[report of findings for 2012 deep monitoring well … · 2020. 11. 29. · report of findings 20 f...

23
FTS i\IL- p ... 3: 13 FE B 26 n · Field & Technical Services 200 Third Avenue • Carnegi e, PA 15106 • Phone: 41 2·429·2694 • Fax: 412-279·4512 February 27. 20 13 Ms. Raji Josiam Mail Code 6 SF-AP U.S. Environmental P rotection Agency 1 445 Ross A venue. Suite 1200 Dallas, Texas 75202-2733 RE: Report of Findings 2012 Deep Monitoring WeU Sampling and A nalysis South Cavalcade Superfund Site Houston, Texas Dear Ms. Josiam: This report presents the results of the 20 12 deep mon itorin g wel l ground wate r sampl ing and analysis program conducted in accordance with the Record of Deci sion ( ROD) and United States Environmental Protecti on Agency approved Remedial Design Work Plan ( RDWP ) for the South Cavalcade Superfund Site located in Houston. Texas. The annual groundwater sampling event was conducted on May I 0. 20 12 in accordance with the procedures outlined in the Remedial Desi gn Sa mpling and Analysis Plan and the Remedial Design Qual ity Assurance Plan. The obje ct ive of the deep we ll sampl in g progr am is to dete rm ine if potentia l.l y carcinogenic po lycyc li c aro mati c hydrocarbon (pcPAH) compounds are present above background concentrations in groun dwater in the deep aq uifers beneath the si te. To meet the sampling program objective. two deep monitorin g wells (well DW-02 [approx imately 200 feet deep] and well LCW-01 [approx imately 500 feet deep]) (F igure I) are sa mp led annually. However. due to an obstructi on in the wel l. the operator was not able to sampl e or measure the tota l depth of the deeper monitoring well (LCW-01 ). The results or the fie ld and laboratory analyses of groundwater sampled from DW-02 (Table 1 a nd Attachments A and B) ind icate pcPAH concentrations were less than method detection limits. As shown in Table I. these data are consistent with the previous 16 years of data. Although the deeper well could not be sampl ed , the r esults of the analysis of groundwater from the 'vVell (DW -02) were less than the detecti on I irnit. Therefore. there is no indica ti on 006984

Upload: others

Post on 02-Feb-2021

0 views

Category:

Documents


0 download

TRANSCRIPT

  • FTS

    ~G i\IL-

    p ... 3: 4~ 13 FEB 26 n

    · '~~~ Field & Technical Services 200 Third Avenue • Carnegie, PA 15106 • Phone: 41 2·429·2694 • Fax: 412-279·4512

    February 27. 20 13

    Ms. Raji Josiam Mail Code 6SF-AP U.S. Environmental Protection Agency 1445 Ross A venue. Suite 1200 Dallas, Texas 75202-2733

    RE: Report of Findings 2012 Deep Monitoring WeU Sampling and Analysis South Cavalcade Superfund Site Houston, Texas

    Dear Ms. Josiam:

    This report presents the results of the 20 12 deep monitoring wel l groundwater sampl ing and analysis program conducted in accordance with the Record of Decision (ROD) and United States Environmental Protection Agency approved Remedial Design Work Plan (RDWP) for the South Cavalcade Superfund Site located in Houston. Texas. The annual groundwater sampling event was conducted on May I 0. 2012 in accordance with the procedures outlined in the Remedial Design Sampling and Analysis Plan and the Remedial Design Quality Assurance Plan.

    The objective of the deep well sampling program is to determine if potential.ly carcinogenic polycyc lic aromatic hydrocarbon (pcPAH) compounds are present above background concentrations in groundwater in the deep aquifers beneath the site. To meet the sampling program objective. two deep monitoring wells (well DW-02 [approximately 200 feet deep] and well LCW-01 [approximately 500 feet deep]) (Figure I) are sampled annually. However. due to an obstruction in the wel l. the operator was not able to sample or measure the tota l depth of the deeper monitoring well (LCW-01 ).

