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111 Star Lane Casper, WY 82604 Tel: 307-268-4304 Fax: 609-259-8288
S O V E R E I G N C O N S U L T I N G I N C .
May 14, 2018
Mr. Roland Peterson Wyoming Department of Environmental Quality WYPDES Permitting Water Quality Division 200 W. 17th Street Cheyenne, Wyoming 82002
Subject: WYPDES Industrial Operations, Form G Permit Application WY0048810 Renewal BP Former Refinery, Casper, Wyoming
Dear Mr. Peterson,
Sovereign Consulting Inc. (Sovereign), on behalf of Remediation Management Services Company, a BP affiliated company, is submitting the Industrial Operations, Form G permit application to renew coverage under permit WY0048810. The current permit will expire November 30, 2018.
If you have any questions, please feel free to contact me at (307) 261-4211.
Sincerely,
Jameson Bell Project Engineer [email protected]
Enclosures: Industrial Operations, Form G Permit Application for WY0048810
cc: Sasa Jazic, BP Matt Buchholz, WDEQ
File: Kitty Thomson, Arcadis (Site)
Wyoming Pollutant Discharge Elimination System (WYPDES) Department of Environmental Quality Application for Permit to Discharge Wastewater for:
Industrial operations, Form G April 2017
1. Check the box corresponding to the type of application being applied for:
New
Renewal Major modification Permit number: __WY0048810__________ Expiration Date: ___November 30, 2018_____ 2. General Facility Location: Township(s): ___33N__________________ Range(s) __79W__________________
3. Facility Street address if applicable: __1707 King Boulevard, Casper, Wyoming 82604__________________
4. Receiving Waters __Three Crowns #2, Three Crowns Golf Course (Class 4A water); North Platte River Basin_
5. Name of the facility producing the discharge _____BP Former Refinery_________________________________________________________________________________ 6. Standard Industrial Classification code (SIC Code): _5171 (Petroleum Bulk Station) and 4952 (Wastewater Treatment Plants) and
primary industrial category, per Table I, Appendix B (If Applicable): __no primary industrial category 7. Permittee and Consultant (if applicable) Contact Information: Permittee Contact Name Sasa Jazic
Consultant Contact Name Jameson Bell
Company Name Remediation Management Services Company (a BP affiliated company)
Company Name Sovereign Consulting, Inc.
Mailing Address 150 Warrenville Rd, MC 200-1N
Mailing Address 111 Star Lane
City, State, and Zip Code Naperville, IL 60563
City, State, and Zip Code Casper, WY 82604
Telephone Number 630-386-1620
Telephone Number 307-261-4211
E-Mail Address [email protected]
E-Mail Address [email protected]
Preference for contact: [email protected]
Preference for contact: [email protected]
Please print or type. Submission of illegible materials will result in return of the application to the
applicant.
All items must be completed accurately and in their entirety or the application will be deemed
incomplete and the processing will be delayed or application returned.
An original signature of the applicant is required. Faxes cannot be accepted.
Official Use only Date Received:
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8. Status of applicant: Federal State private public Other ________________
9. Status of applicant (check more than one): Owner Operator
10. Please include a brief description of the nature of the business conducted at this facility and principal products or services provided by the facility.
The facility was formerly a petroleum refinery. Following cessation of operation in 1991, the refinery was decommissioned and there are no plans to restart the refinery operation. The property was redeveloped since that time to include a golf course, a business park, and open land available to public access. Groundwater remediation activities conducted at the property generate water that is treated prior to discharge.
11. Please describe each type of process, operation or production area that contributes wastewater to the effluent for each outfall and the
average flow which each process contributes.
Groundwater recovered from a system of recovery wells is treated in the existing on-site treatment system prior to discharge. Oil recovered from these wells is stored at the site prior to shipping to an off-site recovery/refining facility. The average groundwater pumping rate is 1.1 MGD, while the average oil recovery rate is 550 GD.
12. Please include a brief description of the wastewater treatment at the facility, including the ultimate disposal of any solid or liquid wastes other than by discharge. The existing on-site treatment system consists of an oil/water separator, cascade aerator/air stripper, surface flow wetlands, subsurface flow wetlands, and several golf course storage ponds. Recovered oil from these wells is stored in above ground storage tanks prior to shipping to an off-site recovery/refining facility. Bio-solids that accumulate in the oil/water separator are collected and are dried at the POTW and later disposed of at the City of Casper Regional Solid Waste Facility. Surface flow wetland ponds are occasionally dredged to remove the buildup of precipitated iron and bio-solids; material is dried at the POTW and later disposed of at the City of Casper Regional Solid Waste Facility.
13. For new facilities, the expected date of commencement of discharge. ___________________________________________
For existing facilities, provide actual flow data from each outfall within the last six months Will discharge be continuous or intermittent? If the discharge is to be intermittent the following information for each outfall shall be provided: (I) Number of times per year the discharge is to occur. (II) Anticipated duration of each discharge. (III) Anticipated flow of each discharge. (IV) Months in which discharge is expected to occur.
Outfall 001 – Historical Flow Data
Date Flow (MGD) Date Flow (MGD) Date Flow (MGD)
07//05/2017 1.05 09/25/2017 1.29 12/11/2017 1.01
07/10/2017 1.12 10/02/2017 1.09 12/18/2017 1.10
07/17/2017 1.11 10/09/2017 1.25 12/26/2017 0.96
07/24/2017 1.20 10/16/2017 0.95 01/02/2018 0.82
08/07/2017 1.18 10/23/2017 1.02 01/04/2018 0.94
08/15/2017 1.21 10/30/2017 1.01 01/08/2018 1.01
08/22/2017 1.51 11/06/2017 1.08 01/15/2018 0.97
08//28/2017 1.23 11/13/2017 0.99 01/22/2018 0.87
09/05/2017 1.04 11/20/2017 0.97 01/29/2018 1.05
09/11/2017 1.13 11/27/2017 1.05 02/08/2018 1.19
09/18/2017 1.20 12/05/2017 1.02 02/12/2018 1.21
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14. If requesting modification of existing permit, describe modification requests:
Selenium is a common element found in shallow geologic formations in Natrona County, and the presence of selenium in compliance samples at Outfall 001 is not necessarily related to historical refinery operation. For these reasons, it is requested that selenium not be listed as a required sampling parameter.
b. For each change or improvement, provided projected dates, as accurately as possible, for completion of each step listed below:
�� Begin Construction: ____________________________ �� End Construction: ______________________________ �� Begin Discharge: ______________________________ �� Operational Level Attained:_______________________
Landowner or lessee’s contact information (additional spaces may be added as necessary):
Landowner #1 Name BP Products North America Inc.
Landowner #2 Name
Mailing Address 150 Warrenville Rd, MC 200-1N
Mailing Address
City, State, and Zip Code Naperville, IL 60563
City, State, and Zip Code
b. Access Route: As part of the application, the applicant shall certify under penalty of perjury that the applicant has secured and
shall maintain permission for Department of Environmental Quality personnel and their invitees to access the permitted facility, including (i) permission to access the land where the permitted facility is located, (ii) permission to collect resource data as defined by Wyoming Statute § 6-3-414, and (iii) permission to enter and cross all properties necessary to access the permitted facility if the facility cannot be directly accessed from a public road. A map of access route(s) to the facility shall accompany the application.
15. Facility Flow Diagram:
Please provide a schematic line drawing showing the water flow and water balance through the facility. The water balance must show approximate average flows at intake and discharge points and between units, including treatment units. If a water balance cannot be determined, a pictorial description of the nature and amount of any sources of water and any collection and treatment measures may be provided. Note the following example: The facility flow diagram is shown on Figure 1—Water Treatment System. In 2007, the blowers on the cascade aerator were shut down as low influent VOC and benzene concentrations did not require stripping prior to subsequent treatment in the surface and subsurface flow wetlands. The WDEQ Air Quality Division agreed with this change and influent water samples continue to be collected to ensure compliance with air permit waiver AP-5T2 which covers air emissions from the cascade aerator, surface flow wetlands, and subsurface flow wetlands. 16. Outfall location: Complete the attached Appendix A, Table 1.
17. Outfall Characterization: Complete the attached Appendix A, Table 2. See application instructions for details.
a. Will any flocculants (settling agents or chemical additives) be used to treat water prior to discharge?
YES NO
If yes, list here the chemical name, manufacture, and purpose. Include MSDS sheets. Currently used chemicals include: Phycomycin SCP, Advantis Technologies, Inc., an algaecide used for spring, summer, and fall algal control in wetlands; prior to use WDEQ was notified. The following three plant based cleaners are used at various stages in the water treatment system to control bio-fouling and algal growth. The manufacturer of each product is Green Earth Technologies. Prior to use WDEQ was notified.
1) Casing Cutter – Used to clean and control bio-fouling. 2) OSC-1809 – Used to clean and control bio-fouling (surface wash cleaner). 3) Colloidal Algae Control – Algae control.
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Although not used for water treatment, two herbicides are applied to aquatic vegetation in the ponds of the water treatment system. Prior to use WDEQ was notified.
1) Roundup Custom for Aquatic and Terrestrial Use, manufactured by Monsanto Company – Used to permanently eliminate aquatic vegetation in the ponds of the water treatment system.
2) Reward Landscape and Aquatic, manufactured by Syngenta – Used to remove foliage from aquatic plants. Attachment I includes documentation demonstrating that use of the algaecides, bio-based cleaners and herbicides is not expected to adversely impact water quality at the discharge outfall. Safety Data Sheets for the chemicals listed above are also included in Attachment I.
18. Please complete Appendix A, Tables 2 and 3 for each outfall.
19. Complete Appendix A, Table 4 only if you are required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operations of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application. Not Applicable.
20. Facility map: Attach a description and a clear, legible, detailed topographic map of the discharging facility that extending one mile beyond the property boundaries of the source. Include the following: a. A legend b. Well locations where fluids from the facility are injected underground c. Retention Ponds d. Each intake sites e. Discharge points (outfalls) f. Monitoring and/or compliance points g. Hazardous waste treatment, storage, or disposal facilities h. Immediate receiving streams i. Section, Township, and Range information j. Wells, springs, other surface water bodies, drinking water wells, and surface water intake structures listed in public records, or
otherwise known to the applicant in the map area. k. Location of treatment facilities l. Access Routes See Figure 2 – Water Treatment System Process, Site Plan and Figure 3 – Topo Area Map.
21. Describe the control measures that will be implemented to prevent significant damage to or erosion of the receiving water channel at
the outfall(s)_The outfall is a HDPE lined pond on the Three Crowns Golf Course. Discharge point to the North Platte River is directly to water body, even during low flow conditions, and thus energy is dissipated by the receiving water body.
22. Production:
a. Does an effluent guideline limitation or standard apply to your facility (e.g. metal finishing, fertilizer manufacturing, etc) as stated under Section 306 of the Clean Water Act? (Contact Wyoming DEQ with questions)
YES (complete item 21B below) NO
b. Are the limitations in the applicable effluent guideline express in terms of production or other measure of operation? (In Wyoming, primarily petroleum refining and cheese production)
YES (complete table below) NO
Affected outfalls Quantity per day* Units of Measure Specify Operation, Product,
or Materials
*For new facilities and outfalls, please provide a reasonable measure of expected production. For existing facilities or outfalls, please provide a measure of actual production.
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23. If applicable, provide a list of any toxic pollutants which the applicant currently uses or manufactures as an intermediate or final
product or byproduct. Not Applicable
24. Effluent Characterization
All water quality samples shall be taken as grab samples and analyzed in accordance with 40 CRF Part 136 unless use of another method is required for the pollutant under 40 CFR Subparts N and O.
All applicants must analyze and submit the results for the constituents listed below (see Table 1, Appendix B).
Biochemical Oxygen Demand (BOD5) Ammonia (as N) Chemical Oxygen Demand Temperature Total Organic Carbon pH
Total Suspended Solids Color of Discharge
Primary Industries:
A primary industry is any industry listed under the Primary Industrial Category in Appendix B, Table II. If you are a primary industry (refer to Appendix B, Table II), samples must be collected for all fractions identified in Appendix B, Table I. For Appendix B, Tables IIA – III, mark “X” in the Required Testing column for each fraction related to your industry and provide the sample result. Sample results must be provided for each outfall that has the potential to discharge process wastewater. For Appendix B, Table IV, mark “X” in column “Believed Present” for each pollutant you know or have reason to believe is present. Mark “X” in column “Believed Absent” for each pollutant you believe is absent. If an applicable federal effluent limitations guideline limits the pollutant through permit effluent limitations, the applicant must report quantitative data. For every pollutant discharged which is not so limited in an effluent limitations guideline, the applicant must either report quantitative data or briefly describe the reasons the pollutant is expected to be discharged. For Appendix B, Table V, circle the pollutants you know or have reason to believe are present. For every pollutant from Table V expected to be discharged, from each outfall, provide a brief description of the reasons the pollutant is expected to be discharged, and report any quantitative data you may have.
Base your determination of whether a pollutant will be present in your discharge on your knowledge of the facility’s raw materials, maintenance chemicals, intermediate and final products, byproducts, and any analyses of your effluent or of any similar effluent. You may also provide the determination and the estimates based on available in-house or contractor’s engineering reports or any other studies performed on the facilities.
Secondary Industries:
A secondary industry is an industry that is not listed under the primary Industrial Category in Appendix B, Table II.
For Appendix B, Tables IIA – III, mark “X” in column “Believed Present” for each pollutant you know or have reason to believe is present. Mark “X” in column “Believed Absent” for each pollutant you believe is absent. If you mark column “Believed Present” for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column “Believed Present” for acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4, 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column “Believed Present”, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. For Appendix B, Table IV, mark “X” in column “Believed Present” for each pollutant you know or have reason to believe is present. Mark “X” in column “Believed Absent” for each pollutant you believe is absent. If an applicable federal effluent limitations guideline limits the pollutant through permit effluent limitations, the applicant must report quantitative data. For every pollutant discharged which is not so limited in an effluent limitations guideline, the applicant must either report quantitative data or briefly describe the reasons the pollutant is expected to be discharged. For Appendix B, Table V, circle the pollutants you know or have reason to believe are present. For every pollutant from Table V expected to be discharged, from each outfall, provide a brief description of the reasons the pollutant is expected to be discharged, and report any quantitative data you may have.
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Base your determination of whether a pollutant will be present in your discharge on your knowledge of the facility’s raw materials, maintenance chemicals, intermediate and final products, byproducts, and any analyses of your effluent or of any similar effluent. You may also provide the determination and the estimates based on available in-house or contractor’s engineering reports or any other studies performed on the facilities.
For New Industrial Facilities:
For Appendix B, Tables IIA – IV, mark “X” in column “Believed Present” for each pollutant you know or have reason to believe is present. Mark “X” in column “Believed Absent” for each pollutant you believe is absent. For each pollutant marked as “Believed Present” provide an estimated daily maximum concentration in the “Water Sample Results” column.
For Appendix B, Table V, circle the pollutants you know or have reason to believe are present (no estimated daily maximum concentrations are required).
Base your determination of whether a pollutant will be present in your discharge on your knowledge of the facility’s raw materials, maintenance chemicals, intermediate and final products, byproducts, and any analyses of your effluent or of any similar effluent. You may also provide the determination and the estimates based on available in-house or contractor’s engineering reports or any other studies performed on the facilities.
Each applicant must report the existence of any technical evaluation concerning the wastewater treatment that will be utilized, along with the name and location of similar plants, if information is available.
