safety and environmental risk assessments of industrial activities
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a report by
TNO
Sa f e t y a nd En v i r onmen ta l R i s k
A s s e s smen t s o f I n d u s t r i a l A c t i v i t i e s
Most research in this field is assigned by industries
working with dangerous chemicals. Activities include:
•
accident investigation;• process safety studies (hazard and operability study
(HazOp), layer of protection analysis (LOPA));
• reliability assessments (failure mode and effects
analysis (FMEA), failure mode effect and
criticality analysis (FMECA), fault-tree analyses);
• safety audits and second opinions;
• quantitative risk assessments (QRAs); and
• development and sale of safety-related software
tools.
A c c i d e n t I n v e s t i g a t i o n
Typically, an investigation would involve:
• a site visit – photographs and samples taken;
• retrieval of relevant schematics such as plant lay-
out, patent information and documentation
(PI&D) and operational procedures;
• interviews with personnel involved in the
accident (if possible);
• screening of maintenance history;
• preparation of fact-findings report;
• discussion and brainstorming session to identify
possible causes and to define further actions;• more in-depth interviews, analyses and/or
simulation to find evidence for assumptions;
• presentation of the findings to parties involved,
e.g. the board of management and/or
governmental institutions; and
• final reporting.
S a f e t y o f C h e m i c a l
P r o c e s s e s
HazOp
The HazOp method is a qualitative safety assessment
technique. The method entails the investigation of the
effects of deviations from the design intention for a
process facility. This is done by a team of experts in
different areas such as engineering, operations,
maintenance, safety and chemistry. The team is guided
in a structured brainstorming process, by a leader who
provides structure by using a set of guide-words to
examine deviations from normal process conditions at
various key points (nodes) throughout the process. The
guide-words are applied to the relevant processparameters (e.g. flow, temperature, pressure,
composition) in order to identify the causes and
consequences of deviations in these parameters from
their intended values. Finally, the identification of
unintended (or unacceptable) consequences results in
recommendations for improvement of the process.
These may comprise design modifications, procedural
requirements, modifications in documentation, further
investigations, etc.
LOPA
A more quantitative method to assess the safety of
processes is the LOPA. This method is based on the
identification of potential accident scenarios. A
particular scenario will only take place if certain
undesired initiating events (e.g. overpressure,
operator failure) occur and if layers of protection
(independent protection layers (IPL)) fail or are
absent. In LOPA, the following types of IPLs
are defined:
• process design;
•basic process control system (BPCS);
• critical alarms and human interventions;
• safety instrumented functions (SIF);
• safety instrumented systems (SIS) or emergency
shutdown (ESD);
• physical protection (relief devices);
• post-release physical protection (walls, dikes);
• plant emergency response; and
• community emergency response.
These IPLs are tailored to the prevention of scenarios
resulting from undesired process events (e.g. too high
pressure). In order to be able to deal with accidentscenarios that are a result of degradation mechanisms
(corrosion, erosion, fatigue), TNO added an extra
layer of protection immediately after ‘process design’
called ‘integrity’.
Proces s Sa fe ty for the Oi l and Gas Indus t ry
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A scenario is unleashed once an undesired, initiating
event has occurred (sometimes subject to enabling
conditions). Initiating events and enabling conditions
are assigned a probability of occurrence (in one year).
To prevent a scenario from occurring, only one layer
of protection is required. For a scenario to occur, all
IPLs should fail. In a LOPA all IPLs are assigned a
probability of failure on demand (PFD). Information
from other studies, in particular HazOps, is very
useful during a LOPA.
R e l i a b i l i t y A s s e s s m e n t , F M E ( C ) A a n d
F a u l t - t r e e A n a l y s i s
Reliability of a system or a component is determined
by its design, materials used, environment, operation
and maintenance, and can be expressed in measurable
units by the:
• average lifetime;
• average number of failures per unit of time
(frequency of failures);
• probability that a system, or a part of a system, will
function at a certain time point; and
• availability during a certain time period.
When assessing the reliability of a system, several
steps have to be taken such as:
• system description;
•
investigation of failure possibilities by FMEA or alternative procedure;
• determination of failure probabilities (by means of
event trees and fault trees or Markov modelling);
• analysis of critical items; and
• comparison of results with acceptance criteria.
The most challenging point in the reliability
assessment is the determination of failure
probabilities, especially if there is the possibility that
human error is involved. The approach in general is
to make use of (in order of preference):
• own data as generated by the system itself or
similar systems;
• own data for comparable systems;
• literature data; and
• expert judgement.
FME(C)A
FMEA, or FMECA, is alongside HazOp as one of
the most widely used techniques for screening a
design on possible failures or shortcomings under
practical circumstances. The difference between thetwo techniques is that FMECA is applied mostly on
systems, components or parts with a certain
function, while HazOp is used for processes. The
essence of FMEA is that for a system, or part of it,
the functions are defined. For each function the
possible failure modes are determined and
subsequently categorised on effect and/or
consequence, likelihood of occurrence and the
possibility of observation of the failure. The
magnitude of effect, likelihood and observation
possibility are ranked according to a system with
numbers that may vary from one to five or one to
10. The description of the ranking numbers is
mostly specific for a system. The analysis is carried
out by a team of experts, chaired and assisted by an
independent chairman and scribe respectively. The
result is a set of the so-called reverse polish notation
(RPN)-numbers, which are a multiplication of the
ranking numbers given for effect, likelihood and
observation. RPN-numbers with a value higher
than a pre-determined threshold should result in
actions to improve the design.
