reference material 2008 - 2009 seishin.pdf · · 2009-03-103 3.20 cao 66.25 mgo 1.08 so 3 0.25 na...

Reference Material

2008 - 2009

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Japan Cement Association ● 102L : Certificate of Fineness Analysis

(Ordinary Portland Cement)

● 211R : Certificate of Chemical Analysis Standard Reference Material

(Portland Cement) Constituent Percent by Weight (%)

Ignition loss (ig. loss) 1.86 Insoluble residue (insol.) 0.08

SiO 2 20.77 Al 2 O 3 5.67 Fe 2 O 3 2.65

CaO 64.37 MgO 1.16 SO 3 2.13

Na 2 O 0.22 K 2 O 0.44 TiO 2 0.31 P 2 O 5 0.10 MnO 0.07

Cl 0.009 ● 301Q : Certificate of Reference Material for Heat of Hydration (Moderate Heat Portland Cement)

Heat of solution of dry cement 2481 (J/g) 7 days 267 (J/g)

Heat of hydration 28 days 327 (J/g)

Analytical value (cm 2 /g) Certificate Value 3220

Standard Deviation 9

● 401G : Reference Material for Strength Test

(Ordinary Portland Cement) Compressive Strength (N/mm 2 )

3 days 7 days 28 days Certificate Value 28.1 45.8 64.8

Standard Deviation 0.33 0.85 0.81 ● 701A : Certificate of for Sieving Method (Ordinary Portland Cement)

45 m 32 m 20 m 16 m 10 m

Certificate Value 8.6 18.9 38.5 48.6 68.0 Standard Deviation 0.27 0.27 0.37 0.51 0.32

● JCA-RM-611 : Reference Material for X-ray Fluorescence Analysis

Constituents Reference values (mass%) SiO 2 21.84

Al 2 O 3 5.41 Fe 2 O 3 3.20

CaO 66.25 MgO 1.08 SO 3 0.25

Na 2 O 0.40 K 2 O 0.34 TiO 2 0.30 P 2 O 5 0.59 MnO 0.06 SrO 0.28



Al 2 O 3 5.19 Fe 2 O 3 2.81

CaO 62.95 MgO 1.52 SO 3 4.51




Al 2 O 3 5.36 Fe 2 O 3 2.78

CaO 63.00 MgO 1.07 SO 3 6.07


● JCA-CRM-1 : Certified Reference Material

(Ordinary Portland Cement) Constituents Certified Values (mass%)

SiO 2 20.99 ± 0.05 Al 2 O 3 5.26 ± 0.04 Fe 2 O 3 2.67 ± 0.02

CaO 65.21 ± 0.10 MgO 2.13 ± 0.03 SO 3 2.05 ± 0.09

Na 2 O 0.26 ± 0.02 K 2 O 0.56 ± 0.02 TiO 2 0.35 ± 0.01 P 2 O 5 0.28 ± 0.01 MnO 0.06 ± 0.01 SrO 0.05 ± 0.01

● JCA-CRM-2 : Certified Reference Material (Portland Blast furnace Slag Cement)

Constituents Certified Values (mass%) SiO 2 25.66 ± 0.07

Al 2 O 3 8.94 ± 0.04 Fe 2 O 3 2.08 ± 0.03

CaO 56.33 ± 0.10 MgO 3.05 ± 0.03

Na 2 O 0.24 ± 0.01 K 2 O 0.31 ± 0.02 TiO 2 0.50 ± 0.01 P 2 O 5 0.07 ± 0.01 MnO 0.15 ± 0.01 SrO 0.07 ± 0.01

● Standard sand for the strength test of cement

(JIS R 5201 – 1997) Particle size distribution of JIS Standard sand

Square mesh size (㎜) Cumulative sieve residue (%) 2 0

1.6 7 ± 5 1 33 ± 5

0.5 67 ± 5 0.16 87 ± 5 0.08 99 ± 1

Moisture content of JIS standard sand Less than 0.2% Reference : Chemical analysis (CAJS I-12-1981)

Chemical composition (%) Ig.loss SiO2 Al2O3 Fe2O3 CaO MgO Na2O K2O

0.0 98.4 0.41 0.36 0.16 0.00 0.01 0.01

● 601A : Cement Reference Materials for X-ray Fluorescence Analysis

NOTE : The reference values express mass % on the basis of ignited (975℃) sample whose masses reach constant by making successive 15 minutes ignitions at 975℃ followed each time by cooling and then weighing. The constant mass is reached when the difference between two successive weighings is less than 0.0005 g.

Constituent

Sample No.

SiO 2 Al 2 O 3 Fe 2 O 3 CaO MgO SO 3 Na 2 O K 2 O TiO 2 P 2 O 5 MnO SrO

XRF-1 22.23 5.35 3.05 64.14 1.75 2.33 0.29 0.40 0.33 0.06 0.15 0.037 XRF-2 21.31 5.29 2.93 65.17 1.77 1.91 0.38 0.50 0.31 0.11 0.21 0.045 XRF-3 20.67 4.57 2.43 66.32 1.53 3.18 0.30 0.45 0.28 0.13 0.08 0.049 XRF-4 20.71 4.73 2.80 66.17 1.37 2.64 0.24 0.54 0.26 0.40 0.05 0.036 XRF-5 20.52 5.07 2.99 65.99 0.94 3.02 0.32 0.46 0.25 0.10 0.28 0.027 XRF-6 20.71 5.02 2.70 66.23 1.81 2.61 0.26 0.23 0.24 0.05 0.19 0.035 XRF-7 22.76 4.26 4.11 64.27 1.03 2.42 0.17 0.35 0.25 0.06 0.06 0.030 XRF-8 23.23 3.82 4.02 64.15 1.52 1.93 0.10 0.54 0.27 0.19 0.21 0.038 XRF-9 23.82 3.40 4.18 64.75 0.78 1.94 0.24 0.39 0.16 0.06 0.11 0.024

XRF-10 22.99 6.29 2.39 61.67 2.71 - 0.17 0.62 0.52 0.13 0.14 0.043 XRF-11 24.43 7.37 2.26 59.15 2.63 - 0.26 0.51 0.55 0.23 0.16 0.046 XRF-12 26.34 8.95 1.82 54.90 3.33 - 0.23 0.44 0.73 0.17 0.18 0.051 XRF-13 26.62 9.22 2.02 55.36 2.98 - 0.30 0.41 0.41 0.06 0.61 0.037 XRF-14 25.74 8.70 2.03 55.15 3.98 - 0.26 0.31 0.66 0.04 0.28 0.051 XRF-15 29.29 10.70 1.32 49.28 5.12 - 0.25 0.42 0.64 0.06 0.48 0.071

REFERENCE MATERIALS OF THE CERAMIC SOCIETY OF JAPAN For calibration in chemical investigations of ceramics and glass the Ceramic Society Japan offers following reference materials.

The chemical compositions of those materials were determined by round robin tests.

Chemical Composition of the reference Materials of the Ceramic Society of Japan

Reference Material Chemical Composition (mass %)

Oxide Powder Material

SiO2 Al2O3 Fe2O3 TiO2 ZrO2

(HfO2)

CaO MgO Na2O K2O P2O5 MnO T.S Cr2O3 Ig. loss

Size

JCRM R301 Burned Bauxite 7.24 87.5 1.40 2.90 0.13 0.03 0.02 0.03 0.04 0.07 0.35 100g

JCRM R302 Burned Bauxite 3.45 90.6 1.76 3.17 0.30 0.02 0.03 0.02 0.02 0.05 0.22 100g

JCRM R303

JCRM R304

JCRM R041

Burned Bauxite

Sillimanite

Mullite

5.55

35.90

28.11

89.49

55.94

70.18

1.51

0.585

0.598

2.93

1.33

0.185

0.110

0.105

0.058

0.012

0.427

0.059

0.006

0.451

0.190

0.273

0.197

0.329

0.174

0.064

0.136

4.26

100g

100g

100g

JCRM R404

JCRM R405

JCRM R406

Quartz powder

Silica powder

Silica powder

＞99.99

97.78

96.71

111.07

1.31

0.60.053

0.102

60.022

0.564

0.20.029

0.016

(＜0.1)0.023

0.005

(1)0.060

0.030

(0.4)0.71

0.13

(0.00)

0.23

(<0.2)28

0.00

0.13

0.97

Italic type: mass ppm

100g

100g

100g

JCRM R501 Zircon Sand 32.6 0.39 0.06 0.16 66.5 0.11 100g

JCRM R502 Zircon Sand 32.8 5.87 0.10 0.24 60.3 0.26 100g

JCRM R651 Aluminous Shale 21.74 71.7 1.48 3.15 0.18 0.19 0.10 0.03 0.65 0.19 0.58 100g