25. Use Appendix B, Table VI to list any of the pollutants, for which you are not required to submit a water quality analysis, listed in
Appendix B, Tables II – V below which you know or have reason to believe is discharged or may be discharged from any outfall. For every pollutant you list, briefly describe the reasons you believe to be present and report any analytical data in your possession.
26. Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your
discharges or on receiving water in relation to your discharge within the last three years?
YES NO
If yes, identify the tests and describe their purpose below: ______________________________________________________________________________________________________________________________________________________________________________________________________
27. Dioxin testing: Each applicant for existing facilities must report qualitative data, generated using a screening procedure not
calibrated with analytical standards for 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) if it : Not Applicable
i. Used or manufactures 2,4,5-trichlorophenoxy acetic acid (2,4,5,-T), 2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex, 2,4,5,-
TP); 2-(2,4,5-tricholorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothioate; 2,4,5-trichlorophenol (TCP); or hexachlorophene (HCP); or
ii. Knows or has reason to believe that TCDD is or may be present in an effluent. iii. Applicants for new facilities must report if 2,3,7,8 Tetrachlorodibenzo-P-Dioxin (TCDD) may be discharged if any of the
pollutants defined in 31.i above are used or manufactured or if there is reason to believe that TCDD will or may be present in the effluent.
28. For applications for existing facilities, has the facility ever exceeded permit limits or water quality standards?
YES NO
If yes,
a. Which constituents? Total Suspended Solids (TSS), dissolved iron and total recoverable selenium
b. Has the exceedance been addressed? Yes, exceedances have been addressed.
c. Describe how the exceedance was addressed. Two exceedances of weekly average TSS occurred prior to the permit WY0048810 renewal in 2014 with no exceedances since 2014. The two TSS exceedances were a result of golf course maintenance activities and algal die off in the golf course ponds. Preventive measures to avoid reoccurrences include ongoing coordination with golf course management to ensure maintenance activities are performed appropriately and Phycomycin (chemical approved by WDEQ) is used appropriately to control algae blooms in the water treatment system. There were no iron exceedances after the permit WY0048810 renewal in 2014. The dissolved iron exceedance in April 2013 is believed to be erroneous. Sampling and handling protocols were reviewed to ensure the issue does not
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reoccur. In addition, quality control procedures associated with received laboratory analytical results were revised, per exceedance letter dated 7/11/13. Total recoverable selenium concentration exceeded the permit limit on December 5, 2017. Selenium was below the permit limit in January and February 2018. BP is working with the City of Casper – Publicly Owned Treatment Works to divert discharge from a group of recovery wells to the POTW sanitary sewer.
d. If the facility has never discharged or has not yet been constructed, please indicate below.
YES NO
Report the existence of any technical evaluation concerning the applicant’s wastewater treatment, along with the name and location of similar plants. ___Not applicable for existing facilities
29. Other information: Any optional information the permittee wishes to have considered: Please note Table 1B is added to show
historical effluent characteristics for parameters listed on the current discharge permit.
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Appendix A, Outfall Characterization
TABLE 1: Outfall Location Information
Discharge Point (Outfall)
#
Quarter/ Quarter
Section Township Range
Latitude (NAD 83, decimal
degrees accurate to a
minimum of 5 decimal places)
North
Longitude (NAD 83, decimal
degrees accurate to a minimum of 5
decimal places) West
Immediate Receiving
Stream
Mainstem (closest perennial water)
County
001 SENW 8 33N 79W 42.843093 106.338626
Discharge point: Three Crowns #2, Golf Course Pond
North Platte River
Natrona
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Appendix A, Narrative Outfall Descriptions
Table 2, Narrative Outfall Descriptions
Outfall number
Final Treatment Unit
Water Source #1 Water Source #2 Water Source #3
Indicate if outfall discharge is:
A. Continuous B. Intermittent
C. Seasonal D. No Discharge
(indicate one for each outfall)
Treatment (Description or List codes from “Wastewater Treatment Codes”, Next Page)
(example) 001 Bottom Ash
Settling Pond Bottom Ash Runoff Floor Drain Runoff
Metal Cleaning Wastewater
Continuous 1-U, 4-A
001 Constructed Wetlands and Ponds
Recovered groundwater
Stormwater entering water treatment system at golf course (intermittent source)
A-Continuous Oil/Water Separation Air Stripping – Cascade Aerator 2-B Chemical Oxidation 2-C Chemical Precipitation 1-U Sedimentation Biological Treatment—Constructed Wetlands & Ponds 4-A Discharge to Surface Water 5-Q-Landfill
Additional spaces/tables may be included as necessary. Use the format provided.
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Wastewater Treatment Codes
PHYSICAL TREATMENT PROCESSES 1–A. . . . . . . . . . Ammonia Stripping 1–M . . . . . . . . . . Grit Removal 1–B . . . . . . . . . . Dialysis 1–N . . . . . . . . . . Microstraining 1–C . . . . . . . . . . Diatomaceous Earth Filtration 1–O . . . . . . . . . . Mixing 1–D . . . . . . . . . . Distillation 1–P . . . . . . . . . . . Moving Bed Filters 1–E . . . . . . . . . Electrodialysis 1–Q. . . . . . . . . . . Multimedia Filtration 1–F . . . . . . . . . Evaporation 1–R . . . . . . . . . . Rapid Sand Filtration 1–G . . . . . . . . . . Flocculation 1–S . . . . . . . . . . . Reverse Osmosis (Hyperfiltration) 1–H . . . . . . . . . . Flotation 1–T . . . . . . . . . . . Screening 1–I . . . . . . . . . . Foam Fractionation 1–U . . . . . . . . . . Sedimentation (Settling) 1–J . . . . . . . . . . Freezing 1–V . . . . . . . . . . . Slow Sand Filtration 1–K . . . . . . . . . . Gas–Phase Separation 1–W . . . . . . . . . . Solvent Extraction 1–L . . . . . . . . . . Grinding (Comminutors) 1–X . . . . . . . . . . . Sorption
CHEMICAL TREATMENT PROCESSES 2–A . . . . . . . . . . Carbon Adsorption 2–G . . . . . . . . . . Disinfection (Ozone) 2–B . . . . . . . . . . Chemical Oxidation 2–H . . . . . . . . . . Disinfection (Other) 2–C . . . . . . . . . . Chemical Precipitation 2–I . . . . . . . . . . . Electrochemical Treatment 2–D . . . . . . . . . . Coagulation 2–J . . . . . . . . . . . Ion Exchange 2–E . . . . . . . . . . Dechlorination 2–K . . . . . . . . . . . Neutralization 2–F . . . . . . . . . . Disinfection (Chlorine) 2–L . . . . . . . . . . . Reduction
BIOLOGICAL TREATMENT PROCESSES 3–A . . . . . . . . . . Activated Sludge 3–E . . . . . . . . . . . Pre-Aeration 3–B . . . . . . . . . . Aerated Lagoons 3–F . . . . . . . . . . . Spray Irrigation/Land Application 3–C . . . . . . . . . . Anaerobic Treatment 3–G . . . . . . . . . . Stabilization Ponds 3–D . . . . . . . . . . Nitrification–Denitrification 3–H . . . . . . . . . . Trickling Filtration
OTHER PROCESSES 4–A . . . . . . . . . . Discharge to Surface Water 4–C . . . . . . . . . . Reuse/Recycle of Treated Effluent 4–B . . . . . . . . . . Ocean Discharge Through Outfall 4-D . . . . . . . . . . . Underground Injection
SLUDGE TREATMENT AND DISPOSAL PROCESSES 5–A . . . . . . . . . . Aerobic Digestion 5–M . . . . . . . . . . Heat Drying 5–B . . . . . . . . . . Anaerobic Digestion 5–N . . . . . . . . . . Heat Treatment 5–C. . . . . . . . . . Belt Filtration 5–O . . . . . . . . . . Incineration 5–D. . . . . . . . . . Centrifugation 5–P . . . . . . . . . . . Land Application 5–E . . . . . . . . . . Chemical Conditioning 5–Q . . . . . . . . . . Landfill 5–F . . . . . . . . . . Chlorine Treatment 5–R . . . . . . . . . . Pressure Filtration 5–G . . . . . . . . . . Composting 5–S . . . . . . . . . . Pyrolysis 5–H . . . . . . . . . . Drying Beds 5–T . . . . . . . . . . Sludge Lagoons 5–I. . . . . . . . . . . Elutriation 5–U . . . . . . . . . . Vacuum Filtration 5–J . . . . . . . . . . Flotation Thickening 5–V . . . . . . . . . . Vibration 5–K . . . . . . . . . . Freezing 5–W . . . . . . . . . . Wet Oxidation 5–L . . . . . . . . . . Gravity Thickening
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Appendix A, Discharge Rates
Table 3, Discharge Rates
For Continuously Discharging outfalls
For Non-Continuous Discharging Outfalls
Outfall Number #
Average Daily Discharge (MGD)
Number of times per year the discharge is
to occur
Anticipated duration of each discharge
Anticipated flow of each discharge (MGD)
Months in which discharge is expected to occur.
001 1.10
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Appendix A, Improvements
TABLE 4: Improvements Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operations of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant or loan conditions.
1. Affected outfalls 2. Identification of condition, agreement, etc.
3. Brief description of project
4. Final Compliance Date
Outfall Source of discharge A. Required B. Projected
Not Applicable
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Appendix B, Table I
Table I: Effluent Characteristics per outfall You must provide the results of at least one analysis for every pollutant in this table for each outfall.
Outfall #___001______ Maximum Daily Value
Maximum 30-day value
(if available)
Long term average value (Jan 2014 – Feb 2018) Number of Analyses
Parameter Mass Concentration Mass Concentration Mass Concentration
Biochemical Oxygen Demand (BOD)
58.0 lb/day
1.0 mg/L1
4.6 mg/L (DUP)2 1
Total Suspended Solids (TSS) 440 lb/day 35 mg/L (Dec 2015) 213 lb/day 23.4 mg/L (Dec 2015) 69.0 lb/day 7.58 mg/L 213
Total Organic Carbon (TOC) 94.5 lb/day 7.5 mg/L 1
Chemical Oxygen Demand (COD) 402 lb/day 31.9 mg/L 1
Ammonia (as N) 2.14 lb/day 0.17 mg/L 1
Flow, discharge, MGD Value: 1.51 MGD (8/22/17) Value: Value 1.10 MGD 163
pH (range) S.U. Max: 8.35 (7/7/14) Min: 7.38 (12/8/14) Max Min Not Applicable 49
Temperature (Winter) °C Value: 10.97 (Oct. – Mar.) Value Value 6.08 10
Temperature (Summer) °C Value: 24.4 (Apr. – Sept.) Value Value 16.97 11
Color of Discharge Value: 20 standard units 1
Table IB: Effluent Characteristics of Currently Permitted Constituents
Outfall #___001______ Maximum Daily Value
Maximum 30-day value (if available)
Long term average value
(Jan 2014 – Feb 2018) Number of Analyses
Parameter Concentration Concentration Concentration Benzene 0.5 µg/L1 0.5 µg/L1 50
Dissolved Iron 210 µg/L 31.8 µg/L 50
pH 8.35 Range: 7.38 to 8.35 49
Specific Conductance 4030 (µS/cm) 2966 (µS/cm) 50
Benzene, Ethylbenze, Toluene, Xylene (BTEX) 0.5 µg/L1 0.5 µg/L1 50
Total Petroleum Hydrocarbons (TPH) 8.7 mg/L 2.7 mg/L 51
Total Recoverable Selenium 5.6 µg/L 2.12 µg/L 50
Total Suspended Solids 35 mg/L 23.4 mg/L 7.58 mg/L 213
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1 Consistent with EPA methods which reference the American Chemical Society Committee on Environmental Improvement, non-detectable data is represented by a value that is half of the detection limit.
2 Value of sample and duplicate for Biochemical Oxygen Demand (BOD) reported in Table I. The maximum value is used for mass loading.
Analytical reports are found in Attachment II.
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Appendix B, Table II
Table II--Testing Requirements for Toxic Pollutants by PRIMARY INDUSTRIAL CATEGORY
Organic Toxic Pollutants GS/MS Fraction (listed in Table IIA-Table IID)
Other Toxic Pollutants (Listed in Table III)
PRIMARY INDUSTRIAL CATEGORY Volatile See Table IIA
Acid See Table IIB
Base/Neutral See Table IIC
Pesticides See Table IID
(Metals and Cyanide) and Total Phenols
Adhesives and Sealants........... X X X NR X Aluminum Forming................. X X X NR X Auto and Other Laundries......... X X X X X Battery Manufacturing............ X NR X X X Coal Mining...................... X X X NR X Coil Coating..................... X X X X X Copper Forming................... X X X NR X Electric and Electronic Components X X X X X Electroplating................... X X X NR X Explosives Manufacturing......... NR X X NR X Foundries........................ X X X NR X Gum and Wood Chemicals........... X X X X X Inorganic Chemicals Manufacturing X X X NR X Iron and Steel Manufacturing..... X X X NR X Leather Tanning and Finishing.... X X X X X Mechanical Products Manufacturing X X X NR X Nonferrous Metals Manufacturing.. X X X X X Ore Mining....................... X X X X X Organic Chemicals Manufacturing.. X X X X X Paint and Ink Formulation........ X X X X X Pesticides....................... X X X X X Petroleum Refining............... X X X X X Pharmaceutical Preparations...... X X X NR X Photographic Equipment and Supplies........................ X X X X X Plastic and Synthetic Materials Manufacturing................... X X X X X Plastic Processing............... X NR NR NR X Porcelain Enameling.............. X NR X X X Printing and Publishing.......... X X X X X Pulp and Paper Mills............. X X X X X Rubber Processing................ X X X NR X Soap and Detergent Manufacturing. X X X NR X Steam Electric Power Plants...... X X X NR X Textile Mills.................... X X X X X Timber Products Processing....... X X X X X X = testing is required NR =testing is not required unless believed to be present.
Page 17 of 23
Appendix B, Table IIA
1 Consistent with EPA methods which reference the American Chemical Society Committee on Environmental Improvement, non-detectable
data is represented by a value that is half of the detection limit.
Notes: In tables IIA-VI, if an average constituent concentration is provided, the number of analyses used to determine the average will be noted in parentheses.
