properties of gas and liquid experiment
TRANSCRIPT
SUMMARY
Th is exper iment o f s tudy ing the p roper t ies o f gas and l i qu id by us ing
Armf ie ld Proper t ies o f Gases and L iqu ids appara tus i s d iv ided in to
two par ts , wh ich a re Par t A and Par t B . Par t A i s conduc ted to
de te rmine the v iscos i t y o f a i r . The ma in techn ique o f th i s exper iment
i s to de te rmine the p ressure d rop by read ing the mercury leve l o f
manometer a t bo th s ides . I t i nvo lves c los ing the vacuum pump va lve
fo r every 10 seconds a f te r le t t i ng the con t ro l tap to exhaus t to
a tmosphere . The v iscos i t y o f gas , o r in th is con tex t , v i scos i t y o f a i r ,
i s de te rmined by us ing the Po iseu i l l e fo rmu la , s ta ted in Theory
sec t ion . The v iscos i t y o f a i r i s ca lcu la ted to be 1 .387x10 - 5 Ns /m 2 ,
wh ich i s 25 .83 percen tage o f e r ro r . The v iscos i t y o f gas i s then
p roved to be dependent o f p ressure , and i t i nc reases upon the
inc rease o f tempera tu re . Par t B i s conduc ted to de te rmine the
v iscos i t y o f l i qu id , in th is con tex t , g l ycer ine . I t i s bas ica l l y conduc ted
to record the t ime taken fo r a ba l l bear ing , wh ich i s denser than the
l i qu id , to fa l l a t a ce r ta in d is tance ins ide a v iscometer . The v iscos i t y
o f l i qu id i s de te rmined us ing S toke ’s Law o f d rag fo rce , and the
va lue o f v i scos i t y o f g lycer ine i s 5 .914 Ns /m 2 . The v iscos i t y o f l i qu id
however i s tempera tu re dependence , and i t i nc reases w i th a
decrease o f tempera tu re . The exper iment i s comple ted and
success fu l l y conduc ted .
1 | P a g e
INTRODUCTION
When a rea l f l u id f l ows , an ad jacen t layers move w i th d i f fe ren t
ve loc i t i es , where there a re f r i c t iona l fo rces tha t invo lves oppos ing
th is mot ion . Thus , d iss ipa t ion o f some o f the energy occurs . The
quan t i t y tha t descr ibes to what ex ten t th i s happens in a cer ta in f lu id
i s ca l led v iscos i t y der i ves f rom the La t in word “v i scum” fo r m is t le toe
(v i scous g lue , made f rom ber r ies and was used to coa t l ime- tw igs to
ca tch b i rds . V iscos i t y , o r common ly symbo l i zed as Ƞ i s a f lu id
p roper ty wh ich ind ica tes how res is tan t tha t f l u id i s to f l ow. V iscos i t y
p roper t ies can a lso be though t o f as an in te rna l res is tance to f low
p rocesses .
Indus t r ia l app l i ca t ions h igh ly depend on the p roper t ies o f the
mate r ia ls used such as v iscos i t y , dens i t y and d i f fus iv i t y . Ma jo r i t y o f
many p lan t opera t ions invo lved gases and l i qu ids .
A l though i t i s o f ten supposed tha t the thermodynamic
p roper t ies o f gases and l i qu ids a re known w i th accuracy su f f i c ien t
fo r v i r tua l l y a l l t echno log ica l purposes , th is i s no t in fac t the case .
A l though such p roper t ies can somet imes be es t imated f rom
thermodynamic mode ls , i t i s o f ten essen t ia l to measure key
p roper t ies in o rder to va l ida te o r op t im ise the ava i lab le mode ls .
Fur thermore , the deve lopment o f new mode ls i s dependent to a la rge
ex ten t upon the ava i lab i l i t y o f appropr ia te exper imenta l da ta .
2 | P a g e
AIMS / OBJECTIVES
The exper iment i s conduc ted in o rder to a t ta in a few ob jec t i ves
wh ich i s to de te rmine the v iscos i t y o f gases w i th p ressure d i f fe rence ,
to conc lude the dependency o f gases and l i qu ids w i th tempera tu re
and p ressure , to compare the theore t i ca l va lues o f v i scos i t y o f gases
and l i qu ids w i th exper imenta l va lues ob ta ined , to de te rmine the
v iscos i t y o f l i qu ids w i th bo th tempera tu re and p ressure d i f fe rence , as
we l l as to be ab le to ana lyze the e f fec t o f tempera tu re and buoyancy
on the p roper t ies .
