queensland western australia pre-biotic organic · pdf filevictor harbor bordertown kingston...

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Chromatogram of fluid inclusions of a > 2.7 bn years old hydrothermal quartz boulder (run time from 25 to 55 min) Analysis of hydrothermal quartz veins from the Archaean Yilgarn craton, impact- generated quartz veins of the Shoemaker-crater and hydrothermal quartz boulders from a 2.7 to 3 billon years old conglomerate near Murchison (West Australia). In one of the samples from the conglomerate, a wide spectrum of organic com- pounds such as bromomethane, butane, benzene and toluene have been detected. The time interval between the quartz formation, its erosion and its sedimentation is unknown. Possibly, the analyzed quartz sample was formed in a hydrothermal vein long before any living cells have existed on earth. In this case, the given result would be the first indication for pre-biotic organic chemistry. Pre-biotic organic chemistry in hydrothermal quartz veins from the Archaean Yilgarn province, Australia Mayer, C. (1) , Schreiber, U. (1) , Dyker, G. (2) , Kirnbauer, T. (3) , Mulder, I. (4) , Sattler, T. (4) , Schöler, H. (4) , and Tubbesing, C. (4) (1) University of Duisburg-Essen, Essen, (2) Ruhr-University Bochum, (3) Technische Fachhochschule „Georg Agricola“, Bochum, (4) University of Heidelberg (all Germany) EGU General Assembly 2013 | Poster EGU2013-7712 | G11 | BG1.1 Corresponding author: [email protected] References Ulrich Schreiber, Oliver Locker-Grütjen & Christian Mayer (2012): Hypothesis: Origin of Life in Deep-Reaching Tectonic Faults. Orig Life Evol Biosph. DOI 10.1007/s11084-012-9267-4 Hypothetical model for the origin of life in early continental crust (Schreiber et al. 2012) From upper mantle, ascending of: scCO 2 , scH 2 O, scN 2 ?, Traces of H 2 , CH 4 , NH 3 Noble gases: He, Rn, Ne etc.; dissolved: Me 1+ , Me 2+ , Actinides, SO 2 /H 2 S, Halogenides, Boron compounds Me 2+ Me 3+ (REE) water column, 2 kbar (if open completely) Apatite in dissolution (Ca 2+ ,PO 4 4- ) gabbroide rock in dissolution Formation of quartz and ore dykes; siliceous-, mineral-, metallic surfaces reaction environments in cavities or micro cracks (nm – cm) H 2 O scH 2 O scCO 2 Origin of prebiotic molecules Drawn by G. Berberich, 2013 CO 2 H 2 O undersaturated by CO 2 scH 2 O/H 2 O Transition zone depending on geothermal gradient and caused by earth tides, earthquakes etc. Assumed crustal thickness of proto-continent Temperature gradient may be variable 1 km 5 km 10 km 20 km H 2 O saturated by CO 2 3. Ascending of CO 2 bubbles in CO 2 -undersaturated H 2 O 2. Condensation of prebiotic molecules and chain-linking 1. Enrichment of molecules 7. High concentration of prebiotic molecules in nanopores 6. Enrichment of prebiotic molecules on top of the water column 5. Release of prebiotic molecules 4. Burst of bubbles into small frag- ments which accumulate at the water surface 3. Bubbles reaching water-gas inter- face 2. Bubbles partially stabilized by single layer lipid membrane 1. Slowly expanding bubbles Transition zone CO 2 scCO 2 Transition zone 4. Micro bubbles remain intact and might serve as micro- compartments for enriched prebiotic molecules 3. Finalising of single-layer lipid membrane 2. Shrinking of bubbles 1. Diffusion of CO 2 H 2 O 3. Ascending of CO 2 bubbles in CO 2 -saturated H 2 O 2. Condensation of prebiotic mole- cules and chain-linking 1. Enrichment of molecules scCO 2 /CO 2 Trans. zone Lipids prebiotioc molecules scCO 2 >2.7 Billion years old conglomerate near Murchison L Macleod L Auld L Disappointment L Carnegie L Wells L Carey L Rebecca L Dundas L Cowan L Moore L Barlee L Austin De R Fortescue R Ashburton River Gascoyne R Murchison R Grey HAMERSLEY RANGE Mt Meharry 1253 GIBSO GREAT SANDY DESERT LITTLE SANDY DESERT PILBARA WESTERN AUSTRALIA Barrow I Dirk Hartog I Shark Bay INDIAN OCEAN Narrogin Lancelin Telfer Newman Port Hedland Paraburdoo Onslow Pannawonica Karratha Roebourne Exmouth Carnarvon Denham Meekatharra Wiluna War Leinster Laverton Leonora Mount Magnet Balladonia Norseman Esperance Kambalda Northampton Morawa Dongara Moora Dalwallinu Wongan Hills Merredin Kellerberrin Northam York Corrigin Southern Cross Pingelly Collie Lake Grace Katanning Busselton Margaret River Denmark Mount Barker Manjimup Kojonup Ravensthorpe Jerramungup Tom Price Yarrie Bunbury Rockingham Mandurah Kalgoorlie-Boulder Geraldton Albany PERTH A A Murchinson Jack Hills N‘ Jack Hills Shoemaker Crater 500 kilometres 100 0 100 200 300 400 AUSTRALIA FOLIO MAP Produced by the National Geographic Information Group Geoscience Australia, GEOCAT 73102 www.ga.gov.au Australian crustal elements Archaean Paleo- proterozoic Shoemaker Crater © T. Kirnbauer Geological map of the Shoemaker crater FID-Analysis of a fluid inclusion of a hydrothermal quartz (Shoemaker Crater) Landsat image of the Shoemaker crater © T. Kirnbauer COS Methyl- chloride Iso-Butylene + Butylene 1,3-Butadiene cis-Butylene trans-Butylene Methylbromide Pentene Furane Isoprene Methyliodide CS2 0 10 km Methane Ethane Propane Propene Acetylene Butene Chromatogram of fluid inclusions of a > 2.7 bn years old hydrothermal quartz boulder (run time from 12.75 to 25 min) Sampling locations Chromatograms of fluid inclusions of different hydrothermal quartz samples Ethyliodide Benzene p-Xylene m-Xylene o-Xylene + Styrene Toluene

