quantum information processing by nmr: recent...
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![Page 1: Quantum Information Processing by NMR: Recent Developments.chep.iisc.ac.in/Meetings/CQIQC/ICQIQC/talks/Jan07_Kumar.pdf · Anil Kumar, K. R. Koteswara Rao and V.S. Manu Indian Institute](https://reader036.vdocuments.us/reader036/viewer/2022071101/5fdad033cc16a6765a46d888/html5/thumbnails/1.jpg)
Anil Kumar, K. R. Koteswara Rao and V.S. Manu Indian Institute of Science, Bangalore
Quantum Information Processing by NMR: Recent Developments.
ICQIQC-2013, Jan 7-11, Bangalore
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Experimental Techniques for Quantum Computation:
1. Trapped Ions
4. Quantum Dots
3. Cavity Quantum Electrodynamics (QED)
6. NMR
Ion Trap:Ion Trap:Linear Paul-Trap
~16 MHz
1kV
1kV
LaserCooled
IonsT ~ mK
Quantum Dots:Quantum Dots:
mElectrodesDot
Circle
http://theorie5.physik.unibas.ch/qcomp/node3.html
http://news.uns.purdue.edu/html4ever/010917.Chang.quantum.html
7. Josephson junction qubits 8. Fullerence based ESR quantum computer
5. Cold Atoms
2. Polarized Photons Lasers
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Ion Trap:Ion Trap:Linear Paul-Trap
~16 MHz
1kV
1kV
LaserCooled
IonsT ~ mK
Nobel Prize in Physics 2012
Trapped Ions Cavity Quantum Electrodynamics (QED)
Haroche has been one of the pioneers in the field of cavity quantum electrodynamics, He observed a single atom interacting with a few photons inside a reflective cavity and can keep a photon bouncing back and forth in a centimeter-sized cavity billions of times before it escapes
Wineland performed quantum-probing experiments with trapped ions. The tight confinement of ions in these electric field traps causes ion motion to be restricted to distinct quantum states, each of which represents a different frequency of bouncing back-and-forth between the electric field “walls.”
Michael Schirber
David Wineland Serge Haroche
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0
1. Nuclear spins have small magnetic moments and behave as tiny quantum magnets.
2. When placed in a magnetic field (B0), spin ½ nuclei orient either along the field (|0 state) or opposite to the field (|1 state) .
4. Spins are coupled to other spins by indirect spin-spin (J) coupling, and controlled (C-NOT) operations can be performed using J-coupling. Multi-qubit gates
Nuclear Magnetic Resonance (NMR)
3. A transverse radio-frequency field (B1) tuned at the Larmor frequency of spins can cause transition from |0 to |1 (NOT Gate by a 1800 pulse). Or put them in coherent superposition (Hadamard Gate by a 900 pulse). Single qubit gates.
NUCLEAR SPINS ARE QUBITS
B1
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DSX 300 7.0 Tesla
AMX 400 9.4 Tesla
AV 500 11.7 Tesla
AV 700 16.5 Tesla
DRX 500 11.7 Tesla
NMR Research Centre, IISc 1 PPB
Field/ Frequency stability = 1:10 9
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Why NMR?
> A major requirement of a quantum computer is that the coherence should last long.
> Nuclear spins in liquids retain coherence ~ 100’s millisec and their longitudinal state for several seconds.
> A system of N coupled spins (each spin 1/2) form an N qubit Quantum Computer.
> Unitary Transform can be applied using R.F. Pulses and J-evolution and various logical operations and quantum algorithms can be implemented.
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NMR sample has ~ 1018 spins.
Do we have 1018 qubits?
No - because, all the spins can’t be individually addressed.
Spins having different Larmor frequencies can be addressed in the frequency domain resulting-in as many “qubits” as Larmor
frequencies, each having 1018 spins. (ensemble computing)
Progress so far
One needs resolved couplings between the spins in order to encode information as qubits.
