richard d. mccullough mellon college of science carnegie ... · 1999-2000: technical advisory...

Richard D. McCullough Mellon College of Science Carnegie Mellon University

4400 Fifth Avenue Pittsburgh, PA 15213 Tel: (412) 268-5124

Date of Birth: April 9, 1959

PROFESSIONAL APPOINTMENTS 2001-Present: Dean, Mellon College of Science 1998-2001: Head of Chemistry, Carnegie Mellon University 1998-Present: Professor, Department of Chemistry, Carnegie Mellon University 1996-1997: Associate Head of Chemistry, Carnegie Mellon University 1995-1998: Associate Professor, Department of Chemistry, Carnegie Mellon University 1990-1995: Assistant Professor, Department of Chemistry, Carnegie Mellon University 2002-Present: Founder and Board of Directors, Plextronics, Inc. 2002-Present: Scientific Infrastructure Investment Committee, Pittsburgh Life Sciences Greenhouse 2001-Present: Board of Directors, Mellon Pittsburgh Corporation 2004-Present: State of Washington Nanotechnology Initiative Steering Committee (only out-of-state academic representative) 1999-2000: Technical Advisory Board, BF Goodrich Performance Materials 1999-2001: Chair of the Board, Cyert Center for Early Education 1998-Present: Editorial Board, Advanced Materials 1994-2000: International Advisory Board, Journal of Materials Chemistry 1996: Visiting Professor, University of Copenhagen 1993-1995: Consultant for the Polaroid Corporation in Cambridge, MA,

EDUCATION

1988-1990 Postdoctoral Fellow, Columbia University, New York, NY Research Advisor: Professor Ronald Breslow

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1982-1988 Ph.D., Organic Chemistry, The Johns Hopkins University, Baltimore, MD Research Advisor: Professor Dwaine O. Cowan 1977-1982 B.S., Chemistry, cum laude 1982, The University of Texas at Dallas

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PRINCIPAL RESEARCH INTERESTS

Organic and Materials Chemistry. Development of Nanoelectronic Materials and Devices Based on Conductive Polymers. Regioregular Polythiophenes. Self-Assembly, Nanofabrication, and Synthesis of Highly Conductive Organic Conducting Polymers for Use as Transistors, Sensors, Electrostatic Dissipative Materials, Hole Transport Layers in Organic Light Emitting Diodes. Conjugated Polymer Hybrid MEMS Sensors. Biomaterials. New Design Methods and the Synthesis of Organic-Inorganic Hybrid Nanomagnets and High Spin Materials. Biomimetic Chemistry and Assembly.

HONORS

2006 Entrepreneurship Award – Carnegie Science Center 2005 University of Texas, Dallas – Alumni Merit Award recipient 2002 2002 American Chemical Society Akron Section Award This award is given to scientists and engineers under 45 years of age working in any branch of chemistry and residing within a 300 mile radius of Akron, who "demonstrate exceptional promise for making significant contributions to chemical science." 1992 AT&T Special Foundation Award

1987 Sarah and Adolph Roseman Achievement Award in Research and Teaching awarded by The Johns Hopkins University

PROFESSIONAL ACTIVITIES 10 Invited Lectures since 1991 in North America, Europe, and Asia.

PUBLICATIONS 1. "An Approach to the Synthesis of TMTTeF," Cowan, D. O.: Lerstrup, K.; Veciana, J.; Rovira, C.; Bailey, A.; McCullough, R. Mol. Cryst. Liq. Cryst. 1985, 102, 285-294. 2. "Tellurium Containing Organic Metals," Cowan, D. O.; Mays, M.; Lee, M.; McCullough, R.; Bailey, A.; Lerstrup, K.; Wiygul, F.; Kistenmacher, T.; Poehler, T.; Chiang, L.-Y. Mol. Cryst. Liq. Cryst. 1985, 125, 191-204. 3. "A Convenient Synthesis of Hexamethylenetetraselenafulvalene (HMTSF)," McCullough, R. D.; Cowan, D. O. J. Org. Chem. 1985, 50, 4644-4648. 4. "The Synthesis and Study of New Selenium and Tellurium Heterocyclic π-Donors," Lerstrup, K.; Bailey, A.; McCullough, R. D.; Mays, M.; Cowan, D. O. Synth. Met. 1986, 19, 647-652. 5. "Tetratellurafulvalene (TTeF)," McCullough, R. D.; Kok, G. B.; Lerstrup, K. L.; Cowan, D. O. J. Am. Chem. Soc. 1987, 109, 4115-4116.

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6. "Initial Study of the New Tellurium Containing Charge Transfer Organic Metal: Tetratellurafulvalene-Tetracyanoquinodimethane (TTeF-TCNQ)," Mays, M. D.; McCullough, R. D.; Cowan, D. O.; Poehler, T. O.; Bryden, W. A.; Kistenmacher, T. J. Solid State Commun. 1988, 65, 1089-1092. 7. "An Improved Synthesis of Tetratellurafulvalene via 1,2-Bis(trimethylstannylethylene)," McCullough, R. D.; Bailey, A. B.; Mays, M. D.; Cowan, D. O. Synth. Met. 1989, 27, 487-492. 8. "New Organic π-Donors: Analogues of HMTSF and HMTTeF," Bailey, A. B.; McCullough, R. D.; Mays, M. D.; Cowan, D. O.; Lerstrup, K. A. Synth. Met. 1989, 27, 425-430. 9. "Electrical and Magnetic Studies on Some New Organic Conductors Made With Tetratellurafulvalene (TTeF)," Mays, M. D.; McCullough, R. D.; Bailey, A. B.; Cowan, D. O.; Poehler, T. O.; Kistenmacher, T. J. Synth. Met. 1989, 27, 493-498. 10. “Substrate Selectivity in Epoxidation by Metalloporphyrin and Metallosalen Catalysts Carrying Binding Groups,” Breslow, R.; Brown, A. B.; McCullough, R. D.; White, P. W. J. Am. Chem. Soc. 1989, 111, 4517-4518. 11. "Organic Metals Containing Tellurium," Cowan, D. O.; McCullough, R. D.; Bailey, A.; Lerstrup, K.; Talham, D.; Herr, D.; Mays, M. Phosphorus, Sulfur, Silicon, Relat. Elem. 1992, 67, 277-294. At Carnegie Mellon 12. "Enhanced Electrical Conductivity in Regioselectively Synthesized Poly(3-alkylthiophenes)," McCullough, R. D.; Lowe, R. D. J. Chem. Soc., Chem. Commun. 1992, 70-72. 13. "Design, Synthesis, and Control of Conducting Polymer Architectures: Structurally Homogeneous Poly(3-alkylthiophenes)," McCullough, R.D.; Lowe, R. D.; Jayaraman, M.; Anderson, D. L. J. Org. Chem., 1993, 58, 904-912. 14. "Design and Control of Conducting Polymer Architectures: Synthesis and Properties of Regiochemically Well-Defined Poly(3-alkylthiophenes)," McCullough, R. D.; Lowe, R. D.; Tristram-Nagle, S.; Jayaraman, M.; Anderson, D. L.; Ewbank, P. C. Synth. Met., 1993, 55, 1198-1203. 15. "Novel Coordination Complexes of Tetrathiafulvalene Derivatives," McCullough, R. D.; Seth, J.; Belot, J. A.; Majetich, S. A.; Carter, A. C. Synth. Met., 1993, 56, 1989-1994. 16. "Connected Cadmium Selenide Nanocrystallites" Majetich, S. A.; Carter, A. C.; McCullough, R. D in "Nanophase and Nanocomposite Materials", eds. S. Komarneni, J.C. Parker, and G.J. Thomas, Materials Research Society, Pittsburgh, PA 1993, 286, 86-92. 17. "Self-Oriented Poly(3-Alkylthiophenes): New Insights on Structure-Property Relationships in Conducting Polymers," McCullough, R. D.; Tristram-Nagle, S.; Williams, S. P.; Lowe, R. D.; Jayaraman, M. J. Am. Chem. Soc. 1993, 115, 4910-4911.

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18. "Selective Generation, Isolation, and Purification of Tetrathiafulvalene Tetrathiolate: A Versatile Building Block for New Materials," McCullough, R. D.; Belot, J. A.; Seth, J. J. Org. Chem. 1993, 58, 6480-6482. 19. "Toward Tuning Electrical and Optical Properties in Conjugated Polymers Using Side-Chains: The Synthesis and Physical Properties of a Series of the First Head-to-Tail Heteratom Functionalized Polythiophenes," McCullough, R. D.; Williams, S. P. J. Am. Chem. Soc. 1993, 115, 11608-11609. 20. "Cadmium Selenide Nanocrystallite Networks", Majetich, S. A.; Seth, J.; McCullough, R. D.; Belot, J. A. Z. Physik D 1993, 26 , 210-212. 21. "Synthesis and Physical Properties of Self-Orienting, Head-To-Tail Polythiophenes," McCullough, R. D.; Williams, S. P.; Jayaraman, M.; Reddinger, J.; Miller, L.; Tristram-Nagle, S. in "Electrical, Optical, and Magnetic Properties of Organic Solid State Materials,' Dalton, L.; Lee, C., eds., Materials Research Society, Pittsburgh, PA 1994, 328, 215-220.

