presentationofdelawaresectionawardtodr.cecilr.dybowski ...$10 per person for students for...

8
Nonprofit Organization U.S. Postage PAID WILMINGTON, DE 19850 Permit No. 1602 Published by the Delaware Section of the American Chemical Society P.O. Box 711 – Montchanin, DE 19710 C C ALENDAR ALENDAR OF OF E E VENTS VENTS January 22 ChemVets Meeting January 30 Section Awards Dinner, Blue and Gold Club February 1 Process Spectroscopy Topical Group/Society for Applied Spectroscopy Meeting, Agilent Little Falls Site February 22 Section Meeting, Iron Hill Brewery March 6 Science Café, Tavern at the Blue and Gold Club March 22 Carothers Award Banquet, DuPont Country Club April 6 Delaware Academy of Sciences’Three Legends Luncheon, DuPont Country Club April 22 Earth Day Section Meeting, location TBA Volume 65/1 For information on section activities visit our web site at: http://membership.acs.org/d/del/ JANUARY 2008 Presentation of Delaware Section Award to Dr. Cecil R. Dybowski Presentation of Tillmanns-Skolnik Award to Dr. Michael A. Stemniski Wednesday, January 30, 2008 Blue and Gold Club University of Delaware delchem Jan 08:DC 12/17/07 7:41 PM Page 02

Upload: others

Post on 27-Jun-2020

2 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: PresentationofDelawareSectionAwardtoDr.CecilR.Dybowski ...$10 per person for students For reservations or additional information: Please cont act Sujata Bhatia at: sujata.k.bhatia@usa.dupont.com

Nonprofit

Organization

U.S.

Posta

ge

PA

IDWILMINGT

ON,D

E19850

Perm

itNo

.1602

Pub

lish

edby

the

Del

awar

eSe

ctio

nof

the

Am

eri

can

Ch

em

ica

lS

oci

ety

P.O

.Box

711

–M

ontc

hani

n,D

E19

710

CCALENDAR

ALENDAR

OF

OFEEVENTS

VENTS

January22

ChemVetsMeeting

January30

Section

Awards

Dinner,BlueandGoldClub

February

1ProcessSpectroscopyTopicalGroup/Societyfor

Applied

SpectroscopyMeeting,A

gilentLittleFallsSite

February

22Section

Meeting,IronHillBrewery

March

6Science

Café,Tavern

attheBlueandGoldClub

March

22CarothersAwardBanquet,D

uPontCountry

Club

April6

DelawareAcademyofSciences’Three

Legends

Luncheon,DuPontCountry

Club

April22

EarthDay

Section

Meeting,locationTBA

Volume 65/1

For information on section activities visit our web site at:h t t p : / / m emb e r s h i p . a c s . o r g / d / d e l /

JANUARY 2008

Presentation of Delaware Section Award to Dr. Cecil R. Dybowski

Presentation of Tillmanns-Skolnik Award to Dr. Michael A. Stemniski

Wednesday, January 30, 2008

Blue and Gold ClubUniversi ty of Delaware

delchem Jan 08:DC 12/17/07 7:41 PM Page 02

Page 2: PresentationofDelawareSectionAwardtoDr.CecilR.Dybowski ...$10 per person for students For reservations or additional information: Please cont act Sujata Bhatia at: sujata.k.bhatia@usa.dupont.com

DEL-CHEM BULLETIN – JANUARY 2008 152 DEL-CHEM BULLETIN – JANUARY 2008

DuPont Analytical SolutionsFrom rapid, routine testing to complex problem-solving. Oneof the world’s largest, and most diverse analytical laboratories,with the experience to solve your analytical challenges in:

Electronic Materials • Personal Care • Catalysis • Coatings, Pigments, and AdhesivesSpecialty Chemicals • Films and Packaging • Pharmaceuticals • Plastics • Fibers • Textiles

DuPont Analytical Solutions email: [email protected]. Box 80302 web: http://DASolutions.dupont.comWilmington, DE 19880-0302 FAX: (302) 695-1717Phone: (302) 695-1018

Contact us for all your analytical needs.

