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PROCESS MODERNIZATION - PROCESS SAFETY Dust Explosion Hazards Ashok Ghose Dastidar, PhD MBA Vice President, Dust & Flammability Testing and Consulting Services

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Page 1: PROCESS MODERNIZATION - PROCESS SAFETY...PROCESS MODERNIZATION - PROCESS SAFETY Dust Explosion Hazards Ashok Ghose Dastidar, PhD MBA Vice President, Dust & Flammability Testing and

PROCESS MODERNIZATION - PROCESS SAFETY

Dust Explosion Hazards

Ashok Ghose Dastidar, PhD MBA Vice President, Dust & Flammability

Testing and Consulting Services

Page 2: PROCESS MODERNIZATION - PROCESS SAFETY...PROCESS MODERNIZATION - PROCESS SAFETY Dust Explosion Hazards Ashok Ghose Dastidar, PhD MBA Vice President, Dust & Flammability Testing and

2 Proprietary property of Fauske & Associates, LLC

Disclosure

There may be references to products and/or services that are offered by Fauske & Associates, LLC (FAI)

throughout this presentation

Please note that these references are not intended as a solicitation of FAI (or other’s) products and services; but rather to provide the information and anecdotal

scenarios needed to possibly prevent hazardous situations, and for your operations to be as

safe as possible

Page 3: PROCESS MODERNIZATION - PROCESS SAFETY...PROCESS MODERNIZATION - PROCESS SAFETY Dust Explosion Hazards Ashok Ghose Dastidar, PhD MBA Vice President, Dust & Flammability Testing and

3 Proprietary property of Fauske & Associates, LLC

Ashok Ghose Dastidar

B.Sc. Chemistry – Dalhousie University MBA – Saint Mary’s University Master of Applied Science – Technical University of Nova

Scotia Ph.D. Chemical Engineering– Dalhousie University 22 years research in the field of dust & gas/vapor explosions Safety Consulting Engineers, Inc. 2001-2007 Fauske & Associates, LLC 2007- Memberships – AIChE, ASTM, NFPA Editorial Advisory Board of Powder/Bulk Solids and Journal

of Loss Prevention in the Process Industries Chairperson of the ASTM E27.05 Subcommittee on Dust

Explosion Test Methods

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4 Proprietary property of Fauske & Associates, LLC

Presentation Topics

Introduction Review Of Recent Dust Explosions Hazard Identification Material Characterization Hazard Mitigation Questions And Answers

Page 5: PROCESS MODERNIZATION - PROCESS SAFETY...PROCESS MODERNIZATION - PROCESS SAFETY Dust Explosion Hazards Ashok Ghose Dastidar, PhD MBA Vice President, Dust & Flammability Testing and

5 Proprietary property of Fauske & Associates, LLC

Dust Explosions What Are They?

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6 Proprietary property of Fauske & Associates, LLC

Dust Fires & Explosions

Like all fires, a dust fire occurs when fuel (the combustible dust) is exposed to heat (an ignition source) in the presence of oxygen (air)

Removing any one of these elements of the classic fire triangle eliminates the possibility of a fire

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7 Proprietary property of Fauske & Associates, LLC

Dust Fires & Explosions (continued)

Dust explosions require the presence of two additional elements –

dust dispersion and confinement

Suspended dust burns more rapidly and confinement allows for pressure buildup; removal of

either the suspension or the confinement elements prevents an explosion, although a fire

may still occur

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8 Proprietary property of Fauske & Associates, LLC

Introduction

Dust explosions are a serious hazard in process industries - Loss of land, labor and capital

Current state – (key findings from U.S. Chemical Safety & Hazards Investigations Board (USCSB) report)

At least 281 combustible dust fires and explosions occurred in general industry between 1980 and 2005, which - Caused at least 119 fatalities and 718 injuries in the United

States - Occurred in a wide range of industries and involved many types

of combustible dusts - Currently NO national standard for worker protection; OSHA

has 29CFR 1910.272 (1987)

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9 Proprietary property of Fauske & Associates, LLC

Introduction (continued)

Consensus standards, developed by the NFPA, that provide detailed guidance for preventing and mitigating dust fires and explosions are widely considered to be effective, however: - These standards are voluntary, unless adopted as part of a fire

code by a state or local jurisdiction — and have not been adopted in many states and local jurisdictions, or have been modified - NFPA standards are part of the International Fire Code and Uniform