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22. "Toward New Magnetic, Electronic, and Optical Materials: Synthesis and Characterization of New Bimetallic Tetrathiafulvalene Tetrathiolate Building Blocks," McCullough, R. D.; Belot, J. A. Chem. Mater. 1994, 6, 1396-1403. INVITED. Invited manuscript for the Special Issue on Solid State Organic Chemistry dedicated to the late Margaret (Peggy) Etter. 23. "1H NMR Characterization of the CdSe Nanocrystallite Surface," Majetich, S. A.; Carter, A. C.; Belot, J. A.; McCullough, R. D. J. Phys. Chem., 1994, 98, 13705-13710. 24. "The Tuning of Conjugation by Recipe: The Synthesis and Properties of Random Head-to-Tail Poly(3-alkylthiophene) Copolymers," McCullough, R. D.; Jayaraman, M. J. Chem. Soc., Chem. Commun., 1995, 135-138. 25. "The First Synthesis and New Properties of Regioregular, Head-To-Tail Coupled Polythio-phenes." McCullough, R. D.; Williams, S. P.; Tristram-Nagle, S.; Jayaraman, M.; Ewbank, P. C.; Miller, L. Synt. Met., 1995, 69, 279-282. 26. "New Bimetallic Tetrathiafulvalene Building Blocks and Self-Assembled, Two Dimensional Conductors Derived From Regioregular, Head-to-Tail Coupled Polythiophenes" McCullough, R. D.; Belot, J. A.; Williams, S. P. in "Molecular Engineering of Advanced Materials", Becher, J., Schaumburg, K. Eds., NATO Advanced Research Workshop Series, Series C: Mathematical and Physical Sciences, 1995, 456, 349-363. 27. "Building Block Ligands For New Molecular Conductors: Homobimetallic Tetrathiafulvalene Tetrathiolates and Metal Diselenolenes and Ditellurolenes," McCullough, R. D.; Belot, J. A.; Seth, J.; Rheingold, A. L.; Yap, G. P. A.; Cowan, D. O. J. Mater. Chem., 1995, 5, 1581-1587. Invited manuscript for Special Issue on Molecular Conductors. 28. "Toward New Electronic, Magnetic, and Optical Materials: Structure and Properties of the First Homobimetallic Tetrathiafulvalene Tetrathiolate Building Block," McCullough, R. D.; Belot, J. A.; Rheingold, A. L.; Yap, G. J. Am. Chem. Soc., 1995, 117, 9913-9914. 29. "Dramatic Conjugational Interchange in Regiochemically Pure Polythiophenes Via a Chemoselective Recognition Response," McCullough, R. D.; Williams, S. P. Chem. Mater. 1995, 7, 2001-2003. 30. "Intermolecular Association and Supramolecular Organization in Dilute Solution. 1. Regioregular Poly(3-dodecylthiophene)," Yue, S.; Berry, G. C.; McCullough, R. D. Macromolecules, 1996, 29, 933-939. 31. "Evidence of a Novel Side Chain Structure in Regioregular Poly(3-Alkylthiophenes)," Prosa, T. J.; Winokur, M. J.; McCullough, R. D. Macromolecules, 1996, 29, 3654-3657. 32. "Optimizing the Synthesis of Tetratellurafulvalene (TTeF)," Herr, D. E.; Mays, M. D.; McCullough, R. D.; Bailey, A. B.; Cowan, D. O. J. Org. Chem., 1996, 61, 7006-7011. 33. "Quadratic Electro-optical Measurements of Polythiophene Films by a Modified Mach-Zehnder Interferometer," Jakobsen, C.; Petersen, J. C.; Geisler, T.; Bjornholm, T.; Greve, D. R.; McCullough, R. D. J. Opt. Soc. Am. 1996, 115, 235-240.

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34. "Improved Electroluminescent In Poly(3-alkylthiophenes) With High Head-to-Tail Ratios," Mehta, P.; McCullough, R. D. J. Mater. Chem. 1996, 6, 1763-1766. 35. "Third-Harmonic Generation From Regioregular and Regioirregular Poly(3-dodecyl- thiophenes). Dependence of χ3 on Conjugation Length," Bjornholm, T.; Greve, D. R.; Geisler, T.; Petersen, J. C.; Jayaraman, M.; McCullough, R. D. Adv. Mater. 1996, 8, 920-923. 36. "A Facile and Efficient Synthesis of Vanadocenes With Alkyl Annulated Cyclopentadienyl Rings," McCullough, R. D.; Belot, J. A. Organometallics 1996, 15, 5062-5065. 37. "Self-Assembly and Disassembly of Regioregular, Water Soluble Polythiophenes: Chemoselective Ionchromatic Sensing in Water," McCullough, R. D.; Ewbank, P. C.; Loewe, R. S. J. Am. Chem. Soc. 1997, 119, 631-632. 38. "Self-assembly and Chemical Response of Conducting Polymer Superstructures," McCullough, R. D.; Ewbank, P. C. Synth. Met. 1997, 84, 311-312. 39. "Self-Assembly in Regioregular Polythiophenes," McCullough, R. D. Annu. Tech. Conf.-Soc. Plast. Eng., 1997, 56, 102-105. 40. "Saturation effects in the Nonlinear Optical Response of Regioregular, Highly Conjugated Poly(3-alkylthiophene) Thin Films," Synth. Met. 1997, 84, 531-532. 41. Bjørnholm, T.; Greve, D. R.; McCullough, R. D.In Supramolecular Engineering of Synthetic Metallic Materials: Conducotrs and Magnets; Veciana, J., Rovira, C., Amabilino, D. B., Eds.; NATO ASI Series C, Volume 518, Kluwer: Dordrect, 1998; pp 477-483. 42. "Regioregular, Head-to-Tail Coupled Poly(3-alkylthiophene) and its Derivatives," McCullough, R. D.; Ewbank, P. C. in the Handbook of Conducting Polymers, 2nd edition, Marcell Dekker, 1998, Chapter 9. 225-258. INVITED 43. "The Chemistry of Conducting Polythiophenes," McCullough, R. D. Adv. Mater. 1998, 10, 1-24 (review). INVITED 44. "Structured Amphiphilic Regioregular Polythiophene Nanosheet Conductors: 2-D Self-Assembly of Highly Conjugated Polymers," Thomas Bjornholm, Daniel R. Greve, Niels Reitzel, Kristian Kjær, Paul Howes, Mani Jayaraman, Paul C. Ewbank, Richard D. McCullough J. Am. Chem. Soc. 1998, 120, 7643-7644. 45. Greve, D. R.; Reitzel, N.; Hassenkam, T.; Bøgelund, J.; Kjaer, K.; Howes, P. B.; Larsen, N. B.; Jayaraman, M.; McCullough, R. D.; Bjørnholm, T. "Directed self-assembly of amphiphilic regioregular polythiophenes on the nanometer scale." Synth. Met. 1999, 102, 1502-1505. 46. "The Chemistry of Polythiophenes: From Synthesis to Self-Assembly to Intelligent Materials," McCullough, R. D. Handbook of Oligothiophenes and Polythiophenes, 1999, 1-44.