Table IIA VOLATILE COMPOUNDS (Complete table and include lab reports if applicable) Organic Toxic Pollutants
GS/MS Fraction Pollutant Mark with “X” Water Sample
Result (if required)
Required Testing
Believed Absent
Believed Present
1 V acrolein X 2 V acrylonitrile X 3 V benzene X 0.5 ug/L1 (50) 4V. Bis (Chloromethyl) Ether (542-88-1) X 5 V bromoform X 6 V carbon tetrachloride X 7 V chlorobenzene X 8 V chlorodibromomethane X 9 V chloroethane X 10 V 2-chloroethylvinyl ether X 11 V chloroform X 12 V dichlorobromomethane X 13V. Dichlorodifluoromethane (75-71-8)
X
14 V 1,1-dichloroethane X 15 V 1,2-dichloroethane X 16 V 1,1-dichloroethylene X 17 V 1,2-dichloropropane X 18 V 1,3-dichloropropylene X 19 V ethylbenzene X 0.5 ug/L1 (2)
20 V methyl bromide X 21 V methyl chloride X 22 V methylene chloride X 23 V 1,1,2,2-tetrachloroethane X 24 V tetrachloroethylene X 25 V toluene X 0.5 ug/L1 (2)
26 V 1,2-trans-dichloroethylene X 27 V 1,1,1-trichloroethane X 28 V 1,1,2-trichloroethane X 29 V trichloroethylene X 30V. Trichlorofluoromethane (75-69-4)
X
31 V vinyl chloride X
Page 18 of 23
Appendix B, Table IIB
Table IIB ACID COMPOUNDS (Complete table and include lab reports if applicable) Organic Toxic Pollutants
GS/MS Fraction Mark with “X”
Water Quality Results Pollutant Required
Testing Believed Absent
Believed Present
1A 2-chlorophenol X 2A 2,4-dichlorophenol X 3A 2,4-dimethylphenol X 4A 4,6-dinitro-o-cresol X 5A 2,4-dinitrophenol X 6A 2-nitrophenol X 7A 4-nitrophenol X 8A p-chloro-m-cresol X 9A pentachlorophenol X 10A phenol X 11A 2,4,6-trichlorophenol X
Appendix B, Table IIC
Table IIC-BASE/NEUTRAL COMPOUNDS (Complete table and include lab reports if applicable) Organic Toxic Pollutants
GS/MS Fraction Pollutant Mark with “X” Water Sample
Results(if required)
Required Testing
Believed Absent
Believed Present
1 B acenaphthene X 2 B acenaphthylene X 3 B anthracene X 4 B benzidine X 5 B benzo(a)anthracene X 6 B benzo(a)pyrene X 7 B 3,4-benzofluoranthene X 8 B benzo(ghi)perylene X 9 B benzo(k)fluoranthene X 10B. Bis (2-Chloroethoxy) Methane X 11 B bis(2-chloroethyl)ether X 12 B bis(2-chloroisopropyl)ether X 13 B bis (2-ethylhexyl)phthalate X 14 B 4-bromophenyl phenyl ether X 15 B butylbenzyl phthalate X 16 B 2-chloronaphthalene X 17 B 4-chlorophenyl phenyl ether X 18 B chrysene X 19 B dibenzo(a,h)anthracene X 20 B 1,2-dichlorobenzene X 21 B 1,3-dichlorobenzene X 22 B 1,4-dichlorobenzene X 23 B 3,3'-dichlorobenzidine X 24 B diethyl phthalate X 25 B dimethyl phthalate X 26 B di-n-butyl phthalate X 27 B 2,4-dinitrotoluene X 28 B 2,6-dinitrotoluene X
Page 19 of 23
Table IIC-BASE/NEUTRAL COMPOUNDS (Complete table and include lab reports if applicable) Organic Toxic Pollutants
GS/MS Fraction Pollutant Mark with “X” Water Sample
Results(if required)
Required Testing
Believed Absent
Believed Present
29 B di-n-octyl phthalate X 30B. 1,2-Diphenylhydrazine (as Azobenzene) X 31B. Fluoranthene (206 X 32B. Fluorene X 33B. Hexachlorobenzene X 34B. Hexachlorobutadiene X 35B. Hexachlorocyclopentadiene X 36B Hexachloroethane X 37B. Indeno X 38B. Isophorone X 39B. Naphthalene X 2.5 ug/L1 (2) 40B. Nitrobenzene X 41B. N-Nitrosodimethylamine X 42B. N-Nitrosodi-N-Propylamine X 43B. N-Nitrosodiphenylamine X 44B. Phenanthrene X 45B. Pyrene X 46B.1,2,4-Tri-Chlorobenzene X 1 Consistent with EPA methods which reference the American Chemical Society Committee on Environmental Improvement, non-detectable
data is represented by a value that is half of the detection limit.
Page 20 of 23
Appendix B, Table IID
Table IID-PESTICIDE COMPOUNDS (Complete table and include lab reports if applicable) Pollutant Mark with “X” Water Sample
Results Required
Testing Believed Absent
Believed Present
1P aldrin X
2P alpha-BHC X
3P beta-BHC X
4P gamma-BHC X
5P delta-BHC X
6P chlordane X
7P 4,4'-DDT X
8P 4,4'-DDE X
9P 4,4'-DDD X
10P dieldrin X
11P alpha-endosulfan X
12P beta-endosulfan X
13P endosulfan sulfate X
14P endrin X
15P endrin aldehyde X
16P heptachlor X
17P heptachlor epoxide X
18P PCB-1242 X
19P PCB-1254 X
20P PCB-1221 X
21P PCB-1232 X
22P PCB-1248 X
23P PCB-1260 X
24P PCB-1016 X
25P toxaphene X
Page 21 of 23
Appendix B, Table III
Antimony, Total Recoverable X Arsenic, Dissolved X 2.9 ug/L (2) Beryllium, Total Recoverable X Cadmium, Dissolved X 0.04 ug/L1 (2) Chromium, Dissolved X 0.71 ug/L1 (2) Copper, Dissolved X 4.85 ug/L (2) Cyanide, Dissolved X 2.5 ug/L1 Hardness (as CaCO3), Total
X
Believed present in effluent because of presence in influent water
Lead, Dissolved X 0.14 ug/L (2) Mercury, Dissolved X 0.1 ug/L1 (3) Nickel, Dissolved X 4.1 ug/L (2) Phenols, Total Recoverable X 25 ug/L1 (12) Selenium, Total Recoverable X 2.12 ug/L (50) Silver, Dissolved X 0.25 ug/L1 (2) Thallium, Total Recoverable X Zinc, Dissolved X 5.35 ug/L (2) DIOXIN X 2,3,7,8-Tetra-Chlorodibenzo-P-Bioxin X
1 Consistent with EPA methods which reference the American Chemical Society Committee on Environmental Improvement, non-detectable
data is represented by a value that is half of the detection limit.
Table III—Metals(Total Recoverable), Cyanide, Total Phenols, and Hardness Pollutant Mark with “X” Water Sample
Results Required
Testing Believed Absent
Believed Present
Page 22 of 23
Appendix B, Table IV
TABLE IV: Conventional and Nonconventional Pollutants: Pollutant Mark with “X” Water Sample Results Believed Absent Believed Present Bromide X Chlorine, Total Residual X E. coli X Fluoride X Nitrate-Nitrite X Nitrification may occur if
ammonia is present from golf course activities
Nitrogen, Total Organic X Believed present due to biological activity in WTS ponds
Oil and Grease X The WTS treats water contaminated by oil. See Table 1B in Appendix B for TPH and BTEX results
Phosphorus X Phosphorous may be present as a result of golf course activities
Radioactivity X Alpha, Total X Beta, Total X Radium, Total Recoverable X Radium 226, Total Recoverble X
Sulfate X 1180 mg/L Sulfide X 0.5 ug/L1 Sulfite X Surfactants X Aluminum, Dissolved X Barium, Total Recoverable X 60.5 ug/L (4)
Boron X Cobalt X Iron, Dissolved X 32 ug/L (50) Magnesium, Total X 125 mg/L Molybdenum X 3.35 ug/L (3) Manganese, Dissolved X 0.138 mg/L Tin X Titanium X
1 Consistent with EPA methods which reference the American Chemical Society Committee on Environmental Improvement, non-detectable
data is represented by a value that is half of the detection limit.
Page 23 of 23
Appendix B, Table V
Appendix B, Table VI
1 Consistent with EPA methods which reference the American Chemical Society Committee on Environmental Improvement, non-detectable data is represented by a value that is half of the detection limit.
TOXIC POLLUTANTS AND HAZARDOUS SUBSTANCES Circle any constituent(s) below you believe to be present in the discharge
TABLE V TOXIC POLLUTANT Asbestos
HAZARDOUS SUBSTANCES Acetaldehyde Diethyl amine Napthenic acid Monomethyl amine Allyl alcohol Dintrobenzene Naled Allyl chloride Diquat Nitrotoluene Amyl acetate Disulfoton Parathion Aniline Diuron Phenolsulfonate Asbestos Epichlorohydrin Phosgene Benzonitrile Ethion Propargite Benzyl chloride Ethylene diamine Propylene oxide Butyl acetate Ethylene dibromide Pyrethrins Butylamine Formaldehyde Quinoline Captan Furfural Resorcinol Carbaryl Guthion Strontium Carbofuran Dimethyl amine Strychnine Carbon disulfide Isoprene Styrene Chlorpyrifos Isopropanolamine TDE (Tetrachlorodiphenyl ethane) Coumaphos Kelthane Trichlorofon Cresol Kepone 2,4,5-T (2,4,5-Trichlorophenoxyacetic acid) Crotonaldehyde Malathion 2,4,5-TP [2-(2,4,5-Trichlorophenoxy) propanoic acid] Cyclohexane Mercaptodimethur Triethanolamine Diazinon Methoxychlor Triethylamine Dicamba Methyl mercaptan Trimethylamine Dichlobenil Methyl methacrylate Uranium Dichlone Methyl parathion Vanadium 2,4-D (2,4-Dichlorophenoxyacetic acid) Mevinphos Vinyl acetate 2,2-Dichloropropionic acid Mexacarbate Xylene Dichlorvos Monoethyl amine Xylenol
TABLE VI Use the space below to list any of the pollutants in the above tables (II-VI) which you are not required to submit a water quality sample and you know or have reason to believe is discharged or may be discharged from any outfall. For every pollutant you list, briefly describe the reasons you believe to be present and report any analytical data in your possession.
1. Pollutant 2. Source 1. Pollutant 2. Source
Xylene BTEX is in found at the site in the recovered product, but residual is removed in water treatment process (2) 1.5 ug/L1
Figures
EXISTING RECOVERY
WELLS
1.10 MGD
OIL WATER
SEPARATOR
OWS
EFFLUENT
SUMP
CASCADE
INLET
SPLITTER
STRUCTURE
CASCADE
AERATOR
CASCADE
JUNCTION
STRUCTURE
SURFACE FLOW
WETLAND
INLET SPLITTER
STRUCTURE
SURFACE FLOW
WETLAND (2)
SURFACE FLOW
WETLAND
OUTLET CONTROL
STRUCTURE(2)
GOLF COURSE
POND
GOLF COURSE
POND
SUBSURFACE FLOW
WETLAND
INLET SPLITTER
STRUCTURE
SUBSURFACE FLOW
WETLAND (2)
SUBSURFACE
FLOW
WETLAND
OUTLET
CONTROL
STRUCTURE (8)
STORMWATER
WETLAND (5)
STORMWATER
WETLAND
OUTLET
CONTROL
STRUCTURE
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CROWNS #2 GOLF COURSE POND
1.10 MGD + STORMWATER
(OUTFALL 001)
TO POTW
1.10 MGD + STORMWATER
WETLAND
TREATMENT
EFFLUENT
SUMP
Sovereign Consulting Inc.111-A North Gold DriveRobbinsville, NJ 08691(609) 259-8200 Fax (609) 259-8288
Project No.
Water Treatment SystemWYPDES Permit WY 0048810
File: 0318_Hydraulic_Profile_Fig1.dwg Date: 3/14/2018
Former BP Casper RefineryCasper, Wyoming
Figure 1
Cherry S
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CASCADE
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NORTH PLATTE RIVER
STORM WATER
WETLAND 2B
SURFACE FLOW
WETLAND
STORM WATER
WETLAND 2A
THREE
CROWNS #2
GOLD COURSE
POND
THREE
CROWNS #1
GOLD COURSE
POND
LEGEND
RECOVERY WELL
Sovereign Consulting Inc.111-A North Gold DriveRobbinsville, NJ 08691(609) 259-8200 Fax (609) 259-8288
Project No.
Water Treatment System-ProcessSite Layout
File: 0318_WaterTreatmentSystem_SP_Fig2.dwg Date: 4/2/2018
Former BP Casper RefineryCasper, Wyoming
Figure 2
CATCH BASIN
BARRIER WALL
R-74
0 450225
SCALE IN FEET
C.B. 24
Cherry St.
Walnut St.
Co llin s Drive
West Twelfth St.
Midwest St.
Prongho
rn St.
First S t.
Locust St.
Birch S
t.
Maple St.
Sycam
ore St.
West Thirteenth St.
Midwest St.
West Yellowstone Highway
Walnut St.
Poplar St.
2
5
5
5
2
3
SWSW
NWSW
SWNW SENW
NWNW
NESE
1SESE
1NESW
1SWSW
DRWN:DATE:
WYPDES Permit WY0048810 Minor ModificationBP Former Refinery, Casper, Wyoming
Atlantic Richfield Company
TOPO AREA MAP
07/22/09 FIGURE 3E.S.S./GOL
LEGEND
0 1800900
1"=1800'
SECTION NUMBER
11SESE
QTR/QTR SECTION WITHDOMESTIC WATER WELLS -NUMBER OF WELLS WITHINQTR/QTR SECTION
1NESW
QTR/QTR SECTION WITHSURFACE WATER INTAKE -NUMBER OF INTAKES WITHINQTR/QTR SECTION
NOTE: ALL WELLS LOCATED INTOWNSHIP 33NRANGE 79W
BASE IMAGE DATED 1984
Attachment I
Chemical Use Correspondence and Chemical SDS
March 23, 2016
Roland Peterson
Senior Analyst, WYPDES Permitting
Water Quality Division
Wyoming Department of Environmental Quality
200 West 17th Street, 4th Floor
Cheyenne, WY 82002
RE: Aquatic Herbicide - Periodic Use Request
WYPDES Permit Number WY0048810
Former BP Casper Refinery
Dear Mr. Peterson:
BP Products North America, Inc. requests WDEQ approval for the periodic use of Roundup CustomTM for
Aquatic & Terrestrial Use and Reward® Landscape and Aquatic Herbicide, in the Water Treatment System
(WTS) at the Former BP Casper Refinery (i.e., Site). This WTS utilizes a system of open water ponds that also
serve as water features for the back 9 of the Three Crowns Golf Course (See Figure 1). The periodic
application of aquatic herbicides is proposed to control undesirable growth of cattails in the WTS open
water ponds (i.e., Surface Flow Wetlands, Storm Water Wetlands, golf course pond, canal). The surface
area of these open water features totals under 12 acres.
The two referenced herbicides are chemicals specifically formulated for use in water to control aquatic plants
and are registered for aquatic use by the United States Environmental Protection Agency (EPA) as required by
the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA). This registration assures that pesticides,
when used in accordance with product labels, will not cause unreasonable harm to the environment.
Application of the two aquatic herbicides will be done in strict accordance with the respective herbicide label.
Attached please find the label for each of these two aquatic herbicides.
Excessive growth of cattails in the WTS open water ponds creates the need for periodic removal of growth to
prevent short circuiting of flows, maintain design hydraulic retention times, and limit head loss through the
shallow impoundments. Periodic use of the aquatic herbicides at the time of emergent plant growth will serve to
reduce maintenance requirements for the WTS.
Atlantic Richfield proposes to monitor oxygen levels in the WTS on a weekly basis for a period of six weeks
following herbicide application. This monitoring will be done to ensure that residual dissolved oxygen
concentrations throughout the treatment train are adequate for the bio-oxidation of organics and the precipitation
of iron. Operating history strongly indicates that the WTS has excess capacity with regard to organic loading.
The label for Roundup CustomTM, EPA Registration Number: 524-343, was last amended by EPA on November
7, 2013. The active ingredient in Roundup CustomTM is glyphosate. This is a broad spectrum, systemic, post-
emergent herbicide capable of eliminating the entire plant. Plants can take several weeks to be eliminated and a
repeat application is often necessary to remove plants that were missed during the first application.
