processing and applications of metals and cer
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Presentation
on
Advances
in
Material Science
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Rank Country/Region 2007 2008
World World 1,351.3
1China People's
Republic of China494.9 500.5
EU European
Union 209.7 198.0
2 Japan Japan 120.2 118.7
3
United
States United
States
98.1 91.4
4 Russia Russia 72.4 68.5
5 India India 53.1 55.2
http://www.absoluteastronomy.com/topics/Worldhttp://www.absoluteastronomy.com/topics/People's_Republic_of_Chinahttp://www.absoluteastronomy.com/topics/People's_Republic_of_Chinahttp://www.absoluteastronomy.com/topics/European_Unionhttp://www.absoluteastronomy.com/topics/European_Unionhttp://www.absoluteastronomy.com/topics/Japanhttp://www.absoluteastronomy.com/topics/United_Stateshttp://www.absoluteastronomy.com/topics/United_Stateshttp://www.absoluteastronomy.com/topics/Russiahttp://www.absoluteastronomy.com/topics/Indiahttp://www.absoluteastronomy.com/topics/Indiahttp://www.absoluteastronomy.com/topics/Russiahttp://www.absoluteastronomy.com/topics/United_Stateshttp://www.absoluteastronomy.com/topics/United_Stateshttp://www.absoluteastronomy.com/topics/Japanhttp://www.absoluteastronomy.com/topics/European_Unionhttp://www.absoluteastronomy.com/topics/European_Unionhttp://www.absoluteastronomy.com/topics/People's_Republic_of_Chinahttp://www.absoluteastronomy.com/topics/People's_Republic_of_Chinahttp://www.absoluteastronomy.com/topics/World -
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The ability of metals to resist corrosion is to some extent dependent
upon their position in the electrochemical series
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Metal Ion Reactivity Extraction
K K+
reacts with water
electrolysis
Na Na+
Li Li+
Sr Sr2+
Ca Ca2+
Mg Mg2+
reacts with acidsAl Al3+
C included for comparison
Zn Zn2+
reacts with acidssmelting
with coke
Cr Cr2+
Fe Fe2+
Cd Cd2+
Co Co2+
Ni Ni2+
Sn Sn2+
Pb Pb2+
H2 H+ included for comparison
Cu Cu2+may react with
some
strongly oxidizin
g acids
heat or
physical
extraction
Ag Ag+
Hg Hg2+
Au Au3+
Pt
Going from bottomto top, the metals:
increase in reactivity;
lose electrons more
readily to form
positive ions;
corrode or tarnish
more readily;
require more energy
(and differentmethods) to be
separated from their
ore
http://en.wikipedia.org/wiki/Potassiumhttp://en.wikipedia.org/wiki/Waterhttp://en.wikipedia.org/wiki/Sodiumhttp://en.wikipedia.org/wiki/Lithiumhttp://en.wikipedia.org/wiki/Strontiumhttp://en.wikipedia.org/wiki/Calciumhttp://en.wikipedia.org/wiki/Magnesiumhttp://en.wikipedia.org/wiki/Acidhttp://en.wikipedia.org/wiki/Aluminiumhttp://en.wikipedia.org/wiki/Carbonhttp://en.wikipedia.org/wiki/Zinchttp://en.wikipedia.org/wiki/Smeltinghttp://en.wikipedia.org/wiki/Coke_(fuel)http://en.wikipedia.org/wiki/Chromiumhttp://en.wikipedia.org/wiki/Ironhttp://en.wikipedia.org/wiki/Cadmiumhttp://en.wikipedia.org/wiki/Cobalthttp://en.wikipedia.org/wiki/Nickelhttp://en.wikipedia.org/wiki/Tinhttp://en.wikipedia.org/wiki/Leadhttp://en.wikipedia.org/wiki/Hydrogenhttp://en.wikipedia.org/wiki/Copperhttp://en.wikipedia.org/wiki/Oxidizing_acidhttp://en.wikipedia.org/wiki/Oxidizing_acidhttp://en.wikipedia.org/wiki/Silverhttp://en.wikipedia.org/wiki/Mercury_(element)http://en.wikipedia.org/wiki/Goldhttp://en.wikipedia.org/wiki/Platinumhttp://en.wikipedia.org/wiki/Platinumhttp://en.wikipedia.org/wiki/Goldhttp://en.wikipedia.org/wiki/Mercury_(element)http://en.wikipedia.org/wiki/Silverhttp://en.wikipedia.org/wiki/Oxidizing_acidhttp://en.wikipedia.org/wiki/Oxidizing_acidhttp://en.wikipedia.org/wiki/Copperhttp://en.wikipedia.org/wiki/Hydrogenhttp://en.wikipedia.org/wiki/Leadhttp://en.wikipedia.org/wiki/Tinhttp://en.wikipedia.org/wiki/Nickelhttp://en.wikipedia.org/wiki/Cobalthttp://en.wikipedia.org/wiki/Cadmiumhttp://en.wikipedia.org/wiki/Ironhttp://en.wikipedia.org/wiki/Chromiumhttp://en.wikipedia.org/wiki/Coke_(fuel)http://en.wikipedia.org/wiki/Smeltinghttp://en.wikipedia.org/wiki/Zinchttp://en.wikipedia.org/wiki/Carbonhttp://en.wikipedia.org/wiki/Aluminiumhttp://en.wikipedia.org/wiki/Acidhttp://en.wikipedia.org/wiki/Magnesiumhttp://en.wikipedia.org/wiki/Calciumhttp://en.wikipedia.org/wiki/Strontiumhttp://en.wikipedia.org/wiki/Lithiumhttp://en.wikipedia.org/wiki/Sodiumhttp://en.wikipedia.org/wiki/Waterhttp://en.wikipedia.org/wiki/Potassium -
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They may be tempered and hardened. Martensite gives steel greathardness, but it also reduces its toughness and makes it brittle, so few
steels are fully hardened.