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47. "A Very Simple Method to Prepare Head-to-Tail Coupled, Regioregular Poly(3-alkylthiophenes) Using Grignard Metathesis," Loewe, R. S.; Khersonsky, S. M.; McCullough, R. D. Adv. Mater. 1999, 11, 250-253. 48. "Investigating the Synthesis of Unsymmetrical Tetrathiafulvalene Derivatives: Improved Yields by the Hidden Equivalent Method," McCullough, R. D.; Petruska, M. A.; Belot, J. A. Tetrahedron, 1999, 115, 2231-2238. 49. "Employing MALDI-MS on Polyalkylthiophenes: Analysis of Molecular Weights, Molecular Weight Distributions, End Group Structures, and End Group Modifications," Liu, J.; Loewe, R. S.; McCullough, R. D. Macromolecules 1999, 32, 5777-5785. 50. "Polythiophene Nanowires," Bjørnholm, T.; Hassenkam, T.; Greve, D. R.; McCullough, R. D.; Jayaraman, M.; Savoy, S. M.; Jones, C. E.; McDevitt, J. T. Adv. Mater. 1999, 11, 1218-1221 (paper featured on the cover). 51. "Self-Assembly of Conjugated Polymers at the Air/Water Interface. Structure and Properties of Langmuir-Blodgett Films of Amphiphilic Polythiophenes," Reitzel, N.; Greve, D. R.; Kjaer, K.; Howes, P. B.; Jayaraman, M.; Savoy, S.; McCullough, R. D.; McDevitt, J. T.; Bjornholm, T. B. J. Am. Chem. Soc., 2000, 122, 5788-5800. 52. "Regioselective Synthesis and Analysis of Polythienylvinylene," Loewe, R. L.; McCullough, R. D. Chem. Mater. 2000, 12, 3214-3221. 53. "Water Soluble Amine Functionalized Polythiophenes Bind DNA," Ewbank, P. C.; Nuding, G.; Suenaga, H.; McCullough, R. D.; Shinkai, S. Tetrahedron Lett. 2000, 42, 155-157. 54. "Regioregular, Head-to-Tail Coupled Poly(3-alkylthiophenes) Made Easy by the GRIM Method: Investigation of the Reaction and Why It Works," Loewe, R. S.; Ewbank, P. C.; Liu, J.; Zhai, L.; McCullough, R. D. Macromolecules 2001, 34, 4324-4333. 55. "Temperature and Voltage Dependent Optical Properties of Conducting Polymer in Synthetic Opal as Photonic Crystal", Satoh, S.; Kajii, H.; Kawagishi, Y.; Tamura, T.; Fujii, A.; Ozaki, M.; McCullough, R. D.; Yoshino, K., Synth. Met. 2001, 121, 1503-1504. 57. “Self-assembly of amphiphilic conducting polymers into nanowires, nanocircuites, and multifunctional materials”, McCullough, R.D.; Liu, Jinsong; Sheina, Elena; Heuze, Karine; Stokes, Kristoffer; Jayaraman, Manikandan; Bjornholm, Thomas,;McDevitt, John T., Poly. Mater. Sci., 2001, 84, 858. 58. “Self-Assembly of Electrically Conductive Polymer Nanostructures: Synthesis and Properties of Well-Defined Regioregular Polythiophene Diblock and Triblock Copolymers,” Liu, J.; Sheina, E.; Kowalewski, T.; McCullough, R. D. Angew. Chem. Int. Ed. Engl. 2002, 41, 329-332. 59. "Layer-by-Layer Electrostatic Self-Assembly of Polythiophene," Zhai, L. and R.D. McCullough, Adv. Mater. 2002, 14, 901-905.

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60. "Synthesis and Characterization of Poly(methylacrylate) Grafted from Poly(thiophene) to Form Solid State Fluorescent Materials," Constanzo, P. J.; Stokes, K. K.; (McCullough, R. D.) Macromolecules, 2002, 35, 6804-6810. 61. "End-Group-Modification of Regioregular Polythiophene Through Post-Polymerization Functionalization," Liu, J.; McCullough, R. D., Macromolecules, 2002, 35, 9882-9889. 62. “Tuning the Electrical Conductivity and Self-Assembly of Regioregular Polythiophene by Block Copolymerization: Nanowire Morphologies in New Di- and Triblock Copolymers,” Liu, J., Sheina, E., Kowalewski, T., and R.D. McCullough, Angew. Chem. Int. Ed., 2002, 41, 329-332. 63. “Complex nanostructured materials from segmented copolymers prepared by ATRP” Kowalewski, T., McCullough, R.D., and K. Matyjaszewski Eur. Phys. J. E, 2003, 10, 5-16. 64. “A Simple Method to Generate Side-chain Derivatives of Regioregular Polythiophene via the GRIM Metathesis and Post-polymerization Functionalization” Zhai, L., Pilston, R.L., Zaiger, K.L., Stokes, K. and R.D. McCullough, Macromolecules, 2003, 36, 61-64. 65. “Soft-lithography Patterning of Functionalized Regioregular Polythiophenes” Zhai, L., Laird, D.W., and R.D. McCullough Langmuir, 2003, 19, 6492-6497. 66. “New Phosphonic Acid Functionalized, Regioregular Polythiophenes," Stokes, K. K.; Heuzé, K.; McCullough, R. D., Macromolecules, 2003, 36, 7114-7118. 67. “Regioregular Polythiophene/Gold Nanoparticle Hybrid Materials” Zhai, L., and McCullough, R.D., J. Mater. Chem., 2004, 14, 141-143. 68. "In-situ End Group Functionalization of Regioregular Poly(3-alkylthiophene) using the Grignard Metathesis Polymerization Method," Jeffries-EL, M.; Sauvé, G., and McCullough, R. D. Adv. Mater., 2004, 16, No. 12., 1017-1019. 69. "Chain Growth Mechanism for Regioregular Nickel-Initiated Cross-Coupling Polymerizations," Sheina, E. E.; Liu, J.; Iovu, M. C.; Laird, D. W.; McCullough, R. D. Macromolecules, 2004, 37, pg. 3526-3528. 70. “Regioregular Poly(thiophene-3-alkanoic acid)s: Water Soluble Conducting Polymers Suitable for Chromatic Chemosensing in Solution and Solid State”, Ewbank, P. C.; Loewe, R. S.; Zhai, L.; Reddinger, J.; Sauvé, G.; McCullough, R. D., Tetrahedron, 2004, 60, pg. 11269-11275. (invited) 71. “Regioregular Poly(3-Alkylthiophene) Conducting Block Copolymers”, Mihaela Corina Iovu; Malika Jeffries-EL; Elena E. Sheina; Jessica R. Cooper; Richard D. McCullough; Polymer, 2005, 46, 8582-8586. 72. “Highly Conductive, Regioregular Alkoxy-Functionalized Polythiophenes: A New Class of Stable, Low Band Gap Materials”, Elena E. Sheina; Sonya M. Khersonsky; Edward G. Jones; Richard D. McCullough; Chem. Mater. 2005, 17; 3317-3319.

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73. “Experimental Evidence for the Quasi-“Living” Nature of the Grignard Metathesis Method for the Synthesis of Regioregular Poly(3-alkylthiophenes)”, Mihaela Corina Iovu; Elena E.Sheina; Roberto R. Gil; Richard D. McCullough; Macromolecules, 2005, 38; 8649-8656. 74. “Facile Synthesis of End-Functionalized Regioregular Poly(3-alkylthiophene)s via Modified Grignard Metathesis Reaction” Malika Jeffries-EL, Genevieve Sauve, and Richard D. McCullough, Macromolecules, 2005, 38, 10346-10352. 75. “Nanostructure Dependence on Field-Effect Mobility of Regioregular Poly(3-hexylthiopehene) Thin Film Field Effect Transistors”, Zhang, Rui; Li, Bo; Cooper, Jessica; Iovu, Mihaela; Sauve, Genevieve; Jeffries-EL, Malika; Jia, Shijun; Tristram-Nagle, Stephanie; Smilgies, Detlef M.; Lambeth, Davi d N., McCullough, Richard D.; and Tomasz Kowalewski, J. Am. Chem. Soc., 2006, 128, 3480-348. 76. "Volatile Organic Compound Detection Using Nanostructured Copolymers", Li, Bo; Sauve, Genevieve; Iovu, Mihaela C.; Jeffries-EL, Malika; Zhang, Rui; Cooper, Jessica; Santhanam, Suresh; Schultz, Lawrence; Revelli, Joseph C.; Kusne, Aaron G.; Kowalewski, Tomasz; Snyder, Jay L.; Weiss, Lee E.; Fedder, Gary K.; McCullough, Richard D.; Lambeth, David N.; Nano Lett. 2006, 6, 1598-1602. 77. “Inkjet printed chemical sensor array based on polythiophene conductive polymers”, Li, Bo; Santhanam, Suresh, Schultz, Lawrence, Jeffries-EL, Malika, Iovu, Mihaela C., Sauve, Genevieve, Cooper, Jessica, Zhang, Rui, Revelli, Joseph C., Kusne, Aaron G., Snyder, Jay L., Kowalewski, Tomasz, Weiss, Lee E., McCullough, Richard D., Fedder, Gary K., Lambeth, David N. , Sensors and Actuators, 2006, doi:10.1016/j.snb.2006.09.064, in press. 78. “Regioregular Polythiophenes” Jeffries-EL, M.; McCullough, R.D., Handbook of Conducting Polymers, 3rd Ed., 2 Volume Set, 2006, Terje A. Skotheim, Intex, Tucson, AZ, USA; John Reynolds, University of Florida, Gainesville, FL, USA. Series: Handbook of Conducting Polymers, Third Edition. 79. “Communication Platform Synthesis for Libraries of Conducting Block Copolymers: Persistent Nanofibrils with Varying Degrees of Long-Range Order” Mihaela C. Iovu, Rui Zhang, Malika Jeffries-EL, Ashley B. Krankowski, Detlef M. Smilgies, Tomasz Kowalewski, Richard D. McCullough 2006, submitted. Patent Disclosures McCullough, Richard D.; Liu, Jinsong; Ewbank, Paul C.; Sheina, Elena E., “Polythiophenes, Block Copolymers Made Therefrom, and Methods of Forming the Same” US Patent 7,089,294 (2006) McCullough, Richard D.; Liu, Jinsong; Ewbank, Paul C.; Sheina, Elena E. “Polythiophenes, Block Copolymers, Made Therefrom, and Methods of Forming the Same”, US Patent 6,887,965 (2003) McCullough, Richard D.; Liu, Jinsong; Ewbank, Paul C.; Sheina, Elena E. Polythiophenes, block copolymers, and their preparation. US 6602974 U.S. (2003)

