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TRANSCRIPT
QUALITY ASSURANCE REVIEW OFV ' INORGANIC ANALYSIS LAB-DATA PACKAGE (<r u-,./-"- A
Case No.: Z(Tj S/fa (06fi. Applicable Sample No.'s: Mg. ZLOl^_~ ——— ""'' |:
Contract No.: —""" Region: ^ . _In IL lift- ' ' ; i,'Contract Laboratory: c *"! . Reviewer: .£Applicable IFB No.: _______ Review Date:
The Inorganic analytical data for this case has been reviewed. The qualityassurance evaluation 1s summarized 1n the following table:
FRACTION '
VIEWER'S EVALUATION*
Acceptable
Acceptable with .r^pfrionU)
!lu'est1 enable
Unacceptable
TASK I:ICP or AA ,Motsle /
/
•
TASK II:Furnace AA ,Motale /
/
. • • .
TASK III:Cold vapor W
7TASK III:Cvanlde
r4-TASK III:Anraonla .
-/
TASK III:
*tf-
*Def1n1t1ons of the evaluation score categories follow.
This evaluation was based upon an analysis of the review Items Indicated below:
Q DATA COMPLETENESS [] INITIAL CALIBRATION VERIFICATION.;,* , Q BLANK ANALYSIS RESULTS Q CONTINUING"CAL~IBRATION VERIFICATION
.[] MATRIX SPIKE RESULTS Q INTERFERENCE QC RESULTS.•'.', D DUPLICATE ANALYSIS RESULTS Q DETECTION LIMITS RESULTS
Q STANDARD ADDITIONS RESULTS Q INSTRUMENT SENSITIVITY REPORTSData review forms are attached for each of the review Items Indicated above.
COWENTS:
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\- '•''~J I1ATA EVALUATION SCORE CATEGORIESACCEPTABLE! DATA ARE WITHIN ESTABLISHED CONTROL LIMITS, ORTHE DATA WHICH ARE OUTSIDE ESTABLISHED CONTROLLIMITS DO NOT AFFECT THE VALIDITY OF THEANALYTICAL RESULTS,
DATA ARE NOT COMPLETELY WITHIN ESTABLISHED. ACCEPTABLE LIMITS, THE DEFICIENCIES ARE IDENTIFIED ANDWITH EXCEPTIONS! SPECIFIC DATA ARE STILL VALID, GIVEN CERTAINQUALIFICATIONS WHICH ARE LISTED BELOW,
QUESTIONABLE! DATA ARE' NOT WITHIN ESTABLISHED CONTROL LIMITS,THE DEFICIENCIES BRING. THE VALIDITY OF THE ENTIREDATA SET INTO QUESTION, HOWEVER, THE DATA VALIDITYi IS NEITHER PROVED NOR DISPROVED BY THE AVAILABLEINFORMATION,
UNACCEPTABLE: DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS,THE DEFICIENCIES IMPLY THE RESULTS ARE NOTMEANINGFUL,
002160
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E REVIEW OF bV "KT . ORGANIC ANALYSIS LAB DATA PACKAGE ff —^ *-A- P.1 Jr .-
{ Case No.: "~~*-U±Contract No.: <sB~Ql -£>$(• vContract Laboratory: -filet*!. (*>pqClApplicable I FB No.: ' — — s
assurance
.Applicable Sample No.'s: g--$$~/i - $?'(, ' !Region: - /2- 1<5 ff 7- J/ff: ;fe
_ ' ,;;•fHf Reviewer; •Ar J«j96«/( I2.~ is"di iV.;>.,,
Review Date: '7/04. ^-j^er-The organic analytical data for this case have been reviewed, the quality
evaluation 1s summarized 1n the following table:
REVIEWER'S. EVALUATION*
Acceptable
-.-Acceptable with'_ixcept1ori(s)
questionable
Unacceptable
Volatlles
y/
FRACTION
Adds
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'Definitions of the evaluation score categories follow.