Martensite is not shown in the equilibrium phase diagram of the iron-carbon
system because it is not an equilibrium phase. Equilibrium phases form by slow
cooling rates allowing sufficient time for diffusion, whereas martensite is usually
formed by fast cooling rates
Too much martensite leaves steel brittle, too little leaves it soft
http://en.wikipedia.org/wiki/Phase_diagramhttp://en.wikipedia.org/wiki/Brittlenesshttp://en.wikipedia.org/wiki/Hardnesshttp://en.wikipedia.org/wiki/Hardnesshttp://en.wikipedia.org/wiki/Brittlenesshttp://en.wikipedia.org/wiki/Phase_diagramhttp://en.wikipedia.org/wiki/Phase_diagramhttp://en.wikipedia.org/wiki/Phase_diagram -
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(Fe) accounts for more than 95% by weigh, Carbon and Silicon are
other alloying elements
Applications of grey cast irons: gears, flywheels, water pipes,
engine cylinders, brake discs, gears
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White cast iron is named after its white surface when fractured,
due to its carbideimpurities which allow cracks to pass straight
through.
White cast iron C 3.4, Si 0.7, Mn 0.6
Applications of white cast irons: brake shoes, shot blasting nozzles, mill
liners, crushers, pump impellers and other abrasion resistant parts.
http://en.wikipedia.org/wiki/Carbidehttp://en.wikipedia.org/wiki/Carbide -
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Ductile or nodular iron C 3.4, P 0.1, Mn 0.4,Ni 1.0, Mg 0.06
http://en.wikipedia.org/wiki/Nickelhttp://en.wikipedia.org/wiki/Nickel -
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Malleable iron (ASTM A47) C 2.5, Si 1.0, Mn 0.55
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Die Casting
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Continuous Casting
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CO2
+ C ---> 2 CO
Reaction of Cementite to Carbon
Monoxide:
2 CO + 3 Fe --->Fe3C + CO
2
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1 % C i di b l f
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1. % C in medium carbon steels ranges from _____________.
(a) 0.30.4 (b) 0.30.5 (c) 0.30.6 (d) None
2. Stainless steel is so called because of its ________________.
(a) High strength (b) High corrosion resistance (c) High ductility (d) Brittleness
3. In white cast irons, carbon present as ________________.(a) Graphite flakes (b) Graphite nodules (c) Cementite (d) Carbon does not exist
4. Refractory metal
(a) Ag (b) W (c) Pt (d) Ni
5. Not a noble metal
(a) Cu (b) Ag (c) Au (d) Pt
6. Noble metal
(a) Al (b) Ag (c) Mo (d) W
7. Usual casting method for making dental crowns
(a) Sand casting (b) Die casting (c) Continuous casting (d) Investment casting
8. Prime structural disadvantage of P/M products
(a) Low density (b) Porosity (c) High damping capacity (d) None
9. Not an important heat treatment process parameter
(a) Heating rate (b) Temperature (c) Cooling rate (d) Atmosphere
10. Final structure of austempered steel
(a) Pearlite (b) Ferrite + graphite (c) Bainite (d) Martensite
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11. The following statement is true for Explosive forming
a. Very large sheets with relatively complex shapes, although usually
axisymmetric can be formed
b. Low tooling costs, but high labor cost
c. Suitable for low-quantity productiond. All
12. The Drawing Operation is
a. Shallow or deep parts with relatively simple shapes
b. High production rates
c. High tooling and equipment costsd. All
13. Cold-working metal forming is performed at a temperature above the
recrystallization
a. True b False
14 The most widely used drill is the general-purpose twist drill, which has
many variations. The flutes
on a twist drill are helical and are not designed for cutting but for
removing chips from the hole.
a. True b. False
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Thank You