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QUEST CCS PROJECT
PCCC2 Conference Bergen, Norway
Sept 19, 2013 Use this area for cover image
(height 6.5cm, width 8cm)
Steve Peplinski – Quest Engineering Manager
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Location
September 19, 2013 2 PCCC2 Conference
Alberta
Canada
Quest Fort Saskatchewan
Fort McMurray
Edmonton
Calgary
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Introduction - The Athabasca Oil Sands Project
September 19, 2013, 3 PCCC2 Conference
Peace River
Calgary
Edmonton
Corridor Pipeline
Fort McMurray
Muskeg River Mine
Ore
Scotford Upgrader
Bitumen to Synthetic cru(255,000 bpd)
Scotford Refinery
(Shell only)
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General Features
September 19, 2013
4 PCCC2 Conference
Quest CCS Project - fully integrated CCS (capture, transport & storage)
JV among Shell (60%); Chevron (20%); and Marathon (20%) – part of AOSP
Located at Scotford Upgrader Complex
One million tonnes CO2 per year capacity for 25 years
35% reduction of Upgrader CO2 emissions Project Approval – Sept 2012
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Hardware
PCCC2 Conference
SALT SEALS
Cement
SHALE SEALS
TARGET FORMATION
Capture at the Scotford Upgrader from 3 Hydrogen Manufacturing Units
CO2 transported by 12 inch pipeline to storage, with 6 inch laterals
Pipeline to 65 km north of the Upgrader
Route selected to meet stakeholder requirements: 28 km follows existing ROW Drilled under North Saskatchewan
River 30+ re-routes to accommodate
landowner wishes
Base plan: 3 injection wells and associated monitoring
September 19, 2013 5
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Storage
May 14, 2013 6 PCCC2 Conference
SALT SEALS
Intermediate Casing
Main Injection Casing
Cement
Surface Casing
Tubing
SHALE SEALS
TARGET FORMATION
Packer Assembly
Perforations allow CO2 to penetrate the formation
Saline aquifer storage
Injection Formation - Basal Cambrian Sands (BCS)
2,300 m depth, Prairies deepest sandstone
Multiple caprock and salt seal layers in the storage complex
No significant faulting visible from wells or seismic
The BCS is well below hydrocarbon bearing formations and potable water zones in the region
Relatively few wells drilled into the BCS, none within 10 km of the proposed storage site
Wells and Drilling
Conventional drilling methods
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Well Program Drilling finished, completions
ongoing
Capture & Pipeline Engineering finalized
Site underground construction complete
First module delivery Q4 2013
Major Equipment deliveries complete
Pipeline construction begins Q3 2013
Community Advisory Panel Initial kickoff in January,
with regular updates
Final Regulatory Approvals Pipeline laterals expected end
2013 September 19, 2013 7 PCCC2 Conference
Timeline and Upcoming Activities
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Process Selection & Integration
1. Why activated amine (ADIP-x)? 2. HMU integration issues 3. CO2 Compression, integration with
pipeline and wells
September 19, 2013 8 PCCC2 Conference
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Why activated amine (ADIP-x)?
Process Selection completed in Q1 2010 with the following constraints:
Design Basis capacity of 1.2 million tonnes per year, On-stream factor of 90% = 1.08 million tonnes per year calendar day capacity
Maximum pressure drop through the CO2 facility less than 70 kPa
Temperature of the PSA inlet gas after CO2 capture shall not exceed 35°C in order to maintain the H2 absorption capacity
Chemical solvent carryover to the PSA should be less than 1 ppmw. Chemical solvents can contaminate the PSA’s adsorbents.
Onsite electrical power availability limited due to HV substation constraints
Limited plot space available next to HMU units
September 19, 2013 9 PCCC2 Conference
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Selection Drivers
Why activated amine (ADIP-x)? - CO2 Source Selection
10 Sept 19,2013 PCCC2 Conference
Scotford Upgrader
Pre-combustion
Post-combustion
Steam Methane
Reformers
• Fired heater
• Boilers • Gas
turbines
Parameter Post-Comb
D/S of PSA
U/S of PSA
System pressure
X X √
CO2 concentration
X √ √
CO2 partial pressure
X X √
Other impurities
X √ √
Plot space X X √
Downstream of PSA
Upstream of PSA
H2, CO2, CO, CH4
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Why activated amine (ADIP-x)?
CRITERIA ADIP-X MDEA SELEXOL MEMBRANE PSA METHANOL
ABSORPTION AMMONIA
ABSORPTION LIQUE-
FACTION
HSE RISKS
CAPEX
OPEX
HMU RELIABILITY EFFECTS
COMMERCIAL
CONSTRUCTABILITY
Influencing Factors
Construction in brownfield location influenced 75% of options
Commercial scalability unproven for 5 of 8 options
Local Opex factors - steam versus electricity costs
September 19, 2013 11 PCCC2 Conference
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Quest – Capture Facilities
12 Sept 19, 2013
PCCC2 Conference
Scotford Upgrader
Steam
HC Gas H2 + CO2
HP Steam Utili
ties
H2
CO2 to
atmospher
e
Reformer Hydrocrac
kers (Upgrader & Refinery)
PSA
CO2+CO+H2
Quest
Tie-In
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Capture Design
September 19, 2013 13 PCCC2 Conference
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Capture 3D Model – Amine Stripper & CO2 Compression
Sept ember 19, 2013 14 PCCC2 Conference
Amine Stripper
Compressor building
Compressor
Intercooling
TEG Dehydratio
n
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Integration with Existing HMUs
September 19, 2013 15 PCCC2 Conference
H2 Manufacturing Unit Pressure Swing Adsorption (PSA) H2 Separation
Steam + NG
Product H2
CH4 + Slip H2 & CO2
HMU operation
Steam Balance
PSA adsorbent fill
Control system
Loss of
CO2
Storage Complex 2 km deep
Storage Site
3
CO2 Pipeline
2 1
Amine Unit Compressor
CO2
Dense phase transport Capacity Let down at choke
valve
Off gas Fuel
akeup Fuel (NG)
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Integration with Existing HMUs
What does HMU do when Quest is online/offline?