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“Nickel(II) -Diimine catalysts for the synthesis of regioregular poly(3-alkyl/alkoxy-substituted thiophenes)” (composition of matter) Richard D. McCullough; Mihaela Corina Iovu; Elena E. Sheina. “Copolymers containing different regioregular poly(3-alkylthiophene) blocks synthesized by “living” Grignard metathesis method” (composition of matter) Richard D. McCullough; Mihaela Corina Iovu; Elena E. Sheina. McCullough, Richard D.; Sheina, Elena; Iovu, Mihaela C. “Living Synthesis of Conducting Polymers Including Regioregular Polymers, Polythiophenes, and Block Copolymers” US Patent 11/394,202 (2006) Articles in Preparation Invited Articles: Feature Article for Journal of Materials Chemistry. In non-refereed journals (partial list) “The synthesis of well-defined conducting poly(3-alkylthiophenes)” McCullough, R.D. and R.D. Loewe, Polym Prepr, 1992, 33, 195-196. “Using a functionalized, structurally pure head-to-tail poly(3-substituted thiophene) to probe environmental effects on material properties” McCullough, R.D. and S.P. Williams, Polym Prepr, 1994, 35, 300-301. “Tuning Electronic and Photonic Properties in Conducting Polymers With Side-Chains and By Recipe: Head-to-Tail Poly(3-substituted)thiophenes and Random Co-Polymers of Head-to-Tail Poly(3-alkylthiophenes).” McCullough, R. D.; Williams, S. P.; Jayaraman, M. Polym. Prepr. 1994, 190-192.

"Synthesis of well-defined alternating and Random Co-Polymers of Electrically Conductive Poly(3-alkylthiophenes)" Jayaraman, M.; McCullough, R. Polym. Prepr., 1994, 35, 299-300. "Using a Functionalized, Structurally Pure HT-Poly(3-substitutedthiophene) to Probe Environmental Effects on Material Properties." McCullough, R. D.; Williams, S. P. Polym. Prepr. 1994, 300-301. "Synthesis of Head-to-Tail Poly(3-alkylthiophenes)" McCullough, R. D.; Reddinger, J.; Williams, S. P.; Jayaraman, M.; Ewbank, P.; Miller, L. Polym. Prepr. 1994, 35, 302-303. “Synthesis and physical properties of self-orienting head-to-tail polythiophenes” McCullough, R.D., S.P. Williams, et al., Matr Res Soc Symp Proc, 1994, 328, 215-220.

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“Newbiometallic tetrathiafulvalene building blocks and self-assembled, two-dimensional conductors derived from regioregular, head-to-tail coupled polythiophenes” McCullough, R.D., J.A. Belot, et al., NATO ASI Series, Series C: Mathematical and Physical Sciences, 1995, 456, 349-363. "Self-Assembled and Chemically Responsive Conducting Polymer Superstructures," McCullough, Richard D. Polym. Prepr. 1995, 36, 535. "A Dramatic Conjugational Interchange in the Regioregular, Polythiophene, HT Poly(3-[2,5,8-trioxa-nonyl]thiophene) via a Chemoselective Recognition Response," McCullough, R. D.; Williams, S. P. Polym. Prepr. 1995, 190-192. "Regioregular Water Soluble Poly(3-substituted)-thiophenes: The Precursors to Self-Assembling Conducting Polymers Possess Suprising Chemosensory Potential," Ewbank, P. C.; Reddinger, J. L.; McCullough, R. D. Polym. Prepr. 1995, 198-199. "Synthesis of Well-Defined Perfectly Alternating Copolymers of Electrically Conductive Poly(3-alkylthiophenes)," Jayaraman, M.; McCullough, R. D., Polym. Prepr. 1995, 78. “Self-assembly in regioregular polythiophenes” McCullough, R.D., Annual Technical Conference – Society of Plastic Engineers, 1997, 55th, 1366-1368. “Analysis of regioregular poly(3-alkylthiophenes) by MALDI-MS.” Liu, J. and R.D. McCullough, Polym Prepr (American Chemical Society, Division of Polymer Chemistry), 1999, 40, 695. “Using Grignard metathesis to synthesize regioregular, head-to-tail coupled poly(3-substituted)thiophenes.” Loewe, R.S. and R.D. McCullough, Polym Prepr (American Chemical Society, Division of Polymer Chemistry), 1999, 40, 852-853. “Supramolecular engineering of conducting thin films by covalently hinging electroactive molecular surfactants.” Bjornholm, T., D.R. Greve, et al., NATO ASI Series, Series C: Mathematical and Physical Sciences, 1999, 518, 477-483. “Regioregular, head to tail coupled, amine functionalized polythiophenes.” Ewbank, P.C., G. Nuding, et al., Polym Prepr, 1999, 40, 855. “Toward new amphiphilic polythiophenes: Synthesis of regioregular phosphonic acid functionalized polythiophenes” Heuze, K. and R.D. McCullough, Polym Prepr., 1999, 40, 854. "End-Group Functionalization of Regioregular Head-to-Tail Poly(3 Alkylthiophenes)," Liu, J.; McCullough, R. D. Polym. Prepr, 2000, 41, 1235-1236. “Optical properties of highly fluorescent conducting polymers lasing in micro-cavity and in opal matrix as phonic crystal”, Fujii, Akihiko; Langa, Tong; Kawagishi, Yoshiaki; Ozaki, Masanori; Yoshino, Katsumi; McCullough, Richard D., Osaka Univ., Japan, 2000, Denki Zairyo Gijutsu Zasshi, 2000, 9, 97-100.

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“Self-assembly of amphiphilic conducting polymers into nanowires, nanocircuits, and multifunctional materials” McCullough, R.D., J. Liu, et al., Polymeric Materials Science and Engineering, 2001, 84, 858. “Carbohydrate functionalized polythiophenes as biosensors”, Zaiger, Karen; Zhai, Lei; McCullough, Richard D., Polym. Prepr., 2001, 42, 332. “Toward tunable, light-emitting polythiophenes”, Pilston, R.L.; Ricou, J.I.F., McCullough, R.D., Polym. Mater. Sci. Engr., 2001, 84, 703. “ATRP approach to synthesize well-defined diblock copolymers containing regioregular head-to-tail poly(3-hexylthiophene)s.” Liu, Jinsong; McCullough, Richard D., Polym. Mater. Sci. Engr., 2001, 84, 662-663. “Characterization of polythiophene random copolymers that include m-linked monomer units”, Pilston, Richard L.; McCullough, Richard D., Polym. Mater. Sci. Engr., 2002, 86, 191-192. “Regioregular polythiophene for integrated circuits.”, Zhai, Lei; Liard, Darin W.; McCullough, Richard D., Polym. Mater. Sci., Engr., 2002, 87, 288-289. “Synthesis and properties of conducting elastomers”, Sheina, Elena E.; Liu, Jinsong; McCullough, Richard D., Polym. Mater. Sci. Engr., 2002, 86, 177-178. “Design and synthesis of novel glycopolythiophenes”, Jeffries-El, Malika; Zaiger, Karen; McCullough, Richard D., Polym. Mater. Sci. Engr., 2002, 86, 166. “Toward processable, regioregular 2,5-polypyrroles via nickel-catalyzed polycondensation”, Laird, Darin W.; McCullough, Richard D., Polym. Mater. Sci. Engr., 2002, 86, 157-58. “Nanowires formed from block copolymers of regioregular polythiophene”, Liu, Jinsong; Sheina, Elena; Zhai, Lei; Kowalewski, Tomasz; McCullough, Richard D., Polym. Mater. Sci. Engr. 2002, 85, 35. “The power of MALDI for preparing electrically conductive nanowires.” McCullough, Richard D., Polym. Mater. Sci. Engr., 2003, 88, 129. “Toward poly(3- and 3,4-aslkxythiophenes).” Sheina, Elena E.; Khersonsky, Sonya M.; Jones, Edward G; McCullough, Richard D., ACS, Div. Poly. Chem., 2003, 44(1), 843-844. Iovu, M.; Jeffries-El, M.; Sheina, E. E.; Krankowski, A.; Sauve, G.; McCullough, R. D., Abstracts of Papers, 228th ACS National Meeting, Philadelphia, PA, United States, August 22-26, 2004, POLY. “Control of end-groups of regioregular poly(3-alkylthiophenes) using Grignard metathesis”, Sauvé, Genevieve; Jeffries-El, Malika; McCullough, Richard D., Polymer Preprints 2003, 44(2), 432. “Synthesis and characterization of poly(3-hexylthiophene)-b-polystyrene di-block copolymers”, Iovu, M. C.; Jeffries-El, M.; Sheina, E. E.; Krankowski, A. B.; Sauve, G.; McCullough, R. D.,