– same day service

delchem Jan 08:DC 12/17/07 7:41 PM Page 04

Page 3: PresentationofDelawareSectionAwardtoDr.CecilR.Dybowski ...$10 per person for students For reservations or additional information: Please cont act Sujata Bhatia at: sujata.k.bhatia@usa.dupont.com

DEL-CHEM BULLETIN – JANUARY 2008 314 DEL-CHEM BULLETIN – JANUARY 2008

CHAIR’S COLUMNCHAIR’S COLUMNDEL-CHEM BulletinEDITOR

Sheree R. Gold(610) 485-3479

Inter Media Consultants

ADVERTISING MANAGERVince Gale(781) 837-0424MBO Services

DELAWARE SECTION OFFICERSSujata Bhatia . . . . . . . . . . . . . . . . . . . . . . . .Chair

(302) 738-7250 [email protected]

Narmada Gunawardena . . . . . . . . . . . . Past Chair(302) 885-9516 AstraZeneca

[email protected] Qi . . . . . . . . . . . . . . . . . . . Chair-Elect

(302) 695-1660 [email protected]

John Gavenonis . . . . . . . . . . . . . . Secretary(302) 999-5600 DuPont

[email protected] Wang . . . . . . . . . . . . . . . . . . . .Treasurer

(302) 885-6138 [email protected]

DIRECTORSWayne Brubaker

(302) 695-4178 [email protected]

Allison Moore(302) 995-4140 Hercules

[email protected] L. Moore

(302) 631-0314 Dade [email protected]

COUNCILORSAl Denio

(302) 455-0389 Emeritus [email protected]

Erin A. S. Doherty(302) 995-4191 [email protected]

John Gavenonis(302) 999-5600 DuPont

[email protected]

Narmada Gunawardena(302) 885-9516 AstraZeneca

[email protected] G. Hollomon(302) 995-3993 [email protected]

ALTERNATE COUNCILORSJoshua AyersAstraZeneca

[email protected] W. Henry

(410) 398-9484 Retired [email protected] Kissounko

(302) 831-0376 University of [email protected] Martin

(610) 499-4515 Widener [email protected]

Nora S. Radu(302) 695-3363 DuPont

[email protected]

“THE DEL-CHEM BULLETIN”IS PUBLISHED EIGHT TIMES A YEAR.

CIRCULATION– 2,400 COPIES PER ISSUE

Welcome to 2008 and a new year of chem-ical achievements in Delaware! I am look-ing forward to chairing the Delaware Sec-tion of ACS this year, so that we can worktogether to promote the chemical sciences.

We will kick off the year withour Delaware Section Awardsmeeting on January 30. Wewill honor two distinguishedDelaware chemists who havemade outstanding contribu-tions to chemical research andchemical education. Dr. Cecil

R. Dybowski will receive the DelawareACS Section Award for his achievementsin NMR spectroscopy, and will present atalk entitled, “A History of Magnetic Res-onance, with Echoes in Delaware.” Dr.Michael A. Stemniski will receive the Till-manns-Skolnik Award for his tirelessefforts in bringing chemistry to youngpeople, ensuring a new generation ofinspired chemists. The event will be heldat the Blue and Gold Club on the UD cam-pus, and all chemistry professionals, fac-ulty, and students are encouraged toattend.

Please also save the dates for our February22 section meeting on “Science and theLaw,” and our March 12 Carothers AwardDinner, as well as our next science café onMarch 6. One of my goals for this year isto increase the diversity of topics and par-ticipants at Delaware ACS section events,so that we can discuss relevant currentevents in chemistry, and strengthen rela-tionships between the Delaware ACS sec-tion and local universities.

Speaking of universities, this issue of theDel-Chem Bulletin also highlights animportant chemical milestone achieved atthe University of Delaware. Dr. KlausTheopold’s laboratory made the GuinnessBook of World Records for creating theworld’s shortest chemical bond betweentwo metals. This historic achievementconfirms that Delaware chemists are con-tinuing to play a pivotal role in theprogress of chemistry.

I am honored to serve as the chair of sucha talented professional group of chemists,and I welcome your ideas and suggestions.I wish you a very happy and successfulnew year. Let’s celebrate Delaware chem-istry together in 2008!