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Page 1: QUEENSLAND WESTERN AUSTRALIA Pre-biotic organic · PDF fileVictor Harbor Bordertown Kingston SE Naracoorte Millicent Ouyen Swan Hill Horsham ... Saumarez Reef T R F Ashmore Reef Scott

Chromatogram of fluid inclusions of a > 2.7 bn years old hydrothermal quartz boulder (run time from 25 to 55 min)

Analysis of hydrothermal quartz veins from the Archaean Yilgarn craton, impact-

generated quartz veins of the Shoemaker-crater and hydrothermal quartz boulders

from a 2.7 to 3 billon years old conglomerate near Murchison (West Australia).

In one of the samples from the conglomerate, a wide spectrum of organic com-

pounds such as bromomethane, butane, benzene and toluene have been detected.

The time interval between the quartz formation, its erosion and its sedimentation is

unknown.

Possibly, the analyzed quartz sample was formed in a hydrothermal vein long before

any living cells have existed on earth. In this case, the given result would be the first

indication for pre-biotic organic chemistry.

Pre-biotic organic chemistry in hydrothermal quartz veins from the Archaean Yilgarn province, Australia Mayer, C.(1), Schreiber, U.(1), Dyker, G.(2), Kirnbauer, T.(3), Mulder, I.(4), Sattler, T.(4), Schöler, H.(4), and Tubbesing, C.(4)

(1)University of Duisburg-Essen, Essen, (2)Ruhr-University Bochum, (3) Technische Fachhochschule „Georg Agricola“, Bochum, (4)University of Heidelberg (all Germany)

EGU General Assembly 2013 | Poster EGU2013-7712 | G11 | BG1.1 Corresponding author: [email protected] Schreiber, Oliver Locker-Grütjen & Christian Mayer (2012): Hypothesis: Origin of Life in Deep-Reaching Tectonic Faults. Orig Life Evol Biosph. DOI 10.1007/s11084-012-9267-4

Hypothetical model for the origin of life in early continental crust (Schreiber et al. 2012)

From upper mantle, ascending of: scCO2, scH2O, scN2?, Traces of H2, CH4, NH3

Noble gases: He, Rn, Ne etc.; dissolved: Me1+, Me2+, Actinides, SO2/H2S, Halogenides, Boron compounds

Me2+

Me3+ (REE)

water column, 2 kbar (if opencompletely)

Apatite in dissolution (Ca2+,PO4

4-)

gabbroide rock in dissolution

Formation of quartz and ore dykes;

siliceous-, mineral-,metallic surfaces

reaction environments in cavities or micro cracks

(nm – cm)

H2O

scH2O

scCO2

Ori

gin

of

pre

bio

tic m

ole

cule

s

Drawn by G. Berberich, 2013

CO2

H2O undersaturated by CO2

scH2O/H2O Transition zonedepending on geothermal gradient and caused by

earth tides, earthquakes etc.

Ass

umed

cru

stal

thi

ckne

ss o

f p

roto

-co

ntin

ent

Tem

per

atur

e g

rad

ient

may

be

vari

able

1 km

5 km

10 km

20 km

H2O saturated by CO2

3. Ascending of CO2 bubbles inCO2-undersaturated H2O

2. Condensation of prebiotic molecules and chain-linking

1. Enrichment of molecules

7. High concentration of prebiotic molecules in nanopores

6. Enrichment of prebiotic molecules on top of the water column

5. Release of prebiotic molecules 4. Burst of bubbles into small frag-

ments which accumulate at the water surface

3. Bubbles reaching water-gas inter-face

2. Bubbles partially stabilized by single layer lipid membrane

1. Slowly expanding bubbles

Transition zone

CO2

scCO2

Transition zone

4. Micro bubbles remain intact and might serve as micro-compartments for enriched prebiotic molecules

3. Finalising of single-layer lipid membrane

2. Shrinking of bubbles 1. Diffusion of CO2 � H2O

3. Ascending of CO2 bubbles inCO2-saturated H2O

2. Condensation of prebiotic mole-cules and chain-linking

1. Enrichment of molecules

scC

O2/

CO

2 Tr

ans.

