proposed pesticides intermediates & specialty...
TRANSCRIPT
25
FORM-1
for
PROPOSED PESTICIDES INTERMEDIATES &
SPECIALTY CHEMICALS IN EXISTING
INORGANIC CHEMICALS UNIT
of
M/S. PRAGNA PHARMA PVT. LTD.
PLOT NO. D2/CH/224, GIDC INDUSTRIAL ESTATE,
DAHEJ-2, TAL: VAGRA, DIST: BHARUCH-392130
(GUJ.)
NABL Accredited Testing Laboratory
ISO 9001:2008 Certified Company
Aqua-Air Environmental Engineers P. Ltd.
403, Centre Point, Nr. Kadiwala School, Ring
Road, Surat - 395002
Prepared By:
NABL Accredited Testing Laboratory
ISO 9001:2008 Certified Company
Aqua-Air Environmental Engineers P. Ltd.
403, Centre Point, Nr. Kadiwala School, Ring
Road, Surat - 395002
NABL Accredited Testing Laboratory
ISO 9001:2008 Certified Company
Aqua-Air Environmental Engineers P. Ltd.
403, Centre Point, Nr. Kadiwala School, Ring
Road, Surat - 395002
Prepared By:
26
APPENDIX I
(See paragraph - 6)
FORM 1
(I) Basic Information
Sr.
No.
Item Details
1. Name of the project/s M/s. PRAGNA PHARMA PVT. LTD.
2. S. No. in the schedule 5(f) & 5(b)
3. Proposed capacity/area/length/tonnage to
be handled/command area/lease
area/number of wells to be drilled
For detail Please refer Annexure – I
4. New/Expansion/Modernization Expansion
5. Existing Capacity/Area etc. For detail Please refer Annexure-I
6. Category of Project i.e. ‘A’ or ‘B’ A
7. Does it attract the general condition? If
yes, please specify.
No
8. Does it attract the specific condition? If yes,
please specify.
No
9. Location Plot No. D2/CH/224, GIDC Industrial
Estate, Dahej-2, Taluka: Vagra, Dist:
Bharuch, Gujarat
Plot/Survey/Khasra No. Plot No. D2/CH/224
Village GIDC Industrial Estate, Dahej-2
Tehsil Vagra
District Bharuch
State Gujarat
10. Nearest railway station/airport along with
distance in kms.
Nearest Railway Station: Bharuch (45 Km)
Nearest Airport: Vadodara (100 km)
11. Nearest Town, city, District Headquarters
along with distance in kms.
Nearest City: Bharuch (45 Km)
12. Village Panchayats, Zilla Parishad,
Municipal Corporation, local body
(complete postal address with telephone
nos. to be given)
--
13. Name of the applicant M/s. PRAGNA PHARMA PVT. LTD.
14. Registered Address M/s. PRAGNA PHARMA PVT. LTD.
Plot No. D2/CH/224, GIDC Industrial Estate,
Dahej-2, Taluka: Vagra, Dist: Bharuch,
Gujarat
15. Address for correspondence:
Name Mr. Jigneshkumar Kalidas Patel
Designation (Owner/Partner/CEO) Director
Address M/s. PRAGNA PHARMA PVT. LTD.
Plot No. 1210, GIDC, Ankleshwar-393002,
Dist: Bharuch, Gujarat
Pin Code 393002
E-mail [email protected]
27
Telephone No. Mobile: +919723812606
Tel. No: (02646)238106
Fax No. --
16. Details of Alternative Sites examined, if
any.
Location of these sites should be shown on
a topo sheet.
NA
17. Interlinked Projects No
18. Whether separate application of
interlinked project has been submitted?
No
19. If yes, date of submission No
20. If no, reason No
21. Whether the proposal involves
approval/clearance under: if yes, details of
the same and their status to be given.
(a) The Forest (Conservation) Act, 1980?
(b) The Wildlife (Protection) Act, 1972?
(c) The C.R.Z. Notification, 1991?
No
22. Whether there is any Government
Order/Policy relevant/relating to the site?
No
23. Forest land involved (hectares) No
24. Whether there is any litigation pending
against the project and/or land in which
the project is propose to be set up?
(a) Name of the Court
(b) Case No.
(c) Orders/directions of the Court, if any
and its relevance with the proposed
project.
No
Capacity corresponding to sectoral activity (such as production capacity for manufacturing, mining
lease area and production capacity for mineral production, area for mineral exploration, length for
linear transport infrastructure, generation capacity for power generation etc.,)
(II) Activity
1. Construction, operation or decommissioning of the Project involving actions, which will cause
physical changes in the locality (topography, land use, changes in water bodies, etc.)
Sr.
No.
Information/Checklist confirmation Yes/
No
Details thereof with approximate
quantities frates, wherever possible)
with source of information data
1.1 Permanent or temporary change in land
use, land cover or topography including
increase intensity of land use (with
respect to local land use plan)
No Proposed Project will be carried out
within the existing premises.
1.2 Clearance of existing land, vegetation
and Buildings?
Yes Minor site clearance activities shall be
carried out.
1.3 Creation of new land uses?
No
28
1.4 Pre-construction investigations e.g.
bore
Houses, soil testing?
No
1.5 Construction works?
Yes For detail Please refer Annexure – II
1.6 Demolition works? No --
1.7 Temporary sites used for construction
works or housing of construction
workers?
No
1.8 Above ground buildings, structures or
earthworks including linear structures,
cut and fill or excavations
Yes For detail Please refer Annexure – II
1.9 Underground works mining or
tunneling?
No
1.10 Reclamation works?
No
1.11 Dredging?
No
1.12 Off shore structures?
No
1.13 Production and manufacturing
processes?
Yes List of products attached in Annexure-I
and Manufacturing process is attached in
Annexure –III.
1.14 Facilities for storage of goods or
materials?
Yes Areas for storage of raw materials and
finished products will be developed.
1.15 Facilities for treatment or disposal of
solid waste or liquid effluents?
Yes Details of the Liquid Effluent is given as
Annexure – V and Details of solid waste is
given as Annexure –VI.
1.16 Facilities for long term housing of
operational workers?
No
1.17 New road, rail or sea traffic during
Construction or Operation?
No
1.18 New road, rail, air waterborne or other
transport infrastructure including new
or altered routes and stations, ports,
airports etc?
No
1.19 Closure or diversion of existing
transport routes or infrastructure
leading to changes in traffic
movements?
No
1.20 New or diverted transmission lines or No
29
Pipelines?
1.21 Impoundment, damming, culverting,
realignment or other changes to the
hydrology of watercourses or aquifers?
No
1.22 Stream crossings?
No
1.23 Abstraction or transfers of water form
ground or surface waters?
Yes Water Source: GIDC Water supply
1.24 Changes in water bodies or the land
surface
Affecting drainage or run-off?
No
1.25 Transport of personnel or materials for
construction, operation or
decommissioning?
Yes By road only.
1.26 Long-term dismantling or
decommissioning or restoration works?
No
1.27 Ongoing activity during
decommissioning which could have an
impact on the environment?
No
1.28 Influx of people to an area either
temporarily or permanently?
No
1.29 Introduction of alien species?
No
1.30 Loss of native species or genetic
diversity?
No
1.31 Any other actions? No
2. Use of Natural resources for construction or operation of the Project (such as land, water,
materials or energy, especially any resources which are non-renewable or in short supply):
Sr.
No.
Information/checklist confirmation Yes/No Details there of (with approximate
quantities frates, wherever possible) with
source of information data
2.1 Land especially undeveloped or
agricultural land (ha)
No
2.2 Water (expected source & competing
users) unit: KLD
Yes Water Source: GIDC Water Supply
Please refer Annexure – IV.
2.3 Minerals (MT) No
30
2.4 Construction material - stone, aggregates,
and / soil (expected source -MT)
Yes Construction materials, like steel, cement,
crushed stones, sand, rubble, etc. required
for the project shall be procured from the
local market of the region.
2.5 Forests and timber (source - MT) No.
2.6 Energy including electricity and fuels
(source, competing users) Unit: fuel (MT),
energy (MW)
Yes Power required : 1000 KVA
D.G. Set : 500 KVA (during emergency
only)
Source: DGVCL
Fuel Requirement:
Existing :
Natural Gas: 1500 m3/Month
OR
LDO: 120 Ltrs/Hours
Proposed:
Natural Gas: 72000 SCM/Month
LDO/Furnace Oil : 100 Ltrs/Hours
Solid Fuel : 150 MT/Month
Diesel: 60 Lit/Hours
2.7 Any other natural resources (use
appropriate standard units)
No
3. Use, storage, transport, handling or production of substances or materials, which could be
harmful to human health or the environment or raise concerns about actual or perceived
risks to human health.
Sr.
No.
Information/Checklist confirmation Yes/No Details there of (with approximate
quantities/rates, wherever possible)
with source of information data
3.1 Use of substances or materials, which are
hazardous (as per MSIHC rules) to human
health or the environment (flora, fauna, and
water supplies)
Yes For detail please refer Annexure – VIII.
3.2 Changes in occurrence of disease or affect
disease vectors (e.g. insect or water borne
diseases)
No
3.3 Affect the welfare of people e.g. by
changing living conditions?
No
3.4 Vulnerable groups of people who could be
affected by the project e.g. hospital
patients, children, the elderly etc.
No
3.5 Any other causes No
31
4. Production of solid wastes during construction or operation or decommissioning (MT/month)
Sr.
No.
Information/Checklist confirmation Yes/No Details there of (with approximate
quantities/rates, wherever possible)
with source of information data
4.1 Spoil, overburden or mine wastes No
4.2 Municipal waste (Domestic and or
commercial wastes)
No
4.3 Hazardous wastes (as per Hazardous Waste
Management Rules)
Yes Please refer Annexure –VI.
4.4 Other industrial process wastes Yes Please refer Annexure- VI.
4.5 Surplus product No
4.6 Sewage sludge or other sludge from
effluent treatment
Yes
Please refer Annexure- VI.
4.7 Construction or demolition wastes No
4.8 Redundant machinery or equipment No
4.9 Contaminated soils or other materials No
4.10 Agricultural wastes No
4.11 Other solid wastes No
5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr)
Sr.
No.
Information/Checklist confirmation Yes/No Details there of (with approximate
quantities/rates, wherever possible)
with source of information data
5.1 Emissions from combustion of fossil fuels
from stationary or mobile sources
Yes Please refer as Annexure – VII.
5.2 Emissions from production processes Yes Please refer as Annexure – VII.
5.3 Emissions from materials handling storage
or transport
No
5.4 Emissions from construction activities
including plant and equipment
No
5.5 Dust or odors from handling of materials
including construction materials, sewage
and waste
No
5.6 Emissions from incineration of waste Yes
5.7 Emissions from burning of waste in open
air (e.g. slash materials, construction
debris)
No
5.8 Emissions from any other sources No
32
6. Generation of Noise and Vibration, and Emissions of Light and Heat:
Sr.
No.
Information/Checklist confirmation Yes/No Details there of (with approximate
quantities/rates, wherever possible)
with source of information data
with source of information data
6.1 From operation of equipment e.g. engines,
ventilation plant, crushers
Yes The Noise level will be within the
prescribed limit. At noisy area,
adequate preventive & control
measures will be taken. No significant
noise, vibration or emission of light &
heat from the unit.
6.2 From industrial or similar processes Yes -do-
6.3 From construction or demolition No
6.4 From blasting or piling No
6.5 From construction or operational traffic No
6.6 From lighting or cooling systems No
6.7 From any other sources No
7. Risks of contamination of land or water from releases of pollutants into the ground or into
sewers, surface waters, groundwater, coastal waters or the sea:
Sr.
No.
Information/Checklist confirmation Yes/No Details there of (with approximate
quantities/rates, wherever possible)
with source of information data
7.1 From handling, storage, use or spillage of
hazardous materials
No All the raw material shall be stored
separately in designated storage area
with safely measures. For detail please
refer Annexure – VIII
7.2 From discharge of sewage or other
effluents to water or the land (expected
mode and place of discharge)
No Sewage shall be disposed of through
specific tank & soak pit.
7.3 By deposition of pollutants emitted to air
into the and or into water
No
7.4 From any other sources No
7.5 Is there a risk of long term build up of
pollutants in the environment from these
sources?
No
33
8. Risk of accidents during construction or operation of the Project, which could affect human
health or the environment
Sr. No. Information/Checklist confirmation Yes/No Details there of (with approximate
quantities/rates, wherever possible)
with source of information data
8.1 From explosions, spillages, fires etc. from
storage, handling, use or production of
hazardous substances
Yes For detail please refer Annexure – VIII.