    The results or the fie ld and laboratory analyses of groundwater sampled from DW-02 (Table 1 and Attachments A and B) indicate pcPAH concentrations were less than method detection limits. As shown in Table I. these data are consistent with the previous 16 years of data. Although the deeper well could not be sampled, the results of the analysis of groundwater from the shallo~ver 'vVell (DW -02) were less than the detection I irnit. Therefore. there is no indication

    006984

  • Report of Findings 20 f 2 Deep .\foniloring /Fell Sampling and Analysis Sowh Cavalcade 5;upe1jimd Site. Houslon. Texas Page 2 Februwr 27. 2nt 3

    of potential impact to the deeper aquifers because if any migration existed. constituents would be detected fi rst in \Ve il DW-02.

    If you have questions. fee l free to ca ll Angela Gate hie ofFTS at ( 4 12) 428-941 1.

    Sincerely.

    Field & Technical Services

    ~J~ Angela Gatch ie Project Scientist

    Attachments

    cc: Mike Bollinger- Beazer (.pdt) Jim Zubrow- Key (.pdt) Fay Duke-TCEQ (Report)

    Enclosures:

    Copy of Letter Report and .pdf submittal

    FTS

    006985

  • Report Q( Findings lnJ 1 Deep .lfoniforing Well Sampling anti .-lna(l'Sis Svwh Camlcade Supe1jimd Sile. Hous/on. Texas

    TABLE

    Report of Findings 20 12 Deep Monitoring Well Sampling and Analysis South Cavalcade Superfund Site Houston. Texas

    F"T S

    006986

  • Samplo Location: DW-02 LCW-01 OW-02 Sample Date: Mar-95 Mar-95 Apr-96

    I METHOD I BENZO(AlPYRENE UGIL 002 u 002 u 002 u BENZO(A)ANTHRACENE UGIL 002 u 002 u 0.02 u BENZO(B)FLUORANTHENE UG/L 0 02 u 0.02 u 0.02 u BENZO(K)FLUORANTHENE UG/L 0 02 u 0.02 u 002 u CHRYSENE UG/L 0 15 u 0.15 u 015 u DIBENZOiA.H)ANTHRACENE UG/L 0 03 u 0.03 u 0.03 u INDEN0(1 ,2,3-CD)PYRENE UGIL 0.05 u 0.05 u 0.05 u

    Notes: U indicates compound was analyzed lor. bul not detected In 1998, neuher well LCW-01 nor well DW-02 were sampled

    Table 1 South Cavalcade

    Analytical Summary 1995 -2012 Annual Deep Well Groundwater Sampling

    South Cavalcade, Texas

    LCW-01 OW-02 DW-02 OW-02 DW-02 DW-02 DW-02 DW-02 Apr-96 Mar-97 Sep-S9 Mar-00 Mar-01 Dec-02 Dec-03 Dec-04

    0.02 u 0.054 u 0.02 UJ 0.02 u 0.22 u 020 u 0.19 u 019 u 0.02 u 0.02 u 0.02 u 0.02 u 0,22 u 0.20 u 019 u 019 u 0.02 u 0.053 u 0.02 UJ 0 02 u 0.22 u 020 u 019 u 0 19 u 0.02 u 0.046 u 0.02 u 0.02 u 0.22 u 0.20 u 0 19 u 0 19 u 0.20 u 0.150 u 0.15 u 0.15 u 2.20 u 0 20 u 019 u 0,19 u 0.03 u 0.03 u 0.03 u 0.03 u 0.22 u 0.20 u 019 u 0.19 u 0.05 u 0.05 u 0.05 u 0.05 u 0.22 u 0.20 u 0 19 u 0.19 u

    FTS

    DW-02 DW-02 DW-02 DW-02 DW-02 DW-02 DW-02 DW-02 Dec-05 Dec-06 Dec-07 Dec-08 Dec-09 Dec-10 Apr-11 May-12