Atlantic Richfield Company a BP affiliated company
111 Star Lane Casper, WY 82604
Phone: (307) 268-4304 Fax: (307) 261-4288
E-Mail: [email protected]
March 23, 2016
Mr. Peterson Page 2 of 2
The label for Reward® Landscape and Aquatic Herbicide, EPA Registration Number: 100-1091, was last
amended by EPA on October 9, 2009. The active ingredient in Reward® is diquat dibromide. This is a fast-
acting, non-selective, contact herbicide which removes the vegetative part of the plant but does not kill the roots.
It is used primarily for short-term (one season) control of a variety of submerged aquatic plants and is suitable
for spot treatment.
Atlantic Richfield Company appreciates the WDEQ Water Quality Division’s efforts in working with the Site to
maintain remediation facilities while ensuring compliance with effluent limitations. Please contact Clay Price at
307-261-4324 if you have any questions, comments, or if you would like additional information about the
proposed use of these aquatic herbicides in the WTS.
Sincerely,
Sasa Jazic
Project Manager
Atlantic Richfield Company
Figure 1: Water Treatment System – Process (1/1)
Attachments
Label: Roundup ControlTM for Aquatic & Terrestrial Use
Label: Reward® Landscape and Aquatic Herbicide
cc: Matt Buchholz, WDEQ (electronic file)
Clay Price, TREC, Inc. (electronic file)
Dale Edwards, TREC, Inc. (electronic file)
Kitty Thomson (site file), TREC, Inc. (electronic file)
SAFETY DATA SHEET
AB PHYCOMYCIN SCP REVISION DATE : 05/26/2015 Page 1 of 10
FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL SDS QUESTIONS & REQUESTS, CALL:
1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347)
PRODUCT NAME: AB PHYCOMYCIN SCP
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Supplier Applied Biochemists (WI) W175 N11163 Stonewood Drive , Suite 234 Germantown, WI, 53022 USA Telephone: +12622554449 Telefax: +12622554449 Web: www.appliedbiochemists.com Manufacturer Advantis Technologies 1200 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States of America
REVISION DATE: 05/26/2015 SUPERCEDES: 10/29/2012
MSDS Number: 000000024551 SYNONYMS: CHEMICAL FAMILY: None DESCRIPTION / USE None established FORMULA: None established
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Oxidizing solids
: Category 3
Corrosive to metals
: Category 1
Acute toxicity (Oral)
: Category 4
Skin irritation
: Category 2
Eye irritation
: Category 2A
GHS Label element
SAFETY DATA SHEET
AB PHYCOMYCIN SCP REVISION DATE : 05/26/2015 Page 2 of 10
Hazard pictograms
:
Signal word
: Warning
Hazard statements
: H272 May intensify fire; oxidiser. H290 May be corrosive to metals. H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation.
Precautionary statements
: Prevention: P210 Keep away from heat. P220 Keep/Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P234 Keep only in original container. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/ eye protection/ face protection. Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P390 Absorb spillage to prevent material damage. Storage: P406 Store in corrosive resistant stainless steel container with a resistant inner liner. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS OR CHEMICAL NAME CAS # % RANGE Sodium Percarbonate 15630-89-4
80 - 90
SAFETY DATA SHEET
AB PHYCOMYCIN SCP REVISION DATE : 05/26/2015 Page 3 of 10
Sodium carbonate 497-19-8
10 - 16
sodium silicate 1344-09-8
1 - 3
SECTION 4. FIRST AID MEASURES General Advice: Call a poison control center or doctor for treatment advice. For 24-hour
emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.
Inhalation: IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an
ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.
Skin Contact: IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.
Eye Contact: IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
Ingestion: IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person.
SECTION 5. FIREFIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible, pyrophoric or
explosive. Flammable Properties Fire / Explosion Hazards: May intensify fire; oxidiser. Extinguishing Media: Water spray Fire Fighting Instructions: Use water spray to cool unopened containers. In case of fire, use
normal fire-fighting equipment and the personal protective equipment recommended in Section 8 to include a NIOSH approved self-contained breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
SAFETY DATA SHEET
AB PHYCOMYCIN SCP REVISION DATE : 05/26/2015 Page 4 of 10
Personal Protection for Emergency Situations:
Use the personal protective equipment recommended in Section 8 and a NIOSH approved self-contained breathing apparatus.
Spill Mitigation Procedures Air Release: Keep people away from and upwind of spill/leak. Water Release: If the product contaminates rivers and lakes or drains inform
respective authorities. Land Release: Sweep up and shovel into suitable containers for disposal.Avoid
creating dust. Additional Spill Information : Prevent further leakage or spillage if safe to do so. Use personal
protective equipment as required. Evacuate personnel to safe areas.
SECTION 7. HANDLING AND STORAGE Handling: Do not take internally. Avoid contact with skin, eyes and clothing. If
in eyes or on skin, rinse well with water. Avoid breathing dust. Storage: Store in a cool dry ventilated location, away from sources of ignition
or other incompatible conditions and chemicals. Keep container(s) closed.
Incompatible Materials for Storage: Refer to Section 10, "Incompatible Materials."
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Local exhaust ventilation is recommended if vapors, mists or aerosols are
generated. Otherwise, use general exhaust ventilation.No exposure limits exist for the constituents of this product.
Protective Equipment for Routine Use of Product Respiratory Protection : Respiratory protection not normally needed., If vapors, mists or aerosols are
generated, wear a NIOSH approved respirator. Skin Protection : Avoid contact with skin. Impervious gloves Eye Protection: Chemical resistant goggles must be worn. Protective Clothing Type: impervious clothing General Protective Measures:
Ensure that eyewash stations and safety showers are close to the workstation location.
Components with workplace control parameters
no data available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: solid Form No data. Color: No data. Odor: No data. Molecular Weight: None established
SAFETY DATA SHEET
AB PHYCOMYCIN SCP REVISION DATE : 05/26/2015 Page 5 of 10
pH : 10.4 - 10.6 () 10 g/l (as aqueous solution)
Boiling Point: Not applicable
Melting point/freezing point
no data available
Bulk Density: () no data available
Vapor Pressure: Not applicable Vapor Density: Not applicable Viscosity: Not applicable Solubility in Water: 140 g/l
75 °F (24 °C)
Partition coefficient n-octanol/water:
No data
Evaporation Rate: Not applicable Oxidizing: None established Volatiles, % by vol.: no data available VOC Content This product does not contain any chemicals listed under the U.S.
Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450.
HAP Content No data
SECTION 10. STABILITY AND REACTIVITY Stability and Reactivity Summary: Stable under normal conditions. Conditions to Avoid: Heat, Exposure to moist air or water Chemical Incompatibility: Water, Acids, Bases, Reducing agents, Organic materials,
Flammable materials, metal salts Hazardous Decomposition Products: Oxygen, Steam and heat Decomposition Temperature: No data
SECTION 11. TOXICOLOGICAL INFORMATION Component Animal Toxicology Oral LD50 value:
Sodium Percarbonate LD50 = 2,400 mg/kg Rat
LD50 = 1,034 mg/kg Rat
Sodium carbonate LD50 = 4,090 mg/kg Rat
sodium silicate LD50 = 1,960 mg/kg Rat Component Animal Toxicology Dermal LD50 value:
Sodium Percarbonate LD50 > 2,000 mg/kg Rabbit
Sodium carbonate LD50 Believed to be > 2,000 mg/kg Rabbit
SAFETY DATA SHEET
AB PHYCOMYCIN SCP REVISION DATE : 05/26/2015 Page 6 of 10
sodium silicate LD50 > 4,640 mg/kg Rabbit Component Animal Toxicology Inhalation LC50 value: Sodium Percarbonate No data
Sodium carbonate LC50 1 h = 4.6 mg/l Rat
sodium silicate no data available
Product Animal Toxicity Oral LD50 value: Believed to be approximately 1,158 mg/kg Dermal LD50 value: No data. Inhalation LC50 value:
No data.
Skin Irritation: Moderate skin irritant Eye Irritation: Severe eye irritant Skin Sensitization: Not believed to be sensitising to skin.
Sodium Percarbonate This material tested negative for skin sensitization in animals.
Subchronic / Chronic Toxicity:
There are no known or reported effects from chronic exposure.
Sodium carbonate Male rats were exposed to an aerosol of 2% aqueous solution of this chemical, 4 hr.day, 5 days/week for 3-1/2 months. No effect was observed at a concentration of 10 or 20 mg/cubic meter. At 70 mg/cubic meter weight gain was decreased and the lungs showed thickening of the intra-alveolar walls, hyperemia, and lymphoid infiltration., Repeated or prolonged skin contact with this product may cause dermatitis and blistering.
Reproductive and Developmental Toxicity:
Not known or reported to cause reproductive or developmental toxicity.
Sodium carbonate This chemical has been tested in laboratory animals
and no evidence of teratogenicity was seen. Mutagenicity: Not known or reported to be mutagenic.
Sodium carbonate This product was determined to be non-mutagenic in the Ames assay. It was also shown to be non-clastogenic in the chromosomal aberration test.
Carcinogenicity: This product is not known or reported to be carcinogenic by any reference
source including IARC, OSHA, NTP or EPA.
SAFETY DATA SHEET
AB PHYCOMYCIN SCP REVISION DATE : 05/26/2015 Page 7 of 10
SECTION 12. ECOLOGICAL INFORMATION Overview: This material is not expected to be harmful to aquatic life., Based on the physical
properties of this product, significant environmental persistence and bioaccumulation would not be expected.
Ecological Toxicity Values for: Sodium carbonate
Pimephales promelas (fathead minnow)
- (nominal, static). 96 h LC50 < 850 mg/l
Bluegill - (nominal, static). 96 h LC50 = 320 mg/l Mosquito fish - (nominal, static). 96 h LC50 = 740 mg/l
Daphnia magna, - (nominal, static). 48 h LC50= 265 mg/l Ceriodaphnia dubia - (nominal) 48 h EC50= 199.82 mg/l
Navicula seminulum (diatom) - (nominal, static). 96 h EC50 = 242 mg/l Ecological Toxicity Values for: sodium silicate
Gambusia affinis (Mosquito fish) - static test 96 h LC50 = 1,800 - 2,320 mg/l Lepomis macrochirus (Bluegill sunfish)
- 96 h LC50 = 301 - 478 mg/l
Fish, fresh water (brachydaniorerio)
- semi-static test 96 h LC50 = 3,185 mg/l
Daphnia magna (Water flea) - static test 48 h LC50= 494 mg/l Ceriodaphnia dubia - 48 h EC50= 33.53 mg/l
SECTION 13. DISPOSAL CONSIDERATIONS
CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES.
Waste Disposal Summary : If this product becomes a waste, it meets the criteria of a hazardous
waste as defined under 40 CFR 261 and would have the following EPA hazardous waste number: D001.
Disposal Methods : As a nonhazardous liquid waste, it should be disposed of in
accordance with local, state and federal regulations.
SAFETY DATA SHEET
AB PHYCOMYCIN SCP REVISION DATE : 05/26/2015 Page 8 of 10
SECTION 14. TRANSPORT INFORMATION
DOT UN number : 3378 Description of the goods : Sodium carbonate peroxyhydrate Class : 5.1 Packing group : III Labels : 5.1 Emergency Response Guidebook Number
: 140
IATA UN number : 3378 Description of the goods : Sodium carbonate peroxyhydrate Class : 5.1 Packing group : III Labels : 5.1 Packing instruction (cargo aircraft)
: 563
Packing instruction (passenger aircraft)
: 559
Packing instruction (passenger aircraft)
: Y546
IMDG-CODE UN number : 3378 Description of the goods : SODIUM CARBONATE PEROXYHYDRATE Class : 5.1 Packing group : III Labels : 5.1 EmS Number 1 : F-A EmS Number 2 : S-Q
SECTION 15. REGULATORY INFORMATION
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals.
Signal word : DANGER! Hazard statements : Harmful if swallowed.
Harmful if inhaled. Corrosive. Causes skin burns. Corrosive. Causes irreversible eye damage. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
SAFETY DATA SHEET
AB PHYCOMYCIN SCP REVISION DATE : 05/26/2015 Page 9 of 10
EPCRA - Emergency Planning and Community Right-to-Know Act
SARA 302 No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302.
SARA 313
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
US State Regulations
Massachusetts Right To Know
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know
Sodium carbonate 497-19-8
New Jersey Right To Know
Sodium carbonate 497-19-8 Silicic acid, sodium salt 1344-09-8
SAFETY DATA SHEET
AB PHYCOMYCIN SCP REVISION DATE : 05/26/2015 Page 10 of 10
California Prop 65
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
The components of this product are reported in the following inventories:
TSCA
: The components of this product are listed on the TSCA Inventory of Existing Chemical Substances.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION SECTIONS REVISED: 3 Major References : Available upon request. THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS. ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT. .
Color:
Odor:
Aspiration Hazard:
Amount
Prop.
Prop.
Prop.
Prop.
Prop.
Prop.
Prop.
Prop.
Prop.
SAFETY DATA SHEETSection 1: Product and Company Identification
Product Use: Plant Based Cleaner
Product Name:
Green Earth TechnologiesSupplier:
Address: 106 Gaither Drive
Mount Laurel, NJ 08054
Opaque White or Amber
Physical State: Liquid
Emergency Overview
Hazards of Product:
D-Glycolpyranoside hexyl
Soapy Odor
Filtered Water 7732-18-5
Coconut Fatty Acid
Section 2: Hazards Identification
No evidence of adverse effect.
Eye Contact:
Skin Contact:
Skin Absorption: No evidence of adverse effect.
OSHA Hazard Communication Standard
This product is a "Non-Hazardous Chemical" as defined by the OSHA Hazard Communication Standard
29 CFR 1910.1200.
Potential Health EffectsNo evidence of adverse effect.
Section 3: Composition Information
Component CAS #
Corn Oil 8001-30-7
Inhalation: No evidence of adverse effect.
Ingestion: No evidence of adverse effect.
No evidence of adverse effect.
61788-47-4
Coconut Oil 8001-31-8
79-14-1Glycolic Acid
Tween 85 9055-70-3
Biosoft N91-8 68439-46-3
Glucopon 215 UP 68515-73-1
54549-24-5
Casing Cutter
Phone Number: 856-206-0058
EMERGENCY TELEPHONE NUMBER
Local Contact: 856-206-0058
Product Name: Casing Cutter Page 1 of 5 Issue Date: 08/01/2016
fire.
Section 4: First Aid Measures
General Advice: First Aid responders should pay attention to self-protection and use the recommended
protective clothing. If potential for exposure exists refer to Section 8 for specific personal
protective equipment.
No evidence of adverse effects.Ingestion:
None known.
Medical conditions aggravated by exposure:
Note to Physicians:
Inhalation: No evidence of adverse effects.
No evidence of adverse effects.Skin Contact:
Eye Contact: Flush eyes with water for 5 minutes.
Environmental Precautions:
Evacuate the area as the floor may be slippery. Use care to prevent
slips and falls.
None required.
Protection to Firefighters:
Section 6: Accidental Release Measures
Personal Precautions:
No specific instructions.
Section 5: Fire Fighting Measures
Suitable Extinguishing media:
Flammable Properties:
Store in cool, well ventilated area. Avoid low temperatures.
No special procedures required.
Storage Procedures:
Section 8: Exposure Controls/Personal Protection
Exposure Limits: None established.
Methods for Containment and Cleanup: Rinse area thoroughly with water. This product is safe to wash into
drains and waste systems.
Section 7: Handling and Storage
Handling Procedures:
Other Safety Equipment:
None required.