zo

ne

Lipids

prebiotioc molecules

scCO2

>2.7 Billion years old conglomerate near Murchison

L Woods

L Amadeus

L Macleod

L Mackay

L Auld

L Disappointment

L Carnegie

L Wells

L Carey

L Rebecca

L Dundas

L Cowan

L Moore

L Barlee

L Austin

L Maurice(Carle-Thulka)

L FromeL Torrens

L Eyre South

L Gairdner

L Everard

L Blanche

L Eyre North

L Pedder

L Dalrymple

L Alexandrina

L Argyle

R

Dar

ling

River

LachlanR

Bogan

R

Macq

uarie

R

Gwydir R

Dry

sdale

R

Fitzroy

Riv

er

Vic

tori

aR

Roper R

Go

yde

rR

R

McA

rthur

R

Nicholson

Warr

eg

o

Riv

er

Neb

ine

Ck

Moonie R

Mara

noa

R

Daw

son

R

Be

lyand

oR

Burdekin

R

Holroyd R

Gilbert

Leic

hh

ard

tR

Flin

ders

River

NormanR

Par

oo

R

Thom

son

R

Bullo

oR

iver

Dia

man

tina

River

Georg

ina

RSan

dove

r

R

Finke

Cooper

Ck

War

burto

n

R

Macumba

R

DeR

Fortescue R

Ashburton

River

Gascoyne R

Murc

his

on

R

Grey

River

Murray

R

Murrumbidgee

MitchellR

DalyRiver

Ord R

R

GR

EAT

DIV

IDIN

G

RA

NG

E

GR

EA

T

RAN

GE

MACDONNELL

PETERMANN

RANGES

HAMERSLEY RANGE

KINGLEOPOLD

RANGES

FLIN

DE

RS

RA

NG

ES

RA

DIV

IDIN

G

Mt Meharry1253

Mt Squires704

Mt Ord947

Mt Remarkable751

Mt Evelyn366

Mt Zeil1531

Mt Woodroffe1435

St Mary Peak1168

Mt Kosciuszko2229

Ulu u-Ayers Rock863

r

Mt Buller1805

Round Mtn1586

Consuelo Peak1174

Mt Dalrymple1300

Bartle Frere1622

Mt Ossa1617

T A N A M I D E S E R T

S I M P S O N D E S E R T

G R E A T V I C T O R I A D E S E R T

G I B S O N D E S E R T

G R E A T S A N D Y D E S E R T

L I T T L E S A N D Y D E S E R T

S T R Z E L E C K I

D E S E R T

A R N H E M L A N D

N U L L A R B O R P L A I N

K I M B E R L E Y

P I L B A R A

C A P E

Y O R K

P E N I N S U L A

G U L F C O U N T R Y

B A R K L Y

T A B L E L A N D

CH

AN

NE

L

CO

UN

TR

Y

V I C T O R I A

T A S M A N I A

A C T

N E W S O U T H W A L E S

Q U E E N S L A N D

N O R T H E R N T E R R I T O R Y

W E S T E R N A U S T R A L I A

S O U T H A U S T R A L I A

Warrior Reefs

Osprey Reef

Willis Group

Lihou Reefs

Flinders Reefs

Marion Reef

Saumarez Reef

GR

EA

T

BA

RR

IER

REEF

Ashmore Reef

Scott Reef

Rowley Shoals

Flinders IKing I

Cape Barren I

Bruny I

Lord Howe I

Kangaroo I

Fraser I

Curtis I

Hinchinbrook I

Prince of Wales I

Moa I

Mornington I

Vanderlin I

Groote Eylandt

Wessel IsCroker IMelville I

Bathurst I

Augustus I

Barrow I

Dirk Hartog I

Bigge I

TORRES STRA IT

GULF

OF

CARPENTAR IA

Halifax Bay

BroadSound

Repulse Bay

BAS S STRA IT

GREAT AUSTRAL IAN B IGHT

Spen

cer G

ulf

JosephBonaparte

Gulf

Shark Bay

CollierBay

Blue Mud Bay

Van DiemenGulf

TASMAN SEA

CORAL SEA

SOLOMON SEA

ARAFURA SEA

T IMOR S EA

S O U T H P A C I F I C O C E A N

I N D I A N O C E A N

I N D I A N O C E A N

S O U T H E R N O C E A N

S O U T H P A C I F I C O C E A N

P A P U A N E W

G U I N E A

I N D O N E S I AS O L O M O N

I S L A N D S

EAST TIMOR

MADURA

NEW GEORGIA

ISLANDS

LOMBOKJAVA

BALI

SUMBASUMBAWA

FLORES

TIMOR

TANIMBARWETAR

ALOR

D'ENTRECASTEAUXISLANDS

Yulara

Hermannsburg

Papunya

Narrogin

Lancelin

Telfer

Newman

Port Hedland

Paraburdoo

OnslowPannawonica

Karratha Roebourne

Exmouth

Carnarvon

DenhamMeekatharra

Wiluna

Warburton

Leinster

Laverton

Leonora

Mount Magnet

BalladoniaNorseman

Esperance

Kambalda

Northampton

MorawaDongara

Moora

Dalwallinu

Wongan Hills

MerredinKellerberrinNortham

York

Corrigin

Southern Cross

Pingelly

CollieLake Grace

KatanningBusselton

Margaret River

DenmarkMount Barker

Manjimup

Kojonup

Ravensthorpe

Jerramungup

Tom Price

Yarrie

Daly River

Yuendumu

Tennant Creek

Elliott

Kalkarindji(Wave Hill)