    019 u 020 u 020 u 019 u 020U 020U 019 u 019 u 019 u 020 u 020 u 019 u 020 u 0 20 u 019 u 0 19 u 019 u 0 20 u 020 u 0 19 u 0 20 u 0 20 u 0 19U 0 19 u 019 u 0 20 u 0 20 u 0 19 u 020 u 0 20 u 019 u 0 19 u 0.19 u 0.20 u 0 20 u 0 19 u 0.20 u 0.20 u 0.19 u 0 19 u 0.19 u 0.20 u 0 20 u 019 u 0.20 u 0.20 u 0.19 u 019 u 0.19 u 0.20 u 0 20 u 0 19 u 0.20 u 0 20 u 0.19 u 0 19 u

    lol l

    006987

  • Report of Findings ?O!'J Deep .\loni10ring ll'el/ Sampling and Ana~I'Sis South ("(ll'a/cade Supet:ftmd Site. Houston. Texas

    FIGURE

    Site Location Map South Cavalcade Superfund Site Houston. Texas

    FT S

    006988

  • • I

    \ •·

    l r r

    \ I

    I

    DW-02

    -$-

    LCW-01

    -$-

    \ I

    \ I

    \ I I

    I

    \ I

    \ I

    I

    \

    LQCAllON Of fORMER WOOD TREAllNC AREA

    N LEGEND

    PROPERlY IIOIJNOAA'r

    RAI.JER IIONI!llRJHG WEll. LOCATION

    AREA OF LOCATION

    BEAZER EAST, INC PITISBURGH, PENNSYLVANIA

    SOliTH CAVALCADE HOUSTON, TEXAS

    SrrE LOCATION MAP

    FIELD ac TECHNICAl SERI/ICES, llC

    200 THIRD AVENUE CARNEGIE, PA 15106

    006989

  • Report of Findings 2012 Deep .l!onitoring Well Sampling and Analysis South Cal'a!cade Superfimd Site. Houslon. Texas

    ATTACHMENT A

    Analytical Data Package

    Report of Findings 20 12 Deep Monitoring Well Sampling and Analysis South Cavalcade Superfund Site Houston. Texas

    006990

  • ·········· LINKS

    Review your project results through

    Totd-Acce5s

    Have a Question?

    U' A~k The Ex ert

    Visit us at:

    Test America THE LEADER IN ENVIRONMENTAL TESTING

    ANALYTICAL REPORT TestAmerica Laboratones Inc TestAmerica Pittsburgh 301 Alpha Drive RIDC Park Pittsburgh, PA 15238 Tel: (412)963-7058

    TestAmerica Job ID. 180-10681 -1 Client Project/Site: South Cavalcade

    For Field & Technical Services LLC 200 Third Avenue Carnegie, Pennsylvania 15106

    Attn: Ms. Angie Gatchie

    ~~ Authorized for release by: 512512012 9:07:21 AM

    Veronica Bortot Project Manager II veronica [email protected]

    This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

    Results relate only to the items tested and the sample(s) as received by the laboratory.

    D

    006991

  • Client: Field & Technical Services LLC Project/Site: South Cavalcade

    Table of Contents

    TestAmerica Job 10: 180-10661-1

    Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 Certification Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 Receipt Checklists. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

    Page 2 of 14 TestAmenca Pittsburgh

    5/25/2012

    B

    006992

  • Client: Field & Technical Services LLC Project/Site: South Cavalcade

    Job ID: 180-10681 -1

    Laboratory: TestAmerica Pittsburgh

    Narrative

    Comments

    No additional comments.

    Receipt

    Case Narrative

    Job Nar rative 180-10681-1

    TestAmerica Job 10 180-10681-1

    The samples were received on 5111!2012 9:25AM; the samples arrived in good condition, properly preserved and, where required. on ice. The temperatures of the 2 coolers at receipt time were 1 .2° C and 3.8° C.

    GC/MS Semi VOA

    No analytical or quality issues were noted.

    Organic Prep No analytical or quality issues were noted.