THEORY
Viscos i t y i s the res is tance a mate r ia l has to change in fo rm.
H igh ly v i scous l i qu ids , l i ke moto r o i l o r mo lasses , take much longer
f l ow f rom the i r con ta iner than a re la t i ve ly low v iscos i t y l i qu id , l i ke
benzene o r d ie thy l e ther . To quan t i f y v i scos i t y , we w i l l imag ine our
bu lk f l u id as cons is t ing o f a number o f ve ry th in layers . In o rder fo r
the f lu id to f l ow, a fo rce w i l l be requ i red to s l ide these layers
re la t i ve to one ano ther . The amount o f fo rce ( f ) requ i red i s assumed
to be d i rec t l y p ropor t iona l to the a rea ( A) o f the layers in con tac t
w i th one ano ther and the ve loc i t y d i f fe rence ( υ ) be tween the layers .
Fur thermore , the fo rce i s inverse ly p ropor t iona l to the d is tance ( d )
be tween the layers . V iscos i t y ( η ) can then be in t roduced as a
cons tan t o f p ropor t iona l l y , y ie ld ing a fo rce equa t ion o f the fo rm
3 | P a g e
. . . . . . . . . . . . . . . . . (1 )
D imens iona l ana lys is o f equa t ion (1 ) g ives S I Un i t s fo r
v i scos i t y o f kg m - 1 s - 1 . However , the un i t tha t i s t yp ica l l y emp loyed
in p rac t i ce i s ca l led the 'po ise ' ( P ) , where 1 P = 1 g ram cm - 1 s - 1 .
L iqu id v iscos i t ies a re usua l l y repor ted in ‘ cen t ipo ise , ’ cP , and gas
v iscos i t y a re repor ted in ‘m ic ropo ise , ’ μP .
The v iscos i t y depends on tempera tu re , dens i t y , and p ressure .
L ikew ise , in so -ca l led non-Newton ian f lu ids , the v iscos i t y a lso
depends on o ther fac to rs fo r ins tance ; so -ca l led th ixo t rop ic l i qu ids
such as ke tchup and concre te have a lower v iscos i t y when they a re
ag i ta ted . A t tempts to ca lcu la te v iscos i t ies f rom the s ta t i s t i ca l
p roper t ies o f the f lu id a re success fu l on ly fo r s imp le f lu ids (such as
nob le gases a t low p ressure ) . For these s imp le f lu ids , one f inds tha t
the v iscos i t y inc reases w i th inc reas ing tempera tu re . For mos t
l i qu ids , however , the tempera tu re dependence i s oppos i te , and the
v iscos i t y decreases w i th tempera tu re , as shown in the f igu re be low.
4 | P a g e
Viscos i t y in fac t i s bas ica l l y re fe r red to laminar f l ow. The
mo lecu les nex t to the sur face where a f lu id o r gas i s f l ow ing over i t
have zero speed . The speed inc reases w i th the d is tance f rom the
mo lecu les to the sur face . Th is d i f fe rence in speed shows the f r i c t ion
exer ted on the gas and l i qu id , where each mo lecu les be ing pushed
pas t each o ther . Thus , v i scos i t y de te rmines the amount o f f r i c t ion ,
wh ich in tu rn de te rmines the amount o f energy absorbed by the f low.
I t has been we l l known tha t the v iscos i t y o f l i qu id wate r
exh ib i t s d i f fe ren t behav iour f rom o ther o rd inary l i qu ids . Many
empi r i ca l equa t ions wh ich were app l ied to l i qu id wate r fa i led to
p red ic t the exac t va lue o f the v iscos i t y . However , some re fe rence
books show tha t the va lue o f v i scos i t y o f l i qu id i s 0 .3000 Ns /m 2 o r
0 .03 P . Meanwh i le , the va lue o f v i scos i t y o f a i r i s 1 .87 x 10 - 5 Ns /m 2
o r 1 .87 x 10 - 6 P .