JCRM R701 Feldspar 68.0 17.31 0.092 0.009 3.35 10.4 0.49 50g

JCRM R802 Pyrophllite 60.7 32.3 0.23 0.19 0.04 ＜0.01 0.09 0.07 0.05 6.0 50g

JCRM R901

JCRM R902

JCRM R903

Talc

Talc

Talc

59.77

60.77

55.76

0.924

0.115

2.447

1.224

0.091

0.564

0.019

0.004

0.075

0.438

0.342

0.998

31.22

31.97

31.84

0.054

0.006

0.029

0.004

0.003

0.007

0.195

0.046

0.051

0.004

( 0.002 )

( 0.003 )

6.14

6.64

8.23

50g

50g

50g

SO3

JCRM R031

JCRM R032

JCRM R033

Alumina Fine Powder

Alumina Fine Powder

Alumina Fine Powder

0.0009

0.015

0.095

0.000

0.015

0.0000

0.013

0.004

0.0001

0.034

0.020

0.0000

0.001

0.001

0.0019

0.343

0.064

0.0003

0.003

0.003

0.017 0.25

0.25

0.08

50g

50g

50g

Nonoxide Material T.Si T.N Al Fe Ca Mg W Ti Mn Co O C V Cr Ni Zr

JCRM R003

JCRM R004

JCRM R005

Silicon Nitride Powder



59.55

59.41

59.24

39.00

38.58

38.44

0.035

0.184

0.0042

0.028

0.130

0.0036

0.222

0.0026

0.0040

1.27

1.67

1.65

0.096

0.214

0.170

20g

20g

20g

T.C F.C F.Si F.SiO2

JCRM R021

JCRM R022

JCRM R023

Silicon Carbide Powder



68.8

68.1

69.3

29.9

30.4

29.6

0.039

0.058

0.003

0.018

0.051

0.015

0.007

0.025

0.003

0.0021

0.005

0.001

0.86

1.62

0.39

0.010

0.003

＜0.001

＜0.001

0.001

＜0.001

0.15

0.01

0.01

1.08

0.98

0.86

0.57

0.31

0.20

0.002

＜0.001

＜0.001

0.004

0.006

0.001

0.0010

0.001

0.001

0.001

0.001

＜0.001

50g

50g

50g

Glass SiO2 Al2O3 Fe2O3 TiO2 ZrO2 Na2O K2O B2O3 Cl

JCRM R102 Borosilicate Glass 80.5 2.27 0.033 0.011 0.032 4.00 0.029 12.7 0.057 50g

( ): Reference value

Reference Material Chemical Composition (mass %)

Oxide Powder Material

SiO2 Al2O3 Fe2O3 TiO2 MnO P2O5 CaO MgO Na2O K2O Nb2O5 HfO2 S Ig. loss

Size

JCRM R051

JCRM R052

JCRM R053

JCRM R054

Zirconia powder

Zirconia powder

Zirconia powder

Zirconia powder

(0.005)

0.019

0.036

0.300 0.136

0.0017

(0.0004)

0.030

0.132

(0.0005)

0.0012

0.127

0.136

0.0017

0.019

0.021

0.535

0.0004

0.0042

0.0020

0.208

0.015

0.021

0.028

0.0027

0.0013

(0.0007)

(0.0003)

0.054

0.427

1.96

1.81

1.67

1.60

0.71

0.25

0.65

0.15

50g

50g

50g

50g

JCRM R604

JCRM R605

JCRM R751

Gairome Clay

Caolin

Pottery Stone

47.88

49.77

79.32

35.37

35.64

14.15

1.357

0.283

0.340

0.865

0.068

0.010

0.006

0.003

0.020

0.105

0.009

0.216

0.004

0.033

0.251

0.004

0.049

0.083

0.032

0.121

0.468

(0.008)

(3.00)

(0.014)

(0.023)

(0.0010)

13.37

13.90

2.73

50g

50g

50g

JCRM R702

JCRM R703

JCRM R803

Albite

Potassiumfeldspar

Pyrophyllite

67.69

66.99

68.52

19.64

17.93

23.95

0.058

0.082

0.047

0.030

0.005

0.104

0.004

0.003

0.0014

0.139

0.008

0.018

0.546

0.095

0.033

0.103

0.040

0.017

11.31

3.32

0.165

0.137

11.02

2.32

0.02

0.23

0.36

4.40

50g

50g

50g

( ): Reference value

Certified Reference Material Series for X-ray Fluorescence Analysis of Refractories

JRRM 101-110 (Series No.1 for Fireclay Refractories)

Unit: mass% Constituent SiO2 Al2O3 Fe2O3 TiO2 MnO CaO MgO Na2O K2O JRRM 101 88.57 8.16 0.314 0.302 0.116 1.061 0.217 1.013 0.165

JRRM 102 80.47 13.79 3.978 0.454 0.015 0.049 0.673 0.303 0.145

JRRM 103 80.32 18.07 0.407 0.370 0.005 0.072 0.016 0.124 0.350

JRRM 104 67.35 22.52 3.244 2.943 0.017 0.259 0.070 0.300 3.048

JRRM 105a 69.17 25.35 0.768 2.249 0.119 0.407 0.222 0.651 0.817 JRRM 106 63.61 29.91 1.922 0.679 0.024 0.146 0.980 0.599 1.816

JRRM 107 55.32 37.08 2.202 1.155 0.019 0.710 0.492 0.218 2.573

JRRM 108 55.31 40.08 1.547 1.053 0.020 0.277 0.270 0.207 0.809

JRRM 109 54.23 41.24 0.892 1.961 0.011 0.146 0.126 0.307 0.793

JRRM 110 49.54 46.68 0.848 1.666 0.014 0.107 0.166 0.085 0.342

Note: The above values show the contents after igniting for one hour at 800±25℃.


JRRM 121-135 (Series No.2 for Fireclay Refractories)

Unit: mass% Constituent SiO2 Al2O3 Fe2O3 TiO2 MnO CaO MgO Na2O K2O P2O5 Cr2O3 ZrO2 LOI* JRRM 121 86.30 6.073 0.407 0.056 0.023 1.967 0.126 3.207 0.234 0.324 0.018 1.119 0.057

JRRM 122 78.24 10.26 0.248 1.037 0.204 0.435 0.657 1.041 2.057 4.898 0.818 0.203 0.127

JRRM 123 79.16 13.31 4.134 0.459 0.012 0.135 1.328 0.296 0.109 0.807 0.014 0.008 0.037

JRRM 124 73.92 16.56 2.603 2.746 0.246 1.099 0.109 0.313 1.791 0.191 0.117 0.112 0.103

JRRM 125 79.27 18.71 0.504 0.309 0.008 0.130 0.084 0.072 0.691 0.046 0.010 0.023 0.077

JRRM 126 66.96 21.39 3.349 2.848 0.038 0.456 0.127 0.284 3.135 0.497 0.650 0.049 0.175

JRRM 127 68.59 23.08 0.926 2.194 0.174 0.182 0.153 1.756 0.542 1.785 0.273 0.046 0.072

JRRM 128 54.38 26.05 4.458 1.379 0.244 2.803 3.106 0.374 1.849 3.362 0.854 1.014 0.024

JRRM 129 62.26 30.10 1.460 0.966 0.018 0.157 2.232 0.234 1.927 0.201 0.107 0.112 0.117

JRRM 130 53.47 32.74 0.531 3.358 0.370 1.954 0.619 2.320 1.420 0.919 1.054 0.835 0.116

JRRM 131 52.71 36.63 2.208 1.162 0.032 0.785 1.023 0.768 2.619 1.611 0.070 0.264 0.174

JRRM 132 50.61 39.11 1.645 0.298 0.119 1.298 0.349 2.162 0.797 2.386 0.116 0.752 0.154

JRRM 133 50.10 39.02 3.693 1.932 0.017 0.109 2.034 0.335 0.914 0.344 1.277 0.573 0.089

JRRM 134 47.28 44.36 1.079 1.740 0.245 0.200 0.205 0.132 0.375 3.834 0.244 0.358 0.146

JRMM 135 37.26 48.92 3.057 0.076 0.049 2.360 1.245 2.879 2.776 0.487 0.427 0.203 0.183

Note: The above values show contents after drying for two hours at 110±5℃. (*) Indicated value


JRRM 201-210 (Series No.1 for Silica Refractories) Unit: mass%

Constituent SiO2 Al2O3 Fe2O3 TiO2 MnO CaO MgO Na2O K2O JRRM 201 84.36 9.715 1.465 0.032 0.147 2.779 0.732 0.316 0.144

JRRM 202 85.72 7.595 3.972 0.567 0.004 0.817 0.020 1.014 0.025

JRRM 203 87.33 5.094 1.785 0.182 0.112 3.976 0.471 0.616 0.242

JRRM 204 89.64 4.497 2.081 0.150 0.107 1.792 0.313 0.315 0.907

JRRM 205 90.40 3.089 1.248 0.325 0.064 3.110 0.092 0.932 0.500

JRRM 206 92.88 1.772 3.205 0.018 0.018 1.205 0.072 0.180 0.507

JRRM 207 94.05 1.703 0.965 0.079 0.042 2.518 0.160 0.047 0.212

JRRM 208 94.43 0.463 0.064 0.005 0.001 4.197 0.056 0.634 0.022

JRRM 209 96.22 0.876 0.373 0.050 0.068 1.893 0.106 0.033 0.170

JRRM 210 97.69 0.163 0.833 0.005 0.002 0.301 0.788 0.021 0.007

Note: The above values show contents after igniting for one hour at 800±25℃.


