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964oM -°27

RYDR06FOLOG/CaL.

ASSESSMENT EPoIr'ww. 'f p ~,~,~ ors ~uP

ACTRR I> PfTA

FromNORMA S . FUJIKAWA

I I

FtZOµ s eQT sAMPu~.Aer 1>sLTA 4L ptss+

CLIENT : GROUNDWATER RESOURCES

PROJECT It : 864 0PROJECT NAME : ROCKETDYNE SSFL

ATI I .D .

AnalyIicoITechnologies,lnc. '3115 t88

: 803149

DATE RECEIVED : 03/16/8 8

REPORT DATE : 03/31/8 8

--------------- ------------------------------- -

ATI # CLIENT DESCRIPTION

----- --- - -- - - -- -- --- - - - - - - -- ---4

FLUOR-3 D e- - -- --

I tt MATRIX DATE COLLECTED

-------------------------------

01 RS-10 WATER 03/15/88

02 ABSP4 1 .0'-1 .5' T SOIL 03/15/88 -

03 ABSPS 1 .0'-1 .5' T SOIL 03/15/88

04 ABSP6 1.0'-1 .5' T ~DIL 03/15/880 ABSP6 2 .5'-3 .0' SUIZ 03/15/88

06 ABSP7 1 .0'-1 .5' T SOIL 03/15/88

_07 ABSPS 1 .0'-1 .5' T 7.`.9 SOIL 03/15/88

08 DELTA5 1 .2'-1 .7' T G+(6 7.77 SOIL 03/15/88

09 DELTA6 1 .2'-1 .7' 9.17 SOIL 03/15/88

FOR COMPARISO N

BACKGROUND SAMPLE (taken 300'H.of x5-6 , E. of ALFA facili ty)

NO VOLATILE ORGANICS except- for 0.1 &-g/kg TOLUENENO BASE NEUTRALS OR ACID ORGANICS except for 0.68 DI-N-BUTYLNO FORMALDEHYDE PHTHALAT ENO FLUORIDENO KEROSENE

3 HYDROCARBONS (C10-C24) at 3,1 . 1 ag/kg

SOIL pH = 6 .6

I IBNA0138182 9

HDMSe00214355

Pte :19W w-846

ROGdceT9 YN£ IM Fb U NDM EAITS

SURFACE IMPOUNDMENT FINDING S

Mvrc 20(5, ,, va NO VOLATILE ORGANICS :,tea fo✓ K O5 EPo - NO ACID ORGANICS

Ir,re. .ffut I Z J87 Rte- - NO BASE NEUTRALSNO "FOP L4LDEBIDE

u(~t6

A P T F I + 2 j' I t . 6.1 ---, 10 .0

1 [FLUORIDE in AP27--1 - 54-130 mg/kg(FLUORIDE £1 APTF-2 - 71-282 mg/kgE'EROSF.VE in both - 15 mg/kgDIb7HIL PM7MLATE in AP1T-- 2- 0.02-0.05 mg/kg

*SoZub24 Limit 11v eshoZd Conc. (STZC) Title 22- 180 mg

+S B ACK GriD = Q. O Z 1;~~

6015 A.! . M,c,ozl e e 'lU

{0 .(L."- 4ov {Ca1t.o-en.in.c. 4-J;44- C8.- Z41 zk & GC ,, +&o d w ~. ~,ea w~¢00.

aj,-Jio ► a oL c c~.~t i.F,Q a n~ C04" -_ A.4-

&',4 Gs JL , AdEK,

EC L

2 , 2,4 , and 6 mg/kg methylene chloride0 .6 mg/kg TC E1 mg/kg trichlorofluoromethane (Freon HF ; Freon 11 )up to 1300 mg/kg sulfate (from data on early HAR work before it was discontinued )

SURFACE IMPOUNDMENT FINDINGS STL - IV-1

NO YOLATILE ORGANICSNO ACID ORGANICSMM0SE1VE 27 mg/kg

i -NITROSODIPHE2ITL 4HIRE 0.03, 0.04 mg/kg---LAf3 814G2D = 0.02

pH 8.2-10. 0BIS (2-EvEz BEI) PHTHALATE

LAe SK Ga-D 0 . 41 mg/kc0.oz FLUOPA'9THETE 0 .03 mg/kgo.04 PHENAN:HR VE' 0.06, 0 .10 mg/kg

PYRE7IE 0.02 mg/kg

ST-17 - 2

NO POMALDEHIDE PH 7.7- 8.0NO VOLATILE ORGANICS ABOVE LAB DbTE TI08 LDfIINO ACID ORGANICS DISzfIL PHTHALATE 0.03 mg/kg

8 CK G u D 9 -r or- ALFA :

BACKGROUND SAMPLE ( taken 300'N .of HS-6, E . of ALFA facility )

