December13,2018Attn:JennyFilipy,P.E.WashingtonStateDepartmentofEcologyEasternRegion4601NMonroeSpokane,WA99205RE: NoticeofConstructionApplicationforSGLCompositesLLC,MosesLakeFacilityDearMs.Filipy:TrinityConsultantsissubmittingtheattachedNoticeofConstruction(NOC)applicationforSGLCompositesLLC(SGL).SGLownsandoperatesacarbonfiberplantlocatedinMosesLake,WA(theMosesLakeFacility).SGLisrequestingtoamendtheirexistingApprovalOrder,15AQ‐E636,toremovesourcesnotplannedtobebuiltandrequestasyntheticminorlimitswithrespecttothePreventionofSignificantDeterioration(PSD)programtosupersedetheircurrentPSDpermit14‐02.Thefilingfeeof$875wassubmittedelectronically.Ifyouhaveanyquestionsorcommentsabouttheinformationpresentedintheapplication,pleasedonothesitatetocallmeat(253)867‐5600ext.1005,orDavidHellerat(509)762‐4633.Sincerely,TRINITYCONSULTANTSINC.AshleyJonesSeniorConsultantCc:DavidHeller,SGLAaronDay,TrinityConsultants

PROJECT REPORT SGL Composites LLC > Moses Lake Facility

Notice of Construction Application Approval Order No.15AQ-E636 Modification

PreparedBy:

AaronM.Day,P.E.–PrincipalConsultant

AshleyJones–SeniorConsultantHuiCheng–SeniorConsultant

TRINITYCONSULTANTS2081972ndAvenueSouth

Suite610Kent,WA98032(253)867‐5600

December2018

Environmental solutions delivered uncommonly well

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application Trinity Consultants i

TABLE OF CONTENTS

1. EXECUTIVE SUMMARY 1-1 

2. FACILITY DESCRIPTION 2-1 2.1.ProductionLines1through6............................................................................................................................2‐1 2.2.EmergencyGeneratorsandFirePumps.........................................................................................................2‐2 2.3.Facility‐WidePotentialtoEmit.........................................................................................................................2‐2 

2.3.1.Start‐UpMode............................................................................................................................................................................2‐3 2.3.2.NormalOperationMode........................................................................................................................................................2‐3 2.3.3.ShutdownMode.........................................................................................................................................................................2‐4 2.3.4.RTOBypassMode......................................................................................................................................................................2‐4 2.3.5.SCRBypassMode.......................................................................................................................................................................2‐5 2.3.6.StandbyMode.............................................................................................................................................................................2‐6 2.3.7.EmergencyGeneratorsandFirePumps..........................................................................................................................2‐6 

3. REQUESTED PERMIT CHANGES 3-1 3.1.ProposedLimits.....................................................................................................................................................3‐1 3.2.RequestforSyntheticMinorPermitLimit.....................................................................................................3‐1 3.3.OtherMiscellaneousChanges............................................................................................................................3‐2 

4. REGULATORY REVIEW 4-1 4.1.PSDApplicability...................................................................................................................................................4‐1 4.2.TitleVOperatingPermitApplicability...........................................................................................................4‐1 4.3.FederalStandards.................................................................................................................................................4‐1 4.4.BestAvailableControlTechnology..................................................................................................................4‐1 4.5.AirQualityAnalysis..............................................................................................................................................4‐2 

APPENDIX A: APPLICATION FORM AND ASSOCIATED DOCUMENTS A-1 

APPENDIX B: EMISSION CALCULATIONS B-1 

APPENDIX C: NOX CERM DATA C-1 

APPENDIX D: BACKGROUND INFORMATION FOR BACT D-1 

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LIST OF TABLES

Table2‐1.NormalOperationModeLines1‐6HourlyEmissionsPerLine 2‐3 

Table2‐2.ShutdownModeLines1‐6HourlyEmissionsPerLine 2‐4 

Table2‐3.RTOBypassModeLines1‐6HourlyEmissionsPerLine 2‐5 

Table2‐4.SCRBypassModeLines1‐6HourlyEmissionsPerLine 2‐6 

Table2‐5.Facility‐WidePTE 2‐8 

Table3‐1.ProposedLimits 3‐1 

Table3‐2.Facility‐WideAnnualNOXEmissions 3‐2 

Table4‐1.IncrementAnalysis 4‐2 

Table4‐2.NAAQSAnalysis 4‐2 

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application Trinity Consultants 1-1

1. EXECUTIVE SUMMARY

SGLCompositesLLC(SGL)ownsandoperatesacarbonfiberplantlocatedinMosesLake,WA(theMosesLakeFacility).SGLisrequestingtoamendtheirexistingApprovalOrder,15AQ‐E636,toremovesourcesassociatedwithPhases3‐6andrequestasyntheticminorlimitwithrespecttothePreventionofSignificantDeterioration(PSD)programtosupersedetheircurrentPSDpermit14‐02.SGLisrequestingtoremoveLines7‐10andallassociatedequipmentfromthecurrentpermitbecausetheselineshavenotbeenbuilt,andarenotcurrentlypartofSGL’sbusinessplantobuild.RemovingLines7‐10associatedequipmenteliminatesallbutNOXfrombeingabovethePSDthreshold1.SGLisrequestingasyntheticminorlimitforNOXtomakethefacilityasyntheticminorfacilitywithrespecttoPSDforallpollutants.SGLalsorequeststhattherevisedOrderofApproval(OA)permitwillsupersedeallexistingOAsandtheexistingPSDpermit14‐02.AletterwillalsobesenttoEcologyheadquarterstorescindthePSDpermitwiththeissuanceoftherevisedOA.Asanadministrativenote,SGLhasidentifiedthatthelinespeedonLines1‐6canberunatahigherspeedthanthepreviouslynotednominalcapacityofthelines.TheincreasedlinespeedisnotexpectedtoimpactanyofthecurrentSGLpermitlimits,andSGLisnotrequestinganypermitlimitincreases.Thisreportservesasthenoticeofconstruction(NOC)applicationfortheproposedchangeandconsolidationofpermitconditionsandrequirements.InaccordancewithWashingtonregulations,aBestAvailableControlTechnology(BACT)reviewhasbeenperformedforeachidenticalprocesslinetoverifytheBACTdeterminationoriginallyapprovedinpriorpermitsisstillappropriate.Aqualitativeairqualityanalysis(AQA)hasbeenperformedtodemonstratethatnonationalambientairqualitystandard(NAAQS)ortoxicairpollutants(TAPs)willbeexceededasaresultofthechange.

ThisNOCapplicationincludesthefollowingelements:

Section2.FacilityDescription Section3.RequestedPermitChanges Section4.RegulatoryReview AppendixA:ApplicationFormandAssociatedDocuments AppendixB:EmissionCalculations AppendixC:NOXContinuousEmissionRateMonitor(CERM)SummaryData AppendixD:BackgroundInformationforBACT

1EcologycurrentlyviewstheSGLMosesLakefacilityasbeingonthe“Listof28”sourcecategorywithaPSDthresholdof100tpyofacriteriapollutant.SGLdoesnotagreewiththisposition.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application 2-1 Trinity Consultants

2. FACILITY DESCRIPTION

SGLownsandoperatestheMosesLakeFacilitylocatedat8781RandolphRoadNE,MosesLake,Washington.SGLwasissuedPSDPermit14‐02onApril13,2015forLines3‐102,andFinalApprovalOrderNo.15AQ‐E636onMarch17,2016forLines1‐2andpollutantsfromLines3‐103thatdidnottriggerPSDpermitting.

SGLissubmittingthisNOCapplicationtorequestformodificationtotheApprovalOrderNo.15AQ‐E636toremovelines7‐10fromthepermitandrequestaPSDsyntheticminorlimit.SGLisrequestingasyntheticminoremissionlimitforNOXemissionsat90tonsperyear(tpy).TheMosesLakeFacilitywillremainamajorsourceofhazardousairpollutant(HAP)duetopotentialhydrogencyanide(HCN)emissionsbeinghigherthan10tpy.ThissectionsummarizestheemissionsourcesattheMosesLakeFacilityandthepotentialtoemit(PTE)fortheMosesLakeFacilityforLines1‐6.

2.1. PRODUCTION LINES 1 THROUGH 6

TheMosesLakeFacilitymanufacturescarbonfiber,andbeganoperationin2012withtheinstallationofLine1.Between2013and2015,Lines2,3,4,and5beganoperation.Line6waspermittedasPhase2ofconstructionandisstillintheconstructionphase.SGLexpectstoreceiveanextensionthroughSeptember30,2019forconstructionofLine6inthenearfuture.4

SGLestimatestheactualcapacityof2,150metrictonsperyearcanbeachievedoneachlinewithoutmakingphysicalmodifications.SGLexpectsthatoneortwolinesmayrunattheprojectedcapacity,andtheotherlinesmayoperatelessthancapacity.Eachcarbonfiberproductionlineconsistsofthefollowingprocesses:

Feedandpretension.Thisprocessinvolvesfeedingfilamentsofpolyacrylonitrile(PAN)throughaseriesofrollerstoapplyuniformtension.PANissplicedtogetherbyjoiningtheendofoneboxtothebeginningofanotherwithheatappliedbytheportableelectricovens(referredtoas“pre‐oxidationovens”).

Oxidation.ThefilamentsofPANisthenheatedintheelectricoxidationovens.Inthisstep,theacrylonitrilemoleculesarecyclizedandrearrangedinamorestablebondingform.

Carbonization.Thefiberisthensenttoalow‐temperaturefurnaceandahigh‐temperaturefurnaceinanoxygen‐freeenvironment,toburnoffnon‐carbonatoms.

Surfacetreatment.Duringthisstage,thesurfaceofthefiberisslightlyetchedtogivethembetterbondingproperties.ThefiberistreatedwithammoniumbicarbonatesolutionattheMosesLakeFacility,andthenwashedanddriedwithwater.

Sizing.Aresinsizingcoatingisappliedusingadouble‐tiprollerbathandsqueegee,toimprovehandlingandtransportationofthefibers.

Windingandpackaging.Thefinishedcarbonfiberisspooledontocardboardspoolsandwrappedforshipment.

2Lines3‐10triggeredPSDfornitrogenoxides(NOX),particulatematterlessthan10micronsandlessthan2.5microns(PM10/PM2.5),andvolatileorganiccompounds(VOC).

3Lines3‐10wereissuedaFinalOrderofApprovalforcarbonmonoxide(CO),sulfurdioxide(SO2),andtoxicairpollutants(TAPs).

4ThePSD14‐02amendmentfortheLine6constructionextensionwaspostedfor30‐daypubliccommentonNovember14,2018.Theamendmentisexpectedtobefinalizedinthenearfuture.

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Emissionsareexpectedfromtheoxidationovens,low‐temperaturefurnace,andhigh‐temperaturefurnace,andarecontrolledbythefollowingdevices:

Foreachline,theoxidationovensarecontrolledbyaRegenerativeThermalOxidizer(RTO)followedbyaSelectiveCatalystReactor(SCR).ThereisalsoasecondRTOservingasabackup.EachRTOhasan8.4MMBtu/hrnaturalgas‐firedpreheater.TheSCRhasa4.6MMBtu/hrnaturalgas‐firedpreheater.

Foreachline,thelow‐temperaturefurnaceandthehigh‐temperaturefurnacearecontrolledbyathermaloxidizer(TO),equippedwitha4MMBtu/hrnaturalgas‐firedpreheater.

Emissionsfromthepre‐oxidationsplicersweredeterminedtobeinsignificantemissionunitsperWashingtonAdministrativeCode(WAC)173‐401‐530(4)5forTitleVpurposes,butwereincludedinApprovalOrderNo.15AQ‐E636.6Aspermitted,SGLcouldhaveuptoatotalof50pre‐oxidationsplicersattheMosesLakeFacility.

2.2. EMERGENCY GENERATORS AND FIRE PUMPS

Theproductionlinesaresupportedbyemergencygeneratorstoensureoperationoftheovenfansincaseofagridpowerfailure,andfirepumpsforfiresuppressionpurposes.

Lines1and2aresupportedbyten(10)naturalgas‐firedemergencygenerators,witheachratedat454horsepower(hp).Thefacilityalsopermittedtwonaturalgas‐firedenginestoprovidepowertotheirfirepumps,eachratedat454hp.Theseemergencygeneratorsareexpectedtobeoperatedforupto34hoursperyearperengineandtheenginesassociatedwiththefirepumpsareexpectedtobeoperatedforupto38hoursperyearperengine.TherearenochangestooperationornumberofemergencygeneratorsneededforLines1and2.Ithasbeendeterminedthatthefacilityhascurrentlyonlyinstalledonefirepumpandassociatedengine,butwiththeconfirmationofallanalysesinthisapplication,SGLwouldliketorequestaneighteenmonthextensiontoconstructandinstallthesecond454hpfirepumpwiththeassociatedengine.Thecalculationsandanalysescontinuetoincludebothfirepumpengines.

Lines3through6aresupportedbyfour(4)diesel‐firedemergencygenerators,witheachratedat2,937hp.Themaximumhoursofoperationforalloftheseemergencygeneratorswillbe72hoursperyeartotalfor8hoursperyeartestingperengine,8hoursperyearemergencyoperationperengine,and8hoursperyearforaperformancetestofanygivenengine.Thisisthesameoperatingscenarioascurrentlypermitted,butreducedfrom136hours/yearduetotheremovalofLines7‐10.

2.3. FACILITY-WIDE POTENTIAL TO EMIT

PTEfromthecarbonfiberproductionlinesandtheemergencyenginesarecalculatedusingthemethodologiesdiscussedinthissection.Theemissionsfromtheproductionlinesaredeterminedbasedonsixdifferentoperatingmodes,asdescribedbelow.AprocessflowdiagramshowingtheprocessesandairflowsforeachproductionlineisprovidedinAppendixA.Therehavebeennochangestotheoperatingscenariosfromcurrentpermittedoperation.Nohourlyemissionsforeachlineareimpactedandthefollowingsectionsaretosummarizethehourlyemissionsbyoperatingscenarioforeachline.Detailedemissioncalculationsincluding

5AccordingtotheTitleVpermitapplicationsubmittedonSeptember26,2016.

6ApprovalOrderNo.15AQ‐E636included50hand‐heldpre‐oxidationovensforsplicingforthepotentialofLines1‐10.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application 2-3 Trinity Consultants

criteriapollutants,TAPsandHAPsforallproductionlinesandassociatedequipmentareprovidedinAppendixB.

2.3.1. Start-Up Mode

Inthestart‐upmode,theoxidationovensattheproductionlinesareheatingbuthavenotreachedthetemperatureandspeedsnecessaryfornormaloperations.Duringstartup,therawmaterialPANispartiallyoxidizedandisnotsenttothefurnacesforcarbonization.ThesepartiallyoxidizedPANisdiscardedaswaste.SincetheemissionsinthismodeareexpectedtobelowerthantheNormalOperationMode,thereisnooperationlimitfortheStart‐UpMode.

2.3.2. Normal Operation Mode

Whentheovensandfurnacesreachthenormaloperationtemperatures,theproductionlinesareintheNormalOperationMode.EmissionsfromtheoxidationovensarefirstlysenttoRTOandthentheSCRforemissioncontrol.TheexhaustfromtheSCRisroutedforheatrecoverybeforeexhaustinginthemainstack.The8.4MMBtu/hrRTOpreheaterandthe4MMBtu/hrSCRpreheaterareinoperationinthismode.NormallythesecondRTOservingasthebackupisnotinoperation.However,theemissionsfromthesecondRTOfiringat2.04MMBtu/hrareconservativelyincludedforPTEpurposesonly.

EmissionsfromthefurnacesaresenttotheTO,andthe4MMBtu/hrpreheaterisinoperationinthismode.Thewasteheatisalsorecoveredbeforetheexhaustisroutedtothemainstack.

HourlyemissionsforcriteriapollutantsandHAPs/TAPswithcurrentpermitlimitsinthenormaloperationmodeforeachlinearesummarizedinTable2‐1,whichareidenticaltotheemissionlimitsinPSDPermit14‐02andApprovalOrderNo.15AQ‐E636.Onannualbasis,eachlinecouldbeoperatedupto8760hoursperyear.MoredetailsontheemissionsfromNormalOperationModeareavailableinAppendixB.

Table2‐1.NormalOperationModeLines1‐6HourlyEmissionsPerLine

Pollutant

OxidationOvensb(lb/hr)

Furnacesc(lb/hr)

SCRHeaterd(lb/hr)

SCRAmmoniaSlip

(lb/hr)

TotalforEachLine(lb/hr)

NOXa ‐‐ ‐‐ ‐‐ ‐‐ 8.5CO 0.6 0.4 0.4 ‐‐ 1.3SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7PMe ‐‐ ‐‐ ‐‐ ‐‐ 1.1

PM10/PM2.5e ‐‐ ‐‐ ‐‐ ‐‐ 3.0VOC 0.2 1.4 0.02 ‐‐ 1.7HCNf 1.1 0.3 ‐‐ ‐‐ 1.4

Acrylonitrilef 5.6E‐03 ‐‐ ‐‐ ‐‐ 5.6E‐03Ammoniaf 0.5 0.1 ‐‐ 2.4 3.0

aNOXhourlyemissionrateisbasedonSCRvendorquote.bOxidationovensCO,SO2,andVOCemissionsarecalculatedusingtheRTOoutletconcentrationfrom2013sourcetestingplusnaturalgascombustionemissionsfromthebackuppreheaterusingAP‐42,Section1.4emissionfactor.

cFurnacesCOandVOCemissionsarebasedonoriginalPSDapplicationforPSDpermit14‐02.SO2emissionsarebasedonAP‐42,Section1.4emissionfactorfornaturalgascombustion.

dSCRheaterCO,SO2andVOCemissionsarebasedonAP‐42,Section1.4emissionfactorsfornaturalgascombustion.ePM,PM10andPM2.5emissionsarebasedonoriginalPSDapplication.PM10andPM2.5includebothfilterableandcondensableparticulatematter.ItisconservativelyassumedthatPM2.5emissionsarethesameasPM10emissions.

fApprovalOrderNo.15AQ‐E636establishedlimitsforHCN,acrylonitrile,andammonia.Therefore,hourlyemissionsforthesepollutantsareprovidedhere,whicharebasedonoriginalPSDapplication.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application 2-4 Trinity Consultants

2.3.3. Shutdown Mode

Shutdownmodeoccursattheendofeachproductioncampaignaboutevery15to30days.Inthismode,freshairisdrawnintotheovensandtheemergencyventdoorsareopened.Theemergencyfanwillalsobeturnedontopushtheexcessairtothemainstack(Line1)ortheatmosphere(otherlines).TheRTOwillbefullyfunctionalinthismode,buttheexhaustairfromtheovensbypassestheRTO.Thepurposeofthismodeistopreventormitigateanovenfireorduringnormalshutdowntopreservetheoxidationprofileonthebandwhichimprovessafetyduringstartup.Theshutdownmodeisexpectedtolastnomorethan90seconds.TheTOandtheSCRarealsoinoperationatthistime.

EmissionsfortheShutdownModearetheweightedaverageoftheexhaustflowratesfromtheRTOwithRTONormalOperationModeemissionsandthedesigncapacityoftheemergencyfanwithRTOinletemissions(i.e.,RTOBypassMode).7AlthoughtheShutdownModewillnotlastlongerthan90seconds,thehourlyemissions,whicharesummarizedinTable2‐2,conservativelyassumedthatitwouldlastforanentirehour.Onannualbasis,itisconservativelyassumedthatoneshutdownoccurrenceperday(i.e.,maximumof9.13hoursperyear)foreachline.MoredetailsontheemissionsfromShutdownModeareavailableinAppendixB.

Table2‐2.ShutdownModeLines1‐6HourlyEmissionsPerLine

Pollutant

OxidationOvensb

(lb/hr)Furnacesc(lb/hr)

SCRHeaterc(lb/hr)

SCRAmmoniaSlip

(lb/hr)

TotalforEachLine(lb/hr)

NOXa ‐‐ ‐‐ ‐‐ ‐‐ 8.5CO 0.6 0.4 0.4 ‐‐ 1.3SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7PMa ‐‐ ‐‐ ‐‐ ‐‐ 1.1

PM10/PM2.5a ‐‐ ‐‐ ‐‐ ‐‐ 3.0

VOC4.3forLine1

5.6forLines2‐6 1.4 0.02 ‐‐5.7forLine1

7.1forLines2‐6

HCNd17.8forLine1

23.3forLines2‐60.3 ‐‐ ‐‐

18.0forLine123.6forLines2‐6

Acrylonitriled0.10forLine1

0.14forLines2‐6‐‐ ‐‐ ‐‐

0.10forLine10.14forlines2‐6

Ammoniad5.7forLine1

7.5forLines2‐60.1 ‐‐ 2.4

8.3forLine110.0forLines2‐6

aNOXhourlyemissionrateisbasedonSCRvendorquote.PM,PM10 andPM2.5 emissionsareassumedtobethesameasNormalModeemissions,whichareexpectedhigherthantheShutdownMode.

bOxidationovensCO,SO2,VOC,andHCNemissionsaretheweightedaverageofnormaloperationemissionsattheRTOwiththetypicalRTOexhaustflowrateandtheRTOinletemissionswiththeemergencyfancapacity.Line1hasahigheremergencyfancapacity;therefore,emissionsforLine1aredifferentthanLines2‐6.

cFurnacesemissionsarethesameastheNormalModeemissions.dApprovalOrderNo.15AQ‐E636didnotestablishlimitsforHCN,acrylonitrile,andammoniaforShutdownMode.HourlyemissionsforthesepollutantsprovidedherearebasedonoriginalPSDapplication.

2.3.4. RTO Bypass Mode

ThismodeisonlyneededintherareeventthattheRTOhasanequipmentfailure.ThebypassisneededwhentheRTOshutsdownandtheplantoperatorswillevaluatewhethertheRTOcouldberestartedortheproduction 7ShutdownemissionsaremonitoredsolelybytheCERMSonLine1andonallotherlinestheshutdownemissionsareevaluatedbythesumoftheCERMSand8.5lb/hrtoaccountfortheportionthatgoestoatmosphere,inaccordancetoApprovalOrderNo.15AQ_E636.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application 2-5 Trinity Consultants

lineneedtobeshutdownuntiltheRTOcanberepaired.OnlyVOC,acrylonitrile,ammonia,andHCNemissionsarehigherattheRTOinletthanRTOoutletbasedon2013sourcetesting.HourlyemissionsforthesepollutantsarebasedontheRTOinletemissionrates,andhourlyemissionsforotherpollutantsareconservativelyassumedtobethesameastheNormalOperationModeemissions.EventhoughtheexhaustfromoxidationovensbypasstheRTOandtheSCR,theNOXemissionsforRTOBypassModearenotexpectedtobehigherthannormaloperations,becausethemajorityofNOXemissionsaregeneratedattheRTO.

HourlyemissionsfortheRTOBypassModearesummarizedinTable2‐3.Onannualbasis,itisassumedthattheRTOwillbebypassedfor4.5hoursperyearforeachline.MoredetailsontheemissionsfromRTOBypassModeareavailableinAppendixB.

Table2‐3.RTOBypassModeLines1‐6HourlyEmissionsPerLine

Pollutant

OxidationOvensa(lb/hr)

Furnaces(lb/hr)

SCRHeater(lb/hr)

SCRAmmoniaSlip

(lb/hr)

TotalforEachLine(lb/hr)

NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.5CO 0.6 0.4 0.4 ‐‐ 1.3SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7PM ‐‐ ‐‐ ‐‐ ‐‐ 1.1

PM10/PM2.5b ‐‐ ‐‐ ‐‐ ‐‐3.0forLines1‐22.0forLines3‐6

VOC 7.2 1.4 0.02 ‐‐ 8.6HCNc 29.7 0.3 ‐‐ ‐‐ 30.0

Acrylonitrilec 0.17 ‐‐ ‐‐ ‐‐ 0.17Ammoniac 9.5 0.1 ‐‐ ‐‐ 9.6

aVOCandHCNemissionsarebasedon2013sourcetestingforRTOinlet.EmissionsforotherpollutantsareconservativelyassumedtobethesameastheNormalOperationModeemissions.

bPM10/PM2.5emissionlimitsforLines3‐6arefromPSDPermit14‐02.cApprovalOrderNo.15AQ‐E636didnotestablishlimitsforHCN,acrylonitrile,andammoniaforRTOBypassMode.HourlyemissionsforthesepollutantsprovidedherearebasedonoriginalPSDapplication.

2.3.5. SCR Bypass Mode

IntheeventofanSCRmalfunction,theSCRwillbebypassed.EmissionsfromtheoxidationovenswillcontinuetoberoutedtoRTOandthenexhaustthroughthemainstack.SincetheSCRisusedforNOXcontrol,onlyNOXemissionsareexpectedtobehigherthanNormalOperationModeemissions.NOXemissionsfromtheTOareaccountedforseparatelyandarenotimpactedbytheSCRBypassMode.ItisconservativelyassumedthattheSCRHeaterisstillinoperationinthismode.