8.2 From any other causes No
8.3 Could the project be affected by natural
disasters causing environmental damage
(e.g. floods, earthquakes, landslides,
cloudburst etc)?
No
9. Factors which should be considered (such as consequential development) which could lead to
environmental effects or the potential for cumulative impacts with other existing or planned
activities in the locality
Sr. No.
Information/Checklist confirmation
Yes/No
Details there of (with approximate
quantities/rates, wherever possible)
with source of information data
9.1 Lead to development of supporting. lities, ancillary development or development stimulated by the project which could have impact on the environment e.g.
• Supporting infrastructure (roads, power supply, waste or waste water
treatment, etc.) • housing development
• extractive industry
• supply industry
• other
Yes For detail please refer Annexure – IX.
9.2 Lead to after-use of the site, which could
have an impact on the environment
No
9.3 Set a precedent for later developments No
9.4 Have cumulative effects due to
proximity to other existing or planned
projects with similar effects
No
34
(II) Environmental Sensitivity
Sr.
No.
Areas Name/
Identity
Aerial distance (within 5 km)
Proposed project location
boundary
1 Areas protected under international
conventions, national or local legislation for
their ecological, landscape, cultural or other
related value
- The site is located in Notified
Industrial Area of GIDC Estate, Dahej-
2, Dist: Bharuch, Gujarat.
2 Areas which important for are or sensitive
Ecol logical reasons - Wetlands, watercourses
or other water bodies, coastal zone,
biospheres, mountains, forests
-
3 Area used by protected, important or
sensitive Species of flora or fauna for
breeding, nesting, foraging, resting, over
wintering, migration
-
4 Inland, coastal, marine or underground
waters
- N.A.
5 State, National boundaries
- N.A.
6 Routes or facilities used by the public for
access to recreation or other tourist, pilgrim
areas
- Public Transportation
7 Defense installations - N.A.
8 Densely populated or built-up area Bharuch Bharuch is around 45 km from the
proposed project site.
9 Area occupied by sensitive man-made land
uses Hospitals, schools, places of worship,
community facilities)
- N.A.
10 Areas containing important, high quality or
scarce resources (ground water resources,
surface resources, forestry, agriculture,
fisheries, tourism, minerals)
- N.A.
11 Areas already subjected to pollution
environmental damage. (those where
existing legal environmental standards are
exceeded)or
- N.A.
12 Are as susceptible to natural hazard which
could cause the project to present
environmental problems (earthquake s,
subsidence ,landslides, flooding erosion, or
extreme or adverse climatic conditions)
- N.A.
IV). Proposed Terms of Reference for EIA studies: For detail please refer Annexure – X
35
I hereby given undertaking that the data and information given in the application and
enclosures are true to the best of my knowledge and belief and I am aware that if any part of
the data and information submitted is found to be false or misleading at any stage, the
project will be rejected and clearance given, if any to the project will be revoked at our risk
and cost.
Date: May 26, 2017
Place: Ankleshwar
NOTE:
1. The projects involving clearance under Coastal Regulation Zone Notification, 1991 shall submit
with the application a C.R.Z. map duly demarcated by one of the authorized agencies, showing the
project activities, w. r. t. C.R.Z. (at the stage of TOR) and the recommendations of the State Coastal
Zone Management Authority (at the stage of EC). Simultaneous action shall also be taken to obtain
the requisite clearance under the provisions of the C.R.Z. Notification, 1991 for the activities to be
located in the CRZ.
2. The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere Reserves,
Migratory Corridors of Wild Animals, the project proponent shall submit the map duly authenticated
by Chief Wildlife Warden showing these features vis-à-vis the project location and the
recommendations or comments of the Chief Wildlife Warden thereon (at the stage of EC).
3. All correspondence with the Ministry of Environment & Forests including submission of application
for TOR/Environmental Clearance, subsequent clarifications, as may be required from time to time,
participation in the EAC Meeting on behalf of the project proponent shall be made by the authorized
signatory only. The authorized signatory should also submit a document in support of his claim of
being an authorized signatory for the specific project.
36
LIST OF ANNEXURES
SR. NO. NAME OF ANNEXURE
I List of products with their production capacity
II Layout Map of the Plant
III Brief Manufacturing Process Description with Chemical and Mass Balance
IV Details of Water Consumption Wastewater Generation
V Effluent Treatment Scheme
VI Details of Hazardous /Solid Waste Generation, Handling and Disposal
VII Details of Air pollution Control System (Stack & Vent)
VIII Details of Hazardous Chemicals Storage & Handling
IX Socio-economic Impacts
X Proposed Terms of Reference for EIA studies
XI Plot Allotment Letter
XII Water Supply Letter
XIII CETP Membership Certificate
XIV RSPL Membership Certificate
XV TSDF Membership Certificate
XIV Toposheet
37
ANNEXURE – 1
LIST OF PRODUCTS WITH THEIR PRODUCTION CAPACITY
LIST OF PRODUCTS
Sr.
No.
NAME OF PRODUCTS CAS
No.
Existing
Quantity
Additional
Quantity
Total
Quantity
after
expansion
(MT/Month)
1 Zinc Sulphate liq. 7733-02-0 1500 -- 1500
2 Zinc Sulphate powder 7733-02-0 1000 -- 1000
3 Zinc Oxide 1314-13-2 400 -- 400
4 Manganese Sulphate liq. 7785-87-7 1500 -- 1500
5 Manganese Sulphate
powder
7785-87-7 500 --- 500
6 Copper sulphate
(CUSO4.5H2O)
7758-98-7 300 -- 300
7 Magnesium Sulphate
powder
7487-88-9 500 -- 500
8 Spray Drying of
chemicals on job work
basis
-- 1000 -- 1000
9 2,5 DiChloro Para
Phenylene Diamine
105-56-6 25.0 25.0
10 2 Nitro 4 Methoxy
Aniline
20103-09-
7
25.0 25.0
11 2,5 Dimethyl-P-
Phenylenediamine
96-96-8 25.0 25.0
12 2-Mercapto 5-Methoxy
Benzimedazole
07-01-
6393
33.3 33.3
13 3-[4-chloro-5-
(cyclopentyloxy)-2-
fluorophenyl]-5-(propan-
2-ylidene)-1,3-oxazolidin-
2,4-dione. (PIK)
37052-78-
1
29.2 29.2
14 Sodium/Potessium { 2-[
2,6 Dichloro Phenyl]
Amino} Phenyl} Acetate
110956-
75-7
41.7 41.7
15 2 Chlor PPD 15307-79-
6
25 25
16 2 –{ 2[ 2-{2, 6 dichloro
phenyl } Amino ] Phenyl
Acetyl ] Oxyacetic Acid
139272-
67-6
41.7 41.7
17 2-Chloro 1-Phenoxy
Benzene
2689-07-8 41.7 41.7
38
18 2,3 Xylil Anthranilic Acid 61-68-7 41.7 41.7
19 2 Chloro 5 Methyl PPD 09-03-
5307
25 25
20 5 Amino Ortho Toludine 95-53-4 25 25
21 4-Bromo Anisole 104-92-7 25 25
22 2 Chloro 4 Flouro 5 Nitro
Benzyl Chloride
120890-
66-6
33.3 33.3
23 3 Amino 4 Methoxy
Acetanilide
6375-47-9 41.7 41.7
24 Para Anisidine 104-94-9 41.7 41.7
25 Para Amino Salicylic Acid 65-49-6 41.7 41.7
26 Nitro to amino
conversion by catalytic
hydrogenation
-- -- 83.3 83.3
Benzyl Alcohol 100-51-6
P-Hydroxy Benzyl Alcohol 623-05-2
P-Chloro Benzyl Alcohol 873-76-7
P-nitro Benzyl Alcohol 619-73-8
2,4 Di Nitro Benzyl
Alcohol etc.
483-66-2
27 Aldehyde to alcohol
conversion by catalytic
hydrogenation
-- -- 83.3 83.3
P-Amino Methyl
Benzoate
619-45-4
5-Amino Salicylic Acid 89-57-6
4-Amino 2-Chloro Aniline 615-66-7
2,5 Di Amino Toluene 95-80-7
Aniline etc.. 62-53-3
28 2-Amino Ethane Thiol
Hydrochloride
156-57-0 83.3 83.3
29 Dimethyl
CyanoCarbodithiomidiate
10191-60-
3
83.3 83.3
30 4-Chloro 3-ethyl-1-
methyl-1H-pyrazole 5-
carboxylic acid (PIC-T1)
127892-
62-0
25 25
31 1-[4-(4-
methylphenoxy)phenyl]
methanamine
Hydrochloride (PIC-T2)
262862-
66-8
25 25
TOTAL 6700 945.9 7645.9
39
LIST OF RAW MATERIALS
SR. NO. Name of Raw Materials CAPACITY
(MT/Month)
Existing
1. Zinc Sulphate liq.
1. Zinc Ingots/Zinc brass/ash 600
2. Sulphuric Acid 98% 630
2.Zinc Sulphate Powder
1. Zinc Ingots/Zinc brass/ash 600
2. Sulphuric Acid 98% 630
3.Zinc Oxide
1. Zinc Ingots 322
2. Oxygen 80
4.Manganese Sulphate Liq.