SSuujjaattaa BBhhaatt iiaaSSuujjaa ttaa BBhhaattii aa

INDEX OF ADVERTISERS

Bruker Daltronics . . . . . . . . . . .14Chemir . . . . . . . . . . . . . . . . . . .14ChemoDynamics . . . . . . . . . . .10DuPont . . . . . . . . . . . . . . . . . .15HPLC . . . . . . . . . . . . . . . . . . . . .2IQ Synthesis . . . . . . . . . . . . . .15Mass Vac . . . . . . . . . . . . . . . . .10Micron . . . . . . . . . . . . . . . . . . . . 6NuMega . . . . . . . . . . . . . . . . . .14Robertson Microlit . . . . . . . . . .15Schwarzkopf . . . . . . . . . . . . . .14

DDiirreeccttoorryy ooff SSeerrvviicceess

delchem Jan 08:DC 12/17/07 7:41 PM Page 06

Page 4: PresentationofDelawareSectionAwardtoDr.CecilR.Dybowski ...$10 per person for students For reservations or additional information: Please cont act Sujata Bhatia at: sujata.k.bhatia@usa.dupont.com

4 DEL-CHEM BULLETIN – JANUARY 2008 DEL-CHEM BULLETIN – JANUARY 2008 13

Delaware Section of the American Chemical SocietyJanuary General Meeting

Section Awards Dinner

Presentation of the Delaware Section and Tillmanns-Skolnik Awards

A History of Magnetic Resonance, with Echoes of DelawareDate: Wednesday, January 30, 2008

Location: Blue and Gold Club, Main Dining Room University of Delaware44 Kent WayNewark, DE 19716http://www.udel.edu/BGClub

Time: 6:00 PM – Registration & Social (cash bar in Tavern)6:30 PM – Dinner7:15 PM – Presentation by Dr. Cecil Dybowski

Cost: $20 per person for Delaware ACS members and guest$25 per person for non-ACS members$10 per person for students

For reservations or additional information: Please contact Sujata Bhatia at:[email protected] (preferred) or 302-695-8140 before noon on Monday,January 28, 2008. Reservations not cancelled by Monday, January 28, 2008 will be billed.

Abstract:Magnetic resonance spectroscopy has been intimately intertwined with fundamentaldevelopments in physics and chemistry during the last century. Without a doubt, NMRspectroscopy is nowadays a major analytical tool for chemists. There are few, if any, majorchemistry research centers that do not own and operate some sort of NMR facility or seekto have magnetic resonance spectroscopy available to their scientists. Yet, the origins ofmagnetic resonance are far removed from the routine analysis of materials arising fromchemical reactions, with which most chemists now associate this technique. Indeed, mag-netic resonance today is far more than simple analysis of materials; it is a lively, evolvingfield of study even sixty years after its discovery.The history of magnetic resonance shows the influence of war, of philosophical upheavalthat resulted in the development of the quantum theory of the world, of petty disagree-ments, of work on teams and in isolation, of the influence of government programs, andof the tug of commercialization of scientific work. In short, it mirrors many pivotal fac-tors that influence a wide variety of endeavors in science.In this history stand the people of magnetic resonance – spectroscopists who have spenttheir lives studying how spins whirl in their unending dance. I shall discuss various con-tributions, including those of scientists at the University of Delaware with whom I havehad the pleasure to associate over the years, which will hopefully put the efforts of mag-netic resonance spectroscopists into the larger context of the flow of ideas and develop-ments that characterized a time of seemingly limitless curiosity and boundless enthusiasmabout physics and chemistry.

UD Chemists Set World RecordChemists from the University of Delawareand coworkers have set a new world recordfor the shortest chemical bond everrecorded between two metals, break-ing a previous chemical record that stoodfor nearly 30 years. The record-breakingmetal-metal bond was achieved by form-ing multiple bonds between two atoms ofchromium. In this latest multiple-bond-ing advance, graduate student Kevin A.Kreisel and chemistry professor KlausH. Theopold of the University of

Delaware and coworkers synthesized a new type of quintuple-bonded dichromium complex,one that surpasses all known compounds for having the shortest measured metal-metal bondlength (J. Am. Chem. Soc., DOI: 10.1021/ja076356t).

In the complex, each chromium atom is coordinated to two nitrogenatoms, one each from two bridging diazadiene ligands containingdiisopropylphenyl groups. The result is a tight Cr2N4 core structure.The most noticeable feature is the very short 1.8028-Å Cr–Cr bond,which is the shortest metal-metal distance reported to date for anisolable compound. In collaboration with Clark R. Landis of theUniversity of Wisconsin, Madison, the researchers supported theirexperimental observations with calculations to confirm the bondingand electronic structure of the complex, including a bond order of 4.28.

Before the UD discovery, the previous record for the shortest metal-metal bond was 1.828-Å,achieved by F. Albert Cotton and coworkers at Texas A&M University in 1978 with a quadruple-bonded dichromium complex (Inorg. Chem. 1978, 17, 2084).