HourlyemissionsfortheSCRBypassModelaresummarizedinTable2‐4.Onannualbasis,theSCRwillnotbebypassedformorethan100hoursperyearforeachline.MoredetailsontheemissionsfromSCRBypassModeareavailableinAppendixB.

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Table2‐4.SCRBypassModeLines1‐6HourlyEmissionsPerLine

Pollutant

OxidationOvensa(lb/hr)

Furnacesa(lb/hr)

SCRHeater(lb/hr)

SCRAmmoniaSlip

(lb/hr)

TotalforEachLine(lb/hr)

NOX 14.9 3.0 ‐‐ ‐‐ 17.9CO 0.6 0.4 0.4 ‐‐ 1.3SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7PM ‐‐ ‐‐ ‐‐ ‐‐ 1.1

PM10/PM2.5b ‐‐ ‐‐ ‐‐ ‐‐ 3.0forLines1‐22.0forLines3‐6

VOC 0.2 1.4 0.02 ‐‐ 1.7HCNc 1.1 0.3 ‐‐ ‐‐ 1.4

Acrylonitrilec 5.6E‐03 ‐‐ ‐‐ ‐‐ 5.6E‐03Ammoniac 0.5 0.1 ‐‐ ‐‐ 0.6

aNOXemissionsfromtheoxidationovensarebasedon2013sourcetestatRTOoutletplusemissionsforthebackupheater.NOXemissionsfromthefurnaces(i.e.,TO)arebasedonsite‐specificdata.

bPM10/PM2.5emissionlimitsforLines3‐6arefromPSDPermit14‐02.cApprovalOrderNo.15AQ‐E636didnotestablishlimitsforHCN,acrylonitrile,andammoniaforSCRBypassMode.HourlyemissionsforthesepollutantsprovidedherearebasedonoriginalPSDapplication.

2.3.6. Standby Mode

TheRTOandTOaremaintainedatanormaloperatingtemperaturebetweencampaignsintheStandbyMode.EmissionsareonlyexpectedfromthenaturalgascombustionattheRTOheatersandtheTOheater,sincethefurnacesareelectricallyheated.SCRisnotoperationalinthismode.SinceemissionsfromtheStandbyModeareexpectedtobelowerthanNormalOperationModeemissions,itisconsideredpartoftheNormalOperationalModefordeterminingPTE.

2.3.7. Emergency Generators and Fire Pumps

Emissionsfromthe10naturalgas‐firedemergencygeneratorsforLines1and2andthe2naturalgas‐firedenginesforthefirepumpsarecalculatedbasedon40CFRSubpartJJJJlimitsforNOX,CO,andVOC,andarebasedonAP‐42,Table3.2‐3emissionfactorsforotherpollutants.Onannualbasis,the10emergencygeneratorswillbeoperatedfornogreaterthan340hoursperyear,andthe2firepumpswillbeoperatedfornogreaterthan76hoursperyear,includingtestingandemergencyoperations.

Emissionsfromthe4diesel‐firedemergencygeneratorsforLines3through6arecalculatedbasedonvendordataformeetingTier4emissionstandardsunder40CFRSubpartIIIIforNOX,CO,VOCandPMwithadd‐oncontrols.OtherpollutantemissionsarebasedonAP‐42,Section3.4emissionfactors.Thecalculationmethodologyhasnotchanged,onlythetotalnumberofengines.ThefollowingmethodologiesareusedtocalculatethePTEfortheseemergencygenerators:

Ittakesapproximately10minutesforenginestostartup;therefore,coldstartemissionsareaccountedforusinguncontrolledemissionratesforthefirst10minutesinanhour.Theuncontrolledemissionratesareprovidedbytheenginevendor.

Theenginemaybeoperatedat70%duringnormaloperation,orat100%loadduringperformancetestandemergencyuse.Inordertoallowmaximumoperationalflexibility,thehigherresultanthourlyemissionrateat70%loadand100%usingload‐specificemissionfactorsprovidedbythevendorareusedtodeterminethehourlyemissionsoutsideofthecoldstartperiod.

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Theroutinequarterlytestis2hourspertest,andonlyoneenginewillbetestedatthesametime.However,all4enginesmaybetestedinthesameday.Totalroutinequarterlytestwillbe32hoursperyearforallengines.Coldstartemissionsareaccountedforinthefirsthourofthetestforeachengine.

Therewillbeoneenginebeingtestedduringarequiredperformancetestingevery60months.Performancetestingwilllast8hours,anditwillstartfollowingaroutinequarterlytesting.Therefore,nocold‐startemissionsareaccountedforperformancetesting.Performancetestingwillbe8hourperyearatmaximumforallengineswithoneenginebeingtested.

Emergencyoperationisneededduringpoweroutage,andmayincludecoldstart.Therefore,coldstartemissionsareaccountedforinthefirsthouroftheevent.Itisassumedthattheemergencyoperationwillnotbegreaterthan8hoursperyearperengine.

Facility‐wideemissionssummaryareprovidedinTable2‐5,andarecomparedtotheTitleVandPSDmajorsourcethresholds.NotethatSGLisrequestingasyntheticminorlimitforNOXat90tpy;therefore,theNOXemissionsforeachemissionunitarenotpresented.

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Table2‐5.Facility‐WidePTE

EmissionUnitsPM PM10 PM2.5 SO2 NOx VOC CO CO2e

SingleHAP

TotalHAPs

(tpy) (tpy) (tpy) (tpy) (tpy) (tpy) (tpy) (tpy) (tpy) (tpy)Line1a 4.82 13.14 13.14 3.01 ‐‐ 7.42 5.79 7,215 6.14 6.33

Line2a 4.82 13.14 13.14 3.01 ‐‐ 7.42 5.79 7,215 6.17 6.36

Lines3‐6b 19.27 52.56 52.56 12.02 ‐‐ 29.70 23.16 28,858 24.67 25.44

Lines1‐2EGENsc 3.38E‐03 1.38E‐02 1.38E‐02 5.10E‐04 ‐‐ 0.17 0.68 39 ‐‐ 1.15E‐02

Lines3‐6EGENsc 7.82E‐03 4.08E‐03 4.08E‐03 1.28E‐03 ‐‐ 1.05E‐02 0.16 113 ‐‐ 1.09E‐03

FirewaterPumpEGENsc 1.51E‐03 3.08E‐03 3.08E‐03 1.14E‐04 ‐‐ 0.04 0.15 17 ‐‐ 5.14E‐03

Pre‐OxidationOvensd 1.96E‐04 5.54E‐04 5.54E‐04 3.15E‐04 ‐‐ 3.33E‐03 3.93E‐03 ‐‐ 1.37E‐02 1.38E‐02

TOTALe 29 79 79 18 90 45 36 43,457 37 38PSDMajorSource

Thresholdf 100 100 100 100 100 100 100 ‐‐ ‐‐ ‐‐

TitleVMajorSourceThresholdg

‐‐ 100 100 100 100 100 100 ‐‐ 10 25

aThePTEforLines1and2arebasedontheconfigurationsoftheproductionslinesandapplicableemissionlimitsfromApprovalOrderNo.15AQ‐E636.TheexhaustflowratesforLine2aredifferentthanLine1;therefore,emissionsforthesetwolinesarecalculatedseparately.SGLdoesnotoperatethesecondRTOinstandby,buttheemissionsfromthesecondRTOareconservativelyincludedforPTEpurposes.

bLines3‐6havethesameexhaustflowratesasLine2.However,Lines3‐6aresubjecttoBACTlimitsestablishedinPSDPermit14‐02.PTEemissionsfortheselinesarebasedonemissionlimitsinPSDPermit14‐02andApprovalOrderNo.15AQ‐E636,inadditiontopubliclyavailableemissionfactorsforpollutantswithoutanyemissionlimit.SGLdoesnotoperatethesecondRTOinstandby,buttheemissionsfromthesecondRTOareconservativelyincludedforPTEpurposes.

cEmergencygeneratorandfirewaterpumpengineemissionsarebasedonthesameassumptionsmadeintheoriginalPSDapplicationforPSDPermit14‐02,butrevisedtoreflecttheemissionlimitsinPSDPermit14‐02andApprovalOrderNo.15AQ‐E636whereapplicable.

dPre‐oxidationovensemissionsareconsistentwithoriginalPSDapplicationforPSDpermit14‐02.eSGLalsousesepoxyresin;however,noVOCorHAPareemittedbasedonSDSdata.SGLrequestsforasyntheticminorNOXemissionlimitof90tpy.fPSDmajorsourcethresholdsareobtainedfrom40CFR52.21(b)(1)(i)(a).Greenhousesgases(GHG)isnotsubjecttoPSDreviewifPSDreviewistriggeredforanyotherpollutant.EcologystatedthatSGLisafacilitysubjectto100tpythresholdsforPSDpurposesinaresponseonSeptember10,2018.

gTitleVmajorsourcethresholdsareobtainedfromWAC173‐401‐200.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application Trinity Consultants 3-1

3. REQUESTED PERMIT CHANGES

3.1. PROPOSED LIMITS

SGLissubmittingthisNOCapplicationtoremoveLines7‐10fromtheApprovalOrderNo.15AQ‐E636,sinceitisnotinSGL’splantoconstructthesepermittedlines.Additionally,SGLisrequestingasyntheticminoremissionlimitforNOXemissionsat90tpy.TheMosesLakeFacilitywillremainamajorsourceofHAPduetopotentialHCNemissionsbeinghigherthan10tpy,asshowninTable2‐5.SGLsubmittedaTitleVairoperatingpermitapplicationinSeptember2016fortheMosesLakeFacility,buthasnotreceivedanissuedTitleVoperatingpermit.SGLrequeststheproposedchangestobeincludedintheTitleVoperatingpermittobeissuedbyEcology.

AsdiscussedinSection2.3,theshort‐termhourlyemissionsforeachproductionlineandemissionsfromtheemergencygeneratorsandfirepumpswillremainunchangedasthoseinthePSDPermit14‐02andApprovalOrderNo.15AQ‐E636.However,PSDPermit14‐02andApprovalOrderNo.15AQ‐E636alsosetannualemissionlimitsforLines3‐10.WithremovingLines7‐10,SGLproposestoupdatetheannualemissionlimitsforLines3‐6.Lines1‐2limitswillremainunaffected.TheproposedrevisedemissionlimitsaresummarizedinTable3‐1.

Table3‐1.ProposedLimits

CurrentEmissionLimit SourceofLimit ProposedLimit467tonsNOXper12‐monthrollingperiod;Lines3‐10andassociatedequipment

ConditionVII.A.,PSDPermit14‐02 90tonsNOXper12‐monthrollingperiod,facility‐wide

39tonsPMper12‐monthrollingperiod;Lines3‐10andassociatedequipment

ConditionVII.A.,PSDPermit14‐02None;PMisnotapermittedpollutant

90tonsPM10/PM2.5per12‐monthrollingperiod;Lines3‐10andassociatedequipment

ConditionVII.A.,PSDPermit14‐0253tonsPM10/PM2.5per12‐monthrollingperiod;Lines3‐6andassociatedequipment

60tonsVOCper12‐monthrollingperiod;Lines3‐10andassociatedequipment

ConditionVII.A.,PSDPermit14‐0230tonsVOCper12‐monthrollingperiod;Lines3‐6andassociatedequipment

47tonsCOper12‐monthrollingperiod;Lines3‐10andassociatedequipment

Condition7.7,ApprovalOrderNo.15AQ‐E636

25tonsCOper12‐monthrollingperiod;Lines3‐6andassociatedequipment

25tonsSO2per12‐monthrollingperiod;Lines3‐10andassociatedequipment

Condition7.7,ApprovalOrderNo.15AQ‐E636

12tonsSO2per12‐monthrollingperiod;Lines3‐6andassociatedequipment

408.5poundsacrylonitrileper12‐monthrollingperiod;Lines3‐10andassociatedequipment

Condition7.7,ApprovalOrderNo.15AQ‐E636

204.2poundsacrylonitrileper12‐monthrollingperiod;Lines3‐6andassociatedequipment

595poundsammoniaperday;Lines3‐10andassociatedequipment

Condition7.7,ApprovalOrderNo.15AQ‐E636

302 poundsperday;Lines3‐6 andassociatedequipment

310poundsHCNperday;Lines3‐10andassociatedequipment

Condition7.7,ApprovalOrderNo.15AQ‐E636

177 poundsperday;Lines3‐6 andassociatedequipment

3.2. REQUEST FOR SYNTHETIC MINOR PERMIT LIMIT

SGLrequestsforasyntheticminorlimitof90tpyNOXfortheMosesLakeFacility.EventhoughthepotentialNOXemissionsforLines1‐6arehigherthan90tpy,theactualNOXemissionsaremuchlowerthan90tons.Table3‐2

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application Trinity Consultants 3-2

showsthefacility‐wideannualNOXemissionssince2014andwhichlineswereoperatinginthegivenyear.2012and2013onlyhadLines1and2operatingpriortotheinstallationofSCRanddonotreflectcurrentoperations.

Table3‐2.Facility‐WideAnnualNOXEmissions

Year LinesOperating

Facility‐WideNOXEmissions(tpy)

2014 Lines1,2,3,4 402015 Lines1,2,3,4,5 452016 Lines3,4,5 302017 Lines3,4,5 36

Additionally,SGLhasreviewedtheContinuousEmissionRateMonitoring(CERM)datainstalledonLines1‐5fromJanuary2014throughOctober2018.AcopyoftheNOXCERMsummarydataisprovidedinAppendixC.SGLfoundthefollowingbasedontheCERMdatareview:

Thelb/hrNOXemissionsweretypicallywellbelow8.5lb/hrlimitforNormalOperationMode.Themonthlyaveragelb/hrNOXemissionrateacrossalllinesintheperiodrangesfrom0.03to5.26lb/hr,whicharewellbelowthe8.5lb/hrlimit.

Onannualbasis,themaximumacrosslinesandperiodreviewedofannuallb/hraverageNOXemissionrateis3.19lb/hr.Assumingcontinuousoperationwiththisrate,theannualNOXemissionsforeachlinewillbeapproximately14tpy,andwillbe84tpyfor6lines,whichisstillbelow90tpy.

Basedonthedatareviewed,theactualNOXemissionsfromtheMosesLakeFacilitywillbeabletokeepbelow90tpy,andrequestsforasyntheticminorNOXlimitat90tpy.8

3.3. OTHER MISCELLANEOUS CHANGES

SGLproposesthefollowingchangestoApprovalOrderNo.15AQ‐E636:

ChangethecompanynameandpermitholdernametoSGLCompositesLLC,andreplaceSGLAutomotiveCarbonFibersLLCorSGLACFwith“SGL”.

RemoveConditions4and11.2forthelandpurchaserequirement.AdditionallandwillnotbepurchasedbecauseLines7‐10willnotbeconstructed.9

UpdateConditions8.3and9toincluderequirementsforLines3‐6inadditiontothoseforLines1‐2only. RemoveallconditionsorrelevantconditiontermscoveringLines7‐10.

8AstacktestisexpectedforJanuaryorearlyFebruary2019toverifythattheincreasespeeddidnotimpactshort‐termemissionratesagainstcurrentpermitlimits.

9AccordingtoTSDforApprovalOrderNo.14AQ‐E586,theASILexceedanceforacrylonitrilewilloccurifLine8isaddedtotheoperation.PurchaseofimpactedpropertywasproposedbySGLatthattime.Therefore,emissionsfromLines3‐6willnotresultinanyASILexceedanceforacrylonitrile,andlandpurchasewouldnotbenecessarytodemonstrateTAPcompliance.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application Trinity Consultants 4-1

4. REGULATORY REVIEW

Thefollowingsectionsidentifytheregulatoryrequirementsapplicabletothisapplication.

4.1. PSD APPLICABILITY

PSDisthemajorNewSourceReviewpermittingprogramforattainmentpollutants.TheMosesLakefacilityislocatedinGrantCounty,whichisdesignatedasanattainmentareaforallcriteriapollutants.ThefacilitywasclassifiedasamajorsourceunderthePSDprogramandthecurrentPSDPermit14‐02wasissuedinApril2015.WiththisNOCapplication,SGLisrequestingasyntheticminorNOXemissionlimitat90tpy.AsshowninTable2‐5,thePTEfortheMosesLakeFacilityisbelowthemajorsourcethresholdforpollutantsotherthanNOX.SGLrequestsanorderofapprovaltobeissuedtosupersedePSDPermit14‐02byincorporatingallapplicablerequirementsandlimitsfromPSDPermit14‐02.AseparatelettertoEcologyheadquarterswillbesubmittedrequestingPSDPermit14‐02tobecomevoidwiththeissuanceoftherevisedOA.

4.2. TITLE V OPERATING PERMIT APPLICABILITY

ATitleVoperatingpermitisrequiredforanymajorsourcedefinedunderWAC173‐401‐200.AsshowninTable2‐5,theMosesLakeFacilitywillcontinuetohavethepotentialtoemitmorethan10tpyofHCN,whichisaHAP.Therefore,theMosesLakeFacilitywillcontinuetobeconsideredamajorsourceofHAP,andrequiresaTitleVoperatingpermit.SGLhassubmittedtheinitialTitleVoperatingpermitapplicationinSeptember2016,buthasnotreceivedafinalpermitfromEcology.SGLrequeststheTitleVoperatingpermittobeissuedtoreflectthecorrectemissionunitsandemissionlimitsfortheMosesLakeFacility.

4.3. FEDERAL STANDARDS

WAC173‐400‐115adoptsfederalNewSourcePerformanceStandards(NSPS)byreference.NSPSapplytocertaintypesofequipmentthatarenewlyconstructed,modified,orreconstructedafteragivenapplicabilitydate.Sincenophysicalmodificationofanyequipmentistakingplace,therewillbenochangetoNSPSapplicabilityorrequirementstotheexistingequipment.

NationalEmissionStandardsforHazardousAirPollutants(NESHAPs)havebeenestablishedin40CFRPart61andPart63tocontrolemissionsofHazardousAirPollutants(HAP)fromstationarysources.ThispermittingapplicationdoesnotimpactexistingrequirementsortriggeranyadditionalNESHAPrequirementsatthefacility.

4.4. BEST AVAILABLE CONTROL TECHNOLOGY

Atop‐downBestAvailableControlTechnology(BACT)analysiswascompletedaspartoftheoriginalPSDapplicationreviewbackin2014.ForthisapplicationtorevisetheApprovalOrderNo.15AQ‐E636,aBACTreviewfocusingonanypotentialchangesorupdatestotherelevantBACTinformationisperformedinordertoconfirmthattheconclusionsoftheoriginalBACTdeterminationpresentedinPSDPermit14‐02forLines3to6,andcurrentrequirementsforLines1‐2inApprovalOrderNo.15AQ‐E636areappropriate.

ThefocusofthisapplicationistoconfirmthattheBACTdeterminationinPSDPermit14‐02andApprovalOrderNo.15AQ‐E636wouldbeunchanged.TheBACTdeterminationsinPSDPermit14‐02wereestablishedbasedoncosteffectivenesscalculationsintermsofcostpertonsofpollutantsremovedforLines3‐6.TheBACTdeterminationsinApprovalOrderNo.15AQ‐E636arefromtheApprovalOrderNo.10AQ‐E362forLines1‐2whicharealsobasedoncosteffectivenesscalculations.Becausethisapplicationdoesnotchangetheemission

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application Trinity Consultants 4-2

ratesinthepermit,thecostpertonvaluesinthepreviousanalysesarealsounchanged.Therefore,theassumptionsusedinPSDPermit14‐02andApprovalOrderNo.10AQ‐E362remainvalidwiththispermittingaction,andnoupdatestotheBACTlimitsarenecessary.

Thoughnotnecessarytore‐validatetheoriginalBACTanalyses,recentBACTdeterminationswerereviewedandnonewtechnologieswereimplementedasBACTsincePSDPermit14‐02wasissued.ThatreviewisincludedasbackgroundinformationinAppendixD.

4.5. AIR QUALITY ANALYSIS

AnairqualityanalysishasbeenperformedaspartofthePSDPermit14‐02evaluation,including:

Acumulativeregionalanalysiswasalsoperformedaspartoftheairqualityanalysisatthattime,includingproposedproductionlines(Lines3‐10),existingproductionlines(Lines1‐2),plusbackgroundaccountingforneighboringfacilitiesatthattimetocomparetotheNAAQSforNO2,PM10,andPM2.5.

Amodelinganalysisontheproposedproductionlines(Lines3‐10)andassociatedequipmenttocomparedtotheSignificantImpactLevels(SILs)forNO2,PM10,PM2.5,CO,andSO2.

AnincrementalanalysisforNO2,PM10,andPM2.5tocomparetotheClassIIPSDincrements.

Theconclusionfortheprojectwas“nosignificantadverseimpactonairquality.”10BecausetheairqualityimpactsofthefacilitywillbeimprovedbyremovingLines7‐10fromthepermit,thisconclusionwillcontinuetobevalidwiththispermittingaction.

TheTSDforPSDPermit14‐02presentedthePSDIncrementandNAAQSresultsinTables4‐1and4‐2.

Table4‐1.IncrementAnalysis

Pollutant Avg.Period

MaximumModeledConcentration

(µg/m3)

ClassIIPSDIncrement(µg/m3)

NO2 Annual 5.8 25PM10 24‐hr 8.97 30

PM2.524‐hr 8.97 9.0Annual 1.9 4.0

Table4‐2.NAAQSAnalysis

CriteriaPollutant Avg.Period

MaximumConcentration(Facility)

(µg/m3)Background(µg/m3)

Total(µg/m3)

Standard(µg/m3)

NO21‐hr 89.8 16.0 105.8 188Annual 6.4 2.8 9.2 100

PM10 24‐hr 11.4 92 103.4 150

PM2.524‐hr 11.8 19.4 31.2 35Annual 3.3 6.5 9.8 12

10Section9oftheTSDforPSDPermit14‐02.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application A-1 Trinity Consultants

APPENDIX A: APPLICATION FORM AND ASSOCIATED DOCUMENTS

Notice of Construction Application

ECY 070-410 (Rev. 11/2016) Page 1 of 6

A notice of construction permit is required before installing a new source of air pollution or modifying an existing source of air pollution. This application applies to facilities in Ecology’s jurisdiction. Submit this application for review of your project. For general information about completing the application, refer to Ecology Forms ECY 070-410a-g, “Instructions for Ecology’s Notice of Construction Application.” Ecology offers up to 2 hours of free pre-application help. We encourage you to schedule a pre-application meeting with the contact person specified for the location of your proposal (see below). For more help than the initial 2 free hours, submit Part 1 of the application and the application fee. You may schedule a meeting with us at any point in the process.

Completing the application, enclose it with a check for the initial fee and mail to:

To request ADA accommodation, call (360) 407-6800, 711 (relay service), or 877-833-6341 (TTY).

Check the box for the location of your proposal. For help, call the contact listed below. Ecology Permitting Office Contact

CRO

Chelan, Douglas, Kittitas, Klickitat, or Okanogan County Ecology Central Regional Office – Air Quality Program

Lynnette Haller (509) 457-7126

lynnette.haller@ecy.wa.gov

ERO

Adams, Asotin, Columbia, Ferry, Franklin, Garfield, Grant, Lincoln, Pend Oreille, Stevens,

Walla Walla, or Whitman County Ecology Eastern Regional Office – Air Quality Program

Jolaine Johnson (509) 329-3452

jolaine.johnson@ecy.wa.gov

NWRO

San Juan County Ecology Northwest Regional Office – Air Quality Program

Dave Adler (425) 649-7267

david.adler@ecy.wa.gov

IND

Kraft and Sulfite Paper Mills and Aluminum Smelters Ecology Industrial Section – Waste 2 Resources Program

Permit manager: ____________________________________

James DeMay (360) 407-6868

james.demay@ecy.wa.gov

NWP

U.S. Department of Energy Hanford Reservation Ecology Nuclear Waste Program

Phil Gent (509) 372-7983

phil.gent@ecy.wa.gov

WA Department of Ecology Cashiering Unit P.O. Box 47611 Olympia, WA 98504-7611

For Fiscal Office Use Only: 001-NSR-216-0299-000404

Notice of Construction Application

ECY 070-410 (Rev. 11/2016) Page 2 of 6

Check the box for the fee that applies to your application.

New project or equipment

$1,500: Basic project initial fee covers up to 16 hours of review

$10,000: Complex project initial fee covers up to 106 hours of review

Change to an existing permit or equipment

$200: Administrative or simple change initial fee covers up to 3 hours of review Ecology may determine your change is complex during completeness review of your application. If your project is complex, you must pay the additional $675 before we will continue working on your application.

$875: Complex change initial fee covers up to 10 hours of review

$350 flat fee: Replace or alter control technology equipment (WAC 173-400-114) Ecology will contact you if we determine your change belongs in another fee category. You must pay the fee associated with that category before we will continue working on your application.