F a u l t - t r e e A n a l y s i s
Fault-tree analysis focuses on one particular accident
or main system failure (top event), and provides a
method for determining causes of that event. The
fault tree is a graphical model that displays the
various combinations of equipment failures (minimal
cut sets), dependent failures and human failures that
can result in the top event of interest. Boolean logic
rules are used to determine the minimal cut sets.
Quantification of the minimal cut sets is possible by
various means, e.g. direct estimation of the basicevent probability, kinetic theory, Markov processes
or Monte Carlo simulation. The construction of a
fault tree is carried out by means of standard symbols
such as ‘and gates’, ‘or gates’ and ‘basic events’. A
very large and complicated fault-tree can be analysed
by a dedicated computer program, which in practice
is seldom necessary.
S a f e t y A u d i t s a n d S e c o n d O p i n i o n s
TNO is frequently asked to perform second opinions
and safety audits. Required activities may varyconsiderably, depending on the questions to be
answered, but generally involve application of a
selection of the various ‘safety tools’ available at TNO,
some of which are described below. Again, if required,
expertise from other TNO institutes can be used.
• Second opinion on safety report or accident
prevention policy (document review), sometimes
involving recalculation of safety risks (QRAs).
• Evaluation of work procedures (document study
as well as observations on site).
• Safety assessment of installations (document and
drawings review, qualitative or quantitative
safety studies).
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Process Sa fe ty for the Oi l and Gas Industry
• Audit of safety management systems (document
review, interviews, questionnaires, observations,
Deming-circle evaluation).
Q u a n t i t a t i v e R i s k A s s e s s m e n t s a n d
S a f e t y - r e l a t e d S o f t w a r e
Industrial pollution control and industrial risk
management are major topics in the environmental
policy of the EU. Recent directives such as the
integrated Pollution Prevention and Control
directive (IPPC 96/61/EC) and Seveso II
(96/82/EC) are important examples of the
implementation of this policy. QRAs are often
important requirements under these regulations.
Typically, results of a QRA are applied to areas like:
•
environmental licences;• land-use planning – where extension of housing or
industry is possible and where it should be avoided;
• prioritising accident scenarios for which
emergency preparedness planning should be
considered; and
• prioritising possibilities for risk reduction.
TNO has developed several software products for this
purpose called EFFECTS, DAMAGE, RISK-
CURVES, FACTS and FRIENDS.
EFFECTS
Directives like Seveso II in the EU and US
Department of Labor Occupational Safety and Health
Administration (OSHA) guidelines in the US require
the assessment of the potential impact of releases of
flammable or toxic substances. TNO has responded
to this need by developing EFFECTS, a program that
comprises up-to-date models for the quantification of
physical behaviour after the release of both flammable
and toxic materials. The danger of a release of
hazardous materials is ever-present in the chemical
and petrochemical industry and in oil and gasproduction installations and chemical product storage.
Predicting the effects of such releases can be of vital
importance to people, companies, authorities and
emergency response organisations. A geographic
information system (GIS) functionality has recently
been implemented in the EFFECTS software.
DAMAGE
When hazardous materials are released into the
environment, they can cause damage to people and
properties. TNO’s software tool DAMAGE predictsthe consequences of these releases. It is developed for
all those who are responsible for safe handling and
storage of dangerous goods. DAMAGE contains
models for heat radiation, explosions and toxic effects.
RISKCURVES
Expanding industrial operations and densely
populated areas, sometimes close to an industrial
site, increases the need for tailor-made risk
assessments and risk evaluations. For more than a
decade RISKCURVES has been, and still is, the
leading software tool to perform complex QRAs.
RISKCURVES contains many features and
options such as individual, societal and transport
risk calculations, analyses of these risks, links to and
from geographical information systems (GIS), risk
contours, report generator etc. Based on the
Yel low and Green Books, RISKCURVES
provides a sound scientific basis to perform QRAs.
FACTS
In the late 1970s, TNO created FACTS, a databasecontaining information about serious industrial
accidents involving hazardous materials which
caused, or could have caused, severe damage and
danger. The information stored in FACTS is
obtained from professional sources, such as
accident reports made by companies, government
agencies or from publications in technical
periodicals and other literature. Of course,
information from a number of sources is
confidential. TNO treats this information with
strict anonymity.
FACTS is the most comprehensive database of its
kind available on the market today. More than
18,000 accidents recorded in FACTS are available
for the purpose of risk analyses, risk and safety
management, damage prevention, emergency
response and training. You can also select accidents
that occurred during activities or processes similar
to those performed in your own company or
organisation. Lessons learned from the past now
help to improve actual safety.
FRIENDS
FRIENDS is a handy mini database on CD-ROM
offering summaries of more than 18,000 industrial
accidents with hazardous materials. The summaries
contain information such as the involved
chemicals, the (type of) location, the activity, the
year of occurrence the number of injuries and
fatalities, etc. FRIENDS contains a powerful
database explorer that optimises the selection
process for accident information by specifying
simple or highly complex search profiles.
The result is that FRIENDS gives a customised
summary of accidents, which is needed for analysis,
training or prevention purposes. FRIENDS is
updated yearly.
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Re s ea r ch and
Dev e l opmen t
Currently, research and development (R&D) is
focused on:
• improvement of QRA effect models;
• improvement of safety and emergency prepared-
ness in tunnels and underground structures;
• integration of technical and organisational safety
assessments;
• integration of safety with business; and
• assessment of the reliability and the proper
functioning of software in safety instrumented
systems. ■
For further information about TNO, please e-mail:
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