Fire Code - Also, some regions have adopted NFPA 1: FIRE CODE – see Chapter

40 - These codes are also Recognized And Generally Accepted Good

Engineering Practices (REGEGAP)

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10 Proprietary property of Fauske & Associates, LLC

Review of Historical Dust Explosions

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11 Proprietary property of Fauske & Associates, LLC

Turin, Italy December 14th, 1785

Count Morozzo – Academy of Science of Turin (1795)

Bakers Shop/Flour Warehouse - Two injuries; one had burns from the fire,

the other jumped to get away and broke his leg

Lessons Learned - Worried about fermentation gases –

known issue with flour warehouses at the time

- Determined dust ignited - Fuel = flour - Oxidizer = air - Ignition source = lamp or ES - Dispersion = dropping flour on floor - Confinement = room

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12 Proprietary property of Fauske & Associates, LLC

Grain Dust Explosions in USA

Inland Grain Terminal, St. Joseph, MO, April 1980 - Killed 1 person - Injured 4 - $ 2 M - Electric arc from damaged level

indicator in one of the silos. Explosion traveled though head house to other silos

River Grain Terminal, St. Paul, MN, June 1980 - No fatalities - 13 injured - $300K - Electrician working on live electrical while

loading operations were taking place - Explosion traveled along tunnel to head

house and then to bucket elevators and on into other tunnels

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13 Proprietary property of Fauske & Associates, LLC

Grain Dust Explosions in USA (continued)

Train-Loading Country Grain Terminal, Fonda, IA, July 1980 - No fatalities or injuries - $ 30 K - Electrical welding on a bucket elevator.

Hot work as ignition source. Traveled to other bucket elevators

Large Export Grain Silo Plant, Corpus Christi, TX, April 1981 - 9 killed - 30 injured - $30 M - Smoldering lumps of grain entering

bucket elevator. - Propagated to other elevators – head

house – tunnels – silos and conveyers OSHA 29CFR 1910.272 in 1987

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14 Proprietary property of Fauske & Associates, LLC

Review of Recent Dust Explosions

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15 Proprietary property of Fauske & Associates, LLC

West Pharmaceutical Services, Inc.

North Carolina, 2003 Plastic molding

manufacturer Polyethylene powder 6 workers killed Hundreds of injuries Plant destroyed Facility was the major

employer in area

Source: U.S. Chemical Safety & Hazards Investigations Board (USCSB)

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16 Proprietary property of Fauske & Associates, LLC

CTA Acoustics, Inc.

Kentucky, 2003 Acoustic board

manufacturer Phenolic resin dust 7 workers killed 37 injuries

Source: USCSB

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17 Proprietary property of Fauske & Associates, LLC

Hayes Lemmerz International, Inc.

Indiana, 2003 Aluminum casting

facility Aluminum dust 1 worker killed Several injuries

Source: USCSB

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18 Proprietary property of Fauske & Associates, LLC

Hayes Lemmerz International, Inc.

Source: USCSB

Source: USCSB

Source: USCSB

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19 Proprietary property of Fauske & Associates, LLC

Fugitive Dust Buildup Cause of Secondary Explosions

Source: USCSB

Source: USCSB Source: USCSB

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20 Proprietary property of Fauske & Associates, LLC

Imperial Sugar

Georgia, 2008 Agricultural industrial

facility Sugar dust 14 workers killed 38 Injuries Milling and packaging

Source: USCSB

Source: USCSB

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21 Proprietary property of Fauske & Associates, LLC

Fugitive Dust Buildup Cause of Secondary Explosions

Source: USCSB

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22 Proprietary property of Fauske & Associates, LLC

The “ Typical” Explosion Event

Process Equipment

Initial Internal Deflagration

0 25 50 75 100 125 150 175 200 225 250 275 300 325

Time, msec.

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23 Proprietary property of Fauske & Associates, LLC

The “Typical” Explosion Event (continued)

Process Equipment

Initial Internal Deflagration Initial Internal Deflagration

0 25 50 75 100 125 150 175 200 225 250 275 300 325

Time, msec.

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24 Proprietary property of Fauske & Associates, LLC

The “Typical” Explosion Event (continued)

Process Equipment

Initial Internal Deflagration

Initial Internal Deflagration

0 25 50 75 100 125 150 175 200 225 250 275 300 325

Time, msec.