1-7
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This evaluation was based.-DATA COMPLETENESS
Base/ PCB's/^Neutrals/ Pesticides TCDD
'/
upon an analysis of the review Items Indicated below:f
^BLANK ANALYSIS RESULTS QjSURROGATE SPIKE RESULTS [*
^MATRIX SPIKE/METHOD STANDARD^-RESULTS
~
DUPLICATE ANALYSIS RESULTS VEVALUATION OF CONFIRMATIONS V
Data review forms are attached for each of the review
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["STANDARDS/•^CALIBRATION CHECK STANDARDSINTERNAL STANDARDS PERFORMANCE ,.
002181Items Indicated above.
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o DATA EVALUATION SCORE CATEGORIES
'' ACCEPTABLE! DATA ARE WITHIN ESTABLISHED CONTROL LIMITS, ORTHE DATA WHICH ARE OUTSIDE ESTABLISHED CONTROLLIMITS DO NOT AFFECT THE VALIDITY OF THEANALYTICAL RESULTS,
DATA ARE NOT COMPLETELY WITHIN ESTABLISHEDACCEPTABLE LIMITS, THE DEFICIENCIES ARE IDENTIFIED ANDWITH EXCEPTIONS! SPECIFIC DATA ARE STILL VALID, GIVEN CERTAIN miQUALIFICATIONS WHICH ARE LISTED BELOW, 1?|
QUESTIONABLE! DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS,THE DEFICIENCIES BRING. THE VALIDITY OF THE ENTIREDATA SET INTO QUESTION, HOWEVER, THE DATA VALIDITYIS NEITHER PROVED NOR DISPROVED BY THE AVAILABLEINFORMATION,
UNACCEPTABLE! DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS,THE DEFICIENCIES IMPLY THE RESULTS ARE NOTMEANINGFUL, , i?I
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PROJECT NAME!
PROJECT NO,!n
QUALITY ASSURANCE REVIEW OFORGANIC ANALYSIS LAB DATA PACKAGE /(/' U"1'H"
CaseNo.: *- 3ji _______ Applicable Sample No. 's:Contract No.: £& ~ a ("6 7 $4- • Region:Contract Laboratory: /??£_? j dn^ Ck , Reviewer: -J n A/f /IApplicable IFB No.: —— ' — Review Date:
The organic analytical data for .this case have been reviewed* The qualityi
REVIEWER'S. EVALUATION*i
Acceptable| ———————————————————
.-.Acceptable with\_Jxcept1on(s)
Questionable
Unacceptable
*Defln1t1on•
[2G\2
Data revlevi
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s of the evaluation score categories foThis evaluation was based upon an ana
""DATA COMPLETENESS"BLANK ANALYSIS RESULTS"SURROGATE SPIKE RESULTS"MATRIX SPIKE/METHOD STANDARDRESULTS
]. DUPLICATE ANALYSIS RESULTSEVALUATION OF CONFIRMATIONS
forms are attached for each of the rev617 ty-o/Z 9M/
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FRACTIONBase/Neutrals
'
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PCB's/Pesticides TCDD
-x'
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w.is of the revtew items Indicated below: .
^TENTATIVELY IDENTIFIED COMPOUNDSCHROMATOGRAPHIC SENSITIVITY CHECKS'DFTPP AND BFB SPECTRUM TUNE RESULTS'STANDARDS"CALIBRATION CHECK STANDARDS"INTERNAL STANDARDS PERFORMANCEk •items Indicated above.* dW fy S
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PATH pVALUATinN SCORE CATEGORIES
ACCEPTABLE; DATA ARE WITHIN ESTABLISHED CONTROL LIMITS, ORTHE DATA WHICH ARE OUTSIDE ESTABLISHED CONTROLLIMITS DO NOT AFFECT THE VALIDITY OF THEANALYTICAL RESULTS,DATA ARE NOT COMPLETELY WITHIN ESTABLISHED ;;i|;. ACCEPTABLE LIMITS, THE DEFICIENCIES ARE IDENTIFIED AND laa
H|TH EXCEPTIONS! SPECIFIC DATA ARE STILL VALID; GIVEN CERTAIN $WQUALIFICATIONS WHICH ARE LISTED BELOW,
QUESTIONABLE! DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS,THE DEFICIENCIES BRING. THE VALIDITY OF THE ENTIREDATA SET INTO QUESTION, HOWEVER, THE DATA VALIDITYIS NEITHER'PROVED NOR DISPROVED BY THE AVAILABLEINFORMATION,
UNACCEPTABLE! DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS,THE DEFICIENCIES IMPLY THE RESULTS ARE NOTMEANINGFUL,
• . , . .