    Page 3 of 14 TestAmerica Pittsburgh

    5/25/2012

    El

    006993

  • Defi nitions/Giossary Client: Field & Technical Services LLC Project/Site: South Cavalcade

    Qualifiers

    GCIMS Semi VOA

    Qualifier

    u

    Glossary

    Abbreviation

    l)

    %R

    CNF

    DL. RA. RE. IN

    EDL

    EPA

    MDL

    ML

    NO

    PQL

    QC

    RL

    RPD

    TEF

    TEO

    Qualifier Description

    lndicatesihe -anaiyte -was anaiyzed fOrbut noicietected.-

    These commonly used abbreviations may or may not be present in this report.

    Percent Recovery

    Contains no Free Liquid

    Indicates a Dilution, Reana:ysis, R,e-extraction, or additional initial metals/anion analysis of the sample

    Estimated Detection Limit

    United States Environmental Protection Agency

    Method Detection Limit

    Minimum Level (Dioxin)

    Not detected at the reporting limit {or MDL or EDL if shown)

    Practical Quantitation Limit

    Quality Control

    Reporting Limit

    Relative Percent Difference. a measure of the relative difference between two points

    Toxicity Equivalent Factor (Dioxin)

    Toxicity Equivalent Quotient (Dioxin)

    Page 4 of 14

    TestAmerica Job 10: 180-10681 -1

    TestAmerica Pittsburgh 5/25/2012

    II

    006994

  • Client: Field & Technical Services LLC Project/Site: South Cavalcade

    Laboratory Authority

    TestAmerlca Pltisburgh Arkansas CEQ

    TestAmerica Pittsburgh California

    TestAmer~ca Pittsburgh Connecticut

    TestAmenca Pittsburgh Florida

    TestAmenca Pittsburgh IllinoiS

    TestAmertca Pittsburgh Kansas

    TestAmenca Pittsburgh L·A·B

    TestAmenca Pittsburgh Lou1siana

    TestAmerica Pittsburgh New Hampshire

    TestAmerlca Pitlsburgh New Jersey

    TestAmerlca Pittsburgh New York

    TestAmerica Pittsburgh North Carolina DENR

    TestAmerica Pittsburgh Pennsylvania

    TestAmerica Pittsburgh Pennsylvania

    TestAmerica Pittsburgh South Carolina

    TestAmerica Pittsburgh USDA

    TestAmerica Pittsburgh USDA

    TestAmenca Pittsburgh Utah

    TestAmenca Pittsburgh Virginia

    TestAmerica Pittsburgh West Virginia OEP

    TestAmerica Pittsburgh 'Msconsln

    Certification Summary

    Program

    State Program

    NELAC

    State Program

    NELAC

    NELAC

    NELAC

    OoOELAP

    NELAC

    NELAC

    NELAC

    NELAC

    State Program

    NELAC

    State Program

    State Program

    Federal

    Federal

    NELAC

    NELAC

    State Program

    State Program

    EPA Region

    6

    5

    7

    6

    3

    3

    8

    3

    3

    5

    TestAmerica Job 10: 180-10681 -1

    Certification 10

    88-0690

    4224CA

    PH-0688

    E87t008

    002602

    E-10350

    l2314

    04041

    203011

    PAOOS

    11182

    434

    02-00416

    02-416

    89014002

    P330- 1 0-{)0 139

    P-Soil-01

    STLP

    460 189

    142

    998027800

    Accreditation may not be offered or required tor all methods and analytes reported In th1s package. Please contact your project manager for the laboratory's

    current list of certdied methods and analytes.

    Page 5 of 14 TestAmerica Pittsburgh

    5/25/2012

    006995

  • Client Field & Technical Services LLC Project/Site: South Cavalcade

    Lab Sam pie 10

    18o:iasai-=-1

    180-10681 -2

    180-1068 1-3

    Client Sample 10

    0'1\102-051012

    Dl!P-051012

    DVV02-051012 FIELD BLANK

    Sample Summary

    Page 6 of 14

    Matrix

    Waler

    Waler

    Water

    TestAmerica Job 10: 180-10681-1

    Collected Received

    0511011211 :10 0 511 1/1209:25

    05/10/12 11 :10 0 5/11/12 09:25

    05/10/1211 :10 05111/1209:25

    TestAmerica Pittsburgh 5125/2012

    006996

  • Client: Field & Technical Services LLC Project/Site: South Cavalcade

    Method Description

    Method Summary

    Method

    8270C LL semivoialiie0;9aniC: compoundsbyGCMs - i:owlevels

    Protocol References:

    TestAmerica Job ID: 180-10681 -1

    Protocol ·sws4s ·--

    Laboratory

    TAL PIT

    SW846 ="Test Methods For Evaluating Solid Waste. Physical/Chemical Methods", Third Edition. November 1986 And Its Updates.