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NMR Hamiltonian H = HZeeman + HJ-coupling
= izi Jij Ii Ij
i i < j
Weak coupling Approximation ijJij
Two Spin System (AM)
A2 A1 M2 M1
A M
M1= A
M2= A
A1= M
A2= M
H = izi Jij Izi Izj
Under this approximation spins having same Larmor Frequency
can be treated as one Qubit
i i < j
Spin States are eigenstates
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13CHFBr2
An example of a three qubit system.
A molecule having three different nuclear spins (each spin ½ ), having different Larmor frequencies, coupled to each other with large 1 and 2 bond couplings,
forms a nice hetero-nuclear 3-qubit (19F-13C-1H) system.
1H = 500 MHz 13C = 125 MHz 19F = 470 MHz
13C
Br (spin 3/2) is a quadrupolar nucleus, is decoupled from the rest of the spin system and can be ignored.
JCH = 225 Hz JCF = -311 Hz JHF = 50 Hz
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1 Qubit
00
01 10
11
0
1
CHCl3
000
001 010
011
100
101 110
111
2 Qubits 3 Qubits
Homo-nuclear spins having different Chemical shifts (Larmor frequencies) also form multi-qubit systems
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Pseudo-Pure States
Pure States:
Tr(ρ ) = Tr ( ρ2 ) = 1 For a diagonal density matrix, this condition requires that all energy levels except one have zero populations.
Such a state is difficult to create in room temperature liquid-state NMR
We create a state in which all levels except one have EQUAL populations. Such a state mimics a pure state.
ρ = 1/N ( α1 - Δρ )
Under High Temperature Approximation
Here α = 105 and U 1 U-1 = 1
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Pseudo-Pure State
In a two-qubit Homo-nuclear system: (Under High Field Approximation)
(i) Equilibrium: ρ = 105 + Δρ = {2, 1, 1, 0} Δρ ~ Iz1+Iz2 = { 1, 0, 0, -1} (ii) Pseudo-Pure Δρ = {4, 0, 0, 0}
0
1
2
1
0
0
4
0 Δρ ~ Iz1+Iz2 + 2 Iz1Iz2
= { 3/2, -1/2, -1/2, -1/2}
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• Spatial Averaging • Logical Labeling
• Temporal Averaging • Pairs of Pure States (POPS) • Spatially Averaged Logical Labeling Technique (SALLT)
Cory, Price, Havel, PNAS, 94, 1634 (1997)
E. Knill et al., PRA, 57, 3348 (1998)
N. Gershenfeld et al, Science, 275, 350 (1997) Kavita, Arvind, Anil Kumar, PRA 61, 042306 (2000)
B.M. Fung, Phys. Rev. A 63, 022304 (2001)
T. S. Mahesh and Anil Kumar, PRA 64, 012307 (2001)
Preparation of Pseudo-pure states
Using long lived Singlet States S.S. Roy and T.S. Mahesh, PRA, 82, 052302 (2010).
•
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Spatial Averaging: Most commonly used method
X
(2) X
(1)
1/2J
2 4 5 6 1 3
Gx
Y
(1)
I1z + I2z + 2I1zI2z = 1/2
3 0 0 0 0 -1 0 0 0 0 -1 0 0 0 0 -1
Pseudo-pure state
I1z = 1/2
1 0 0 0 0 1 0 0 0 0 -1 0 0 0 0 -1
I2z = 1/2
1 0 0 0 0 -1 0 0 0 0 1 0 0 0 0 -1
2I1z I2z = 1/2 1 0 0 0 0 -1 0 0 0 0 -1 0 0 0 0 1
Eq.= I1z+I2z I1z + I2z + 2I1zI2z
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1. Preparation of Pseudo-Pure States
2. Quantum Logic Gates
3. Deutsch-Jozsa Algorithm
4. Grover’s Algorithm
5. Hogg’s algorithm
6. Berstein-Vazirani parity algorithm
7. Quantum Games
8. Creation of EPR and GHZ states
9. Entanglement transfer
Achievements of NMR - QIP
10. Quantum State Tomography
11. Geometric Phase in QC
12. Adiabatic Algorithms
13. Bell-State discrimination
14. Error correction
15. Teleportation
16. Quantum Simulation
17. Quantum Cloning
18. Shor’s Algorithm
19. No-Hiding Theorem
Maximum number of qubits achieved in our lab: 8 Also performed in our Lab.