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25 Proprietary property of Fauske & Associates, LLC

Explosion Types

Primary explosion – usually in process equipment

A primary dust explosion occurs when a dust suspension within a container, room or piece of equipment is ignited and explodes

A secondary explosion occurs when dust accumulated on floors or other surfaces is lifted into the air and ignited by the primary explosion

Source: USCSB

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26 Proprietary property of Fauske & Associates, LLC

Fugitive Dust Buildup

Source: USCSB

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27 Proprietary property of Fauske & Associates, LLC

Process Equipment

Initial Internal Deflagration Initial Internal Deflagration

The “Typical” Explosion Event (continued)

0 25 50 75 100 125 150 175 200 225 250 275 300 325

Time, msec.

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28 Proprietary property of Fauske & Associates, LLC

Process Equipment

Containment Failure from

Initial Deflagration

The “Typical” Explosion Event (continued)

0 25 50 75 100 125 150 175 200 225 250 275 300 325

Time, msec.

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29 Proprietary property of Fauske & Associates, LLC

Process Equipment

Secondary Deflagration

Initiated

The “Typical” Explosion Event (continued)

0 25 50 75 100 125 150 175 200 225 250 275 300 325

Time, msec.

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30 Proprietary property of Fauske & Associates, LLC

The “Typical” Explosion Event (continued)

Process Equipment

Secondary Deflagration Propagates

Through Interior

0 25 50 75 100 125 150 175 200 225 250 275 300 325

Time, msec.

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31 Proprietary property of Fauske & Associates, LLC

The “Typical” Explosion Event (continued)

Process Equipment

Secondary Deflagration Vents from Structure

0 25 50 75 100 125 150 175 200 225 250 275 300 325

Time, msec.

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32 Proprietary property of Fauske & Associates, LLC

The “Typical” Explosion Event (continued)

Secondary Deflagration Causes Collapse and Residual Fires

0 25 50 75 100 125 150 175 200 225 250 275 300 325

Time, msec.

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33 Proprietary property of Fauske & Associates, LLC

Hazard Identification

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34 Proprietary property of Fauske & Associates, LLC

Five elements needed to support a citation There has to be:

- A hazardous condition - A violation of an OSHA standard (or the general duty clause) - Employee (or subcontractor) exposure - Employer knowledge (of the condition - NOT that it was a

violation of the law), and - A feasible abatement

OSHA’s Mission

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35 Proprietary property of Fauske & Associates, LLC

OSHA Has Promised Enforcement

In a top-down fashion, using 64 SIC codes with inspections and citations utilizing the GDC

Over 1,500 combustible dust inspections have been conducted since the NEP inception

Over 9,000 violations! Most citations have been by way of the Hazard Communication Standard and the Housekeeping Standard

Penalties have brought in millions of dollars

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36 Proprietary property of Fauske & Associates, LLC

The OSHA Inspection Plan for Combustible Dust

Appendix B of the dust inspection program identifies a number of questions to be asked by the OSHA inspector during an inspection focused on combustible dust

Any inquiry into combustible dust hazards must utilize Recognized and Generally Accepted Good Engineering Practices (RAGAGEP) - NFPA 654

- Any number of additional questions suggested by the facility operations, activities and environment

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37 Proprietary property of Fauske & Associates, LLC

1. What Types of Combustible Dust Does the Facility Have

OSHA will test the dust at the lab Additional (less reliable) sources

- MSDS sheets - Supplier data sheets and advice - Table 4.5.2 of NFPA 499 - Table 1 in NMAB 353-3

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38 Proprietary property of Fauske & Associates, LLC

2. Does the Facility Have a Housekeeping Program with Regular Cleaning Frequencies

Is it established for floors and horizontal surfaces, such as ducts, pipes, hoods, ledges and beams to minimize dust accumulations?

Is the dust on floors, structural members and other surfaces removed concurrently with operations?

Is there dust accumulation of 1/32 inch thick or greater? What are the dimensions of

- The room - The area covered with the dust

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39 Proprietary property of Fauske & Associates, LLC

Fugitive Dust Accumulations

Depth of Dust Accumulation (in.) Frequency Housekeeping Requirements Area Electrical

Classification

< 1/32 Continuous / frequent

Clean up as necessary to maintain an average accumulation below 1/64 in.

Unclassified; however, electrical enclosures should be dust tight

1/32 to 1/8 Infrequent Clean up during same shift Unclassified; however, electrical enclosures should be dust tight

1/32 to 1/8 Continuous / frequent

Clean as necessary to maintain an average accumulation below 1/16 in. Class II, Division 2

> 1/8 Infrequent Immediately shut down and clean Class II, Division 2

> 1/8 Continuous / frequent

Clean at frequency appropriate to minimize accumulation Class II, Division 1

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40 Proprietary property of Fauske & Associates, LLC

3. Are the Dust-Containing Systems Properly Designed

Are the dust-containing systems (ducts and dust collectors) designed (so) that fugitive dusts are not allowed to accumulate in the work area?