1. Manganese oxide powder 300
2. Sulphuric Acid 98% 360
5.Manganese Sulphate Powder
1. Manganese oxide powder 2585
2. Sulphuric Acid 98% 315
6.Magnesium Sulphate powder
1. Magnesium oxide powder 300
2. Sulphuric Acid 98% 325
7.Copper Sulphate (CuSO4.5H2O)
1. Copper metal/Cu ash 180
2. Sulphuric Acid 98% 325
8. Spray Drying job work
1. Dilute Solutions of solutes to be dried --
Proposed
1. 2,5 DiChloro Para Phenylene Diamine
1. acetic anhydride 0.67
2. 2,5-dichloro aniline 1.00
40
3. sulphuric acid-48% 2.40
4. con. Nitric acid 0.39
5. hydrochloric acid 3.99
6. iron powder 0.90
7. sodium carbonate 0.06
2. 2 Nitro 4 Methoxy Aniline
1. para anicidine 0.83
2. acetic anhydride 0.73
3. nitric acid 0.43
4. MDC 2.50
5. soda 0.17
6. caustic 1.17
3. 2,5 Dimethyl-P-Phenylenediamine
1. 2,5 xylidine 1.25
2. sod carbonate 0.55
3. BSC 1.83
4. toluene 2.50
5. nitric acid 0.65
6. sulphuric acid 1.25
7. acetic acid 0.13
8. iron powder 0.68
4.2-Mercapto 5-Methoxy Benzimedazole
1. 4-methoxy nitro aniline 0.95
2. NaHS 2.10
3. CS2 0.43
4. NaOH 0.23
5. DMF 2.40
6. carbon 0.03
5. 3-[4-chloro-5-(cyclopentyloxy)-2-fluorophenyl]-5-(propan-2-ylidene)-1,3-oxazolidin-2,4-
dione. (PIK)
1. PICK3 0.96
41
2. TOLUENE 0.26
3. ECF 0.67
4. 40%NAOH 2.05
5. CPB 1.15
6. CAT-2 0.20
7. ETHANOL 0.27
8. CAT-3 0.02
9. CAT-4 0.07
10. ECG 0.89
11. CHARCOAL 0.01
12. SILICA GEL 0.01
6. Sodium/Potessium { 2-[ 2,6 Dichloro Phenyl] Amino} Phenyl} Acetate
1. indolinone 1.00
2. caustic flacks 0.14
7. 2 Chlor PPD
1. 2chloro para nitro aniline 1.27
2. methanol 2.55
3. H2 0.05
8. 2 –{ 2[ 2-{2, 6 dichloro phenyl } Amino ] Phenyl Acetyl ] Oxyacetic Acid
1. tba 0.26
2. MCAA 0.33
3. (2-((2,6,DICHLORO
PHENYL)AMINO)PHENYL)ACETATE 1.11
4. FORMIC ACID 1.93
9. 2-Chloro 1-Phenoxy Benzene
1. phenol 0.65
2. ODCB 2.02
3. KOH 0.39
10. 2,3 Xylil Anthranilic Acid
1. ocba 0.83
2. 2,3 xylidine 0.71
42
3. caustic 0.19
4. So. Bicarbonate 0.53
5. HCL 0.88
11. 2 Chloro 5 Methyl PPD
1. soda 0.40
2. BSC 1.50
3. 5-chloro methyl aniline 1.20
4. toluene 1.80
5. nitric acid 0.54
6. sulphuric acid 1.00
7. hydrogen gas 0.05
12. 5 Amino Ortho Toludene
1. O T 1.25
2. sod bicarbonate 0.62
3. BSC 2.06
4. nitric acid 0.75
5. toluene 2.50
6. sulphuric acid 1.25
7. methanol 2.50
8. H2 gas 0.06
13. 4-Bromo Anisole
1. phenole 0.54
2. DMS 0.51
3. NaOH 0.95
4. EDC 1.73
5. Bromine 0.92
6. NaHCO3 0.12
14. 2 Chloro 4 Flouro 5 Nitro Benzyl Chloride
1. 2 chloro 4-floro -1-(trichloromethyl)benzene 1.05
2. oleum 23% 1.80
3. nitric acid 0.84
43
4. sodium carbonate 0.91
5. methanol 1.40
15.3 Amino 4 Methoxy Acetanilide
1. methanol 1.31
2. dinitrochloro benzene 1.25
3. caustic 0.31
4. methanol 0.20
5. acetic anhydride 0.64
6. hydrogen 0.08
16. Para Anisidine
1. pncb 1.33
2. methanol 1.28
3. methanol 0.28
4. caustic 0.35
5. H2 0.05
17. Para Amino Salicylic Acid
1. para nitro salicylic acid 1.25
2. methanol 1.50
3. H2 0.04
18. amino derivatives
1. nitro compound 1.36
2. solvent 2.73
3. catalyst 0.05
4. h2 gas 0.11
5. carbon 0.05
19. alcohol derivatives
1. aldehyde compound 1.00
2. solvent 2.00
3. catalyst 0.03
4. h2 gas 0.08
5. carbon 0.03
44
20 A. 2-Amino Ethane Thiol Hydrochloride- route-1
1. 2-Aminoethanol 0.75
2. DM Water 3.01
3. C.S.Lye 1.04
4. CS2 0.93
5. Con.Hcl 0.68
6. NaOH solution(30 %) 0.94
7. Methanol 3.29
20 B. 2-Amino Ethane Thiol Hydrochloride- route-2
1. 2-Aminoethanol 0.66
2. THIONYL CHLORIDE 1.32
3. TOLUENE 1.98
4. NaHS (30 %) 2.02
5. IPA HCL 2.44
6. NaOH solution ( 10 % ) 0.62
7. NaOH solution ( 25 % ) 2.13
21. Dimethyl CyanoCarbodithiomidiate
1. Cynamide 0.73
2. CS2 0.60
3. 22.5 % NAOH 2.79
4. DMS 2.03
5. CYCLOHEXANE/Ethanol 5.00
22.4-Chloro 3-ethyl-1-methyl-1H-pyrazole 5-carboxylic acid (PIC-T1)
1. Methyl Ethyl Ketone 0.64
2. Toluene 5.24
3. Sodium Ethoxide 0.73
4. Di Ethyl Oxalate 1.35
5. Hydrochloric Acid-30% 3.35
6. Sodium bi carbonate 0.06
7. G.Acetic Acid 0.27
8. 80% Hydrazine Hydrate 0.77
45
9. Di Methyl Sulphate 1.00
10. C.S Lye (48%) 1.97
11. Chlorine Gas 0.33
12. Methanol 4.00
23. 1-[4-(4-methylphenoxy)phenyl]methanamine Hydrochloride (PIC-T2)
1. DMF 3.30
2. NaH 0.20
3. p-Cresol 0.59
4. p-Chlorobenzonitrile 0.68
5. Toluene 4.00
6. IPA 10.34
7. Raney Ni 0.20
8. Ammonia gas 0.02
9. H2 0.09
10. 16% IPA HCl 1.12
46
ANNEXURE – 2
PLANT LAYOUT
47
ANNEXURE – 3
MANUFACTURING ACTIVITIES
DESCRIPTION OF MANUFACTURING PROCESS WITH FLOW DIAGRAM:
EXISTING :
1) ZINC SULPHATE LIQ.
BRIEF PROCESS: Required quantity of water is taken in reactor and Sulphuric acid is added at controlled rate
with temperature control. Next Zinc Ingots/Zinc Ash are added to the reactor with
temperature control by circulating cooling water in reactor jacket. After the reaction is
complete, the mass is filtered to separate insoluble material as sludge.
The Filtrate is zinc sulphate liquid which is sent for packaging.
Chemical Reaction:
Zn + H2SO4 ZnSO4
65 98 177
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT
Qty(in
kg)
1 Zinc ingots/brass/ash 600 Zinc Sulphate Solution 1500
2 Sulphuric Acid 625 Effluent 100
3 Water 550 Wet cake/sludge 175
Total 1775 Total 1775
2) ZINC SULPHATE (powder)
BRIEF PROCESS:
Stage-1:Preparation of Zinc Sulphate Solution Zinc Sulphate solution is obtained by reaction of zinc Ingots/Zinc Ash with sulphuric acid as
detailed in manufacturing process of Zinc Sulphate solution.
Stage-2: Filtration After completion of the reaction filter the reaction mass. The wet cake/sludge will be
recycling in next batch. Solution will be carry forward for evaporation.
Stage-3: Evaporation The zinc sulphate solution is then evaporated to concentrate it up to Zinc content.
Stage-4: Crystallization & Centrifuging The concentrated solution is then cooled to 150 C to obtain of Zinc Sulphate.
The slurry is then centrifuged to separate crystals and mother liquor. Mother liquor is
recycled in next batch and crystals are sent for drying and packaging.
Stage-5: Spray drying Centrifuged wet cake dried and packed.
Chemical Reaction:
Zn + H2SO4 ZnSO4
65 98 177
Mass Balance:
48
Sr
No. INPUT Qty(in kg) OUTPUT
Qty(in
kg)
1 Zinc ingots/brass/ash 600 Zinc Sulphate (powder) 1000
2 Sulphuric Acid 625 Effluent 100
3 Water 550 Wet cake/sludge 175
Total 1775 Total 1775
3) ZINC oxide
BRIEF PROCESS: Zinc oxide is obtained by oxidation of Zinc. Zinc ingots are heated to red hot in furnace and
oxygen gas is passed at controlled rate. Zinc ingots get oxidized and zinc oxide is obtained as
fine white powder. Unreacted material of the zinc ingots come out as zinc scrap.
Chemical Reaction:
2Zn + O2 2ZnO
MW 65 32 81
Zinc oxygen Zinc Oxide
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT
Qty(in
kg)
1 Zinc ingots/brass/ash 600 Zinc Sulphate Solution 1500
2 Sulphuric Acid 625 Effluent 100
3 Water 550 Wet cake/sludge 175
Total 1775 Total 1775
4) MANGANESE SULPHATE SOLUTION
BRIEF PROCESS: 70% Sulphuric acid is charged gradually in reaction vessel. Then Manganese Oxide powder
(MnO) is added to the mixture with stirring. The reaction takes place and MnO dissolves in
the solution forming Manganese Sulphate solution.
Chemical Reaction:
MnO + H2SO4 MnSO4 + H2O
71 98 151 18
Manganese oxide Sulphuric
Acid
Manganese
SulphateWater
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT
Qty(in
kg)
1 Manganese oxide powder 517
Manganese Sulphate
Solution 2600
2 Sulphuric Acid 625 Filter Cake 192
3 Water 1650
Total 2792 Total 2792
49
5) MANGANESE SULPHATE POWDER
BRIEF PROCESS:
Stage 1-Preparation of manganese sulphate solution
Manganese sulphate solution is obtained by reaction of manganese oxide with sulphuric acid
as detailed in manufacturing process of manganese sulphate solution.
Stage 2-Filtration After completion of the reaction filter the reaction mass. The wet cake/sludge will be recycle
in next batch. Solution will be carry forward for evaporation.
Stage 3-Evaporation The of manganese sulphate solution is then evaporated to concentrate it up to manganese
content.
Stage 4 – Crystallization & Centrifuging The concentrated solution is then cooled to 15° C to obtain heptahydrate crystals of
manganese sulphate.
The slurry is then centrifuged to separate crystals & mother liquor. Mother liquor is recycle
in next batch & crystal are sent for drying & packaging.
Stage 5 – Spray drying Centrifuged wet cake Dried & packed.
Chemical Reaction:
MnO + H2SO4 MnSO4 + H2O
71 98 151 18
Manganese oxide Sulphuric acid Manganese Sulphate
Water
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT
Qty(in
kg)
1 Manganese oxide powder 517
Manganese Sulphate
Powder 1000
2 Sulphuric Acid 625 Effluent 100
3 Water 550 Wet Cake/Sludge 192
Total 2792 Total 2792
6) COPPER SULPHATE
BRIEF PROCESS:
Stage 1 - Preparation of Copper Sulphate solution Copper Sulphate solution is obtained by reaction of copper ash, brass or copper metallic
content with sulphuric acid.
Stage 2- Filtration After completion of the reaction filter the reaction mass.The wet cake/sludge will be
recycling in next batch. Solution will be carry forward for evaporation and chilling.
Stage 3- Evaporation The of copper sulphate solution is than evaporated to concentrate it up to copper content.
Stage 4 – Crystallization & Centrifuging The concentrated solution is than cooled to 15 ˚C to obtain heptahydrate crystals of copper
sulphate.
The slurry is then centrifuged to separate crystals and mother liquor. Mother liquor is
recycled in next batch and the crystals are sent for drying and packaging.
50
Stage 5 – Spray drying Centrifuged wet cake dried and packed
Chemical Reaction:
CuO + H2SO4 CuSO4 + H2O
MW 79.5 98 159.5 18
Copper Oxide Sulphuric Acid Copper Sulphate
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT
Qty(in
kg)
1 Copper oxide brass/ash powder 600 Copper Sulphate Powder 1000
2 Sulphuric Acid 650 Effluent 100
3 Water 500 Wet Cake/Sludge 650
Total 1750 Total 1750
7) MAGNESIUM SULPHATE POWDER
BRIEF PROCESS:
Stage 1 – Preparation of Copper Sulphate solution Magnesium Sulphate solution is obtained by reaction of magnesium ash, brass or
magnesium metallic content with sulphuric acid.
Stage 2 –Filtration After completion of the reaction filter the reaction mass. The wet cake/sludge will be
recycling in next batch. Solution will be carry forward for evaporation and chilling.
Stage 3 – Evaporation The of magnesium sulphate solution is then evaporated to concentrate it up to magnesium
content.
Stage 4 – Crystallization & Centrifuging The concentrated solution is then cooled to 15 ˚C to obtain hepta hydrate crystals of
magnesium sulphate.
The slurry is then centrifuged to separate crystals and mother liquor. Mother liquor is
recycled in next batch and the crystals are sent for drying and packaging.
Stage 5 – Spray drying Centrifuged wet cake dried and packed
Chemical Reaction:
MgO + H2SO4 MgSO4 + H2O
MW 40.3 98 120.4 18
Magnesium Oxide Sulphuric Acid magnesium sulphate
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT
Qty(in
kg)
1
Magnesium oxide brass/ash
powder 600
Magnesium Sulphate
Powder 1000
2 Sulphuric Acid 650 Effluent 100
3 Water 500 Wet Cake/Sludge 650
Total 1750 Total 1750
51
8) SPRAY DRYING PROCESS
BRIEF PROCESS:
Dilute solutions of inorganic and organic chemicals shall be dried in Spray dryer and
packed in HDPE bags.
Flow Diagram:
Aprox.20% or 25% solution
Exhaust air to vent after passing
through wet scrubber with ventury
PRODUC
Hot air
TO Packaging
SPRAY
DRYING
52
PROPOSED:
1) 2,5 DICHLORO PARA PHENYLENE DIAMINE
BRIEF PROCESS: Cheak reactor is clean & dry. Charge acetic anhydride & 2,5 DCA , heat reaction mass to re
flux & maintain. Charge H2SO4 & NH3 for further reaction at RT. Add ice to isolate material.
Take reaction with caustic lye. Take reduction by iron powder add soda to maintain reaction
add HCL in reaction mass maintain for few hour till reaction is complete. Filtration, draying &
pack materials.