Lajamanu

Borroloola

Katherine Barunga (Bamyili)

Ngukurr

Numbulwar

AlyangulaPine Creek

Batchelor

Jabiru

OenpelliNguiu

NhulunbuyGaliwinku

Maningrida

Oodnadatta

Innamincka

Port Douglas

Bamaga

WeipaLockhart River

KowanyamaCooktown

NormantonDoomadgee

Georgetown

Mareeba

Innisfail

Greenvale

Ingham

Ayr

BowenCharters Towers

Hughenden Collinsville

Cloncurry

BouliaWinton

Longreach

Barcaldine Emerald

Clermont

Moranbah

Blackall

Tambo

Springsure

Windorah

Proserpine

DysartMiddlemount

Blackwater

Woorabinda

Biloela

Kalumburu

Wyndham

Kununurra

Halls CreekFitzroy Crossing

Derby

Broome

Lombadina

Birdsville

Thursday Island

BalranaldHay

Ivanhoe

GawlerNuriootpa

Murray Bridge

Victor Harbor

Bordertown

Kingston SE

Naracoorte

Millicent

Ouyen

Swan Hill

Horsham

Hamilton

Portland

Ararat

Smithton

Queenstown

Wilcannia

White Cliffs

Andamooka

Coober Pedy

Tarcoola

Woomera

Marree

Leigh Creek

Ceduna

Streaky BayWudinna

Tumby Bay

Port Lincoln

Kingscote

Cleve

Port Augusta

Hawker

Peterborough

Port Pirie

ClareKadinaRenmark

CharlevilleQuilpie

Thargomindah

Cunnamulla

Broken Hill

Deniliquin Tumut

Bega

CoomaNarooma

Batemans BayUlladulla

Gilgandra

CowraYoung

GriffithWest Wyalong

Narrandera

Katoomba

Bairnsdale

BenallaWangaratta

Echuca

SaleMoe

Wonthaggi

Kingston

UlverstoneGeorge Town

Bridgewater

Burnie

St Marys

Bowral

Cobar

Nyngan

Bourke Brewarrina

Lightning RidgeCollarenebri

Walgett

Moree

Narrabri

Gunnedah

MudgeeParkes

Singleton

SconeTaree

Kempsey

Yamba

BallinaTenterfield

Glen Innes

GraftonInverell

St GeorgeDirranbandi Goondiwindi

SuratTara

RomaMiles

TaroomGayndah

Gympie

Kingaroy

Dalby

Gatton

Beaudesert

Warwick

Monto

Mount Isa

Armidale

Bunbury

RockinghamMandurah

Kalgoorlie-Boulder

Geraldton

LauncestonDevonport

Whyalla

Mount Gambier

Bendigo

Melton

Mildura

Shepparton

Ballarat

Warrnambool

Alice Springs

Darwin

Wagga Wagga

Dubbo

BathurstOrange Maitland

Tamworth

Goulburn

Albury–Wodonga

NowraQueanbeyan

Port Macquarie

Coffs Harbour

Tweed Heads

Lismore

Cairns

Mackay

Rockhampton

Gladstone

Bundaberg

Maryborough

Hervey Bay

Toowoomba

Sunbury

Albany

Palmerston

Traralgon

CANBERRA

WOLLONGONG

CENTRAL COAST

NEWCASTLE

GEELONG

HOBART

GOLD COAST

TOWNSVILLE

SUNSHINE COAST

MELBOURNE

ADELAIDESYDNEY

BRISBANE

PERTH

Tropic of Capricorn Tropic of Capricorn

Simple Conic Projection with Standard Parallels 18°S and 36°S

500 kilometres100 0 100 200 300 400

AUSTRALIAAUSTRALIA

HYPSOMETRIC TINTS BATHYMETRIC TINTS

Heights and depths are shown in metres

2000 1500 1000 500 200 0 200

EDITION 3

Population figures based on

2006 Census data

Populated places

1 000 000 or greater

100 000 - 999 999

20 000 - 99 999

Less than 20 000

State boundary

Reef

Spot elevation

Lake, non-perennial

Lake, perennial

River, non-perennial

River, perennial

1435Road, principal sealed

Road, principal unsealed

Road, secondary sealed

Road, secondary unsealed

Road, minor sealed

Road, minor unsealed

Operational railways

AUSTRALIA FOLIO MAPProduced by the National Geographic Information GroupGeoscience Australia, GEOCAT 73102www.ga.gov.au

© Commonwealth of Australia (Geoscience Australia) 2011This material is released under the Creative CommonsAttribution 3.0 Australia Licence

9 314231 000687

Murchinson

Jack HillsN‘ Jack Hills

Shoemaker Crater

L Woods

L Amadeus

L Macleod

L Mackay

L Auld

L Disappointment

L Carnegie

L Wells

L Carey

L Rebecca

L Dundas

L Cowan

L Moore

L Barlee

L Austin

L Maurice(Carle-Thulka)