None required.
None required.
None required.
None required.
None required.
Engineering Controls:
Respiratory Protection:
Eye/Face Protection:
Skin Protection:
Gloves:
This material will not burn. Use extinguishing media appropriate for surrounding
As defined by OSHA, this product is non-flammable.
No special precautions needed.
Product Name: Casing Cutter Page 2 of 5 Issue Date: 08/01/2016
Color:
Odor:
pH: 4.1-4.4
Evaporation Rate:
Lower: N/A
Upper: N/A
None
None
Vapor Density (air = 1):
0.986 20°C/20°C Calculated
Complete
No dangerous reactions known under normal use.
Stable at typical use temperatures.
Ingestion:
Dermal:
Flammability (solid, gas)
Section 9: Physical and Chemical Properties
Flash Point:
Autoignition Temperature:
Explosion Sensitivity to Impact:
Explosion Sensitivity to Static Discharge:
Not applicable to liquids
No test data available
Flammable Limits in Air
No test data available
Physical State:
Odor Threshold:
Melting Point:
Freezing Point:
No test data available
No test data available
Not applicable to liquids
None (TCC)
-4° C (25° F)
Liquid
Soapy Odor
Chemical Stability:
Possibility of Hazardous Reactions: None known
None knownIncompatible Materials:
No test data availableMolecular Weight:
Section 10: Stability and Reactivity
Reactivity:
Solubility in Water (by Weight):
Decomposition: No test data available
No test data availableOxidizing Properties:
Vapor Pressure: <0.01 mmHg Estimated
>1 Estimated
Specific Gravity (H2O = 1):
Products of Combustion:
Appearance
None knownSkin Corrosion/Skin Irritation:
Inhalation: None known
Eye Damage/Eye Irritation: None known
Hazardous Decomposition Products:
Section 11: Toxicological Information
Acute Toxicity
None known
None known
None
Opaque White or Amber
Product Name: Casing Cutter Page 3 of 5 Issue Date: 08/01/2016
None
None
DOT Bulk:
IMDG:
No
No
No
Reactive Hazard: No
No
Sensitization
Skin:
Chronic Toxicity and Carcinogenicity:
Developmental Toxicity:
No evidence of adverse effects.
No evidence of adverse effects.
Respiratory:
No evidence of adverse effects.
No evidence of adverse effects.
No evidence of adverse effects.Repeated Dose Toxicity:
Readily BiodegradablePersistence and Degradability:
Section 13: Disposal Considerations
Chemicals contained are not listed as hazardous waste. This product is safe to wash into waste systems.
All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations.
No evidence of adverse effects.Reproductive Toxicity:
Section 12: Ecological Information
Ecotoxicity:
Aquatic Toxicity:
Not regulatedICAO/IATA:
Section 15: Regulatory Information
Regulations may vary in different locations. As your supplier, we have no control over the management practices
or manufacturing processes of parties handling or using this material. The information presented here pertains
only to the product as shipped in its intended condition as described in SDS Section: Composition Information.
Section 14: Transport Information
DOT Non-Bulk: Not regulated
Delayed (Chronic) Health Hazard:
Fire Hazard:
Sudden Release of Pressure Hazard:
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community
Right-To-Know Act of 1986) Sections 313
This product is a "Non-Hazardous Chemical" as defined by the OSHA Hazard Communication Standard
29 CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community
Right-To-Know Act of 1986) Sections 311 and 312
Immediate (Acute) Health Hazard:
Not regulated
Not regulated
Product Name: Casing Cutter Page 4 of 5 Issue Date: 08/01/2016
Key To Abbreviations:
Prop.: Proprietary
CAS: Chemical Abstract Service
PPE: Personal Protective Equipment
NE: None Established
N/A: Not Applicable
TCC: Tag Closed Cup
OSHA: Occupational Safety and Health Administration
Last Revision Date: 08/01/2016Prepared by: Paul N. Andrecola Ph.D., Ch.E., P.E. Phone: 856-206-0058
this material if it is used in combination with any other materials. This information is accurate to the best of
Green Earth Technologies' knowledge or obtained from sources G.E.T. believes to be accurate. Before using any product,
read all warnings and instructions on the label.
Product Literature
Information on this product and other products we offer can be found on our web site. Call your Sales or Customer
Service Representative if you require additional information.
HMIS Health: 0 Fire: 0 Reactivity: 0 Special: 0
reproductive harm, at levels which would require a warning under the statute.
U.S. Toxic Substances Control Act
All components of the product are on the TSCA Inventory or are exempt from TSCA Inventory requirements
under 40 CFR 720.30
Section 16: Other Information
Extremely Hazardous Substance (40 CFR 355, Appendix A)
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
this statue.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer, birth defects or other
this statue.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Special Hazardous Substances List
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
this statue.
U.S. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
The information contained in this document applies to this specific material as supplied. It may not be valid for
this statue.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Hazardous Substances List and/or
Pennsylvania Environmental Hazardous Substance List
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
Product Name: Casing Cutter Page 5 of 5 Issue Date: 08/01/2016
Color:
Odor: Mild
Aspiration Hazard:
Amount
25-50%
15-20%
15-20%
15-20%
1-5%
10-15%
29 CFR 1910.1200.
Potential Health EffectsNo evidence of adverse effect.
Section 3: Composition Information
Component CAS #
Filtered Water 7732-18-5
Inhalation: No evidence of adverse effect.
Ingestion: No evidence of adverse effect.
No evidence of adverse effect.
SAFETY DATA SHEETSection 1: Product and Company Identification
Product Use: Plant Based Algaecide
Product Name:
Green Earth Technologies
OSHA Hazard Communication Standard
This product is a "Non-Hazardous Chemical" as defined by the OSHA Hazard Communication Standard
Phone Number: 856-206-0058
Local Contact:
Supplier:
Address: 106 Gaither Drive
Mount Laurel, NJ 08054
Opaque Yellow
Physical State: Liquid
Emergency Overview
Hazards of Product:
856-206-0058
EMERGENCY TELEPHONE NUMBER
Section 2: Hazards Identification
No evidence of adverse effect.
Eye Contact:
Skin Contact:
Skin Absorption: No evidence of adverse effect.
61788-47-4
8001-31-8
8002-75-3
532-32-1
Coconut Fatty Acid
Coconut Oil
Palm Oil
Sodium Benzoate
Glycolic Acid 79-14-1
Colloidal Algae Control
Product Name: Colloidal Algae Control Base Page 1 of 5 Issue Date: 03/21/2015
fire.
Section 4: First Aid Measures
General Advice: First Aid responders should pay attention to self-protection and use the recommended
protective clothing. If potential for exposure exists refer to Section 8 for specific personal
protective equipment.
No evidence of adverse effects.Ingestion:
None known.
Medical conditions aggravated by exposure:
Note to Physicians:
Inhalation: No evidence of adverse effects.
No evidence of adverse effects.Skin Contact:
Eye Contact: Flush eyes with water for 5 minutes.
Environmental Precautions:
Evacuate the area as the floor may be slippery. Use care to prevent
slips and falls.
None required.
Protection to Firefighters:
Section 6: Accidental Release Measures
Personal Precautions:
No specific instructions.
Section 5: Fire Fighting Measures
Suitable Extinguishing media:
Flammable Properties:
Store in cool, well ventilated area. Avoid low temperatures.
No special procedures required.
Storage Procedures:
Section 8: Exposure Controls/Personal Protection
Exposure Limits: None established.
Methods for Containment and Cleanup: Rinse area thoroughly with water. This product is safe to wash into
drains and waste systems.
Section 7: Handling and Storage
Handling Procedures:
Other Safety Equipment:
None required.
None required.
None required.
None required.
None required.
None required.
Engineering Controls:
Respiratory Protection:
Eye/Face Protection:
Skin Protection:
Gloves:
This material will not burn. Use extinguishing media appropriate for surrounding
As defined by OSHA, this product is non-flammable.
No special precautions needed.
Product Name: Colloidal Algae Control Base Page 2 of 5 Issue Date: 03/21/2015
Color:
Odor: Mild
pH: 3.3-3.7
Evaporation Rate:
Lower: N/A
Upper: N/A
None
None
Vapor Density (air = 1):
1.001 20°C/20°C Calculated
Water dispersible
No dangerous reactions known under normal use.
Stable at typical use temperatures.
Ingestion:
Dermal:
Flammability (solid, gas)
Section 9: Physical and Chemical Properties
Flash Point:
Autoignition Temperature:
Explosion Sensitivity to Impact:
Explosion Sensitivity to Static Discharge:
Not applicable to liquids
No test data available
Flammable Limits in Air
No test data available
Physical State:
Odor Threshold:
Melting Point:
Freezing Point:
No test data available
No test data available
Not applicable to liquids
None (TCC)
-4° C (25° F)
Liquid
Chemical Stability:
Possibility of Hazardous Reactions: None known
None knownIncompatable Materials:
No test data availableMolecular Weight:
Section 10: Stability and Reactivity
Reactivity:
Solubility in Water (by Weight):
Decomposition: No test data available
No test data availableOxidizing Properties:
Vapor Pressure: <0.01 mmHg Estimated
>1 Estimated
Specific Gravity (H2O = 1):
Products of Combustion:
Appearance
Inhalation: None known
Eye Damage/Eye Irritation: None known
Hazardous Decomposition Products:
Section 11: Toxicological Information
Acute Toxicity
None known
None known
None
None knownSkin Corrosion/Skin Irritation:
Opaque Yellow
Product Name: Colloidal Algae Control Base Page 3 of 5 Issue Date: 03/21/2015
None
None
DOT Bulk:
IMDG:
No
No
No
Reactive Hazard: No
No
Respiratory:
No evidence of adverse effects.
No evidence of adverse effects.
No evidence of adverse effects.Repeated Dose Toxicity:
Sensitization
Skin:
No evidence of adverse effects.Reproductive Toxicity:
Section 12: Ecological Information
Ecotoxicity:
Aquatic Toxicity:
Chronic Toxicity and Carcinogenicity:
Developmental Toxicity:
No evidence of adverse effects.
No evidence of adverse effects.
Regulations may vary in different locations. As your supplier, we have no control over the management practices
or manufacturing processes of parties handling or using this material. The information presented here pertains
only to the product as shipped in its intended condition as described in SDS Section: Composition Information.
Section 14: Transport Information
DOT Non-Bulk: Not regulated
Readily BiodegradablePersistance and Degradability:
Section 13: Disposal Considerations
Chemicals contained are not listed as hazardous waste. This product is safe to wash into waste systems.
All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations.
This product is a "Non-Hazardous Chemical" as defined by the OSHA Hazard Communication Standard
29 CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community
Right-To-Know Act of 1986) Sections 311 and 312
Immediate (Acute) Health Hazard:
Not regulated
Not regulated
Not regulatedICAO/IATA:
Section 15: Regulatory Information
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
this statue.
Delayed (Chronic) Health Hazard:
Fire Hazard:
Sudden Release of Pressure Hazard:
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community
Right-To-Know Act of 1986) Sections 313
Product Name: Colloidal Algae Control Base Page 4 of 5 Issue Date: 03/21/2015
Key To Abbriviations:
Prop.: Proprietary
CAS: Chemical Abstract Service
PPE: Personal Protective Equipment
NE: None Established
N/A: Not Applicable
TCC: Tag Closed Cup
OSHA: Occupational Safety and Health Administration
Last Revision Date: 03/21/2015Prepared by: Paul N. Andrecola Ph. D., Ch. E., P.E. Phone: 856-206-0058
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Hazardous Substances List and/or
Pennsylvania Environmental Hazardous Substance List
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
The information contained in this document applies to this specific masterial as supplied. It may not be valid for
this material if it is used in combination with any other materials. This information is accurate to the best of
Green Earth Technologies' knowledge or obtained from sources G.E.T. believes to be accurate. Before using any product,
read all warnings and instructions on the label.
Product Literature
Information on this product and other products we offer can be found on our web site. Call your Sales or Customer
Service Representative if you require additional information.
HMIS Health: 0 Fire: 0 Reactivity: 0 Special: 0
reproductive harm, at levels which would require a warning under the statute.
U.S. Toxic Substances Control Act
All components of the product are on the TSCA Inventory or are exempt from TSCA Inventory requirements
under 40 CFR 720.30
Section 16: Other Information
Extremely Hazardous Substance (40 CFR 355, Appendix A)
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
this statue.
California Proposition 65 (Safe Drinking Water and Toixc Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer, birth defects or other
this statue.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Special Hazardous Substances List
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
this statue.
U.S. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302
Product Name: Colloidal Algae Control Base Page 5 of 5 Issue Date: 03/21/2015
Color:
Odor: Mild
Aspiration Hazard:
Amount
Prop.
Prop.
Prop.
Prop.
Prop.
Prop.
Prop.
Prop.
SAFETY DATA SHEETSection 1: Product and Company Identification
Product Use: Plant Based Surface Wash Cleaner
Product Name:
Green Earth Technologies
Phone Number: 856-206-0058
Local Contact:
Supplier:
Address: 106 Gaither Drive
Mount Laurel, NJ 08054
Amber
Physical State: Viscous Liquid
Emergency Overview
Hazards of Product:
856-206-0058
Tween 85
EMERGENCY TELEPHONE NUMBER
Section 2: Hazards Identification
No evidence of adverse effect.
Eye Contact:
Skin Contact:
Skin Absorption: No evidence of adverse effect.
OSHA Hazard Communication Standard
This product is a "Non-Hazardous Chemical" as defined by the OSHA Hazard Communication Standard 29 CFR 1910.1200.
Potential Health Effects
No evidence of adverse effect.
Section 3: Composition Information
Component CAS #
Corn Oil 8001-30-7
Inhalation: No evidence of adverse effect.
Ingestion: No evidence of adverse effect.
No evidence of adverse effect.
Filtered Water 7732-18-5
8001-31-8
61788-47-4
64336-70-7
Coconut Oil
Coconut Fatty Acid
D-Glycopyranside, hexyl
Glucopon 215 UP 68515-73-1
Biosoft N91-8 68439-46-3
9055-70-3
OSC-1809
Harmonization Code: 3402.90.5030
Product Name: OSC-1809 Page 1 of 5 Issue Date: 07/24/2016
Section 4: First Aid Measures
General Advice: First Aid responders should pay attention to self-protection and use the recommended
protective clothing. If potential for exposure exists refer to Section 8 for specific personal
protective equipment.
No evidence of adverse effects.Ingestion:
None known.
Medical conditions aggravated by exposure:
Note to Physicians:
Inhalation: No evidence of adverse effects.
No evidence of adverse effects.Skin Contact:
Eye Contact: Flush eyes with water for 5 minutes.
Environmental Precautions:
Evacuate the area as the floor may be slippery. Use care to prevent
slips and falls.
None required.
Protection to Firefighters:
Section 6: Accidental Release Measures
Personal Precautions:
No specific instructions.
Section 5: Fire Fighting Measures
Suitable Extinguishing media:
Flammable Properties:
Store in cool, well ventilated area. Avoid low temperatures.
No special procedures required.
Storage Procedures:
Section 8: Exposure Controls/Personal Protection
Exposure Limits: None established.
Methods for Containment and Cleanup: Rinse area thoroughly with water. This product is safe to wash into
drains and waste systems.
Section 7: Handling and Storage
Handling Procedures:
Other Safety Equipment:
None required.
None required.
None required.
None required.
None required.
None required.