Chemical Reaction: STEP –I ACETYLATION
NH21
2
3
4
5
6
7
Cl8
Cl9
+
CH31 2
O3
O4
5
O6
CH37
acetic anhydride
1
NH2
3
4
5
6
7
8
Cl9
Cl10
CH311O
12
N-(2,5-dichlorophenyl)acetamide
+ CH31
2
O3
OH4
102
acetic acid
204 60
2,5-dichloroaniline
162
STEP- II NITRATION
NH
Cl
Cl
CH3O
+ OH N+
O-
O
+ OH S
O
O
OH
NH
Cl
Cl
CH3O
N+
O-
O
N-(2,5-dichloro-4-nitrophenyl)acetamide
sulfuric acidnitric acid
N-(2,5-dichlorophenyl)acetamide
+ OH S
O
O
OH + OH2
watersulfuric acid
204
63 98
249
98
18
STEP-III HYDROLYSIS
NH
Cl
Cl
CH3O
N+
O-
O
N-(2,5-dichloro-4-nitrophenyl)acetamide
249
+ Na OH
NH2
Cl
Cl
N+
O-
O
2,5-dichloro-4-nitroaniline
207
+Na
CH3
O
O
sodium acetate
82
40
53
STEP-IV
REDUCTIONNH2
Cl
Cl
N+
O-
O
+ 2 Fe2+ soda water
NH2
Cl
Cl
NH H
+fe derivatives H
2O+
2,5-DCPPD
177
2,5-dichloro-4-nitroaniline
207
+ 6 Hcl
112 219325 36
M.W 538=538
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT
Qty(in
kg)
1 Acetic Anhydride 335 Product 500
2 2:5 DCA 210 Acetic Acid 625
3 H2SO4 1200 H2SO4 (70%) 1554
4 Nitric Acid 194 Effluent 2817
5 Caustic Lye 1040 Iron Sludge 407
6 Soda Ash 30
7 Iron Powder 344
8 HCl 2250
9 Ice 300
Total 5903 Total 5903
54
2) 2 Nitro 4 Methoxy Aniline
BRIEF PROCESS:
Checkreactor is clean & dry. Charge para anisidine& acetic anhydride, maintain to reflux
&distill acetic acid. Add HNO3 & MDC for further reaction. Filter mass & give watch of soda
water to w/c.Do hydrolysis in another reactor by caustic lye & water. Filter mass dry & pack
product.
Chemical Reaction:
Mass Balance:
Sr
No.
INPUT Qty(in kg) OUTPUT Qty(in kg)
1 PARA ANISIDINE 500 Product 600
2 Acetic Anhydride 435 Recovered MDC 1480
3 Nitric Acid 260 MDC Loss 20
4 MDC 1500 Effluent 2180
5 Caustic Lye (48%) 400 Residue 15
6 Water 1000
7 Soda 200
Total 4295 Total 4295
55
3) 2,5 Dimethyl-P-Phenylenediamine
BRIEF PROCESS:
Cheak reactor is clean & dry. Charge water Na2CO3 & 2, 5 xylidine .Do addition of
BSC. Maintain reaction filter mass. Take mass in another reactor. Charge toluene.
Addition of HNO3. Maintain reaction mass. Filter mass & add into other reactor. Add
H2SO4 dump mass in water. Filter the mass. Do reduction with iron powder. Acetic
acid in water media. Filter mass & draying of product and pack materials.
Chemical Reaction:
NH2
CH3
CH3
N+
O-
O
2,5-dimethyl-4-nitroaniline
166
Fe2+
56/240
NH2
CH3
CH3
NH2
+ OH2
2,5-dimethylbenzene-1,4-diamine
2
36
136
4 CH3COOH
+ Fe derivative
290
M.W 462=462
NH2
CH3
CH3
+ 1/2 Na2co3
S
O
O Cl
2,5-dimethylaniline
121
53
176.5
benzenesulfonyl chloride
S
O
O
NH
CH3
CH3
+
+
+
Nacl
58.5
1/2 H2O
9
22
N-(2,5-dimethylphenyl)benzenesulfonamide
261
S
O
O
NH
CH3
CH3
N-(2,5-dimethylphenyl)benzenesulfonamide
261
HNO3 Nitration
63
S
O
O
NH
CH3
CH3
N+
O-
O
+ OH2
18
S
O
O
NH
CH3
CH3
N+
O-
O
N-(2,5-dimethyl-4-nitrophenyl)benzenesulfonamide
306
Hydrolysis H2SO4 Media
OH2
306
18
NH2
CH3
CH3
N+
O-
O
+
SO O
OH
2,5-dimethyl-4-nitroaniline
benzenesulfonic acid
166
158
1/2 CO2
56
Mass Balance:
Stage-I:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 2,5xylidine 500 Product 400
2 Sodium Carbonate 219 Dil. H2SO4 1695
3 BSC 730 Effluent 2521
4 Toluene 1000 Iron Sludge 350
5 Nitric Acid 260 Toluene Recover 960
6 H2SO4 500 Toluene Loss 35
7 Acetic Acid 50 Dist. Residue 5
8 Iron 231
9 Water 2476
Total 5966 Total 5966
57
4) 2-Mercapto 5-Methoxy Benzimedazole
BRIEF PROCESS:
Take 30% NaHs in S.S.Reactor and add 4 Methoxy Nitro Aniline slowly slowly on room
temperature. After addition maintain for two hour than rising the temperature slowly up to
85- 90° C. Than cool the mass up to 15 to 20° C and filter through C.F. and after filtration take
wet cake in S.S.Reactor in pressure of water + NaOH and add CS2 slowly slowly at room
temperature. After addition CS2 rise the temperature up to 105 – 110° C and maintain up to 4
hour after than make a cooling and isolate the product than filter through C.F. and give wash
of chilled water 5° c ,purify wet cake by solvent using carbon and dry the wet cake through
try Dryer or RVD.
Chemical Reaction:
OCH3
NO2
NH2
+ NaHS
4-methoxy-2-nitroaniline
M.W - 168
M.W - 56
OCH3
NH2
NH2
M.W - 138
CS2
N
NH
H3CO
SH
2-marcapto 5-methoxy benzimedazole
M.W- 180
+M.W-76
H2S
M.W- 34+ Na2S + SO2
M.W-78 M.W-64
4-methoxy benzene-1,2-diamine
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 4 Methoxy Nitro Aniline 950 Product 1000
2 NaHS (30%) 2100 NaHS – recycled to next batch 1406
3 CS2 430 DMF Recover 2328
4 Caustic Flakes 226 DMF Loss 65
5 DMF 2400 Dis. Residue 7
6 Carbon 25 Spent Carbon 15
7 Water 1500 Effluent to ETP 2710
8 Drying Loss 100
Total 7631 Total 7631
58
5) 3-[4-chloro-5-(cyclopentyloxy)-2-fluorophenyl]-5-(propan-2-ylidene)-1,3-
oxazolidin-2,4-dione. (PIK)
BRIEF PROCESS:
STAGE- 1& 2 First Take PICK3 Organic & Toluene in GLR than add ECF and after ECF add 40 % NaOH. Than
Sample it after Sample Clearance transfer the material in S.S.Reactor and add CPB & Cat-2
than add 40 % NaOH after addition maintain two hour and add water and after settling below
aqueous layer is NaBr and upper organic layer is for Toluene Recovery and than add Ethanol
for Crystallization after Crystallization Filter it.
STAGE – 3 First Take Wet Cake and than add Cat-3 and Cat-4 and add ECG than heat the mass and
Sample it. After than add Toluene and Charcoal & Silica Gel than Filter the Charcoal than
Recover Toluene and Than add Ethanol for Crystallization and than filter it and wash it Wet
Cake again than dry the Wet Cake to get final dry product.
Chemical Reaction:
STAGE- 1 &2 ClF
NH2 OOC2H5
O
5-amino-2-chloro-4-fluorophenyl ethyl carbonate
M.W : 233.62
ClCOOC 2H5
40% NaOH
TOLUENE
M.W : 108.52ClF
H5C2OOCHN OOC2H5
O
2-chloro-5-[(ethoxycarbonyl)amino]-4-fluorophenyl ethyl carbonate
M.W : 305.68
Bu4NBr
cyclo pentyl bromide
40% NaOH
ClF
H5C2OOCHN O
ethyl [4-chloro-5-(cyclopentyloxy)-2-fluorophenyl]carbamate
M.W : 301.74
PICK4
PICK3EPF
STAGE-3 ClF
H5C2OOCHN O
M.W : 301.74
+
ClF
O
O
N
CH3
CH3
O
O
M.W : 353.77
COOC 2H5
OHCH3
O
M.W : 144.16
PICK4
PIK
ethyl 2-hydroxy-3-methylbut3-enoate
ethyl [4-chloro-5-(cyclopentyloxy)-2-fluorophenyl]carbamate
3-[4-chloro-5-(cyclopentyloxy)-2-fluorophenyl]-5-(1-methylethylidene)-1,3-oxazolidine-2,4-dione
FeCl3
(Bu)3N
59
Mass Balance:
Stage-I & II:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
Step-1 & 2
1 Toluene 2141 Step -1&2 1200
2 PICK3 963 Toluene Recover 2066
3 ECF 673 Toluene Loss 65
4 40% NaOH 2053 Ethanol Recover 1517
5 CPB 1152 Ethanol Loss 70
6 CAT-2 IN WATER 200 Dist. Residue 10
7 Ethanol 1597 NaBR (By-Product) 1012
8 Water 1833 Effluent to ETP 3499
Water to be recycled 500
Total 9939 Total 9939
STEP-III:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
Step-3
1 Step -1&2 1200 Product 1000
2 Cat-3 17 Process Waste 56
3 Cat-4 74 Spent Catalyst 20
4 ECG 889 Spent Charcoal 22
5 Toluene 1660 Toluene Recover 1610
6 Charcoal 9 Toluene Loss 45
7 Silica gel 9 Ethanol Recover 2145
8 Ethanol 2247 Ethanol Loss 95
9 Dist. Residue 12
Recover ECG 1100
Total 6105 Total 6105
60
6) Sodium/Potassium { 2-[ (2,6 dichloro phenyl)amino] Phenyl} Acetate
BRIEF PROCESS:
In SSR, charge C. S. Lye solution ,Charge indolinine ,Maintain for 10 hours 45-55 ⁰C temp,
Check TLC ,Filter it, collect w/c ,Dry Material in FBD/Tray Dyer & Pack.
Chemical Reaction:
NHCl
Cl
O
OH
296
NaOH/KOH
40/56
NaNH
Cl
Cl
O
O /K
{2-[(2,6-dichlorophenyl)amino]phenyl}acetic acid
sodium/potessium{2-[(2,6-dichlorophenyl)amino]phenyl}acetate
318/324
18
+ OH2
sodium/potessium{2-[(2,6-dichlorophenyl)amino]phenyl}acetate
Mass Balance:
Sr
No.
INPUT Qty(in kg) OUTPUT Qty(in kg)
1 Indolinone 1000 Product 1000
2 Caustic Flake 250 Effluent 1250
3 Water 1000
Total 2250 Total 2250
61
7) 2 Chlor PPD
BRIEF PROCESS:
Reduction of 2 chloroparanitro aniline with hydrogen is done. Filtration of the product is
carried out with CF or ANF, Drying and Packing is done.
Chemical Reaction:
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 2 chlro para nitro Aniline 700 Product 550
2 Hydrogen 25 Recovered Methanol 1372
3 Methanol 1400 Methanol Loss 28
4 Drying Loss 140
5 Disti. Residue 10
Total 2125 Total 2125
62
74 150.5
+
NaNH
Cl
Cl
O
O
318
+
+
Cl
O
OH
chloroacetic acid
94.5
CH3
CH3
CH3OH
BUTANOLTBCA
18
OH2
150.5
TBCA
Cl
O
O
CH3
CH3
CH3
Cl
O
O
CH3
CH3
CH3
NHCl
Cl
O
OO
O
CH3
CH3
CH3
ESTER
410
NHCl
Cl
O
OO
O
CH3
CH3
CH3
ESTER
410
+ 3HCHO
NHCl
Cl
O
OO
OH
CH3
CH3
CH3OH
+
+
OH24
74
72
90
FORMIC ACID
ACECLOFENAC
354
+NaCl
58.5
8) 2 –{ 2[ 2-{2, 6 dichloro phenyl } Amino ] Phenyl Acetyl ] Oxyacetic Acid
BRIEF PROCESS:
4-(2-Methoxy ethyl) phenol reacted with epichlorhydrin in presence of caustic soda flakes
solution at 42 0C to produce Epoxide or 3-[4-(2-methoxyehtyl) phenoxy]-1,2-epoxypropane.
Dry and clean GLR ,Charge TBA in GLRUnder stirring, charge Mono chloro Acetic AcidCooland
than chill up to -5⁰CMaintain 4 hours 0-5⁰CSettle the mass and collect TBCA upper layer.
Check GLR, dry and cleanCollect TBCA and start heating.
Charge Sodium{ 2-[ (2,6 dichloro phenyl)amino] Phenyl} Acetate under stirring at room temp
in 4 hours,Maintain 6 hours at temp 80-85⁰C. Check TLC ,If condensation is okay, cool the
mass up to 50⁰C,Now charge formic acid, add in 2 hours at temp 50-55⁰C,Maintain 60-65⁰C
for 10 to 12 hours,Check TLC, if ok, cool the mass up to 20-20 ⁰C, Filter through C/F and
collect w/c, purify wet cake by solvent using carbon and dry the material in ANFD.
