labelling of certain mixtures: ?estricted to professional users. 99/45/EC - 2001 /60/EC and 200618/EC included Other regulations: German regulation: Soluble nickel salts are carcinogenic substances, category 1.

Other regulations: The product is classified and labelled in accordance with EC directives or respective national laws.

16. OTHER INFORMATION

Text of R phrases mentioned in Section 3 R 8 Contact with combustible material may cause fire. R20122 Harmful by inhalation and if swallowed. R34 Causes burns. R38 Irritating to skin. R41 Risk of serious damage to eyes. R42143 May cause sensitization by inhalation and skin contact. R48123 Toxic: danger of serious damage to health by prolonged exposure through inhalation. R49 May cause cancer by inhalation. R50 Very toxic to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. R61 May cause harm to the unborn child. R68 Possible risk of irreversible effects. Text of R phrases mentioned in Section 3

The information provided is based on our current knowledge and experience and apply to the product as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety datasheet does not free the recipient of the product from his own responsibility to follow the relevant rules and regulations concerning this product. I This data sheet contains changes from the previous version in section(s): 14

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Zardoclean S 5174 lersion: 2 18.07.2008

. IDENTIFICATION OF THE SUBSTANCElPREPARATlON AND OF THE :OMPANYlUNDERTAKING


Commercial Product Name

Recommended use : Cleaning agent

Corn pany :

Lead Organisation: Contact person: Telephone: Telefax:


Emergency telephone:

Gardoclean S 5174

Chemetall plc Denbigh Road Bletchley Milton Keynes MKI 1 PB

01908649333 01908 373939

+44(0)1908 649333 [email protected]

01908 649333

I. HAZARDS IDENTIFICATION ~ ~ ~ ~~~


Classification:

Corrosive R35 Causes severe burns.

Harmful R22 Harmful if swallowed.

1. COMPOSlTlONllNFORMATION ON INGREDIENTS Hazardous components

Potassium Hvdroxide 25.00 - 50.00 Yo

Classification: Xn; R22 C; R35 CAS-NO.: 1310-58-3 EINECS-NO.: 215-181-3

sodium N-~2-carboxvethvl~-N-~2-ethvlhexvl~-beta-alaninate 2.50 - 5.00 YO

Classification: Xi: R41 CAS-NO.: 94441-92-6 EINECS-NO.: 305-318-6

Alcohol alkoxvlate 0.10 - 1.00 % Classification: N; R50

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0


Sardoclean S 5174 fersion: 2 18.07.2008


I

0

General advice: Take off contaminated clothing and shoes immediately. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a physician. Skin contact: Wash off immediately with plenty of water. If symptoms persist, call a physician. Inhalation: Move to fresh air. If symptoms persist, call a physician. Ingestion: Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Call a physician immediately.

~ ~~ ~


Special protective equipment for fire-fighters In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Suitable extinguishing media: Carbon dioxide (C02), Dry powder, Water spray, Alcohol-resistant foam Further information: The product itself does not burn.


Personal precautions Wear personal protective equipment. Evacuate personnel to safe areas. Environmental precautions: Do not flush into surface water or sanitary sewer system. Methods for cleaning up: Soak up with liquid binder (sand, kieselguhr, acid binder, universal binder). Sweep up or vacuum up spillage and collect in suitable container for disposal.

I. HANDLING AND STORAGE

Handling

Safe handling advice: Have eye wash bottle or eye rinse ready at the work place. Advice on protection against fire and explosion: No special protective measures against fire required.

Storage

Requirements for storage areas and containers Store at room temperature in the original container. Keep container tightly closed. Further information: Avoid contact with amphoteric metals (e.g. aluminium, lead, zinc).

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Gardoclean S 5174 Jersion: 2 18.07.2008

3. EXPOSURE CONTROLSlPERSONAL PROTECTION ~ ~ ~ _ _ _ _ _ ~ ~ ~ ~ ~


Potassium Hydroxide 1310-58-3

STEL 2.00 mglm3 2007 EH40 WEL


Respiratory protection : Not required; except in case of aerosol formation. Hand protection : Material: butyl-rubber Break through time: > 480 min General advice: The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN 374 derived from it., The exact break through time can be obtained from the protective glove producer and this has to be observed.

I Value I Update I Basis

Eye protection: Tightly fitting safety goggles Skin and body protection: Protective suit Hygiene measures Take off contaminated clothing and shoes immediately. Avoid contact with the skin and the eyes. Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and at the end of workday.


Form: Colour: Odour:

Melting pointhange:

Boiling poinffrange:

Flash point:

Density:

Solubility/qualitative:

pH:

liquid light brown slight

c -10 "C

115 "C

not applicable

1.36 g/cm3

completely miscible

13.6 at: 43 g/L


Materials to avoid:

Amphoteric metals are attacked developing hydrogen (combustible).

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Gardoclean S 5174 Jersion: 2 18.07.2008

Hazardous decomposition products:

No decomposition if stored and applied as directed

Hazardous reactions: Exothermic reaction with strong acids.


Skin irritation: Causes severe burns.

Eye irritation: Causes severe burns,

Sensitisation: not applicable

Further toxicological information: Harmful if swallowed., Ingestion: Corrosive to mouth, oesophagus and stomach.



Chemical Oxygen Demand (COD): ca. 90 mg/g

Further information: slightly water endangering


Waste key for the unused product: 1 101 13 degreasing wastes containing dangerous substances

Product: Dispose of as hazardous waste in compliance with local and national regulations.

Contaminated packaging: Dispose of as hazardous waste in compliance with local and national regulations.