Engineering Controls:
Respiratory Protection:
Eye/Face Protection:
Skin Protection:
Gloves:
This material will not burn. Use extinguishing media appropriate for surrounding fire.
As defined by OSHA, this product is non-flammable.
No special precautions needed.
Product Name: OSC-1809 Page 2 of 5 Issue Date: 07/24/2016
Color:
Odor: Mild
pH: 8.0-9.8
Evaporation Rate:
Lower: N/A
Upper: N/A
None
None
Vapor Density (air = 1):
1.001 20°C/20°C Calculated
Complete
No dangerous reactions known under normal use.
Stable at typical use temperatures.
Ingestion:
Dermal:
Flammability (solid, gas)
Section 9: Physical and Chemical Properties
Flash Point:
Autoignition Temperature:
Explosion Sensitivity to Impact:
Explosion Sensitivity to Static Discharge:
Not applicable to liquids
No test data available
Flammable Limits in Air
No test data available
Physical State:
Odor Threshold:
Melting Point:
Freezing Point:
No test data available
No test data available
Not applicable to liquids
None (TCC)
-4° C (25° F)
Viscous Liquid
Chemical Stability:
Possibility of Hazardous Reactions: None known
None knownIncompatible Materials:
No test data availableMolecular Weight:
Section 10: Stability and Reactivity
Reactivity:
Solubility in Water (by Weight):
Decomposition: No test data available
No test data availableOxidizing Properties:
Vapor Pressure: <0.01 mmHg Estimated
>1 Estimated
Specific Gravity (H2O = 1):
Products of Combustion:
Appearance
Inhalation: None known
Eye Damage/Eye Irritation: None known
Hazardous Decomposition Products:
Section 11: Toxicological Information
Acute Toxicity
None known
None known
None
None knownSkin Corrosion/Skin Irritation:
Amber
Product Name: OSC-1809 Page 3 of 5 Issue Date: 07/24/2016
None
None
DOT Bulk:
IMDG:
No
No
No
Reactive Hazard: No
No
Respiratory:
No evidence of adverse effects.
No evidence of adverse effects.
No evidence of adverse effects.Repeated Dose Toxicity:
Sensitization
Skin:
No evidence of adverse effects.Reproductive Toxicity:
Section 12: Ecological Information
Ecotoxicity:
Aquatic Toxicity:
Chronic Toxicity and Carcinogenicity:
Developmental Toxicity:
No evidence of adverse effects.
No evidence of adverse effects.
Regulations may vary in different locations. As your supplier, we have no control over the management practices
or manufacturing processes of parties handling or using this material. The information presented here pertains
only to the product as shipped in its intended condition as described in SDS Section: Composition Information.
Section 14: Transport Information
DOT Non-Bulk: Not regulated
Readily BiodegradablePersistence and Degradability:
Section 13: Disposal Considerations
Chemicals contained are not listed as hazardous waste. This product is safe to wash into waste systems.
All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations.
This product is a "Non-Hazardous Chemical" as defined by the OSHA Hazard Communication Standard
29 CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community
Right-To-Know Act of 1986) Sections 311 and 312
Immediate (Acute) Health Hazard:
Not regulated
Not regulated
Not regulatedICAO/IATA:
Section 15: Regulatory Information
Delayed (Chronic) Health Hazard:
Fire Hazard:
Sudden Release of Pressure Hazard:
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community
Right-To-Know Act of 1986) Sections 313
Product Name: OSC-1809 Page 4 of 5 Issue Date: 07/24/2016
Key To Abbreviations:
Prop.: Proprietary
CAS: Chemical Abstract Service
PPE: Personal Protective Equipment
NE: None Established
N/A: Not Applicable
TCC: Tag Closed Cup
OSHA: Occupational Safety and Health Administration
Last Revision Date: 07/24/2016Prepared by: Paul N. Andrecola Ph.D., Ch.E., P.E. Phone: 856-206-0058
this statue.
U.S. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
this statue.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Hazardous Substances List and/or
Pennsylvania Environmental Hazardous Substance List
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
The information contained in this document applies to this specific material as supplied. It may not be valid for
this material if it is used in combination with any other materials. This information is accurate to the best of
Green Earth Technologies' knowledge or obtained from sources G.E.T. believes to be accurate. Before using any product,
read all warnings and instructions on the label.
Product Literature
Information on this product and other products we offer can be found on our web site. Call your Sales or Customer
Service Representative if you require additional information.
HMIS Health: 0 Fire: 0 Reactivity: 0 Special: 0
reproductive harm, at levels which would require a warning under the statute.
U.S. Toxic Substances Control Act
All components of the product are on the TSCA Inventory or are exempt from TSCA Inventory requirements
under 40 CFR 720.30
Section 16: Other Information
Extremely Hazardous Substance (40 CFR 355, Appendix A)
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
this statue.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer, birth defects or other
this statue.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Special Hazardous Substances List
To the best of our knowledge, this product does not contain chemicals at levels which require reporting under
Product Name: OSC-1809 Page 5 of 5 Issue Date: 07/24/2016
MONSANTO COMPANYRoundup CustomfTMI for Aquatic & Terrestrial Use Version: 1.0
Page: 1 /9Effective date: 05/29/2015
MONSANTO COMPANYSafety Data Sheet
Commercial Product
1. PRODUCT AND COMPANY IDENTIFICATION
1.1. Product identifier
Roundup Custom[TM] for Aquatic & Terrestrial Use
1.1.1. Chemical name
Not applicable.1.1.2. Synonyms
None.
1.1.3. EPA Reg. No.524-343
1.2. Product useHerbicide
1.3. CompanyMONSANTO COMPANY, 800 N. Lindbergh Blvd., St. Louis, MO, 63167Telephone: 800-332-3111, Fax: 314-694-5557E-mail: [email protected]
1.4. Emei^ency numbersFOR CHEMICAL EMERGENCY, SPILL LEAK, FIRE, EXPOSURE, OR ACCIDENT CallCHEMTREC - Day or Night: 1 -800-424-9300 toll free in the continental U.S., Puerto Rico, Canada, orVirgin Islands. For calls originating elsewhere: 703-527-3887 (collect calls accepted).FOR MEDICAL EMERGENCY - Day or Night: +1 (314) 694-4000 (collect calls accepted).
2. HAZARDS IDENTIFICATION
2.1. Classification
OSHA Hazard Communication Standard, 29 CFR 1910.1200 (2012)Not classified as hazardous.
2.2. Appearance and odour (colour/form/odour)Colourless-Amber /Liquid, (viscous) / Odourless
2.3. OSHA StatusThis product is not hazardous according to the OSHA Hazard Communication Standard. 29 CFR1910.1200.
Refer to section 11 for toxicological and section 12 for environmental information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Active ingredientIsopropylamine salt ofN-(phosphonomethyl)glycine; {Isopropylamine salt ofglyphosate}
Composition
MONSANTO COMPANYRoundup CustomHTM] for Aquatic & Terrestrial Use Version: 1.0
Page: 2/9Effective date: 05/29/2015
COMPONENT CAS No. % by weight (approximate)Isopropylamine salt ofglyphosate 38641-94-0 53.8Water 7732-18-5 46.2
4. FIRST AID MEASURES
Use personal protection recommended in section
4.1. Description of first aid measures4.1.1. Eye contact: If in eyes, hold eye open and rinse slowly and gently for 15-20 minutes. Remove
contact lenses, if present, after first 5 minutes, then continue rinsing. Call a poison control center ordoctor for treatment advice.
4.1.2. Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Wash clothes and cleanshoes before re-use.
4.1.3. Inhalation: If inhaled, move person to fresh air. If person is not breathing, call emergency number orambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a poisoncontrol center or doctor for treatment advice.
4.1.4. Ingestion: Call poison control center or doctor immediately for treatment advice. Have person sip aglass of water if able to swallow. Do not induce vomiting unless told to do so by the poison center ordoctor. Do not give anything by mouth to an unconscious person.
4.2. Most important symptoms and effects, both acute and delayed4.2.1. Eye contact, short term: Not expected to produce significant adverse effects when recommended
use instructions are followed.
4.2.2. Skin contact, short term: Not expected to produce significant adverse effects when recommendeduse instructions are followed.
4.2.3. Inhalation, short term: Not expected to produce significant adverse effects when recommended useinstructions are followed.
4.2.4. Single ingestion: Not expected to produce significant adverse effects when recommended useinstructions are followed.
4.3. Indication of any immediate medical attcDtion and special treatment needed
4.3.1. Advice to doctors: This product is not an inhibitor ofcholinesterase.4.3.2. Antidote: Treatment with atropine and oximes is not indicated.
5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media5.1.1. Recommended: Water, foam, diy chemical, carbon dioxide (C02)
5.2. Special hazards5.2.1. Unusual fire and explosion hazards
None.
Minimise use of water to prevent environmental contamination.Environmental precautions: see section 6.
5.2.2. Hazardous products of combustionCarbon monoxide (CO), phosphorus oxides (PxOy), nitrogen oxides (NOx)
5.3. Fire fighting equipment: Self-contained breathing apparatus. Equipment should be thoroughlydecontaminated after use.
5.4. Flash point
MONSANTO COMPANYRoundup Custom[TM] for Aquatic & Terrestrial Use Version: 1.0
Page: 3/9Effective date: 05/29/2015
Does not flash.
6. ACCIDENTAL RELEASE MEASURES
6.1. Environmental precautionsSMALL QUANTITIES:Low environmental hazard.
LARGE QUANTITIES:Minimise spread.Keep out of drains, sewers, ditches and water ways.
6.2. Methods for cleaning upSMALL QUANTITIES:Absorb only in non-combustible material.Sweep, scoop or vacuum to remove.LARGE QUANTITIES:Absorb in earth, sand or absorbent material.
Dig up heavily contaminated soil.Collect in containers for disposal.Flush residues with small quantities of water.Minimise use of water to prevent environmental contamination.Refer to section 7 for types of containers.
Refer to section 13 for disposal of spilled material.Use handling recommendations in Section 7 and personal protection recommendations in Section 8.
7. HANDLING AND STORAGE
Good industrial practice in housekeeping and personal hygiene should be followed.
7.1. Precautions for safe handlingAvoid contact with eyes, skin and clothing. When using do not eat, drink or smoke. Wash handsthoroughly after handling or contact. Wash contaminated clothing before re-use. Thoroughly cleanequipment after use. Do not contaminate drains, sewers and water ways when disposing of equipment rinsewater. Refer to section 13 of the safety data sheet for disposal ofrinse water.
7.2. Conditions for safe storageMinimum storage temperature: -15 °CMaximum storage temperature: 50 °CCompatible materials for storage: stainless steel, fibreglass, plasticIncompatible materials for storage: galvanised steel, unlined mild steel, see section 10,Keep out of reach of children.Keep away from food, drink and animal feed.Keep only in the original container.Keep container tightly closed in a cool, well-ventilated place.Partial crystallization may occur on prolonged storage below the minimum storage temperature.If frozen, place in warm room and shake frequently to put back into solution.Minimum shelf life: 5 years.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
S.I. Airborne exposure limitsComponents Exposure Guidelines
Isopropylamine salt ofglyphosate No specific occupational exposure limit has been established.
Water ^q^pecific occupational exposure limit has been established.
MONSANTO COMPANYRoundup CustomfTMI for Aquatic & Terrestrial Use Version: 1.0
Page: 4/9Effective date: 05/29/2015
8.2. Engineering controls: No special requirement when used as recommended.
8.3. Recommendations for personal protective equipment8.3.1. Eye protection: No special requirement when used as recommended.8.3.2. Skin protection: No special requirement when used as recommended.8.3.3. Respiratory protectioD: No special requirement when used as recommended.
When recommended, consult manufacturer of personal protective equipment for the appropriate type of equipmentfor a given application.
9. PHYSICAL AND CHEMICAL PROPERTIES
These physical data are typical values based on material tested but may vary from sample to sample. Typical valuesshould not be construed as a guaranteed analysis of my specific lot or as specifications for the product.
Colour/colour range: | Colourless - AmberOdour: Odourless
Form: Liquid, (viscous)Physical form changes (melting, boiling, etc.):
Melting point: Not applicable.Boiling point: No data.
Flash point: Does not flash.
Explosi ve properties: No data.
Auto i^iition temperature: No data.
Self-accelerating decompositiontemperature (SADT):
No data.
Oxidizing properties: No data.
Specific gravity: 1.206 (3,20 °C/15.6 °C
Vapour pressure: No significant volatility; aqueous solution.Vapour density: No data.
Evaporation rate: No data.
Dynamic viscosity: No data.
Kinematic viscosity: No data.
Density: 1.206g/cm3(%20°CSolubility: Water: Completely miscible.
JES. 4.6 - 4.8 @ 63 g/1Panition coefficient: log Pow: < 0.000 (active ingredient)
10. STABILITY AND REACTIVITY
lO.l.ReactivityReacts with galvanised steel or unlined mild steel to produce hydrogen, a highly flammable gas that couldexplode.
10.2. StabilityStable under normal conditions of handling and storage.
10.3. Possibility of hazardous reactionsReacts with galvmised steel or unlined mild steel to produce hydrogen, a highly flammable gas that couldexplode.
MONSANTO COMPANYRoundup CustomfTMI for Aquatic & Terrestrial Use Version: 1.0
Page: 5/9Effective date: 05/29/2015
10.4. [Dcompatible niaterialsgalvanised steel;unlined mild steel;see section 10.;Compatible materials for storage: see section 7.2.
10.5. Hazardous decompositionThermal decomposition: Hazardous products of combustion: see section 5.
11. TOXICOLOGICAL INFORMATION
This section is intended for use by toxicologists and other health professionals.
Likely routes of exposure: Skin contact, eye contact, inhalation
Potential health effects
Eye contact, short term: Not expected to produce significant adverse effects when recommended use instructionsare followed.
Skin contact, short term: Not expected to produce significant adverse effects when recommended useinstructions are followed.
Inhalafion, short term: Not expected to produce significant adverse effects when recommended use instructionsare followed.
Single ingestion: Not expected to produce significant adverse effects when recommended use instructions arefollowed.
Data obtained on product, similar products and on components are summarized below.
Iso pro pvla mine salt of slvDliosate <'62%1
Data obtained on product and components are summarized below.Acute oral toxicitv
Rat, LD50 (limit test): > 5,000 mg/kg body weightPractically non-toxic. No mortality.
Mouse, LD50 (limit test): > 5,000 mg/kg body weightPractically non-toxic. No mortality.
Acute dermal toxicitv
Rabbit, LD50 (limit test): > 5,000 mg/kg body weightPractically non-toxic. No mortality.
Skin irritation
Rabbit, 6 animals, Draize test:Days to heal: 3Primary Irritation Index (PII): 0.0/8.0Essentially non irritating.
Eye irritation
Rabbit, 6 animals, OECD 405 test:Days to heal: 0Essentially non irritating.
Acute inhalation toxicitv
Rat, LC50, 4 hours, aerosol: > 4.24 mg/LPractically non-toxic. No mortality. Maximum attainable concentration.
Skin sensitization
Guinea pig, 3-induction Buehlertest:Positive incidence: 0 %
Negative.
N-^DhosDhonomethvIlelvcine: i filvohosate acidi
MONSANTO COMPANYRoundup Custom[TM] for Aquatic & Terrestrial Use Version: 1.0
Page: 6/9Effective date: 05/29/2015
Genotoxicitv
Not genotoxic.
Carcinoeenidtv
Not carcinogenic in rats or mice.