Read each statement, then check the box next to it to acknowledge that you agree.

The initial fee you submitted may not cover the cost of processing your application. Ecology will track the number of hours spent on your project. If the number of hours Ecology spends exceeds the hours included in your initial fee, Ecology will charge you $95 per hour for the extra time.

You must include all information in this application. Ecology may not process your application if it does not include all the information requested.

Submittal of this application allows Ecology staff to inspect your facility.

Notice of Construction Application

ECY 070-410 (Rev. 11/2016) Page 4 of 6

Part 2: Technical Information The Technical Information may be sent with this application to the Ecology Cashiering Unit, or may be sent directly to the appropriate Ecology office along with a copy of this application. For all sections, check the box next to each item as you complete it.

III. Project Description Attach the following to your application:

Description of your proposed project Projected construction start and completion dates Operating schedule and production rates List of all major process equipment with manufacturer and maximum rated capacity Process flow diagram with all emission points identified Plan view site map Manufacturer specification sheets for major process equipment components Manufacturer specification sheets for pollution control equipment Fuel specifications, including type, consumption (per hour and per year), and percent sulfur

IV. State Environmental Policy Act (SEPA) Compliance Check the appropriate box below.

SEPA review is complete. Include a copy of the final SEPA checklist and SEPA determination (e.g., DNS, MDNS, EIS) with your application.

SEPA review has not been conducted.

If SEPA review will be conducted by another agency, list the agency. You must provide a copy of the final SEPA checklist and SEPA determination before Ecology will issue your permit.

Agency Reviewing SEPA:

_________________________________________________________________

If SEPA review will be conducted by Ecology, fill out a SEPA checklist and submit it with your application. You can find a SEPA checklist online at http://www.ecy.wa.gov/programs/sea/sepa/forms.htm.

Notice of Construction Application

ECY 070-410 (Rev. 11/2016) Page 5 of 6

V. Emissions Estimations of Criteria Pollutants Does your project generate air pollutant emissions? Yes No

If yes, provide the following information about your air pollutant emissions:

Air pollutants emitted, such as carbon monoxide (CO2), lead (Pb), nitrogen dioxide (NO2), ozone (O3), and volatile organic compounds (VOC), particulate matter (PM2.5, PM10, TSP), sulfur dioxide (SO2)

Potential emissions of criteria air pollutants in tons per hour, tons per day, and tons per year (include calculations)

Fugitive air pollutant emissions – pollutant and quantity

VI. Emissions Estimations of Toxic Air Pollutants Does your project generate toxic air pollutant emissions? Yes No

If yes, provide the following information about your toxic air pollutant emissions:

Toxic air pollutants emitted (specified in WAC 173-460-1501)

Potential emissions of toxic air pollutants in pounds per hour, pounds per day, and pounds per year (include calculations)

Fugitive toxic air pollutant emissions - pollutant and quantity

VII. Emission Standard Compliance Does your project comply with all applicable standards identified? Yes No

Provide a list of all applicable new source performance standards, national emission standards for hazardous air pollutants, national emission standards for hazardous air pollutants for source categories, and emission standards adopted under the Washington Clean Air Act, Chapter 70.94 RCW.

VIII. Best Available Control Technology Provide a complete evaluation of Best Available Control Technology (BACT) for your proposal.

1 http://apps.leg.wa.gov/WAC/default.aspx?cite=173-460-150

Notice of Construction Application

ECY 070-410 (Rev. 11/2016) Page 6 of 6

IX. Ambient Air Impacts Analyses Does your project cause or contribute to a violation of any ambient air quality standard or acceptable source impact level? Yes No Provide the following:

Ambient air impacts analyses for criteria air pollutants (including fugitive emissions)

Ambient air impacts analyses for toxic air pollutants (including fugitive emissions)

Discharge point data for each point included in ambient air impacts analyses (include only if modeling is required)

Exhaust height Exhaust inside dimensions (diameter or length and width) Exhaust gas velocity or volumetric flow rate Exhaust gas exit temperature Volumetric flow rate Discharge description (i.e., vertically or horizontally) and if there are any obstructions (e.g., raincap)

Emission unit(s) discharging from the point Distance from the stack to the nearest property line Emission unit building height, width, and length Height of tallest building on-site or in the vicinity, and the nearest distance of that building to the exhaust

Facility location (urban or rural)

SGL Composites LLCMoses Lake Facility

Process Operating Modes (Lines 1 – 6)

Green = Normal Operating Mode Blue = Shutdown Mode Orange = RTO Bypass Mode Purple = SCR Bypass Mode

Note that the oxidation ovens at Line 1 do not vent to atmosphere directly in the Shutdown Mode, but to the main stack for Line 1.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application B-1 Trinity Consultants

APPENDIX B: EMISSION CALCULATIONS

SGL‐MosesLakeFacilityTable1a.FacilityPotentialtoEmit

PM PM10 PM2.5 SO2 NOx VOC CO CO2e SingleHAP TotalHAPs(tpy) (tpy) (tpy) (tpy) (tpy) (tpy) (tpy) (tpy) (tpy) (tpy)

Line1a 4.82 13.14 13.14 3.01 ‐‐ 7.42 5.79 7,215 6.14 6.33Line2a 4.82 13.14 13.14 3.01 ‐‐ 7.42 5.79 7,215 6.17 6.36

Lines3‐6b 19.27 52.56 52.56 12.02 ‐‐ 29.70 23.16 28,858 24.67 25.44Lines1‐2EGENsc 3.38E‐03 1.38E‐02 1.38E‐02 5.10E‐04 ‐‐ 0.17 0.68 39 ‐‐ 1.15E‐02Lines3‐6EGENsc 7.82E‐03 4.08E‐03 4.08E‐03 1.28E‐03 ‐‐ 1.05E‐02 0.16 113 ‐‐ 1.09E‐03

FirewaterPumpEGENsc 1.51E‐03 3.08E‐03 3.08E‐03 1.14E‐04 ‐‐ 0.04 0.15 17 ‐‐ 5.14E‐03Pre‐OxidationOvensd 1.96E‐04 5.54E‐04 5.54E‐04 3.15E‐04 ‐‐ 3.33E‐03 3.93E‐03 ‐‐ 1.37E‐02 1.38E‐02

TOTALe 29 79 79 18 90 45 36 43,457 37 38

PSDMajorSourceThresholdf 100 100 100 100 100 100 100 ‐‐ ‐‐ ‐‐a

b

c

d

e

f SGLisconsideredachemicalmanufacturingfacilitywithSICcode2823accordingtoEcology'sdeterminationonSeptember10,2018.Themajorsourcethresholdis100tpyinaccordanceto40CFR62.21(b)(1)(i)(a).GHGisnotsubjecttoPSDreviewifthefacilityisnotaPSDsourceforanyotherregulatedpollutant.

EmissionUnits

ThePTEforLines1and2arebasedontheconfigurationsoftheproductionslinesandapplicableemissionlimitsfromApprovalOrderNo.15AQ‐E636.TheexhaustflowratesforLine2aredifferentthanLine1;therefore,emissionsforthesetwolinesarecalculatedseparately.SGLdoesnotnormallyoperatethesecondRTOinStandbyModeanymore,buttheemissionsforthesecondRTOareconservativelyincludedforPTEpurposes.

Lines3‐6havethesameexhaustflowratesasLine2.However,Lines3‐6aresubjecttoBACTlimitsestablishedinPSDPermit14‐02.PTEemissionsfortheselinesarebasedonemissionlimitsinPSDPermit14‐02andApprovalOrderNo.15AQ‐E636,inadditiontopubliclyavailableemissionfactorsforpollutantswithoutanyemissionlimit.SGLdoesnotnormallyoperatethesecondRTOinStandbyModeanymore,buttheemissionsforthesecondRTOareconservativelyincludedforPTEpurposes.

EmergencygeneratorandfirewaterpumpengineemissionsarebasedonthesameassumptionsmadeintheoriginalPSDapplicationforPSDPermit14‐02,butrevisedtoreflecttheemissionlimitsinPSDPermit14‐02andApprovalOrderNo.15AQ‐E636whereapplicable.

Pre‐oxidationovensemissionsareconsistentwithoriginalPSDapplicationforPSDpermit14‐02.

SGLalsousesepoxyresin;however,noVOCorHAPemissionsareemittedbasedonSDSdata.SGLrequestsasyntheticminorlimitof90tpyNOX.

SGLMosesLakeFacilityPTELines1‐6

Table2a.AnnualOperationsInputs

NormalModew/SCR SCRBypass

Shutdownrate

RTOBypass

NormalModew/SCR SCRBypass

Shutdownrate

RTOBypass

NormalModew/SCR SCRBypass

Shutdownrate

RTOBypass

Lines1‐2EGENs

Lines3‐6EGENsb

FirewaterPumpEGENs

Pre‐OxidationOvensa

hr/day 24 24 0.025 1.5 24 24 0.025 1.5 24 24 0.025 1.5 0.5 2 4hr/yr 8760 100 9.125 4.5 8760 100 9.125 4.5 8760 100 9.125 4.5 34 16 38#Units/yr 1 1 1 1 1 1 1 1 4 4 4 4 10 4 2 5aPre‐oxidationovensarepermittedtobenomorethan50unitsaccordingtoCondition2.4of15AQ‐E636.Theemissionsarecalculatedbasedonagroupof10ovens,soamultiplierof5isusedhere.bLines3‐6EGENswillhaveatotalof16hrsperengineasindicatedplusanadditional8hrsforperformancetestingperyearforoneEGENperyear.

Table2b.CriteriaPollutantsAnnualEmissions

Normal SCRBypassRTO

ShutdownRTOBypass TOTALa Normal SCRBypass

RTOShutdown

RTOBypass TOTALa Normal SCRBypass

RTOShutdown

RTOBypass TOTALa

Lines1‐2EGENs

Lines3‐6EGENs

FirewaterPumpEGENs

AmmoniumBicarbonate

Pre‐OxidationOvens

10102‐44‐0 NOX 37.23 0.90 0.04 0.02 37.70 37.23 0.90 0.04 0.02 37.70 148.92 3.58 0.16 0.08 150.80 0.34 0.16 0.08 3.93E‐03630‐08‐0 CO 5.79 0.07 6.03E‐03 2.97E‐03 5.79 5.79 0.07 6.03E‐03 2.97E‐03 5.79 23.16 0.26 0.02 1.19E‐02 23.16 0.68 0.16 0.15 3.93E‐037446‐09‐05 SO2 3.01 0.03 3.13E‐03 1.54E‐03 3.01 3.01 0.03 3.13E‐03 1.54E‐03 3.01 12.02 0.14 1.25E‐02 6.18E‐03 12.02 5.10E‐04 1.28E‐03 1.14E‐04 3.15E‐04PM PM(Filt.) 4.82 0.06 5.02E‐03 2.48E‐03 4.82 4.82 0.06 5.02E‐03 2.48E‐03 4.82 19.27 0.22 0.02 9.90E‐03 19.27 3.38E‐03 7.82E‐03 1.51E‐03 1.96E‐04PM10 PM10(Filt.&Cond.) 13.14 0.15 1.37E‐02 6.75E‐03 13.14 13.14 0.15 1.37E‐02 6.75E‐03 13.14 52.56 0.40 0.05 0.02 52.56 1.38E‐02 4.08E‐03 3.08E‐03 5.54E‐04PM2.5 PM2.5(Filt.&Cond.) 13.14 0.15 1.37E‐02 6.75E‐03 13.14 13.14 0.15 1.37E‐02 6.75E‐03 13.14 52.56 0.40 0.05 0.02 52.56 1.38E‐02 4.08E‐03 3.08E‐03 5.54E‐04VOC VOC 7.38 0.08 0.03 0.02 7.42 7.38 0.08 0.03 0.02 7.42 29.54 0.34 0.13 0.08 29.70 0.17 1.05E‐02 0.04 3.33E‐03CO2e CO2e 7,215 82 8 4 7,215 7,215 82 8 4 7,215 28,858 329 30 15 28,858 39 113 17 0.00E+00

Line1 Lines3,4,5,and6Line2

CompoundCAS

Line1 Lines3,4,5,and6Line2

tpytpytpytpy

aBecauseproposedpotentialemissionsduringNormalModearenotlimitedbelow8,760,proposedannualemissionsduringalternatemodesareonlyaccountedforasthenetincreaseaboveNormalModeemissionratesduringtheallowedtimeperiod.ApartfromNOxemissionsduringSCRBypassmodeandVOCemissionsduringRTOShutdownandRTOBypass,nootherpollutantisemittedinratesthatexceedthoseduringNormalMode.

bSGLalsousesepoxyresinatthefacility;however,noVOCorTAP/HAPcontentispresentintheresinusedperSDSdata.

Unitstpytpytpytpy

SGLMosesLakeFacilityPTELines1‐6Table2c.ToxicAirPollutantsandHazardousAirPollutantsAnnualEmissions

HAP? TAP? Normal SCRBypassRTO

ShutdownRTOBypass TOTALa Normal SCRBypass

RTOShutdown

RTOBypass TOTALa Normal SCRBypass

RTOShutdown

RTOBypass TOTALa

Lines1‐2EGENs

Lines3‐6EGENs

FirewaterPumpEGENs

AmmoniumBicarbonate

Pre‐OxidationOvens

75‐07‐0 Acetaldehyde Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 9.92E‐04 1.74E‐05 4.43E‐04 ‐‐107‐02‐8 Acrolein Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 9.35E‐04 5.44E‐06 4.18E‐04 0.00E+00107‐13‐1 Acrylonitrile Yes Yes 0.02 2.80E‐04 4.70E‐04 3.89E‐04 0.03 0.02 2.80E‐04 6.19E‐04 3.89E‐04 0.03 0.10 1.12E‐03 2.48E‐03 1.56E‐03 0.10 ‐‐ ‐‐ ‐‐ 8.00E‐057664‐41‐7 Ammonia No Yes 13.25 0.03 0.04 0.02 13.29 13.25 0.03 0.05 0.02 13.30 53.01 0.13 0.18 0.09 53.19 ‐‐ ‐‐ ‐‐ 0.25 4.39E‐037803‐63‐6 AmmoniumBisulfate No Yes 13.14 ‐‐ 1.37E‐02 ‐‐ 13.14 13.14 ‐‐ 1.37E‐02 ‐‐ 13.14 52.56 ‐‐ 0.05 ‐‐ 52.56 ‐‐ ‐‐ ‐‐ 0.00E+007783‐20‐2 AmmoniumSulfate No Yes 13.14 ‐‐ 1.37E‐02 ‐‐ 13.14 13.14 ‐‐ 1.37E‐02 ‐‐ 13.14 52.56 ‐‐ 0.05 ‐‐ 52.56 ‐‐ ‐‐ ‐‐ 0.00E+007440‐38‐2 Arsenic Yes Yes 1.64E‐05 1.87E‐07 1.70E‐08 8.40E‐09 1.64E‐05 1.64E‐05 1.87E‐07 1.70E‐08 8.40E‐09 1.64E‐05 6.54E‐05 7.47E‐07 6.81E‐08 3.36E‐08 6.54E‐05 ‐‐ ‐‐ ‐‐ 9.47E‐1071‐43‐2 Benzene Yes Yes 7.36E‐04 8.41E‐06 7.67E‐07 3.78E‐07 7.36E‐04 7.36E‐04 8.41E‐06 7.67E‐07 3.78E‐07 7.36E‐04 2.95E‐03 3.36E‐05 3.07E‐06 1.51E‐06 2.95E‐03 5.62E‐04 5.36E‐04 2.51E‐04 9.94E‐097440‐41‐7 Beryllium Yes Yes 9.81E‐07 1.12E‐08 1.02E‐09 5.04E‐10 9.81E‐07 9.81E‐07 1.12E‐08 1.02E‐09 5.04E‐10 9.81E‐07 3.92E‐06 4.48E‐08 4.09E‐09 2.02E‐09 3.92E‐06 ‐‐ ‐‐ ‐‐ 5.68E‐1174‐83‐9 Bromomethane Yes Yes 7.67E‐04 8.75E‐06 7.98E‐07 3.94E‐07 7.67E‐04 7.67E‐04 8.75E‐06 7.98E‐07 3.94E‐07 7.67E‐04 3.07E‐03 3.50E‐05 3.19E‐06 1.58E‐06 3.07E‐03 ‐‐ ‐‐ ‐‐ 0.00E+0079‐34‐5 1,1,2,2‐Tetrachloroethane Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 8.99E‐06 ‐‐ 4.02E‐06 ‐‐79‐00‐5 1,1,2‐Trichloroethane Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 5.44E‐06 ‐‐ 2.43E‐06 ‐‐75‐34‐3 1,1‐Dichloroethane Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 4.02E‐06 ‐‐ 1.80E‐06 ‐‐107‐06‐2 1,2‐Dichloroethane Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 4.02E‐06 ‐‐ 1.80E‐06 ‐‐78‐87‐5 1,2‐Dichloropropane Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 4.62E‐06 ‐‐ 2.07E‐06 ‐‐106‐99‐0 1,3‐Butadiene Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 2.36E‐04 ‐‐ 1.05E‐04 0.00E+00542‐75‐6 1,3‐Dichloropropene Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 4.51E‐06 ‐‐ 2.02E‐06 ‐‐7440‐43‐9 Cadmium Yes Yes 8.99E‐05 1.03E‐06 9.37E‐08 4.62E‐08 8.99E‐05 8.99E‐05 1.03E‐06 9.37E‐08 4.62E‐08 8.99E‐05 3.60E‐04 4.11E‐06 3.75E‐07 1.85E‐07 3.60E‐04 ‐‐ ‐‐ ‐‐ 5.21E‐0975‐15‐0 CarbonDisulfide Yes Yes 1.19E‐02 1.36E‐04 1.22E‐05 5.92E‐06 1.19E‐02 1.19E‐02 1.36E‐04 1.21E‐05 5.92E‐06 1.19E‐02 0.05 5.45E‐04 4.84E‐05 2.37E‐05 0.05 ‐‐ ‐‐ ‐‐ 1.02E‐0656‐23‐5 CarbonTetrachloride Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 6.29E‐06 ‐‐ 2.81E‐06 ‐‐108‐90‐7 Chlorobenzene Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 4.59E‐06 ‐‐ 2.05E‐06 ‐‐67‐66‐3 Chloroform Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 4.87E‐06 ‐‐ 2.18E‐06 ‐‐74‐87‐3 Chloromethane Yes Yes 2.70E‐04 3.09E‐06 2.82E‐07 1.39E‐07 2.70E‐04 2.70E‐04 3.09E‐06 2.82E‐07 1.39E‐07 2.70E‐04 1.08E‐03 1.23E‐05 1.13E‐06 5.55E‐07 1.08E‐03 ‐‐ ‐‐ ‐‐ 0.00E+0018540‐29‐9 ChromiumVI Yes Yes 4.58E‐06 5.23E‐08 4.77E‐09 2.35E‐09 4.58E‐06 4.58E‐06 5.23E‐08 4.77E‐09 2.35E‐09 4.58E‐06 1.83E‐05 2.09E‐07 1.91E‐08 9.41E‐09 1.83E‐05 ‐‐ ‐‐ ‐‐ 2.65E‐107440‐48‐4 Cobalt Yes Yes 6.87E‐06 7.84E‐08 7.15E‐09 3.53E‐09 6.87E‐06 6.87E‐06 7.84E‐08 7.15E‐09 3.53E‐09 6.87E‐06 2.75E‐05 3.14E‐07 2.86E‐08 1.41E‐08 2.75E‐05 ‐‐ ‐‐ ‐‐ 3.98E‐107440‐50‐8 Copper No Yes 6.95E‐05 7.93E‐07 7.24E‐08 3.57E‐08 6.95E‐05 6.95E‐05 7.93E‐07 7.24E‐08 3.57E‐08 6.95E‐05 2.78E‐04 3.17E‐06 2.90E‐07 1.43E‐07 2.78E‐04 ‐‐ ‐‐ ‐‐ 4.02E‐09106‐46‐7 Dichlorobenzene Yes Yes 9.81E‐05 1.12E‐06 1.02E‐07 5.04E‐08 9.81E‐05 9.81E‐05 1.12E‐06 1.02E‐07 5.04E‐08 9.81E‐05 3.92E‐04 4.48E‐06 4.09E‐07 2.02E‐07 3.92E‐04 ‐‐ ‐‐ ‐‐ 5.68E‐0975‐09‐2 Dichloromethane Yes Yes 2.59E‐06 2.96E‐08 2.70E‐09 1.33E‐09 2.59E‐06 2.59E‐06 2.96E‐08 2.70E‐09 1.33E‐09 2.59E‐06 1.04E‐05 1.18E‐07 1.08E‐08 5.32E‐09 1.04E‐05 1.46E‐05 ‐‐ 6.55E‐06 0.00E+00DPM DieselEngineParticulate No Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 3.53E‐03 ‐‐ ‐‐100‐41‐4 Ethylbenzene Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 8.82E‐06 ‐‐ 3.94E‐06 ‐‐106‐93‐4 EthyleneDibromide Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 7.57E‐06 ‐‐ 3.38E‐06 ‐‐50‐00‐0 Formaldehyde Yes Yes 6.13E‐03 7.00E‐05 6.39E‐06 3.15E‐06 6.13E‐03 6.13E‐03 7.00E‐05 6.39E‐06 3.15E‐06 6.13E‐03 0.02 2.80E‐04 2.56E‐05 1.26E‐05 0.02 7.29E‐03 5.45E‐05 3.26E‐03 3.55E‐07110‐54‐3 Hexane Yes Yes 0.12 1.42E‐03 1.30E‐04 6.40E‐05 0.12 0.12 1.42E‐03 1.30E‐04 6.40E‐05 0.12 0.50 5.69E‐03 5.19E‐04 2.56E‐04 0.50 ‐‐ ‐‐ ‐‐ 8.52E‐0674‐90‐8 HydrogenCyanide Yes Yes 6.00 0.07 0.08 0.07 6.14 6.00 0.07 0.11 0.07 6.17 24.00 0.27 0.43 0.27 24.67 ‐‐ ‐‐ ‐‐ 1.37E‐027439‐96‐5 Manganese Yes Yes 3.11E‐05 3.55E‐07 3.24E‐08 1.60E‐08 3.11E‐05 3.11E‐05 3.55E‐07 3.24E‐08 1.60E‐08 3.11E‐05 1.24E‐04 1.42E‐06 1.29E‐07 6.38E‐08 1.24E‐04 ‐‐ ‐‐ ‐‐ 1.80E‐097439‐97‐6 Mercury Yes Yes 2.13E‐05 2.43E‐07 2.21E‐08 1.09E‐08 2.13E‐05 2.13E‐05 2.43E‐07 2.21E‐08 1.09E‐08 2.13E‐05 8.50E‐05 9.71E‐07 8.86E‐08 4.37E‐08 8.50E‐05 ‐‐ ‐‐ ‐‐ 1.23E‐0967‐56‐1 Methanol Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 1.09E‐03 ‐‐ 4.86E‐04 ‐‐91‐20‐3 Naphthalene Yes Yes 4.99E‐05 5.69E‐07 5.20E‐08 2.56E‐08 4.99E‐05 4.99E‐05 5.69E‐07 5.20E‐08 2.56E‐08 4.99E‐05 1.99E‐04 2.28E‐06 2.08E‐07 1.02E‐07 1.99E‐04 3.45E‐05 9.67E‐05 1.54E‐05 2.89E‐097440‐02‐0 Nickel Yes Yes 1.72E‐04 1.96E‐06 1.79E‐07 8.82E‐08 1.72E‐04 1.72E‐04 1.96E‐06 1.79E‐07 8.82E‐08 1.72E‐04 6.87E‐04 7.84E‐06 7.15E‐07 3.53E‐07 6.87E‐04 ‐‐ ‐‐ ‐‐ 9.94E‐09115‐07‐1 Propylene No Yes 4.74E‐04 5.41E‐06 4.94E‐07 2.43E‐07 4.74E‐04 4.74E‐04 5.41E‐06 4.94E‐07 2.43E‐07 4.74E‐04 1.90E‐03 2.16E‐05 1.97E‐06 9.74E‐07 1.90E‐03 ‐‐ 1.93E‐03 ‐‐ 0.00E+007782‐49‐2 Selenium Yes Yes 1.96E‐06 2.24E‐08 2.04E‐09 1.01E‐09 1.96E‐06 1.96E‐06 2.24E‐08 2.04E‐09 1.01E‐09 1.96E‐06 7.85E‐06 8.96E‐08 8.18E‐09 4.03E‐09 7.85E‐06 ‐‐ ‐‐ ‐‐ 1.14E‐10100‐42‐5 Styrene Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 4.23E‐06 ‐‐ 1.89E‐06 ‐‐108‐88‐3 Toluene Yes Yes 1.13E‐03 1.29E‐05 1.17E‐06 5.79E‐07 1.13E‐03 1.13E‐03 1.29E‐05 1.17E‐06 5.79E‐07 1.13E‐03 4.51E‐03 5.15E‐05 4.70E‐06 2.32E‐06 4.51E‐03 1.98E‐04 1.94E‐04 8.87E‐05 1.61E‐087440‐62‐2 Vanadium No Yes 1.88E‐04 2.15E‐06 1.96E‐07 9.66E‐08 1.88E‐04 1.88E‐04 2.15E‐06 1.96E‐07 9.66E‐08 1.88E‐04 7.52E‐04 8.59E‐06 7.84E‐07 3.86E‐07 7.52E‐04 ‐‐ ‐‐ ‐‐ 1.09E‐08108‐05‐4 VinylAcetate Yes Yes 0.02 2.55E‐04 2.28E‐05 1.11E‐05 0.02 0.02 2.55E‐04 2.27E‐05 1.11E‐05 0.02 0.09 1.02E‐03 9.07E‐05 4.44E‐05 0.09 ‐‐ ‐‐ ‐‐ 2.28E‐0675‐01‐4 VinylChloride Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 2.55E‐06 ‐‐ 1.14E‐06 ‐‐1330‐20‐7 Xylenes Yes Yes ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 6.93E‐05 1.33E‐04 3.10E‐05 ‐‐56‐55‐3 Benz(a)anthracene Yes Yes 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 5.89E‐07 6.72E‐09 6.13E‐10 3.02E‐10 5.89E‐07 ‐‐ 4.30E‐07 ‐‐ 8.52E‐1250‐32‐8 Benzo(a)pyrene Yes Yes 9.81E‐08 1.12E‐09 1.02E‐10 5.04E‐11 9.81E‐08 9.81E‐08 1.12E‐09 1.02E‐10 5.04E‐11 9.81E‐08 3.92E‐07 4.48E‐09 4.09E‐10 2.02E‐10 3.92E‐07 ‐‐ 1.77E‐07 ‐‐ 5.68E‐12205‐99‐2 Benzo(b)fluoranthene Yes Yes 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 5.89E‐07 6.72E‐09 6.13E‐10 3.02E‐10 5.89E‐07 ‐‐ 7.67E‐07 ‐‐ 8.52E‐12207‐08‐9 Benzo(k)fluoranthene Yes Yes 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 5.89E‐07 6.72E‐09 6.13E‐10 3.02E‐10 5.89E‐07 ‐‐ 1.51E‐07 ‐‐ 8.52E‐12218‐01‐9 Chrysene Yes Yes 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 5.89E‐07 6.72E‐09 6.13E‐10 3.02E‐10 5.89E‐07 ‐‐ 1.06E‐06 ‐‐ 8.52E‐1253‐70‐3 Dibenzo(a,h)anthrancene Yes Yes 9.81E‐08 1.12E‐09 1.02E‐10 5.04E‐11 9.81E‐08 9.81E‐08 1.12E‐09 1.02E‐10 5.04E‐11 9.81E‐08 3.92E‐07 4.48E‐09 4.09E‐10 2.02E‐10 3.92E‐07 ‐‐ 2.39E‐07 ‐‐ 5.68E‐12193‐39‐5 Indeno(1,2,3‐cd)pyrene Yes Yes 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 5.89E‐07 6.72E‐09 6.13E‐10 3.02E‐10 5.89E‐07 ‐‐ 2.86E‐07 ‐‐ 8.52E‐1256‐49‐5 3‐Methylcholanthrene Yes Yes 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 1.47E‐07 1.68E‐09 1.53E‐10 7.56E‐11 1.47E‐07 5.89E‐07 6.72E‐09 6.13E‐10 3.02E‐10 5.89E‐07 ‐‐ ‐‐ ‐‐ 8.52E‐1257‐97‐6 7,12‐Dimethylbenz[a]anth Yes Yes 1.31E‐06 1.49E‐08 1.36E‐09 6.72E‐10 1.31E‐06 1.31E‐06 1.49E‐08 1.36E‐09 6.72E‐10 1.31E‐06 5.23E‐06 5.97E‐08 5.45E‐09 2.69E‐09 5.23E‐06 ‐‐ ‐‐ ‐‐ 7.57E‐1183‐32‐9 Acenaphthene Yes No ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 3.23E‐06 ‐‐ ‐‐208‐96‐8 Acenaphthylene Yes No ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 6.37E‐06 ‐‐ ‐‐120‐12‐7 Anthracene Yes No ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 8.49E‐07 ‐‐ ‐‐191‐24‐2 Benzo(g,h,i)perylene Yes No ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 3.84E‐07 ‐‐ ‐‐206‐44‐0 Fluoranthene Yes No ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 2.78E‐06 ‐‐ ‐‐86‐73‐7 Fluorene Yes No ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 8.84E‐06 ‐‐ ‐‐85‐01‐8 Phenanthrene Yes No ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 2.82E‐05 ‐‐ ‐‐129‐00‐0 Pyrene Yes No ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ 2.56E‐06 ‐‐ ‐‐aBecauseproposedpotentialemissionsduringNormalModearenotlimitedbelow8,760,proposedannualemissionsduringalternatemodesareonlyaccountedforasthenetincreaseaboveNormalModeemissionratesduringtheallowedtimeperiod.Apartfromacrylonitrile,ammoniaandhydrogencyanideemissionsduringRTOShutdownandRTOBypass,nootherpollutantisemittedinratesthatexceedthoseduringNormalMode.