    Laboratory References:

    TAL PIT = TestAmerica Pittsburgh, 301 Alpha Drive. RIDC Park. Pittsburgh, PA 15238, TEL (412)963-7058

    Page 7 of 14 TestAmerica Pittsburgh

    5/25/2012

    II

    006997

  • Client Sample Results Client: Field & Technical Services LLC

    Project/Site: South Cavalcade

    Client Sample ID: DW02-051012 Date Collected: 05/1 0/12 11 1 0

    Date Received: 05/11 /12 09 25

    Method: 8270C LL - Semlvolatile Organic Compounds by GCMS -Low Levels Analyte Result Qualifier RL MDL

    8enzoJaJanit1racei16

    Benzo[b]fluoranthene

    Benzo[k]fluoranthene

    Benzo[alpyrene

    Chrysene

    Di~enz(a. h)anthracene

    lndeno[1 ,2.3-cd]pyrene

    Surrogate

    ra/Pile-i1;,T-ei14 Nitrobenzene-d5

    2-F/uorobipheny/

    Client Sample ID: DUP-051012 Date Collected 05/1 Of12 11.10

    Date Received· 05/11112 09·25

    0.19

    0.19

    0,19

    0.19

    0.19

    0.19

    0.19

    %Recovery

    83

    78

    77

    u

    u u u u u

    u

    Qualifier

    0.19

    0,19

    0.19

    0.19

    0.19

    0.19

    0,19

    Limits

    10. 132

    23.112

    19 . 107

    Method: 8270C LL- Semivolatile Organic Compounds by GCMS - Low Levels Analyte Result Qualifier RL MDL

    Benzo[a]anthracene 0.21 u Benzo[b]fluoranthene 0.21 u Benzo[k]fluoranthene 0.21 u Benzo[a]pyrene 0.21 u Chrysene 0.21 u Oibenz(a.h)anthracene 0.21 u lndeno[1 .2,3-cd]pyrene 0.21 u

    Surrogate %Recovery Qualifier

    ieiP"henyr-d i4 99 Nilrobenzene-d5 85

    2-F/uorobipheny! 81

    Client Sample ID: DW02-051012 FIELD BLANK Date Collected 05/10/1211 10

    Date Received: 05/11/12 09:25

    0.21

    0.21

    0.21

    0.21

    0.21

    0.21

    0.21

    Limits

    10 - 132

    23- 112

    19 . 107

    M ethod 8270C LL - Semivolatile Organic Compounds by GCMS -Low Levels Analyte Result Qual ifier RL

    Benzo[a]anthracene 0.20 u o.2o Benzo[b]fluoranlhene 0.20 u 0.20 Benzo[k]fiuorant.,ene 0.20 u 0.20 Benzo[a]pyrene 0.20 u 0.20 Chrysene 0.20 u 0.20 Oibenz(a.h)anthracene 0.20 u 0.20 lndeno[1.2,3-cdjpyrene 0.20 u 0.20