NO VOLATILE ORGANICS except for 0 .1 mg/kg TOLUENENO BASE NEUTRALS OR ACID ORGANICS except for 0 .68 DI-N-BUTYL PHTHALATENO FORMALDEHYDENO FLUORIDENO KEROSEN E

3 HYDROCARBONS (CIO-C24 ) at 3,1,1 mg/kg

SOIL pH - 6 .6

I IBNA0138183 0

SURFACE IMPOUNDMENT FINDINGS

HDMSe00214356

pp' sU?.FA{E7 lMPOUMitHAR j~>Ai-p~

SURFACE IMPOUNDMENT FINDINGS ABSP _ P tt 7.9 - $.4 \

NO VOLATILE ORGANICS VVZD. HYDROCARBONS AT 17 and 140 mg/kgNO ACID ORGANICS N1TROSOD1PE0TLANIRE AT 0 .12 mg/kg where detect. 0.IC

NO XEROSFIPE

SURFACE IMPOUNDMENT FINDINGS DELTA

PH 7.3 - 8 . 0

TOTAL PLHORIDE 63-570 mg/kg TOTAL ZYLPYES 0 .6 and 6 .20 mg/kgDISSOLVED FLUORIDE 4.8-63 mg/kg BENZENE 0.07 mg/kgTRICHZOROETHYLERE 84 mg/kg 81'RYLBENZENE 0.2E a9/kg . r

SURFACE IMPOUNDMENT FINDING S

90 VOLATILE ORGANICS50 ACID ORGANICSNO BASE/NEUTRALSa0 FO10LALDP.SIDE

PLP

pH 7.7- 10 . 0

SURFACE IMPOUNDMENT FINDINGS SPA - I (14pec; -for

NO•VOLATILE ORGANICSNO ACID ORGANICSNO FORMALDEHYDE

p H

TOTAL FLUORIDE 63-95 mg/kgO .I 8

EIS-(2 - ETBYL EA L ) PHTHALATE 0.19 + 0.23 mg/k g

DI-ETHYL PHTHALATE 0.04 mg/kg --dst . li.mit /

SURFACE IMPOUNDMENT FINDINGS SPA- 2 (used for NTO rineates)

NO VOLATILE ORGANICS pH 4 . 8 - 9 . 3NO ACID ORGANICS TOTAL FLUORIDE 70 - 110 mg/kg

NO BASE/NEUTRALSNO FORMALDEHYDE

BEK. KGROVND EPssT OF A IFPr

NO FORMALDEHYDENO FLUORID ENO KEROSENE

3 HYDROCARBONS (CIO-C24) at 3,1 . 1 mg/kgSOIL pH -6.6

NO BASE NEUTRALS OR ACID ORGANICS except for 0 .68 DI-N-BUTYL PHTHALATE

BACKGROUND SAMPLE (taken 300'N . of WS-6, E. of ALFA facility)

NO VOLATILE ORGANICS except for 0 .1 mg/kg TOLUENE

BNA0138183 1

HDMSe00214357

SPLIT 5AM ?LIMG OFFSALL RESULTS IN MG/KG 3115166Split Sampling with DOHS 3/15/8 8

ABSP5 1 .0' - 1 .5' TDecalin - 4, 10Nitrated H-C12 - 8No VOAsNo Xylene sNo Semi -Volatile organic sNo base neutrals ( NDMA)(MTH 8270)Aromatic H-C13 - 2Branched HC14 - 3Extractable

C6 - C18 - 3000C19- C30 - 900

ABSP6 1 .0' - 1 .5' TBo semi-volatiles , no base/neutrals(MTH 8270)No VOAsNo Xylene sOxygenated H - C16 - 0 .1Phthalate - 0 . 3Aromatic H - C30 - 0 . 3

ABSP6 2 . 5' - 3 .0' TNo semi -volatiles, no base/neutrals ~TH 8270No VOAs .No XylenesOxygenated H - C16 - 0 .1Aromatic H - C24 - 0 .3phthalate - 0 .2branched H-C28 - 0 .3molecular sulfur - 0 . 3

ABSP7 1 .0 ' - 1 .5' TNo VOAS ; No semi -volatiles ; no base/neutralsTotal Xylenes - 0 .1 3Decalin - 5Nitrated C12 - 5Aromatic H-C13 - 3Branched H-C12 - 5Branched H-C14 - 5Extractable H-C6-18 - 2000

ae

ABSP8 1 . 0' - 1 .5' TNo semi-volatiles ; no base/neutralsNo VOAsNo Xylenes

Branched HC14 - 1Branched HC15 - 1Branched HC16 - 1Branched HC16 - 1Branched HC17 - 0 . 7