Chemical Reaction:
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 MCA 223 Product 675
2 TBA 174 Dil. Formic Acid 900
3
sodium {2-[2,6
dichlorophenyl)amino]phenyl}
Acetate 750 Effluent to ETP 797
4 Formic Acid 1300 Toluene Recover 1920
5 Toluene 2000 Toluene Loss 70
6 Carbon 25 Dist. Residue 10
Drying Loss 90
Spent Carbon 10
Total 4472 Total 4472
63
9) 2-Chloro 1-Phenoxy Benzene
BRIEF PROCESS:
Take ODCB in S.S. Reactor than add molten phenol. Then add KOH flakes than heat up to 140°
C temperatures, and maintain reaction mass and filter the salt and do the fractional
distillation of filtrate ML and collect the product.
Chemical Reaction:
OH
+
Cl
ClKOH / NaOH
O
Cl
PhenolOrtho Dichloro Benzene
2-Chloro 1 Phenoxy Benzene
+ + H2O
F. W :94.11 F. W: 147.00 F. W:204.65
KCl
F.W:74.55 F. W: 18.01
Mass Balance:
Sr
No.
INPUT Qty(in kg) OUTPUT Qty(in kg)
1 Phenol 1000 Product 1544
2 ODCB 3124 Recovered ODCB 1824
3 KOH 595 Dist. Residue 30
4 KOH 792
5 Effluent 529
Total 4719 Total 4719
64
10) 2,3 Xylil Anthranilic Acid
BRIEF PROCESS:
Take 1000 liters water and add NaOH and OCBA, maintain for 1 hour at room temperature,
Addition of Xylidine in 60 minutes ,Rise temperature up to reflux (95-98⁰C) ,Maintain it for 5
to 6 hours, dump in to HCl ,Decrease temp. up to 30 ⁰C and then filter it though C/F ,purify
wet cake by using dmf and carbon and Dry the wet cake and go for packing .
Chemical Reaction:
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 OCBA 500 Product 600
2 2:3 xylidine 425 Recovered DMF 1455
3 NaOH 115 DMF Loss 35
4 Sod bicarbonate 320 Dist. Residue 10
5 HCL 530 Spent Carbon 15
6 DMF 1500 Effluent 2390
7 Activated Carbon 20 Drying Loss 155
8 Water 1250
Total 4660 Total 4660
65
11) 2 Chloro 5 Methyl PPD
BRIEF PROCESS:
Check reactor is clean & dry. Take water, soda ash, 2-chloro 5-methyl aniline. Start addition of
BSC at specific temperature. Maintain reaction for few hours. Filter the mass & charge in
other reactor. Add toluene & start addition of HNO3 at specific temperature condition to
complete nitration reaction. Filter mass & charge in reactor. Add H2SO4 &water, maintain
and filter mass. Charge wet cake in reactor. Add water and pass H2 gas at specific
temperature & pressure condition. Filter mass, dry & pack materials
Chemical Reaction:
66
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 BSC 750 Product 500
2 Soda Ash 200 Recovered Toluene 870
3 2-chloro 5-methyl Aniline 600 Toluene Loss 25
4 Toluene 900 Dist. Residue 5
5 Nitric Acid 270 Dil. Sulfuric Acid 1480
6 Sulfuric Acid 500 Effluent 2365
7 Hydrogen Gas 25
8 Water 2000
Total 5245 Total 5245
67
12) 5 Amino Ortho Toludine
BRIEF PROCESS: Cheak reactor is clean & dry. Charge water, OT base, soda. Start charging BSC under specific
condition & maintain. Filter mass and charge w/c in another reactor, charge toluene & start
addition of HNO3, maintain reaction and filter mass, do hydrolysis by sulphuric acid and
dump mass in water& filter mass. Charge in other reactor. Add methanol and pass H2 gas at
specific temperature and pressure to complete reaction, dry,& pack materials
Chemical Reaction:
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 Ortho Toluene 500 Product 400
2 Soda Ash 247 Recovered Toluene 950
3 BSC 824 Toluene Loss 40
4 Toluene 1000 Dist. Residue 20
5 Nitric Acid 300 Dil. Sulfuric Acid 1900
6 Sulfuric Acid 500 Effluent 1495
7 Hydrogen Gas 25 Recovered Methanol 950
8 Water 1400 Methanol Loss 40
9 Methanol 1000
Total 5795 Total 5795
68
13) 4-Bromo Anisole
BRIEF PROCESS:
Phenol reacts with dimethyl sulphate in presence of sodium hydroxide to get anisole. Anisole
react with bromine to get crude 4-bromo anisole. Crude 4-bromo anisole take for fractional
distillation to get pure 4-bromo anisole.
Chemical Reaction:
4-Bromo Anisole
OCH3 OCH3
Br
Br2 + HBr
Anisole 4-Bromo Anisole
M.W : 108.14 M.W : 187.04
M.W : 80.91M.W ; 159.81
OH
Phenol
M.W : 94.11
C.S Lye (48%)
S OCH3
O
O
H3CO
M.W : 126.13
Di Methyl sulphate
+ Na2SO4
M.W.: 142
M.W: 40
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 Phenol 700 Product 1300
2 DMS 657 Recovered EDC 2190
3 Caustic Lye 1240 EDC Loss 50
4 EDC 2254 Dist. Residue 14
5 Bromine 1192 NaBr Sol. 1225
6 NaHCO3 1610 Effluent 4974
7 Water 2100
Total 9753 Total 9753
69
14) 2 Chloro 4 Flouro 5 Nitro Benzyl Chloride
BRIEF PROCESS: Cheak reactor is clean & dry. Charge 2 chloro 4 fluoro toluene, pass chlorine gas at specific
temp. & pressure of UV light. Transfer mass in other reactor. Start addition mixture off oleum
& nitric acid. Maintain to complete reaction & check result. Dump mass in water and filter the
mass. Charge wet cake in other reactor, add water & give wash of Na2Co3 & filter mass. Take
methanol in other reactor. Charge w/c .heat mass to reflux & chill mass & filter, dry & pack
material.
Chemical Reaction:
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 2 chlro 4 floro Toluene 1050 Product 1712
2 chlorine gas 1550 Recovered Methanol 2330
3 Oleum 23% 3075 Methanol Loss 50
4 Nitric Acid 1474 Dist. Residue 20
5 Hydrogen Peroxide 630 HCl (30%) 2513
6 Na2CO3 150 Dil. H2SO4 6486
7 Methanol 2400 Effluent 1578
8 Water 4360
Total 14689 Total 14689
70
15) 3 Amino 4 Methoxy Acetanilide
BRIEF PROCESS:
Check reactor is clean and dry, add 2,4 DNCD and caustic lye slowly after reaction is over.
Then proceed for filteration of mass with centrifuge.Transfer the ml for ME distillation.Charge
the methoxy mass in reactor. Add methanol and then add slowly iron powder and acetic acid,
cool the mass and add MGO and acetic anhydride Filter the mass by centrifuge, dry and pack.
Chemical Reaction:
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 2:4 DNCB 1000 Product 800
2 DMS 657 Recovered Methanol 1010
3 Caustic Flake 250 Methanol Loss 30
4 Methanol 1210 Dist. Residue 10
5 Hydrogen 60 NaCl 300
6 Acetic Anhydride 515 Effluent to Reuse 1542
Total 3692 Total 3692
71
16) Para Anisidine
BRIEF PROCESS:
Cheak reactor is clean & dry. charge PNBC, methanol, charge methoxide prepared by MEOH
& NAOH, maintain to complete reaction. Pass H2 gas to do hydrogenation, filter mass to
separate salt. Take distillation of methanol. The high vacuum distillation of product &
materials.
Chemical Reaction:
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 PNCB 1000 Product 750
2 Caustic Flake 260 Recovered Methanol 1130
3 Methanol 1170 Methanol Loss 30
4 Hydrogen 40 Dist. Residue 10
NaCl 550
Total 2470 Total 2470
72
17) Para Amino Salicylic Acid
BRIEF PROCESS: Cheak reactor is clean & dry& ready for batch charging. Charge PNSA & methanol. Start H2
gas passing at specific temperature & pressure to complete reaction. Filter mass & dry wet
cake & pack finish materials.
Chemical Reaction:
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 PNSA 1250 Product 1000
2 Methanol 1500 Recovered Methanol 1450
3 Hydrogen Gas 42 Methanol Loss 40
4 Dist. Residue 10
5 Drying Loss 292
Total 2792 Total 2792
73
18) NITRO TO AMINO CONVERSION BY CATALYTIC HYDROGENATION
BRIEF PROCESS: Charge solvent in hydrogenation reactor and add nitro compound and catalyst, mix well heat
up to boiling point of solvent and start purging of H2 gas, as reaction completed filter the
catalyst and purify product by charcolisation then isolate and filter the product and dry to get
final AMINO product.
Chemical Reaction:
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 Nitro Compound 750 Product 550
2 Solvent 1500 Recovered Solvent 1470
3 Catalyst 25 Solvent Loss 20
4 Carbon 25 Dist. Residue 10
5 Hydrogen 60 Spent Catalyst 27
Spent Carbon 30
Effluent 253
Total 2360 Total 2360
74
19) ALDEHYDE TO ALCOHOL CONVERSION BY CATALYTIC HYDROGENATION
BRIEF PROCESS:
Charge solvent in hydrogenation reactor and add aldehyde compound and catalyst, mix well
heat up to boiling point of solvent and start purging of H2 gas, as reaction completed filter
the catalyst and purify product by charcolisation then isolate and filter the product and dry to
get final ALCOHOL product.
Chemical Reaction:
Mass Balance:
Sr No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 Aldehyde Compound 750 Product 550
2 Solvent 1500 Recovered Solvent 1470
3 Catalyst 25 Solvent Loss 20
4 Carbon 25 Dist. Residue 10
5 Hydrogen 60 Spent Catalyst 27
Spent Carbon 30
Effluent 253
Total 2360 Total 2360
75
20) 2-Amino Ethane Thiol Hydrochloride
BRIEF PROCESS:
Route -1
2-aminoethanol react with carbon disulphide to get 2-aminoethanthiol. 2-aminoethanthiol
react with hydrochloric acid to get 2-aminoethane thiolhydrochloride.
Chemical Reaction:
OH
NH2
2-aminoethanol
F.W : 61.08
CS2
NaOH
F.W : 76.14
F.W : 39.99
SH
NH2
2-aminoethanethiol
F.W : 77.15
+ NaHS + CO2
F.W: 56.06 F.W: 44.01
2HCl
SH
NH2 HCl
2-aminoethanethiol hydrochloride
F.W: 113.61
F.W: 36.5
+ H2S + NaCl
F.W: 34 F.W: 58.5
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT
Qty(in
kg)
1 2-Aminoethanol 752 Product 1000
2 DM Water 3008 FILTRATE ML( TO ETP/MEE) 5451
3 C.S.Lye 1038 NaHS -30% SOLUTION 1414
4 CS2 932
DRYINGCONDENSATE(INCINERABLE
WASTE) 359
5 Con.Hcl 677 DISTILLED METHANOL 3167
6 Water 752
7 NaOH solution(30 %) 944
8 Methanol 3289
Total 11391 Total 11391
76
21) 2-aminoethane thiolhydrochloride
BRIEF PROCESS:
Route -2 2-aminoethanol react with thionyl chloride to get 2-chloroethanthiol hydochlorider. 2-
chloroethanthiol hydochlorider react with NaHS to get 2-aminoethane thiolhydrochloride.