On ly s ign i f i can t s t ruc tu re theory o f v i scos i t y had f i t ted the
v iscos i t y o f l i qu id wate r w i th success by assuming tha t the so l id - l i ke
5 | P a g e
vo lume was summed up to the mo le f rac t ion o f the i ce mix tu re . On
the o ther hand , the v iscos i t y o f wa te r vapour canno t be ca lcu la ted
success fu l l y by the p rev ious theory and any o ther v i scos i t y
equa t ions wh ich descr ibe the l i qu id s ta te . There fo re , no theory o f
v i scos i t y can be app l i cab le fo r bo th l i qu id wate r and wate r vapour .
There a re a few fac to rs tha t in f luence the v iscos i t y va lue o f a
f l u id . Cer ta in ly the s t reng th o f in te rmo lecu la r a t t rac t ions has an
in f luence ; n i t ro benzene has a much h igher v i scos i t y than regu la r
benzene because the fo rmer i s capab le o f d ipo le -d ipo le a t t rac t ions
wh ich a re cons iderab ly s t ronger than the d ispers ion fo rces o f
a t t rac t ion p resen t in bu lk benzene. Other fac to rs inc lude the s ize
and shape o f mo lecu les o f the respec t i ve f lu id .
As ment ioned ear l ie r , v i scos i t y va r ies w i th tempera tu re ,
genera l l y decreas ing as a tempera tu re i s inc reased . Th is occurs due
to the inc reased k ine t i c mot ion a t h igher tempera tu res p romotes the
b reak ing o f in te rmo lecu la r bonds be tween ad jacen t layers . A
cons iderab le amount o f research has been car r ied ou t in an a t tempt
to unders tand the exac t na tu re o f tempera tu re var ia t ion o f v i scos i t y .
One re la t i ve ly s imp le mode l assumes tha t the v iscos i t y obeys an
‘A r rhen ius - l i ke ’ equa t ion o f the fo rm;
. . . . . . . . . . . . . . . . . . . (2 )
where A and E a a re cons tan ts fo r a g iven f lu id . A i s ca l led the p re -
exponent ia l fac to r and E a can be in te rp re ted as the ac t i va t ion energy
fo r v i scous f low. No te tha t th i s express ion i s near l y iden t i ca l to the
Ar rhen ius equa t ion tha t descr ibes the tempera tu re var ia t ion o f the
ra te cons tan t ( k ) o f a chemica l reac t ion , excep t equa t ion (3 ) does
6 | P a g e
not have a nega t i ve s ign in the exponent ia l wh ich causes the
v iscos i t y to ge t sma l le r w i th inc reas ing tempera tu re .
There i s a lso ano ther method o f ca lcu la t ion wh ich invo lves
v iscos i t y o f a l i qu id tha t f l ows in a cy l ind r i ca l tube . The theory tha t
i s a lso known as Po iseu i l l e ’ s Law is an express ion fo r the f low ra te
Q ( i n m 3 / s ) i n te rms o f the v iscos i t y Ƞ , t he rad ius R ( i n m) o f the
p ipe , i t s leng th L ( i n m) , and the p ressure d i f fe rence ∆p t u b e ( in Pa)
over the leng th o f the o f the f low;
Q = πR 4 ∆p t u b e
8ȠL . . . . . . . . . . . . . . . . . (3 )
When the f lu id en te rs the p ipe i t has to be acce le ra ted , and
energy conserva t ion requ i res tha t th i s i s assoc ia ted w i th a p ressure
d rop . Thus , on ly a f rac t ion o f the to ta l p ressure d i f fe rence ∆p
be tween in take and ou t le t o f the p ipe i s ava i lab le fo r ∆p t u b e . F rom
Bernou l l i ’ s Law and the fac t tha t the f low ra te i s the a rea o f the
c ross sec t ion t imes the average f low ve loc i t y v , o r Q = πR 2 v , one
der i ves eas i l y tha t
∆p t u b e = ∆p – ρQ 2 _
2π 2 R 4 . . . . . . . . . . . . . . . . (4 )
where ρ ( i n kg /m 3 ) i s the dens i t y o f the f lu id . Inser t ing Equat ion (4 )