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Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 2004, 45, 645-646. “End functionalized poly(3-alkylthiophenes) as building blocks for the synthesis of diblock copolymers” Jeffries-El, M.; Iovu, M. C.; Sheina, E.; Sauve, G.; McCullough, R. D., Polym Prepr (American Chemical Society, Division of Polymer Chemistry) 2004, 45, 551-552. “Synthesis of poly(3-hexylthiophene) di-block copolymers using atom transfer radical polymerization”, Iovu, Mihaela C.; Sheina, Elena E.; Sauvé, Genevieve; Jeffries-El, Malika; Cooper, Jessica; McCullough, Richard D., Polymer Preprints 2004 , 45(1), 278-279. “In situ end group modification of regioregular poly(3-alkylthiophenes) via Grignard metathesis (GRIM) polymerization”, Jeffries-EL, Malika, Sauvé, Genevieve; Iovu, Mihaela; McCullough, Richard D., Polymer Preprints 2004, 45(1), 183-184. Media Coverage at CMU "Chemistry and Industry", Highlights Section, paper published in J. Chem. Soc., Chem. Commun. 1992, 70 was highlighted in February 1992 edition. "Chemistry and Industry", Highlights Section, paper published in J. Am. Chem. Soc. 1993, 115, 11608, was highlighted in January 1994 edition.

LECTURES – while at CMU

Over 134 national and international, invited lectures. 1991 Department of Chemistry, Duquesne University 1992 Symposium on Well-Defined Polymers, National American Chemical Society (ACS) Meeting, San Francisco, CA, April, 1992. 1993 Florida Advanced Materials Conference, Palm Coast, FL, March 1993. University of Michigan, Ann Arbor, MI, March, 1993. Polaroid Corporation, Cambridge, MA, April 1993. University of Massachusetts, Lowell, MA, April 1993. NSF Workshop on Reactive Intermediates, Lake Tahoe, NV, June, 1993. Physical Organic Gordon Conference, NH, June, 1993. Symposium on Supramolecular Chemistry, Organic Division, Central Regional ACS Meeting, Pittsburgh, PA, October, 1993. Symposium on Conducting Polymers, Polymer Division, Central Regional ACS Meeting, Pittsburgh, PA, October, 1993. Symposium on Electrical, Optical, and Magnetic Properties of Organic Solid State Materials. Materials Research Society Meeting, Boston, MA, November, 1993. 1994

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PPG Industries, Inc., Pittsburgh, PA, January, 1994. Pittsburgh Polymer Section of the ACS, Pittsburgh, PA, January, 1994 Symposium on Conjugated Polymers, Polymer Division, National ACS Meeting, San Diego, CA, March, 1994. University of Copenhagen, Copenhagen, Denmark, May, 1994. NATO Advanced Research Workshop on Molecular Engineering For Advanced Materials, Hindsgavl, Denmark, May, 1994. Symposium on Organometallic Chemistry in Polymer Synthesis, Organic Division, Great Lakes & Central Regional ACS Meeting, Ann Arbor, MI, June, 1994. International Conference on Synthetic Metals (ICSM), Seoul, Korea, July, 1994. University of Rochester, Rochester, NY, October, 1994. Southeastern Magnetic Resonance Conference (SEMRC), Chapel Hill, NC, October, 1994. Symposium on the Chemistry and Properties of Highly Conjugated Polymers, Organic Division, Southwest Regional ACS Meeting, Ft. Worth, TX, November, 1994. University of Texas, Austin, TX, December, 1994. University of Texas, Arlington, TX, December, 1994. University of Pennsylvania, Philadelphia, PA, December, 1994. Columbia University, New York, NY, December, 1994. 1995 Akron Polymer Lecture Group, Akron, OH, February, 1995. Indiana University, Bloomington, IN, February, 1995. Tulane University, New Orleans, LA, April, 1995. Symposium on the Synthesis of Well-Defined Macromolecules for Function and Assembly, National ACS Meeting, Anaheim, CA, April, 1995. Carl Marvel Award for Creative Invention in Polymer Chemistry Symposium Honoring Prof. Kris Matyjaszewski, National ACS Meeting, Anaheim, CA, April, 1995. Symposium on Materials through Molecular Design, National ACS Meeting, Anaheim, CA, April, 1995. Symposium on Functional Polymers, Midwest Regional ACS Meeting, Akron, OH, May, 1995. Wright Patterson Air Force Base, OH, May, 1995. University of Delaware, Newark, DE, June 1995. Symposium on Electrical, Optical, and Magnetic Properties of Organic Solid State Materials. Materials Research Society Meeting, Boston, MA, November, 1995. 1996 University of Pittsburgh, Pittsburgh, PA, February 1996. Symposium on Inorganic-Organic Hybrid Materials, National ACS Meeting, New Orleans, LA, March, 1996. Dickinson College, Carlisle, PA, April 1996. New York University, New York, NY, April 1996. Center For Interdisciplinary Studies of Molecular Interactions (CISMI), Copenhagen, Denmark, May 1996. Symposium on Molecules For Advanced Materials and Nanostructures, University of Copenhagen, Copenhagen, Denmark, May 1996. Royal Institute of Technology, Stockholm, Sweden, June 1996. University of Groningen, Groningen, The Netherlands, June 1996. Risø National Laboratory, Roskilde, Denmark, June 1996. Philips Electronics, Einhoven, The Netherlands, June 1996.

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Eindhoven University of Technology, The Netherlands, June 1996. NKT Corporation, Copenhagen, Denmark, July 1996. Dako Industries, Copenhagen, Denmark, July 1996. Symposium on Intrinsically Conductive Polymers, Midwest Regional ACS Meeting, South Carolina, November, 1996. 1997 Symposium on Conducting Elastomers, Wright Patterson Air Force Base, OH, January, 1997. Florida Advanced Materials Conference, March, 1997 Symposium on Electronic Polymers, ANTEC Society of Plastic Engineers, Toronto, April, 1997. Georgetown University, Washington, D.C., April 1997. George Washington University, Washington, D.C., April 1997. 1998 NATO Advanced Research Workshop, "Supramolecular Engineering of Synthetic Metallic Materials: Conductors and Magnets" Barcelona, Spain, January 1998. Workshop on New Advanced Materials, Wright Patterson Air Force Base, Feb. 1998. University of Copenhagen, Symposium on "Supramolecular Chemistry as Applied to Advanced Materials," Copenhagen, Denmark, 1998. Bowling Green State University, April 1998. Vanderbilt University, Nashville, TN, November, 1998. 1999 Marshall University, February 1999. Symposium on Nanodevices, National American Chemical Society Meeting, Anaheim, CA, March, 1999. NSF Workshop on Reactive Intermediates, Austin, TX, May, 1999. Pennsylvania Governor's Institute Keynote Lecture, Pittsburgh, PA, June, 1999. Symposium on Inherently Conductive Polymers, Toronto, September, 1999. Bayer Keynote Lecture, Bayer Polymer Symposium, September, 1999. Symposium on High Temperature Superconductors and Hybrid Materials, American Chemical Society Southwest Regional Meeting, El Paso, Texas, October, 1999. Symposium on Electroactive Materials, New York, NY, December, 1999. 2000 Wright Patterson Air Force Base, OH, February 2000. Northwestern University, IL, March 2000. University of Copenhagen, May 2000. SMARTON conference of the European National Science Foundation, May 2000. Keynote Lecture for the Pennsylvania Governors Institute, Carnegie Mellon University, July 2000. Keynote Speaker on Nanotechnology, National Starch and Chemical Company, September 2000. Poly Millenial 2000, Kona, HI, December, 2000. Pacifichem 2000, HI, December, 2000. 2001 Albion College, February Wright Patterson Air Force Base, OH, February Symposium on the "Impact of Solid State and Materials Chemistry on Current Technologies,"

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National ACS Meeting, San Diego, CA, April Symposium on "Functional Polymers and Denrimers: From Synthesis to Applications", National ACS Meeting, San Diego, CA, April Gordon Conference,"The Chemistry of Electronic Materials," Connecticut College, NH, July University of Nebraska, NE, May University of Texas, Austin, TX, September University of Washington, Seattle, WA, October 2002 International Chemical Conference, Taipei, Taiwan, February Fifth International Symposium on Functional pi-Electron Systems, May 2003 PPG, Monroeville, PA, February 2003. CASE Conference Development for Deans, San Francisco, CA, February 2003. Symposium on "MALDI and ESI Mass Spectrometry Techniques for Polymer." National ACS Meeting, New Orleans, March 2003 DuPont 2003 Discovery Chemistry Seminar Series, Wilmington, DE, March 2003 National Organization for Black Chemists and Chemical Engineers (NOBCChE) Annual Meeting, Indianapolis, IN, April 2003 Association of American Universities Deans’ Conference, San Diego, CA, April 2003. 26th Australian Polymer Symposium, Noosa, Queensland, Australia, July 2003 Annual Review for MURIs on Multifunctional Nanosensors, AFOSR, University of Santa Barbara,