Chemical Reaction:
OH
NH2
2-aminoethanol
SOCl2
F.W:61.08
F.W: 119Cl
NH2 HCl + SO2
F.W: 116
F.W: 64
NaHS
F.W: 56
HClSH
NH2 + NaCl
F.W: 58.5
2-chloroethanolamine hydrochloride
2-aminorthanethiol hydrochloride
F.W: 113.5 Mass Balance:
Sr No. Material INPUT Qty(in kg) Material OUTPUT
Qty(in
kg)
1 2-Aminoethanol 661 Product 1000
2 THIONYL CHLORIDE 1322 HCL - 30 % 1364
3 TOLUENE 1983 NaOH SOLUTION(10 %) 648
4 NaHS (30 %) 2023 Na2SO4 SOLUTION (25 %) 2843
5 IPA HCL 2438
FILTRATE ML 1 & 2( TO
ETP/MEE) 3279
6 Water 2231 DISTILLED TOLUENE 1942
7 NaOH solution ( 10 % ) 620 DISTILLED IPA 1983
8 NaOH solution ( 25 % ) 2132 RESIDUE 353
Total 13412 13412
77
22) Dimethyl CyanoCarbodithiomidiate
BRIEF PROCESS Cyanamide and carbon disulphide react with sodium hydroxide to produce disodium cyano
carbodithioimidiate. Disodiumcyanocarbodithioimidiate react with dimethyl sulphate to get
dimethyl cyano carbodithioimidate
Chemical Reaction:
CS2 +NH2
N
F.W : 76.14
Carbon disulphide cyanamide
F.W : 42.04
2NaOH
F.W : 40
N S-Na
+
S-Na
+N
F.W : 162.14
Di sodium cyano carbonodithioimidiate
+ 2H2O
F.W : 36.03
Di Methyl Sulphate
F.W. 126.13
N
N
SCH3
SCH3
+
S
O
O
OCH3H3CO
F. W : 142.04F.W:146.23
Dimethyl cyanocarbonodithioimidateSodium Sulphate
Na2SO4
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 Cynamide 660 Product 900
2 WATER 1572 FILTRATE ML 5588
3 CS2 538 Distilled cyclohexane/Ethanol 4275
4 22.5 % NAOH 2515 Incinerable waste 845
5 DMS 1823
6 CYCLOHEXANE/Ethanol 4500
Total 11608 Total 11608
78
23) 4-Chloro 3-ethyl-1-methyl-1H-pyrazole 5-carboxylic acid (PIC-T1)
BRIEF PROCESS:
Methyl ethyl ketone and di ethyl oxalate react in presence of sodium ethoxide to get
ethyl 2,4 dioxohexanoate. Ethyl 2,4 dioxohexanoate cyclise with hydrazine hydrate to
get 1-93-ethyl-1H-pyrazol-5-yl)propan-1-one further react with di methyl sulphate to
get 1-(3-ethyl-1-methyl-1H-pyrazol-5-yl)propan-1-one react with chlorine gas and
sodium hydroxide to get 4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carboxylic acid.
Chemical Reaction:
CH3
CH3
O
Methyl Ethyl Ketone
+
OC2H5
OC2H5
O
O
Di ethyl Oxalate
F.W: 146.14
NaoC2H5
F.W: 68
CH3
O
O
O
O
CH3
ethyl 2,4-dioxohexanoate
F.W:172.18
+ 2C2H5OH
F.W: 92.14
NH2NH2 H2O
F.W: 50.06
NNH
CH3
O
CH3
1-(3-ethyl-1H-pyrazol-5-yl)propan-1-one
F.W : 152.19
1/2 Di Methyl sulphate
F.W: 126.13N
NCH3
O
CH3
CH3
1-(3-ethyl-1-methyl-1H-pyrazol-5-yl)propan-1-one
NN
CH3
OH
O
CH3
Cl
4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carboxylic acid
F.W : 166.22
F.W : 188.61
Chlorine gas
Sodium Hydroxide
HCl F.W: 36.5
+ NaCl
F.W: 58.5
+ 3H2O
F.W : 54+H2SO4
F.W: 98
H2O
+ CH3OH + NaOH
F.W : 40F.W : 32
F.W : 35.5
F.W : 40
F.W : 18
F.W: 72
Mass Balance:
79
Sr.
No
INPUT Quantity (in
Kg)
OUTPUT Quantity
(in Kg)
1 Methyl Ethyl Ketone 636 Product 1000
2 Toluene 5241 distilled Toluene 4716
3 Sodium Ethoxide 726 NaCL 543
4 Di Ethyl Oxalate 1351 Filtrate ml to ETP/MEE 25334
5 Hydrochloric Acid-30% 3347 HCL -30% 689
6 Sodium bi carbonate 55 HYPO (14 % solution) 216
7 DM Water 16640 Condensate of drying 275
8 G.Acetic Acid 266 Distilled methanol 3561
9 80% Hydrazine Hydrate 774
10 Di Methyl Sulphate 1002
11 C.S Lye (48%) 1970
12 Chlorine Gas 326
13 Methanol 4000
Total 36334 Total 36334
80
24) 1-[4-(4-methylphenoxy)phenyl]methanamine Hydrochloride (PIC-T2)
BRIEF PROCESS:
P-Cresol react with 4-chlorobenzonitrile in presence of sodium hydride to get 4-(4-
methylphenoxy)benzonitrile. Hydrogenation of 4-(4-methylphenoxy)benzonitrile to
get 1-[4-(4-methylphenoxy)phenyl]methanamine react with IPA Hcl to get 1-[4-(4-
methylphenoxy)phenyl]methanamine hydrochloride.
Chemical Reaction: CH3
OH
CN
Cl
+
P Cresol
F. W : 108.14
4-chlorobenzonitrile
F. W: 137.57
O
CH3CN
4-(4-methylphenoxy)benzonitrile
F.W: 209.24
O
CH3CH2NH2
1-[4-(4-methylphenoxy)phenyl]methanamine Hydrochloride
HCL
F.W : 249.77
Sodium Hydride
F. W : 24+ NaCl
F.W: 58.5
Hydrogenation
Raney Ni
+ H2
2H2
Mass Balance:
Sr
No. INPUT Qty(in kg) OUTPUT Qty(in kg)
1 DMF 2640 Product 800
2 NaH 158 Distill DMF 2627
3 p-Cresol 473 FILTRATE ML ( TO ETP) 2155
4 p-Chlorobenzonitrile 542 Distill Toluene 3190
5 Toluene 3196 Recycle Raney Ni 162
6 DM Water 1595 Distill IPA 8220
7 IPA 8270 H2 GAS 13
8 Raney Ni 162
FILTRATE ML-
2(INCINERABLE WASTE) 806
9 Ammonia gas 15
DRYING CONDENSATE
(INCINERABLE WASTE) 46
10 H2 72
11 16% IPA HCl 896
Total 18019 Total 18019
81
ANNEXURE - IV
WATER CONSUMPTION AND WASTEWATER GENERATION
WATER CONSUMPTION
SR.
No.
WATER
CONSUMPTION
QUANTITY (KL/DAY)
Existing Additional Total after proposed
expansion
1. Domestic 4.0 2.0 6.0
2. Process 100.0 43.0 143.0
3. Boiler 20.0 50.0 70.0
4. Cooling 10.0 20.0 30.0
5. Washing 11.0 5.0 16.0
5. Other (Gardening) 5.0 1.0 6.0
TOTAL (Industrial) 141.0 118.0 259.0
TOTAL (Domestic +Industrial) 150.0 121.0 271.0
WASTE WATER GENERATION
SR.
No.
WASTE WATER GENERATION
QUANTITY (KL/DAY)
Existing Additional Total after proposed
expansion
1. Domestic 2.5 2.0 4.5
2. Process 33.0 62.0 95.0
3. Boiler 5.5 12.0 17.5
4. Cooling 3.5 7.0 10.5
5. Washing 2.5 5.0 7.5
6. Other (Gardening) 0.0 0.0 0.0
TOTAL (Industrial) 44.5 86.0 130.5
TOTAL (Domestic +Industrial) 47.0 88.0 135.0
82
Water Balance Diagram (Existing):
(Unit-KL/Day)
Water –150 KL/Day
Domestic- 4.00 Gardening- 5.00 Industrial –141.00
2.5 KL/Day �
Specific
tank/soak pit
system Process- 100 Washing- 11 Boiler- 20
Cooling- 10
Process- 33 Washing- 2.5 Boiler- 5.5 Cooling- 3.5
ETP
M/S. GIDC, Dahej (discharged to underground
pipline) for further treatment & disposal = 44.5
KLD
83
Water Balance Diagram (Proposed):
(Unit-KL/Day)
Water –121 KL/Day
Domestic- 2 Gardening- 1 Industrial –118
2.0 KL/Day �
Specific
tank/soak pit
system Process- 43 Washing- 5 Boiler- 50
Cooling- 20
Process- 62 Washing- 5 Boiler- 12 Cooling- 7
ETP (56 KL/Day Low COD Effluent + 35 KL/Day-MEE Condensate)
)
81 KL/Day
Reuse/Recycle
30 KL/Day – High COD
Effluent + 10 KL/Day RO
Reject � MEE
5 KL/Day �
MEE
35 KL/Day �
MEE
Condensate
91 KL/Day � RO
84
Water Balance Diagram (Total):
(Unit-KL/Day)
Water –271 KL/Day
Domestic- 6 Gardening- 6 Industrial –259
4.5 KL/Day �
Specific
tank/soak pit
system Process- 143 Washing- 16 Boiler- 70
Cooling- 30
Process- 95 Washing- 7.5 Boiler- 17.5 Cooling- 10.5
ETP (100.5 KL/Day Low COD Effluent + 35 KL/Day-MEE Condensate)
)
81 KL/Day
Reuse/Recycle
30 KL/Day – High COD
Effluent + 10 KL/Day RO
Reject � MEE
5 KL/Day �
MEE
35 KL/Day �
MEE
Condensate
91 KL/Day � RO M/S. GIDC, Dahej (discharged to underground
pipline) for further treatment & disposal = 44.5
KLD
85
ANNEXURE - V
EFFLUENT TREATMENT PLANT
PROCESS DESCRIPTION: ETP (EFFLUENT TREATMENT PLANT)
EXISTING:
For Low COD and TDS Stream I (44.5 KLD)
M/s. Pragna Pharma P. Ltd. shall have an Effluent treatment plant consisting of primary,
secondary, tertiary and advanced treatment units. The effluent confirming to inlet standards
of GIDC drain shall be discharged in to underground drainage line. The details of ETP are as
follows.
First all non-toxic and biodegradable streams (low & medium COD) of wastewater shall pass
through Screen Chamber (SC) where floating material shall be removed with help of Screen
(S-01). Then effluent shall be collected in Collection cum Equalization tank-1 (CET-1). Pipe
grid is provided at bottom of the CET-1 to keep all suspended solids in suspension and to
provide proper mixing by mixer.
Then after, equalized wastewater shall be pumped to Neutralization Tank-1 (NT-1) where
the continuous addition and stirring of caustic solution is done to maintain neutral pH of
wastewater from Caustic Dosing Tanks (CDT) as per requirement by gravity. Then after,
neutralized wastewater shall go to Flash Mixer-1 (FM-1) by gravity. Alum and Polyelectrolyte
shall be dosed from Flocculants Dosing Tank (FLDT) and Polyelectrolyte Dosing Tank (PEDT)
respectively by gravity into FM-1 to carry out coagulation by using a Flash Mixer.
Then after, coagulated wastewater shall be settled in Primary Tube Settler-1 (PTS-1). Clear
supernatant from PTS-1 shall be passed in Aeration Tank (AT-1) here, biodegradation of
organic matter of the wastewater shall be carried out by bacteria (suspended growth) in the
AT-1 and for that oxygen shall be supplied by 2 nos. of air blowers (B-02) through diffusers.
Air blowers also keep MLSS in suspension.
Then after, wastewater shall go to Secondary Settling Tank-1 (SST-1) from AT. Here, the
suspended solids shall be settled. Sludge shall be removed from bottom of SST-1 and
pumped to AT to maintain MLSS and excess activated sludge shall be sent to Sludge Sump
(SS). Clear supernatant from SST-1 shall go to Aeration Tank-2 (AT-2). Here biodegradation
of left out organic matter of the wastewater shall be carried out by bacteria (suspended
growth) and for that oxygen shall be supplied by two nos. of blowers (B-03) with help of
diffusers. Then after, wastewater shall go to Secondary Tube Settler-2 (SST-2) from AT-2.
Here, the suspended solids shall be settled. Activated sludge shall be removed from bottom
of SST-2 and pumped to AT-2 to maintain MLSS and remaining will be sent to SS. Nutrients
will be added from NDTs to Aeration Tank-2 for growth of Bacteria. Clear effluent is the
collected in of Intermediate Sump (IS) by gravity.
Thereafter, the wastewater shall be passed through Pressure Sand Filter (PSF) to remove left
out TSS and Activated Carbon Filter (ACF) and collected in Treated Effluent Sump. Clear
supernatant from SST shall be collected in Treated Effluent Sump before sent to GIDC drain
for deep sea disposal.
86
Sludge settled in PTS-1&2 and excess sludge from SST-1&2 shall be collected in Sludge Sump
then sludge shall be pumped to Filter Press where, dewatering shall be carried out before
storage in HWSA and ultimate disposal to TSDF. Leachate from FP shall be sent back to CET-
1 for further treatment.