in to Equat ion (3 ) and so lv ing fo r Ƞ , y ie lds the equa t ion we need to
ana lyze in th is exper iment ;
. . . . . . . . . . . . . . . . . . . . . (5 )
7 | P a g e
The re la t ionsh ip be tween t ime, t , and change in manometer
leve l can be ca lcu la ted by us ing the fo l low ing express ion ;
t =
8 LV ° μ
P A a4 π ln
(PA+P2 ) (PA−P1)(PA−P2) (PA+P1) .....................(6)
where t = t ime o f exper iment (s )
µ = v iscos i t y (Ns /m 2 )
L = leng th o f tube (0 .5 m)
V 0 = vo lume o f the vesse l (0 .0193 m 3 )
a = rad ius o f tube (0 .000575 m)
P 1 = in i t i a l p ressure (N /m 2 )
P 2 = f ina l p ressure (N /m 2 )
P A = A tmospher ic p ressure (N /m 2 )
The p ressure can be ca lcu la ted by us ing the fo l low ing express ion ;
P = ρgh . . . . . . . . . . . . . . . . . . . . . . (7 )
where ρ = dens i t y o f manometer f l u id (kg /m 3 )
g = acce le ra t ion due to g rav i t y (9 .81 m/s 2 )
h = he igh t o f mercury (m)
George S toke ’s Law o f V iscos i t y es tab l i shed the sc ience o f
hydrodynamics . I t i nvo lves se t t l i ng o f sphere and a lso der i va t ions o f
8 | P a g e
var ious f low re la t ionsh ips rang ing f rom wave mechan ics to v i scous
res is tance . S tokes came ou t w i th a fo rmu la tha t can p red ic t the ra te
a t wh ich a sphere fa l l s th rough a v iscous gas o r l i qu id .
As a mat te r o f fac t , the to ta l fo rces on a par t i c le mov ing in a
f lu id cons is t o f two par ts , wh ich a re sk in f r i c t ion and a lso d rag
fo rmat ion . Sk in f r i c t ion occurs due to the shear ing o f a l i qu id
whereas d rag fo rmat ion i s a resu l t f rom the fo rmat ion o f a wake
beh ind the par t i c le and cor respond ing d iss ipa t ion o f energy . Bo th
fo rces depend upon ra te a t wh ich the par t i c le i s t rave l l i ng . Sk in
f r i c t ion i s p redominan t in v i scous range wh i le d rag fo rmat ion i s
p redominan t in tu rbu len t range .
When a spher ica l par t i c le moves in a f lu id , i t w i l l acce le ra te
un t i l t he ne t downward fo rce i s ba lanced by the upward d rag fo rce .
Ne t t downward fo rce =
43π ( d3 )
3
( ps−p )g
=
π3d3( ps−p )
..................(8)
Net t upward fo rce = 3πȠdv
=
π3d3( ps−p )
......................(9)
9 | P a g e
Thus , the te rmina l se t t l i ng ve loc i t y laminar f l ow reg ion ;
V t =
d2g18 μ
( ps−p ) ................(10)
where d = d iameter o f sphere (m)
g = acce le ra t ion due to g rav i t y (9 .81 m/s 2 )
µ = v iscos i t y o f f l u id (kg /s .m)
ρ s = dens i t y o f sphere (kg /m 3 )
ρ = dens i t y o f f l u id (kg /m 3 )
Th is ve loc i t y i s te rmina l ve loc i t y the sphere w i l l a t ta in fa l l i ng
th rough the l i qu id o r gas . The equa t ion above works i f the mot ion i s
s low enough to keep the f lows in laminar domain . Once the speeds
inc rease pas t a l im i t , the d rag g rows a t la rge ra tes . Somet imes i t i s
necessary to f i gu re ou t i f t he dominan t va r iab le i s the v iscous f low o r
ine r t ia l f l ow.
10 | P a g e
EXPERIMENTAL PROCEDURE
Part A: Determinat ion of v iscosi ty o f gas
1. Th is exper iment i s se t up w i th the con t ro l tap c losed on the
cap i l l a ry tube .
2 . The vesse l i s evacua ted by open ing the vacuum con t ro l va lve to
i t s max imum l im i ts , and the p ressure d i f fe rence on the
manometer in mm Hg i s recorded .
3 . The vacuum pump va lve i s c losed and the con t ro l tap i s
exhaus ted to a tmosphere , th i s i s c losed a t 10 seconds in te rva ls
and the manometer read ing i s recorded .