In other labs.: 12 qubits; Negrevergne, Mahesh, Cory, Laflamme et al., Phys. Rev. Letters, 96, 170501 (2006).
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Recent Developments in our Laboratory
1. Use of Genetic Algorithm in Quantum Information Processing.
(a) Gates and Bell State creation.
(b) Quantum Simulation of Dzyaloshinsky-Moriya (DM) interaction in presence of Heisenberg XY interaction.
(Poster No. 54; V.S. Manu) 2. Study of frustration in quantum Ising spin systems by NMR.*
* Work carried out in collaboration with Aditi Sen (De), Ujjwal Sen, Hemanth Katiyar
and T.S. Mahesh. (Poster No. 22; Koteswara Rao )
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The Genetic Algorithm
Directed search algorithms based on the mechanics of biological evolution
Developed by John Holland, University of Michigan (1970’s)
John Holland Charles Darwin 1866 1809-1882
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“Genetic Algorithms are good at taking large, potentially huge, search spaces and navigating them, looking for optimal combinations of things, solutions one might not otherwise find in a lifetime”
Genetic Algorithm
Here we apply Genetic Algorithm to Quantum Information Processing
In the first part (a) we have used GA for
Quantum Logic Gates (operator optimization) and
Quantum State preparation (state-to-state optimization)
V.S. Manu et al. Phys. Rev. A 86, 022324 (2012)
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Representation Scheme
Representation scheme is the method used for encoding the solution of the problem to individual genetic evolution. Designing a
good genetic representation is a hard problem in evolutionary computation. Defining proper representation scheme is the first
step in GA Optimization.
In our representation scheme we have selected the gene as a combination of
(i) an array of pulses, which are applied to each channel with amplitude (θ) and phase (φ), (ii) An arbitrary delay (d). It can be shown that the repeated application of above gene forms the most general pulse sequence in NMR
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The Individual, which represents a valid solution can be represented as a matrix of size (n+1)x2m. Here ‘m’ is the number of genes in each individual and ‘n’ is the number of channels (or spins/qubits). So the problem is to find an optimized matrix, in which the optimality condition is imposed by a “Fitness Function”
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Fitness function
In operator optimization GA tries to reach a preferred target Unitary Operator (Utar) from an initial random guess pulse sequence operator (Upul). Maximizing the Fitness function Fpul = Trace (Upul Χ Utar )
In State-to-State optimization Fpul = Trace { U pul (ρin) Upul (-1) ρtar † }
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Two-qubit Homonuclear case
H = 2π δ (I1z – 12z) + 2π J12 (I1zI2z)
Single qubit rotation
δ = 500 Hz, J= 3.56 Hz
φ1 = 2π, φ2 = π, Θ = π/2, φ = π/2
φ1 = π, φ2 = 0 Θ = π/2, φ = π/2
π/2 π/2
Simulated using J = 0
Hamiltonian used
Non-Selective (Hard) Pulses applied in the centre
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Fidelity for finite J/δ
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Controlled- NOT:
Equilibrium
00
01 10 11
1
-1 0 0
00
01 10 11
1
-1 0
0
00
01 10 11
1 -1 0
0
00
01 10 11 1
-1 0
0 00
01 10 11 1
-1
0 0
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Pseudo Pure State (PPS) creation
All unfilled rectangles represent 900 pulse The filled rectangle is 1800 pulse. Phases are given on the top of each pulse.