Effluent treatment Plant (Dimension):
S.N. Name of unit Size (m x m x m)
L x B x (LD+FB) No. MOC/ Remark
Stream I (Low COD & TDS Stream) 44.5 m3/D
1 Screen Chamber (SC-01) 1.0 m x 0.7 m
(0.05 m+0.3 FB) 1
RCC M25+A/A
Bk. Lining
2
Collection cum
Equalization Tank-1 (CET-
01)
3.0 m x2.5 m x
(2.0 m+0.5 FB) 1
RCC M25+A/A
Bk. Lining
3 Neutralization Tank-1 (NT-
01)
1.0 m x 1.0 m x
(2.0 m +0.5 FB) 1
RCC M25+A/A
Bk. Lining
4 Flash Mixer-1 (FM-01) 1.0 m x1.0 m x
(1.8 m +0.7 FB) 1 RCC M25
5 Primary Tube Settler-1
(PTS-01)
2.5 m x 2.0 m x
(1.5 m + 0.75HB+0.5
FB)
1 RCC M25
6 Aeration Tank-1 (AT-01) 8.0 m x 3.5 m x
(4.0 m+0.5 m) 1 RCC M25
7 Secondary Settling Tank-1
(SST-01)
3.0 m x 2.0 m x
(2.0 m + 0.75 HB+0.5
FB)
1 RCC M25
8 Aeration Tank-2 (AT-02) 4.0 m x 3.5 m x
(4.0 m+0.5 m) 1 RCC M25
9 Secondary Settling Tank-2
(SST-02)
3.0 m x 2.0 m x
(2.0 m + 0.75 HB+0.5
FB)
1 RCC M25
10 Intermediate Sump (IS-01) 2.0 x 1.5 x (2.5 m+0.5) 1 RCC M25
11 Pressure Sand Filter (PSF-
01) 2.22 m3/hr 1 FRP
12 Activated Carbon Filter
(ACF-01) 2.22 m3/hr 1 FRP
13 Treated effluent Sump 4.0 m x 3.0 m x
(2.5 m + 0.5) RCC M25
14 Sludge Sump(SS-01) 2.0 x 1.5 x (2.5 m+0.5) 1 RCC M25
15 Filter Press(FP-01) 9 m3
/ batch 1 PP
87
RCC M25 = REINFORCED CEMENT CONCRETE (M 25 GRADE)
PCC = PLAIN CEMENT CONCREAT
SS = STAINLESS STEEL
PP = POPYPROPELINE
Flow Diagram:
Mode of Disposal:
MODE OF DISPOSAL
INDUSTRIAL
Generation Quantity Mode of Disposal
Existing: 44.5 KL/Day
Treated effluent is disposed off into deep sea through GIDC
Drainage line.
DOMESTIC 2.5 KL/Day
MODE OF DISPOSAL Discharged in to Septic Tank & Soak Pit.
88
PROPOSED: For Low COD and TDS Stream I (56 KLD)
M/s. Pragna Pharma P. Ltd. shall have a Effluent treatment plant consisting of primary,
secondary, tertiary and advanced treatment units. The details of ETP are as follows.
First all non-toxic and biodegradable streams (low & medium COD) of wastewater shall
collected in Equalization cum Neutralisation Tank-1 (ENT-1) where caustic solution is done
to maintain neutral pH of wastewater from Caustic Dosing Tanks (CDT-01) as per
requirement by gravity. .Mixer is provided in ENT-02 to keep all suspended solids in
suspension and to provide proper mixing.
Then after, neutralized wastewater shall go to Flash Mixer-1 (FM-01) by gravity. Alum and
Polyelectrolyte shall be dosed from Flocculants Dosing Tank (FDT-01) and Polyelectrolyte
Dosing Tank (PEDT-01) respectively by gravity into FM-1 to carry out coagulation by using a
Flash Mixer.
Then after, coagulated wastewater shall be settled in Primary Tube Settler-1 (PTS-01). Clear
supernatant from PTS-1 shall be passed in Aeration Tank (AT-01) here, biodegradation of
organic matter of the wastewater shall be carried out by bacteria (suspended growth) in the
AT-01 and for that oxygen shall be supplied by 2 nos. of air blowers (B-02) through diffusers.
Air blowers also keep MLSS in suspension.
Then after, wastewater shall go to Secondary Settling Tank-1 (SST-01) from AT-1. Here, the
suspended solids shall be settled. Sludge shall be removed from bottom of SST-01 and
pumped to AT-02 to maintain MLSS and excess activated sludge shall be sent to Sludge
Sump (SS-01). Clear supernatant from SST-01 shall go to Aeration Tank-2 (AT-02).
Here biodegradation of left out organic matter of the wastewater shall be carried out by
bacteria (suspended growth) and for that oxygen shall be supplied by two nos. of blowers
(B-03) with help of diffusers. Then after, wastewater shall go to Secondary Tube Settler-2
(SST-02) from AT-2. Here, the suspended solids shall be settled. Activated sludge shall be
removed from bottom of SST-2 and pumped to AT-2 to maintain MLSS and remaining will be
sent to SS. Nutrients will be added from Nutrient Dosing Tank (NDT-01) to Aeration Tank-2
for growth of Bacteria. Clear effluent is the collected in of Intermediate Sump (IS-01) by
gravity.
Thereafter, the wastewater shall be passed through Multi Gain Filter (MGF-01) to remove
left out TSS and Activated Carbon Filter (ACF-01) and collected in Treated Effluent Sump.
From TWS-01 water shall be sent to RO for further treatment. RO reject shall be mixed with
effluent in ME Feed Tank. RO permeate shall be reuse in plant.
Sludge settled in PTS-01 & 02 and excess sludge from SST-01 & 02 shall be collected in
Sludge Sump then sludge shall be pumped to Filter Press where, dewatering shall be carried
out before storage in HWSA and ultimate disposal to TSDF. Leachate from FP-01 shall be
sent back to ENT-01 for further treatment.
89
For High TDS Stream II (40 KLD) - 30 KLD (High COD) + 10 KLD (RO Reject)
All High COD & TDS streams of wastewater shall be collected in Equalization cum
Neutralization Tank-2 (CET-02) where caustic shall be added from Caustic Dosing tank to
maintain neutral pH of waste water. Mixer is provided in ENT-02 to keep all suspended
solids in suspension and to provide proper mixing.
Then after, neutralized wastewater shall be pumped to Flash Mixer-2 (FM-02) where Alum
and poly shall be added from Flocculant Dosing Tank (FDT-01) and Poly Dosing Tank (PEDT-
01) respectively. Then after, coagulated wastewater shall be settled in Primary Tube Settler-
2 (PTS-02). Sludge settles in PTS-02 shall be sent to Sludge sump (SS-01).
Clear effluent from PTS-01 shall be collected in Holding Tank (HT-01) before pumped to
strippers. Effluent from stripper shall be then collected in MEE Feed Tank(MFT-01) here RO
Reject shall be mixed with it. Then before it will be pumped to Multiple Effect Evaporator for
further treatment. Condensate from MEE will be treated in ETP and it will be
reused/recycled in existing premises. And thick liquid shall be sent to Agitated Thin Film
Dryer (ATFD-01) for drying. Solids from ATFD-01 shall be collected and stored in HWSA for
disposal in TSDF.
90
Effluent Treatment Plant (Dimension):
S.
N. Name of unit
Size (m x m x m)
L x B x (LD+FB) No. MOC/ Remark
Stream I (Low COD Stream) 56 KLD + 35 KLD MEE Condensate
1 Equalization cum
Neutralisation Tank (ENT-01) 5.25 m x4.0 m x
(3.0 m+0.5 FB)
2 RCC M25+A/A Bk.
Lining
2 Flash Mixer-1 (FM-01) 1.3 m x1.3 m x
(2.5 m +0.5 FB)
1 RCC M25
3 Primary Tube Settler-1(PTS-
01) 4.0 m x 2.5 m x
(2.0 m + 0.75HB+0.5 FB)
1 RCC M25
4 Aeration Tank-1 (AT-01) 10 m x 6.0 m x
(4.5 m+0.5 m)
1 RCC M25
5 Secondary Settling Tank-1
(SST-01) 4.0 m x 3.3 m x
(2.5 m + 0.75 HB+0.5 FB)
1 RCC M25
6 Aeration Tank-2 (AT-02) 10 m x 6.0 m x
(4.5 m+0.5 m)
1 RCC M25
7 Secondary Settling Tank-2
(SST-02) 4.0 m x 3.0 m x
(2.5 m + 0.75 HB+0.5 FB)
1 RCC M25
8 Intermediate Sump (IS-01) 3.0 x 2.0 x (3.0 m+0.5)
1 RCC M25
9 Multi Grain Filter (MGF-01) 6.0 m3/hr 1 FRP/MSEP
10 Activated Carbon Filter (ACF-
01) 6.0 m3/hr
1 FRP/MSEP
11 Treated effluent Sump 5.25 m x4.0 m x
(3.0 m+0.5 FB)
1 RCC M25
12 RO Units (RO-01) 100 KLD 1 STD.
13 Sludge Sump(SS-01) 2.0 x 2,0 x (2.5 m+0.5) 1 RCC M25
15 Filter Press(FP-01) 30 m3/D 1 PP
Stream II High COD Stream (40 KLD) -30 KLD (High COD) + 10 KLD (RO Reject)
1 Equalization cum
Neutralisation Tank-2 (ENT-
02)
3.5 x 3.5 x (3.0LD+0.5 FB) 1 RCC M25+A/A
Bk. Lining
3 Flash Mixer-2(FM-02) 1.0 x 1.0 x (1.5LD+0.5 FB) 1 RCC M25
4 Primary Tube Settler-02
Tank (PTS-02)
2.5 x 1.5 x (2.0LD+0.5 FB) 1 RCC M25
5 Holding Tank (HT-01) 3.5 x 3.5 x (3.0 LD+0.5 FB) 1 RCC M25
6 Strippers (ST-01) 34 m3/day 1 SS316L
7 MEE Feed Tank (MFT-01) 5.0 x 3.5 x (3.0 LD+0.5 FB) 1 RCC M25
91
8 Four Stages Multiple Effect
Evaporators with Agitated
Thin Film Dryer (MEE-01,
ATFD-01)
34 m3/day 1 SS316L
RCC M25 = REINFORCED CEMENT CONCRETE (M 25 GRADE)
PCC = PLAIN CEMENT CONCREAT
SS = STAINLESS STEEL
PP = POPYPROPELINE
Flow Diagram:
Mode of Disposal:
MODE OF DISPOSAL
INDUSTRIAL
Generation Quantity Mode of Disposal
Proposed Total: 86.0 KL/Day
30 KL/Day
(Concentrated Stream)
Shall be subjected to MEE and treated in ETP and it will be
reused/recycled in Plant premises.
56 KL/Day
(Dilute Stream)
Treated effluent will be reused/recycled in plant premises.
DOMESTIC 2.0 KL/Day
MODE OF DISPOSAL Discharged in to Septic Tank & Soak Pit.
92
ANNEXURE-VI
DETAILS OF HAZARDOUS WASTE GENERATION & DISPOSAL
CAT.
NO. HAZARDOUS WASTE
Existing
Quantity
Additional
Quantity
Total
Quantity METHOD OF DISPOSAL
33.1 Discarded
Containers/Bags
/liner
Bags = 167
Nos. /Month
Drums = 42
Nos. /Month
Bags = 4,167
Nos./Month
Drums =
1,250
Nos./Month
Bags = 4,334
Nos./Year
Drums =
1,292
Nos./Month
Collection, Storage,
Decontamination,
Transportation & Sale to
registered recycler or
reuse within premises.
5.1 Used Oil 0.167
Kg/Month
12.50
Kg/Month
12.50
Kg/Month Collection, Storage,
Transportation & Sale to
GPCB authorized re-
processor.