14. TRANSPORT INFORMATION

Regulation : ADR UN/ID No.: 1814 Proper shipping name: POTASSIUM HYDROXIDE SOLUTION Packaging group: II Class: 8 ADR/RID-Labels: 8

Regulation : RID 416

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3ardoclean S 51 74 ‘ersion: 2 18.07.2008

UN/ID No.: 1814 Proper shipping name: POTASSIUM HYDROXIDE SOLUTION Packaging group: I1 Class: 8 ADR/RID-Labels: 8

Regulation : IMDG UNAD No.: 1814 Proper shipping name: POTASSIUM HYDROXIDE SOLUTION Packaging group: II Class: 8 Ems: F-A S-B

Regulation : IATA-C UN/ID No.: 1814 Proper shipping name: POTASSIUM HYDROXIDE SOLUTION Packaging group: II Class: 8

Regulation : IATA-P UN/ID No.: 1814 Proper shipping name: POTASSIUM HYDROXIDE SOLUTION Packaging group: II Class: 8


Hazardous components which must be listed on the label: Potassium Hydroxide

Labelling: 1x1 Corrosive

R-phrase( s):

S-phrase( s):

R22 Harmful if swallowed. R35 Causes severe burns.

S26

S36/37/39

s45

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste.

S60

Special labelling of certain preparations: Ingredients according to Regulation (EC) No.648/2004 on detergents: Amphoteric surfactants, 5 % Non ionic surfactants 5% EDTA, 5 %

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Zardoclean S 5174 fersion: 2 18.07.2008

Other regulations: The product is classified and labelled in accordance with EC directives or respective national laws.

~ ~~ ~

16. OTHER INFORMATION ~~ ~ ~~

Text of R phrases mentioned in Section 3 R22 Harmful if swallowed. R35 Causes severe burns. R41 Risk of serious damage to eyes. R50 Very toxic to aquatic organisms.


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SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

Gardolene V 651 3 Version: 2 24.10.2007

1. IDENTIFICATION OF THE SUBSTANCElPREPARATlON AND OF THE COMPANYlUNDERTAKlNG


Commercial Product Name

Recommended use : Activating rinsing agent for metal surfaces before phosphating.

Gardolene V 651 3

Company: Chemetall plc Denbigh Road Bletchley Milton Keynes MKI 1 PB

Lead Organisation: Contact person: Telephone: 01908 649333 Telefax: 01908 373939


+49(0)69 7165 2292 [email protected]

I Emergency telephone: 01908 649333


Additional advice: Not a hazardous substance or preparation according to EC-directives 67/548/EEC or 19991451EC. The product does not need to be labelled in accordance with EC directives or respective national laws.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Mixture of inorganic salts.


not aDDliCable


General advice: Take off contaminated clothing and shoes immediately. Eye contact:

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SAFETY DATA SHEET iccording to Regulation (EU) No. 1907/2006

3ardolene V 651 3 /ersion: 2 24.10.2007

In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Skin contact: Wash off immediately with plenty of water. Inhalation: Provide fresh air. If symptoms persist, call a physician. Ingestion : Clean mouth with water and drink afterwards plenty of water. Call a physician immediately.


Suitable extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information: Use water spray to cool unopened containers. Standard procedure for chemical fires.


Personal precautions Wear personal protective equipment. Environmental precautions: Do not flush into surface water or sanitary sewer system. Methods for cleaning up: Sweep up or vacuum up spillage and collect in suitable container for disposal.

'. HANDLING AND STORAGE

Handling

Safe handling advice: Avoid dust formation. Advice on protection against fire and explosion: No special protective measures against fire required.

Storage

Requirements for storage areas and containers Keep container tightly closed in a dry and well-ventilated place. Further information: Keep in a dry place.

I. EXPOSURE CONTROLS I PERSONAL PROTECTION


no data available


Respiratory protection : Breathing apparatus only if aerosol or dust is formed. Hand protection : General advice: The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN 374 derived from it., The exact break through time can be

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SAFETY DATA SHEET iccording to Regulation (EU) No. 1907/2006

Sardolene V 651 3 lersion: 2 24.10.2007

obtained from the protective glove producer and this has to be observed.

Eye protection: Tightly fitting safety goggles Skin and body protection: Protective suit Hygiene measures Take off contaminated clothing and shoes immediately. Avoid contact wit.. the skin an( e eyes. Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and at the end of workday.


Form: Colour: Odour:

powder white odourless

Flash point:

Autoignition temperature:

not applicable

not self-inflammable

Explosive properties Lower explosion limit: no explosion risk

Bulk density:

Water solubility:

pH:

ca. 800 kglm3 at: 20 "C Method: DIN 53468

soluble

8.1 - 9.1 at: 10 gIL at: 20 "C


Conditions to avoid:

Avoid contact with amphoteric metals (e.g. aluminium, lead, zinc).

Materials to avoid:

Amphoteric metals are attacked developing hydrogen (combustible). Note: No decomposition if used as directed.


Skin irritation: May cause skin irritation in susceptible persons.

Eye irritation: Contact with eyes may cause irritation.

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Sensitisation: No sensitising effects are known.



Further information: slightly water endangering

Further information: Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.


Waste key for the unused product: 060300 wastes from the MFSU of salts and their solutions and metallic oxides

Product: Dispose of as special waste in compliance with local and national regulations.

Contaminated packaging: Dispose of as special waste in compliance with local and national regulations.

114. TRANSPORT INFORMATION I


Further information: Not a hazardous substance or preparation according to EC-directives 67/548/EEC or 1999/45/EC.The product does not need to be labelled in accordance with EC directives or respective national laws.

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16. OTHER INFORMATION


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safety data sheets · 2014-03-03 · company telephone telefax : chemetall ltd denbigh road...

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