production of synthetic fuels using electrolysis

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Production of Syhthetic Fuels using Electrolysis Shital Das PhD Superviors: Mogens Mogensen, Peter V. Hendriksen, John B. Hansen, Sune D. Ebbesen

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The objective of this study is to investigate in depth the technical and economic feasibility of producing synthetic hydrocarbon fuels from synthesis gas, which is formed by high temperature (600 – 1000 degC) electrolysis of steam and CO2 using the solid oxide electrolyser cell (SOEC). Furthermore, catalytic conversion of synthesis gas into a number of fuels is a well-known industrial process. The vision behind the project is that renewable energy (e.g. electricity from wind turbines) may be converted into synthetic fuels such as methane (CH4), methanol (CH3OH) or dimethyl ether (DME). Synthetic fuel made from renewable energy may become interesting when fossil fuels become scarcer in the future. A conceptual process model is developed based on experimental results from our laboratory and open literature. This work demonstrates that production of DME from electrolysis derived synthesis gas is technically feasible.

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Page 1: Production of Synthetic Fuels Using Electrolysis

Production of Syhthetic Fuels using Electrolysis

Shital Das

PhD Superviors: Mogens Mogensen, Peter V. Hendriksen, John B. Hansen, Sune D. Ebbesen

Page 2: Production of Synthetic Fuels Using Electrolysis

2 Risø DTU, Technical University of Denmark

Renewable Energy: Demand and Supply Mismatch

Curtsey: Anne Hauch

Page 3: Production of Synthetic Fuels Using Electrolysis

3 Risø DTU, Technical University of Denmark

Possibilities to Capture and Use CO2

C. Graves, et al. Renewable and Sustainable Energy Reviews 15 (2011) 1-23

Page 4: Production of Synthetic Fuels Using Electrolysis

4 Risø DTU, Technical University of Denmark

Renewable Energy: Demand and Supply – Closing the Mismatch

PowerPlant

CHP

Boiler

Transport

Elec.demand

Districtheating demand

Individualheating

Heatstorage

WindPower

Fuel

Fuel

Fuel

Electrolyser/ H2 Storage

Brian Vad Mathiesen, Fuel Cells and electrolysers in future energy systems, PhD Thesis, Aalborg University

Synthetic fuels are used for heating and electricity

Page 5: Production of Synthetic Fuels Using Electrolysis

5 Risø DTU, Technical University of Denmark

Renewable Energy: Demand and Supply Closing the Mismatch

Brian Vad Mathiesen, Fuel Cells and electrolysers in future energy systems, PhD Thesis, Aalborg University

PowerPlant

CHP

Boiler

Transport

Elec.demand

Districtheating demand

Individualheating

Heatstorage

WindPower

Fuel

Fuel

Fuel

Electrolyser/ H2 Storage

Synthetic fuels are used for transportation

Page 6: Production of Synthetic Fuels Using Electrolysis

6 Risø DTU, Technical University of Denmark

Dimethyl Ether (DME) as Transportation Fuel

Lower greenhouse gas (CO2 and NOx) and soot emission

Can be used in present diesel engine technology with some modification

Comparable engine efficiency with diesel

Page 7: Production of Synthetic Fuels Using Electrolysis

7 Risø DTU, Technical University of Denmark

How to Split CO2 and H2O?

Building block for any synthetic fuel synthesis

Synthesis gas

Page 8: Production of Synthetic Fuels Using Electrolysis

8 Risø DTU, Technical University of Denmark

Concept of SOEC stack

Page 9: Production of Synthetic Fuels Using Electrolysis

9 Risø DTU, Technical University of Denmark

Proposed DME synthesis process

Page 10: Production of Synthetic Fuels Using Electrolysis

10 Risø DTU, Technical University of Denmark

Abundant renewable energy can be used in SOEC to convert steam and CO2 to synthesis gas, which can

catalytically be converted to dimethyl ether.