JRRM 301-310 (Series No.1 for High Alumina Refractories)

Unit: mass% Constituent SiO2 Al2O3 Fe2O3 TiO2 MnO CaO MgO Na2O K2O B2O3* JRRM 301 43.91 46.80 3.529 1.031 0.018 0.797 0.690 0.170 2.007 0.87 JRRM 302 37.70 53.93 4.490 0.597 0.200 0.871 0.697 0.565 0.667 ― JRRM 303 36.16 59.25 1.476 0.164 0.008 1.039 0.855 0.699 0.207 ― JRRM 304 27.55 63.06 3.469 4.340 0.059 0.183 0.376 0.276 0.388 ― JRRM 305 20.03 68.69 2.816 3.300 0.010 0.655 0.304 0.808 3.116 ― JRRM 306 17.35 74.19 1.956 2.685 0.019 0.626 0.100 0.994 1.758 ― JRRM 307 10.87 80.14 2.972 1.229 0.016 0.152 0.612 1.084 2.361 ― JRRM 308 10.25 86.59 0.412 1.795 0.112 0.099 0.053 0.263 0.108 ― JRRM 309 2.124 89.83 1.277 3.856 0.003 1.023 0.288 0.422 0.922 ― JRRM 310 0.412 94.71 0.024 2.064 0.045 0.038 0.979 0.081 1.326 ―

Note: The above values show contents after igniting for one hour at 800±25℃. (*) Indicated value


JRRM 401-410 (Series No.1 for Magnesia Refractories)

Unit: mass% Indicated value Constituent

SiO2 Al2O3 Fe2O3 CaO MgO TiO2 MnO Na2O K2O Cr2O3 P2O5 B2O3

JRRM 401 6.424 8.106 3.890 0.208 81.24 0.017 0.011 0.006 0.003 0.004 0.035 0.016

JRRM 402 5.462 1.999 5.050 3.570 83.77 0.026 0.011 0.010 0.001 0.006 0.077 0.127

JRRM 403 8.144 4.060 1.553 0.615 85.48 0.003 0.014 0.004 0.001 0.010 0.044 0.031

JRRM 404 1.223 6.014 2.908 1.786 88.02 0.007 0.030 0.009 0.001 0.006 0.053 0.011

JRRM 405 3.479 1.372 1.346 1.690 91.95 0.054 0.074 0.009 0.015 0.014 0.120 0.011

JRRM 406 1.196 1.139 0.874 4.805 91.85 0.004 0.011 0.002 0.000 0.006 0.041 0.013

JRRM 407 2.432 0.100 2.145 0.675 94.55 0.003 0.014 0.004 0.001 0.080 0.044 0.023

JRRM 408 0.460 2.554 0.134 0.672 96.19 0.004 0.010 0.001 0.000 0.009 0.015 0.099

JRRM 409 0.534 0.202 0.490 0.744 98.03 0.003 0.015 0.002 0.001 0.019 0.023 0.033

JRRM 410 0.188 0.058 0.050 0.595 99.08 0.003 0.010 0.001 0.000 0.003 0.045 0.026

Note: The above values show the contents after burning for sixty minutes at 1050±25℃.


JRRM 501-510 (Series No.1 for Chrome-Magnesia Refractories)

Unit: mass% Indicated value Constituent SiO2 Al2O3 Fe2O3 TiO2 MnO CaO MgO Cr2O3

LOI P2O5 V2O5 NiO ZnO JRRM 501 0.926 2.922 4.806 0.006 0.020 0.923 87.60 2.828 0.137 0.036 0.019 0.018 0.006

JRRM 502 3.118 11.98 1.021 0.013 0.018 0.201 76.28 7.498 0.065 0.026 0.024 0.026 0.004

JRRM 503 9.096 7.147 3.006 0.047 0.038 3.815 63.11 13.60 0.111 0.032 0.037 0.036 0.013

JRRM 504 2.189 17.56 4.112 0.013 0.011 2.608 54.85 18.35 0.124 0.034 0.016 0.015 0.011

JRRM 505 1.823 7.768 17.76 0.118 0.109 0.492 50.14 21.74 0.085 0.023 0.075 0.078 0.021

JRRM 506 2.165 14.69 7.490 0.134 0.072 0.460 46.65 28.19 0.070 0.018 0.086 0.094 0.010

JRRM 507 5.698 25.02 12.98 0.166 0.115 1.615 22.36 32.03 -0.111 0.010 0.130 0.202 0.037

JRRM 508 3.081 3.891 22.70 0.014 0.006 1.031 30.86 38.18 0.053 0.016 0.008 0.010 0.005

JRRM 509 1.964 20.28 10.15 1.203 0.082 2.867 20.45 42.57 0.137 0.013 0.118 0.044 0.037

JRRM 510 4.914 12.21 14.99 0.133 0.176 0.291 16.86 50.38 -0.255 0.016 0.111 0.193 0.041

JRRM 511 2.909 6.684 27.22 0.105 0.127 0.071 10.62 52.51 -0.483 0.004 0.054 0.108 0.052

JRMM 512 10.57 29.25 26.01 0.047 0.025 4.061 24.81 4.989 0.028 0.019 0.012 0.018 0.013

Note: The above values show contents after drying for two hours at 110±5℃.


JRRM 601-610 (Series No.1 for Zircon-Zirconia Refractories)

Unit: mass% Constituent SiO2 Al2O3 Fe2O3 TiO2 CaO MgO Na2O K2O P2O5 Cr2O3 ZrO2 HfO2 LOI* JRRM 601 0.263 0.119 0.101 0.168 5.581 0.064 0.004 0.002 0.007 0.003 92.01 1.591 0.079

JRRM 602 0.334 0.078 1.618 0.164 0.220 5.290 0.766 0.004 1.338 0.015 88.25 1.522 0.252

JRRM 603 0.966 5.293 2.858 0.932 0.953 0.967 0.187 0.652 0.837 0.029 84.70 1.453 0.115

JRRM 604 3.045 6.917 0.429 0.134 0.094 0.017 1.087 1.937 1.992 3.062 79.26 1.356 0.235

JRRM 605 10.78 4.832 0.176 0.127 1.939 1.993 0.457 0.541 0.352 1.548 75.36 1.314 0.314

JRRM 606 22.03 0.532 0.933 0.117 0.021 0.320 2.028 0.014 0.019 0.008 72.35 1.265 0.328

JRRM 607 32.75 3.519 0.120 0.136 0.048 0.031 0.026 0.043 0.085 0.002 61.31 1.211 0.569

JRRM 608 34.62 0.707 0.092 0.102 0.521 3.125 0.031 0.019 0.117 0.497 58.84 1.217 0.069

JRRM 609 40.50 0.885 0.150 0.153 0.300 0.150 0.942 0.028 0.081 0.012 55.56 1.122 0.122

JRRM 610 45.66 0.451 0.308 0.099 3.075 0.547 0.043 0.010 0.113 0.009 48.70 0.986 0.074

Note: The above values show contents after drying for two hours at 110±5℃. (*) Indicated value


JRRM 701-710 (Series No.1 for Alumina-Zirconia-Silica Refractories)

Unit: mass% Indicated value

Constituent SiO2 Al2O3 Fe2O3 TiO2 CaO MgO Na2O K2O Cr2O3 ZrO2 HfO2 LOI MnO P2O5

JRRM 701 28.44 10.09 2.007 4.961 2.073 0.476 1.846 0.024 1.010 48.06 0.850 0.098 0.007 0.027

JRRM 702 9.99 38.14 0.374 0.210 1.552 1.979 2.024 0.579 0.111 42.54 2.086 0.180 0.004 0.028

JRRM 703 14.64 46.34 0.059 0.072 0.037 0.011 0.535 0.002 0.006 37.35 0.727 0.096 0.000 0.035

JRRM 704 42.61 19.58 0.553 1.025 0.155 0.515 0.228 0.402 0.518 33.46 0.682 0.079 0.089 0.130

JRRM 705 1.999 64.14 0.141 2.021 0.191 0.460 0.300 0.018 2.019 27.96 0.484 0.166 0.004 0.017

JRRM 706 39.33 25.95 0.130 3.778 1.587 0.158 3.496 0.952 0.010 22.72 1.190 0.729 0.004 0.016

JRRM 707 21.17 55.78 1.814 0.289 1.086 0.844 0.199 0.155 0.180 18.16 0.376 0.011 0.003 0.055

JRRM 708 0.546 79.52 0.800 1.020 1.172 1.646 0.089 0.746 0.297 12.84 1.033 0.136 0.001 0.002

JRRM 709 34.38 50.35 0.476 0.091 0.524 1.208 1.038 0.216 2.916 8.322 0.184 0.202 0.002 0.009

JRRM 710 5.624 82.29 1.150 3.002 0.225 0.049 1.419 0.636 1.027 2.965 1.511 0.094 0.002 0.042

Note: The above values show contents after drying for two hours at 110±5℃


JRRM 801-810 (Series No.1 for Alumina-Magnesia Refractories)