L FromeL Torrens

L Eyre South

L Gairdner

L Everard

L Blanche

L Eyre North

L Pedder

L Dalrymple

L Alexandrina

L Argyle

R

Dar

ling

River

LachlanR

Bogan

R

Macq

uarie

R

Gwydir R

Dry

sdale

R

Fitzroy

Riv

er

Vic

tori

aR

Roper R

Go

yde

rR

R

McA

rthur

R

Nicholson

Warr

eg

o

Riv

er

Neb

ine

Ck

Moonie R

Mara

noa

R

Daw

son

R

Be

lyand

oR

Burdekin

R

Holroyd R

Gilbert

Leic

hh

ard

tR

Flin

ders

River

NormanR

Par

oo

R

Thom

son

R

Bullo

oR

iver

Dia

man

tina

River

Georg

ina

RSan

dove

r

R

Finke

Cooper

Ck

War

burto

n

R

Macumba

R

DeR

Fortescue R

Ashburton

River

Gascoyne R

Murc

his

on

R

Grey

River

Murray

R

Murrumbidgee

MitchellR

DalyRiver

Ord R

R

GR

EAT

DIV

IDIN

G

RA

NG

E

GR

EA

T

RAN

GE

MACDONNELL

PETERMANN

RANGES

HAMERSLEY RANGE

KINGLEOPOLD

RANGES

FLIN

DE

RS

RA

NG

ES

RA

DIV

IDIN

G

Mt Meharry1253

Mt Squires704

Mt Ord947

Mt Remarkable751

Mt Evelyn366

Mt Zeil1531

Mt Woodroffe1435

St Mary Peak1168

Mt Kosciuszko2229

Ulu u-Ayers Rock863

r

Mt Buller1805

Round Mtn1586

Consuelo Peak1174

Mt Dalrymple1300

Bartle Frere1622

Mt Ossa1617

T A N A M I D E S E R T

S I M P S O N D E S E R T

G R E A T V I C T O R I A D E S E R T

G I B S O N D E S E R T

G R E A T S A N D Y D E S E R T

L I T T L E S A N D Y D E S E R T

S T R Z E L E C K I

D E S E R T

A R N H E M L A N D

N U L L A R B O R P L A I N

K I M B E R L E Y

P I L B A R A

C A P E

Y O R K

P E N I N S U L A

G U L F C O U N T R Y

B A R K L Y

T A B L E L A N D

CH

AN

NE

L

CO

UN

TR

Y

V I C T O R I A

T A S M A N I A

A C T

N E W S O U T H W A L E S

Q U E E N S L A N D

N O R T H E R N T E R R I T O R Y

W E S T E R N A U S T R A L I A

S O U T H A U S T R A L I A

Warrior Reefs

Osprey Reef

Willis Group

Lihou Reefs

Flinders Reefs

Marion Reef

Saumarez Reef

GR

EA

T

BA

RR

IER

REEF

Ashmore Reef

Scott Reef

Rowley Shoals

Flinders IKing I

Cape Barren I

Bruny I

Lord Howe I

Kangaroo I

Fraser I

Curtis I

Hinchinbrook I

Prince of Wales I

Moa I

Mornington I

Vanderlin I

Groote Eylandt

Wessel IsCroker IMelville I

Bathurst I

Augustus I

Barrow I

Dirk Hartog I

Bigge I

TORRES STRA IT

GU LF

OF

C A RPENTA R IA

Halifax Bay

BroadSound

Repulse Bay

BAS S STRA IT

GREAT AUSTRAL IAN B IGHT

Spen

cer G

ulf

JosephBonaparte

Gulf

Shark Bay

CollierBay

Blue Mud Bay

Van DiemenGulf

TASMAN SEA

CORAL SEA

SOLOMON SEA

A RA FURA SEA

T IMOR SEA

S O U T H P A C I F I C O C E A N

I N D I A N O C E A N

I N D I A N O C E A N

S O U T H E R N O C E A N

S O U T H P A C I F I C O C E A N

P A P U A N E W

G U I N E A

I N D O N E S I AS O L O M O N

I S L A N D S

EAST TIMOR

MADURA

NEW GEORGIA

ISLANDS

LOMBOKJAVA

BALI

SUMBASUMBAWA

FLORES

TIMOR

TANIMBARWETAR

ALOR

D'ENTRECASTEAUXISLANDS

Yulara

Hermannsburg

Papunya

Narrogin

Lancelin

Telfer

Newman

Port Hedland

Paraburdoo

OnslowPannawonica

Karratha Roebourne

Exmouth

Carnarvon

DenhamMeekatharra

Wiluna

Warburton

Leinster

Laverton

Leonora

Mount Magnet

BalladoniaNorseman

Esperance

Kambalda

Northampton

MorawaDongara

Moora

Dalwallinu

Wongan Hills

MerredinKellerberrinNortham

York

Corrigin

Southern Cross

Pingelly

CollieLake Grace

KatanningBusselton

Margaret River

DenmarkMount Barker

Manjimup

Kojonup

Ravensthorpe

Jerramungup

Tom Price

Yarrie

Daly River

Yuendumu

Tennant Creek

Elliott

Kalkarindji(Wave Hill)