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QUALITY ASSURANCE REVIEW FORM
'O PROJECT NAME: _••'.-.•'PROJECT MO,!
QUALITY ASSURANCE REVIEW OFORGANIC ANALYSIS LAB DATA PACKAGE
Case No.: £3 ?3_____ Applicable Sample No.'s:Contract No.: (+%•<> I ~L19V Region:Contract Laboratory: /yifffrt/-&>/«?/» .."to* Reviewer: /fcCa_ _ ftApplicable IFB No.: _______
The organic analytical data for this case have been reviewed. The qualityassurance evaluation 1s summarized 1n the following table:
"Definitions of the-evaluation score categories follow.This evaluation was based upon an analysis of the review Items Indicated below:
DATA COMPLETENESS Q"TENTATIVELY IDENTIFIED COMPOUNDS
FIGURE 1rr
.REVIEWER'S. EVALUATION*-•~\ ,
• •-'•'•Acceptable
Acceptable withExceptlon(s)
Questionable
Unacceptable
FRACTION
Volatlles
/
'
Adds
/Cft. /v,
•
Base/Neutrals
MfrlivK.
PCB'S/Pesticides
VTCDD
j/
BLANK ANALYSIS RESULTS'SURROGATE SPIKE RESULTS [P'DFTPP AND BFB SPECTRUM TUNE RESULTS
\s\•MATRIX SPIKE/METHOD STANDARDRESULTS'DUPLICATE ANALYSIS RESULTS
CHROMATOGRAPHIC SENSITIVITY CHECKS
STANDARDS
CALIBRATION CHECK STANDARDSEVALUATION OF CONFIRMATIONS IM INTERNAL STANDARDS PERFQRWUICE
TH - so -013ti)-Sb.o«<rO"'1
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DRAFTTABLE 2
DATA EVALUATION SCORE CATEGORIES
DATA ARE WITHIN ESTABLISHED CONTROL LIMITS, ORTHE DATA WHICH ARE OUTSIDE ESTABLISHED CONTROLLIMITS DO NOT AFFECT THE VALIDITY OF THEANALYTICAL RESULTS,
DATA ARE NOT COMPLETELY WITHIN ESTABLISHEDACCEPTABLE LIMITS, THE DEFICIENCIES ARE IDENTIFIED ANDWITH EXCEPTIONS! SPECIFIC DATA ARE STILL VALID, GIVEN CERTAINQUALIFICATIONS WHICH ARE LISTED BELOW,
QUESTIONABLE! DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS,- THE DEFICIENCIES BRING. THE VALIDITY OF THE ENTIRE
,' . DATA SET INTO QUESTION, HOWEVER, THE DATA VALIDITYvj • . IS NEITHER PROVED NOR DISPROVED BY THE AVAILABLE'
• ." • -'INFORMATION, • ,'
UNACCEPTABLE! •••• DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS,'THE DEFICIENCIES IMPLY THE RESULTS ARE NOTMEANINGFUL,
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O QUALITY ASSURANCE REVIEW OF
PROJECT .NAME!