Unit: mass% Indicated value

Constituent SiO2 Al2O3 Fe2O3 TiO2 CaO MgO Na2O K2O P2O5 LOI MnO Cr2O3 ZrO2

JRRM 801 0.355 93.49 2.009 0.217 0.141 3.261 0.199 0.014 0.002 0.149 0.002 0.003 0.008

JRRM 802 3.329 84.25 1.035 1.484 2.003 6.312 0.159 0.462 0.957 0.063 0.003 0.002 0.002

JRRM 803 0.583 74.23 4.904 2.516 0.576 16.20 0.869 0.007 0.017 0.364 0.005 0.002 0.004

JRRM 804 5.178 64.66 4.020 0.132 4.767 20.84 0.089 0.044 0.111 0.012 0.020 0.010 0.002

JRRM 805 2.498 58.03 0.732 1.059 0.282 36.04 0.540 0.015 0.682 0.174 0.006 0.001 0.000

JRRM 806 0.514 48.85 0.165 0.004 0.979 49.43 0.049 0.001 0.048 0.212 0.026 0.006 0.001

JRRM 807 0.586 39.96 0.323 0.198 2.759 55.07 0.329 0.153 0.530 0.574 0.005 0.002 0.001

JRRM 808 0.799 28.68 0.565 0.714 0.994 67.01 0.409 0.692 0.229 0.844 0.017 0.001 0.001

JRRM 809 0.363 19.86 0.115 2.888 4.479 70.11 0.049 0.989 1.068 0.484 0.006 0.001 0.001

JRRM 810 4.211 10.08 3.118 1.916 0.180 78.96 0.759 0.167 0.513 0.222 0.016 0.004 0.004

Note: The above values show contents after igniting for 30 minutes at 1000±25℃.

Certified Reference Material for Carbon Analysis of refractories

JRRM 1001-1009 (Series No.1 for Calibration of Carbon Analyzer)

Unit: mass% Certified value Approximate value

C Total C Free SiC LOI Al Fe Ti Ca Mg Si Free O N

JRRM 1001 (SiC 100) 29.81 0.04 99.58 ― 0.008 0.044 0.0035 <0.001 <0.001 0.06 0.048 0.030

JRRM 1002 (C 5) 5.03 4.98 0.06 5.11 ― ― ― ― ― ― ― ―

JRRM 1003 (C 10) 10.06 10.01 ― 10.11 ― ― ― ― ― ― ― ―

JRRM 1004 (C 20) 20.04 19.92 ― 20.01 ― ― ― ― ― ― ― ―

JRRM 1005 (C 30) 29.93 29.81 ― 29.95 ― ― ― ― ― ― ― ―

JRRM 1006 (C 50) 49.99 49.97 ― 49.95 ― ― ― ― ― ― ― ―

JRRM 1007 (C 10-SiC 90) 36.75 10.01 89.29 ― ― ― ― ― ― ― ― ―

JRRM 1008 (C 5-SiC 30) 14.12 5.21 29.74 ― ― ― ― ― ― ― ― ―

JRRM 1009 (C 40-SiC 6) 39.43 37.67 6.18 ― ― ― ― ― ― ― ― ―

Note: The above values show contents after drying for two hours at 110±5℃ *) JRRM 1001 are available individually. (Others are available at set only from JRRM 1001 to JRRM 1009)

I. CRMs for Chemical Analysis

I-1. Pure iron series

Mass content in % C Si Mn P S Ni Cr Mo Cu Co Al As Sn B N Na

JSS No.

○ 001-6 High grade pure iron 1 0.00024 0.0001 (0.000003) (0.00005) 0.00015 (0.00002) (<0.00006) (<0.00002) 0.000036 0.000032 (<0.0001) (<0.0003) (0.00003) (<0.00002) 0.00021

003-5 High grade pure iron 3 0.00046 0.0049 0.0027 0.00043 (0.0002) 0.00004 (0.0001) 0.00007 0.00154 0.00022 0.0078 (0.0002) 0.00049 (0.00002) 0.00078

○ 009-3 Pure iron (III) oxide (0.02) (<0.004) (0.00006) (<0.0002) (0.0001) (0.00003) 0.00097 (<0.0001) (<0.0001) (0.0003) (<0.0001) (<0.0002) (<0.0001)

☆Continued

Mass content in % Mg Ca W V Ti Pb Zn Zr Se Te Sb Nb Bi K T.Fe Net weight

JSS No. (g)

○ 001-6 High grade pure iron 1 (<0.00006) (<0.0002) (0.00001) (<0.00003) (<0.00002) 0.000018 0.00019 (<0.00003) 100

003-5 High grade pure iron 3 (<0.00003) (<0.0003) 0.00004 (<0.00003) (<0.0001) (<0.00001) (<0.00005) (<0.00002) (<0.0001) (<0.00005) (<0.00002) (<0.00005) 150

○ 009-3 Pure iron (III) oxide (0.00003) (<0.0001) (<0.0001) (<0.0001) (<0.0001) (<0.0002) (<0.0001) (<0.0002) 69.84 50

C.W.: 0.16 Ig.Loss: (0.4)

I-2. Carbon steel series

Mass content in % C Si Mn P S Cu Al N Net weight

JSS No. (g)

023-8 13 Carbon steel 0.112 0.22 0.48 0.020 0.0067 0.010 (0.015) (0.0037) 150

030-7 20 Carbon steel 0.196 0.24 0.75 0.024 0.0076 0.024 0.023 0.0033 150

050-6 40 Carbon steel 0.38 0.19 0.50 0.013 0.0057 0.008 0.023 0.0029 150

057-7 52 Carbon steel 0.522 0.231 0.726 0.0159 0.0125 0.0096 0.0338 0.0043 150

061-7 63 Carbon steel 0.626 0.206 0.513 0.0240 0.0106 0.0086 (0.002) 0.0036 150

066-4 85 Carbon steel 0.845 0.227 0.788 0.0175 0.0052 0.0117 0.038 0.0047 150

I-3. Pig iron series

Mass content in % C Si Mn P S Ni Cr Mo Cu V Ti As N Net weight

JSS No. (g)

X 102-7 Pig iron for steel making

○ 110-12 Pig iron for casting 4.18 1.70 0.392 0.0902 0.0251 0.0117 0.0162 0.003 0.0100 0.0324 0.0022 0.0044 100

120-1 Castiron: 3 C 2.85 1.32 0.70 0.053 0.0095 0.12 0.28 (0.007) 0.29 0.007 0.006 0.0058 150

( ) Non-certified value

*(This value means the carbon content in the metal with removal of contaminated carbon on the surface of test portion) ※ In preparation

○ New/Renewal CRMs

X Sold out

Japanese Iron and Steel Certified Reference Materials

I-4. Low alloy steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu V Al Net weight

JSS No. (g)

○ 150-16 Low alloy steel No.1 0.475 0.219 0.137 0.0346 0.0296 3.98 0.298 0.201 (<0.003) 0.0195 0.023 150

○ 151-16 Low alloy steel No.2 0.393 0.103 1.697 0.0297 0.0174 2.92 0.101 0.0540 0.0969 0.0503 0.0279 150

○ 152-16 Low alloy steel No.3 0.277 0.387 0.440 0.0174 0.0056 1.98 0.584 1.010 0.500 0.100 0.0212 150

X 153-14 Low alloy steel No.4

154-14 Low alloy steel No.5 0.102 0.589 1.224 0.0023 0.0046 0.505 2.03 0.394 0.201 0.301 150

155-15 Low alloy steel No.6 0.0360 0.490 0.178 0.00163 0.0045 0.173 3.09 0.718 0.385 0.396 150

I-5. Minor elements determination series B

Mass content in % C Si Mn Ni Cr Mo V Co Ti Al As Sn B Zr Sb

JSS No.