Part B: Determinat ion of the v iscosi ty o f l iqu id
1. Ba l l bear ing i s a l lowed to fa l l d i f fe ren t known d is tance in a
ver t i ca ls co lumn o f l i qu id , he ld a t a cons tan t tempera tu re .
2 . The hea t ing f lu id i s s low ly c i rcu la ted th rough the tes t ce l l f rom
the thermos ta t i c ba th and i t s tempera tu re i s measured .
3 . The c i rcu la t ion o f f l u id th rough the tes t ce l l i s commenced f rom
the thermos ta t i c ba th a t a p rede te rmined low tempera tu re un t i l
t he tempera tu re reg is te red a t the top o f ce l l rema ins cons tan t .
4 . The thermometer i s then removed and a ba l l bear ing i s inser ted
in to the top o f v i scometer tube .
5 . The s top i s s ta r ted when the ba l l passes the top mark on the
co lumn and i s s topped when the ba l l passes the bo t tom mark .
6 . The d is tance be tween these marks i s p r in ted on the g lass and
the re la t i ve te rmina l ve loc i t y cou ld there fo re be de te rmined .
11 | P a g e
7. The dens i t y o f the f lu id and sphere mus t be de te rmined and the
v iscos i t y o f the f lu id a t the p rede te rmined tempera tu re i s
ca lcu la ted f rom the laminar f l ow re la t ionsh ips .
APPARATUS
Par t A : De te rmina t ion o f the v iscos i t y o f gas
1 . The Armf ie ld Proper t ies o f gases and l i qu id appara tus
2 . S topwatch
Par t B : De te rmina t ion o f the v iscos i t y o f l i qu id
1 . V iscometer
12 | P a g e
2. Vern ie r sca le
3 . S tand and c lamp
4. S topwatch
5 . Sphere bear ing
6 . G lycer ine (g lycero l )
RESULT
Par t A : De te rmina t ion o f v i scos i t y o f gas
T ime
(s )
Pressure , P 1
(h 1 )
P ressure , P 2
(h 2 )
P ressure d i f fe rence ,
∆P (mmhg)
ln (h 1 / h 2 )
0 445 158 287 1.035
10 415 188 227 0.792
20 389 214 175 0.598
30 367 236 131 0.442
40 350 253 97 0.325
50 337 266 71 0.237
60 327 276 51 0.170
70 320 283 37 0.123
80 315 288 27 0.090
90 311 292 19 0.063
13 | P a g e
Par t B : De te rmina t ion o f v i scos i t y o f l i qu id
H i g h o f
b a l l
b e a r i n g
f a l l i n g
( m m )
T i m e ( s )
1 s t r e a d i n g
T i m e ( s )
2 n d r e a d i n g
T i m e ( s )
3 r d r e a d i n g
T i m e ( s )
A v e r a g e
V e l o c i t y , v
( m / s )
2 2 0 4 . 8 5 6 . 2 2 6 . 0 6 5 . 7 1 0 . 0 3 9
2 0 0 4 . 5 6 7 . 0 6 5 . 7 8 5 . 8 0 0 . 0 3 5
1 7 5 5 . 6 8 4 . 1 3 4 . 2 5 4 . 6 9 0 . 0 3 7
1 0 0 1 . 5 9 2 . 0 6 2 . 4 7 2 . 0 4 0 . 0 4 9
2 5 0 . 7 2 0 . 5 6 0 . 6 8 0 . 6 5 0 . 0 3 9
Dens i t y o f g lycer in , ρ = 1261 kg /m 3
Dens i t y o f ba l l , ρ s = 1130631.213 kg /m 3
Diameter o f ba l l bear ing = 0 .6184 x 10 - 3 m
Mass o f ba l l bear ing = 0 .14 x 10 - 3 kg
SAMPLE CALCULATION
Par t A : De te rmina t ion o f v i scos i t y
Atmospher ic pressure ,P A
= ρgh
= 13580(kg /m 3 ) x 9 .81(m/s ) x 0 .76(m)
= 101247.048 (kg /s .m)
= 101247.048 (N /m 2 )
Pressure a f ter 10 seconds,P 1
= 13580(kg /m 3 ) x 9 .81(m/s ) x 0 .227(m)
= 30240.89 (kg /s .m)
= (101247.048 - 30240 .89) (N /m 2 )
14 | P a g e
= 71006.158 (N /m 2 )
Pressure a f ter 80 seonds,P 2
= 101247.048 – [13580(kg /m 3 ) x 9 .81(m/s ) x 0 .027 (m) ]
= 97650.118 (N /m 2 )
T ime, t
= ( t 2 – t 1 )
= 80s – 10s
= 70s
Thus , by app ly ing equa t ion (6 ) , the v iscos i t y o f a i r can now be
ca lcu la ted .