Lajamanu

Borroloola

Katherine Barunga (Bamyili)

Ngukurr

Numbulwar

AlyangulaPine Creek

Batchelor

Jabiru

OenpelliNguiu

NhulunbuyGaliwinku

Maningrida

Oodnadatta

Innamincka

Port Douglas

Bamaga

WeipaLockhart River

KowanyamaCooktown

NormantonDoomadgee

Georgetown

Mareeba

Innisfail

Greenvale

Ingham

Ayr

BowenCharters Towers

Hughenden Collinsville

Cloncurry

BouliaWinton

Longreach

Barcaldine Emerald

Clermont

Moranbah

Blackall

Tambo

Springsure

Windorah

Proserpine

DysartMiddlemount

Blackwater

Woorabinda

Biloela

Kalumburu

Wyndham

Kununurra

Halls CreekFitzroy Crossing

Derby

Broome

Lombadina

Birdsville

Thursday Island

BalranaldHay

Ivanhoe

GawlerNuriootpa

Murray Bridge

Victor Harbor

Bordertown

Kingston SE

Naracoorte

Millicent

Ouyen

Swan Hill

Horsham

Hamilton

Portland

Ararat

Smithton

Queenstown

Wilcannia

White Cliffs

Andamooka

Coober Pedy

Tarcoola

Woomera

Marree

Leigh Creek

Ceduna

Streaky BayWudinna

Tumby Bay

Port Lincoln

Kingscote

Cleve

Port Augusta

Hawker

Peterborough

Port Pirie

ClareKadinaRenmark

CharlevilleQuilpie

Thargomindah

Cunnamulla

Broken Hill

Deniliquin Tumut

Bega

CoomaNarooma

Batemans BayUlladulla

Gilgandra

CowraYoung

GriffithWest Wyalong

Narrandera

Katoomba

Bairnsdale

BenallaWangaratta

Echuca

SaleMoe

Wonthaggi

Kingston

UlverstoneGeorge Town

Bridgewater

Burnie

St Marys

Bowral

Cobar

Nyngan

Bourke Brewarrina

Lightning RidgeCollarenebri

Walgett

Moree

Narrabri

Gunnedah

MudgeeParkes

Singleton

SconeTaree

Kempsey

Yamba

BallinaTenterfield

Glen Innes

GraftonInverell

St GeorgeDirranbandi Goondiwindi

SuratTara

RomaMiles

TaroomGayndah

Gympie

Kingaroy

Dalby

Gatton

Beaudesert

Warwick

Monto

Mount Isa

Armidale

Bunbury

RockinghamMandurah

Kalgoorlie-Boulder

Geraldton

LauncestonDevonport

Whyalla

Mount Gambier

Bendigo

Melton

Mildura

Shepparton

Ballarat

Warrnambool

Alice Springs

Darwin

Wagga Wagga

Dubbo

BathurstOrange Maitland

Tamworth

Goulburn

Albury–Wodonga

NowraQueanbeyan

Port Macquarie

Coffs Harbour

Tweed Heads

Lismore

Cairns

Mackay

Rockhampton

Gladstone

Bundaberg

Maryborough

Hervey Bay

Toowoomba

Sunbury

Albany

Palmerston

Traralgon

CANBERRA

WOLLONGONG

CENTRAL COAST

NEWCASTLE

GEELONG

HOBART

GOLD COAST

TOWNSVILLE

SUNSHINE COAST

MELBOURNE

ADELAIDESYDNEY

BRISBANE

PERTH

Tropic of Capricorn Tropic of Capricorn

Simple Conic Projection with Standard Parallels 18°S and 36°S

500 kilometres100 0 100 200 300 400

AUSTRALIAAUSTRALIA

HYPSOMETRIC TINTS BATHYMETRIC TINTS

Heights and depths are shown in metres

2000 1500 1000 500 200 0 200

EDITION 3

Population figures based on

2006 Census data

Populated places

1 000 000 or greater

100 000 - 999 999

20 000 - 99 999

Less than 20 000

State boundary

Reef

Spot elevation

Lake, non-perennial

Lake, perennial

River, non-perennial

River, perennial

1435Road, principal sealed

Road, principal unsealed

Road, secondary sealed

Road, secondary unsealed

Road, minor sealed

Road, minor unsealed

Operational railways

AUSTRALIA FOLIO MAPProduced by the National Geographic Information GroupGeoscience Australia, GEOCAT 73102www.ga.gov.au

© Commonwealth of Australia (Geoscience Australia) 2011This material is released under the Creative CommonsAttribution 3.0 Australia Licence

9 314231 000687

L Woods

L Amadeus

L Macleod

L Mackay

L Auld

L Disappointment

L Carnegie

L Wells

L Carey

L Rebecca

L Dundas

L Cowan

L Moore

L Barlee

L Austin

L Maurice(Carle-Thulka)