CAS Compound

Line1(tpy) Lines3,4,5,and6(tpy)Line2(tpy) Emissions(tpy)

SGL‐MosesLakeFacility

SummaryofLine1Emissions

Line1Specifications

SCRAmmoniaSlip(lb/hr) 2.4

RTOSpecifications

RTOHeaterFiringrate 8.40MMBtu/hr

RTOBackupHeaterFiringrate 2.04MMBtu/hr

OxidationovenShutdownDuration 90seconds

shutdownperDay 1

shutdownsperYear 365

RTOBypass(hrs/day) 1.5

RTOBypass(hrs/yr) 4.5

TOSpecifications

TOHeaterFiringrate 4.00MMBtu/hr

StackExhaustFlowInformation

TypicalRTOExhaustgasflowrate 57,400cfm June2013RTOSourceTestResults

Line1Exhaustgasvolumeflow 80,000cfm ShutdownFanSpecification‐providedbySemra(SGLACF)during4/30/2013phoneconversation.

SGL‐MosesLakeFacility

SummaryofLine1EmissionsTable3a.Line1RTO‐HourlyEmissionSummary

CAS Compound Normal SCRBypass RTOShutdown RTOBypass Normalb,g SCRBypasscRTOShutdown

dRTO

BypasseMaximumHourly

10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.50 14.90 8.50 8.50 14.90

630‐08‐0 CO ‐‐ ‐‐ ‐‐ ‐‐ 0.56 0.56 0.56 0.56 0.567446‐09‐05 SO2 ‐‐ ‐‐ ‐‐ ‐‐ 0.68 0.68 0.68 0.68 0.68

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.10 1.10 1.10 1.10 1.10PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 3.00 3.00 3.00 3.00

PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 3.00 3.00 3.00 3.00

VOC VOC ‐‐ ‐‐ ‐‐ ‐‐ 0.24 0.24 4.29 7.20 7.20CO2e CO2e

g ‐‐ ‐‐ ‐‐ ‐‐ 1646.12 1646.12 1644.86 1644.86 1646.12

107‐02‐8 Acroleinf ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrileb,e ‐‐ ‐‐ ‐‐ ‐‐ 5.6E‐03 5.6E‐03 0.10 0.17 0.17

7664‐41‐7 Ammoniab,e ‐‐ ‐‐ ‐‐ ‐‐ 0.50 0.50 5.74 9.50 9.50

7803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐38‐2 Arsenic 2.0E‐07 2.0E‐07 2.0E‐07 2.0E‐07 2.0E‐06 2.0E‐06 2.0E‐06 2.0E‐06 2.0E‐06

71‐43‐2 Benzene 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05

7440‐41‐7 Beryllium 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐07 1.2E‐07 1.2E‐07 1.2E‐07 1.2E‐07

74‐83‐9 Bromomethanef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

106‐99‐0 1,3‐Butadienef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐43‐9 Cadmium 1.1E‐06 1.1E‐06 1.1E‐06 1.1E‐06 1.1E‐05 1.1E‐05 1.1E‐05 1.1E‐05 1.1E‐05

75‐15‐0 CarbonDisulfideb,e ‐‐ ‐‐ ‐‐ ‐‐ 2.3E‐03 2.3E‐03 2.2E‐03 2.2E‐03 2.3E‐03

74‐87‐3 Chloromethanef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

18540‐29‐9 ChromiumVI 5.5E‐08 5.5E‐08 5.5E‐08 5.5E‐08 5.7E‐07 5.7E‐07 5.7E‐07 5.7E‐07 5.7E‐07

7440‐48‐4 Cobalt 8.2E‐08 8.2E‐08 8.2E‐08 8.2E‐08 8.6E‐07 8.6E‐07 8.6E‐07 8.6E‐07 8.6E‐07

7440‐50‐8 Copper 8.3E‐07 8.3E‐07 8.3E‐07 8.3E‐07 8.7E‐06 8.7E‐06 8.7E‐06 8.7E‐06 8.7E‐06

106‐46‐7 Dichlorobenzene 1.2E‐06 1.2E‐06 1.2E‐06 1.2E‐06 1.2E‐05 1.2E‐05 1.2E‐05 1.2E‐05 1.2E‐05

75‐09‐2 Dichloromethanef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

50‐00‐0 Formaldehyde 7.4E‐05 7.4E‐05 7.4E‐05 7.4E‐05 7.7E‐04 7.7E‐04 7.7E‐04 7.7E‐04 7.7E‐04

110‐54‐3 Hexane 1.8E‐03 1.8E‐03 1.8E‐03 1.8E‐03 0.02 0.02 0.02 0.02 0.02

74‐90‐8 HydrogenCyanideb,e ‐‐ ‐‐ ‐‐ ‐‐ 1.10 1.10 17.75 29.70 29.70

7439‐96‐5 Manganese 3.7E‐07 3.7E‐07 3.7E‐07 3.7E‐07 3.9E‐06 3.9E‐06 3.9E‐06 3.9E‐06 3.9E‐06

7439‐97‐6 Mercury 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07 2.7E‐06 2.7E‐06 2.7E‐06 2.7E‐06 2.7E‐06

91‐20‐3 Naphthalene 6.0E‐07 6.0E‐07 6.0E‐07 6.0E‐07 6.2E‐06 6.2E‐06 6.2E‐06 6.2E‐06 6.2E‐06

7440‐02‐0 Nickel 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05

115‐07‐1 Propylenef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7782‐49‐2 Selenium 2.4E‐08 2.4E‐08 2.4E‐08 2.4E‐08 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07

540‐84‐1 2,2,4‐Trimethylpentanek ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

108‐88‐3 Toluene 3.3E‐06 3.3E‐06 3.3E‐06 3.3E‐06 3.5E‐05 3.5E‐05 3.5E‐05 3.5E‐05 3.5E‐05

7440‐62‐2 Vanadium 2.3E‐06 2.3E‐06 2.3E‐06 2.3E‐06 2.4E‐05 2.4E‐05 2.4E‐05 2.4E‐05 2.4E‐05

108‐05‐4 VinylAcetateb,e ‐‐ ‐‐ ‐‐ ‐‐ 5.1E‐03 5.1E‐03 5.0E‐03 4.9E‐03 5.1E‐03

56‐55‐3 Benz(a)anthracene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

50‐32‐8 Benzo(a)pyrene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08

205‐99‐2 Benzo(b)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

207‐08‐9 Benzo(k)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

218‐01‐9 Chrysene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

53‐70‐3 Dibenzo(a,h)anthracene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08

193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

56‐49‐5 3‐Methylcholanthrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

57‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐08 1.6E‐08 1.6E‐08 1.6E‐08 1.6E‐07 1.6E‐07 1.6E‐07 1.6E‐07 1.6E‐07a

b

c

d

e

f

g

RTObypassemissionsarebasedonRTOinletemissionsfrom2013sourcetesting,includingVOC,acrylonitrile,ammonia,andhydrogencyanide,whichhavehigheremissionsduringRTObypassthannormaloperation.CarbondisulfideandvinylacetateemissionratesbasedonaverageofJanuary2013andJune2013sourcetestresults.OnlyonesampleinRTOexhaustwasabovedetectionlevel,andemissionsare1/2thedetectionlevelforanymeasurementsbelowdetectionlevel.Otherpollutantsassumesameemissionsasthenormaloperationsincetheyareemittedbytheovens.

Acrolein,bromomethane,chloromethane,dichloromethane,propylene,2,2,4‐trimethylpentane,and1,3butadienenotdetectableinRTOinletorexhaust.

EmissionFactorsa

(lb/MMBtu)HourlyEmissionRates

(lb/hr)

EmissionfactorsbasedonAP‐42,Section1.4(NaturalGasCombustion)correctedtolb/MMBtuusingnaturalgasheatcontent(1,020btu/cf).Unlessnoted,theRTOandSCRmode(i.e.bypassorshutdown)shouldnotaffectemissions.Hourlyemissionsbasedon8.4MMBtu/hrfortheRTOand2.0MMBtu/hrfortheBackupRTOburner.CO,SO2,VOC,acrylonitrile,hydrogencyanide,ammonia,carbondisulfideandvinylacetateemissionsarebasedonsourcetestresultsaspresentedinpreviousPSDapplication.Foracrylonitrile,carbondisulfideandvinylacetate,onlyonesampleinRTOexhaustwasabovedetectionlevel,andemissionsare1/2thedetectionlevelforanymeasurementsbelowdetectionlevel.EmissionforNOXduringnormaloperationstaysat8.5lb/hrbecauseitisbasedonSCRvendorquote.CO,SO2,VOCemissionsfromnaturalgascombustionbasedonAP‐42Chapter1.4factorsarealsoincludedforthebackupburner.

NOXemissionsduringSCRbypassisbasedon2013sourcetestresultsattheRTOexhaustplustheburneremissions(whicharebasedonAP‐42Section1.4uncontrolledfactors).OtherpollutantsassumesameemissionsasthenormaloperationsinceSCRisnotacontroldeviceforpollutantsotherthanNOX.

TheRTOshutdowneventintroducesfreshairtotheovenswhichresultsinincreaseofemissions,whilekeepingthenormalRTOexhaustsystem.RTOshutdownemissionsareconservativelyestimatedforashutdowneventlastinganhoureventhoughthetypicallengthoftheelevatedemissionlevelsis90seconds.TheemissionsestimatedbyweightedaveragethenormaloperationemissionsandRTObypassemissions(seefootnotee)withtheflowratescorrespondingtotheoperationscenario.

CO2emissionsduringnormaloperationarebasedon2013and2014sourcetestingperthe2014PSDapplication.OtherGHGemissions(CH4andN2O)fromnaturalgascombustionattheRTOarealsoaccountedforusingthefiringrateandemissionfactorsbasedon40CFRPart98SubpartC.ThetotalCO2eemissionsarecombinedbasedontheglobalwarmingpotentialsofeachGHGper40CFRPart98SubpartA.NotethatCO2emissionsfromRTOnaturalgascombustionarenotcalculatedseparatelybecauseitisincludedintheCO2testresult.WhentheRTOisshutdownorbypassed,CH4andN2Oemissionsfromnaturalgascombustionarenotincluded.

SGL‐MosesLakeFacility

SummaryofLine1Emissions

Table3b.Line1TO‐HourlyEmissionSummary

CAS Compound Normal SCRBypass RTOShutdown RTOBypass Normalb SCRBypasscRTOShutdown

dRTO

BypassdMaximumHourly

10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.50 3.00 8.50 8.50 8.50630‐08‐0 CO ‐‐ ‐‐ ‐‐ ‐‐ 0.39 0.39 0.39 0.39 0.397446‐09‐05 SO2 5.9E‐04 5.9E‐04 5.9E‐04 5.9E‐04 2.4E‐03 2.4E‐03 2.4E‐03 2.4E‐03 2.4E‐03

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.10 1.10 1.10 1.10 1.10PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 3.00 3.00 3.00 3.00PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 3.00 3.00 3.00 3.00VOC VOC ‐‐ ‐‐ ‐‐ ‐‐ 1.42 1.42 1.42 1.42 1.42

CO2e CO2ef 0.12 0.12 0.12 0.12 0.48 0.48 0.48 0.48 0.48

107‐02‐8 Acroleine ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrilee ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7664‐41‐7 Ammoniab ‐‐ ‐‐ ‐‐ ‐‐ 0.13 0.13 0.13 0.13 0.137803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐38‐2 Arsenic 2.0E‐07 2.0E‐07 2.0E‐07 2.0E‐07 7.8E‐07 7.8E‐07 7.8E‐07 7.8E‐07 7.8E‐07

71‐43‐2 Benzeneb ‐‐ ‐‐ ‐‐ ‐‐ 1.4E‐04 1.4E‐04 1.4E‐04 1.4E‐04 1.4E‐047440‐41‐7 Beryllium 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 4.7E‐08 4.7E‐08 4.7E‐08 4.7E‐08 4.7E‐08

74‐83‐9 Bromomethaneb ‐‐ ‐‐ ‐‐ ‐‐ 1.8E‐04 1.8E‐04 1.8E‐04 1.8E‐04 1.8E‐04

106‐99‐0 1,3‐Butadienee ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐43‐9 Cadmium 1.1E‐06 1.1E‐06 1.1E‐06 1.1E‐06 4.3E‐06 4.3E‐06 4.3E‐06 4.3E‐06 4.3E‐06

75‐15‐0 CarbonDisulfideb ‐‐ ‐‐ ‐‐ ‐‐ 4.3E‐04 4.3E‐04 4.3E‐04 4.3E‐04 4.3E‐04

74‐87‐3 Chloromethaneb ‐‐ ‐‐ ‐‐ ‐‐ 6.2E‐05 6.2E‐05 6.2E‐05 6.2E‐05 6.2E‐0518540‐29‐9 ChromiumVI 5.5E‐08 5.5E‐08 5.5E‐08 5.5E‐08 2.2E‐07 2.2E‐07 2.2E‐07 2.2E‐07 2.2E‐077440‐48‐4 Cobalt 8.2E‐08 8.2E‐08 8.2E‐08 8.2E‐08 3.3E‐07 3.3E‐07 3.3E‐07 3.3E‐07 3.3E‐077440‐50‐8 Copper 8.3E‐07 8.3E‐07 8.3E‐07 8.3E‐07 3.3E‐06 3.3E‐06 3.3E‐06 3.3E‐06 3.3E‐06106‐46‐7 Dichlorobenzene 1.2E‐06 1.2E‐06 1.2E‐06 1.2E‐06 4.7E‐06 4.7E‐06 4.7E‐06 4.7E‐06 4.7E‐06

75‐09‐2 Dichloromethaneb ‐‐ ‐‐ ‐‐ ‐‐ 5.9E‐07 5.9E‐07 5.9E‐07 5.9E‐07 5.9E‐0750‐00‐0 Formaldehyde 7.4E‐05 7.4E‐05 7.4E‐05 7.4E‐05 2.9E‐04 2.9E‐04 2.9E‐04 2.9E‐04 2.9E‐04

110‐54‐3 Hexaneb ‐‐ ‐‐ ‐‐ ‐‐ 1.9E‐03 1.9E‐03 1.9E‐03 1.9E‐03 1.9E‐03

74‐90‐8 HydrogenCyanideb ‐‐ ‐‐ ‐‐ ‐‐ 0.27 0.27 0.27 0.27 0.277439‐96‐5 Manganese 3.7E‐07 3.7E‐07 3.7E‐07 3.7E‐07 1.5E‐06 1.5E‐06 1.5E‐06 1.5E‐06 1.5E‐067439‐97‐6 Mercury 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07 1.0E‐06 1.0E‐06 1.0E‐06 1.0E‐06 1.0E‐0691‐20‐3 Naphthalene 6.0E‐07 6.0E‐07 6.0E‐07 6.0E‐07 2.4E‐06 2.4E‐06 2.4E‐06 2.4E‐06 2.4E‐067440‐02‐0 Nickel 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐06 8.2E‐06 8.2E‐06 8.2E‐06 8.2E‐06 8.2E‐06

115‐07‐1 Propyleneb ‐‐ ‐‐ ‐‐ ‐‐ 1.1E‐04 1.1E‐04 1.1E‐04 1.1E‐04 1.1E‐047782‐49‐2 Selenium 2.4E‐08 2.4E‐08 2.4E‐08 2.4E‐08 9.4E‐08 9.4E‐08 9.4E‐08 9.4E‐08 9.4E‐08

540‐84‐1 2,2,4‐Trimethylpentaneb ‐‐ ‐‐ ‐‐ ‐‐ 4.5E‐07 4.5E‐07 4.5E‐07 4.5E‐07 4.5E‐07

108‐88‐3 Tolueneb ‐‐ ‐‐ ‐‐ ‐‐ 2.1E‐04 2.1E‐04 2.1E‐04 2.1E‐04 2.1E‐047440‐62‐2 Vanadium 2.3E‐06 2.3E‐06 2.3E‐06 2.3E‐06 9.0E‐06 9.0E‐06 9.0E‐06 9.0E‐06 9.0E‐06

108‐05‐4 VinylAcetatee ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐56‐55‐3 Benz(a)anthracene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0950‐32‐8 Benzo(a)pyrene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09205‐99‐2 Benzo(b)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09207‐08‐9 Benzo(k)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09218‐01‐9 Chrysene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0953‐70‐3 Dibenzo(a,h)anthracene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0956‐49‐5 3‐Methylcholanthrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0957‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐08 1.6E‐08 1.6E‐08 1.6E‐08 6.3E‐08 6.3E‐08 6.3E‐08 6.3E‐08 6.3E‐08

a

b

c

d RTOshutdownandRTObypassemissionsareassumedthesameasthenormaloperationscenarioforTO.e Acrolein,acrylonitrile,vinylacetate,and1,3butadienenotdetectedinTOexhaust.f CO2eemissionsarethesumofCH4andN2Oemissionsapplyingfortheglobalwarmingpotentialsbasedonapproachesspecifiedfornaturalgascombustionin40CFRPart98.TheCO2emissionsfromtheTOareassumedtobeincludedintheRTOprocessemissionswhicharebasedonsourcetestresults.

HourlyEmissionRates(lb/hr)

EmissionfactorsbasedonAP‐42,Section1.4(NaturalGasCombustion)correctedtolb/mmBtuusingnaturalgasheatcontent(1,020btu/cf).Unlessnoted,theRTOandSCRmode(i.e.bypassorshutdown)shouldnotaffectemissions.Hourlyemissionsbasedon4.0MMBtu/hr.

EmissionFactorsa

(lb/MMBtu)

CO,SO2,VOC,hydrogencyanide,ammonia,benzene,bromomethane,carbondisulfide,dichloromethane,hexane,propylene,2,2,4‐trimethylpentane,andtolueneemissionsarebasedonsourcetestresultsaspresentedinpreviousPSDapplication,andscaledupbytheproposedproductionrateversusthecurrentproductionrate(seefootnoteg).Benzene,bromomethane,carbondisulfide,chloromethane,dichloromethane,2,2,4‐trimethylpentane,andtoluenelb/hremissionsbasedonJanuary2013sourcetestresults.AverageofthreeTOexhaustsamples,andemissionsare1/2thedetectionlevelforanymeasurementsbelowdetectionlevel.EmissionforNOXduringnormaloperationstaysat8.5lb/hrbecauseitisbasedonSCRvendorquoteforcombinedexhaustatthemainstack.ItisconservativelyassumedthatPM=PM10=PM2.5.

SCRbypassNOXemissionsarebasedonCEMSdata.OtherpollutantsassumesameemissionsasthenormaloperationsinceSCRisnotacontroldeviceforpollutantsotherthanNOX.