No fugitive dust

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41 Proprietary property of Fauske & Associates, LLC

4. Are Dust Collectors Greater Than 8 Cubic Feet in Volume Located Inside of Buildings

Outside location Engineered containment Venting to outside Suppression

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42 Proprietary property of Fauske & Associates, LLC

Do such areas have explosion relief venting distributed over the exterior walls of buildings and enclosures

Is such venting directed to a safe location away from employees

5. If Dust Explosion Hazards Exist in Rooms, Buildings or Other Enclosures

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43 Proprietary property of Fauske & Associates, LLC

Chokes Flame front diverters Rotary valves Automatic fast-acting valves Chemical isolation systems

6. Are There Isolation Devices to Prevent Deflagration Propagation Between

Pieces of Equipment Connected by Ductwork

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44 Proprietary property of Fauske & Associates, LLC

7. Is There an Ignition Control Program

Is there an ignition control program (grounding and bonding and other methods of dissipating electrostatic charge for ductwork)?

NFPA 77 for Electrostatic Hazards

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45 Proprietary property of Fauske & Associates, LLC

Separators - Magnets

• Permanent • Electromagnets with power indicator

- Pneumatic - Grating devices

8. Are There Separator Devices to Remove Foreign Materials

Capable of Igniting Combustible Dusts

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46 Proprietary property of Fauske & Associates, LLC

Such as sweepers or vacuum cleaners used in dusty areas See 1910.307 Hardware Store “Shop-vacs” are not permitted in classified

locations

9. Are Electrically-Powered Cleaning Devices Approved for the Hazard Classification

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47 Proprietary property of Fauske & Associates, LLC

10. Is Smoking Permitted Only in Safe Designated Areas

Are areas where smoking is prohibited posted with "No Smoking" signs?

Rules followed in all locations? How often do you audit? How often do you train employees and contractors?

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48 Proprietary property of Fauske & Associates, LLC

11. Is the Exhaust From the Dust Collectors Recycled

NFPA 654 (2006) - Requires discharge to a restricted area, away from intakes - Recycling to the pneumatic conveying system is permitted

Return to building air prohibited where - Recycle air at < 99.9% efficiency of 10 µm - Return of energy from a fire or explosion - Recycle of air where hybrid mixtures, gases or vapors are

involved - Recycling of exhaust that reduces building air to < 19.5% oxygen

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49 Proprietary property of Fauske & Associates, LLC

12. Does Dust Collector System Have Protection

Does the dust collector system have spark detection and explosion/deflagration suppression systems?

Are they sized properly? Do you have documentation and engineering designs? There are alternative measures covered later in this lecture

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50 Proprietary property of Fauske & Associates, LLC

Big: PVC or other similar duct materials are powerful static accumulators — and combustible, as well

Transparent view ports may - Disrupt electrical continuity - Generate static

Temporary expedients can be a hazard Note: Dust collector bags are typically combustible

13. Are All Components of the Dust Collection System

Constructed of Noncombustible Materials

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51 Proprietary property of Fauske & Associates, LLC

Various requirements ~18m/s – 1068 m/min 3560 ft/min Higher velocities may be required for denser

dusts/powders How often do you audit? Alarms or warnings for low velocity?

14. Are Ducts Designed to Maintain Sufficient Velocity to Ensure

the Transport of Both Coarse & Fine Articles

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52 Proprietary property of Fauske & Associates, LLC

Conductive parts can be: - Grounded individually - Bonded together and grounded

See NFPA 77 How often do you audit? Is it mentioned on your PM schedule? On training documents?