L FromeL Torrens

L Eyre South

L Gairdner

L Everard

L Blanche

L Eyre North

L Pedder

L Dalrymple

L Alexandrina

L Argyle

R

Dar

ling

River

LachlanR

Bogan

R

Macq

uarie

R

Gwydir R

Dry

sdale

R

Fitzroy

Riv

er

Vic

tori

aR

Roper R

Go

yde

rR

R

McA

rthur

R

Nicholson

Warr

eg

o

Riv

er

Neb

ine

Ck

Moonie R

Mara

noa

R

Daw

son

R

Be

lyand

oR

Burdekin

R

Holroyd R

Gilbert

Leic

hh

ard

tR

Flin

ders

River

NormanR

Par

oo

R

Thom

son

R

Bullo

oR

iver

Dia

man

tina

River

Georg

ina

RSan

dove

r

R

Finke

Cooper

Ck

War

burto

n

R

Macumba

R

DeR

Fortescue R

Ashburton

River

Gascoyne R

Murc

his

on

R

Grey

River

Murray

R

Murrumbidgee

MitchellR

DalyRiver

Ord R

R

GR

EAT

DIV

IDIN

G

RA

NG

E

GR

EA

T

RAN

GE

MACDONNELL

PETERMANN

RANGES

HAMERSLEY RANGE

KINGLEOPOLD

RANGES

FLIN

DE

RS

RA

NG

ES

RA

DIV

IDIN

G

Mt Meharry1253

Mt Squires704

Mt Ord947

Mt Remarkable751

Mt Evelyn366

Mt Zeil1531

Mt Woodroffe1435

St Mary Peak1168

Mt Kosciuszko2229

Ulu u-Ayers Rock863

r

Mt Buller1805

Round Mtn1586

Consuelo Peak1174

Mt Dalrymple1300

Bartle Frere1622

Mt Ossa1617

T A N A M I D E S E R T

S I M P S O N D E S E R T

G R E A T V I C T O R I A D E S E R T

G I B S O N D E S E R T

G R E A T S A N D Y D E S E R T

L I T T L E S A N D Y D E S E R T

S T R Z E L E C K I

D E S E R T

A R N H E M L A N D

N U L L A R B O R P L A I N

K I M B E R L E Y

P I L B A R A

C A P E

Y O R K

P E N I N S U L A

G U L F C O U N T R Y

B A R K L Y

T A B L E L A N D

CH

AN

NE

L

CO

UN

TR

Y

V I C T O R I A

T A S M A N I A

A C T

N E W S O U T H W A L E S

Q U E E N S L A N D

N O R T H E R N T E R R I T O R Y

W E S T E R N A U S T R A L I A

S O U T H A U S T R A L I A

Warrior Reefs

Osprey Reef

Willis Group

Lihou Reefs

Flinders Reefs

Marion Reef

Saumarez Reef

GR

EA

T

BA

RR

IER

REEF

Ashmore Reef

Scott Reef

Rowley Shoals

Flinders IKing I

Cape Barren I

Bruny I

Lord Howe I

Kangaroo I

Fraser I

Curtis I

Hinchinbrook I

Prince of Wales I

Moa I

Mornington I

Vanderlin I

Groote Eylandt

Wessel IsCroker IMelville I

Bathurst I

Augustus I

Barrow I

Dirk Hartog I

Bigge I

TORRES STRA IT

GULF

OF

CARPENTAR IA

Halifax Bay

BroadSound

Repulse Bay

BAS S STRA IT

GREAT AUSTRAL IAN B IGHT

Spen

cer G

ulf

JosephBonaparte

Gulf

Shark Bay

CollierBay

Blue Mud Bay

Van DiemenGulf

TASMAN SEA

CORAL SEA

SOLOMON SEA

ARAFURA SEA

T IMOR SEA

S O U T H P A C I F I C O C E A N

I N D I A N O C E A N

I N D I A N O C E A N

S O U T H E R N O C E A N

S O U T H P A C I F I C O C E A N

P A P U A N E W

G U I N E A

I N D O N E S I AS O L O M O N

I S L A N D S

EAST TIMOR

MADURA

NEW GEORGIA

ISLANDS

LOMBOKJAVA

BALI

SUMBASUMBAWA

FLORES

TIMOR

TANIMBARWETAR

ALOR

D'ENTRECASTEAUXISLANDS

Yulara

Hermannsburg

Papunya

Narrogin

Lancelin

Telfer

Newman

Port Hedland

Paraburdoo

OnslowPannawonica

Karratha Roebourne

Exmouth

Carnarvon

DenhamMeekatharra

Wiluna

Warburton

Leinster

Laverton

Leonora

Mount Magnet

BalladoniaNorseman

Esperance

Kambalda

Northampton

MorawaDongara

Moora

Dalwallinu

Wongan Hills

MerredinKellerberrinNortham

York

Corrigin

Southern Cross

Pingelly

CollieLake Grace

KatanningBusselton

Margaret River

DenmarkMount Barker

Manjimup

Kojonup

Ravensthorpe

Jerramungup

Tom Price

Yarrie

Daly River

Yuendumu

Tennant Creek

Elliott

Kalkarindji(Wave Hill)

Lajamanu

Borroloola

Katherine Barunga (Bamyili)