SGL‐MosesLakeFacility

SummaryofLine1Emissions

Table3c.Line1‐HourlyEmissionSummaryforNormalOperation

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Totala

10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.5

630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

VOC VOC 0.2 1.4 0.02 ‐‐ 1.7

CO2e CO2ec 1646.1 0.5 0.55 ‐‐ 1647.2

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrile 5.6E‐03 ‐‐ ‐‐ ‐‐ 5.6E‐03

7664‐41‐7 Ammonia 0.5 0.1 ‐‐ 2.4 3.0

7803‐63‐6 AmmoniumBisulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7783‐20‐2 AmmoniumSulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐06

71‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐04

7440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐07

74‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04

106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐05

75‐15‐0 CarbonDisulfide 2.3E‐03 4.3E‐04 ‐‐ ‐‐ 2.7E‐03

74‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐06

7440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐06

7440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05

106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐05

75‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐07

50‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03

110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐02

74‐90‐8 HydrogenCyanide 1.1 0.3 ‐‐ ‐‐ 1.4

7439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐06

7439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐06

91‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐05

7440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05

115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐04

7782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07

108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐04

7440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05

108‐05‐4 VinylAcetate 5.1E‐03 ‐‐ ‐‐ ‐‐ 5.1E‐03

56‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

50‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

53‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

56‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

57‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07a

b

c

Table3d.Line1‐HourlyEmissionSummaryforSCRBypass

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Total10102‐44‐0 NOX 14.9 3.00 ‐‐ ‐‐ 17.9630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0VOC VOC 0.2 1.4 0.02 ‐‐ 1.7CO2e CO2e 1646.1 0.5 ‐‐ ‐‐ 1646.6

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐107‐13‐1 Acrylonitrile 5.6E‐03 ‐‐ ‐‐ ‐‐ 5.6E‐037664‐41‐7 Ammonia 0.5 0.1 ‐‐ ‐‐ 0.67803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐0671‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐047440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐0774‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐0575‐15‐0 CarbonDisulfide 2.3E‐03 4.3E‐04 ‐‐ ‐‐ 2.7E‐0374‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐067440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐067440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐0575‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐0750‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐0274‐90‐8 HydrogenCyanide 1.1 0.3 ‐‐ ‐‐ 1.47439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐067439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐0691‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐057440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐047782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐047440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05108‐05‐4 VinylAcetate 5.1E‐03 ‐‐ ‐‐ ‐‐ 5.1E‐0356‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0850‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0853‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0856‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0857‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07

a

NormalEmissionRates(lb/hr)

SCRBypassEmissionRatesa(lb/hr)

NOXemissionsarelimitedattheoutletemissionlevelprovidedbytheSCRvendor.PM,PM10andPM2.5emissionsareproposedasasinglelimitatthemainstack.

PertheDecember2014PSDapplication,theSCRsystemcontributestheammoniumsulfateandammoniumbisulfateemissionsandarethemaincomponentofPMemissionsfromSCR.

CO2eemissionsarethesumofCH4andN2Oemissionsapplyingfortheglobalwarmingpotentialsbasedonapproachesspecifiedfornaturalgascombustionin40CFRPart98.TheCO2emissionsfromtheSCRHeaterareassumedtobeincludedintheRTOprocessemissionswhicharebasedonsourcetestresults.

AmmoniaInjectionisnotoperatingduringSCRBypass.

SGL‐MosesLakeFacility

SummaryofLine1Emissions

Table3e.Line1‐HourlyEmissionSummaryforShutdownOperation

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Total10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.5

630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1

PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

VOC VOC 4.3 1.4 0.02 ‐‐ 5.7CO2e CO2e 1,644.9 0.48 0.55 ‐‐ 1645.9

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrile 0.10 ‐‐ ‐‐ ‐‐ 0.10

7664‐41‐7 Ammonia 5.7 0.1 ‐‐ 2.4 8.3

7803‐63‐6 AmmoniumBisulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7783‐20‐2 AmmoniumSulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐06

71‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐04

7440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐07

74‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04

106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐05

75‐15‐0 CarbonDisulfide 2.2E‐03 4.3E‐04 ‐‐ ‐‐ 2.7E‐03

74‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐06

7440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐06

7440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05

106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐05

75‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐07

50‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03

110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐02

74‐90‐8 HydrogenCyanide 17.75 0.27 ‐‐ ‐‐ 18.02

7439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐06

7439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐06

91‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐05

7440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05

115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐04

7782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07

108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐04

7440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05

108‐05‐4 VinylAcetate 5.0E‐03 ‐‐ ‐‐ ‐‐ 5.0E‐03

56‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

50‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

53‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

56‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

57‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07a

b

Table3f.Line1‐HourlyEmissionSummaryforRTOBypass

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Total10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.5630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0VOC VOC 7.2 1.4 0.02 ‐‐ 8.6CO2e CO2e 1,644.9 0.48 0.55 ‐‐ 1645.9

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐107‐13‐1 Acrylonitrile 1.7E‐01 ‐‐ ‐‐ ‐‐ 1.7E‐017664‐41‐7 Ammonia 9.5 0.1 ‐‐ ‐‐ 9.67803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐0671‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐047440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐0774‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐0575‐15‐0 CarbonDisulfide 2.2E‐03 4.3E‐04 ‐‐ ‐‐ 2.6E‐0374‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐067440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐067440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐0575‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐0750‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐0274‐90‐8 HydrogenCyanide 29.7 0.3 ‐‐ ‐‐ 30.07439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐067439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐0691‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐057440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐047782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐047440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05108‐05‐4 VinylAcetate 4.9E‐03 ‐‐ ‐‐ ‐‐ 4.9E‐0356‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0850‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0853‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0856‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0857‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07

a

NOXemissionsarelimitedattheoutletemissionlevelprovidedbytheSCRvendor.PertheDecember2014PSDapplication,theSCRsystemcontributestheammoniumsulfateandammoniumbisulfateemissionsandarethemaincomponentofPMemissionsfromSCR.

DuringanRTOBypassoxidationovenandTOexhaustalsobypasstheSCRsystem,ammoniaInjectionisnotoperated.OxidationovenNOxemissionsarelowerbecausetheRTOcontroldevicegeneratesNOx.

NormalwithShutdownEmissionRates(lb/hr)

RTOBypassEmissionRates(lb/hr)

SGL‐MosesLakeFacility

SummaryofLine2Emissions

Line2Specifications

SCRAmmoniaSlip(lb/hr) 2.4

RTOSpecifications

RTOHeaterFiringrate 8.40MMBtu/hr

RTOBackupHeaterFiringrate 2.04MMBtu/hr

OxidationovenShutdownDuration 90seconds

shutdownperDay 1

shutdownsperYear 365

RTOBypass(hrs/day) 1.5

RTOBypass(hrs/yr) 4.5

TOSpecifications

TOHeaterFiringrate 4.00MMBtu/hr

StackExhaustFlowInformation

TypicalRTOExhaustgasflowrate 57,400cfm June2013RTOSourceTestResults

Line2Exhaustgasvolumeflow 200,000cfm ShutdownFanInformation‐providedbySemra(SGLACF)during6/26/2013email.

SGL‐MosesLakeFacility

SummaryofLine2EmissionsTable4a.Line2RTO‐HourlyEmissionSummary

CAS Compound Normal SCRBypass RTOShutdown RTOBypass Normalb,g SCRBypasscRTOShutdown

dRTO

BypasseMaximumHourly

10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.50 14.90 8.50 8.50 14.90

630‐08‐0 CO ‐‐ ‐‐ ‐‐ ‐‐ 0.56 0.56 0.56 0.56 0.567446‐09‐05 SO2 ‐‐ ‐‐ ‐‐ ‐‐ 0.68 0.68 0.68 0.68 0.68

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.10 1.10 1.10 1.10 1.10PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 3.00 3.00 3.00 3.00

PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 3.00 3.00 3.00 3.00

VOC VOC ‐‐ ‐‐ ‐‐ ‐‐ 0.24 0.24 5.65 7.20 7.20CO2e CO2e

g ‐‐ ‐‐ ‐‐ ‐‐ 1646.12 1646.12 1644.86 1644.86 1646.12

107‐02‐8 Acroleinf ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrileb,e ‐‐ ‐‐ ‐‐ ‐‐ 5.6E‐03 5.6E‐03 0.14 0.17 0.17

7664‐41‐7 Ammoniab,e ‐‐ ‐‐ ‐‐ ‐‐ 0.50 0.50 7.49 9.50 9.50

7803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐38‐2 Arsenic 2.0E‐07 2.0E‐07 2.0E‐07 2.0E‐07 2.0E‐06 2.0E‐06 2.0E‐06 2.0E‐06 2.0E‐06

71‐43‐2 Benzene 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05

7440‐41‐7 Beryllium 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐07 1.2E‐07 1.2E‐07 1.2E‐07 1.2E‐07

74‐83‐9 Bromomethanef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

106‐99‐0 1,3‐Butadienef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐43‐9 Cadmium 1.1E‐06 1.1E‐06 1.1E‐06 1.1E‐06 1.1E‐05 1.1E‐05 1.1E‐05 1.1E‐05 1.1E‐05

75‐15‐0 CarbonDisulfideb,e ‐‐ ‐‐ ‐‐ ‐‐ 2.3E‐03 2.3E‐03 2.2E‐03 2.2E‐03 2.3E‐03

74‐87‐3 Chloromethanef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

18540‐29‐9 ChromiumVI 5.5E‐08 5.5E‐08 5.5E‐08 5.5E‐08 5.7E‐07 5.7E‐07 5.7E‐07 5.7E‐07 5.7E‐07

7440‐48‐4 Cobalt 8.2E‐08 8.2E‐08 8.2E‐08 8.2E‐08 8.6E‐07 8.6E‐07 8.6E‐07 8.6E‐07 8.6E‐07

7440‐50‐8 Copper 8.3E‐07 8.3E‐07 8.3E‐07 8.3E‐07 8.7E‐06 8.7E‐06 8.7E‐06 8.7E‐06 8.7E‐06

106‐46‐7 Dichlorobenzene 1.2E‐06 1.2E‐06 1.2E‐06 1.2E‐06 1.2E‐05 1.2E‐05 1.2E‐05 1.2E‐05 1.2E‐05

75‐09‐2 Dichloromethanef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

50‐00‐0 Formaldehyde 7.4E‐05 7.4E‐05 7.4E‐05 7.4E‐05 7.7E‐04 7.7E‐04 7.7E‐04 7.7E‐04 7.7E‐04

110‐54‐3 Hexane 1.8E‐03 1.8E‐03 1.8E‐03 1.8E‐03 0.02 0.02 0.02 0.02 0.02

74‐90‐8 HydrogenCyanideb,e ‐‐ ‐‐ ‐‐ ‐‐ 1.10 1.10 23.32 29.70 29.70

7439‐96‐5 Manganese 3.7E‐07 3.7E‐07 3.7E‐07 3.7E‐07 3.9E‐06 3.9E‐06 3.9E‐06 3.9E‐06 3.9E‐06

7439‐97‐6 Mercury 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07 2.7E‐06 2.7E‐06 2.7E‐06 2.7E‐06 2.7E‐06

91‐20‐3 Naphthalene 6.0E‐07 6.0E‐07 6.0E‐07 6.0E‐07 6.2E‐06 6.2E‐06 6.2E‐06 6.2E‐06 6.2E‐06

7440‐02‐0 Nickel 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05

115‐07‐1 Propylenef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7782‐49‐2 Selenium 2.4E‐08 2.4E‐08 2.4E‐08 2.4E‐08 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07

540‐84‐1 2,2,4‐Trimethylpentanek ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

108‐88‐3 Toluene 3.3E‐06 3.3E‐06 3.3E‐06 3.3E‐06 3.5E‐05 3.5E‐05 3.5E‐05 3.5E‐05 3.5E‐05

7440‐62‐2 Vanadium 2.3E‐06 2.3E‐06 2.3E‐06 2.3E‐06 2.4E‐05 2.4E‐05 2.4E‐05 2.4E‐05 2.4E‐05

108‐05‐4 VinylAcetateb,e ‐‐ ‐‐ ‐‐ ‐‐ 5.1E‐03 5.1E‐03 5.0E‐03 4.9E‐03 5.1E‐03

56‐55‐3 Benz(a)anthracene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

50‐32‐8 Benzo(a)pyrene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08

205‐99‐2 Benzo(b)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

207‐08‐9 Benzo(k)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

218‐01‐9 Chrysene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

53‐70‐3 Dibenzo(a,h)anthracene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08

193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

56‐49‐5 3‐Methylcholanthrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

57‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐08 1.6E‐08 1.6E‐08 1.6E‐08 1.6E‐07 1.6E‐07 1.6E‐07 1.6E‐07 1.6E‐07a

b

c

d

e

f

g

TheRTOshutdowneventintroducesfreshairtotheovenswhichresultsinincreaseofemissions,whilekeepingthenormalRTOexhaustsystem.RTOshutdownemissionsareconservativelyestimatedforashutdowneventlastinganhoureventhoughthetypicallengthoftheelevatedemissionlevelsis90seconds.TheemissionsestimatedbyweightedaveragethenormaloperationemissionsandRTObypassemissions(seefootnotee)withtheflowratescorrespondingtotheoperationscenario.

EmissionFactorsa

(lb/MMBtu)HourlyEmissionRates

(lb/hr)

EmissionfactorsbasedonAP‐42,Section1.4(NaturalGasCombustion)correctedtolb/MMBtuusingnaturalgasheatcontent(1,020btu/cf).Unlessnoted,theRTOandSCRmode(i.e.bypassorshutdown)shouldnotaffectemissions.Hourlyemissionsbasedon8.4MMBtu/hrfortheRTOand2.0MMBtu/hrfortheBackupRTOburner.CO,SO2,VOC,acrylonitrile,hydrogencyanide,ammonia,carbondisulfideandvinylacetateemissionsarebasedonsourcetestresultsaspresentedinpreviousPSDapplication.Foracrylonitrile,carbondisulfideandvinylacetate,onlyonesampleinRTOexhaustwasabovedetectionlevel,andemissionsare1/2thedetectionlevelforanymeasurementsbelowdetectionlevel.EmissionforNOXduringnormaloperationstaysat8.5lb/hrbecauseitisbasedonSCRvendorquote.CO,SO2,VOCemissionsfromnaturalgascombustionbasedonAP‐42Chapter1.4factorsarealsoincludedforthebackupburner.

NOXemissionsduringSCRbypassisbasedon2013sourcetestresultsattheRTOexhaustplustheburneremissions(whicharebasedonAP‐42Section1.4uncontrolledfactors).OtherpollutantsassumesameemissionsasthenormaloperationsinceSCRisnotacontroldeviceforpollutantsotherthanNOX.

RTObypassemissionsarebasedonRTOinletemissionsfrom2013sourcetesting,includingVOC,acrylonitrile,ammonia,andhydrogencyanide,whichhavehigheremissionsduringRTObypassthannormaloperation.CarbondisulfideandvinylacetateemissionratesbasedonaverageofJanuary2013andJune2013sourcetestresults.OnlyonesampleinRTOexhaustwasabovedetectionlevel,andemissionsare1/2thedetectionlevelforanymeasurementsbelowdetectionlevel.Otherpollutantsassumesameemissionsasthenormaloperationsincetheyareemittedbytheovens.

Acrolein,bromomethane,chloromethane,dichloromethane,propylene,2,2,4‐trimethylpentane,and1,3butadienenotdetectableinRTOinletorexhaust.

CO2emissionsduringnormaloperationarebasedon2013and2014sourcetestingperthe2014PSDapplication.OtherGHGemissions(CH4andN2O)fromnaturalgascombustionattheRTOarealsoaccountedforusingthefiringrateandemissionfactorsbasedon40CFRPart98SubpartC.ThetotalCO2eemissionsarecombinedbasedontheglobalwarmingpotentialsofeachGHGper40CFRPart98SubpartA.NotethatCO2emissionsfromRTOnaturalgascombustionarenotcalculatedseparatelybecauseitisincludedintheCO2testresult.WhentheRTOisshutdownorbypassed,CH4andN2Oemissionsfromnaturalgascombustionarenotincluded.

SGL‐MosesLakeFacility

SummaryofLine2Emissions

Table4b.Line2TO‐HourlyEmissionSummary

CAS Compound Normal SCRBypass RTOShutdown RTOBypass Normalb SCRBypasscRTOShutdown

dRTO

BypassdMaximumHourly

10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.50 3.00 8.50 8.50 8.50630‐08‐0 CO ‐‐ ‐‐ ‐‐ ‐‐ 0.39 0.39 0.39 0.39 0.397446‐09‐05 SO2 5.9E‐04 5.9E‐04 5.9E‐04 5.9E‐04 2.4E‐03 2.4E‐03 2.4E‐03 2.4E‐03 2.4E‐03

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.10 1.10 1.10 1.10 1.10PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 3.00 3.00 3.00 3.00PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 3.00 3.00 3.00 3.00VOC VOC ‐‐ ‐‐ ‐‐ ‐‐ 1.42 1.42 1.42 1.42 1.42

CO2e CO2ef 0.12 0.12 0.12 0.12 0.48 0.48 0.48 0.48 0.48

107‐02‐8 Acroleine ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrilee ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7664‐41‐7 Ammoniab ‐‐ ‐‐ ‐‐ ‐‐ 0.13 0.13 0.13 0.13 0.137803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐38‐2 Arsenic 2.0E‐07 2.0E‐07 2.0E‐07 2.0E‐07 7.8E‐07 7.8E‐07 7.8E‐07 7.8E‐07 7.8E‐07

71‐43‐2 Benzeneb ‐‐ ‐‐ ‐‐ ‐‐ 1.4E‐04 1.4E‐04 1.4E‐04 1.4E‐04 1.4E‐047440‐41‐7 Beryllium 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 4.7E‐08 4.7E‐08 4.7E‐08 4.7E‐08 4.7E‐08

74‐83‐9 Bromomethaneb ‐‐ ‐‐ ‐‐ ‐‐ 1.8E‐04 1.8E‐04 1.8E‐04 1.8E‐04 1.8E‐04

106‐99‐0 1,3‐Butadienee ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐43‐9 Cadmium 1.1E‐06 1.1E‐06 1.1E‐06 1.1E‐06 4.3E‐06 4.3E‐06 4.3E‐06 4.3E‐06 4.3E‐06

75‐15‐0 CarbonDisulfideb ‐‐ ‐‐ ‐‐ ‐‐ 4.3E‐04 4.3E‐04 4.3E‐04 4.3E‐04 4.3E‐04

74‐87‐3 Chloromethaneb ‐‐ ‐‐ ‐‐ ‐‐ 6.2E‐05 6.2E‐05 6.2E‐05 6.2E‐05 6.2E‐0518540‐29‐9 ChromiumVI 5.5E‐08 5.5E‐08 5.5E‐08 5.5E‐08 2.2E‐07 2.2E‐07 2.2E‐07 2.2E‐07 2.2E‐077440‐48‐4 Cobalt 8.2E‐08 8.2E‐08 8.2E‐08 8.2E‐08 3.3E‐07 3.3E‐07 3.3E‐07 3.3E‐07 3.3E‐077440‐50‐8 Copper 8.3E‐07 8.3E‐07 8.3E‐07 8.3E‐07 3.3E‐06 3.3E‐06 3.3E‐06 3.3E‐06 3.3E‐06106‐46‐7 Dichlorobenzene 1.2E‐06 1.2E‐06 1.2E‐06 1.2E‐06 4.7E‐06 4.7E‐06 4.7E‐06 4.7E‐06 4.7E‐06

75‐09‐2 Dichloromethaneb ‐‐ ‐‐ ‐‐ ‐‐ 5.9E‐07 5.9E‐07 5.9E‐07 5.9E‐07 5.9E‐0750‐00‐0 Formaldehyde 7.4E‐05 7.4E‐05 7.4E‐05 7.4E‐05 2.9E‐04 2.9E‐04 2.9E‐04 2.9E‐04 2.9E‐04

110‐54‐3 Hexaneb ‐‐ ‐‐ ‐‐ ‐‐ 1.9E‐03 1.9E‐03 1.9E‐03 1.9E‐03 1.9E‐03

74‐90‐8 HydrogenCyanideb ‐‐ ‐‐ ‐‐ ‐‐ 0.27 0.27 0.27 0.27 0.277439‐96‐5 Manganese 3.7E‐07 3.7E‐07 3.7E‐07 3.7E‐07 1.5E‐06 1.5E‐06 1.5E‐06 1.5E‐06 1.5E‐067439‐97‐6 Mercury 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07 1.0E‐06 1.0E‐06 1.0E‐06 1.0E‐06 1.0E‐0691‐20‐3 Naphthalene 6.0E‐07 6.0E‐07 6.0E‐07 6.0E‐07 2.4E‐06 2.4E‐06 2.4E‐06 2.4E‐06 2.4E‐067440‐02‐0 Nickel 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐06 8.2E‐06 8.2E‐06 8.2E‐06 8.2E‐06 8.2E‐06

115‐07‐1 Propyleneb ‐‐ ‐‐ ‐‐ ‐‐ 1.1E‐04 1.1E‐04 1.1E‐04 1.1E‐04 1.1E‐047782‐49‐2 Selenium 2.4E‐08 2.4E‐08 2.4E‐08 2.4E‐08 9.4E‐08 9.4E‐08 9.4E‐08 9.4E‐08 9.4E‐08

540‐84‐1 2,2,4‐Trimethylpentaneb ‐‐ ‐‐ ‐‐ ‐‐ 4.5E‐07 4.5E‐07 4.5E‐07 4.5E‐07 4.5E‐07

108‐88‐3 Tolueneb ‐‐ ‐‐ ‐‐ ‐‐ 2.1E‐04 2.1E‐04 2.1E‐04 2.1E‐04 2.1E‐047440‐62‐2 Vanadium 2.3E‐06 2.3E‐06 2.3E‐06 2.3E‐06 9.0E‐06 9.0E‐06 9.0E‐06 9.0E‐06 9.0E‐06

108‐05‐4 VinylAcetatee ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐56‐55‐3 Benz(a)anthracene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0950‐32‐8 Benzo(a)pyrene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09205‐99‐2 Benzo(b)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09207‐08‐9 Benzo(k)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09218‐01‐9 Chrysene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0953‐70‐3 Dibenzo(a,h)anthracene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0956‐49‐5 3‐Methylcholanthrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0957‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐08 1.6E‐08 1.6E‐08 1.6E‐08 6.3E‐08 6.3E‐08 6.3E‐08 6.3E‐08 6.3E‐08

a

b

c

d RTOshutdownandRTObypassemissionsareassumedthesameasthenormaloperationscenarioforTO.e Acrolein,acrylonitrile,vinylacetate,and1,3butadienenotdetectedinTOexhaust.f

EmissionFactorsa

(lb/MMBtu)HourlyEmissionRates

(lb/hr)

EmissionfactorsbasedonAP‐42,Section1.4(NaturalGasCombustion)correctedtolb/mmBtuusingnaturalgasheatcontent(1,020btu/cf).Unlessnoted,theRTOandSCRmode(i.e.bypassorshutdown)shouldnotaffectemissions.Hourlyemissionsbasedon4.0MMBtu/hr.CO,SO2,VOC,hydrogencyanide,ammonia,benzene,bromomethane,carbondisulfide,dichloromethane,hexane,propylene,2,2,4‐trimethylpentane,andtolueneemissionsarebasedonsourcetestresultsaspresentedinpreviousPSDapplication,andscaledupbytheproposedproductionrateversusthecurrentproductionrate(seefootnoteg).Benzene,bromomethane,carbondisulfide,chloromethane,dichloromethane,2,2,4‐trimethylpentane,andtoluenelb/hremissionsbasedonJanuary2013sourcetestresults.AverageofthreeTOexhaustsamples,andemissionsare1/2thedetectionlevelforanymeasurementsbelowdetectionlevel.EmissionforNOXduringnormaloperationstaysat8.5lb/hrbecauseitisbasedonSCRvendorquoteforcombinedexhaustatthemainstack.ItisconservativelyassumedthatPM=PM10=PM2.5.

SCRbypassNOXemissionsarebasedonCEMSdata.OtherpollutantsassumesameemissionsasthenormaloperationsinceSCRisnotacontroldeviceforpollutantsotherthanNOX.

CO2eemissionsarethesumofCH4andN2Oemissionsapplyingfortheglobalwarmingpotentialsbasedonapproachesspecifiedfornaturalgascombustionin40CFRPart98.TheCO2emissionsfromtheTOareassumedtobeincludedintheRTOprocessemissionswhicharebasedonsourcetestresults.

SGL‐MosesLakeFacility

SummaryofLine2Emissions

Table4c.Line2‐HourlyEmissionSummaryforNormalOperation

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Totala

10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.5

630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

VOC VOC 0.2 1.4 0.02 ‐‐ 1.7

CO2e CO2ec 1646.1 0.5 0.55 ‐‐ 1647.2

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrile 5.6E‐03 ‐‐ ‐‐ ‐‐ 5.6E‐03

7664‐41‐7 Ammonia 0.5 0.1 ‐‐ 2.4 3.0

7803‐63‐6 AmmoniumBisulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7783‐20‐2 AmmoniumSulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐06

71‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐04

7440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐07

74‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04

106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐05

75‐15‐0 CarbonDisulfide 2.3E‐03 4.3E‐04 ‐‐ ‐‐ 2.7E‐03

74‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐06

7440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐06

7440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05

106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐05

75‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐07

50‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03

110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐02

74‐90‐8 HydrogenCyanide 1.1 0.3 ‐‐ ‐‐ 1.4

7439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐06

7439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐06

91‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐05

7440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05

115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐04

7782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07

108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐04

7440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05

108‐05‐4 VinylAcetate 5.1E‐03 ‐‐ ‐‐ ‐‐ 5.1E‐03

56‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

50‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

53‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

56‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

57‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07a

b

c

Table4d.Line2‐HourlyEmissionSummaryforSCRBypass

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Total10102‐44‐0 NOX 14.9 3.00 ‐‐ ‐‐ 17.9630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0VOC VOC 0.2 1.4 0.02 ‐‐ 1.7CO2e CO2e 1646.1 0.5 ‐‐ ‐‐ 1646.6

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐107‐13‐1 Acrylonitrile 5.6E‐03 ‐‐ ‐‐ ‐‐ 5.6E‐037664‐41‐7 Ammonia 0.5 0.1 ‐‐ ‐‐ 0.67803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐0671‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐047440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐0774‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐0575‐15‐0 CarbonDisulfide 2.3E‐03 4.3E‐04 ‐‐ ‐‐ 2.7E‐0374‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐067440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐067440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐0575‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐0750‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐0274‐90‐8 HydrogenCyanide 1.1 0.3 ‐‐ ‐‐ 1.47439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐067439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐0691‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐057440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐047782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐047440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05108‐05‐4 VinylAcetate 5.1E‐03 ‐‐ ‐‐ ‐‐ 5.1E‐0356‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0850‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0853‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0856‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0857‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07

a

NOXemissionsarelimitedattheoutletemissionlevelprovidedbytheSCRvendor.PM,PM10andPM2.5emissionsareproposedasasinglelimitatthemainstack.