Santa Barbara, CA, August 2003. Invited Seminar, Department of Chemistry, Syracuse University, NY, October 2003. Murtiashaw Lecture in the Department of Chemistry/Biochemistry, University of South Carolina, SC, October 2003. American Chemical Society Central Regional Annual Meeting, Pittsburgh, PA, October 2003. PPG Coatings, Allison Park, PA, September 2003. The Pennsylvania State University, Invited Seminar, Department of Chemistry, University Park, PA, November 2003. University of Massachusetts, Amherst, MA, December 2003. 2004 Symposium on Electrically Active Polymers, National American Chemical Society Meeting Anaheim, CA, March-April 2004 Washington Technology Center, University of Washington, Seattle, WA, March 2004. 87th Canadian Society of Chemistry Conference and Exhibition, London, Ontario, Canada, May-June 2003 MURI Programs Conference, Cheat Lake, WV, August 2004. Seminar in Polymer Chemistry at the Max Planck Institute, Frankfurt, Germany, September Keynote Speaker ICP Conference, Pittsburgh, PA, October 2004. Invited Seminar, Department of Chemistry, University of Texas, Austin, TX, October 2004. Invited Seminar, University of Connecticut, Polymer Division, Storrs, CT, December 2004. 2005 Invited Seminar, Department of Chemistry, Juniata College, PA, January 2005. American Chemical Society 229th National Meeting, Marvel Award Symposium, San Diego, CA, March 2005.

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Chemistry presentations to sophomore high school students at Fox Chapel High School, Pittsburgh, PA, May 2005 MURI 3rd Annual Review Meeting, San Diego, CA, July 2005 SPIE International Society for Optical Engineering, San Diego, CA, July 2005. Invited Seminar, Department of Chemistry, North Dakota State University, Fargo, ND, Sept. Sukant Tripathy Memorial Symposium, U. Massachusetts, Lowell, invited speaker, Dec. 1-2, Pacifichem 2005 Symposium, Honolulu, HI, invited speaker, Dec. 17-20, 2005. 2006 Invited Talk, International Conference on Science and Technology of Synthetic Materials (ICSM) Trinity College, Dublin, IRELAND, July 2-7 Presentation to the University Advancement core, July Invited Talk, 232nd ACS National Meeting “Entrepreneurship in Polymers and Technology”, September 10-14, San Francisco, CA Invited Talk, Wake Forest University, Winston-Salem, NC, September 20 Invited Talk, Johns Hopkins University, Baltimore, MD, October 24 Invited Talk, CASW Program, Baltimore, MD, October 31 2007 Invited Speaker, Third International Smart Coatings Symposium, Orlando, FL, February 21-23 Invited Speaker, Annual Technical Conference, Tepper School of CMU, Pittsburgh, PA, March 18. Invited Speaker, “30 Years of Conducting Polymers”, American Chemical Society meeting, Chicago, IL, March 25-29. Invited Speaker, Organic Field Effect Transistors VI (SPIE), San Diego, CA, August 26-30. Invited Speaker, 9th European Conference on Molecular Electronics, Metz, FR, September 5-8. Invited Speaker, Colloquium Spectroscopicum Internationale XXXV, Xiamen, China, September 23-27

Other Talks Other Talks and Posters National American Chemical Society Meeting, San Francisco, CA, April, 1992 (poster). International Conference on Synthetic Metals (ICSM), Sweden, July, 1992 (poster). Gordon Research Conference, Polymers West, Ventura, CA, January, 1993 (poster). National ACS Meeting, Organic Division, Chicago, Illinois, August, 1993 (talk). Professor Dwaine O. Cowan Symposium, May 1995. Internal and Outreach Lectures Lecturer for the Post College Education Program, Carnegie Mellon University, 1990. Undergraduate Seminar "New Organic Electronic Materials", October, 1990. Graduate Student Seminar "The Renaissance of Conducting Polymers", November, 1990. Lecturer for the Post College Education Program, Carnegie Mellon University, 1991. Presentation at Departmental Retreat-Camp Soles, 1991-2000. Departmental Materials Chemistry Seminar Series, 1995. Chemistry Demonstration to Carnegie Mellon Child Care Center Kids Camp, 1995. Presentation to Science Students at Fox Chapel High School, 1996. Presentation to alumni in Academy of Lifelong Learning "Understanding, Creating, & Using Matter", 1996

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Presentation at Chemistry Department’s Undergraduate Seminar Series, CMU, November 10, 2005 CMU Fusion Forum, April 2006 CMU “Meeting of the Minds”, May 2006 PSC 20th Birthday Celebration, June 2006 CMU “Approach to Research”, June 2006 CMU Fusion Forum, November 2006

CONSULTING ACTIVITIES Consultant for the Polaroid Corporation in Cambridge, MA, 1993-1995. Planning Committee Florida Advanced Materials Conference, 1993-1995. Air Force Research and National Materials Advisory Board Workshop, 1999. Technology Advisory Board Member for B.F. Goodrich, 1999-2000 Consultant to Plextronics, Inc., 2003-present.

EDITORIAL POSITIONS Journal of Materials Chemistry (Royal Society of Chemistry), Member of International Advisory Board, 1994-1997. Editorial Board, Advanced Materials, 1998-present.

PANELS & OUTSIDE COMMITTEE WORK

NSF Small Business Innovative Research Panel Member (1996) NSF Materials Chemistry Workshop Reviewer of Applications (1997) Organizer for International Union of the Materials Research Society Symposium on Optoelectronic Materials and Conducting Polymers, Cancun, Mexico, August, 1995 Co-organizer Professor Dwaine O. Cowan Symposium, May 1995 Siemens-Westinghouse Regional Science Fair Judge, 1999-2003 Siemens-Westinghouse Regional Science Fair, Lead Judge, 2000

PROFESSIONAL SOCIETIES Member of the American Chemical Society

PAST RESEARCH FUNDING

Faculty Development Fund

"New Methods to Molecular and Organic Ferromagnetism: Synthesis of High Spin Materials."

Period Covered 2/91-6/93

$2885.80

American Chemical Society Petroleum Research Fund PRF-Type G

"A Self-Assembly Approach to Novel Conducting Polymers"


$21,000

NSF Chemistry Division

"The Design, Synthesis, and Development of Self-Assembling


$215,000

20

Conducting Oligomers and Polymers"

AT&T Foundation Special Foundation Award

"Investigation of the Electrical and Electrochemical Properties of Conducting and Magnetic Organic Materials"


$29,000

Faculty Development Fund

"New Synthetic Methods Leading to Carbon-Sulfur Based Molecular Wires, Optical Switches, and Magnets."


$2000

Polaroid Corporation Research Award

"Design and Synthesis of New Luminescent Materials"

$7,000

NATO Collaborative Research Grant

"Supramolecular Chemistry and Non-Linear Optical Properties of Organized Polythiophene Assemblies"


$8,500

NATO Collaborative Research Grant

"Supramolecular Chemistry of Regioregular Amphiphilic Poly(3-alkylthiophene) Derivatives"


$11,200

Air Force Small Business Technology Transfer Research Grant (STTR) with the EIC Corporation

"Enhanced Non-Linear Optical Properties in Regioregular Conjugated Polymers"


$100,000 (Total) ($40K RDM)

New Energy and Industrial Technology Development Organization (NEDO)

"Tunable Photonic Crystals from Interpenetrating Electroactive Networks: Design, Synthesis, and Devices"


$780,000 (Total) ($130,000 RDM)

Air Force SBIR New Polymers for Airplane Canopies


$100,000 $33K RDM

NSF Chemistry Division-renewal of above grant

"Self-Assembly in Conducting Polymers"


$475,000

Air Force-Wright Patterson Air Force Base

"New Conducting Polymer Elastomers"


$200,000

National Institute of Occupational Health and Safety

"MEMS/Conducting Polymer Sensors"


$400K $150K RDM

NSF Chemistry Division-renewal of above grant

“Self-Assembly in Conducting Polymer Nanostructures and Superstructures” PI: McCullough


$550,000

CURRENT RESEARCH FUNDING

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Air Force MURI "Single Chip Multi-Modal Nanosenors" PI: Dr. David Lambeth CMU Electrical/Computer Engineering


$2.9M $419K RDM

Pennsylvania Department of Health

"Integrated Protein Informatics for Cancer Research" PI: McCullough


$3.5M $32K RDM

NIOSH “Integration of Monolithic CMOS Technologies” G. Fedder, PI


$450K

NSF CRIF "Purchase of a High Field NMR" PI: McCullough

$319K

NSF “Conducting Block Copolymer Nanostructures”