Fidelity w.r.t. to J/δ
00 01 10 11
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0
0
0
0
Bell state creation: From Equilibrium (No need of PPS)
Bell states are maximally entangled two qubit states.
The Singlet Bell State
Experimental Fidelity > 99.5 %
Shortest Pulse Sequence for creation of Bell States directly from Equilibrium
All blank pulses are 900 pulses. Filled pulse is a 1800 pulse. Phases and delays Optimized for best fidelity.
T1=8.7 s Ts=11.2 s V.S. Manu et al. Phys. Rev. A 86, 022324 (2012)
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(b) Quantum Simulation of Dzyaloshinsky-Moriya (DM) interaction (HDM) in presence of Heisenberg XY interaction (HXY) for study of Entanglement Dynamics
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DM Interaction1,2 Anisotropic antisymmetric exchange interaction arising from spin‐orbit coupling. Proposed by Dzyaloshinski to explain the weak ferromagnetism of antiferromagnetic crystals (Fe2O3, MnCO3).
Quantum simulation of a Hamiltonian H requires unitary operator decomposition (UOD) of its evolution operator, (U = e‐iHt) in terms of experimentally preferable unitaries.
Using Genetic Algorithm optimization, we numerically evaluate the most generic UOD for DM interaction in the presence of Heisenberg XY interaction.
1. I. Dzyaloshinsky, J. Phys & Chem of Solids, 4, 241 (1958). 2. T. Moriya, Phys. Rev. Letters, 4, 228 (1960).
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Decomposing the U in terms of Single Qubit Rotations (SQR) and ZZ‐ evolutions.
SQR by Hard pulse
ZZ evolutions by Delays
The Hamiltonian
Heisenberg XY interaction DM interaction
Evolution Operator:
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Fidelity is defined as.
A. The Decomposition for ϒ = 0 ‐1:
1
Manu et al. to be communicated. Fidelity > 99.99 %
Period of U(ϒ,τ)
This has a maximum value of 12.59. Optimization is performed for τ ‐> 0‐15, which includes one complete period.
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2
When ϒ > 1 ‐> ϒ’ < 1
3Phys. Rev. A, 69 012313 (2009)
ϒ’ = 1/ ϒ
Using above decomposition, we studied entanglement preservation in a two qubit system.
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Hou et al. 2 demonstrated a mechanism for entanglement preservation using H(J,D). They showed that preservation of initial entanglement is performed by free evolution interrupted with a certain operator O, which makes the state to go back to its initial state.
2Hou et al. Annals of Physics, 327 292 (2012)
Entanglement Preservation
Without Operator O
Our study experimentally demonstrates the entanglement preservation procedure of Hou et al.
With Operator O
Poster No. 54
concurrence
µi are eigen values of the operator ρSρ*S, where S= σ1y ⊗ σ2y
Manu et al. (to be communicated)
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Quantum simulation of frustrated Ising spins by NMR
K.R.Koteswara Rao1, Aditi Sen (De)2, Ujjwal Sen2, H. Katiyar3, T.S. Mahesh3 and Anil Kumar1
1 Indian Institute of Science, Bangalore 2 Harish-Chandra Research Institute, Allahabad 3 Indian Institute of Science Education and Research, Pune
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A spin system is frustrated when the minimum of the system energy does
not correspond to the minimum of all local interactions1. Frustration in
electronic spin systems leads to exotic materials such as spin glasses and
spin ice materials.
If J is negative Ferromagnetic
If J is positive Anti-ferromagnetic
The system is frustrated
3-spin transverse Ising system
≫
The system is non-frustrated
1H. T. Diep, Frustrated Spin Systems (World Scientific (2004))
Transverse field Ising interaction
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Here, we simulate experimentally the ground state of this spin system in
both the frustrated and non-frustrated regimes using Nuclear Magnetic
Resonance.
We use two different multipartite quantum correlation measures to
distinguish these phases.