NormalEmissionRates(lb/hr)

PertheDecember2014PSDapplication,theSCRsystemcontributestheammoniumsulfateandammoniumbisulfateemissionsandarethemaincomponentofPMemissionsfromSCR.

CO2eemissionsarethesumofCH4andN2Oemissionsapplyingfortheglobalwarmingpotentialsbasedonapproachesspecifiedfornaturalgascombustionin40CFRPart98.TheCO2emissionsfromtheSCRHeaterareassumedtobeincludedintheRTOprocessemissionswhicharebasedonsourcetestresults.

SCRBypassEmissionRatesa(lb/hr)

AmmoniaInjectionisnotoperatingduringSCRBypass.

SGL‐MosesLakeFacility

SummaryofLine2Emissions

Table4e.Line2‐HourlyEmissionSummaryforShutdownOperation

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Total10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.5

630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1

PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

VOC VOC 5.6 1.4 0.02 ‐‐ 7.1CO2e CO2e 1,644.9 0.48 0.55 ‐‐ 1645.9

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrile 1.4E‐01 ‐‐ ‐‐ ‐‐ 1.4E‐01

7664‐41‐7 Ammonia 7.5 0.1 ‐‐ 2.4 10.0

7803‐63‐6 AmmoniumBisulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7783‐20‐2 AmmoniumSulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐06

71‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐04

7440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐07

74‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04

106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐05

75‐15‐0 CarbonDisulfide 2.2E‐03 4.3E‐04 ‐‐ ‐‐ 2.7E‐03

74‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐06

7440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐06

7440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05

106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐05

75‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐07

50‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03

110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐02

74‐90‐8 HydrogenCyanide 23.3 0.3 ‐‐ ‐‐ 23.6

7439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐06

7439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐06

91‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐05

7440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05

115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐04

7782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07

108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐04

7440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05

108‐05‐4 VinylAcetate 5.0E‐03 ‐‐ ‐‐ ‐‐ 5.0E‐03

56‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

50‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

53‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

56‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

57‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07a

b

Table4f.Line2‐HourlyEmissionSummaryforRTOBypass

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Total10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.5630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0VOC VOC 7.2 1.4 0.02 ‐‐ 8.6CO2e CO2e 1,644.9 0.48 0.55 ‐‐ 1645.9

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐107‐13‐1 Acrylonitrile 1.7E‐01 ‐‐ ‐‐ ‐‐ 1.7E‐017664‐41‐7 Ammonia 9.5 0.1 ‐‐ ‐‐ 9.67803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐0671‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐047440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐0774‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐0575‐15‐0 CarbonDisulfide 2.2E‐03 4.3E‐04 ‐‐ ‐‐ 2.6E‐0374‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐067440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐067440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐0575‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐0750‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐0274‐90‐8 HydrogenCyanide 29.7 0.3 ‐‐ ‐‐ 30.07439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐067439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐0691‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐057440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐047782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐047440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05108‐05‐4 VinylAcetate 4.9E‐03 ‐‐ ‐‐ ‐‐ 4.9E‐0356‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0850‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0853‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0856‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0857‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07

a

PertheDecember2014PSDapplication,theSCRsystemcontributestheammoniumsulfateandammoniumbisulfateemissionsandarethemaincomponentofPMemissionsfromSCR.

RTOBypassEmissionRates(lb/hr)

DuringanRTOBypassoxidationovenandTOexhaustalsobypasstheSCRsystem,ammoniaInjectionisnotoperated.OxidationovenNOxemissionsarelowerbecausetheRTOcontroldevicegeneratesNOx.

NormalwithShutdownEmissionRates(lb/hr)

NOXemissionsarelimitedattheoutletemissionlevelprovidedbytheSCRvendor.

SGL‐MosesLakeFacility

SummaryofLines3,4,5,and6Emissions (Per Line)

Line3‐6SpecificationsSCRAmmoniaSlip(lb/hr) 2.4

RTOSpecificationsRTOHeaterFiringrate 8.40MMBtu/hrRTOBackupHeaterFiringrate 2.04MMBtu/hrOxidationovenShutdownDuration 90secondsshutdownperDay 1shutdownsperYear 365RTOBypass(hrs/day) 1.5RTOBypass(hrs/yr) 4.5

TOSpecificationsTOHeaterFiringrate 4.00MMBtu/hr

StackExhaustFlowInformationTypicalRTOExhaustgasflowrate 57,400cfm June2013RTOSourceTestResultsLines3,4,5,6Exhaustgasvolumeflow 200,000cfm ShutdownFanInformation‐providedbySemra(SGLACF)during6/26/2013email.

SGL‐MosesLakeFacility

SummaryofLines3,4,5,and6Emissions (Per Line)Table5a.Line3‐6:RTO‐HourlyEmissionSummary

CAS Compound Normal SCRBypass RTOShutdownRTOBypass Normalb SCRBypassc

RTOShutdownd

RTOBypasse

MaximumHourly

10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.50 14.90 8.50 8.50 14.90

630‐08‐0 CO ‐‐ ‐‐ ‐‐ ‐‐ 0.56 0.56 0.56 0.56 0.567446‐09‐05 SO2 ‐‐ ‐‐ ‐‐ ‐‐ 0.68 0.68 0.68 0.68 0.68

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.10 1.10 1.10 1.10 1.10PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 2.00 3.00 2.00 3.00

PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 2.00 3.00 2.00 3.00

VOC VOC ‐‐ ‐‐ ‐‐ ‐‐ 0.24 0.24 5.65 7.20 7.20CO2e CO2e

g ‐‐ ‐‐ ‐‐ ‐‐ 1646.12 1646.12 1644.86 1644.86 1646.12

107‐02‐8 Acroleinf ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrileb,e ‐‐ ‐‐ ‐‐ ‐‐ 5.6E‐03 5.6E‐03 0.14 0.17 0.17

7664‐41‐7 Ammoniab,e ‐‐ ‐‐ ‐‐ ‐‐ 0.50 0.50 7.49 9.50 9.50

7803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐38‐2 Arsenic 2.0E‐07 2.0E‐07 2.0E‐07 2.0E‐07 2.0E‐06 2.0E‐06 2.0E‐06 2.0E‐06 2.0E‐06

71‐43‐2 Benzene 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05

7440‐41‐7 Beryllium 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐07 1.2E‐07 1.2E‐07 1.2E‐07 1.2E‐07

74‐83‐9 Bromomethanef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

106‐99‐0 1,3‐Butadienef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐43‐9 Cadmium 1.1E‐06 1.1E‐06 1.1E‐06 1.1E‐06 1.1E‐05 1.1E‐05 1.1E‐05 1.1E‐05 1.1E‐05

75‐15‐0 CarbonDisulfideb,e ‐‐ ‐‐ ‐‐ ‐‐ 2.3E‐03 2.3E‐03 2.2E‐03 2.2E‐03 2.3E‐03

74‐87‐3 Chloromethanef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

18540‐29‐9 ChromiumVI 5.5E‐08 5.5E‐08 5.5E‐08 5.5E‐08 5.7E‐07 5.7E‐07 5.7E‐07 5.7E‐07 5.7E‐07

7440‐48‐4 Cobalt 8.2E‐08 8.2E‐08 8.2E‐08 8.2E‐08 8.6E‐07 8.6E‐07 8.6E‐07 8.6E‐07 8.6E‐07

7440‐50‐8 Copper 8.3E‐07 8.3E‐07 8.3E‐07 8.3E‐07 8.7E‐06 8.7E‐06 8.7E‐06 8.7E‐06 8.7E‐06

106‐46‐7 Dichlorobenzene 1.2E‐06 1.2E‐06 1.2E‐06 1.2E‐06 1.2E‐05 1.2E‐05 1.2E‐05 1.2E‐05 1.2E‐05

75‐09‐2 Dichloromethanef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

50‐00‐0 Formaldehyde 7.4E‐05 7.4E‐05 7.4E‐05 7.4E‐05 7.7E‐04 7.7E‐04 7.7E‐04 7.7E‐04 7.7E‐04

110‐54‐3 Hexane 1.8E‐03 1.8E‐03 1.8E‐03 1.8E‐03 0.02 0.02 0.02 0.02 0.02

74‐90‐8 HydrogenCyanideb,e ‐‐ ‐‐ ‐‐ ‐‐ 1.10 1.10 23.32 29.70 29.70

7439‐96‐5 Manganese 3.7E‐07 3.7E‐07 3.7E‐07 3.7E‐07 3.9E‐06 3.9E‐06 3.9E‐06 3.9E‐06 3.9E‐06

7439‐97‐6 Mercury 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07 2.7E‐06 2.7E‐06 2.7E‐06 2.7E‐06 2.7E‐06

91‐20‐3 Naphthalene 6.0E‐07 6.0E‐07 6.0E‐07 6.0E‐07 6.2E‐06 6.2E‐06 6.2E‐06 6.2E‐06 6.2E‐06

7440‐02‐0 Nickel 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05 2.1E‐05

115‐07‐1 Propylenef ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7782‐49‐2 Selenium 2.4E‐08 2.4E‐08 2.4E‐08 2.4E‐08 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07

540‐84‐1 2,2,4‐Trimethylpentanek ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

108‐88‐3 Toluene 3.3E‐06 3.3E‐06 3.3E‐06 3.3E‐06 3.5E‐05 3.5E‐05 3.5E‐05 3.5E‐05 3.5E‐05

7440‐62‐2 Vanadium 2.3E‐06 2.3E‐06 2.3E‐06 2.3E‐06 2.4E‐05 2.4E‐05 2.4E‐05 2.4E‐05 2.4E‐05

108‐05‐4 VinylAcetateb,e ‐‐ ‐‐ ‐‐ ‐‐ 5.1E‐03 5.1E‐03 5.0E‐03 4.9E‐03 5.1E‐03

56‐55‐3 Benz(a)anthracene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

50‐32‐8 Benzo(a)pyrene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08

205‐99‐2 Benzo(b)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

207‐08‐9 Benzo(k)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

218‐01‐9 Chrysene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

53‐70‐3 Dibenzo(a,h)anthracene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08

193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

56‐49‐5 3‐Methylcholanthrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08 1.8E‐08

57‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐08 1.6E‐08 1.6E‐08 1.6E‐08 1.6E‐07 1.6E‐07 1.6E‐07 1.6E‐07 1.6E‐07a

b

c

d

e

f

g

HourlyEmissionRates(lb/hr)

EmissionfactorsbasedonAP‐42,Section1.4(NaturalGasCombustion)correctedtolb/MMBtuusingnaturalgasheatcontent(1,020btu/cf).Unlessnoted,theRTOandSCRmode(i.e.bypassorshutdown)shouldnotaffectemissions.Hourlyemissionsbasedon8.4MMBtu/hrfortheRTOand2.0MMBtu/hrfortheBackupRTOburner.CO,SO2,PM,PM10,PM2.5,VOC,acrylonitrile,hydrogencyanide,ammonia,carbondisulfideandvinylacetateemissionsarebasedonsourcetestresultsaspresentedinpreviousPSDapplication.Foracrylonitrile,carbondisulfideandvinylacetate,onlyonesampleinRTOexhaustwasabovedetectionlevel,andemissionsare1/2thedetectionlevelforanymeasurementsbelowdetectionlevel.EmissionforNOXduringnormaloperationstaysat8.5lb/hrbecauseitisbasedonSCRvendorquote.PM,PM10andPM2.5emissionsarebasedonthecurrentPSDpermitlimit(1.1lb/hrforPMand3lb/hrforPM10andPM2.5duringnormaloperationsand2lb/hrduringSCRbypassandRTObypass)forLines3‐6.CO,SO2,VOCemissionsfromnaturalgascombustionbasedonAP‐42Chapter1.4factorsarealsoincludedforthebackupburner.

NOXemissionsduringSCRbypassisbasedon2013sourcetestresultsattheRTOexhaustplustheburneremissions(whicharebasedonAP‐42Section1.4uncontrolledfactors).OtherpollutantsassumesameemissionsasthenormaloperationsinceSCRisnotacontroldeviceforpollutantsotherthanNOX.

TheRTOshutdowneventintroducesfreshairtotheovenswhichresultsinincreaseofemissions,whilekeepingthenormalRTOexhaustsystem.RTOshutdownemissionsareconservativelyestimatedforashutdowneventlastinganhoureventhoughthetypicallengthoftheelevatedemissionlevelsis90seconds.TheemissionsestimatedbyweightedaveragethenormaloperationemissionsandRTObypassemissions(seefootnotee)withtheflowratescorrespondingtotheoperationscenario.

EmissionFactorsa

(lb/MMBtu)

RTObypassemissionsarebasedonRTOinletemissionsfrom2013sourcetesting,includingVOC,acrylonitrile,ammonia,andhydrogencyanide,whichhavehigheremissionsduringRTObypassthannormaloperation.CarbondisulfideandvinylacetateemissionratesbasedonaverageofJanuary2013andJune2013sourcetestresults.OnlyonesampleinRTOexhaustwasabovedetectionlevel,andemissionsare1/2thedetectionlevelforanymeasurementsbelowdetectionlevel.Otherpollutantsassumesameemissionsasthenormaloperationsincetheyareemittedbytheovens.

Acrolein,bromomethane,chloromethane,dichloromethane,propylene,2,2,4‐trimethylpentane,and1,3butadienenotdetectableinRTOinletorexhaust.

CO2emissionsduringnormaloperationarebasedon2013and2014sourcetestingperthe2014PSDapplication.OtherGHGemissions(CH4andN2O)fromnaturalgascombustionattheRTOarealsoaccountedforusingthefiringrateandemissionfactorsbasedon40CFRPart98SubpartC.ThetotalCO2eemissionsarecombinedbasedontheglobalwarmingpotentialsofeachGHGper40CFRPart98SubpartA.NotethatCO2 emissionsfromRTOnaturalgascombustionarenotcalculatedseparatelybecauseitisincludedintheCO2testresult.WhentheRTOisshutdownorbypassed,CH4andN2Oemissionsfromnaturalgascombustionarenotincluded.

SGL‐MosesLakeFacility

SummaryofLines3,4,5,and6Emissions (Per Line)Table5b.Line3‐6:TO‐HourlyEmissionSummary

CAS Compound Normal SCRBypass RTOShutdownRTOBypass Normalb SCRBypassc

RTOShutdownd

RTOBypassd

MaximumHourly

10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.50 3.00 8.50 8.50 8.50630‐08‐0 CO ‐‐ ‐‐ ‐‐ ‐‐ 0.39 0.39 0.39 0.39 0.397446‐09‐05 SO2 5.9E‐04 5.9E‐04 5.9E‐04 5.9E‐04 2.4E‐03 2.4E‐03 2.4E‐03 2.4E‐03 2.4E‐03

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.10 1.10 1.10 1.10 1.10PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 2.00 3.00 3.00 3.00PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.00 2.00 3.00 3.00 3.00VOC VOC ‐‐ ‐‐ ‐‐ ‐‐ 1.42 1.42 1.42 1.42 1.42

CO2e CO2ef 0.12 0.12 0.12 0.12 0.48 0.48 0.48 0.48 0.48

107‐02‐8 Acroleine ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrilee ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7664‐41‐7 Ammoniab ‐‐ ‐‐ ‐‐ ‐‐ 0.13 0.13 0.13 0.13 0.137803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐38‐2 Arsenic 2.0E‐07 2.0E‐07 2.0E‐07 2.0E‐07 7.8E‐07 7.8E‐07 7.8E‐07 7.8E‐07 7.8E‐07

71‐43‐2 Benzeneb ‐‐ ‐‐ ‐‐ ‐‐ 1.4E‐04 1.4E‐04 1.4E‐04 1.4E‐04 1.4E‐047440‐41‐7 Beryllium 1.2E‐08 1.2E‐08 1.2E‐08 1.2E‐08 4.7E‐08 4.7E‐08 4.7E‐08 4.7E‐08 4.7E‐08

74‐83‐9 Bromomethaneb ‐‐ ‐‐ ‐‐ ‐‐ 1.8E‐04 1.8E‐04 1.8E‐04 1.8E‐04 1.8E‐04

106‐99‐0 1,3‐Butadienee ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐43‐9 Cadmium 1.1E‐06 1.1E‐06 1.1E‐06 1.1E‐06 4.3E‐06 4.3E‐06 4.3E‐06 4.3E‐06 4.3E‐06

75‐15‐0 CarbonDisulfideb ‐‐ ‐‐ ‐‐ ‐‐ 4.3E‐04 4.3E‐04 4.3E‐04 4.3E‐04 4.3E‐04

74‐87‐3 Chloromethaneb ‐‐ ‐‐ ‐‐ ‐‐ 6.2E‐05 6.2E‐05 6.2E‐05 6.2E‐05 6.2E‐0518540‐29‐9 ChromiumVI 5.5E‐08 5.5E‐08 5.5E‐08 5.5E‐08 2.2E‐07 2.2E‐07 2.2E‐07 2.2E‐07 2.2E‐077440‐48‐4 Cobalt 8.2E‐08 8.2E‐08 8.2E‐08 8.2E‐08 3.3E‐07 3.3E‐07 3.3E‐07 3.3E‐07 3.3E‐077440‐50‐8 Copper 8.3E‐07 8.3E‐07 8.3E‐07 8.3E‐07 3.3E‐06 3.3E‐06 3.3E‐06 3.3E‐06 3.3E‐06106‐46‐7 Dichlorobenzene 1.2E‐06 1.2E‐06 1.2E‐06 1.2E‐06 4.7E‐06 4.7E‐06 4.7E‐06 4.7E‐06 4.7E‐06

75‐09‐2 Dichloromethaneb ‐‐ ‐‐ ‐‐ ‐‐ 5.9E‐07 5.9E‐07 5.9E‐07 5.9E‐07 5.9E‐0750‐00‐0 Formaldehyde 7.4E‐05 7.4E‐05 7.4E‐05 7.4E‐05 2.9E‐04 2.9E‐04 2.9E‐04 2.9E‐04 2.9E‐04

110‐54‐3 Hexaneb ‐‐ ‐‐ ‐‐ ‐‐ 1.9E‐03 1.9E‐03 1.9E‐03 1.9E‐03 1.9E‐03

74‐90‐8 HydrogenCyanideb ‐‐ ‐‐ ‐‐ ‐‐ 0.27 0.27 0.27 0.27 0.277439‐96‐5 Manganese 3.7E‐07 3.7E‐07 3.7E‐07 3.7E‐07 1.5E‐06 1.5E‐06 1.5E‐06 1.5E‐06 1.5E‐067439‐97‐6 Mercury 2.5E‐07 2.5E‐07 2.5E‐07 2.5E‐07 1.0E‐06 1.0E‐06 1.0E‐06 1.0E‐06 1.0E‐0691‐20‐3 Naphthalene 6.0E‐07 6.0E‐07 6.0E‐07 6.0E‐07 2.4E‐06 2.4E‐06 2.4E‐06 2.4E‐06 2.4E‐067440‐02‐0 Nickel 2.1E‐06 2.1E‐06 2.1E‐06 2.1E‐06 8.2E‐06 8.2E‐06 8.2E‐06 8.2E‐06 8.2E‐06

115‐07‐1 Propyleneb ‐‐ ‐‐ ‐‐ ‐‐ 1.1E‐04 1.1E‐04 1.1E‐04 1.1E‐04 1.1E‐047782‐49‐2 Selenium 2.4E‐08 2.4E‐08 2.4E‐08 2.4E‐08 9.4E‐08 9.4E‐08 9.4E‐08 9.4E‐08 9.4E‐08

540‐84‐1 2,2,4‐Trimethylpentaneb ‐‐ ‐‐ ‐‐ ‐‐ 4.5E‐07 4.5E‐07 4.5E‐07 4.5E‐07 4.5E‐07

108‐88‐3 Tolueneb ‐‐ ‐‐ ‐‐ ‐‐ 2.1E‐04 2.1E‐04 2.1E‐04 2.1E‐04 2.1E‐047440‐62‐2 Vanadium 2.3E‐06 2.3E‐06 2.3E‐06 2.3E‐06 9.0E‐06 9.0E‐06 9.0E‐06 9.0E‐06 9.0E‐06

108‐05‐4 VinylAcetatee ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐ ‐‐56‐55‐3 Benz(a)anthracene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0950‐32‐8 Benzo(a)pyrene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09205‐99‐2 Benzo(b)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09207‐08‐9 Benzo(k)fluoranthene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09218‐01‐9 Chrysene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0953‐70‐3 Dibenzo(a,h)anthracene 1.2E‐09 1.2E‐09 1.2E‐09 1.2E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09 4.7E‐09193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0956‐49‐5 3‐Methylcholanthrene 1.8E‐09 1.8E‐09 1.8E‐09 1.8E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐09 7.1E‐0957‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐08 1.6E‐08 1.6E‐08 1.6E‐08 6.3E‐08 6.3E‐08 6.3E‐08 6.3E‐08 6.3E‐08

a

b

c

d RTOshutdownandRTObypassemissionsareassumedthesameasthenormaloperationscenarioforTO.e Acrolein,acrylonitrile,vinylacetate,and1,3butadienenotdetectedinTOexhaust.f

CO,SO2,VOC,hydrogencyanide,ammonia,benzene,bromomethane,carbondisulfide,dichloromethane,hexane,propylene,2,2,4‐trimethylpentane,andtolueneemissionsarebasedonsourcetestresultsaspresentedinpreviousPSDapplication.Benzene,bromomethane,carbondisulfide,chloromethane,dichloromethane,2,2,4‐trimethylpentane,andtoluenelb/hremissionsbasedonJanuary2013sourcetestresults.AverageofthreeTOexhaustsamples,andemissionsare1/2thedetectionlevelforanymeasurementsbelowdetectionlevel.EmissionforNOXduringnormaloperationstaysat8.5lb/hrbecauseitisbasedonSCRvendorquoteforcombinedexhaustatthemainstack.PM,PM10

andPM2.5emissionsarebasedonthecurrentPSDpermitlimit(3lb/hrduringnormaloperationsand2lb/hrduringSCRbypassandRTObypass)inclusiveofallsources.ItisconservativelyassumedthatPM=PM10=PM2.5.

SCRbypassNOXemissionsarebasedonCEMSdata.OtherpollutantsassumesameemissionsasthenormaloperationsinceSCRisnotacontroldeviceforpollutantsotherthanNOX.

CO2eemissionsarethesumofCH4andN2Oemissionsapplyingfortheglobalwarmingpotentialsbasedonapproachesspecifiedfornaturalgascombustionin40CFRPart98.TheCO2emissionsfromtheTOareassumedtobeincludedintheRTOprocessemissionswhicharebasedonsourcetestresults.

EmissionfactorsbasedonAP‐42,Section1.4(NaturalGasCombustion)correctedtolb/mmBtuusingnaturalgasheatcontent(1,020btu/cf).Unlessnoted,theRTOandSCRmode(i.e.bypassorshutdown)shouldnotaffectemissions.Hourlyemissionsbasedon4.0MMBtu/hr.