Period Covered 8/15/04-7/31/07

$506K

NSF

ACTIVE SCIENTIFIC COLLABORATIONS External to CMU Professor Thomas Bjørnholm, Chemistry, University of Copenhagen, Denmark Thomas and I have a project in supramolecular chemistry and non-linear optics of polythiophene nanostructure assemblies. I spent three months at the University of Copenhagen as a visiting professor in 1996. Thomas and I have a student exchange program. Internal Professor Tomasz Kowalewski, Chemistry Professor Krzysztof Matyjaszewski, Chemistry Professor David Lambeth, Electrical and Computer Engineering Professor Gary Fedder, Electrical and Computer Engineering Professor Lee Weiss, Robotics Institute Have also written grants with Dr. Victor Weedn (MBIC)

REVIEWS OF PUBLICATIONS AND PROPOSALS 1990-present

Proposals National Science Foundation (NSF) Reviewer - Divisions of Chemistry and Materials Research 1. Organic & Macromolecular Program 2. Materials Synthesis and Processing Program 3. Inorganic, Bio-inorganic, & Organometallic Program NSF Experimental Program to Stimulate Competitive Research (EPSCoR) Program Petroleum Research Fund (PRF) Research Corporation NSF Career Proposals ARO NATO Air Force Papers (listed in rough order of frequency)

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Reviewer for: Journal of the American Chemical Society Advanced Materials Macromolecules Chemistry of Materials Journal of Materials Chemistry Journal of Organic Chemistry Journal of the Chemical Society, Chemical Communications Tetrahedron Letters Synthetic Metals Journal of Polymer Science, Chemistry Journal of the Chemical Society, Perkins Transactions Molecular Crystals and Liquid Crystals Book Reviewed for the journal Molecular Crystals and Liquid Crystals the book Low-Dimensional Organic Conductors. By Andrzej Graja (Institute of Molecular Physics, Polish Academy of Sciences, Poznan´, Poland). World Scientific: Singapore. 1992. 306 pages.

SERVICE AND COMMITTEE WORK WITHIN THE UNIVERSITY 1990-1991 Graduate Recruiting Committee-vice chair. Reviewed ≈150 files and met with ≈90% of prospective students (35-50 students total) Junior Organic Faculty Search Committee Departmental Instrumentation Committee Judge for CMU Sigma Xi Undergraduate Research Symposium Colloquium Committee 1991-1992 Graduate Recruiting Committee-vice chair. Reviewed ≈150 files and met with ≈90% of prospective students (35-50 students total) Junior Organic Faculty Search Committee Senior Organic Faculty Search Committee Junior Inorganic Faculty Search Committee Graduate Student Oversight Committee Instrumentation Committee Committee for Chemical Use in Mellon Institute Judge for CMU Sigma Xi Undergraduate Research Symposium 1992-1993 Graduate Recruiting Committee - Chairman Initiated and Led an Annual Round Table Discussion to Advise Undergraduates About Graduate School Departmental Staff Committee Departmental Instrumentation Committee Graduate Student Oversight Committee 1993-1994

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Member of the Executive Committee in Chemistry Graduate Recruiting Committee-Chairman 2nd Annual Round Table Luncheon to Advise Undergraduates About Graduate School Departmental Instrumentation Committee Graduate Student Oversight Committee Undergraduate Laboratory Renovation Committee ad hoc Organic Curriculum Committee College Committee on Health & Safety and Chemical Use in Mellon Institute Task Force on the Chemistry Graduate Program Graduate Fellowship Committee 1994-1995 Member of the Executive Committee in Chemistry Co-Chair Senior Organic Chemistry Faculty Search Committee Graduate Recruiting Committee-Chairman Departmental Infrastructure Committee-co-wrote instrumentation grant with Jon Lindsey Undergraduate Laboratory Renovation Committee Graduate Fellowship Committee MCS Graduate Handbook Committee Judge of Sigma Xi Undergraduate Symposium 1995-1996 Co-Chair Senior Organic Chemistry Faculty Search Committee Department Head Search Committee Departmental Infrastructure Committee-co-wrote instrumentation grant with Jon Lindsey Undergraduate Laboratory Renovation Committee (25 meetings in 1995) Director of Center of Molecular Analysis Search Committee Member of the Executive Committee in Chemistry Departmental Strategic Planning Committee Task Force on Procurement Card Customer Needs Mellon Institute Space Committee Division of Molecular Sciences Brochure Committee 1996-1997 Associate Department Head of Chemistry-responsibility and oversight over undergraduate labs and renovation, teaching assistants, graduate program including admissions and advising, space, infrastructure, substitute for Head at many meetings Chair, Senior/Junior Organic Chemistry Faculty Search Committee Department Head Search Committee Undergraduate Laboratory Renovation Committee Member of the Executive Committee in Chemistry Undergraduate Lab Instructor Search Committee MCS Promotions Review Committee-substitute for Head 1997-1998 Department Head Search Committee Undergraduate Laboratory Renovation Committee - Chair Member of the Executive Committee in Chemistry

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1998-2000: Key Committees or Service Department Head Chair, Organic Chemistry Search Committee Chair, President's Task Force on Infrastructure and Laboratories Subcommittee for the CMU Leadership Committee on Cell, Tissue, and Bone Engineering Initiative MCS College Council MCS College Review Committee Electrical and Computer Engineering Head Search Committee Biology Head Search Committee Inorganic Chemistry Search Committee Polymer/Materials Chemistry Search Committee Undergraduate Laboratory Renovation Committee - Chair Organic Chemistry Search Committee Assistant Vice President of Facilities Management Search Committee 2000-present: Key Committees or Service Provost Search Committee, 2000 Chief Financial Officer Search Committee, 2003 Chair, Dean of the School of Computer Science Search Committee, 2004 Co-Chair, Dean of the School of Engineering Search Committee, 2004 Comptroller Search Committee, 2004 Chair, Custodial Contract Award Committee, 2004 Chair, MCS College Council Polymer/Materials Chemistry Search Committee, 2003, 2004 University Biotechnology Implementation Committee President's Council University Non-Tenure Review Committee University Tenure Review Committee Chair, College Tenure Review Committee Chair, College Non-Tenure Review Committee Board of Trustee's Information Technology Strategic Planning Committee (Chair of

Bioinformatics/Computational Life Sciences) Board of Trustees’ Environmental Strategic Planning Committee Board of Trustees’Research and Commercialization Committee Leader of University's Biotechnology Initiative Hunt Botanical Institute Major Policy Committee

CONTRIBUTIONS TO EDUCATION Courses Taught: 1990-2000 1990 Fall Chemistry 09-711

Physical Organic Chemistry Faculty Course Evalution (FCE) 3.22/5.00

1991 Spring No teaching assignment. Time off to set-up lab.

1991 Fall Chemistry 09-711 Physical Organic Chemistry

FCE 4.00/5.00

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1992 Spring Chemistry 09-132 Experimental Techniques in Chemistry II

FCE 4.21/5.00

1992 Fall Chemistry 09-711 Physical Organic Chemistry

FCE 4.55/5.00

1993, Spring Chemistry 09-132 Experimental Techniques in Chemistry II

FCE 3.63/5.00

1993, Fall Chemistry 09-811 Solid State and Materials Chemistry

FCE none


FCE 3.42/5.00

1994, Fall Chemistry 09-811 Advanced Organic Chemistry

FCE 4.20/5.00

1994, Fall Teaching and Advising Network Class, Pilot Course of "Freshman Seminar" organization by Eric Grotzinger.


FCE 3.70/5.00

1995, Fall Chemistry 09-117 Organic Chemistry I

FCE 3.56/5.00

1996, Spring Chemistry 09-811 Advanced Organic Chemistry

FCE 4.38/5.00

1996, Fall time off as associate head position 1997, Spring Chemistry 09-132

Experimental Techniques in Chemistry II FCE 4.61/5.00


1998, Spring Sabbatical Leave 1998, Fall Chemistry 09-231

Experimental Techniques in Chemistry III

1999, Spring Off as Head 1999, Fall Chemistry 09-231

Experimental Techniques in Chemistry III


CURRENT RESEARCH GROUP

Current Postdoctoral Research Fellows Dr. Genevieve Sauve Dr. Mihaela Iovu Dr. Itaru Osaka Dr. Mishra Sarada Current Graduate Students Rui Zhang (co-advisor with Professor Kowalewski) Jessica Cooper

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Anna Javier Junying Liu Current Undergraduate Students Stefanie Sydlik Former Research Group Members Ph.D Students:

John A. Belot (graduate student, 9/90-5/95), entered Fall 1990 "I. New Metal-Tetrathiafulvalene and Tetrathiafulvalene Building Blocks For New Electronic, Magnetic, and Photonic Materials. II. Surface Characterization of CdSe Nanocrystallite Semiconductors" Thesis Defense: May 1995 John had a postdoctoral with Professor Tobin Marks, Northwestern University; Associate Professor of Chemistry at University of Nebraska Shawn P. Williams (graduate student, 9/90-1/96), entered Fall 1989 Thesis Title: "I. Tuning the Electrical and Optical Properties in Conducting, Head-to-Tail Polythiophenes Through Synthesis and Molecular Recognition. II. Toward Well-Defined Oligomers and Polymers of Pyrrole. Thesis Defense: January 1996 Shawn is the CTO of Plextronics, Inc., Pittsburgh, PA Paul C. Ewbank (graduate student, 6/90-5/96), entered Fall 1989 Thesis Title: "The Development of Electrically Conductive, Self-Assembling Oligomers of Thiophene and Chemosensors and Ionochromic Water Soluble, Regioregular Polythiophenes." Thesis Defense: May 1996 Mani Jayaraman (graduate student, 1/92-2/97), entered Fall 1991 Thesis Title: "Control of Electronic and Photonic Properties and Structures of Polythiophenes by Recipe: Random Head-to-Tail Coupled Copolymers of Polythiophenes and Self-Assembly in Conductive Polymers" Thesis Defense: February 1997 Mani now works for W.R. Grace in Maryland as a senior research scientist. Robert Loewe (graduate student, 1/96-5/00), entered Fall 1995 Thesis Title: "Synthesis, Characterization, and Development of Structurally Homogeneous Polythiophenes (PTs) and Polythienylene Vinylenes (PTVs)" Thesis Defense: May 2000 Rob was a postdoctoral with Professor Jonathan Lindsey at North Carolina State University and is now at a start-up called Zetta-Core. Richard Pilston (graduate student, entered Fall 1995) Thesis Title: “Synthesis and Characterization of Novel Regioregular Polythiophenes, Random Copolymers of Thiophene and Studies of the GRIM Polymerization Method for the Synthesis of Polythiophenes” Thesis Defense: September 2001

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Rich co-founded Plextronics, Inc., in 2002; entering MBA program at Pennsylvania State University in Fall 2005. Jingsong Liu (graduate student, entered Fall 1997) Thesis Title: “End-Group Functionalization of Regioregular Head-to-Tail Poly(3-alkylthiophenes) and its Application to the Synthesis of Well-Defined Rod-Coil Block Copolymers: Tuning the Self-Assembly and Functional Properties of Conducting Polymers” Thesis Defense: January 2002 Lei “James” Zhai (graduate student, entered Fall 1998) Thesis Title: “Fabrication of Micro- and Nanostructures from Functionalized Regioregular Poly(3-alkylthiophenes” Thesis Defense: December 2002 Elena Sheina, (graduate student, entered Fall 1998) Thesis Title: “Synthesis and Characterization of Novel Regioregular Thiophene Polymers with Polyetheric Substituents” Thesis Defense in August 2004 Currently working at Plextronics, Pittsburgh, PA Karen Zaiger, left graduate program in 2002; currently attending school in California. Edward Jones, left graduate program in 2003; received M.S. degree in 8/2005 from CMU. Currently employed as Senior R&D Scientist, Supelco Jessica R. Cooper (graduate student, entered ) Thesis Title: Thesis Defense: Casey Craley (graduate student, entered Fl 2004) Received his M.S. in December, 2006. Has left the program. Anna E. Javier (graduate student, entered Fl 2004) Thesis Title: Thesis Defense: Junying Liu (graduate student, entered Fl 2005) Former Postdoctorals Jyoti Seth (postdoctoral, 8/91-8/92)--was a postdoctoral with Prof. David Bocian, Univ. of California, Riverside and is now at Grace Chemical in Boston. Karine Heuze (postdoctoral, 11/98-11/99)--faculty member at CNRS. Darin Laird research scientist at Plextronics. Malika Jeffries-EL, Assistant Professor at Iowa State University. Former Visiting Research Scientists Iliana Restrepo, University of Cali, Columbia (6/94-8/95) Daniel Greve, University of Copenhagen, Denmark (8/95-11/95)

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Former Undergraduates (37 total) Renae Lowe (Howard Hughes undergraduate fellow, 9/90-8/92)--Finished a Chemistry Ph.D. Program at the University of Texas, Austin working with Professor Marye Anne Fox and it at Proctor and Gamble. Renae presented her work at the 1992 ACS National Meeting in San Francisco, supported by an Eli Lilly Travel Award she won. Renae has four publications working with me. Debbie Anderson (Hughes undergraduate fellow, 6/91-6/93)-- completed medical school at the University of Pittsburgh and is working at Southwestern Medical School in Dallas. Debbie has two publications working with me. Shannon Hayes (undergraduate student, 8/91-5/93)--was a consultant in an environmental firm in Houston, TX and has finished Environmental Studies MS program at the University of Texas, San Antonio. She is at Lucent. Julia Kuo (undergraduate student, 5/92-8/92) Bernadette Baluyot (undergraduate student, 2/93-6/93) senior project MEMS Vani Kanna (undergraduate student, 2/93-6/93) senior project MEMS Lynnette Miller (undergraduate student, 5/92-5/94)-- owns a rock climbing business. Lynnette has presented a poster on her work at the 1993 ACS Regional Meeting. Lynnette has one publication working with me. Jerry Reddinger (undergraduate student, 1/93-5/94)--finished Chemistry Ph.D. Program at the University of Florida working with Prof. John Reynolds. Currently at Nalgene. Jerry has presented a poster on his work at the 1993 ACS Regional Meeting. Jerry has one publication working with me and obtained a Small Undergraduate Research Grant (SURG). Sonika Bhatnagar (undergraduate student, 6/93-5/94)--attended medical school at the Medical College of Pennsylvania. She obtained a Small Undergraduate Research Grant (SURG). Melissa Petruska (undergraduate, 1/93-5/95), NSF pre-doctoral fellow, finished her Ph.D. in Chemistry at the University of Florida working with Professor Daniel Talham. She is a Research Scientist at ATMI, Inc., Danbury, CT. Melissa Petruska has presented her work at the 1994 ACS National Meeting in San Diego, supported by an National Organic Chemistry Undergraduate Travel Award from the Robert Wood Johnson Foundation. Melissa had two publications. She obtained a Small Undergraduate Research Grant (SURG). Molly Dalkiewicz (undergraduate, 1/93-5/95), attended graduate school at Colorado State University. She obtained a Small Undergraduate Research Grant (SURG). Cindy Cepanoske (undergraduate, 1/93-5/95), attended graduate school at the University of Utah She obtained a Small Undergraduate Research Grant (SURG).

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Hindy Bronstein (undergraduate, 9/94-5/95), finished her Ph.D. in Chemistry at Boston College working for Professor Larry Scott. She was a current postdoctoral with Professor Timothy Swager at MIT. She obtained a Small Undergraduate Research Grant (SURG). Zeynep Ebcioglu (undergraduate, 9/94-5/95), medical school at SUNY Buffalo Julie Summers (9/94-5/96), graduate school at University of Chicago in Biochemistry. She obtained a Small Undergraduate Research Grant (SURG). Deborah Smithline (1/96-12/96), has a job at Anderson Consultants. She obtained a Small Undergraduate Research Grant (SURG). Kerry McIntyre (1/96-12/96), is attending graduate school at Darmouth University in Biochemistry. She obtained a Small Undergraduate Research Grant (SURG). Benjamin Rowe (1/96-12/96) Noah Scarr (undergraduate, 9/95-5/96) He obtained a Small Undergraduate Research Grant (SURG). Attended graduate school in chemistry at the University of Oregon. Julie Anne Sippel (5/96-8/96) High School Student from CMU Summer Outreach Program. Anne Marie Devine (9/95-12/97) Obtained a small Undergraduate Research Grant (SURG). Eric Van Ingewen (9/96-5/98) Rachel Hauser (9/95-5/98). She now has a Small Undergraduate Research Grant (SURG). Attended graduate school in Chemistry at USC. Sonya Kerchosky (5/96-8/99) Graduate school in Chemistry at NYU. Eric Silverman (5/97-5/99) Graduate school in Chemistry at University of Florida. Cindy Meisner (5/97-5/99) Kathryn McElroy (9/98-5/99) Graduate school at University of California at Berkeley Kris Stokes (9/97-5/00) at Massachusetts Institute of Technology Alison Cartwright (5/00-8/00) Christine Siverd (8/99-5/01) Marta Biarnes (9/00-5/01) Jill Millstone currently a chemistry graduate student at Northwestern University. Lindsey Ferris (09/03-05/05) – attending graduate school in Ohio

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Ashley Krankowski (01/15/04-05/05) Kelly Collins (01/15/04-12/04) Meara Kauffman – working in lab during Summer 2005; undergrad at Juniata College. Stephanie Sydlik – September 2005-present

02/01/2007

richard d. mccullough mellon college of science carnegie ... · 1999-2000: technical advisory...

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