15. Are Duct Systems, Dust Collectors & Dust-Producing Machinery Bonded & Grounded

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53 Proprietary property of Fauske & Associates, LLC

Worth repeating!!! PVC plastic or other similar duct materials are powerful static

accumulators — and combustible, as well

16. Is Metal Ductwork Used

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54 Proprietary property of Fauske & Associates, LLC

ES and IS calculations KSt, Pmax, MEC, MIE and MIT data Compare with PPC Looking at Class II Division 1 and Division 2 locations May wish to look at European Zone 20, 21 and 22

classification - ATEX requirements in place for decades – rated equipment

readily available

17. In Areas Where a Hazardous Quantity of Dust Accumulates or is Present in Suspension in the Air,

Does all Electrical Wiring & Equipment Comply with (1910.307) Requirements

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55 Proprietary property of Fauske & Associates, LLC

18. Does Dust Collector System Have Protection

NFPA 654 requires a hot work permit system for all - Cutting and welding - Grinding, chipping - Other operations that produce sparks or open flame - Use of cartridge activated tools

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56 Proprietary property of Fauske & Associates, LLC

Intent is to not exceed the capabilities of the fire protection system

Metal bins are typical In corrosive environments and for some

other process reasons - Bins may be fabricated from combustible

high density plastic • Polyethylene or Polypropylene

- Product must not be static generation (triboelectric)

19. Are Bulk Storage Containers Constructed of Noncombustible Materials

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57 Proprietary property of Fauske & Associates, LLC

For static generating dusts Small particle size What to do

- Bonding and grounding

20. Does the Company Use Methods to Dissipate Static

Electricity, Such as by Bonding & Grounding

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58 Proprietary property of Fauske & Associates, LLC

Initial training Refresher Procedures — operations, maintenance and emergency Know about Management of Change (MOC) policies and

issues Audit knowledge? How often?

21. Are Employees Who are Involved in Operating, Maintaining &

Supervising Facilities That Handle Combustible Dust Trained in the Hazards of the Combustible Dust

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59 Proprietary property of Fauske & Associates, LLC

Hazards Orientation and safety rules Operations and upsets Fire and explosion protection Maintenance and housekeeping Emergency response plans Management of Change (MOC)

Operations, Supervisory & Maintenance Staff Need to Know

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60 Proprietary property of Fauske & Associates, LLC

Must be available May not be accurate Employees trained in their use? Audit knowledge? How often?

22. Are MSDS’ for the Chemicals Which Could Become Combustible Dust

Under Normal Operations Available to Employees

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61 Proprietary property of Fauske & Associates, LLC

Where Do Combustible Dust Incidents Happen?

Furniture

& Fixtures

4%

Equipment Manufacturing

7% Fabricated

Metal Products

7%

Other 7%

Electric Services

8%

Rubber & Plastic Products

8%

Primary Metal

Industries 8%

Food Products

24%

Lumber & Wood

Products 15%

Chemical Manufacturing

12%

Source: FM Global

Insurance Company Perspective

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62 Proprietary property of Fauske & Associates, LLC

What Materials Are Involved in Combustible Dust Incidents?

Food 23%

Wood 24%

Metal 20%

Plastic 14%

Coal 8%

Inorganic 4%

Other 7%

Source: FM Global

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63 Proprietary property of Fauske & Associates, LLC

Components of a Combustible Dust Program

1) Management of Change Program 2) Process Hazard Analysis 3) Housekeeping Plan 4) Mitigation of the Hazard 5) Maintenance and Inspection 6) Employee Training

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64 Proprietary property of Fauske & Associates, LLC

“Management of Change” Requirement

Management of Change: Written procedures — to manage change to process materials, technology, equipment, procedures and facilities — shall be established and implemented

The Management of Change procedures shall ensure that the following issues are addressed prior to any change - The technical basis for the proposed change - The safety and health implications - Whether the change is permanent or temporary - Modifications to operating and maintenance procedures - Employee training requirements - Authorization requirements for the proposed change

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65 Proprietary property of Fauske & Associates, LLC

Collect Relevant

Data

Conduct Facility Walk-Through

Start Hazard Evaluation

Risk Assessment

Devise and Implement Hazard Mitigation Plans

Process (Dust) Hazard Analysis

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66 Proprietary property of Fauske & Associates, LLC

What is Included in a Process (Dust) Hazard Analysis?

The design of the processes and facilities shall consider the physical and chemical properties that establish the hazardous characteristics of the materials

The design of the fire and explosion safety provisions shall be based on a process hazard analysis of the facility, the process and the associated fire or explosion hazards

The results of the process hazard analysis shall be documented and maintained for the life of the process

The process hazard analysis shall be reviewed and updated, at least every 5 years

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67 Proprietary property of Fauske & Associates, LLC

Housekeeping Requirements for Dust Control

Continuous suction, to minimize the escape of dust, shall be provided for processes where combustible dust is liberated

The dust shall be conveyed to dust collectors Equipment shall be maintained and operated in a manner

that minimizes the escape of dust Regular cleaning frequencies shall be established, within

operating areas of the facility, to minimize dust accumulation - Dust layers on floors, walls and horizontal surfaces less than