EmissionFactorsa

(lb/MMBtu)HourlyEmissionRates

(lb/hr)

SGL‐MosesLakeFacility

SummaryofLines3,4,5,and6Emissions (Per Line)Table5c.Lines3‐6:HourlyEmissionSummaryforNormalOperation

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Totala

10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.5

630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

VOC VOC 0.2 1.4 0.02 ‐‐ 1.7

CO2e CO2ec 1646.1 0.5 0.55 ‐‐ 1647.2

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrile 5.6E‐03 ‐‐ ‐‐ ‐‐ 5.6E‐03

7664‐41‐7 Ammonia 0.5 0.1 ‐‐ 2.4 3.0

7803‐63‐6 AmmoniumBisulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7783‐20‐2 AmmoniumSulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐06

71‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐04

7440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐07

74‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04

106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐05

75‐15‐0 CarbonDisulfide 2.3E‐03 4.3E‐04 ‐‐ ‐‐ 2.7E‐03

74‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐06

7440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐06

7440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05

106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐05

75‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐07

50‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03

110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐02

74‐90‐8 HydrogenCyanide 1.1 0.3 ‐‐ ‐‐ 1.4

7439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐06

7439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐06

91‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐05

7440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05

115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐04

7782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07

108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐04

7440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05

108‐05‐4 VinylAcetate 5.1E‐03 ‐‐ ‐‐ ‐‐ 5.1E‐03

56‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

50‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

53‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

56‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

57‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07a

b

c

PertheDecember2014PSDapplication,theSCRsystemcontributestheammoniumsulfateandammoniumbisulfateemissionsandarethemaincomponentofPMemissionsfromSCR.CO2eemissionsarethesumofCH4andN2Oemissionsapplyingfortheglobalwarmingpotentialsbasedonapproachesspecifiedfornaturalgascombustionin40CFRPart98.TheCO2emissionsfromtheSCRHeaterareassumedtobeincludedintheRTOprocessemissionswhicharebasedonsourcetestresults.

NOXemissionsarelimitedattheoutletemissionlevelprovidedbytheSCRvendor.PM,PM10andPM2.5emissionsareproposedasasinglelimitatthemainstack.

NormalEmissionRates(lb/hr)

SGL‐MosesLakeFacility

SummaryofLines3,4,5,and6Emissions (Per Line)

Table5d.Lines3‐6:HourlyEmissionSummaryforSCRBypass

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Total10102‐44‐0 NOX 14.9 3.00 ‐‐ ‐‐ 17.9630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 2.0PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 2.0VOC VOC 0.2 1.4 0.02 ‐‐ 1.7CO2e CO2e 1646.1 0.5 ‐‐ ‐‐ 1646.6

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐107‐13‐1 Acrylonitrile 5.6E‐03 ‐‐ ‐‐ ‐‐ 5.6E‐037664‐41‐7 Ammonia 0.5 0.1 ‐‐ ‐‐ 0.67803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐0671‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐047440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐0774‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐0575‐15‐0 CarbonDisulfide 2.3E‐03 4.3E‐04 ‐‐ ‐‐ 2.7E‐0374‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐067440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐067440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐0575‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐0750‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐0274‐90‐8 HydrogenCyanide 1.1 0.3 ‐‐ ‐‐ 1.47439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐067439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐0691‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐057440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐047782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐047440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05108‐05‐4 VinylAcetate 5.1E‐03 ‐‐ ‐‐ ‐‐ 5.1E‐0356‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0850‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0853‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0856‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0857‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07

a

SCRBypassEmissionRatesa(lb/hr)

AmmoniaInjectionisnotoperatingduringSCRBypass.

SGL‐MosesLakeFacility

SummaryofLines3,4,5,and6Emissions (Per Line)

Table5e.Lines3‐6:‐HourlyEmissionSummaryforShutdownOperation

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Total10102‐44‐0 NOX ‐‐ ‐‐ ‐‐ ‐‐ 8.5

630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1

PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 3.0

VOC VOC 5.6 1.4 0.02 ‐‐ 7.1

CO2e CO2e 1,644.9 0.48 0.55 ‐‐ 1645.9

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

107‐13‐1 Acrylonitrile 1.4E‐01 ‐‐ ‐‐ ‐‐ 1.4E‐01

7664‐41‐7 Ammonia 7.5 0.1 ‐‐ 2.4 10.0

7803‐63‐6 AmmoniumBisulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7783‐20‐2 AmmoniumSulfateb ‐‐ ‐‐ ‐‐ 3.0 3.0

7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐06

71‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐04

7440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐07

74‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04

106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐

7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐05

75‐15‐0 CarbonDisulfide 2.2E‐03 4.3E‐04 ‐‐ ‐‐ 2.7E‐03

74‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐06

7440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐06

7440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05

106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐05

75‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐07

50‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03

110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐02

74‐90‐8 HydrogenCyanide 23.3 0.3 ‐‐ ‐‐ 23.6

7439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐06

7439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐06

91‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐05

7440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05

115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐04

7782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07

108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐04

7440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05

108‐05‐4 VinylAcetate 5.0E‐03 ‐‐ ‐‐ ‐‐ 5.0E‐03

56‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

50‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

53‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08

193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

56‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08

57‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07a

b

NormalwithShutdownEmissionRates(lb/hr)

NOXemissionsarelimitedattheoutletemissionlevelprovidedbytheSCRvendor.

PertheDecember2014PSDapplication,theSCRsystemcontributestheammoniumsulfateandammoniumbisulfateemissionsandarethemaincomponentofPMemissionsfromSCR.

SGL‐MosesLakeFacility

SummaryofLines3,4,5,and6Emissions (Per Line)

Table5f.Lines3‐6:HourlyEmissionSummaryforRTOBypass

CAS Compound OxidationOvens Furnaces SCRHeater

SCRAmmonia

Slip Total10102‐44‐0 NOx ‐‐ ‐‐ ‐‐ ‐‐ 8.5630‐08‐0 CO 0.6 0.4 0.4 ‐‐ 1.37446‐09‐05 SO2 0.7 2.4E‐03 2.7E‐03 ‐‐ 0.7

PM PM(Filt.) ‐‐ ‐‐ ‐‐ ‐‐ 1.1PM10 PM10(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 2.0PM2.5 PM2.5(Filt.&Cond.) ‐‐ ‐‐ ‐‐ ‐‐ 2.0VOC VOC 7.2 1.4 0.02 ‐‐ 8.6CO2e CO2e 1,644.9 0.48 0.55 ‐‐ 1645.9

107‐02‐8 Acrolein ‐‐ ‐‐ ‐‐ ‐‐ ‐‐107‐13‐1 Acrylonitrile 1.7E‐01 ‐‐ ‐‐ ‐‐ 1.7E‐017664‐41‐7 Ammonia 9.5 0.1 ‐‐ ‐‐ 9.67803‐63‐6 AmmoniumBisulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7783‐20‐2 AmmoniumSulfate ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐38‐2 Arsenic 2.0E‐06 7.8E‐07 9.0E‐07 ‐‐ 3.7E‐0671‐43‐2 Benzene 2.1E‐05 1.4E‐04 9.5E‐06 ‐‐ 1.7E‐047440‐41‐7 Beryllium 1.2E‐07 4.7E‐08 5.4E‐08 ‐‐ 2.2E‐0774‐83‐9 Bromomethane ‐‐ 1.8E‐04 ‐‐ ‐‐ 1.8E‐04106‐99‐0 1,3‐Butadiene ‐‐ ‐‐ ‐‐ ‐‐ ‐‐7440‐43‐9 Cadmium 1.1E‐05 4.3E‐06 5.0E‐06 ‐‐ 2.1E‐0575‐15‐0 CarbonDisulfide 2.2E‐03 4.3E‐04 ‐‐ ‐‐ 2.6E‐0374‐87‐3 Chloromethane ‐‐ 6.2E‐05 ‐‐ ‐‐ 6.2E‐05

18540‐29‐9 ChromiumVI 5.7E‐07 2.2E‐07 2.5E‐07 ‐‐ 1.0E‐067440‐48‐4 Cobalt 8.6E‐07 3.3E‐07 3.8E‐07 ‐‐ 1.6E‐067440‐50‐8 Copper 8.7E‐06 3.3E‐06 3.8E‐06 ‐‐ 1.6E‐05106‐46‐7 Dichlorobenzene 1.2E‐05 4.7E‐06 5.4E‐06 ‐‐ 2.2E‐0575‐09‐2 Dichloromethane ‐‐ 5.9E‐07 ‐‐ ‐‐ 5.9E‐0750‐00‐0 Formaldehyde 7.7E‐04 2.9E‐04 3.4E‐04 ‐‐ 1.4E‐03110‐54‐3 Hexane 1.8E‐02 1.9E‐03 8.1E‐03 ‐‐ 2.8E‐0274‐90‐8 HydrogenCyanide 29.7 0.3 ‐‐ ‐‐ 30.07439‐96‐5 Manganese 3.9E‐06 1.5E‐06 1.7E‐06 ‐‐ 7.1E‐067439‐97‐6 Mercury 2.7E‐06 1.0E‐06 1.2E‐06 ‐‐ 4.9E‐0691‐20‐3 Naphthalene 6.2E‐06 2.4E‐06 2.8E‐06 ‐‐ 1.1E‐057440‐02‐0 Nickel 2.1E‐05 8.2E‐06 9.5E‐06 ‐‐ 3.9E‐05115‐07‐1 Propylene ‐‐ 1.1E‐04 ‐‐ ‐‐ 1.1E‐047782‐49‐2 Selenium 2.5E‐07 9.4E‐08 1.1E‐07 ‐‐ 4.5E‐07108‐88‐3 Toluene 3.5E‐05 2.1E‐04 1.5E‐05 ‐‐ 2.6E‐047440‐62‐2 Vanadium 2.4E‐05 9.0E‐06 1.0E‐05 ‐‐ 4.3E‐05108‐05‐4 VinylAcetate 4.9E‐03 ‐‐ ‐‐ ‐‐ 4.9E‐0356‐55‐3 Benz(a)anthracene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0850‐32‐8 Benzo(a)pyrene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08205‐99‐2 Benzo(b)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08207‐08‐9 Benzo(k)fluoranthene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐08218‐01‐9 Chrysene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0853‐70‐3 Dibenzo(a,h)anthracene 1.2E‐08 4.7E‐09 5.4E‐09 ‐‐ 2.2E‐08193‐39‐5 Indeno(1,2,3‐cd)pyrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0856‐49‐5 3‐Methylcholanthrene 1.8E‐08 7.1E‐09 8.1E‐09 ‐‐ 3.4E‐0857‐97‐6 7,12‐Dimethylbenz[a]anthracene 1.6E‐07 6.3E‐08 7.2E‐08 ‐‐ 3.0E‐07

a

RTOBypassEmissionRates(lb/hr)

DuringanRTOBypassoxidationovenandTOexhaustalsobypasstheSCRsystem,ammoniaInjectionisnotoperated.OxidationovenNOxemissionsarelowerbecausetheRTOcontroldevicegeneratesNOx.

SGL‐MosesLakeFacility

EmergencyGeneratorsandFirewaterPumps(Lines1&2,10smalleremergencygenerators)GeneratorSpecifications Constants

TotalNumberOfGenerators 10 SGLACF 1020 Btu/ft3natgasMaxGeneratorsTestedTogether 10 SGLACFTotalNumberOfFirewaterPumps 2 SGLACFTestingTime 30minutes/test (perengine)Testsperyear 52 (perengine)TestingHours 26hours/year (perengine,fromSGLACF)Once/yeartestofFWP 4hours/year (in1dayonFWP)EmergencyHours 8hours/year (perengine,fromEcology)TotalOperatinghours‐EGEN 34hours/year (perengine)TotalOperatinghours‐FWP 38hours/yearDesigncapacity 454.00hp (perengine,specsheet)FuelConsumption 4,100cf/h (perengine@100%load,specsheet)InletCapacity 4.2MMBtu/hr (perengine@100%load)

Table6a.EmissionsforEachEmergencyGenerator

Pollutant Cas# g/bhp‐hr lb/MMBtu lb/hr lb/day lb/yrNOX 10102‐44‐0 2.0 ‐ 2.00 2.00 68.1CO 630‐08‐0 4.0 ‐ 4.00 4.00 136.1SO2 7446‐09‐05 ‐ 5.88E‐04 0.003 0.003 0.10VOC VOC 1.0 ‐ 1.00 1.00 34.0PM(filterable) PM ‐ 9.50E‐03 0.02 0.02 0.7PM10(filterable+condensable) PM10 ‐ 1.94E‐02 0.08 0.08 2.8PM2.5(filterable+condensable) PM2.5 ‐ 1.94E‐02 0.08 0.08 2.81,1,2,2‐Tetrachloroethane 79‐34‐5 ‐ 2.53E‐05 5.3E‐05 5.3E‐05 1.8E‐031,1,2‐Trichloroethane 79‐00‐5 ‐ 1.53E‐05 3.2E‐05 3.2E‐05 1.1E‐031,1‐Dichloroethane 75‐34‐3 ‐ 1.13E‐05 2.4E‐05 2.4E‐05 8.0E‐041,2‐Dichloroethane 107‐06‐2 ‐ 1.13E‐05 2.4E‐05 2.4E‐05 8.0E‐041,2‐Dichloropropane 78‐87‐5 ‐ 1.30E‐05 2.7E‐05 2.7E‐05 9.2E‐041,3‐Butadiene 106‐99‐0 ‐ 6.63E‐04 0.001 0.001 0.051,3‐Dichloropropene 542‐75‐6 ‐ 1.27E‐05 2.7E‐05 2.7E‐05 9.0E‐04Acetaldehyde 75‐07‐0 ‐ 2.79E‐03 0.006 0.006 0.2Acrolein 107‐02‐8 ‐ 2.63E‐03 0.005 0.005 0.2Benzene 71‐43‐2 ‐ 1.58E‐03 0.003 0.003 0.1CarbonTetrachloride 56‐23‐5 ‐ 1.77E‐05 3.7E‐05 3.7E‐05 1.3E‐03Chlorobenzene 108‐90‐7 ‐ 1.29E‐05 2.7E‐05 2.7E‐05 9.2E‐04Chloroform 67‐66‐3 ‐ 1.37E‐05 2.9E‐05 2.9E‐05 9.7E‐04Ethylbenzene 100‐41‐4 ‐ 2.48E‐05 5.2E‐05 5.2E‐05 1.8E‐03EthyleneDibromide 106‐93‐4 ‐ 2.13E‐05 4.5E‐05 4.5E‐05 1.5E‐03Formaldehyde 50‐00‐0 ‐ 2.05E‐02 0.043 0.043 1.5Methanol 67‐56‐1 ‐ 3.06E‐03 0.006 0.006 0.2MethyleneChloride 75‐09‐2 ‐ 4.12E‐05 8.6E‐05 8.6E‐05 2.9E‐03Naphthalene 91‐20‐3 ‐ 9.71E‐05 2.0E‐04 2.0E‐04 6.9E‐03Styrene 100‐42‐5 ‐ 1.19E‐05 2.5E‐05 2.5E‐05 8.5E‐04Toluene 108‐88‐3 ‐ 5.58E‐04 0.001 0.001 0.04VinylChloride 75‐01‐4 ‐ 7.18E‐06 1.5E‐05 1.5E‐05 5.1E‐04Xylene 1330‐20‐7 ‐ 1.95E‐04 0.0004 0.0004 0.01CO2 CO2 ‐ 1.10E+02 230 230 7,820CH4 CH4 ‐ 2.20E‐03 0.0046 0.0046 0.16N2O N2O ‐ 2.20E‐04 0.0005 0.0005 0.02

CO2eb CO2e ‐ ‐ 230 230 7,829notes:

(Totalhourlyemissionsbasedon10enginesoperatingfor30minutes,Dailyemissionsbasedon10enginesoperatingfor30minutes(testing),andAnnualemissionsbasedon52thirtyminutetestsand8hrs/yrofemergencyoperation)

EmissionFactoraTestingOperationsSingleEngineEmissionRate

a‐NOX,CO,PM10/PM2.5,SO2andVOChourlyemissionratesarebasedonhourlyemissionlimitsinApprovalOrderNo.15AQ‐E636.AllotheremissionfactorsarefromAP42,Table3.2‐3.Methaneandnitrousoxideemissionfactorsfrom40CFR98,SubpartC,TableC‐1.

b‐CO2ecalculatedbasedonglobalwarmingpotential(GWP)foreachGreenhousegas:CO2=1;CH4=25;andN2O=298(40CFRPart98,SubpartA).

SGL‐MosesLakeFacility

EmergencyGeneratorsandFirewaterPumps(Lines1&2,10smalleremergencygenerators)

Table6b.EmissionsforEachFirewaterPump

Pollutant Cas# g/bhp‐hr lb/MMBtu lb/hr lb/day lb/yrNOX(NSPSStandard) 10102‐44‐0 2.00 ‐ 2.00 8.0 76.1CO(NSPSStandard) 630‐08‐0 4.0 ‐ 4.00 16.0 152.1SO2 7446‐09‐05 ‐ 5.88E‐04 0.003 0.01 0.11VOC VOC 1.0 ‐ 1.00 4.0 38.0PM(filterable) PM ‐ 9.50E‐03 0.04 0.2 1.5PM10(filterable+condensable) PM10 ‐ 1.94E‐02 0.08 0.3 3.1PM2.5(filterable+condensable) PM2.5 ‐ 1.94E‐02 0.08 0.3 3.11,1,2,2‐Tetrachloroethane 79‐34‐5 ‐ 2.53E‐05 1.1E‐04 4.2E‐04 4.0E‐031,1,2‐Trichloroethane 79‐00‐5 ‐ 1.53E‐05 6.4E‐05 2.6E‐04 2.4E‐031,1‐Dichloroethane 75‐34‐3 ‐ 1.13E‐05 4.7E‐05 1.9E‐04 1.8E‐031,2‐Dichloroethane 107‐06‐2 ‐ 1.13E‐05 4.7E‐05 1.9E‐04 1.8E‐031,2‐Dichloropropane 78‐87‐5 ‐ 1.30E‐05 5.4E‐05 2.2E‐04 2.1E‐031,3‐Butadiene 106‐99‐0 ‐ 6.63E‐04 0.0028 0.011 0.111,3‐Dichloropropene 542‐75‐6 ‐ 1.27E‐05 5.3E‐05 2.1E‐04 2.0E‐03Acetaldehyde 75‐07‐0 ‐ 2.79E‐03 0.012 0.047 0.4Acrolein 107‐02‐8 ‐ 2.63E‐03 0.011 0.044 0.4Benzene 71‐43‐2 ‐ 1.58E‐03 0.0066 0.026 0.3CarbonTetrachloride 56‐23‐5 ‐ 1.77E‐05 7.4E‐05 3.0E‐04 2.8E‐03Chlorobenzene 108‐90‐7 ‐ 1.29E‐05 5.4E‐05 2.2E‐04 2.1E‐03Chloroform 67‐66‐3 ‐ 1.37E‐05 5.7E‐05 2.3E‐04 2.2E‐03Ethylbenzene 100‐41‐4 ‐ 2.48E‐05 1.0E‐04 4.1E‐04 3.9E‐03EthyleneDibromide 106‐93‐4 ‐ 2.13E‐05 8.9E‐05 3.6E‐04 3.4E‐03Formaldehyde 50‐00‐0 ‐ 2.05E‐02 0.086 0.3 3.3Methanol 67‐56‐1 ‐ 3.06E‐03 0.013 0.05 0.5MethyleneChloride 75‐09‐2 ‐ 4.12E‐05 1.7E‐04 6.9E‐04 6.5E‐03Naphthalene 91‐20‐3 ‐ 9.71E‐05 4.1E‐04 1.6E‐03 1.5E‐02Styrene 100‐42‐5 ‐ 1.19E‐05 5.0E‐05 2.0E‐04 1.9E‐03Toluene 108‐88‐3 ‐ 5.58E‐04 0.002 0.009 0.09VinylChloride 75‐01‐4 ‐ 7.18E‐06 3.0E‐05 1.2E‐04 1.1E‐03Xylene 1330‐20‐7 ‐ 1.95E‐04 0.0008 0.003 0.03CO2 CO2 ‐ 1.10E+02 460 1,840 17,481CH4 CH4 ‐ 2.20E‐03 0.0092 0.037 0.35N2O N2O ‐ 2.20E‐04 0.0009 0.004 0.03

CO2eb CO2e ‐ ‐ 461 1,842 17,500notes:

a‐NOXandCOemissionfactorsbasedonGeneracNSPScertificationtesting(maximumof2010and2012testing).VOCemissionfactorisbasedonNSPScertificationlevel.AllotheremissionfactorsarefromAP42,Table3.2‐3.Methaneandnitrousoxideemissionfactorsfrom40CFR98,SubpartC,TableC‐1.

b‐CO2ecalculatedbasedonglobalwarmingpotential(GWP)foreachGreenhousegas:CO2=1;CH4=25;andN2O=298(40CFRPart98,SubpartA).

FirewaterPump(testsfor30minutesonceperweek,withanadditional4hourtestonceperyear).Alsoinclude8hoursofemergencyusageintheannualemissionratecalculation.

EmissionFactoraOneFWPEmissionsEmissionRate

SGL‐MosesLakeFacility

EmergencyGenerators(Lines3‐6)CAT3516C2000ekWStandbyTier4Engines‐ULSDFuel

EngineSpecificationsTotalNumberofGens 4 SGLACFMaxGeneratorstestedtogether 1 SGLACFMaxGeneratorstestedperday 4 SGLACFRoutineTestingTime 2hours/test (perengine)ReliabilityTestsperYear 4 (perengine)ReliabilityTestinghours 8hours/yr (perengine,fromSGLACF)PerformanceTestinghours 8hours/yr (oneengineevery60months,continuesfromaquarterlytest)Emergencyhours 8hour/year (perengine,fromEcology)Startuptime 10min/startup (perengine,fromEcology)Numberofstartups 5 (perengine)TotalStartupHours 0.7hour/year (perengine,onestartuppertestandonestartupforbothregenerationandemergencyoperation)TotalControlledHours 15.3hour/year (perengine,fromEcology)TotalNormalOperatingHours 16.0hour/year (perengine)Gen.SetOutputRating 2,937hp (bhp,specsheet)DieselFuelHeatContent 139MMBtu/MgalNormalOperatingLoad 70% (VendorData)Performancetestandemergencyuseoperatingload 100% (maximumpossible)EngineInformationMaximumFuelUseRate 138.0gal/hrPowerRating 2,000ekW

Page 1 of 2

SGL‐MosesLakeFacility

EmergencyGenerators(Lines3‐6)CAT3516C2000ekWStandbyTier4Engines‐ULSDFuelTable7a.Lines3‐6EmergencyGeneratorEmissions

CAS Compound Startupg/hp‐hrControlled70%g/hp‐hr

Controlled100%g/hp‐hr lb/hp‐hr lb/MMBtuc lb/hr lb/day lb/yr lb/hr lb/day lb/yr lb/hr lb/day lb/yr lb/hr lb/day lb/yr

10102‐44‐0 NOxa 4.4 0.75 0.50 ‐‐ ‐‐ 7.58 10.98 43.90 7.58 31.36 31.36 3.40 27.17 27.17 30.32 125.42 328.21

630‐08‐0 COa 3.3 0.54 0.54 ‐‐ ‐‐ 6.43 9.93 39.72 6.43 30.91 30.91 3.50 27.97 27.97 25.74 123.64 310.50

PM PMa ‐‐ 0.034 0.034 ‐‐ ‐‐ 0.22 0.43 1.74 0.22 1.74 1.74 0.22 1.74 1.74 0.87 6.95 15.64

PM10 PM10a ‐‐ 0.034 0.010 ‐‐ ‐‐ 0.15 0.30 1.22 0.06 0.52 0.52 0.15 1.22 1.22 0.26 2.43 8.16

PM2.5 PM2.5a ‐‐ 0.034 0.010 ‐‐ ‐‐ 0.15 0.30 1.22 0.06 0.52 0.52 0.15 1.22 1.22 0.26 2.43 8.16

7446‐09‐05 SO2b ‐‐ 1.2E‐05 ‐‐ 0.04 0.07 0.29 0.04 0.29 0.29 0.04 0.29 0.29 0.14 1.14 2.57

VOC VOCa 0.25 0.05 0.03 ‐‐ ‐‐ 0.46 0.69 2.74 0.46 2.04 2.04 0.23 1.81 1.81 1.83 8.18 20.96

CO2 CO2e ‐‐ ‐‐ 1.6E+02 3127.65 6255.29 25021.18 3127.65 25021.18 25021.18 3127.65 25021.18 25021.18 12510.59 100084.71 225190.59

CH4 CH4e ‐‐ ‐‐ 6.6E‐03 0.13 0.25 1.01 0.13 1.01 1.01 0.13 1.01 1.01 0.51 4.06 9.13

N2O N2Oe ‐‐ ‐‐ 1.3E‐03 0.03 0.05 0.20 0.03 0.20 0.20 0.03 0.20 0.20 0.10 0.81 1.83

CO2e CO2ef ‐‐ ‐‐ ‐‐ 3138.38 6276.76 25107.04 3138.38 25107.04 25107.04 3138.38 25107.04 25107.04 12553.52 100428.16 225963.3575‐07‐0 Acetaldehyde ‐‐ ‐‐ 2.52E‐05 4.83E‐04 9.67E‐04 3.87E‐03 4.83E‐04 3.87E‐03 3.87E‐03 4.83E‐04 3.87E‐03 3.87E‐03 1.93E‐03 0.02 0.03107‐02‐8 Acrolein ‐‐ ‐‐ 7.88E‐06 1.51E‐04 3.02E‐04 1.21E‐03 1.51E‐04 1.21E‐03 1.21E‐03 1.51E‐04 1.21E‐03 1.21E‐03 6.05E‐04 4.84E‐03 1.09E‐0271‐43‐2 Benzene ‐‐ ‐‐ 7.76E‐04 1.49E‐02 0.03 0.12 1.49E‐02 0.12 0.12 1.49E‐02 0.12 0.12 0.06 0.48 1.07