The Delaware Section of the American Chemical Society congratulates Dr. Theopold and hiscoworkers on this historic chemical achievement!

Chemistry students get unique opportunity to interview scientistsLeigh E. Thompson, Science Department, Tower Hill School, Delaware

During National Chemistry Week, chemistry students from Tower Hill School had theunique opportunity to interview scientists from the area to incorporate the theme, “TheMany Faces of Chemistry.” Over fifty scientists from AstraZeneca, DuPont, Agilent, TheUniversity of Delaware, and Colonial Metals participated in the project. The underlyingthemes of team work, communication, and pursuing an enjoyable career were prevalent ineach of the interviews. The students learned how chemistry is used on a daily basis, andthey gained valuable insight into possible careers they had not considered. I would like toextend a special thanks to all the scientists who participated in this project. It was certainlya valuable experience for my students.

delchem Jan 08:DC 12/17/07 7:41 PM Page 08

Page 5: PresentationofDelawareSectionAwardtoDr.CecilR.Dybowski ...$10 per person for students For reservations or additional information: Please cont act Sujata Bhatia at: sujata.k.bhatia@usa.dupont.com

Biography:Dr. Cecil Dybowski, Delaware Section Award WinnerDr. Cecil Dybowski is a Professor in the Department ofChemistry and Biochemistry at the University of Delaware.An expert on nuclear magnetic resonance spectroscopy, he hasauthored over 170 scientific publications that reflect his inter-est in using magnetic resonance to study diverse materials.He received his B.S. in Chemistry with honors from the Uni-versity of Texas at Austin, and his Ph.D. in Chemistry (con-centrating in Chemical Physics) from the University of Texasat Austin.Dr. Dybowski has served as a lecturer for an ACS short course on NMR spectroscopy, andhas served as the President of the Delaware Valley Section of the Society for AppliedSpectroscopy. He is on the editorial boards of Solid State Nuclear Magnetic Resonance,the Open Chemical Physics Journal, and Magnetic Resonance Reviews. He is an Asso-ciate Editor of Applied Spectroscopy, and a Section Editor for the Encyclopedia of Ana-lytical Chemistry. He has been a visiting scientist at the DuPont Company, as well as avisiting professor at the University of California at Berkeley, a distinguished visiting pro-fessor at the Jagiellonian University in Poland, and professeur associé at the UniversitéPierre et Marie Curie in France. He is a member of the Governing Board of the EasternAnalytical Symposium, and a member of several professional societies, including theAmerican Chemical Society, the American Physical Society, the Society for AppliedSpectroscopy, and the Delaware Academy of Chemical Sciences. He was elected a Fel-low of the American Association for the Advancement of Science in 2004. In addition tohis impressive accomplishments in chemistry, Dr. Dybowski is a composer and has writ-ten thirteen musical compositions.

Biography:Dr. Michael A. Stemniski, Tillmanns-Skolnik Award WinnerDr. Michael A. Stemniski is a Professor of Chemistry at theUniversity of Delaware, teaching general chemistry and organ-ic chemistry to diverse groups of students who desire to contin-ue their education. He has been involved in chemical educationin Delaware for over 36 years. Dr. Stemniski began his teach-ing career in Delaware in 1970 as a chemistry teacher at McK-ean High School; this was his primary teaching position until heretired from McKean in 2006. Dr. Stemniski has been teaching courses at the Universityof Delaware since 1972, and continues to teach in the Associate in Arts Program at theUniversity of Delaware Academic Center in Wilmington; the Continuing EducationDepartment in Wilmington; the Summer and Winter sessions in Newark; and SummerCollege in Newark. Dr. Stemniski also served as Adjunct Professor of Chemistry atDelaware Technical and Community College for 25 years.Dr. Stemniski received his B.S. in Chemistry from Villanova University and his Ph.D. inOrganic Chemistry from Fordham University. He then completed a Professional Teach-ing Certificate at the University of Delaware. In addition to teaching chemistry at thehigh school and university levels, Dr. Stemniski has performed several hundred sciencedemonstrations for students and adults at community events. Dr. Stemniski’s “ChemicalDemonstration Show” has entertained and enlightened many young children at theDelaware Section’s annual Chemistry for Kids event, as well as the annual NationalChemistry Week event. His service to the Delaware Section of the ACS in this capacityhas been invaluable. Outside of chemistry, Dr. Stemniski is an avid golfer.