    Surrogate %Recovery Qualifier Limits

    rerphenyl-d14 101 10 . 132

    Nitrobenzene-d5 92 23 - 112

    2-Fiuorobiphenyl 87 19 . 107

    Page 8 of 14

    MDL

    Unit D

    ug/L

    ug/L

    ug/L

    ug/L

    ugiL

    ugll

    ugll

    Unit D

    ugll

    ug/L

    ug/L

    ug/L

    ug/l

    ug/L

    ug/L

    Unit D

    ug/L

    ug/L

    ug/L

    ugll

    ug/L

    ugiL

    ug/L

    TestAmerica Job ID: 180-1 0681-1

    Lab Sample 10: 180-10681-1 Matrix Water

    Prepared Analyzed 011 Fac

    osh?i12 o8 22 05123/1217:12

    05117112 08:22 05123112 17:12

    05/17/12 08:22 0512311217: 12

    05117/12 08; 22 05123112 17:12

    05/17/12 08:22 05/23/121 7:12

    05117/12 08:22 05123/12 17:12

    05/17/12 08:22 05123/12 17:12

    Prepared Analyzed Di/Fac

    05117112 08:22 ii5123!T2 ii. i2 1 05117112 08:22 05123/12 17: 12

    05117112 08.22 05123/12 17.·12

    Lab Sample ID 180-10681-2 Matrix· Water

    Prepared Analyzed Oil Fac

    05117112" 08 22 05123112 18:26

    05117112 08:22 05/23112 18:26

    0511 7112 08:22 05/23,112 18:26

    05117112 08:22 05/23112 18:26

    05117112 08:22 05123112 18:26

    05/17/12 08:22 05123112 18:26

    05/17/12 08:22 05123/12 18:26

    Prepared Analyzed Di/Fac ·· ··-·-·-····--··-··-··-·--·-···--

    05123/12 18:26 05117112 08:22

    05117/12 08:22 05/23/12 18:26

    05117112 08.·22 0512311218.26

    Lab Sample 10: 180-10681-3 Matrix Water

    Prepared

    osi1"7ii2 os22 05/17/12 08:22

    05/17/12 08:22

    05/17/12 08:22

    05117112 08:22

    05117/12 08:22

    05117/12 08 22

    Prepared

    05117112 08:22

    05117112 08.·22

    05117112 08:22

    Analyzed Oil Fac

    osi2-:lh2·i-s:si 05/23/121851

    05123/12 1 8:51

    05/23112 18:51

    05/23,112 1 8:51

    05123112 18:51

    05123/12 18;51

    Analyzed DiiFac

    05123/12 18:51

    05123112 18:51

    05123/12 18:51

    TestAmerica Pittsburgh 5/25/2012

    I

    006998

  • Client: Field & Technical Services LLC Project/Site: South Cavalcade

    QC Sample Results

    Method: 8270C LL - Sem•volatile Organic Compounds by GCMS - Low Levels

    Lab Sample 10: MB 180-36296/1-A Matrix: Water

    Analysis Batch: 36988 MB MB

    Ana lyle Resull Qualifier RL MDL Unit

    Benzo[ai anthracene-- ··- 0.20 u 0.20 ug/L Benzo[bjftuoranthene 020 u 0.20 ugiL Benzo[k]fluoranthene 0.20 u 0.20 ug/L Benzo[ajpyrene 0.20 u 0.20 ug/L Chrysene 0.20 u 0.20 ug/L Dibenz(a,h)anthracene 0.20 u 0.20 ugiL lndeno[1.2, 3-cd]pyrene 0.20 u 0.20 ug/L

    MB MB

    Surrogate %Recove1)' Qualifier Limils

    rerpi>enyl-d14 ················---

    83 10 . 132

    Nitrobenzene-d5 84 23 . 112

    2-Fiuorobiphenyl 84 19.107

    Lab Sample 10: LCS 180-36296/2-A

    Matrix: Water Analysis Batch: 36988

    Spike LCS LCS

    Analyte Added Result Qualifier Unit - - ·--·····-·-···-Benzo[ajanthracene 20.0 14.1 ugiL