PROJECT NO,!
j • ORGANIC ANALYSICase No.: 2.iiiContract No.: ,6 (-61 4-Contract Laboratory: KkddL CyMfaC^Applicable IFB No.: ——
i The organic analytical data forassurance evaluation 1s summarized In the fo
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REVIEWER'S. EVALUATION* Volat1
Acceptable
Acceptable with . ./—, Exception) s) ^'•*~S
' • Questionable >
! "" """"Unacceptable
i> "Definitions of the evaluation score categorii
This evaluation was based upon a
~2 EATA COMPLETENESS' JLANK ANALYSIS RESULTS^'SURROGATE SPIKE RESULTS|— ixM/VTRIX SPIKE/METHOD STANDARLinJESULTSQjWPLICATE ANALYSIS RESULTS[^EVALUATION OF CONFIRMATIONS
Data review forms are attached for each of th
BRENTS: < a ' itjj} s/uefcw
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S LAB DATA PACKAGEApplicable Sample No. 's: <J S'i'1 S»'»yo6»t.Region: > ft is1/ 7- Z2.Reviewer: • ^ -f'adlReview Date: f/?6/0f
this case have been reviewed. The qualityllowlng table:
FRACTION. . . .Hc Base/ PCB's/les fields Neutrals Pesticides TCDQ
/ / s
~T~/' '_,//:
es follow.n analysis of the review Items Indicated below:
• [ TENTATIVELY IDENTIFIED COMPOUNDS^ CHROMATOGRAPHIC SENSITIVITY CHECKS"'TJFTPP AND BFB SPECTRUM TUNE RESULTS
D ~ STANDARDSQ'CALIBRATION CHECK STANDARDS[TflNTERNAL STANDARDS PEWfBlRMfiNJCE1 — ' ^ift'-v
e review items Indicated above.
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V DATA EVALUATION SCORE CATEGORIES
ACCEPTABLE! DATA ARE WITHIN ESTABLISHED CONTROL LIMITS, ORTHE DATA WHICH ARE OUTSIDE ESTABLISHED CONTROLLIMITS DO NOT AFFECT THE VALIDITY OF THEANALYTICAL RESULTS,
'•i'f»;
DATA ARE NOT COMPLETELY WITHIN ESTABLISHED It,..ACCEPTABLE LIMITS, THE DEFICIENCIES ARE IDENTIFIED AND »«\-iWITH EXCEPTIONS! SPECIFIC DATA ARE STILL VALID, GIVEN CERTAIN
QUALIFICATIONS WHICH ARE LISTED BELOW,
QUESTIONABLE! DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS,THE DEFICIENCIES BRING THE VALIDITY OF THE ENTIREDATA SET INTO QUESTION, HOWEVER, THE DATA VALIDITYIS NEITHER PROVED NOR DISPROVED BY THE AVAILABLEINFORMATION,
UNACCEPTABLE! DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS,THE DEFICIENCIES IMPLY THE RESULTS ARE NOTMEANINGFUL,
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QUALITY ASSURANCE REVIEH OFORGANIC ANALYSIS LAB DATA PACKAGE 7
Case No.: _ * .O_____ Applicable Sample No.'s:Contract No.: fcg'-<3/-67f5'4 Region: j____Contract Laboratory: flltfal (',Cb Reviewer: - .Wrf /( __ __ __Applicable IFB No.: — • • • - Review Date: "t/j
The organic analytical data for this case have been reviewed. The qualityassurance evaluation Is summarized In the following table:
REVIEHER'S. EVALUATION*
Acceptable \J
Acceptable with'-• Exceptlori(s) • ' V?
Questionable ' ?