These multipartite quantum correlation measures are defined through
the monogamy of bipartite quantum correlations (Negativity and
Quantum discord).
Let A, B and C be the three parts of a system. Monogamy of quantum
correlations implies that if A and B are strongly correlated then they
can have only a restricted amount of correlations with C.
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(i) Negativity
Negativity1 of an arbitrary bipartite quantum state ( ) is the
absolute value of the sum of the negative eigen values of the partial
transposed state ( ), where the partial transposition is taken with
respect to the subsystem 1.
The corresponding multipartite quantum correlation measure is given by
Negativity is an important bipartite quantum correlation measure, defined
through the entanglement-separability paradigm.
where is the Negativity of the state in the 1:23 partition. is the Negativity of the reduced state and similarly for .
1G. Vidal and R. F. Werner, Phys. Rev. A 65, 032314 (2002).
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(ii) Quantum discord
Quantum discord is defined as the difference between two classically
equivalent formulations of mutual information, when the systems involved are
quantum1, and is given by
,
where and are respectively the measures of total and classical
correlations of .
The corresponding multipartite quantum correlation is given by
and | ,
where is the von Neumann entropy and | ∑ | is the
conditional entropy with the minimization being performed over all possible orthonormal measurement
bases on subsystem A. Here | and the probability .
where is the Discord of the state in the 1:23 partition. is the Discord of the reduced state and similarly for .
1Henderson et al., J. Phys. A 34, 6899 (2001); Ollivier et al., Phys. Rev. Lett. 88, 017901 (2001)
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Quantum adiabatic theorem states that: ‘if a system is initially in the ground
state and if its Hamiltonian evolves slowly with time, it will be found at any
later time in the ground state of the instantaneous Hamiltonian.’
; ;,
Ground State Preparation using adiabatic evolution
The Hamiltonian evolution rate is governed by the expression,
where is a small number, | ; and | ; are respectively the ground and
first excited states of the instantaneous Hamiltonian and is the
energy difference between the corresponding energy levels.
A. Messiah, Quantum Mechanics, vol. II (Wiley, New York (1976)); E. Farhi, J. Goldstone, S. Guttmann, M. Sipser, quantph/0001106
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The system is initially prepared in the ground state of
| |;
| | |
is varied from
0 to adiabatically
is varied from 0 to - adiabatically
Non-frustrated Frustrated
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Energy level diagram E0 and E1 represent the energy
levels corresponding to the ground
state and the excited one which is
relevant in the calculation of the
adiabatic evolution rate.
Though there are energy levels in
between E0 and E1, there are no
possible transitions from the ground
state to these excited states as the
transition amplitudes are zero in
these cases.
Considering the energy gap between E0 and E1, we varied J as a sine hyperbolic
function of t.
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In the actual experimental implementation, the Hamiltonian is discretized1 into M+1 steps as , where T is the total duration of
the adiabatic evolution and m goes from 0 to M.
, where .
Since the two parts of the Hamiltonian do not commute, we use Trotter’s
approximation for small ∆ .
In the experiment J is varied in 21 steps.
1M. Steffen, W. van Dam, T. Hogg, G. Bryeta, I. Chuang, Phys. Rev. Lett. 90, 067903 (2003)
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Chemical Structure of trifluoroiodoethylene and Hamiltonian parameters
| Pseudo-Pure State (PPS) is prepared
from the equilibrium by using the spatial
averaging method.
The initial state | is prepared from the | PPS by applying a rotation with
respect to –y axis on all the three spins.
This rotation was realized by a numerically optimized amplitude and phase
modulated radio frequency (RF) pulse using GRadient Ascent Pulse Engineering
(GRAPE) technique1.
1N. Khaneja and S. J. Glaser et al., J. Magn. Reson. 172, 296 (2005).
Experiment
A three qubit system Diagonal elements are the chemical shifts ( ) and off-diagonal elements are the scalar coupling constants ( )
The experiments have been carried out at a temperature of 290 K on Bruker AV 500
MHz liquid state NMR spectrometers.
