renewable chemistry: the challenges of biomass …€¦ · is there a winner here? sugar succinic...
TRANSCRIPT
RENEWABLE CHEMISTRY: THE
CHALLENGES OF BIOMASS-BASED
CHEMISTRY
Bioeconomy: Research and
Innovation Shaping the New
Biobased Economy
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AGENDA
THE CHALENGES...
THE PRODUCT PARADIGM...
THE FUTURE...
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THE CHALLENGES…
COST...
AVAILABILITY / LOGISTICS...SCALE...
PRODUCT ?
TECHNOLOGY / PRODUCT...
RAW MATERIAL
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PRODUCT APROACH…
Initial importance of sustainability (renewable rawmaterial) and high yields… today, other aspectshave to be considered…
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THE PRODUCT HAS TO BE SUSTAINABLE…
SOCIAL
SUSTAINABILITY
ENVIRONMENT
ECONOMIC“CONSUMERS DO NOT PAY MORE FOR SUSTAINABLE PRODUCTS...”
HIGH YIELDS* / PRODUCTIVITY / NUMBER OF PRODUCTION
STEPS / ENERGY CONSUMPTION-CO2 EMISSION / WATER’s
CONSUMPTION
* LAND’s USE / FOOD COMPETITION
BRAZIL AND THE SUGAR CANE BIOREFINERY... BUT WE
HAVE OTHER BIOMASS / RESIDUES... AND THE CANE
ENERGY?
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THE PRODUCT PARADIGM… DROP IN OR NO DROP IN…
HIGH YIELDS / PRODUCTIVITY
NO DROP IN
SPECIALTIES
FUNCIONALITY
FINE CHEMICALS
APPLICATION DEVELOPMENT / MARKET EFFORTS
O2
COMMODITIES ? (it is important, if we really want a transition... It´s
means volume...)
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COULD GREEN PE BECOME A COMMODITY?
BRASKEM´s green PE is a success !!!But will never be a commodity !!!
SUGAR CANE SUGAR ETHANOL ETHYLENE PE
LOW YIELDSSCALE PROBLEMS (It needs more than a mill of sugar
cane in order to have a commercial scale PE plant)
1 t 0,15 0,07 0,04 0,04
THEORETICAL YIELD
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IS THERE A WINNER HERE?
SUGAR SUCCINIC ACID
PROVIDER
PROCESS FLOW DIAGRAM
PAGE
IMPORTANT NOTICE
Succinic Acid Production Process Evaluation
It is important to understand that the institute had access to publicly available data, such as patents, articles and literature;
as well as consulting specialists in the area. In spite of that, some aspects of the process analyzed might be industrial
secrets, not published in patents or outdated in literature. The design presented in this document is based on the institute
synthesis of the researched process that being the case some differences may arise between this study and the industrial process actually employed. However, the process designed
suitably represents the technology examined accurately enough to develop a conceptual economic evaluation.
E-101
E-105
R-103A/F
V-102A/B
S-202S-101
S-103A/B
K-101
K-102
E-102
E-103 E-104V-101A/B
To A200
From S-205 & S206A/B
Biomass
to waste
Biomass
to waste
CO2
Air
P-102
Nutrients from
OSBL
Water
P-101
Glucose
from OSBL
P-103
Vent
R-102A/B
R-101A/B
P-104
Yeast
Nutrients
VentVent
Air
Air
P-105
Area 100Succinic Acid Production
BioAmber
1
1
3
8
9 16 19
21
PROVIDER
PROCESS FLOW DIAGRAM
PAGE
IMPORTANT NOTICE
Succinic Acid Production Process Evaluation
It is important to understand that the institute had access to publicly available data, such as patents, articles and literature;
as well as consulting specialists in the area. In spite of that, some aspects of the process analyzed might be industrial
secrets, not published in patents or outdated in literature. The design presented in this document is based on the institute
synthesis of the researched process that being the case some differences may arise between this study and the industrial process actually employed. However, the process designed
suitably represents the technology examined accurately enough to develop a conceptual economic evaluation.
K-201
P-206
E-204
V-204
To Vacuum Line
To Wastewater
Treatment
P-201
P-207
From V-102A/B
V-205
S-201
M-201
V-206A/B
S-202
To Wastewater
Treatment
M-202
M-203
MP M-204
T-202A/B
M-205
Succinic Acid
S-204 S-205A/B E-206 V-208
To Atmosphere
To Wastewater
Treatment
To V-102A/B
E-201/E-202/E-203
P-202
T-201
S-203
Area 200Succinic Acid Purification
BioAmber
P-204
To Wastewater
Treatment
P-205
V-207
P-203
Water
E-205
2
34
38
40
43
47
51
1,0 1,12
THEORETICAL YIELD
Company Capacity (t/year) Location Start up
BioAmber 3.000 Pomacle, França 2013
BioAmber-Mitsui 30.000 Sarnia, Canadá 2015
Myriant-UHDE 1.400 Leuna, Alemanha 2012
Myriant 13.600 Lake Providence, EUA 2010
Reverdia 500 Lestrem, França 2010
Reverdia 10.000 Cassano Spinola, Itália 2012
Succinity 10.000 Barcelona, Espanha 2014
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THE INFLUENCE OF STRATEGY
SUGAR GLUCARIC ACID ADIPIC ACID HEXANEDIOL
THEORETICAL YIELD
1 1,17 0,96 0,75
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THE INFLUENCE OF STRATEGY
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OTHER EXAMPLES…
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THE FUTURE… BIO AND NANO THECNOLOGIES…
NEW ENGENEERING NEW MOLECULES / NEW POLYMERS APPLICATION DEVELOPMENT METHANE / CO2?
PHOTOCATALYSIS?
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THE FUTURE… PROCESS INTENSIFICATION…
CAPEX REDUCTION INCREASES EFFICIENCY SCALE FACTOR
IMPORTANCE REDUCTION INCREASES SAFETY
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THE FUTURE… COMPUTER CHEMISTRY…
SINGULARITY 2030 – 2040SUPER INTELLIGENT COMPUTERS
THEY EVOLVE;THEY DO NOT DEPEND ON HUMAN INTERFERENCE;THEY USE RENEWABLE ENERGY SOURCES.
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TECHNICAL GAPS IN BRAZIL…
BRAZIL’s BIOTECHNOLOGY RANK...
REDUCED EFFORTS IN PROCESS INTENSIFICATION AND COMPUTER CHEMISTRY...
A Tabela e a Figura mostram os países que mais publicam de acordo com o Thonsom Reuters Web of Science. Synthetic Biology: Mapping the Scientifc Landscape. PLOS (2012) 7:1-16.
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FINAL REMARKS…
OIL PRICES / CO2 TAXES...
ALCOHOLS AND DIALCOHOLS IN THELIMIT ...
FUEL AND CHEMICALS HAVE TO BECOMPLEMENTARY
IMPORTANCE OF STRATEGIC CHOICES:TECHNOLOGY PLATFORM AND MARKETAPPROACH
BIO/NANOTECHNOLOGY AND PROCESSINTENSIFICATION ARE KEY... COMPUTERCHEMISTRY HAS TO BE CONSIDERED...
BRAZIL HAS A BIG OPPORTUNITY BUT...