t =
8 LV ° μ
P A a4 π ln
(PA+P2 ) (PA−P1)(PA−P2) (PA+P1)
70 = ( (8×0.5×0.0193×μ )(101247.048× (0.000575 )4
×π ))ln
((101247.048+97650.118 )(101247.048−71006.158)(101247.048−97650.118 )(101247.048+71006.158))
µ = 1.387 x 10-5 Ns/m2
0 10 20 30 40 50 60 70 80 90 1000
0.2
0.4
0.6
0.8
1
1.2ln (h1/h2) versus time,t (s)
Time,t (s)
15 | P a g e
Ln (h1/h2)
Par t B : De te rmina t ion o f v i scos i t y o f l i qu id
Veloc i ty o f sphere
= average ve loc i t y
= (0.039+0.035+0.037+0.049+0.0395 )(m/s )
= 0 .0398 m/s
Thus , Vt
0.0398 =
d2g18 μ
( ps−p )
0.0398 = (( 0.6184×10−3 )2×9.8118 μ ) (1130631.213−1261 )
µ = 5.914 Ns/m2
SAMPLE ERROR CALCULATION
Par t A : De te rmina t ion o f v i scos i t y o f gas
The theore t i ca l va lue fo r v i scos i t y o f wa te r i s 1 .87x10 - 5 Ns /m 2 .
Never the less , the va lue ob ta ined f rom the exper iment has a
s ign i f i can t d i f fe rence w i th the theore t i ca l va lue , wh ich i s
1 .387x10 - 5 Ns /m 2 . Thus , we can ca lcu la te the percen tage o f e r ro r ,
as shown above .
16 | P a g e
Percen tage e r ro r = ((1.87×10−5 )−(1.387×10−5)1.87×10−5 ) (×100 % )
= 25 .83 %
DISCUSSION
The exper iment i s conduc ted based on a few ob jec t i ves wh ich
inc lude de te rmin ing the v iscos i t y o f gas and l i qu id and compar ing
i t w i th the theore t i ca l va lue as we l l as s tudy ing the e f fec t o f
tempera tu re and p ressure to the v iscos i t y o f gas and l i qu id .
The va lue o f v i scos i t y o f gas ca lcu la ted based on the
exper imenta l resu l t s i s 1 .387x10 - 5 Ns /m 2 . Never the less , th i s va lue
compr ises a lmos t 30 percen tage o f e r ro r f rom the theore t i ca l
va lue . There fo re , the re mus t have been a lo t o f m is takes and
e r ro rs dur ing the exper iment tha t lead to such e r roneous va lue .
F i rs t l y , the read ing fo r the p ressures on the manometer i s on ly
done once fo r each 10 seconds o f in te rva l . There fo re , we a re no t
ab le to ge t average va lue fo r each in te rva l in o rder to ge t more
accura te va lues .
Second ly , the manometer i s o ld and the sca le on th is
ins t rument i s overshadowed w i th co r ros ion , mak ing i t d i f f i cu l t to
read the mercury leve l on the lower p ressure s ide . Thus , the
read ing recorded may no t be the cor rec t and ac tua l va lues .
Th i rd ly , the va lve i s supposed ly c losed a f te r every 10 seconds
be fo re read ing the p ressures ind ica ted on the manometer .
17 | P a g e
However , i t may no t be c losed a t abso lu te ly a f te r the requ i red
in te rva l .
Nex t , the mercury leve ls observed on the manometer in
be tween 60 to 90 seconds a re vary ing up and down qu i te rap id ly ;
the re fo re i t i s d i f f i cu l t to observe the accura te read ing .