,
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All the unitary operators corresponding to the adiabatic evolution are also
implemented by using GRAPE pulses.
The length of these pulses ranges between 2ms to 30 ms.
Robust against RF field inhomogeneity.
The average Hilbert-Schmidt fidelity is
greater than 0.995
(a)
(b)
(c)
Quadrature components of the
control fields of the GRAPE
pulses corresponding to (a) –
y rotation of all the spins and
combined unitary operators
which implements the last step
in (b) non-frustrated and (c)
frustrated regions.
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Quantum state tomography of the full density matrix is performed after every
second step in both the regimes.
In liquid state NMR quantum information processing, in general we consider
only the deviation part of the density matrix and ignore identity.
The density matrix of NMR systems is given by
∆ , ~ ,
But, for calculating the quantum discord from the experimental density
matrices, we considered the full mixed state NMR density matrix. Although the
discord is very small, it’s behavior is very much similar to that of the pure
states.
where ∆ is the deviation density matrix and N is 2no.of qubits.
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Negativity of spins 1 and 2 (N12) Quantum discord of spins 1 and 2 (D12)
Non-frustrated Frustrated Non-frustrated Frustrated
Bipartite quantum correlations
The fidelity of the experimental initial state is 0.99 and that of all other
final density matrices is greater than 0.984
Negativity as well as Discord between any pair of qubits in non-frustrated regime decays to zero and in frustrated regime goes to a finite value; verified experimentally
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Multipartite quantum correlations
Non‐frustrated regime: Higher
correlations
Frustrated regime: Lower
correlations
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The ground state of the 3-spin transverse Ising spin system has been simulated
experimentally in both the frustrated and non-frustrated regimes using Nuclear
Magnetic Resonance.
Conclusion
To analyze the experimental ground state of this spin system, we used two
different multipartite quantum correlation measures which are defined through
the monogamy considerations of (i) negativity and of (ii) quantum discord.
These two measures have similar behavior in both the regimes although the
corresponding bipartite quantum correlations are defined through widely
different approaches.
The frustrated regime exhibits higher multipartite quantum correlations
compared to the non-frustrated regime and the experimental data agrees with
the theoretically predicted ones.
Koteswara Rao et al. Poster No 22 (to be communicated)
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Thank You
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Two methods of Addressing
Qubit selective pulses And Coupling (J) Evolution
Transition-selective Pulses and no evolution
I1
I2
y x
1/4J 1/4J
00
01 10
11 XOR/C-NOT
I1
I2 NOT1
00
01 10
11
I1z+I2z
I1z+I2x
I1z+2I1zI2y
I1z+2I1zI2z
y
(1/2J)
x
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I1
I2 y x -y
y x -y
00
01 10
11
1
SWAP
I1
I2
y y -x -x
I3
Toffoli C2-NOT
000
001 010
011
100
101 110
111
I1
I2
y y -x x
I3
OR/NOR
000
001 010
011
100
101 110
111 non-selective pulse + a on 000 001
2 3
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We have used both these method for various QC/QIP protocols by NMR
Using qubit selective pulses.
• Experimental Proof of No-Hiding Theorem: Jharana et al. PRL 2011
• Quantum Games: Avik et al.
• Entanglement in 3-spin Heisenberg XY interaction Koteswara Rao et al IJQI 2012
Using Transition selective pulses
Geometric Phase and its use in NMR QIP,CnNOT Gates Swap Gates Entanglement transfer Quadrupolar systems, Strongly coupled Dipolar systems. • Non-Destructive discrinmination of orthogola
states Jharna J.Phys.B 2010; Manu AIP Conf. Proc. 2011
Today I will show you NMR/QIP operations using optimization methods, such as GRAPE and Genetic Algorithm
Characterization of 8=qubit dipolar coupled system: Das et al. AIP Proc. 2006
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Fidelity for finite J/δ