168-7 Minor element No.1 0.053 0.20 0.43 0.017 0.020 0.095 0.077 0.041 0.012 0.0065

169-7 Minor element No.2 0.047 0.21 0.42 0.046 0.108 0.068 0.012 0.040 0.0050 0.013

170-7 Minor element No.3 0.052 0.18 0.43 0.081 0.049 0.011 0.105 0.045 0.032 0.056

171-7 Minor element No.4 0.042 0.21 0.40 0.099 0.074 0.036 0.039 0.037 0.046 0.040

172-7 Minor element No.5 0.051 0.20 0.43 0.010 0.052 0.012 0.0010 0.009 0.0022

173-7 Minor element No.6 0.038 0.21 0.40 0.028 0.031 0.019 0.0041 0.005 0.0051

174-7 Minor element No.7 0.042 0.21 0.40 0.065 0.011 0.034 0.0076 0.014 0.0102

X 175-7 Minor element No.8

☆Continued

Mass content in % Nb Ca Net weight

JSS No. (g)

168-7 Minor element No.1 0.0006 150




172-7 Minor element No.5 0.050 150 ( ) Non-certified value

X 173-7 Minor element No.6 ※ In preparation

174-7 Minor element No.7 0.020 150 ○ New/Renewal CRMs

X 175-7 Minor element No.8 X Sold out

I-6. One element determination series

Mass content in % C Si P S Al B N Net weight

JSS No. (g)

116-1 Pig iron for casting 4.09 0.0186 100

201-13 Steel for carbon 0.0440 150

202-1 Steel for carbon 1.386 150

208- 2 Steel for carbon 1.056 150

X 1201-2 Steel for low carbon


○ 1203-3 Steel for low carbon 0.0097 150


○ 1205-1 Steel for low carbon 0.00105 150

230-5 Steel for phosphorus 0.0113 150

X 232-4 Steel for phosphorus

233-1 Steel for phosphorus 0.0069 150

X 240-13 Steel for sulfur

241-11 Steel for sulfur 0.0194 150



○ 244-9 Steel for sulfur 0.0020 150


280-1 Steel for silicon 0.023 150

330-3 Steel for aluminium 0.0057 150



362-1 Steel for boron 0.0018 150



366-8 Steel for nitrogen 0.00075 150 ( ) Non-certified value

367-8 Steel for nitrogen 0.0034 150 ※ In preparation

370-1 Steel for nitrogen 0.417 150 ○ New/Renewal CRMs

371-1 Steel for nitrogen 0.202 150 X Sold out

I-7. High tensile structural steel series A

Mass content in % C Si Mn P S Ni Cr Mo Cu V Ti Al N Net weight

JSS No. (g)

501-6 SCM 430 0.318 0.246 0.738 0.0232 0.0129 0.063 1.039 0.218 0.1034 0.0210 0.0322 0.0058 150

502-6 SCM 440 0.43 0.25 0.70 0.018 0.0097 0.049 1.01 0.17 0.067 (0.004) 0.026 0.0049 100

I-8. High tensile structural steel series B

Mass content in % C Si Mn P S Ni Cr Mo Cu Al N Net weight

JSS No. (g)

507-5 SCM 435 0.36 0.20 0.76 0.015 (0.0079) 0.075 0.99 0.21 0.17 0.022 0.0102 150

I-9. Cace hardening steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu V Al N Pb Net weight

JSS No. (g)

512-7 S9CK 0.073 0.18 0.45 0.0089 0.0097 0.015 0.059 (0.010) 0.008 (0.001) (0.017) 0.0034 150

513-7 SCr 415 0.173 0.29 0.84 0.016 0.021 0.024 1.14 (0.005) 0.011 0.006 0.034 0.0077 150

X 514-7 SCM 420

517-7 SNCM 616 0.200 0.250 0.826 0.0107 0.0084 3.04 1.75 0.516 0.0132 (0.003) (0.006) 0.0061 150

X 519-1 Lead free cutting steel

I-10. Tool steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu W V N Net weight

JSS No. (g)

601-10 SKS 21 1.143 0.237 0.441 0.0194 (0.0042) 0.0580 0.462 0.106 0.120 0.876 0.110 0.0109 150

602-10 SKS-11 1.242 0.218 0.376 0.0091 0.0089 0.047 0.364 0.101 0.0305 3.62 0.217 0.0082 150

604-9 SKD-6 0.362 1.056 0.346 0.0185 0.0122 0.177 4.90 1.079 0.0630 0.0114 0.512 0.0174 150

605-10 SKT 4 0.574 0.111 0.870 0.0150 0.0126 1.500 0.876 0.368 0.162 0.0072 0.0136 150

I-11. High speed steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu W V Co N Net weight

JSS No. (g)

X 607-8 SKH 3

X 609-9 SKH 55

610-9 SKH 57 1.24 0.30 0.32 0.018 0.0029 0.100 4.04 3.06 0.040 9.07 3.26 9.61 0.0354 150

611-10 SKH 51 0.874 0.332 0.305 0.0267 0.00064 0.116 4.09 4.89 0.0479 6.21 1.83 0.535 0.0252 150


※ In preparation


X Sold out

I-12. Stainless steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu Co Al N Nb Net weight

JSS No. (g)

650-14 SUS 430 0.041 0.41 0.48 0.025 (0.0013) 0.21 16.20 0.012 0.047 0.028 0.002 0.0340 150

651-14 SUS 304 0.046 0.67 1.19 0.027 0.0058 9.03 18.26 0.11 0.12 0.17 (0.002) (0.0426) 150

652-14 SUS 316 0.0358 0.624 1.177 0.0315 0.00135 10.60 16.88 2.06 0.177 0.143 0.0030 0.0191 150

653-14 SUS 309S 0.0564 0.621 1.575 0.0307 0.00094 13.74 22.36 0.146 0.201 0.193 0.005 0.039 150

X 654-10 SUS 310S

655-10 SUS 347 0.045 0.63 0.96 0.024 (0.0005) 9.75 17.53 0.033 0.045 (0.073) (0.003) 0.0072 0.49 150

I-13. Heat resisting steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu Ti Al N Net weight

JSS No. (g)

670-3 SUH 409 0.008 0.55 0.53 0.0020 (0.0005) 0.21 11.23 0.020 0.044 0.26 (0.055) 0.0064 150

I-14. Heat resisting super alloy series

Mass content in % C Si Mn P S Ni Cr Cu Co Ti Al Fe Mg Net weight

JSS No. (g)

680-3 NCF 2 0.051 0.44 0.95 (0.0009) 0.0018 32.80 20.92 0.20 0.40 0.42 0.51 (43.2) 150

683-2 NCF 1 0.049 0.39 0.32 (0.0008) 0.0013 73.43 15.82 0.051 (0.011) 0.013 0.12 9.66 0.013 150

I-15. Ferroalloy series

Mass content in % C Si Mn P S Ni Cr Mo Cu V Co Al Sn Ta Nb Net weight

JSS No. (g)

X 701-5 High carbon ferro manganese

X 705-4 Silicon manganese

720-4 Ferrosilicon (0.045) 76.35 0.21 0.032 (0.003) 1.52 150

X 732-2 High carbon ferro chromium

X 745-3 Low carbon ferromolybdenum

750-2 Ferro vanadium 0.14 0.52 0.018 0.010 53.40 3.20 150

755-2 Ferro niobium 0.100 1.82 0.065 0.013 1.79 0.053 (0.37) 68.14 150

760-3 Ferro nickel 1.73 1.29 0.162 0.0222 0.0093 19.56 1.19 0.0219 0.504 150


※ In preparation


X Sold out

I-16. Iron ore series

Mass content in % CW T.Fe FeO SiO2 Mn P S Cu TiO2 Al2O3 CaO MgO BaO As Ni Cr

JSS No. [Fe2+] [Si] [Ti] [Al] [Ca] [Mg]

801-6 Indian hematite 4.07 61.75 (1.0) 1.95 0.707 0.060 0.0093 (0.002) 0.051 1.09 (0.014) (0.032) 0.0033 (0.005)

803-6 Hermersley hematite 1.93 65.50 (0.27) 2.88 0.020 0.048 (0.011) (0.001) 0.059 1.22 (0.018) 0.020 (0.001) 0.010

[1.35] [0.035] [0.64] [(0.013)] [0.012]

804-2 Iscor hematite 0.37 66.93 (0.29) [1.17] 0.016 0.050 0.0132 [0.023] [0.51] [0.0490] [0.0099] 0.0019 0.0028 0.0244

805-1 MBR hematite 0.72 68.04 0.49 0.25 0.044 (0.003) (0.001) 0.029 1.02 0.028 0.033

[0.23] [0.018] [0.54] [0.020] [0.020]

814-1 Pure magnetite 0.53 65.70 3.88 0.025 0.036 0.845 0.036 0.060 0.47 0.78 1.43 0.007

[1.81] [0.036] [0.25] [0.56] [0.86]

820-3 Robe river limonite 7.93 56.81 0.069 0.0404 0.0141 0.001 0.0027 0.004

X 831-1 Taharoa iron sand

850-4 Marcona pellet (0.07) 65.67 (0.30) 4.12 0.019 0.013 0.006 0.008 0.056 0.40 0.41 0.79 (0.006) (0.003)

[1.93] [0.033] [0.21] [0.30] [0.48]

X 851-4 Sintered ore

852-2 Savage river pellet (0.04) 66.83 1.70 0.077 0.014 (0.002) 0.006 0.48 0.38 0.13 1.15 0.045 (0.004)

[0.79] [0.29] [0.20] [0.094] [0.69]