    Benzo[b]fluoranthene 20.0 14.2 ug/L

    Benzo[k]fluoranthene 20.0 12.6 ug/L

    Benzo[a]pyrene 20.0 14.1 ug/L

    Chrysene 20.0 14.2 ugiL

    Dibenz(a,h)anthracene 20.0 13.6 ug/L

    lndeno(t ,2.3-cdjpyrene 20.0 14.3 ug/L

    LCS LCS

    Surrogate %Recovery Qualifier Limits ··-··- · -·-··-·-

    Terphenyl-d14 82 10.132

    Nitrobenzene-d5 78 23 . 112

    2-Fiuorobiphenyl 78 19 .107

    Lab Sample 10: 180-10681-1 MS

    Matnx: Water

    Analysis Batch: 36988 Sample Sample Spike MS MS

    Analyte Result Qualifier Added Result Qualifier Unit

    Benzo(ajanthracene 0.19 u 19 2 13.• ug/L Benzo(b]fluoranthene 0.19 u 19.2 12.3 ug/L Benzo(k]Ouoranthene 0.19 u 19.2 10.9 ug/L Benzo[a]pyrene 0.19 u 19.2 12.3 ug/L Chrysene 0.19 u 19.2 12.0 UQIL Oibenz(a,h)anthracene 0.19 u 19.2 12.3 ugil lndeno(1 ,2.3-cdjpyrene 0.19 u 19.2 12.4 ugil

    MS MS

    Surrogate %Recovery Qualifier Limits

    Terphenyi-d1 4 76 10 . 132 Nitrobenzene-d5 70 23 - 11 2

    2-Fiuorobiphenyl 60 19 . 107

    Page 9 of 14

    Te

    c

    D Pre~

    05117/1

    05/17/1

    0511711

    05117/1

    05/1711

    0511711

    05/1711

    Pre1

    05117/;

    05/171;

    05/17/;

    ClientS

    D

    c

    D

    006999

  • Client: Field & Technical Services LLC Project/Site: South Cavalcade

    QC Sample Results TestAmerica Job 10: 180-10681-1

    Method. 8270C LL • Semivolatile Organic Compounds by GCMS • Low Levels (Continued)

    Lab Sample 10: 180-10681·1 MSD Matrix: Water Analysis Batch 36988

    Sample Sample

    Anaiyte Result Qualifier

    eienzo[aJantii-fficene - -- -· ··-·-

    0.19 u Benzo[b]fluoranthene 0.19 u Benzo[k]fiuoranthene 0.19 u Benzo[a]pyrene 0.19 u Chrysene 0.19 u Dibenz(a.h)anthracene 0.19 u lndeno[1 .2.3-cd]pyrene 0.19 u

    MSD MSD

    Surrogate %Recovery Qualifier

    T erphen yl-di.4 ·-------- -----------

    81

    Nitrobenzene-ciS 72

    2-F/uorobiphenyl 65

    Spike MSD MSD

    Added Result Qualifier Unit D

    20.4 14.7 ug/L

    20.4 13.0 ugll

    20.4 12.8 ug/L

    20.4 13.5 ugll

    20.4 13.5 ug/L

    20.4 13.7 ug/L

    20.4 13.7 ug/L

    Umits ---------···--

    10. 132

    23. 112

    19 . 107

    Page 10 of 14

    Client Sample ID: DW02-051012

    %Rec

    72

    64

    63

    66

    66

    67

    67

    Prep Type: Totai/NA Prep Batch: 36296

    %Rec. RPD

    Limits RPD Limit

    36: 101 ........ 9

    3s 29 - 98 5 46

    28 - 107 17 31

    26 - 108 40

    37-99 12 42

    19- 118 11 44

    22- 115 10 54

    TestAmerica Pittsburgh 5/25/2012

    D

    007000

  • QC Association Summary Client: Field & Technical Services LLC ProjecVSite: South Cavalcade