1/32” - Use of safe cleaning methods and devices

Surfaces shall be cleaned in a manner that minimizes the generation of dust clouds

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68 Proprietary property of Fauske & Associates, LLC

Housekeeping Requirements for Cleaning

Cleaning methods that produce dust clouds — such as vigorous sweeping or blowing down with steam or compressed air — shall be permitted only if the following requirements are met - The area and equipment shall be vacuumed, prior to blow down,

with low pressure steam or compressed air - Electrical equipment not suited for Class II locations, and other

sources of ignition, shall be shut down or removed from the area (avoid hot surfaces)

- Only a low gauge pressure steam or compressed air — not exceeding a gauge pressure of 15 psi (103 kPa) — shall be used

- No hot surfaces or flames that are capable of igniting a dust cloud or layer shall exist in the area

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69 Proprietary property of Fauske & Associates, LLC

Components of a Combustible Dust Program

Mitigation of the hazard - Covered in the next section

Maintenance and inspection - Written schedules and logs - Primarily looking at ignition source control

Employee training - Dust explosion awareness - How their operations can affect dust explosion safety

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70 Proprietary property of Fauske & Associates, LLC

Material Characterization

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71 Proprietary property of Fauske & Associates, LLC

Combustible Particulate Solid

Any combustible solid material composed of distinct particles or pieces; regardless of size, shape or chemical composition (NFPA 654-2013)

Includes dusts, fines, fibers, flakes, chips, chunks, or a mix of these

Model building codes (e.g. International Building Code — do not have a definition

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72 Proprietary property of Fauske & Associates, LLC

Dust

Traditionally defined as a solid 420 - 500 µm or smaller Combustible dust is a particulate solid that presents a fire or

deflagration hazard when suspended in air or oxidizing atmosphere over a range of concentrations, regardless of shape or size

Definitions are confusing because they are used interchangeably with combustible particulate solid

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73 Proprietary property of Fauske & Associates, LLC

NFPA Dust Hazard Standards

NFPA publishes 5 occupancy standards that are focused on dust explosion hazards - NFPA 652

• NFPA 654

• NFPA 61

• NFPA 664

• NFPA 484

• NFPA 655

NFPA publishes 7 design standards referenced in the 5 occupancy standards - NFPA 68

- NFPA 69

- NFPA 91

- NFPA 13

- NFPA 15

- NFPA 72

- NFPA 70 – NEC • NFPA 499

• NFPA 77

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74 Proprietary property of Fauske & Associates, LLC

NFPA Standards

NFPA 652: Standard on the Fundamentals of Combustible Dust (2016) - New overall standard covering dust explosions

- Addresses theoretical/fundamental aspects of dust explosibility and combustibility

- The “shadow” Correlating Committee then pushes down the requirements to the industry specific standard

- Industry specific standard can adopt or reject with reason

- The industry specific standard is enforced

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75 Proprietary property of Fauske & Associates, LLC

Future Framework

NFPA 652

NFPA 68, 69, 70 etc.

NFPA 61 NFPA 484 NFPA 664 NFPA 654

ASTM

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76 Proprietary property of Fauske & Associates, LLC

Explosion Severity (Pmax and KSt) ASTM E1226

Determined in a 20-L or 1-m³ chamber Indication of the severity of an explosion Data used in the design of explosion protection devices

- Pmax = maximum pressure

- KSt = (dP/dt)max × V⅓

New addition of “Go/No Go” explosibility screening test

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77 Proprietary property of Fauske & Associates, LLC

20-L Siwek Test Chamber

10 kJ ignition source Source: Fauske & Associates, LLC

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78 Proprietary property of Fauske & Associates, LLC

1-m³ FAI Chamber

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79 Proprietary property of Fauske & Associates, LLC

Pmax Maximum Explosion Overpressure Generated in the Test Chamber

Used to design enclosures and predict the severity of the consequence - The higher the number the more severe the dust deflagration

will be • If an enclosure is constructed to withstand this pressure failure,

explosion venting or suppression is not required

Dust Pmax Dust Pmax

Sugar 8.5 Aluminum 12.4

Cellulose 9.7 Magnesium 17.5

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80 Proprietary property of Fauske & Associates, LLC