X 853-1 Algarrobo pellet

☆Continued

Mass content in % V Pb Zn Na2O K2O Net weight

JSS No. [Na] [K] (g)

801-6 Indian hematite (0.003)

803-6 Hermersley hematite (0.002) (0.002) (0.006) (0.005) 100

[(0.004)] [(0.004)]

804-2 Iscor hematite 0.0031 100

805-1 MBR hematite (0.005) (0.002) (0.004) (0.006) 100

[(0.003)] [(0.005)]

814-1 Pure magnetite 0.045 0.032 0.117 0.103 100

[0.087] [0.085]

820-3 Robe river limonite 0.0039 0.001 0.0082 70

X 831-1 Taharoa iron sand

850-4 Marcona pellet 0.025 (0.007) 0.129 0.075 100

[0.095] [0.062]

X 851-4 Sintered ore

852-2 Savage river pellet 0.46 (0.005) 0.030 0.007 100

[0.022] [0.006]

X 853-1 Algarrobo pellet

I-17. Ore series

Mass content in % Mn O (Active) Cr2O3 CW T.Fe SiO2 P S Al2O3 CaO MgO BaO Net weight

JSS No. (g)

X 861-1 Manganese ore

870-2 Chromium ore 48.14 14.04 3.96 (0.002) 0.018 11.62 15.54 100


I-18. Fluorspar series [ ] Metallic form

Mass content in % CaF2 SiO2 CaCO3 P S As Net weight ※ In preparation

JSS No. (g) ○ New/Renewal CRMs

X 883-1 The people's republic of China X Sold out

I-19. Blast Furnace slag series

Mass content in % SiO2 Al2O3 CaO MgO TiO2 MnO T.Fe P S Na K Ni Cr Cl Net weight

JSS No. (g)

905-1 Blast furnace slag 34.2 14.2 42.1 6.8 0.56 0.22 0.17 0.008 0.558 0.143 0.308 70

II. CRMs for Instrumental Analysis

II-1. Carbon steel series

Mass content in % C Si Mn P S Ni Cr Cu Size

JSS No.

410-2 10 Carbon steel 0.099 0.116 0.43 0.029 0.030 0.011 0.011 0.102

411-2 15 Carbon steel 0.138 0.117 0.43 0.029 0.030 0.011 0.010 0.101 35mm φx 30mm

412-2 20 Carbon steel 0.196 0.117 0.43 0.029 0.030 0.011 0.011 0.101

413-2 40 Carbon steel 0.39 0.25 0.56 0.019 0.019 0.011 0.011 0.102

414-2 60 Carbon steel 0.61 0.25 0.55 0.019 0.019 0.011 0.013 0.102

415-2 80 Carbon steel 0.75 0.25 0.55 0.019 0.019 0.011 0.013 0.101

II-2. Low alloy steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu V Size

JSS No.

X 150-13 Low alloy stee 1






II-3. Case hardening steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu V Al Size

JSS No.

X 512-6 S9CK

X 513-6 SCr415

X 514-6 SCM420

X 515-6 SNC415

X 516-6 SNCM24

X 517-6 SNCM616


※ In preparation


X Sold out

II-4. Tool steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu W V Size ( ) Non-certified value

JSS No. ※ In preparation

620-1 SKS 3 0.95 0.24 0.96 0.0082 0.0095 0.038 0.90 0.051 0.022 0.66 (0.009) ○ New/Renewal CRMs

621-1 SKS 2 1.05 0.22 0.69 0.015 0.0065 0.109 0.75 0.107 0.092 1.13 0.064 35mm φx 30mm X Sold out

622-1 SKS 11 1.22 0.31 0.45 0.017 0.0069 0.16 0.36 0.16 0.037 3.44 0.16

623-1 SKD 4 0.30 0.28 0.54 0.013 0.0161 0.20 2.56 0.27 0.014 5.55 0.39

624-1 SKD 6 0.38 0.89 0.30 0.018 (0.012) 0.044 4.92 1.19 0.21 0.103 0.42

625-1 SKT 4 0.57 0.101 0.88 0.016 0.0165 1.51 0.87 0.36 0.16 (0.004) (0.007)

II-5. High speed steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu W V Co N Size

JSS No.

606-8 SKH 2 0.76 0.28 0.31 0.016 0.0008 0.065 4.00 0.58 0.027 17.16 0.83 0.12 0.0290

607-8 SKH 3 0.78 0.30 0.35 0.026 0.0031 0.052 3.97 0.54 0.025 17.48 0.84 4.59 0.0270 35mm φx 30mm

608-8 SKH 4A 0.80 0.36 0.33 0.025 0.0028 0.044 3.99 0.41 0.017 17.03 0.99 9.09 0.0320

609-8 SKH 55 0.89 0.32 0.31 0.027 0.0007 0.12 3.98 4.85 0.053 6.10 1.87 4.63 0.0465

610-8 SKH 57 1.23 0.28 0.31 0.026 0.0015 0.18 3.96 3.09 0.066 8.94 3.25 9.60 0.0348

611-8 SKH 9 0.86 0.37 0.30 0.025 0.0013 0.13 3.97 4.88 0.046 6.27 1.88 0.40 0.0548

II-6. Stainless steel series

Mass content in % C Si Mn P S Ni Cr Mo Cu Co Nb Size

JSS No.

650-13 SUS 430 0.053 0.30 0.48 0.024 (0.0048) 0.18 16.70 0.013 0.020 0.017

651-13 SUS 304 0.018 0.42 1.81 0.026 0.0027 10.20 18.42 0.24 0.16 0.13 35mm φx 30mm

652-13 SUS 316 0.044 0.42 1.73 0.031 0.0027 11.38 16.56 2.13 0.20 0.18

653-13 SUS 309S 0.044 0.40 1.80 0.033 0.0006 13.96 22.43 0.20 0.16 0.20

654-13 SUS 310S 0.046 0.40 1.69 0.026 0.0006 19.42 24.79 0.23 0.15 0.15

655-13 SUS 347 0.036 0.62 1.81 0.028 0.0043 9.52 17.34 0.22 0.20 0.17 0.55

II-7. High Grade Pure Iron Disc Size: 32mm φx 25mm

Mass content in μg/g C Si Mn P S Ni Cr Mo Cu Co Al Sn W B N As

JSS No.

1000-1 Pure iron 4.6* 49 27 4.3 2* 0.4 (1) 0.7 15.4 2.2 78 4.9 0.4 (0.2) 7.8 (<2)

☆Continued

Mass content in % Bi Ca Cd Ce La Mg Nb Pb Sb Se Ta Te Ti V Zn Zr

JSS No.

1000-1 Pure iron (<0.1) (<3) (<0.1) (<0.1) (<0.1) (<0.3) (<0.5) (<0.1) (<0.2) (<1) (<0.1) (<0.5) (<1) (<0.3) (<0.5) (<0.2)

*) This value means the carbon content in the metal with removal of contaminated carbon on the surface of test portion

III. Setting-up sample for determination of gaseous elements in steel

Mass content in (μｇ／ｇ) O N H Size

JSS No. (Uncertified) (Uncertified)

GS-1d 35.4 (200) 1.6

X GS-2d

X GS-3c (5mm dia. x 230mm x 8pcs: apprx. 280g)

○ GS-5e (144) 31.2

X GS-6b

○ GS-12a 4.8 (6mm dia. x 230mm x 8pcs: approx. 410g)

IV. Steel sample of isolation and determination of nonmetallic inclusion

IV-1. Carbide isolation series

Mass content in % Ti Fe Cr Mn Mo Size

JSS No.

221-1b M3C 1.91 0.384 0.138 0.022 18 φx 50mm

222-1a (Cr, Fe)23C6 (0.20) 0.74 18 φx 70mm

222-1b (Cr, Fe)23C6 (0.20) 0.73 18 φx 70mm

IV-2. Sulfide isolation series

Mass content in % S Size

JSS No.

260-1 MnS 0.0046 18 φx 60mm

261-1 MnS 0.023 18 φx 60mm

262-1 TiS 0.049 18 φx 55mm ( ) Non-certified value

263-1 Zr3S4 0.050 18 φx 55mm ※ In preparation

264-1 CaS 0.0016 18 φx 60mm ○ New/Renewal CRMs

265-1 CeS, MnS 0.018 18 φx 60mm X Sold out

October 25, 2007

STANDARD MATERIALS FOR GAS ANALYSIS

(SEISHIN ORIGINAL)

NITROGEN/OXYGEN IN STEEL PINS

Product No. N (ppm) O (ppm) Form Unit Size Price (JPY)

SS-2 10 - 20 100 - 120 1.0g pin (φ5mm×6.5mm) 100 pcs 23,000

SS-3 55 - 70 165 - 185 1.0g pin (φ5mm×6.5mm) 100 pcs 23,000

SS-4 135 - 145 10 - 15 1.0g pin (φ5mm×6.5mm) 100 pcs 23,000

Certificate of analysis for these items are not attached. Value is labeled on each bottle.