Reproductive/DeveloDmental Toxicitv
Developmental effects in rats and rabbits only in the presence of significant maternal toxicity.Reproductive efifects in rats only in the presence of significant maternal toxicity.
12. ECOLOGICAL INFORMATION
This section is intended for use by ecotoxicologists and other environmental specialists.
Data obtained on components are summarized below.
Isonropvlamine salt QLslvphosate f62%t
Data obtained on product and components are summarized below.
Agyatic toxicitv* fish
Bluegill sunfish (Lepomis macrochirus):Acute toxicity, 96 hours, static, LC50: > 1,000 mg/LPractically non-toxic.
Rainbow trout (Oncorhynchus mykiss):Acute toxicity, 96 hours, static, LC50: > 1,000 mg/LPractically non-toxic.
A_quatic toxicitv, invertebrates
Water flea (Daphnia magna):Acute toxicity, 48 hours, static, EC50: 930 mg/LPractically non-toxic.
Aquatic toxicitv, aleae/aquatic plants
Green algae (Scenedesmus subspicatus):Acute toxicity, 72 hours, static, EbC50 (biomass): 72.9 mg/LSlightly toxic.
Green algae (Scenedesmus subspicatus):Acute toxicity, 72 hours, static, NOEC (growth rate): 26.4 mg/L
SojjLoi^anism toxicitv« invertebrates
Earthworm (Eisenia foetida):Acute toxicity, 14 days, LC50: > 5,000 mg/kg dry soilPractically non-toxic.
N-fphosDhonomethvl'kfflvcine: i ptvnhosate acid)
Avian toxicitv
Bobwhite quail (Colinus vit^iaiaDus):Dietary toxicity, 5 days, LC50: > 4,640 mg/kg dietNo more than slightly toxic.
Mallard duck (Anas platyrhynchos):Dietary toxicity, 5 days, LC50: > 4,640 mg/kg dietNo more than slightly toxic.
Bobwhite quail (Colinus virginianus):Acute oral toxicity, single dose, LD50: > 3,851 mg/kg body weightPractically non-toxic.
Arthropod toxicitv
MONSANTO COMPANYRoundup Custom[TM] for Aquatic & Terrestrial Use Version: 1.0
Page: 7/9Effective date: 05/29/2015
Honey bee (Apis mellifera):Oral, 48 hours, LD50: 100 (tg/bee
Honey bee (Apis mellifera):Contact, 48 hours, LD50: > 100 (ig/beePractically non-toxic.
Bioaccu mu lation
Bluegill suaHsh (Lepomis macrochirus):Whole fish: BCF:<1No significant bioaccumulation is expected.
Dissipation
Soil, field:Half life: 2-174 daysKoc: 884 - 60,000 L/kgAdsorbs strongly to soil.
Water, aerobic:Half life: < 7 days
13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods13.1.1. Product
Not classified as hazardous waste by the Resource, Conservation and Recovery Act (RCRA), 40 CFR261. Keep out of drains, sewers, ditches and water ways. Recycle if appropriate facilities/equipmentavailable. Bum in proper incinerator. Follow all local/regional/nationai/intemational regulations.
13.1.2. Container
Dispose of as non hazardous industrial waste. See the individual container label for disposalinformation. Emptied containers retain vapour and product residue. Observe all labeled safeguardsuntil container is cleaned, reconditioned or destroyed. Empty packaging completely. Triple orpressure rinse empty containers. Pour rinse water into spray tank. Do NOT contaminate water whendisposing ofrinse waters. Do NOT re-use containers. Store for collection by approved wastedisposal service. Follow all locaI/regionaL/national/intemational regulations.
Use handling recommendations in Section 7 and personal protection recommendations in Section 8.
14. TRANSPORT INFORMATION
The data provided in this section is for information only. Please apply the appropriate regulations to properlyclassify your shipment for transportation.
14.1. US Depfc of Transportation (DOT) Hazardous Materials Regulations (49 CFR Parts 105-180)Proper Shipping Name
(Technical Name ifrequired):
Not regulated for domestic ground transportation. ()
14.2. IMDG CodeProper Shipping Name
(Technical Name ifrequired):
Not regulated for transport under IMO Regulations ()
14^.IATA/ICAOProper Shipping Name(Technical Name if required):
Not regulated for transport under IATA/ICAO Regulations ()
15. REGULATORY INFORMATION
MONSANTO COMPANYRoundup Custom[TM] for Aquatic & Terrestrial Use Version: 1.0
Page: 8/9Effective date: 05/29/2015
15.1. Environmental Protection Agency15.1.1. TSCA Inventory
All components are on the US EPA's TSCA Inventory
15.1.2. SARA Title III RulesSection 311/312 Hazard Categories: Not applicable.Section 302 Extremely Hazardous Substances: Not applicable.Section 313 Toxic Chemical(s): Not applicable.
15.1.3. CERCLA Reportable quantityNot applicable.
15.1.4. Federal Insecticide, Fungicide, Rodenticide Act (FIFRA)
This chemical is a pesticide product registered by the United States Environmental Protection Agencyand is subject to certain labeling requirements under federal pesticide law. These requirements differfrom the classification criteria and hazard information required for safety data sheets (SDS), and forworkplace labels of non-pesticide chemicals. The hazard infonnation required on the pesticide label isreproduced below. The pesticide label also includes other important information, including directionsfor use.
CAUTION!
Acute oral toxicity: FIFRA category W.Acute oral toxicity: FIFRA category IV.Acute dermal toxicity: FIFRA category TV,Acute inhalation toxicity: FIFRA category IV.Skin irritation: FIFRA category IV.Eye irritation: FIFRA category IV.
16. OTHER INFORMATION
The information given here is not necessarily exhaustive but is representative of relevant, reliable data.Follow all local/regional/national/intemational regulations.Please consult supplier if further information is needed.For more information refer to product label.Please consult Monsanto if further information is needed.
In this document the British spelling was applied.® Registered trademark ofMonsanto Company or its subsidiaries.
Health Flammabllity Instability Additional MarkingsNFPA 0 1 10 = Minimal hazard, 1 = Slight hazard, 2 = Moderate hazard, 3 = Severe hazard, 4 = Extreme hazard
Full denomination of most frequently used acronyms. BCF (Bioconccntration Factor), BOD(Biochemical Oxygen Demand), COD (ChemicalOxygen Demand), EC50 (50% effect concentration), ED50 (50% effect dose), I.M. (intramuscular), I.P. (intrapentoneal), I.V. (intravenous), Koc(Soil adsorption coefficient), LC50 (50% lethality concentrattoii), LD50 (50% iethality dose), LDLo (Lower limit of lethal dosage), LEL (LowerExplosion Limit), LOAEC (Lowest Observed Adverse Eft'ect Concentration), LOAEL (Lowest Observed Adverse Effect Level), LOEC (LowestObserved Effect Concentration), LOEL (Lowest Observed EfTcct Leve!), MEL (Maximum Exposure limit), MTD (Maximum Tolerated Dose),NOAEC (No Observed Adverse Effect Concentration), NOAEL (No Observed Adverse Effect Level), NOEC (No Observed EffectConcentration), NOEI. (No Observed Ettect Level), OEL (Occupational Exposure Limit), PEL (Permissible Exposure Limit), PI1 (PrimaryIrritation Index), Pow (Partition coefficient n-octanoVwater), S.C. (subcutaneous), STEL (Short-Temi Exposure Limit), TLV-C (Threshold LimitVatue-Ceiling), TLV-TWA (Threshold Limit Value - Time Weighted Average), UEL (Upper Explosion Limit)
I This Material Safety Data Sheet (MSDS) serves different purposes than and DOES NOJ REPLACE
MONSANTO COMPANYRoundup Custom[TM] for Aquatic & Terrestrial Use Version: 1.0
Page: 9/9Effective date: 05/29/2015
OR MODIFY THE EPA-APPROVED PRODUCT LABELING (attached to and accompanying theproduct container). This MSDS provides important health, safety, and environmental information foremployers, employees, emergency responders and others handling large quantities of the product inactivities generally other than product use, while the labeling provides that information specifically forproduct use in the ordinary course. Use, storage and disposal of pesticide products are regulated bythe EPA under the authority of the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA)through the product labeling, and alt necessary and appropriate precautionary, use, storage, anddisposal information is set forth on that labeling. It is a violation of federal law to use a pesticideproduct in any manner not prescribed on the EPA-approved label.
Although the information and recommendations set forth herein (hereinafter "Information") arepresented in good faith and believed to be correct as of the date hereof, MONSANTO Company or anyof its subsidiaries makes no representations as to the completeness or accuracy thereof. Information issupplied upon the condition that the persons receiving same will make their own determination as toits suitability for the purposes prior to use. In no event will MONSANTO Company or any of itssubsidiaries be responsible for damages of any nature whatsoever resulting from the use of or relianceupon information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR1MPLED, OF MERCHANTABILITy, FITNESS FOR A PARTICULAR PURPOSE OR. OP ANYOTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO FNFORMATION OR TO THEPRODUCT TO WHICH FNFORMATION REFERS.
000000043082 End of document
Safety Data Sheet
12/31/2014
6/17/2015
Replaces:
Date:
REWARD® Landscape and Aquatic
1. PRODUCT IDENTIFICATION
A12872A
Use: Herbicide
Product identifier on label: REWARD® Landscape and Aquatic
Manufacturer: Syngenta Crop Protection, LLC
Post Office Box 18300
Greensboro NC 27419
Manufacturer Phone: 1-800-334-9481
Emergency Phone: 1-800-888-8372
Product No.:
2. HAZARDS IDENTIFICATION
Danger
Classifications:
Signal Word (OSHA):
May be corrosive to metalsHazard Statements:
Harmful if swallowed
Toxic if inhaled
May cause damage to organs through prolonged or repeated exposure
Corrosive to Metals: Category 1
Oral: Category 4
Inhalation: Category 3
Specific Target Organ Toxicity: Repeated Category 2
Precautionary Statements: Keep only in original container.
Do not breathe mist, vapors, spray.
Wash hands and face thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
If swallowed: Call a poison center, doctor or Syngenta if you feel unwell. Rinse mouth.
If inhaled: Remove person to fresh air and keep comfortable for breathing.
Call a poison center, doctor or Syngenta.
Get medical advice if you feel unwell.
See Section 4 First Aid Measures.
Absorb spillage to prevent material damage.
Store locked up.
Hazard Symbols:
Page 1 of 7
Safety Data Sheet
12/31/2014
6/17/2015
Replaces:
Date:
REWARD® Landscape and Aquatic
Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name ConcentrationCommon Name CAS Number
Other ingredients Other ingredients Trade Secret 62.7%
[6,7-dihydrodipyrido(1,2-a:2',1'-c)pyrazinediium dibromide]
Diquat Dibromide 85-00-7 37.3%
4. FIRST AID MEASURES
Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment.
If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person.
If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice.
If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice.
If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment advice.
Ingestion:
Eye Contact:
Skin Contact:
Inhalation:
Indication of immediate medical attention and special treatment needed:
Most important symptoms/effects:
To be effective, treatment for ingestion of the product must begin IMMEDIATELY. Treatment consists of binding the active ingredient, diquat, in the gut with suspensions of activated charcoal or bentonite clay, administration of cathartics to enhance elimination and removal of diquat from the blood by charcoal hemoperfusion or continuous hemodialysis.
Not Applicable
5. FIRE FIGHTING MEASURES
Suitable (and unsuitable) extinguishing media:
Specific Hazards:
Special protective equipment and precautions for firefighters:
Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect runoff.
This product may form flammable and explosive hydrogen gas when in contact with aluminum.
During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.
Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion.
Flammable hydrogen gas may be formed on contact with incompatible metals. See "Conditions to Avoid", Section 10.
Other Hazard Statements:
Store in corrosive resistant plastic, plastic-lined steel, stainless steel or fiberglass container.
Dispose of contents and container in accordance with local regulations.
Page 2 of 7
Safety Data Sheet
12/31/2014
6/17/2015
Replaces:
Date:
REWARD® Landscape and Aquatic
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment, and emergency procedures:
Methods and materials for containment and cleaning up:
Follow exposure controls/personal protection outlined in Section 8.
Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition.
7. HANDLING AND STORAGE
Precautions for safe handling:
Conditions for safe storage, including any incompatibilities:
This product reacts with aluminum to produce flammable hydrogen gas. Do not mix or store in containers or systems made of aluminum or having aluminum fittings.
Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.
Store locked up.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingestion:
Eye Contact:
Skin Contact:
THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR
THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT.
FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL.
Occupational Exposure Limits:
Appropriate engineering controls:
Use effective engineering controls to comply with occupational exposure limits (if applicable).
Individual protection measures:
Chemical Name OtherOSHA PEL ACGIH TLV Source
Other ingredients Not Applicable Not Applicable Not Applicable Not Applicable
Diquat Dibromide Not Established 0.5 mg/m³ TWA inhalable; 0.1mg/m3 TWA respirable
0.5 mg/m³ TWA Syngenta
Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.
Where eye contact is likely, use chemical splash goggles.
Where contact is likely, wear chemical-resistant gloves (such as barrier laminate, butyl rubber, nitrile rubber, neoprene
Page 3 of 7
Safety Data Sheet
12/31/2014
6/17/2015
Replaces:
Date:
REWARD® Landscape and Aquatic
Inhalation:
rubber, natural rubber, polyvinyl chloride [PVC] or Viton), coveralls, socks and chemical-resistant footwear.
A respirator is not normally required when handling this substance. Use effective engineering controls to comply with occupational exposure limits.
In case of emergency spills, use a NIOSH approved respirator with any N, R, P or HE filter.
Odorless
Dark brown liquid
9. PHYSICAL AND CHEMICAL PROPERTIES
Vapor Pressure:
Solubility (ies):
pH: 4 - 6
Odor:
Appearance:
Not Available
Not Applicable
Initial boiling point and boiling range:
Melting point/freezing point:
Odor Threshold: Not Available
Not Available
Flammability: Not Applicable
Not Applicable
Not Applicable
Flash Point (Test Method):
Flammable Limits (% in Air):
Autoignition Temperature:
Vapor Density:
Relative Density:
Not AvailableDecomposition Temperature:
Not AvailableViscosity:
Not AvailablePartition coefficient: n-octanol/water:
NoneOther:
1.202 g/ml @ 68°F (20°C)
Not Available
Diquat Dibromide < 10(-8) mmHg @ 77°F (25°C)
Diquat Dibromide 718,000 mg/l @ 68°F (20°C) and pH 7.2
Incompatible materials:
Possibility of hazardous reactions: Will not occur.
Chemical stability: Stable under normal use and storage conditions.
10. STABILITY AND REACTIVITY
Flammable hydrogen gas may be formed on contact with aluminum. See "Conditions to Avoid", Section 10.
Hazardous Decomposition Products:
Reactivity: Not reactive.
Conditions to Avoid: Concentrate should not be stored in aluminum containers. Spray solutions should not be mixed, stored or applied in containers other than plastic, plastic-lined steel, stainless steel or fiberglass.
None known.