DPM DEEPd ‐‐ ‐‐ ‐‐ 0.13 0.26 1.05 0.06 0.45 0.45 0.13 1.05 1.05 0.22 2.11 7.0650‐00‐0 Formaldehyde ‐‐ ‐‐ 7.89E‐05 1.51E‐03 3.03E‐03 1.21E‐02 1.51E‐03 1.21E‐02 1.21E‐02 1.51E‐03 1.21E‐02 1.21E‐02 6.05E‐03 0.05 0.1191‐20‐3 Naphthalene ‐‐ ‐‐ 1.40E‐04 2.69E‐03 5.37E‐03 0.02 2.69E‐03 0.02 0.02 2.69E‐03 0.02 0.02 1.07E‐02 0.09 0.19115‐07‐1 Propylene ‐‐ ‐‐ 2.79E‐03 0.05 0.11 0.43 0.05 0.43 0.43 0.05 0.43 0.43 0.21 1.71 3.85108‐88‐3 Toluene ‐‐ ‐‐ 2.81E‐04 5.39E‐03 1.08E‐02 0.04 5.39E‐03 0.04 0.04 5.39E‐03 0.04 0.04 0.02 0.17 0.391330‐20‐7 Xylenes ‐‐ ‐‐ 1.93E‐04 3.70E‐03 7.40E‐03 0.03 3.70E‐03 0.03 0.03 3.70E‐03 0.03 0.03 1.48E‐02 0.12 0.2750‐32‐8 Benzo(a)pyrene ‐‐ ‐‐ 2.57E‐07 4.93E‐06 9.86E‐06 3.94E‐05 4.93E‐06 3.94E‐05 3.94E‐05 4.93E‐06 3.94E‐05 3.94E‐05 1.97E‐05 1.58E‐04 3.55E‐0456‐55‐3 Benzo(a)anthracene ‐‐ ‐‐ 6.22E‐07 1.19E‐05 2.39E‐05 9.54E‐05 1.19E‐05 9.54E‐05 9.54E‐05 1.19E‐05 9.54E‐05 9.54E‐05 4.77E‐05 3.82E‐04 8.59E‐04205‐99‐2 Benzo(b)fluoranthene ‐‐ ‐‐ 1.11E‐06 2.13E‐05 4.26E‐05 1.70E‐04 2.13E‐05 1.70E‐04 1.70E‐04 2.13E‐05 1.70E‐04 1.70E‐04 8.52E‐05 6.81E‐04 1.53E‐03218‐01‐9 Chrysene ‐‐ ‐‐ 1.53E‐06 2.93E‐05 5.87E‐05 2.35E‐04 2.93E‐05 2.35E‐04 2.35E‐04 2.93E‐05 2.35E‐04 2.35E‐04 1.17E‐04 9.39E‐04 2.11E‐0353‐70‐3 Dibenz(a,h)anthracene ‐‐ ‐‐ 3.46E‐07 6.64E‐06 1.33E‐05 5.31E‐05 6.64E‐06 5.31E‐05 5.31E‐05 6.64E‐06 5.31E‐05 5.31E‐05 2.65E‐05 2.12E‐04 4.78E‐04193‐39‐5 Indeno(1,2,3‐cd)pyrene ‐‐ ‐‐ 4.14E‐07 7.94E‐06 1.59E‐05 6.35E‐05 7.94E‐06 6.35E‐05 6.35E‐05 7.94E‐06 6.35E‐05 6.35E‐05 3.18E‐05 2.54E‐04 5.72E‐0483‐32‐9 Acenaphthene ‐‐ ‐‐ 4.68E‐06 8.98E‐05 1.80E‐04 7.18E‐04 8.98E‐05 7.18E‐04 7.18E‐04 8.98E‐05 7.18E‐04 7.18E‐04 3.59E‐04 2.87E‐03 6.46E‐03208‐96‐8 Acenaphthylene ‐‐ ‐‐ 9.23E‐06 1.77E‐04 3.54E‐04 1.42E‐03 1.77E‐04 1.42E‐03 1.42E‐03 1.77E‐04 1.42E‐03 1.42E‐03 7.08E‐04 5.67E‐03 1.27E‐02120‐12‐7 Anthracene ‐‐ ‐‐ 1.23E‐06 2.36E‐05 4.72E‐05 1.89E‐04 2.36E‐05 1.89E‐04 1.89E‐04 2.36E‐05 1.89E‐04 1.89E‐04 9.44E‐05 7.55E‐04 1.70E‐03191‐24‐2 Benzo(g,h,i)perylene ‐‐ ‐‐ 5.56E‐07 1.07E‐05 2.13E‐05 8.53E‐05 1.07E‐05 8.53E‐05 8.53E‐05 1.07E‐05 8.53E‐05 8.53E‐05 4.27E‐05 3.41E‐04 7.68E‐04207‐08‐9 Benzo(k)fluoranthene ‐‐ ‐‐ 2.18E‐07 4.18E‐06 8.36E‐06 3.35E‐05 4.18E‐06 3.35E‐05 3.35E‐05 4.18E‐06 3.35E‐05 3.35E‐05 1.67E‐05 1.34E‐04 3.01E‐04206‐44‐0 Fluoranthene ‐‐ ‐‐ 4.03E‐06 7.73E‐05 1.55E‐04 6.18E‐04 7.73E‐05 6.18E‐04 6.18E‐04 7.73E‐05 6.18E‐04 6.18E‐04 3.09E‐04 2.47E‐03 5.57E‐0386‐73‐7 Fluorene ‐‐ ‐‐ 1.28E‐05 2.46E‐04 4.91E‐04 1.96E‐03 2.46E‐04 1.96E‐03 1.96E‐03 2.46E‐04 1.96E‐03 1.96E‐03 9.82E‐04 7.86E‐03 0.0285‐01‐8 Phenanthrene ‐‐ ‐‐ 4.08E‐05 7.83E‐04 1.57E‐03 6.26E‐03 7.83E‐04 6.26E‐03 6.26E‐03 7.83E‐04 6.26E‐03 6.26E‐03 3.13E‐03 0.03 0.06129‐00‐0 Pyrene ‐‐ ‐‐ 3.71E‐06 7.12E‐05 1.42E‐04 5.69E‐04 7.12E‐05 5.69E‐04 5.69E‐04 7.12E‐05 5.69E‐04 5.69E‐04 2.85E‐04 2.28E‐03 5.12E‐03

notes:

b‐EmissionfactorsfromAP‐42Section3.4,LargeStationaryDieselandDuel‐FuelEngines(October1996).FuelsulfurcontentofULSDis0.0015%.

j‐Hourlyemissionsbasedonthemaximumhourlyrateandtesting1enginesatatime.Dailyemissionsbasedonthehigherof1)reliabilitytestingof4enginesperdayplusone8.0hourperformancetestforoneengine,or2)emergencyoperationsfor8hoursforallengines.Annualemissionsbasedon8hoursofroutinetestsand8hoursofemergencyusepereachengine,plusa8hourperformancetestofoneengine.

RoutineTestingSingleEngineEmissionRateg

e‐GreenhouseGasemissionfactorsfrom40CFR98,SubpartC,TableC‐1.f‐CO2ecalculatedbasedonglobalwarmingpotential(GWP)foreachGreenhousegas:CO2=1;CH4=25;andN2O=298(40CFRPart98,SubpartA).

a‐CO,PM,andVOCemissionfactorsfromVendordata.NOXemissionsduringstartupandnormaloperationarebasedonPSD14‐02limits(4.4g/hp‐hrduringstartupand0.5g/hp‐hrduringnormaloperation).OtherlimitsfromPSD14‐02andApprovalOrderNo.15AQ‐E636forCO,SO2,PM10/PM2.5,VOCandDEEPmatchvendorprovideddata.

PerformanceTestEmissionRatei

d‐DieselEngineExhaustParticulate(DEEP)emissionsbasedonfilterableportionofPM10emissionrate.RatiooffilterablePMtototalPM10basedonemissionsratesfromTable3.4‐2ofAP‐42Section3.4(LargeStationaryDieselandDuel‐FuelEngines).

EmergencyOperationSingleEngineEmissionRateh

h‐Hourlyemissionsbasedon2937hp‐hr/hrandfuelconsumptionrateof138.0gal/hr,startupemissionratebasedonuncontrolledemissionsratesfor10minutes/startupandcontrolledemissionsfortheremainderofthehour.ForNOX,CO,PM/PM10/PM2.5andVOC,emissionsafterstartuparebasedonthehigherofemissionsat70%loadand100%load.Dailyemissionsbasedononehourofemissionsthataccountforcoldstartadjustmentsandsevenhoursofsteady‐stateoperation,andannualemissionsbasedon8hrs/yr.

TotalEmissionRatej

(AllEngines)EmissionFactor

c‐HAPandTAPemissionfactorsbasedonAP‐42,Section3.4(LargeStationaryDieselandDuel‐FuelEngines).

i‐Hourlyemissionsbasedon2937hp‐hr/hrand,fuelconsumptionrateof138.0gal/hr.ForNOX,CO,PM/PM10/PM2.5andVOC,sincetheperformancetestingwillbeperformedafteraquarterlytesting,emissionsarebasedonthehigherofemissionsat70%loadand100%load.Dailyandannualemissionsbasedon8hrspertestandonetestperyear.

g‐Hourlyemissionsbasedon2937hp‐hr/hr,fuelconsumptionrateof138.0gal/hr,startupemissionratebasedonuncontrolledemissionsratesfor10minutes/startupandcontrolledemissionsfortheremainderofthehour.ForNOX,CO,PM/PM10/PM2.5andVOC,emissionsafterstartuparebasedonthehigherofemissionsat70%loadand100%load.Dailyemissionsbasedononehourofemissionsthataccountforcoldstartadjustmentsandonehourofsteady‐stateoperation,andannualemissionsbasedon8hrs/yr.

Page 2 of 2

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application C-1 Trinity Consultants

APPENDIX C: NOX CERM DATA

Note: Periods when the specified production line was not in operation are shaded in gray. An asterisk * indicates an excursion has occurred in the month.

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

averageJan * 5.26Feb * 0.48 * 1.44Mar * 1.45 6.3 2.33Apr * 2.97 8.46 2.87May * 2.11 3.54 1.94 * 2.94Jun * 2.29 6.19 1.63 * 2.65Jul 3.78 1.77 4.75 1.95 * 2.9Aug 3.3 0.96 6.6 1.39 5.7 2.34 6.74 1.17Sep * 1.68 5.39 1.21 7.73 2.45 7.62 1.95Oct 3.6 2.07 5.7 1.15 8.5 2.31 * 2.77Nov 6.6 2.51 4.46 0.73 5.59 2.89 * 2.21Dec * 1.78 * 1.81 4.69 1.90 * 2.08Year * 2.11 * 1.68 * 2.55 * 2.04

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

averageJan 5.71 2.78 7.03 3.45 * 2.51 * 2.95Feb 5.58 2.39 7.25 2.82 4.07 2.65 * 2.32Mar 5.49 1.61 * 1.09 6.24 2.90 6.15 2.18Apr 4.62 2.44 6.39 2.52 * 3.72 3.37 1.89May 6.81 2.49 6.58 2.59 6.79 3.06 7.17 1.49Jun 3.91 1.64 7.05 2.52 * 3.96 7.18 1.50Jul 5.37 1.93 5.20 1.66 * 2.65 3.74 1.09 7.12 0.22Aug 8.34 2.25 5.42 1.89 8.24 3.99 8.13 3.33 4.71 0.65Sep 4.03 2.83 6.81 2.64 * 3.67 6.45 3.22Oct 7.62 1.99 6.24 1.59 7.01 3.02 4.95 3.23 7.16 1.17Nov 4.78 0.29 5.03 3.50 4.32 2.91 3.97 2.74Dec 5.16 1.37 5.08 2.60 4.12 1.56 * 2.07Year 8.34 2.00 * 2.29 * 3.19 * 2.35 * 1.41

2014

2015

Line 1 Line 2 Line 3 Line 4 Line 5

Line 1 Line 2 Line 3 Line 4 Line 5

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

averageJan 4.96 3.14 7.87 2.36 4.04 2.54Feb 5.32 3.57 4.40 2.90 4.13 2.48Mar 4.70 3.62 7.99 2.75 3.23 2.11Apr 4.78 3.78 4.33 2.04 4.75 2.45May 5.19 3.61 1.64 0.78 7.28 1.28Jun 3.82 1.78 * 1.84 3.21 0.41Jul 8.25 3.46 4.19 3.08 0.12 0.03Aug 8.21 2.50 4.06 2.25 0.10 0.00Sep * 3.44 5.11 2.88 0.45 0.03Oct 5.64 2.22 7.77 2.88 4.41 2.99Nov 7.38 2.09 5.30 3.42 6.80 2.70Dec 5.67 0.66 * 1.38 * 1.38Year * 2.82 * 2.38 * 1.46

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

averageJan * 2.71 5.77 2.75 7.91 3.36Feb 7.52 2.72 5.78 3.11 6.14 3.70Mar 7.33 2.87 * 1.84 7.98 3.15Apr 5.70 3.06 7.47 2.61 7.25 3.24May 5.62 2.78 6.31 2.90 5.79 3.10Jun 4.96 2.72 6.31 1.81 3.50 0.83Jul 4.13 2.55 6.92 1.75 5.41 3.34Aug 3.44 2.31 4.76 1.70 4.81 3.53Sep 3.32 1.49 6.09 2.92 6.31 3.44Oct 7.62 3.26 6.17 3.67 5.00 3.22Nov 4.71 3.01 6.89 3.17 4.58 3.14Dec * 2.40 5.98 2.28 5.86 2.11Year * 2.66 * 2.54 7.98 3.01

2016

2017

Line 1 Line 2 Line 3 Line 4 Line 5

Line 1 Line 2 Line 3 Line 4 Line 5

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

average

Max lb/hr

1 hr averageMonthly lb/hr 

averageJan 5.27 2.34 5.57 3.16 * 3.13Feb 4.95 2.97 6.13 3.02 5.91 2.64Mar 4.95 2.80 7.52 2.91 5.94 3.45Apr 5.53 3.63 4.37 2.63 5.57 3.22May 5.50 3.21 5.53 2.26 4.89 3.11Jun 5.14 3.01 4.63 2.72 5.38 3.34Jul 5.29 3.12 5.82 2.86 6.02 1.58Aug 6.03 2.80 7.17 1.70 7.93 3.05Sep 4.87 2.96 5.14 1.80 4.26 2.71Oct 8.23 3.11 5.67 2.49 4.97 1.62NovDecYear 8.23 2.99 7.52 2.55 * 2.78

2018

Line 1 Line 2 Line 3 Line 4 Line 5

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application D-1 Trinity Consultants

APPENDIX D: BACKGROUND INFORMATION FOR BACT

As mentioned in the Technical Support Document (TSD) for PSD Permit 14-02, there are limited number of facilities that have similar carbon fiber manufacturing processes as the Moses Lake Facility. A Clearinghouse review, including EPA’s Reasonably Available Control Technology (RACT)/BACT/Lowest Achievable Control Technology (LAER) Clearinghouse, or RBLC database, California Air Resources Board (CARB) BACT Clearinghouse, BACT workbooks and websites maintained by the Bay Area Air Quality Management District (BAAQMD), the South Coast Air Quality Management District (SCAQMD), the San Joaquin Valley Unified Air Pollution Control District (SJVUAPCD), and the Texas Commission on Environmental Quality (TCEQ), was performed as the basis for the original BACT determination. SGL has reviewed these databases, and found the following:

There are 16 facilities found in RBLC by searching for determinations with NAICS Code 335991, SIC Codes 2824 and 3624, which potentially cover all facilities that have similar carbon fiber manufacturing processes as the Moses Lake Facility. Only determinations for three RBLC IDs, SC-0116 and SC-0122 for Cytec Carbon Fibers, LLC and AL-0226 for Toray Carbon Fiber America, Inc., include BACT determinations for carbon fiber manufacturing processes. No new BACT determinations are identified from the RBLC search. A printout of RBLC search results based on these codes are provided in this appendix. The specific applicable BACT determinations from RBLC are included in Table D-2.

No facilities are identified by searching with NAICS Code 335991, SIC Codes 2824 and 3624 in CARB BACT Clearinghouse.

Since no additional facilities are identified, SGL gathered information on the facilities that were reviewed in the original BACT analysis, as listed in the TSD for PSD Permit 14-02. Table D-1 lists the carbon fiber manufacturing facilities except for the Moses Lake Facility and changes identified since the original BACT determination.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application D-2 Trinity Consultants

Table D-1. List of Carbon Fiber Manufacturing Facilities

Facility Location Permit Date Changes since Issuance of TSD for PSD

Permit 14-02

Cytec

Rock Hill, SC 02/15/2012 Now closed.

Piedmont, SC a 4/30/2008 b

A third carbon fiber line was permitted and installed. NOX and VOC limits are updated per RBLC search results and the Title V operating permit.

Grafil (Mitsubishi Rayon Carbon Fiber and Composites, Inc.)c

Sacramento, CA 07/05/2012 None

Hexcel West Valley City, UT Between 9/1/2010 and 3/22/2018 d

Two additional carbon fiber lines are permitted.d

SGL Carbon (Mitsubishi Rayon Carbon Fiber and Composites, Inc.)b

Evanston, WY 07/28/2008 None

Toho Tenax Rockwood, TN 03/16/2012 None Toray Carbon Fibers America Inc. Decatur, AL 12/20/2007 One additional carbon fiber line is permitted

according to RBLC.

Zoltek Corp. St. Charles, MO 1991 & 1997 Not manufacturing carbon fiber anymore.e

Abilene, TX 02/16/2010 None a The site was previously identified as located in Greenville, SC. According to the operating permit for this site, the site is located in

Piedmont, SC, which is located within Greenville County. Therefore, the location is corrected here. The Title V operating permit reviewed for BACT determinations on all production lines is TV-1200-0374, issued on December 31, 2014. https://www.scdhec.gov/sites/default/files/docs/Environment/AirPermitCoverage/1200-0374.pdf

b This is the permit date obtained from RBLC for the third carbon fiber line (RBLC IDs SC-0116 and SC-0122). According to the TV-1200-0374, the third carbon fiber line was installed in 2014.

c Grafil changed ownership to Mitsubishi Rayon Carbon Fiber and Composites, Inc. in 2013. SGL Evanston, WY facility was sold to Mitsubishi Rayon Carbon Fiber and Composites, Inc. in 2017. The Evanston, WY facility is a minor source.

d Approval Order DAQE-AN113860031-18, issued by Utah Department of Environmental Quality on March 22, 2018, shows that Lines 15 & 16 have been permitted but likely not been installed as of the Approval Order issuance date. Therefore, it is assumed that the permit date is within the last permit date obtained from TSD for PSD Permit 14-02 and this Approval Order issuance date

e August 13, 2015 Permit with review report. https://dnr.mo.gov/env/apcp/permits/docs/zoltec-stcharles2015cp.pdf Table D-2 below summarizes the control technologies and limits for Cytec Piedmont, SC facility, Hexcel West Valley City, UT facility, and Toray Carbon Fibers America Inc., the three facilities that are identified with changes in Table D-1. As shown in Table D-2, there have been no new control technologies implemented on carbon fiber lines since SGL’s original BACT analysis in PSD Permit 14-02.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application Trinity Consultants D-3

Table D-2. Control Technologies Summary

Facility Location Emission

Unit

VOC PM/PM10/PM2.5 NOX

Limit Units Control Limit Units Control Limit Units Control

Cytec Piedmont, SC

Carbon Fiber Line 1 a 20 ppmv TOC TO/Boiler 0.5 lb/MMBtu None None N/A None

Carbon Fiber Line 2 a 20 ppmv TOC

Boiler/ Heater None N/A None None N/A None

Carbon Fiber Line 3 b 20 ppmv TOC TO None N/A None 13.31 lb/hr None

Hexcel West Valley City, UT

Production Lines 13 & 14 c 159.57 Tpy RTO/TO None N/A Baghouse None N/A ULNB

Production Lines 15 & 16 d Unknown N/A RTO/TO Unknown N/A Baghouse/

Filter Box Unknown N/A Low NOX Burner

Toray Industries Decatur, AL

Mfg Process CFA-1 & CFA-2 None N/A TO 0.22 gr/dscf None 1882 ppm LNB for TO

CFA-3 e None N/A TO 0.0219 gr/dscf None 1882 ppm LNB for TO a Title V operating permit TV-1200-0374 specifies that the VOC BACT of 20 ppmv TOC for the process heater, the waste boiler, and the TOs for Line 3. According to the

Statement of Basis for this permit, the process heater serves as a control for the pre-carbonization and carbonization furnaces for Line 2 and the waste boiler serves as the control for Line 1 oxidizers. The 0.5 lb/MMBtu PM limit for Carbon Fiber Line 1 is for the waste boiler as an industrial incinerator according to TV-1200-0374.

b From RBLC search for SC-0122 and SC-0116. c Hexcel has 13 carbon fiber manufacturing lines, and Lines 15&16 were permitted but potentially not installed yet. It appears that a Title V operating permit was not issued

since the updated initial Title V application was submitted in 2016; therefore, the limits and controls for Production Lines 13 & 14 are not updated from the TSD for PSD Permit 14-02.

d Approval Order DAQE-AN113860031-18 indicates Production Lines 15 & 16 are permitted. However, the Approval Order does not provide any information whether emission limits are established as BACT.

e From RBLC search for AL-0226.

SGL Composites LLC | Approval Order No.15AQ-E636 Modification Application Trinity Consultants D-4

SGL’s original BACT analysis determined the following controls and limits as BACT for Lines 1-6, according to the TSD for PSD Permit 14-02 and Approval Order No. 15AQ-E636:

NOX control: Selective Catalytic Reduction (SCR) for RTO exhaust from oxidation processes and water injection to the TOs from carbonization processes. Emission limits are specified for each operation mode for each line on hourly basis and annual emission limits are also specified: • Normal Operation: 8.5 lb/hr for Lines 1-6; • SCR Bypass: 17.9 lb/hr for Lines 3-6; • RTO Bypass: 8.5 lb/hr for Lines 3-6; and • Shutdown: 8.5 lb/hr. • 76 tons per 12-month rolling period for Lines 1-2 and 467 tons per 12-month rolling period for Lines 3-

10. SGL requests a synthetic minor limit at 90 tons per 12-month rolling period (see Table 2-1). PM/PM10/PM2.5: proper operation from oxidation and carbonization processes. Emission limits are specified

for each operation mode for each line on hourly basis and annual emission limits are also specified: • Normal Operation: 1.1 lb/hr for PM, 3.0 lb/hr for PM10/PM2.5 for Lines 1-6; • SCR Bypass: 1.1 lb/hr for PM, 2.0 lb/hr for PM10/PM2.5 for Lines 3-6; • RTO Bypass: 1.1 lb/hr for PM, 2.0 lb/hr for PM10/PM2.5 for Lines 3-6; and • Shutdown: 1.1 lb/hr for PM, 3.0 lb/hr for PM10/PM2.5 for Lines 3-6. • 27 tons PM10/PM2.5 per 12-month rolling period for Lines 1-2 and 39 tons PM and 90 tons PM10/PM2.5

per 12-month rolling period for Lines 3-10. SGL proposes to change the limits for Lines 3-6 (see Table 2-1).

VOC: RTO for oxidation processes and TO for carbonization processes. Emission limits are specified for each operation mode for each line on hourly basis and annual emission limits are also specified: • Normal Operation: 1.7 lb/hr for Lines 1-6; • SCR Bypass: 1.7 lb/hr for Lines 3-6; • RTO Bypass: 8.6 lb/hr for Lines 3-6; and • Shutdown: 7.1 lb/hr for Lines 3-6. • 15 tons per 12-month rolling period for Lines 1-2 and 60 tons per 12-month rolling period for Lines 3-

10. SGL proposes to change the limit for Lines 3-6 (see Table 2-1). Acrylonitrile: proper operation. Annual limits are specified: • 102 lbs per 12-month rolling period for Lines 1-2; • 408.5 lbs per 12-month rolling period for Lines 3-10. SGL proposes to change the limit for Lines 3-6 (see

Table 2-1). Ammonia: proper operation. Daily limits are specified: • 156 lbs per day for Lines 1-2; • 595 lbs per day for Lines 3-10. SGL proposes to change the limit for Lines 3-6 (see Table 2-1).

HCN: proper operation. Daily limits are specified: • 110 lbs per day for Lines 1-2; • 310 lbs per day for Lines 3-10. SGL proposes to change the limit for Lines 3-6 (see Table 2-1).

The control technologies and emission limits in PSD Permit 14-02 and Approval Order No. 15AQ-E636 are consistent with more recent BACT determinations in the industry.