-- Zinc Sludge (Sludge
generation during Zinc
Salts production)
175
MT/Month
-- 175
MT/Month
Collection, Storage,
Transportation & send to
TSDF Site
-- MnSO4 (Sludge
generation during
Manganese Sulphate
production)
112.5
MT/Month
- 112.5
MT/Month
Collection, Storage,
Transportation and send
to TSDF Site
35.3 ETP Sludge 3
MT/Month
41.67
MT/Month 44.67
MT/Month
Collection, Storage,
Transportation & sent to
TSDF Site
29.1 Solid Waste (Inorganic
Waste)
-- 45
MT/Month
45
MT/Month Collection, Storage,
Transportation and
Disposal at TSDF site
-- MEE Salt -- 150
MT/Month
150
MT/Month Collection, Storage,
Transportation and
Disposal at TSDF site
20.3 Distillation Residues -- 220
MT/Month
220
MT/Month Collection, Storage,
Transportation and Co-
processing in Cement
Industries or incineration
at Common Incineration
facility
29.5 Spent Catalyst -- 10
MT/Month
10
MT/Month Collection, Storage,
Transportation and send
to recycler
29.6 Spent Acid -- 550
MT/Month
550
MT/Month Collection, Storage,
Transportation and Sale
to end user
93
-- Sodium Hydro sulfide -- 170
MT/Month
170
MT/Month Collection, Storage,
Transportation and Sale
to end user
- Hydrochloric Acid -- 180
MT/Month
180
MT/Month Collection, Storage,
Transportation and Sale
to end user
- Formic Acid -- 100
MT/Month
100
MT/Month Collection, Storage,
Transportation and Sale
to end user
- Acetic Acid -- 10
MT/Month
10
MT/Month Collection, Storage,
Transportation and Sale
to end user
- Sodium Bromide
Solution
-- 170
MT/Month
170
MT/Month Collection, Storage,
Transportation and Sale
to end user
28.1 Inorganic Salt -- 60
MT/Month
60
MT/Month Collection, Storage,
Transportation and Send
to TSDF site
- NaOH (10%) -- 60
MT/Month
60
MT/Month Collection, Storage,
Transportation and Sale
to end user
- Na2SO4 (25%) -- 250
MT/Month
250
MT/Month Collection, Storage,
Transportation and Sale
to end user
- HYPO -- 10
MT/Month
10
MT/Month Collection, Storage,
Transportation and Sale
to end user
- Potassium Chloride
Salt
-- 25
MT/Month
25
MT/Month Collection, Storage,
Ttransportation and Sale
to end user
29.3 Date expired & Off-
Specification Material
-- 2
MT/Month
2
MT/Month Collection, Storage,
Transportation and sent
for co-processing in
cement industries or
incineration in common
incineration facility
DETAILS OF DISPOSAL OF SOLID WASTES
Industry is a member of TSDF site of M/s. BEIL (Bharuch Enviro Infrastructure Ltd) for suitable
treatment & disposal of hazardous wastes from time to time.
Industry is a member of M/s. RSPL & M/s. SEPPL for Co-processing & common Incineration facility
respectively.
94
ANNEXURE-VII
DETAILS OF AIR POLLUTION CONTROL SYSTEM
DETAILS OF FUELCONSUMPTION
SR. NO. NAME OF FUEL QUANTITY
EXISTING ADDITIONAL
1. Natural Gas
OR
LDO
1500 m3/Month
OR
120 Lit/Hr
72,000
SCM/Month
2. LDO/Furnace Oil -- 100 Lit/Hr
3. Soild Fuel -- 150 MT/Month
4. Diesel -- 60 Lit/Hr
DETAILS OF PROCESS VENT AND BOILER STACK
• EXISTING (FLUE GAS EMISSION THROUGH STACK)
Sr.
No.
Stack
Attached to
Stack Height in
meter
Air Pollution
Control Measure
Parameter Permissible Limit
1.
Boiler
(Capacity = 600
Kg/Hr)
11 --- SPM
SOX
NOX
150 mg/Nm3
100 ppm
50 ppm
2. Hot Air Generator
(3 Nos.)
11 --- SPM
SOX
NOX
150 mg/Nm3
100 ppm
50 ppm
3. Furnace (5 Unit) 20 Cyclone
Separator
SPM
SOX
NOX
150 mg/Nm3
100 ppm
50 ppm
• EXISTING (PROCESS GAS EMISSION THROUGH STACK)
Sr.
No.
Stack
Attached to
Stack Height in
meter
Air Pollution
Control Measure
Parameter Permissible Limit
1.
Spray Dryer (3 Nos.) 12 Wet Scrubber
with ventury
SPM
150 mg/Nm3
95
• PROPOSED (FLUE GAS EMISSION THROUGH STACK)
Sr.
No.
Stack
Attached to
Stack Height in
meter
Air Pollution
Control Measure
Parameter Permissible Limit
1.
Steam Boiler
(800 Kgs/Hr-1 Nos.)
(Fuel –Natural Gas)
15 -- SPM
SOX
NOX
150 mg/Nm3
100 ppm
50 ppm
2. Steam Boiler
(2000 Kgs/Hr-1
Nos.)
(Fuel-Solid Fuel like
Agro Waste, Coal)
30 Multi Cyclone
Separator with
Bag Filter
SPM
SOX
NOX
150 mg/Nm3
100 ppm
50 ppm
3. Steam Boiler
(600 Kgs/Hr)
(Fuel-Natural Gas)
Stand by
15 -- SPM
SOX
NOX
150 mg/Nm3
100 ppm
50 ppm
4. Steam Boiler
(800 Kgs/Hr-1 Nos.)
(Fuel –LDO/Furnace
Oil)
Stand by
30 Multi Cyclone
Separator with
Bag Filter
SPM
SOX
NOX
150 mg/Nm3
100 ppm
50 ppm
5. Thermic Fluid
Heater
(4.0 LAC K.CAL/Hr)
(Fuel-Natural Gas)
15 -- SPM
SOX
NOX
150 mg/Nm3
100 ppm
50 ppm
6. Thermic Fluid
Heater
(6.0 LAC K.CAL/Hr)
(Fuel-Solid Fuel)
30 Multi Cyclone
Separator with
Bag Filter
SPM
SOX
NOX
150 mg/Nm3
100 ppm
50 ppm
7. Thermic Fluid
Heater
(4.0 LAC K.CAL/Hr)
(Fuel-LDO/Furnace
Oil)
Stand By
30 Multi Cyclone
Separator with
Bag Filter
SPM
SOX
NOX
150 mg/Nm3
100 ppm
50 ppm
96
ANNEXURE-VIII
DETAILS OF HAZARDOUS CHEMICALS STORAGE & HANDLING
Sr No. Name of chemical POTENTIAL
HAZARD
Mode of storage
(in drums /carboys
/bags/ storage tank )
MAX
STORAGE
QTY.
1 SULPHURIC ACID CORROSIVE STORAGE TANK 20 KL
2 Hydrochloric acid CORROSIVE STORAGE TANK 20 KL
3 CON.NITRIC ACID CORROSIVE STORAGE TANK 20 KL
4 ACETIC ACID CORROSIVE DRUM 10 KL
5 ACETIC ANHYDRIDE CORROSIVE DRUM 10 KL
6 FORMIC ACID CORROSIVE DRUM 10 KL
7 OLEUM 23% CORROSIVE STORAGE TANK 20 KL
8 NAHS TOXIC STORAGE TANK 10 KL
9 CS2 FLAMMABLE DRUM/ STORAGE TANK 5 MT
10 Bromine CORROSIVE BOTTAL 1 MT
11 Phenol CORROSIVE DRUM 10 MT
12 ODCB TOXIC DRUM 10 MT
13 DMS TOXIC DRUM 5 MT
14 Hydrogen gas FLAMMABLE CYLINDER 0.8 MT
15 2chloro para nitro aniline TOXIC BAG 5 MT
16 5-chloro methyl aniline TOXIC BAG 5 MT
17 ORTHO TOLUDINE FLAMMABLE DRUM 5 MT
18 Para nitro salicylic acid TOXIC BAG 5 MT
19 2,5 dichloro aniline TOXIC DRUM/BAG 5 MT
20 TBA FLAMMABLE DRUM 5 MT
21 MCAA TOXIC DRUM/BAG 5 MT
22 DNCB TOXIC BAG 5 MT
23 2,5 xylidine FLAMMABLE DRUM 5 MT
24 BSC TOXIC DRUM 5 MT
25 4-Methoxy nitro aniline TOXIC DRUM/BAG 5 MT
26 OCBA TOXIC BAG 20 MT
27 2,3 xylidine FLAMMABLE DRUM 10 MT
28 Dinitrochloro benzene TOXIC DRUM/BAG 5 MT
29 2 Chloro 4-floro -1-
(trichloromethyl)benzene CORROSIVE DRUM 10 MT
30 PNCB TOXIC DRUM/BAG 5 MT
31 MDC TOXIC DRUM 10 MT
32 DMF FLAMMABLE DRUM 20 KL
33 Methanol FLAMMABLE STORAGE TANK 20 KL
34 EDC FLAMMABLE DRUM 10 MT
35 Toluene FLAMMABLE STORAGE TANK 20 KL
36 Nitro compound TOXIC DRUM/BAG 10 MT
97
37 Aldehyde compound TOXIC DRUM/BAG 10 MT
38 Ethanol FLAMMABLE STORAGE TANK 20 KL
39 2-Aminoethanol FLAMMABLE DRUM/ STORAGE TANK 20 MT
40 THIONYL CHLORIDE FLAMMABLE DRUM 10 MT
41 Cynamide TOXIC DRUM/ STORAGE TANK 20 MT
42 Sodium Ethoxide FLAMMABLE DRUM 20 MT
43 Di Ethyl Oxalate FLAMMABLE DRUM/BAG 20 MT
44 80% Hydrazine Hydrate FLAMMABLE DRUM 10 MT
45 Ammonia gas CORROSIVE CYLINDER 10 MT
46 NaH FLAMMABLE DRUM/BAG 10 MT
47 Chlorine Gas CORROSIVE CYLINDER 10 MT
48 Raney Ni FLAMMABLE DRUM/BAG 5 MT
98
ANNEXURE – IX
SOCIO - ECONOMIC IMPACTS
1) Employment Opportunities
The manpower requirement for the proposed Expansion project is being expected to generate some
permanent jobs and secondary jobs for the operation and maintenance of plant. This will increase
direct / indirect employment opportunities and ancillary business development to some extent for
the local population.
This phase is expected to create a beneficial impact on the local socio-economic environment.
2) Industries
Required raw materials and skilled and unskilled laborers will be utilized maximum from the local
area. The increasing industrial activity will boost the commercial and economical status of the
locality, to some extent.
3) Public Health
The company regularly examines, inspects and tests its emission from sources to make sure that the
emission is below the permissible limit. Hence, there will not be any significant change in the status
of sanitation and the community health of the area, as sufficient measures have been taken and
proposed expansion under the EMP.
4) Transportation and Communication
Since the existing factory is having proper linkage for the transport and communication, the
development of this project will not cause any additional impact. In brief, as a result of the proposed
expansion project there will be no adverse impact on sanitation, communication and community
health, as sufficient measures have been proposed expansion to be taken under the EMP. The
proposed expansion project is not expected to make any significant change in the existing status of
the socio -economic environment of this region.
99
ANNEXURE-X
______________________________________________________________________
PROPOSED TERMS OF REFERENCE FOR EIA STUDIES
1. Project Description
• Justification of project.
• Promoters and their back ground
• Project site location along with site map of 10 km area and site details providing various
industries, surface water bodies, forests etc.
• Project cost
• Project location and Plant layout.
• Water source and utilization including proposed water balance.
• Product spectrum (proposed products along with production capacity) and process
• List of hazardous chemicals.
• Mass balance of each product
• Storage and Transportation of raw materials and products.
2. Description of the Environment and Baseline Data Collection
• Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 10 km
area.
• Existing environmental status Vis a Vis air, water, noise, soil in 10 km area from the project site.
For SPM, RSPM, SO2, NOx.
• Ground water quality at 8 locations within 10 km.
• Complete water balance
3. Socio Economic Data
• Existing socio-economic status, land use pattern and infrastructure facilities available in the
study area were surveyed.
4. Impacts Identification And Mitigatory Measures
• Identification of impacting activities from the proposed expansion project during construction
and operational phase.
• Impact on air and mitigation measures including green belt
• Impact on water environment and mitigation measures
• Soil pollution source and mitigation measures
• Noise generation and control.
• Solid waste quantification and disposal.
5. Environmental Management Plan
• Details of pollution control measures
• Environment management team
• Proposed schedule for environmental monitoring including post project
6. Risk Assessment
• Objectives and methodology of risk assessment
• Details on storage facilities
• Process safety, transportation, fire fighting systems, safety features and emergency capabilities to
be adopted.
• Identification of hazards
• Consequence analysis through occurrence & evaluation of incidents
• Disaster Management Plan.
100
7. Information for Control of Fugitive Emissions
8. Post Project Monitoring Plan for Air, Water, Soil and Noise.
9. Information on Rain Water Harvesting
10. Green Belt Development plan
101
ANNEXURE-XI
______________________________________________________________________
PLOT ALLOTMENT LETTER
102
103
104
ANNEXURE-XII
______________________________________________________________________
WATER SUPPLY LETTER
105
ANNEXURE-XIII
______________________________________________________________________
Waste water discharge document
106
ANNEXURE-XIV
______________________________________________________________________
RSPL MEMBERSHIP CERTIFICATE
107
ANNEXURE-XV
______________________________________________________________________
TSDF MEMBERSHIP CERTIFICATE
108
ANNEXURE-XVI
______________________________________________________________________
TOPOSHEET