Verify reformer box trip occurrences via dynamic analysis
Confirm steam balance within HMUs for FGR on/off
Loss in H2 production due to Quest?
PSA revised adsorbent fill to post Quest optimized loading
70 Kpa pressure drop forced piping upsizing
Issues – removing CO2 impacts HMU NOx production
Low NOx burners c/w testing (burner management system relook)
Flue gas recirculation permutations September 19, 2013 16 PCCC2 Conference
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HMU NOx
September 19, 2013 17 PCCC2 Conference
Emission Source Air Contaminant/
Parameter Current Limit Requested
Limit
Expansion HMU flue stack (S-44103) Nitrogen oxides 62.7 kg/h 130.0 kg/h
Base plant Train 1 hydrogen manufacturing unit flue stack (S-24103)
Nitrogen oxides 47.5 kg/h 76.5 kg/h
Base plant Train 2 hydrogen manufacturing unit flue stack (S-24203)
Nitrogen oxides 47.5 kg/h 76.5 kg/h
0
50
100
150
200
250
300
350
$- $0.50 $1.00 $1.50 $2.00 $2.50 $3.00 $3.50 $4.00 $4.50
NO
x, k
g/h
Scotford HMU NOx Reduction (Total)
Quest, CO2 Lean
Low Nox Burner (LNB)
Flue Gas Recirculation (FGR)
LNB+ FGR
Current Regulatory (EIA)
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HMU 1 & 2 Scope
September 19, 2013 18 PCCC2 Conference
Amine Absorbers
Flue Gas Recirculat
ion
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Compressor Operating Envelope Integrally Geared, 8 Stages with inlet guide vanes
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6
7
8
9
10
11
12
13
14
15
16
0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5
Pres
sure
, Mpa
Flow rate, Million tpa
PSV Set Pressure
Dense Phase Pressure
Guide Vane Position 65
-10
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Integration of Capture/Pipeline/Wells - envelope
September 19, 2013 20 PCCC2 Conference
3
5
7
9
11
13
15
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5
Pr
ess
ur
e, M
pa
Flow rate, Million tpa
PSV Set
Dense Phase Pressure
Guide Vane Position 65
High Injectivity - FTHP
-10
Base Injectivity - FTHP
Pres. at upstream of choke valve for Compressor discharge
of 11 Mpa
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Quest is the first commercial scale CCS project in Canada
Pace setter for other efforts to manage CO2 footprint in Alberta
Abundant learnings for future projects
Key success factors
Early and extensive stakeholder engagement
Use of proven technology
System optimization (fit for purpose) and integration are important to minimize life cycle cost
HMU integration
Utilities integration
Capture optimization
Worth considering
Capture ready HMU’s or CO2 producers
Improvements in compressor configuration
Early injectivity data
Sept 19, 2013 21 PCCC2 Conference
Learnings and Conclusion
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www.shell.ca/Quest
Thank You!
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Into ‘Execute’ phase to startup in 2015
2013 major activities: Completion of detailed engineering
Begin major construction end 2012 (mod yard work)
Major Equipment delivery and setting onsite
MMV baseline data gathering
Begin operations readiness and training
Completion of regulatory applications (pipeline laterals)
Ongoing stakeholder management
September 19, 2013
23 PCCC2 Conference
Next Steps
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Costs/Revenues and Funding Agreements
PCCC2 Conference
SALT SEALS
Cement
SHALE SEALS
TARGET FORMATION
Total cost of Quest – Cdn$1.4 billion Includes Pre FID, capital and 10 years opex Capital Ratio: 80% Capture, 10% pipeline, 10% wells
Revenues – GHG offsets (credits) Net amount – stored CO2, less direct and indirect emissions Credits to be used first by Shell’s Alberta assets for
regulatory compliance
Government Funding Support – Cdn$865 million Cdn$120 million Canadian Federal Government (Pre FID) Cdn$ 745 million Alberta Province (Construction, Startup and
10 years operation) Extensive knowledge sharing Stringent monitoring (MMV) plan NPV Zero commitment
September 19, 2013 24
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Provincial GHG framework established CCS Act passed in Nov 2010, establishing overall structure
Pore space regulations in place with Quest successfully acquiring required area in May 2011
Participation in Regulatory Framework Assurance (RFA) process and GHG Offset Protocol revisions
No Federal framework to date – possible 2013
Regulatory approvals near complete Federal compliance achieved – EIA submitted, completed
internal and public review
Bundled provincial application submitted – Upgrader amendment, Pipeline, Well and Storage
3 rounds of Information Requests (200+) by provincial regulator, the ERCB
ERCB public hearing March 2012
Summer works and drilling permits to follow ERCB Decision Report September 19, 2013 25 PCCC2 Conference
Regulatory Framework
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General Assessment – Very Positive Major project attributes (technical, costs, regulatory,
stakeholders) tracking as planned
Project Successes Government fiscal support Pore space tenure Capture and Pipeline Front End Engineering and Design (FEED)
completion and Assurance Test Well and aquifer property verification Stakeholder engagement Pipeline routing finalization DNV certification of the storage development plan Regulatory Hearing
Challenges Capital Costs Schedule Pressure Regulatory Uncertainty (GHG Protocols, Federal framework)
September 19, 2013 26 PCCC2 Conference
General Project Assessment