HYDROGEN IN STEEL

Product No. H (ppm) Form Unit Size Price (JPY)

SS-5 6.5 8 10g rod (φ4mm×100mm) 10 pcs 25,000

OXYGEN IN STEEL

Product No. O (ppm) Form Unit Size Price (JPY)

SMO-12 Approximate 1,000ppm 1.0g pin 100 pcs In prep

NOTE: Values listed are nominal and depend on the lot.

Sample № C Si Mn P S Cu Sol. Al Insol. Al Ni Cr Mo V Ti

ST01-d 0.0024 0.006 0.01 0.001 0.001 0.01 0.002 <0.001 0.01 0.01 0.001 0.001 0.001

ST02-d 0.100 0.60 0.15 ─ 0.0032 0.07 ─ ─ 0.05 4.02 0.50 0.40 0.022

ST03-d 0.149 0.40 0.75 ─ 0.006 0.69 0.014 <0.001 0.10 3.22 0.40 0.027 0.10

ST04-d 0.21 0.060 2.00 0.008 0.016 0.11 0.090 0.001 0.50 2.51 0.30 ─ 0.30

ST05-d 0.26 0.25 1.60 0.013 0.0017 0.40 0.041 <0.001 1.05 2.02 0.092 0.30 0.014

ST06-d 0.34 0.34 1.29 0.048 0.0013 0.49 0.023 <0.001 1.55 1.49 0.20 0.058 0.054

ST07-d 0.50 0.30 1.02 0.038 0.026 0.20 0.031 <0.001 2.02 1.02 0.60 0.11 0.20

ST08-d 0.64 0.15 0.51 0.028 0.020 0.30 0.058 <0.001 2.53 0.53 1.02 0.16 0.16

ST09-d 0.80 0.20 0.31 0.018 0.0029 0.17 0.049 <0.001 3.26 0.12 0.82 0.20 ─

ST10-d 0.99 0.11 0.10 0.003 0.009 0.05 0.071 <0.001 4.06 0.05 0.059 0.49 ─

Sample № Co As Sn Ca Nb B Pb Sb Zr W Ce Ta ─

ST01-d 0.002 0.001 0.001 0.0001 0.001 0.0001 <0.001 <0.001 <0.001 <0.01 0.001 <0.001

ST02-d 0.012 ─ 0.064 ─ 0.10 ─ ─ 0.005 ─ ─ 0.044 0.11

ST03-d 0.15 0.009 0.043 ─ 0.072 ─ ─ 0.010 ─ ─ 0.024 0.057

ST04-d 0.052 ─ 0.021 ─ 0.020 ─ ─ 0.050 ─ ─ 0.010 0.023

ST05-d 0.10 0.022 0.011 0.0004 0.051 ─ ─ 0.074 ─ ─ 0.004 0.006

ST06-d 0.20 0.063 ─ 0.0010 0.016 ─ 0.006 0.096 0.004 ─ ─ 0.003

ST07-d ─ 0.043 ─ 0.0020 0.010 0.0024 0.016 ─ 0.009 0.05 ─ 0.19

ST08-d ─ ─ ─ 0.0030 ─ 0.0036 0.003 ─ 0.048 0.11 ─ ─

ST09-d ─ ─ ─ 0.0036 ─ 0.0048 0.010 ─ 0.069 0.20 ─ ─

ST10-d ─ ─ ─ 0.0039 ─ 0.0061 0.086 ─ 0.090 0.16 ─ ─

mass ％

Item No. KTC-1　　Low alloy steel standard

10 pieces/set, Form: 35 dia x 20 mmt

Sample No. C Si Mn P S Cu Sol. Al Insol. Al Ni Cr

A-g 1.00 0.06 0.01 0.001 0.001 0.10 0.077 0.001 4.04 -

B-g 0.01 0.58 0.54 0.045 - 0.70 - - 0.52 3.98

C-g 0.11 - 1.96 - 0.028 - 0.016 0.001 - 0.49

Sample No. Mo V Ti Co As Sn Ca Nb B W

A-g - 0.03 0.30 - - - - 0.11 - 0.21

B-g 0.20 - 0.03 0.01 0.043 0.086 0.0033 - 0.0093 -

C-g 0.98 0.48 - 0.20 - - - - - -

mass ％

Item No. KTC-2　Low alloy steel standard (for standardization)3 pieces/set, Form: 35 dia x 20 mmt

Sample No. C Si Mn P S Cu Sol. Al Insol. Al Ni

ST21-c 0.13 0.18 0.40 0.003 0.026 - - - 4.03

ST22-c 0.036 0.39 0.57 0.028 0.005 - 0.092 0.003 19.85

ST23-c 0.11 0.82 1.60 0.005 0.021 0.048 0.045 0.003 9.99

ST24-c 0.084 0.58 0.78 0.004 0.015 0.029 0.021 0.002 13.93

ST25-d 0.027 1.43 1.42 0.010 0.021 0.011 0.001 0.001 8.05

ST26-c 0.044 1.01 1.19 0.021 0.008 - 0.004 0.002 17.62

ST27-c 0.057 1.19 1.00 0.019 0.011 - 0.016 0.002 15.74

ST28-c 0.016 0.12 0.23 0.034 0.003 - - - 29.62

Sample No. Cr Mo Ti Co As Nb Pb Ta

ST21-c 27.02 - 0.003 0.003 - - - -

ST22-c 25.00 - - - 0.001 - - -

ST23-c 22.17 1.01 - - 0.104 <0.01 0.005 -

ST24-c 20.20 1.50 - - 0.056 - 0.013 -

ST25-d 18.32 2.49 - 0.050 0.012 - 0.044 -

ST26-c 16.18 0.49 0.075 0.21 - 0.29 - 0.40

ST27-c 13.39 0.008 0.24 0.014 - 1.53 - 0.24

ST28-c 10.34 - 0.49 - - 0.72 - 0.060

mass %

Item No. KTC-3 Stainless steel standard (austenite)8 pieces/set, Form: 35 dia x 20 mmt


D-c 0.093 0.50 1.01 0.007 0.027 0.019 0.046 0.004 4.06

E-c 0.055 1.57 1.45 0.010 0.008 0.060 0.030 0.002 14.74

F-d 0.016 0.42 0.20 0.037 0.004 0.014 0.023 <0.001 29.86

Sample No. Cr Mo Ti Co As Nb Pb Ta

D-c 27.12 0.051 0.045 0.026 0.14 0.10 0.014 0.007

E-c 15.71 2.40 0.15 0.21 0.077 0.41 0.14 0.22

F-d 4.62 0.97 0.58 0.068 0.002 1.32 0.001 0.070

mass %

Item No. KTC-4 Stainless steel standard (austenite for standardization)3 pieces/set, Form: 35 dia x 20 mmt


ST31-b 0.068 1.24 0.51 0.023 0.005 0.19 0.10 0.003 3.91

ST32-b 0.040 0.52 1.16 0.030 0.007 0.01 0.013 0.004 2.56

ST33-b 0.044 0.32 0.30 0.008 0.022 0.10 0.031 0.004 1.03

ST34-b 0.084 0.78 0.99 0.025 0.004 0.04 0.045 0.006 0.48

ST35-b 0.22 0.58 1.35 0.002 0.029 <0.01 0.057 0.007 0.05

ST36-b 0.15 0.14 0.43 0.014 0.009 <0.01 0.001 0.008 0.11

ST37-b 0.11 0.99 0.74 0.007 0.019 <0.01 0.001 0.002 0.20

ST38-b 0.30 0.40 0.19 0.010 0.013 <0.01 0.001 0.002 0.01

Sample No. Cr Mo Co Ti As Nb

ST31-b 11.23 0.71 0.19 0.31 0.10 0.90

ST32-b 12.71 1.01 0.014 0.051 0.008 0.082

ST33-b 15.12 1.19 0.10 0.007 0.001 0.30

ST34-b 16.99 0.48 0.051 0.098 0.009 0.083

ST35-b 24.14 0.029 0.005 0.005 <0.001 0.007

ST36-b 22.31 0.043 0.003 0.005 <0.001 0.001

ST37-b 19.51 0.20 0.002 0.003 <0.001 <0.001

ST38-b 25.52 0.004 0.002 0.003 <0.001 <0.001

mass %

8 pieces/set, Form: 35 dia x 20 mmtItem No. KTC-5 Stainless steel standard (ferrite)


G-b 0.031 1.26 1.37 0.029 0.005 0.19 0.086 0.005 3.87

H-b 0.088 0.50 0.47 0.009 0.010 0.04 0.031 0.005 0.57

I-b 0.26 0.22 0.19 0.004 0.028 <0.01 0.001 0.004 0.02

Sample No. Cr Mo Co Ti As Nb

G-b 11.85 1.14 0.19 0.30 0.075 0.98

H-b 17.95 0.49 0.054 0.094 0.011 0.094

I-b 24.47 0.048 0.006 0.013 0.002 0.007

mass %

Item No. KTC-6 Stainless steel standard (ferrite for standardization)3 pieces/set, Form: 35 dia x 20 mmt