The v iscos i t y o f gas i s p ropor t iona l to the tempera tu re , thus as
the tempera tu re i s e leva ted , the v iscos i t y inc reases as we l l . Th is
i s in f luenced to the k ine t i c energy o f the gas mo lecu les . As
tempera tu re inc reases , the mo lecu les o f gas wh ich a re a l ready
fu r ther apar t tend to move rap id ly and thus , the k ine t i c energy
inc reases . The mo lecu les a re co l l i d ing w i th each o ther , and thus
the in te rmo lecu la r fo rces a re no longer neg l ig ib le . Hence , i t
conc ludes tha t the gas i s becoming more v iscous as the
tempera tu re i s ge t t ing h igher . However , v i scos i t y o f gas i s
depend ing on p ressure and no t tempera tu re . As what i s imp l ied
on Po iseu i l l e ’ s Law, the v iscos i t y i s based on the p ressure d rop .
Accord ing to mos t re fe rence books , the v iscos i t y o f l i qu id i s a t
approx imate ly 0 .300 Ns /m 2 . Th is i s way d i f fe ren t w i th the
exper imenta l resu l t ob ta ined , wh ich i s a lmos t 6 Ns /m 2 . However ,
as what has been ment ioned in Theory sec t ion ear l ie r , the
v iscos i t y o f l i qu id i s no t easy to be ca lcu la ted and the exac t va lue
i s d i f f i cu l t to be p red ic ted .
Dur ing the exper iment , i t i s becoming more d i f f i cu l t to record
the t ime taken fo r the ba l l bear ing to move pass the g lycero l a t
decreas ing d is tance requ i red . Th is i s due to the fac t tha t the
c loser the d is tance , the fas te r the ba l l bear ing to reach to the
bo t tom.
18 | P a g e
Next , the eyes o f the observer may no t be para l le l to the sca le
wh ich ind ica tes the d is tance requ i red to record the t ime taken fo r
the ba l l bear ing to reach the bo t tom. There fo re , the resu l t s
recorded a re a f fec ted as we l l .
When tempera tu re i s inc reased , the v iscos i t y o f l i qu id w i l l
dec reased . Th is i s because , the par t i c les o f l i qu id a re mov ing
away f rom each o ther . Thus , the v iscos i t y i s decreased , as the
ba l l bear ing i s mov ing fas te r . V iscos i t y o f l i qu id i s p roven to be
dependent o f tempera tu re .
CONCLUSION
The ob jec t i ves o f th i s exper iment i s sa t i s f ied w i th the va lue o f
v i scos i t y o f gas i s 1 .387x10 - 5 Ns /m 2 whereas the v iscos i t y o f
l i qu id i s 5 .914 Ns /m 2 . A l though the va lues a re d i f fe r ing much w i th
the theore t i ca l va lues , i t i s conc luded tha t v i scos i t y o f gas i s
depend ing upon tempera tu re . When tempera tu re inc reases , the
v iscos i t y a lso inc reases . On the con t ra ry , v i scos i t y o f l i qu id i s
decreas ing in inc reas ing tempera tu re . Thus , i t i s p ressure
depend ing , wh ich i s based on the p ressure d rop .
RECOMMENDATION
I n o rder to ge t more accura te va lue , the read ing fo r mercury
leve l i s necessar i l y taken to a t leas t th ree t imes . Bes ides tha t ,
the manometer shou ld be changed o r mon i to red p roper ly as i t i s
19 | P a g e
t he mos t impor tan t par t o f the appara tus . Th is goes the same w i th
the exper iment conduc ted in Par t B , where the t ime record ing
shou ld be done more than th ree t imes , a t leas t 7 read ings . Thus ,
the average va lue w i l l be more conv inc ing and minor m is takes
migh t no t a f fec t much on the ca lcu la ted va lue .
REFERENCE
* CHEMISTRY-THE CENTRAL SCEINCE (n in th ed i t ion ) -BROWN. LEMAY.BURSTEN
* A BREIF INTRODUCTION OF FLUID MECHANICS(seconds ed i t ion ) -DONALD F .YOUNG-BRUCE R.MUNSON-THEODORE H. OKI ISHI
* Cou lson & R ichardson (1997) , Chemica l Eng ineer ing (Vo l 1 ) , Pergammon Press
APPENDICES
20 | P a g e
21 | P a g e