Extractable H-C14 - C20 - 40

ABSP4 1 .0' - 1 .5' TMETH 8270No semi-organics ( phenols)No base neutrals (NDMA)VOAs not don e

0 .8 of C151 of C160 .8 of C161 of C172 of C25

BNA0138183 2

HDMSeOO214358

Decalin is found in kerosene (also found in hydrogeneration of aromatics) ATalso found amounts of Decalin which is trade name for DECAHYDRONAPHTHALENEClOH18 which is a motor fuel additive , lubricant

Petrol HC ranges Boiling Poem-r) Celli T-16

Light solvents = C3 or less <50°Dave had gasoline = C4 - C13 706 - 160 °this list jet fuel = C12 - C16 1500 - 220°from Diesel Fuel = C12 - C23 150° - 275°Analytical Motor oil = C20-* 250 0Technologies

Note : RP-1 is a straight -run kerosene fraction with a boiling range of180-300 ° C, i . e . - like diesel fuel . R ` I 7 . rr' = 0,0 1

-In their analytical methods, the CA RWQCB ( SF) defined fuel hydrocarbons as :GASOLINE - ( C4 - C12 ) ; JET FUEL ( C10-C16 ) ; DIESEL ( Cg - C22 )

SA I 'C SAMPLING W,rW ..Df+S

:Ps CV4

DELTA5 1 .2' - 1 .7' TNo semi -volatilesNo VOAsNo Xylenesoxygenated H-C16 - 0 .1phthalate - 0 .2Oxygenated HC22 - 0 .2Oxygenated HC30 - 0 . 1

DELTA6 1 .2' - 1 .7' TNo semi -volatiles , No base neutrals

No VOA sNo xylenesphthalate - 0 .9branched HC20 - 0 .2

BNA0138183 3HDMSe00214359

GROUNDWATER RESOURCES CONSULTANTS, INC .

BAR WELLS ASSOCIATED WITH RCRA IMPOUNDMENT S

IMPOUNDMENT NAME WELL IDENTIFIER

APTF 1 & 2 BAR IHAR 2BAR 3HAR 4

HAR 16HAR 24HAR 25

NNSA

1

SPA 1 & 2 HAR 5 HAR 15HAR 6 HAR 22

2A9SA X HAR 12 HAR 2 3HAR 1 3BAR 14

HAR 3 0HAR 3 1

-----------------------------------------------------------------------

ECL BAR 26

-----------------------------------------------------------------------

NA5A DELTA & PLF

A R EA XBAR 7HAR 8HAR 27

HAR 28HAR 2 9

STL-IV I & 2 HAR 1 7HAR 1 8HAR 32

HAR 3 3BAR 34

Nash ABSP AAEA m~. HAR 9HAR 1 1BAR 19

HAR 20HAR 21

BNA0 136 1 836

HDMSe00214360

------------/ COMPOUNDS

o.D--- 826

N-NITROSODIMETHYLAMINEANILINE

BIS(2-CHLOROETHYL)ETHER

"BENZYL ALCOHOL1,2-DICHLOROBENZENEBIS(2-CHLOROISOPROPYL)ETHERN-NITROSO-DI-N-PROPYLAMINEHEXACHLOROETHANENITROBENZENEISOPHORONE

\BENZOIC ACID

BIS(2-CHLOROETHOXY)METHANE1,2,4-TRICHLOROBENZENE

---0- NAPHTHALENE\4-CHLOROANILINEHEXACELOROBUTADIENE

\2-METHYLNAPHTHALEN EHEXACHLOROCYCLOPENTADIENE2-CHLORONAPHTHALENE'2-NITROANILINEDIMETHYL PHTHALATEACENAPHTHYLENE

\3-NITROANILINEACENAPHTHENE

DIBENZOFURAN2,4-DINITROTOLUENE2,6-DINITROTOLUENEDIETHYPHTHALATE4-CHLOROPHENYL-PHENYLETHERFLUORENE

'•4-NITROANILINEN-NITROSODIPHENYLAMINE(1)4-BROMOPHENYL-PHENYLETHERHEXACHLOROBENZENEPHENANTHREN EANTHRANCENE

=-T DI-N-BUTYLPHTHALATEFLUORANTHENEBENZIDINE

.RENE

,TYLBENZYLPETHALATE3,3-DICHLOROBENZIDINEBENZ0(a)ANTHRACENE

BIS(2-ETHYL HEXYL)PHTHALATECARYSENE

DI-N-OCTYL PHTHALAT EBENZ0(b)FLUORANTHENEBENZ 0 (k) FLUORANTHENEBENZO (a) PYREN EINDENO(1,2,3-cd)PYRENED IB ENZ (a, h) ANTHRACENEBENZO (9, h, i) PERYLENE