KSt Normalized Rate of Pressure Rise of a Combustible Dust

Different for every dust, and determined only by testing NFPA and OSHA require that each dust be tested and documented; the use of industry standards or other generic data is not allowed - Any dust with a KSt >0 requires a documented process analysis

and explosion protection - The same dust can have different KSt

- The higher the number the more “explosive” the dust is

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81 Proprietary property of Fauske & Associates, LLC

Hazard Classes of Dust Deflagration – Based on KSt

Hazard Class

KSt (bar-m/sec) Example

St-1 < 200 Bronze 31

Bituminous Coal 129 Sugar 138

St-2 200-300 Cork 202

Cellulose 229 Phenolic Resin 269

St-3 >300 Aluminum Dust 415 Magnesium 508

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82 Proprietary property of Fauske & Associates, LLC

Minimum Explosible Concentration (MEC) ASTM E1515

Lowest dust concentration that will propagate an explosion - Analogous to the Lower Flammability Limit (LFL) for gas/air

mixtures

- The lower the number, the less dispersed dust required for a dust deflagration

Dust MEC

(g/m³) Dust MEC (g/m³)

Sugar 200 Aluminum 30

Cellulose 80 Magnesium 30

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83 Proprietary property of Fauske & Associates, LLC

Industrial hygiene levels lower than explosible range Dust deposits are above explosible range, but may move

down MEC concentrations achievable if dust is present in large

quantities

Minimum Explosible Concentration (MEC) ASTM E1515

(continued)

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84 Proprietary property of Fauske & Associates, LLC

Limiting Oxygen Concentration (LOC) ASTM E2931

Minimum quantity of oxygen required to propagate an explosion - Dust concentration independent - Data can be used to develop an inerting strategy - Start at optimal concentration - Once established, test several other concentrations to verify

Limiting the oxygen concentration of the air surrounding the dust is a method of explosion control

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85 Proprietary property of Fauske & Associates, LLC

Limiting Oxygen Concentration (LOC) ASTM E2931

(continued)

This can be achieved by inerting the atmosphere with non-flammable gas - (nitrogen, carbon dioxide, argon)

Dust Diameter (μm) LOC (%)

Aluminum 22 5

Anthracite coal 17 14

Sulfur 30 7

Wood 27 10

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86 Proprietary property of Fauske & Associates, LLC

Minimum Ignition Energy (MIE) ASTM E2019

Predicts the ease and likelihood of ignition of a dispersed dust cloud

MIE of a flammable dust is the minimum spark energy needed to ignite an ideal concentration under lab conditions - A capacitive discharge spark is used for this test

- Test can be run with or without inductance

- Compared to typical ES ignition sources

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87 Proprietary property of Fauske & Associates, LLC

Minimum Ignition Energy (MIE) ASTM E2019

(continued)

Source: Fauske & Associates, LLC

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88 Proprietary property of Fauske & Associates, LLC

Minimum Ignition Energy (MIE) ASTM E2019

(continued)

Examples: sugar (powdered) 30 mJ, paper dust 20-60 mJ, aluminum 50 mJ, magnesium 40 mJ

MIE (mJ) Recommended Precaution per BS 5958

500 Low sensitivity to ignition; ground plant below this level 100 Consider grounding personnel below this level 25 The majority of ignition incidents occur below this level

10 High sensitivity to ignition. Consider restrictions on the use of high resistivity non-conductors below this level

1 Extremely sensitive to ignition at this level. Handling operations should be such that they minimize the possibility of suspending the powder in air.; dissipate or discourage charge operations

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89 Proprietary property of Fauske & Associates, LLC

Minimum Autoignition Temperature of a Dust Cloud (MIT) ASTM E 1491

Measures the sensitivity to hot surfaces and environments - Hot surfaces in dryers,

bearings and mechanical parts

- Friction spark ignition with MIE data

- Maximum exposure temperature Source: Fauske & Associates, LLC

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90 Proprietary property of Fauske & Associates, LLC

Autoignition Temperature of a Dust Layer (LIT) ASTM E2021

Sensitivity to ignition on hot surfaces - Other side room

temperature

Longer exposure time (1 - 2 hr) - LIT is typically lower than

MIT • Some materials melt

before reacting - Not a true minimum since

layer thickness affects results

Source: Fauske & Associates, LLC

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91 Proprietary property of Fauske & Associates, LLC

Typical Ignition Temperature of Materials

Material

Mean Particle

Size (µm)

MIT Cloud (°C)

AIT Layer (°C)