Unacceptable ryy
FRACTION
Volatlles
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^Definitions of the evaluation score categories foThis evaluation was based upon an ana
2. DATA COMPLETENESS|] 'BLANK ANALYSIS RESULTS* 'SURROGATE SPIKE RESULTSnfMATRIX SPIKE/METHOD STANDARDLJ. RESULTSn/DUPLICATE ANALYSIS RESULTSQ EVALUATION OF CONFIRMATIONS
Data review forms are attached for each of the rev
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How.lysis of the review Items Indicated below:
I ^TENTATIVELY IDENTIFIED COMPOUNDS"^CHROMATOGRAPHIC SENSITIVITY CHECKS~2_ iHPP AND BFB, SPECTRUM TUNE RESULTS"'STANDARDS
^CALIBRATION CHECK STANDARDS^INTERNAL STANDARDS PERFORMANCE
lew Items Indicated above. . fj,Q'2l'*
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%y;V 0 DATA EVALUATION SCORE CATEGORIES
____ DATA ARE WITHIN ESTABLISHED CONTROL LIMITS, ORTHE DATA WHICH ARE OUTSIDE ESTABLISHED CONTROLLIMITS DO NOT AFFECT THE VALIDITY OF THEANALYTICAL RESULTS,Ml
DATA ARE NOT COMPLETELY WITHIN ESTABLISHED if!,1. ACCEPTABLE LIMITS, THE DEFICIENCIES'ARE IDENTIFIED AND yfe|WITH EXCEPTIONS! SPECIFIC DATA ARE STILL VALID, GIVEN CERTAIN
QUALIFICATIONS WHICH ARE LISTED BELOW,
QUESTIONABLE! DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS.THE DEFICIENCIES BRING. THE VALIDITY OF THE ENTIREDATA SET INTO QUESTION, HOWEVER, THE DATA VALIDITYIS NEITHER PROVED NOR DISPROVED BY THE AVAILABLEINFORMATION,
UNACCEPTABLE! DATA ARE NOT WITHIN ESTABLISHED CONTROL LIMITS,THE DEFICIENCIES IMPLY THE RESULTS ARE NOT' •'MEANINGFUL,
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\ Contract No. :' *" f*AContract Laboratory: Cwi
Applicable IFB No.:The Inorganic e
assurance evaluation Ujj
REVIEWER'S EVALUATION1
| Acceptable
Acceptable with .!pipt1on(s)
1 Questionable
Unacceptable\
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NAME: /OJECT NO,!
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ALITY ASSURANCE REVIEH OFNIC ANALYSIS LAB DATA PACKAGE. / s
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1ewer: PButo)£lew Date: V/W7V
nalytlcal data for this case has been reviewed. The qualityummarlzed 1n the following table:
FRACTIONTASK I:ICP or AA
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TASK II:•urnace AAMetals
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TASK III:Cold vapor A/
.
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TASK III: TASK III:Annipnl3 suifide
^Definitions of the evaluation score categories follow.i1
This, evaluation. .was based upon an analysis of the review Items Indicated below:1 , :"'.'•••
! 0DATA COMPLETENESS J2f INITIAL CALIBRATION VERIFICATION ,
1 (•f BLANK ANALYSIS RESULTS jjj CONTINUING "CALIBRATION VERIFICATION
[/{'MATRIX SPIKE RESULTS [v/f INTERFERENCE QC RESULTS|]/| DUPLICATE ANALYSIS RESULTS [^DETECTION LIMITS RESULTftQR^'l
i Q STANDARD ADDITIONS RESULTS Q INSTRUMENT SENSITIVITY REPORTS: Data review forms are attached for eaclr of the review Items Indicated above!* * &*****
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\- • n DATA EVALUATION SCORE CATEGORIES
ftcCEPTABLE! DATA IS WITHIN ESTABLISHED CONTROL LIMITS^ OR THEDATA WHICH IS OUTSIDE ESTABLISHED CONTROL LIMITSDOES NOT AFFECT THE VALIDITY OF THE ANALYTICALRESULTS.
• •.- ' DATA is NQT COMPLETELY WITHIN ESTABLISHED. CONTROLACCEPTABLE:.. LIMITS, THE DEFICIENCIES ARE IDENTIFIED AND SPECIFICWITH, EXCEPTIONS! DATA IS STILL VALID, GIVEN CERTAIN QUALIFICATIONSWHICH ARE LISTED BELOW,QUESTIONABLE; DATA is NOT WITHIN ESTABLISHED CONTROL LIMITS, THE
DEFICIENCIES BRING THE VALIDITY OF THE ENTIRE DATASET INTO QUESTION, HOWEVER; THE DATA VALIDITY ISNEITHER PROVED NOR DISPROVED BY THE AVAILABLE'INFORMATION,
llNflrr.EPTABLE.!
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DATA is NOT WITHIN ESTABLISHED CONTROL LIMITS, THEDEFICIENCIES IMPLY THE RESULTS ARE NOT MEANINGFUL,
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