COMPOUNDS----- ME-l{oD U2 /Q --------------------------PHENOL

2-CHLOROPHENOL2-METHYLPHENOL4-METHYLPHENOL Vo UnfTl 1..E2-NITROPHENOL2,4-DIMETHYLPHENOL (PHENOLS)2,4-DICHLOROPHENOL4-CHLORO- 3-METHYLPHENOL2,4,6-TRICHLOROPHENOL12,4,5-TRICHLORCPHENOL2,4-DINITROPHENOL4-NITROPHENOL

4,6-DINITRO-2-METHYLPHENOL I JPENTACHLOROPHENOL

COMPOUNDS tni oD 22 -O-------------------------CHLOROMETHANEBROMOMETHANEVINYL CHLORIDECHLOROETHANE

b.-METHYLENE CHLORIDEACETON ECARBON DISULFIDE

1,1-DICHLOROETHENE1,1-DICHLOROETHAN E

' 'TRANS-1,2-DICHLOROETHENECHLOROFORM

1,2-DICHLOROETHANE2-BUTANONE (MEK)

- ~b-1,1,1-TRICHLOROETHANECARBON TETRACHLORIDEVINYL ACETATEBROMODICHLOROMETHAN E1,1,2,2-TETRACHLOROETHANE1,2-DICHLOROPROPANETRANS-I,3-DICHLOROPROPENE

"P-TRICHLOROETHENE

DIBROMOCHLOROMETHANE1, 1, 2-TRICHLORETHANEBENZENECIS-1,3-DICHLOROPROPENE2-CHLOROETHYLVINYLETHERBROMOFORM2-HEXANONE (MBK )4-METHYL- PENTANONE (MIBK)TETRACHLOROETHEN ETOLUENE

CHLOROBENZENE

ETHYL BENZENE

STYRENETOTAL XYLENES

CS

BNA0138183 5

1,3-DICHLOROBENZENE1, 4-DICHLOROBENZENE

H DMSe00214361

w84-80151 . NONHALOGENATED VOLATILE ORGANIC S

AcrylamideDiethyl etherEthanolMethyl ethyl ketone (MEK)Methyl isobutyl ketone (MIBK)Paraldehyde (trimer of acetaldehyde )

__A~ a_tA4_

8015 - 2

'i ffRevision 0Date September 1986

I IBNA0138183 6

HDMSe00214362

Vbl-ATlt_ ORCil4NlC 5

Gc - ,)~a~ ,4-c,Q~ c,a- e .2Qo- Gr e -7

Z. S

EPA 8oia 0-'~. LS

Lewu.4 Cu rr w ct a ~ru x.24 ~i 2L =

g2(OD

0 . 5,1,11 L_

G0,55 V OA ,

ER lFQA' AT~~ C(5 - 1 2 '- t..-~ TR!-N5 -1, Z- D(C1WRCCT14€N'c

ASD. Jr MG, 1LG W 4-r w GT ~o v w -i, cT~d_ .5 ^ (L o.r C k1 .

PQL ,4--

F I .DSsc I ~ K-QoSEva ~ 44 Jy+t . uau~ a iwx-4n L.'

~ P g 0 l _ ~,o .su-c~Z .0 0G C .ck.,t . o v'- • - . u~ ~~ ~: ~.~ ,~,~„~ M ,k

EPA Fs O V0 A- 6t ac, -or C64,

BNA0 138 1 83]

M ETff'D FQrLW ME ~i ec~ a 2 .tea-e

`.~+ ...r, o~ e n acs c. ~+tzet t,te co-~ ut

` EPA 4 ~S2o V l„PrT1 LE kl rt. (C5

Gc /i+-a 5 lucu~ s ,-r c sspJ a"e-

!f7aca,c-' S P - I coo o-» cevxn" 6o -So

C~~ A

Ttr ::~, l_

~4 J / L T~ S

AA- Jlkl

3 n w alZ 51-1 ;3 ,~,vr~-~o~ S

3u1LF14CE

1M9ouMD M 4r.

APTF-1Area I/Rocketdyne

APTF-2Area I /Rocketdyne

ABSP

SPA-1

SPA-2

Delta

PLF

STL-IV-1

STL-IV-2

ECL

CAPPcTY,

IN TOTA L

SkfT GA LLO M 5

26' x 30'Cri

` 80GA 6-& .O

40#600

40' x 55' 2,200

based on 7' dept h

131,60 0

75' x 295' 22,125

based on B' dept h

295,000

50' x 25' 1,965 41,300Diameter based on 5' dept h(oval )

20' x 40' 800 18,000(rectangle) based on 3' dept h

85' x 90' 7,650 572,000

34' x 20' 680

based on 10' depth

20,000

83' x 112' 9,296

based on 7' depth

278,140

50' x 118' 5,900 441,00 0

oval-shaped 1,200

based on 10' dept h

44,000