Sample No. C Si Mn P S Cu Ni Cr Mo

B-1 2.4 3.0 0.05 0.005 0.10 0.05 1.0 1.0 0.05

B-2 2.6 2.8 0.2 0.025 0.09 0.2 0.8 0.8 0.2

B-3 3.0 2.2 0.4 0.05 0.06 0.4 0.6 0.6 0.4

B-4 3.3 1.8 0.6 0.07 0.04 0.6 0.4 0.4 0.6

B-5 3.7 1.4 0.8 0.09 0.02 0.8 0.2 0.2 0.8

B-6 4.0 1.0 1.0 0.12 0.003 1.0 0.05 0.05 1.0

mass %

Sample No. Mg C Si Mn P S

M-1 0.05 3.4 2.5 0.1 0.015 0.002

M-2 0.04 3.4 2.5 0.1 0.015 0.002

M-3 0.03 3.4 2.5 0.1 0.015 0.002

M-4 0.02 3.4 2.5 0.1 0.015 0.002

M-5 0.01 3.4 2.5 0.1 0.015 0.002

mass %

Item No. KTC-10 Ductile cast iron (Mg for calibration curve) 5 pieces/set, Form: 34 dia x 5 mmt

Item No. 9 Alloy cast iron (for calibration curve) 6 pieces/set, Form: 34 dia x 5 mmt

Sample No. C Si Mn P S Ni Cr Mo Cu V Ti

D-1a 3.20 3.31 0.13 0.028 0.005 - - 0.11 0.19 0.10 -

D-2a 3.47 2.99 0.50 0.016 0.001 0.41 - 0.22 0.04 0.20 0.010

D-3a 3.60 2.22 0.42 0.033 0.017 0.31 - 0.45 - - 0.24

D-4a 3.19 2.71 0.71 0.020 0.006 0.34 0.21 0.021 - 0.25 -

D-5a 3.78 2.47 0.24 0.044 0.014 - 0.02 0.32 - - 0.18

D-6a 3.93 1.64 0.37 0.071 0.033 0.10 0.31 - 0.31 0.15 0.047

D-7a 3.99 2.02 0.29 0.060 0.021 0.21 - 0.062 0.11 0.055 0.12

D-8a 2.98 2.87 0.20 0.050 0.037 0.01 0.29 0.008 0.52 0.009 -

D-9a 3.20 2.48 0.84 0.004 0.014 - 0.11 0.004 0.01 0.37 -

D-10a 2.79 2.40 0.02 0.008 0.011 - 0.40 - 0.40 0.003 -

Sample No. Al Sn B Pb Sb Ca Bi Zn Ce Mg

D-1a 0.087 - 0.028 0.001 0.062 - - 0.009 0.035 0.046

D-2a 0.074 0.004 0.055 - 0.094 - - 0.002 0.011 0.053

D-3a 0.012 0.014 0.010 - 0.024 - - 0.018 - 0.022

D-4a 0.053 0.44 0.12 0.004 0.009 0.0018 - - 0.008 0.048

D-5a 0.013 - 0.001 0.007 0.16 0.0005 0.001 0.029 - 0.020

D-6a 0.007 0.054 - 0.016 - 0.0005 0.005 - - 0.015

D-7a 0.014 - - 0.009 - - 0.011 0.051 - 0.013

D-8a 0.11 0.30 - 0.009 0.21 - 0.005 - 0.064 0.021

D-9a 0.10 0.20 - 0.037 - 0.0030 - - 0.092 0.007

D-10a 0.029 0.089 0.087 0.026 - 0.0035 0.003 - - 0.003

mass %

Item No. KTC-11 Ductile cast iron (for calibration curve)10 pieces/set, Form: 34 dia x 5 mmt

Sample No. C Si Mn P S Ni Cr Mo Cu V Ti

C-1a 4.00 0.50 0.80 0.005 0.032 - 0.10 0.30 0.50 - -

C-2a 3.85 0.80 0.65 0.012 0.021 - 0.20 0.20 0.40 - -

C-3a 3.70 1.20 0.05 0.020 0.08 - 0.30 0.10 0.30 - -

C-4a 3.55 1.60 0.50 0.30 0.06 0.01 0.40 0.40 0.20 0.04 -

C-5a 3.40 2.00 0.40 0.10 0.04 0.50 0.25 0.05 0.10 0.15 -

C-6a 3.30 2.20 0.35 0.075 0.025 0.40 0.35 0.003 0.01 0.05 0.01

C-7a 3.20 2.40 0.30 0.050 0.016 0.30 0.02 - - 0.10 0.10

C-8a 3.10 2.60 0.25 0.030 0.012 0.20 - - - 0.20 0.05

C-9a 2.95 2.80 0.20 0.50 0.008 0.10 - - - 0.30 0.15

C-10a 2.70 3.00 0.10 0.70 0.005 0.01 - - 0.50 0.01 0.20

Sample No. Al Sn B Pb Sb Ca Bi Zn Ce Mg

C-1a 0.005 - 0.10 - 0.15 - - 0.005 - -

C-2a 0.012 - 0.07 - 0.10 - 0.020 0.002 - -

C-3a 0.020 - 0.05 - 0.05 - 0.012 0.010 - -

C-4a 0.030 - 0.03 - 0.01 - 0.006 0.020 - -

C-5a - - 0.01 0.010 0.005 - 0.003 0.030 0.005 -

C-6a - 0.4 0.005 0.005 - 0.001 0.001 - 0.020 -

C-7a 0.040 0.3 - 0.003 - 0.0010 - - 0.10 -

C-8a 0.050 0.2 - 0.02 - 0.0015 - - 0.075 -

C-9a 0.060 0.1 - 0.03 - 0.0020 - - 0.010 -

D-10a 0.080 0.05 - 0.015 - 0.0040 - - 0.040 -

mass %

Item No. 12　　Plain cast iren (for calibration curve)

10 pieces/set, 34 dia x 5 mmt

Sample No. C Si Mn P S Ni Cr Mo Cu V

FCD-A 3.5 2.5 0.1 <0.02 <0.01 - - - - -

FCD-B 2.1 3.0 0.05 0.7 0.06 0.01 0.5 0.3 0.55 <0.01

FCD-C 0.2 0.5 0.8 <0.01 <0.01 0.5 0.01 <0.01 0.01 0.3

Sample No. Ti Al Sn B Pb Sb Ca Bi Zn Mg

FCD-A <0.01 - - - - - - - - 0.055

FCD-B - <0.01 0.3 0.1 0.01 0.2 <0.001 <0.01 <0.01 -

FCD-C 0.3 0.1 <0.01 <0.01 0.05 0.01 0.003 0.02 0.06 -

mass %

Sample No. C Si Mn P S Ni Cr Mo Cu Mg

FCD-D 3.4 2.5 0.1 0.015 - - - - - 0.05

FCD-E 2.4 3.0 0.05 0.005 0.10 1.0 1.0 0.05 0.05 <0.01

FCD-F 4.0 1.0 1.0 0.12 0.005 0.05 0.05 1.0 1.0 -

mass %

10 pieces/set (A: 4 pieces, B: 4 pieces, C: 2 pieces) Form: 34 dia x 5 mmt, C: 35 dia x 20mmt

10 pieces/set (D: 2 pieces, E: 4 pieces, F: 4 pieces) Form: 34 dia x 5 mmt

Item No. KTC-13 Cast iron　(for standardization)

Item No. KTC-14 Alloy cast iron (for standardization)

Sample No. Sol. N Insol. N C Si Mn P S Al Cr

N-1 0.0012 0.0001 0.015 0.10 0.10 0.002 0.003 0.050 0.21

N-2 0.0048 0.0002 0.014 0.10 0.10 0.002 0.003 0.048 0.29

N-3 0.0076 0.0003 0.012 0.10 0.10 0.002 0.003 0.048 0.19

N-4 0.0110 0.0002 0.012 0.10 0.10 0.003 0.004 0.048 0.20

N-5 0.0194 0.0008 0.012 0.10 0.11 0.003 0.004 0.050 0.41

mass %

Sample No. N C Si Mn P S Cu Ni Cr Mo

A-20 0.033 0.05 0.03 0.01 0.002 0.002 0.01 0.01 3.80 0.01

B-20 0.0015 0.01 0.01 0.01 0.001 0.002 0.01 0.01 0.01 0.01

mass %

Item No. KTC-15 Nitrogen for calibration curve

Item No. KTC-16 Nitrogen for standardization 4 pieces/set (A-20: 2 pieces, B-20: 2 pieces, Form: 35 dia x 20 mmt

　　　　　　　　　 5 pieces/set, Form: 35 dia x 20 mmt

reference material 2008 - 2009 seishin.pdf · · 2009-03-103 3.20 cao 66.25 mgo 1.08 so 3 0.25 na...

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