Page 4 of 7
Safety Data Sheet
12/31/2014
6/17/2015
Replaces:
Date:
REWARD® Landscape and Aquatic
11. TOXICOLOGICAL INFORMATION
Numerical measures of toxicity (acute toxicity/irritation studies (finished product))
Chronic/Subchronic Toxicity Studies
Carcinogenicity
Toxicity of Other Components
Ingestion:
Dermal:
Inhalation:
Eye Contact:
Skin Contact:
Skin Sensitization:
Oral (LD50 Female Rat) :
Mildly Irritating (Rabbit)
Slightly Irritating (Rabbit)
Not a Sensitizer (Guinea Pig)
Dermal (LD50 Rabbit) :
Inhalation (LC50 Rat) :
886 mg/kg body weight
> 5050 mg/kg body weight
0.62 mg/l air - 4 hours
Target Organs
Other Toxicity Information
None
Reproductive/Developmental Effects
Active Ingredients
Inert Ingredients
Likely routes of exposure:
Health effects information
Symptoms of exposure:
Delayed, immediate and chronic effects of exposure:
Diquat Dibromide: Kidney weight decreases and cataracts seen in dogs at 12.5 mg ion/kg/d.No evidence for neurotoxic effects in rats dosed up to 400 ppm ion in the diet for 13 weeks.
Diquat Dibromide: No evidence of carcinogenicity in rat and mouse studies.
Not Applicable
Other ingredients
Diquat Dibromide: Mutagenicity: No evidence in in vivo assays.Development Toxicity: In rabbit studies a small percentage of fetuses had minor defects at 3 and 10 mg ion/kg/d.
Diquat Dibromide: Eye, kidney
Other ingredients: Not Applicable
Chemical Name NTP/IARC/OSHA Carcinogen
Other ingredients No
[6,7-dihydrodipyrido(1,2-a:2',1'-c)pyrazinediium dibromide]
No
Dermal, Inhalation
Not Applicable
Not Applicable
Page 5 of 7
Safety Data Sheet
12/31/2014
6/17/2015
Replaces:
Date:
REWARD® Landscape and Aquatic
12. ECOLOGICAL INFORMATION
Environmental Fate
Eco-Acute Toxicity
The information presented here is for the active ingredient, diquat dibromide.Stable in soil and water. Immobile in soil. Sinks in water (after 24 h).
Diquat Dibromide:
Diquat Dibromide:
Fish (Rainbow Trout) 96-hour LC50 14.83 ppm
Invertebrate (Water Flea) Daphnia Magna 48-hour EC50 0.77 ppm
Green Algae 4-day EC50 9.4 ppb
Bird (Mallard Duck) 14-day LD50 60.6 mg/kg
13. DISPOSAL CONSIDERATIONS
Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations.
Characteristic Waste: Not Applicable
Listed Waste: Not Applicable
Disposal:
14. TRANSPORT INFORMATION
DOT Classification
Ground Transport - NAFTAProper Shipping Name: Corrosive Liquid, N.O.S. (Diquat Dibromide)Hazard Class: Class 8Identification Number: UN 1760Packing Group: PG III
Comments
Water Transport - InternationalProper Shipping Name: Corrosive Liquid, N.O.S. (Diquat Dibromide), Marine PollutantHazard Class: Class 8Identification Number: UN 1760Packing Group: PG III
Air TransportProper Shipping Name: Corrosive Liquid, N.O.S. (Diquat Dibromide)Hazard Class: Class 8Identification Number: UN 1760Packing Group: PG III
Page 6 of 7
Safety Data Sheet
12/31/2014
6/17/2015
Replaces:
Date:
REWARD® Landscape and Aquatic
15. REGULATORY INFORMATION
RCRA Hazardous Waste Classification (40 CFR 261):
Not Applicable
TSCA Status:
Exempt from TSCA, subject to FIFRA
EPCRA SARA Title III Classification:
Section 311/312 Hazard Classes:
Section 313 Toxic Chemicals:
CERCLA/SARA 304 Reportable Quantity (RQ):
Report product spills >= 268 gal. (based on diquat [RQ = 1,000 lbs.] content in the formulation)
Pesticide Registration:
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
EPA Registration Number(s):
100-1091
None
Acute Health Hazard
Caution: Harmful if inhaled. Harmful if swallowed. Causes moderate eye irritation. Avoid breathing spray mist. Avoid contact with eyes, skin, or clothing.
1
00
1
2
16. OTHER INFORMATION
NFPA Hazard Ratings
6/27/2007
12/31/20146/17/2015
Health:
Flammability:
Instability:
Replaces:
Original Issued Date:
Revision Date:
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.
HMIS Hazard Ratings
Health:
Flammability:
Reactivity:
0 Minimal
1 Slight
2 Moderate
3 Serious
4 ExtremeCSyngenta Hazard Category:
2, 4, 11, 16Section(s) Revised:
* Chronic
2
For non-emergency questions about this product call:
1-800-334-9481
Page 7 of 7
Attachment II
Analytical Data – Effluent Characterization
#=CL#
April 09, 2018
LIMS USE: FR - SHANNON BRIGGS
LIMS OBJECT ID: 60266820
60266820
Project:
Pace Project No.:
RE:
Shannon BriggsBP ARCADIS WY111 Star LaneCasper, WY 82604
OUTFALL-001 PERMIT RENEWAL
Dear Shannon Briggs:
Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2018. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Richard Mannz
PM Lab Management(913)599-5665
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 1 of 19
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Kansas Certification IDs
9608 Loiret Boulevard, Lenexa, KS 66219
WY STR Certification #: 2456.01
Arkansas Certification #: 17-016-0
Illinois Certification #: 200030
Iowa Certification #: 118
Kansas/NELAP Certification #: E-10116
Louisiana Certification #: 03055
Nevada Certification #: KS000212018-1
Oklahoma Certification #: 9205/9935
Texas Certification #: T104704407
Utah Certification #: KS00021
Kansas Field Laboratory Accreditation: # E-92587
Missouri Certification: 10070
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 2 of 19
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Lab ID Sample ID Matrix Date Collected Date Received
60266820001 001-032618 Water 03/26/18 14:30 03/27/18 08:50
60266820002 001-032618-DUP Water 03/26/18 14:35 03/27/18 08:50
60266820003 FB01 032618 Water 03/26/18 14:45 03/27/18 08:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 3 of 19
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Lab ID Sample ID Method
Analytes
ReportedAnalysts
60266820001 001-032618 SM 2120B 1OL
SM 2540D 1OL
SM 5210B 1RAD
EPA 350.1 1LDB
EPA 410.4 1MJK
SM 5310C 1LDF
60266820002 001-032618-DUP SM 2120B 1OL
SM 2540D 1OL
SM 5210B 1RAD
EPA 350.1 1LDB
EPA 410.4 1MJK
SM 5310C 1LDF
60266820003 FB01 032618 SM 2120B 1OL
SM 2540D 1OL
SM 5210B 1RAD
EPA 350.1 1LDB
EPA 410.4 1MJK
SM 5310C 1LDF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 4 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Sample: 001-032618 Lab ID: 60266820001 Collected: 03/26/18 14:30 Received: 03/27/18 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 2120B2120B W Apparent Color
Apparent Color 20.0 units 03/28/18 06:001.0 1
Analytical Method: SM 2540D2540D Total Suspended Solids
Total Suspended Solids ND mg/L 03/31/18 09:335.0 1
Analytical Method: SM 5210B Preparation Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND mg/L 04/01/18 09:2703/27/18 11:492.0 1
Analytical Method: EPA 350.1350.1 Ammonia
Nitrogen, Ammonia ND mg/L 04/05/18 19:34 7664-41-70.10 1
Analytical Method: EPA 410.4410.4 COD
Chemical Oxygen Demand 29.7 mg/L 04/06/18 10:0610.0 1
Analytical Method: SM 5310C5310C TOC
Total Organic Carbon 7.5 mg/L 04/03/18 23:05 7440-44-02.0 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 5 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Sample: 001-032618-DUP Lab ID: 60266820002 Collected: 03/26/18 14:35 Received: 03/27/18 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 2120B2120B W Apparent Color
Apparent Color 15.0 units 03/28/18 06:001.0 1
Analytical Method: SM 2540D2540D Total Suspended Solids
Total Suspended Solids ND mg/L 03/31/18 09:345.0 1
Analytical Method: SM 5210B Preparation Method: SM 5210B5210B BOD, 5 day
BOD, 5 day 4.6 mg/L 04/02/18 08:3003/28/18 08:322.0 1
Analytical Method: EPA 350.1350.1 Ammonia
Nitrogen, Ammonia 0.17 mg/L 04/05/18 19:36 7664-41-70.10 1
Analytical Method: EPA 410.4410.4 COD
Chemical Oxygen Demand 31.9 mg/L 04/06/18 10:0610.0 1
Analytical Method: SM 5310C5310C TOC
Total Organic Carbon 7.3 mg/L 04/03/18 14:20 7440-44-01.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 6 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Sample: FB01 032618 Lab ID: 60266820003 Collected: 03/26/18 14:45 Received: 03/27/18 08:50 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 2120B2120B W Apparent Color
Apparent Color ND units 03/28/18 06:001.0 1
Analytical Method: SM 2540D2540D Total Suspended Solids
Total Suspended Solids ND mg/L 03/31/18 07:245.0 1
Analytical Method: SM 5210B Preparation Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND mg/L 04/02/18 08:3203/28/18 08:372.0 1
Analytical Method: EPA 350.1350.1 Ammonia
Nitrogen, Ammonia ND mg/L 04/05/18 20:23 7664-41-70.10 1
Analytical Method: EPA 410.4410.4 COD
Chemical Oxygen Demand ND mg/L 04/06/18 10:0710.0 1
Analytical Method: SM 5310C5310C TOC
Total Organic Carbon ND mg/L 04/03/18 14:33 7440-44-01.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 7 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
519383
SM 2120B
SM 2120B
2120B Color
Associated Lab Samples: 60266820001, 60266820002, 60266820003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2126079
Associated Lab Samples: 60266820001, 60266820002, 60266820003
Matrix: Water
Analyzed
Apparent Color units ND 1.0 03/28/18 06:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 8 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
519966
SM 2540D
SM 2540D
2540D Total Suspended Solids
Associated Lab Samples: 60266820001, 60266820002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2128209
Associated Lab Samples: 60266820001, 60266820002
Matrix: Water
Analyzed
Total Suspended Solids mg/L ND 5.0 03/31/18 09:29
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
60266774001
2128210SAMPLE DUPLICATE:
Total Suspended Solids mg/L 6300 D620 105170
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
60266789002
2128211SAMPLE DUPLICATE:
Total Suspended Solids mg/L 41.0 2 1042.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 9 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
519967
SM 2540D
SM 2540D
2540D Total Suspended Solids
Associated Lab Samples: 60266820003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2128212
Associated Lab Samples: 60266820003
Matrix: Water
Analyzed
Total Suspended Solids mg/L ND 5.0 03/31/18 07:23
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
60266821001
2128213SAMPLE DUPLICATE:
Total Suspended Solids mg/L 14.8 5 1015.6
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
60266822001
2128214SAMPLE DUPLICATE:
Total Suspended Solids mg/L 19.2 D611 1017.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 10 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
519302
SM 5210B
SM 5210B
5210B BOD, 5 day
Associated Lab Samples: 60266820001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2125754
Associated Lab Samples: 60266820001
Matrix: Water
Analyzed
BOD, 5 day mg/L ND 2.0 04/01/18 08:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2125755LABORATORY CONTROL SAMPLE:
LCSSpike
BOD, 5 day mg/L 189198 96 85-115
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
60266760004
2125756SAMPLE DUPLICATE:
BOD, 5 day mg/L 385 D649 17233
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 11 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
519391
SM 5210B
SM 5210B
5210B BOD, 5 day
Associated Lab Samples: 60266820002, 60266820003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2126113
Associated Lab Samples: 60266820002, 60266820003
Matrix: Water
Analyzed
BOD, 5 day mg/L ND 2.0 04/02/18 08:23
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2126114LABORATORY CONTROL SAMPLE:
LCSSpike
BOD, 5 day mg/L 180198 91 85-115
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
60266826001
2126115SAMPLE DUPLICATE:
BOD, 5 day mg/L ND 172.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 12 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
520666
EPA 350.1
EPA 350.1
350.1 Ammonia
Associated Lab Samples: 60266820001, 60266820002, 60266820003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2131073
Associated Lab Samples: 60266820001, 60266820002, 60266820003
Matrix: Water
Analyzed
Nitrogen, Ammonia mg/L ND 0.10 04/05/18 20:19
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2131074LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Ammonia mg/L 5.55 110 90-110
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2131075MATRIX SPIKE SAMPLE:
MSSpike
Result
60266871001
Nitrogen, Ammonia mg/L 10.05 97 90-1105.2
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2131077MATRIX SPIKE SAMPLE:
MSSpike
Result
60266959001
Nitrogen, Ammonia mg/L 4.65 92 90-110ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
60267002002
2131076SAMPLE DUPLICATE:
Nitrogen, Ammonia mg/L ND 18<0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 13 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
520658
EPA 410.4
EPA 410.4
410.4 COD
Associated Lab Samples: 60266820001, 60266820002, 60266820003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2131042
Associated Lab Samples: 60266820001, 60266820002, 60266820003
Matrix: Water
Analyzed
Chemical Oxygen Demand mg/L ND 10.0 04/06/18 10:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2131043LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand mg/L 51.150 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2131044MATRIX SPIKE SAMPLE:
MSSpike
Result
60266774002
Chemical Oxygen Demand mg/L 3970 M11250 74 90-1103040
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2131046MATRIX SPIKE SAMPLE:
MSSpike
Result
60266960001
Chemical Oxygen Demand mg/L 172 M150 89 90-110127
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
60266873001
2131045SAMPLE DUPLICATE:
Chemical Oxygen Demand mg/L 55.9 1 2556.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 14 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
520186
SM 5310C
SM 5310C
5310C Total Organic Carbon
Associated Lab Samples: 60266820001, 60266820002, 60266820003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2129069
Associated Lab Samples: 60266820001, 60266820002, 60266820003
Matrix: Water
Analyzed
Total Organic Carbon mg/L ND 1.0 04/03/18 10:54
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2129070LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon mg/L 5.25 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2129071MATRIX SPIKE SAMPLE:
MSSpike
Result
60266629004
Total Organic Carbon mg/L 7.1 M15 68 80-1203.7
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
60266629005
2129072SAMPLE DUPLICATE:
Total Organic Carbon mg/L 1.2 7 251.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 15 of 19
#=QL#
QUALIFIERS
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 16 of 19
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
60266820
OUTFALL-001 PERMIT RENEWAL
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
60266820001 519383001-032618 SM 2120B
60266820002 519383001-032618-DUP SM 2120B
60266820003 519383FB01 032618 SM 2120B
60266820001 519966001-032618 SM 2540D
60266820002 519966001-032618-DUP SM 2540D
60266820003 519967FB01 032618 SM 2540D
60266820001 519302 520169001-032618 SM 5210B SM 5210B
60266820002 519391 520160001-032618-DUP SM 5210B SM 5210B
60266820003 519391 520160FB01 032618 SM 5210B SM 5210B
60266820001 520666001-032618 EPA 350.1
60266820002 520666001-032618-DUP EPA 350.1
60266820003 520666FB01 032618 EPA 350.1
60266820001 520658001-032618 EPA 410.4
60266820002 520658001-032618-DUP EPA 410.4
60266820003 520658FB01 032618 EPA 410.4
60266820001 520186001-032618 SM 5310C
60266820002 520186001-032618-DUP SM 5310C
60266820003 520186FB01 032618 SM 5310C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 03:32 PM
Pace Analytical Services, LLC
9608 Loiret Blvd.
Lenexa, KS 66219
(913)599-5665
Page 17 of 19
Page 18 of 19
Page 19 of 19