Ngukurr

Numbulwar

AlyangulaPine Creek

Batchelor

Jabiru

OenpelliNguiu

NhulunbuyGaliwinku

Maningrida

Oodnadatta

Innamincka

Port Douglas

Bamaga

WeipaLockhart River

KowanyamaCooktown

NormantonDoomadgee

Georgetown

Mareeba

Innisfail

Greenvale

Ingham

Ayr

BowenCharters Towers

Hughenden Collinsville

Cloncurry

BouliaWinton

Longreach

Barcaldine Emerald

Clermont

Moranbah

Blackall

Tambo

Springsure

Windorah

Proserpine

DysartMiddlemount

Blackwater

Woorabinda

Biloela

Kalumburu

Wyndham

Kununurra

Halls CreekFitzroy Crossing

Derby

Broome

Lombadina

Birdsville

Thursday Island

BalranaldHay

Ivanhoe

GawlerNuriootpa

Murray Bridge

Victor Harbor

Bordertown

Kingston SE

Naracoorte

Millicent

Ouyen

Swan Hill

Horsham

Hamilton

Portland

Ararat

Smithton

Queenstown

Wilcannia

White Cliffs

Andamooka

Coober Pedy

Tarcoola

Woomera

Marree

Leigh Creek

Ceduna

Streaky BayWudinna

Tumby Bay

Port Lincoln

Kingscote

Cleve

Port Augusta

Hawker

Peterborough

Port Pirie

ClareKadinaRenmark

CharlevilleQuilpie

Thargomindah

Cunnamulla

Broken Hill

Deniliquin Tumut

Bega

CoomaNarooma

Batemans BayUlladulla

Gilgandra

CowraYoung

GriffithWest Wyalong

Narrandera

Katoomba

Bairnsdale

BenallaWangaratta

Echuca

SaleMoe

Wonthaggi

Kingston

UlverstoneGeorge Town

Bridgewater

Burnie

St Marys

Bowral

Cobar

Nyngan

Bourke Brewarrina

Lightning RidgeCollarenebri

Walgett

Moree

Narrabri

Gunnedah

MudgeeParkes

Singleton

SconeTaree

Kempsey

Yamba

BallinaTenterfield

Glen Innes

GraftonInverell

St GeorgeDirranbandi Goondiwindi

SuratTara

RomaMiles

TaroomGayndah

Gympie

Kingaroy

Dalby

Gatton

Beaudesert

Warwick

Monto

Mount Isa

Armidale

Bunbury

RockinghamMandurah

Kalgoorlie-Boulder

Geraldton

LauncestonDevonport

Whyalla

Mount Gambier

Bendigo

Melton

Mildura

Shepparton

Ballarat

Warrnambool

Alice Springs

Darwin

Wagga Wagga

Dubbo

BathurstOrange Maitland

Tamworth

Goulburn

Albury–Wodonga

NowraQueanbeyan

Port Macquarie

Coffs Harbour

Tweed Heads

Lismore

Cairns

Mackay

Rockhampton

Gladstone

Bundaberg

Maryborough

Hervey Bay

Toowoomba

Sunbury

Albany

Palmerston

Traralgon

CANBERRA

WOLLONGONG

CENTRAL COAST

NEWCASTLE

GEELONG

HOBART

GOLD COAST

TOWNSVILLE

SUNSHINE COAST

MELBOURNE

ADELAIDESYDNEY

BRISBANE

PERTH

Tropic of Capricorn Tropic of Capricorn

Simple Conic Projection with Standard Parallels 18°S and 36°S

500 kilometres100 0 100 200 300 400

AUSTRALIAAUSTRALIA

HYPSOMETRIC TINTS BATHYMETRIC TINTS

Heights and depths are shown in metres

2000 1500 1000 500 200 0 200

EDITION 3

Population figures based on

2006 Census data

Populated places

1 000 000 or greater

100 000 - 999 999

20 000 - 99 999

Less than 20 000

State boundary

Reef

Spot elevation

Lake, non-perennial

Lake, perennial

River, non-perennial

River, perennial

1435Road, principal sealed

Road, principal unsealed

Road, secondary sealed

Road, secondary unsealed

Road, minor sealed

Road, minor unsealed

Operational railways

AUSTRALIA FOLIO MAPProduced by the National Geographic Information GroupGeoscience Australia, GEOCAT 73102www.ga.gov.au

© Commonwealth of Australia (Geoscience Australia) 2011This material is released under the Creative CommonsAttribution 3.0 Australia Licence

9 314231 000687

Australian crustal elements

Archaean

Paleo- proterozoic

Shoemaker Crater

© T. Kirnbauer

Geological map of the Shoemaker crater

FID-Analysis of a fluid inclusion of a hydrothermal quartz (Shoemaker Crater)

Landsat image of the Shoemaker crater

© T. Kirnbauer

COS

Methyl-chloride

Iso-Butylene + Butylene

1,3-Butadiene

cis-Butylene

trans-Butylene

Methylbromide

Pentene Furane

Isoprene

Methyliodide

CS2

0 10 km

Methane

Ethane

Propane Propene Acetylene Butene

Chromatogram of fluid inclusions of a > 2.7 bn years old hydrothermal quartz boulder (run time from 12.75 to 25 min)

Sampling locations

Chromatograms of fluid inclusions of different hydrothermal quartz samples

EthyliodideBenzene

p-Xylene

m-Xylene

o-Xylene+Styrene

Toluene