    GC/MS Semi VOA

    Prep Batch: 36296

    Lab Sample 10

    180-10681-1

    180-10681-1 MS

    18Q-10681· 1 MSD

    180-10681-2

    180-10681-3

    LCS 180-36296/2-A

    MB 180-3629611-A

    Analysis Batch: 36988

    Lab Sample 10

    180-10681·1

    180· 10681· 1 MS

    180-10681-1 MSO

    180-10681·2

    180-10681·3

    LCS 180-3629612-A

    MB 180-36296/1-A

    Client Sample 10

    owo2:osi ii12

    OW02-051012

    DW02-051012

    DUP-051012

    DW02-051012 FIELD BLANK

    Lab Control Sample

    Method Blank

    Client Sample 10

    owo2-0S1o12-

    owo2-os1o12

    DW02-Q51012

    DUP-051012

    OW02-051012 FIELD BLANK

    Lab Control Sample

    Method Blank

    Prep Type

    Totai/NA

    Totai/NA

    Totai/NA

    Totai!NA

    Totai/NA

    Totai/NA

    Totai/NA

    Prep Type

    Totai/NA

    Total iNA

    Total iNA

    Totai/NA

    Totai/NA

    Totai/NA

    Totai/NA

    Page 11 of 14

    Matrix

    Water

    Water

    Water

    Water

    Water

    Water

    Water

    Matrix

    Water

    Water

    Water

    Water

    Water

    Water

    Water

    TestAmerica Job ID: 180-10681-1

    Method

    3520C

    3520C

    3520C

    3520C

    3520C

    3520C

    3520C

    Method 8276-CLL

    8270C LL

    8270C LL

    8270C LL

    8270C LL

    8270C LL

    8270C LL

    Prep Batch

    Prep Batch

    36296

    36296

    36296

    36296

    36296

    36296

    36296

    TestAmerica Pittsburgh 5/25/2012

    007001

  • Chain of

  • ,-

    ..... 1_..._...~- .• ..,..._._. - aa....• - ......... fiT~~--

    C:'Jain of Custody Recof"d Te?tAmerica

    TAl~18 (1008)

    0 M

    Q) Cl

  • Login Sample Receipt Checklist

    Client Field & Technical Services LLC

    Login Number: 10681

    List Number: 1

    Creator : Ras, Erin F

    Question

    Radioactivity either was not measured or, if measured. is at or below background

    The cooler's custody seal. if present, is intact.

    The cooler or samples do not appear to have been compromised or tampered with.

    Samples were received on Ice.

    Cooler Temperature Is acceptable.

    Cooler Temperature Is recorded.

    COC is present.

    COC is filled out in ink and legible.

    COC is filled out with all pertinent information.

    Is the Field Sampler's name present on COC?

    There are no dlscrepancles between the sample IDs on the containers and theCOC

    Samples are received within Holding Time.

    S ample containers have legible tabels.

    Containers are not broken or leaking.

    Sample collection date/times are provided.

    Appropriate sample containers are used.

    Sample bottles are completely filled.

    Sample Preservation Verified.

    There is sufficient vol. for all requested analyses. Incl. any requested MS/MSDs

    VOA sample vials do not have headspace or bubble is

  • Report ojFindings :!Of] Deep Jlonitoring Well Sampling and Ana~vsis South Cavalcade Supe!:fimd Site. Houston. Texas

    ATTACHMENT B Groundwater Sampling Report Form

    Report of Findings 2012 Deep Monitoring Well Sampling and Anal South Cavalcade Superfund Site Houston, Texas

    007005

  • FTS

    [wELL NO.: DW-02

    GROUNDWATER SAMPLE COLLECTION RECORD

    Time: Start: /0 t.ro Fiolsb: 11 10

    1. WATER LEVEL DATA (meas urcd from top of well casing) CoMet:\ion Fat.tors (Gf) (e xcf·· f)

    a. Total Casing Length: .j?? 1110 .!.-- J'D- 1>? QCSamplcs(uaml!, timc,date): OW 0 .J. - /15/J1$.0 Q.rfot;z 1/JO .$~-JI)~t~

    /)tJ(J:K - os-10 ',;z, l}I"'· .. A< !liD Analytical Parameters Polynuclear Aromatic Hydrocarbons (8310) and :viet hods:

    Comments: l,ist of PAll's- Benzo(a)anthrocene, Benzo(a)pyrenc, Benzo(b)flouranthene, Benzo(k)flourantbene,

    Cl1rysene, Dibenz.o(a,h)anthruc::ene,lndeno( 1 ,2,3-cd)pyrene

    u:1\uscrs\a"'dy !WUies\Copy ofGW sample coUcction 1-09 fonn ill5 07116/99

    007006

    ATTACHMENT A - Analytical Data PackageATTACHMENT B - Groundwater Sampling Report Form

    barcodetext: 684748barcode: *684748*