ABS 200 480 450

Aluminum 70 560 450

Iron 32 520 450

Melamine Resin 56 470 500

Coffee 10 470 450

Wood Dust 14 420 335

PVC emulsion 73 700 450

Data from BGIA

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92 Proprietary property of Fauske & Associates, LLC

Characterizing a Dust’s Hazard

Deposited Dust Dust in Cloud Form Smoldering Gases

Chemical Composition

Heat of Combustion

Melting Point

Sample Modification

Ignitability

Flammability

Ignition Temp. on Hot Surface

Self-Ignition Properties

Exothermic Decomposition

Impact Sensitivity

Electrostatic Properties

Explosible / Nonexplosible

Min. Explosion Dust Concentration

Minimum Ignition Energy

Max. O2 Conc. For Inerting

Max. Explosion Pressure

Max. Rate of Pressure Rise Properties of Hybrid Clouds

(Explosible Gas Mixed w/Dust)

Electrostatic Properties

Ignitability o f Gas

Explosibiltiy of Gas

Minimum Smoldering Temperature of Dust

Sample Splitting

Overall Test Sample

Particle Size Distribution

Moisture Content

Identification

Original Dust Sample

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93 Proprietary property of Fauske & Associates, LLC

Dust Explosion & Fire Characteristics

Variables effecting output - Dust properties

• (type, size and exposed surface area) - Nature of oxidative atmosphere

• (sensitivity to oxygen or other oxidizer) - Dispersion mechanisms

• (lofting of powder – light or fine powders stay lofted)

- Type / magnitude and location of ignition • (low energy ignition or self ignition – fine powder)

- Nature of confinement • (volume, yield strength and initial pressure)

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94 Proprietary property of Fauske & Associates, LLC

Hazard Mitigation

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95 Proprietary property of Fauske & Associates, LLC

Mitigation of the Combustible Dust Hazard

Hazard mitigation methods include - Dust control with an effective

housekeeping program - Containment and removal of

combustible dust - Process equipment and facility

design - Ignition source control

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96 Proprietary property of Fauske & Associates, LLC

Targeted Strategy to Handle Combustible Dust Hazards

Equipment protection - Ignition source avoidance - Oxidant concentration reduction - Fuel concentration reduction - Deflagration venting - Deflagration pressure containment - Deflagration suppression systems - Isolation of equipment

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97 Proprietary property of Fauske & Associates, LLC

Sources of Ignition

Ignition sources that can be effective, by way of proper work practice controls - Smoking - Open flames - Open light (bulbs) - Welding - Abrasive cutting - Grinding - Anti-static clothing

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98 Proprietary property of Fauske & Associates, LLC

Sources of Ignition (continued)

Ignition sources that are part of the process - Open flames - Hot surfaces on process and electrical equipment - Smoldering or burning conveyed process materials - Mechanical impact creating heat or sparks - Electric sparks from equipment - Electric sparks from electrostatic discharges - Exothermic reactions

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99 Proprietary property of Fauske & Associates, LLC

Explosion Prevention Systems: Passive Vents

Source: Fike Source: Rembe

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100 Proprietary property of Fauske & Associates, LLC

Explosion Protection Systems: Flameless Vent

(continued)

Source: Rembe

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101 Proprietary property of Fauske & Associates, LLC

Deflagration Chemical Suppression for a Dust Collector

Fireball

Pressure Wave

Ignition Occurs

Explosion Detected

Suppression begins

Suppression continues

Extinguisher Detector

Time: 20 msec 0 msec 30 msec 40 msec 80 msec

Suppressant

Total Suppression

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102 Proprietary property of Fauske & Associates, LLC

Deflagration Propagation With Vent but Without Isolation

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103 Proprietary property of Fauske & Associates, LLC

Deflagration Propagation Using Flame Front Diversion

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104 Proprietary property of Fauske & Associates, LLC

Explosion Prevention Systems: Passive Inlet Isolation

Source: Rembe

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105 Proprietary property of Fauske & Associates, LLC

Isolation Barriers – Chemical & Mechanical

Source: Fike

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106 Proprietary property of Fauske & Associates, LLC

Deflagration Propagation Using Mechanical Isolation

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107 Proprietary property of Fauske & Associates, LLC

Explosion Prevention Systems: Isolation by Suppression

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108 Proprietary property of Fauske & Associates, LLC

Deflagration Propagation Using Chemical Suppression for Isolation

Source: NFPA

CYCLONE

CHEMICAL SUPPRESSOR

DUST COLLECTOR

IGNITION POINT

VENT

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109 Proprietary property of Fauske & Associates, LLC

The End