DEL-CHEM BULLETIN – JANUARY 2008 512 DEL-CHEM BULLETIN – JANUARY 2008

Minutes of the Executive Committee Meeting continued from 11

Next Meeting:

The next meeting will be tentatively scheduled for December if necessary; contact J. Ayers

for details.

_______________________________

Attendance: Officers and Councilors present: Joshua Ayers, Brian Bidlingmeyer, Wayne

Brubaker, Al Denio, John Gavenonis, Narmada Gunawardena, Norman Henry

Officers and Councilors absent: Bill Barber, Howard Barth, Dean Brown, MargeChristoph, Martha Hollomon, Andrea Martin, Jeff Moore, Nora Radu

Others in Attendance: Tiffany Hoerter, Mike Stemniski, Lois Weyer

Respectfully submitted,

Joshua Ayers

2007 TopHigh SchoolChemistryTeacherAward

Congratulations!!Congratulations!!Delaware Section of the American Chemical

Society would like to CongratulatePatrick Carney who was awarded the 2007Top High School Chemistry Teacher award in

recognition of excellence in teaching high schoolchemistry at William Penn High School.

delchem Jan 08:DC 12/17/07 7:41 PM Page 010

Page 6: PresentationofDelawareSectionAwardtoDr.CecilR.Dybowski ...$10 per person for students For reservations or additional information: Please cont act Sujata Bhatia at: sujata.k.bhatia@usa.dupont.com

DEL-CHEM BULLETIN – JANUARY 2008 116 DEL-CHEM BULLETIN – JANUARY 2008

continued on page 12

Delaware Section of the American Chemical SocietyFebruary General Meeting

Images of Expertise in Litigation and RegulationDr. David Caudill, Villanova University Professor of Law

Date: Thursday, February 22, 2008

Location: Iron Hill Brewery710 South Madison StreetWilmington, DE 19801www.ironhillbrewery.com

Time: 6:00 PM – Registration & Social (bar available)6:30 PM – Dinner7:15 PM – Presentation by Dr. David Caudill

Cost: $20 per person for Delaware ACS members and guest$25 per person for non-ACS members$10 per person for students

For reservations or additional information:Please contact Sujata Bhatia at: [email protected] (preferred) or 302-695-8140 before noon on Monday, February 19, 2008. Reservations not cancelled byMonday, February 19, 2008 will be billed.

Minutes of the Executive Committee MeetingDelaware Section of the American Chemical Society

Tuesday, November 6, 2007, Buckley’s Tavern

Secretary’s Report:

The October 2007 meeting minutes were recorded by Joshua Ayers, accepted by the exec-utive committee by e-mail, and submitted to the Del-Chem Bulletin.Treasurer’s Report:The treasure’s report was postponed till a later date due to the absence of Bill Barber. Thereport may be circulated electronically.

Chair’s Report:

Narmada Gunawardena reviewed previous events. AstraZeneca visits the University ofDelaware was held on October 23rd and was attended by approximately 30 students andfaculty from chemistry and biochemistry, chemical engineering and material science. 12AstraZeneca PAR&D employees and 1 R&D college recruiter from AZ were present.Chemistry for Kids on October 20th was also held however no details were available. Additionally, Narmada spoke about the December meeting, which will be presented byKris McNeill from the University of Minnesota. The dinner and talk about photochemicalreactions in natural waters are scheduled for December 3rd at 5:30PM at the DelawareCountry Club. Contact Narmada for further details.Submissions for the January issue of the Del-Chem Bulletin will be due December 1st.Narmada will work with Sujata to ensure a smooth transition in the coordination of theDel-Chem duties.

Past Chair Report:

John Gavenonis reported that work continues for the National Chemistry Week OpenHouse. He has 9 confirmed tables and 3 potentials that have volunteered to present at theopen house. The event will take place Saturday November 10th at The IndependenceSchool. The theme this year is “The Many Faces of Chemistry ". John is continuing tosoliciting volunteers and has ordered supplies for the event. He plans to fill bags the weekbefore the event. Details of the event were discussed and the placement of tables andother details were decided. Several executive committee members are going to attend theevent and other members of the Delaware Section of the ACS have been encouraged toattend. Lois Weyer has done an excellent job as publicity chair, getting the word out toseveral scout troops and to local papers.

Committee Reports:• Books for Outstanding Chemistry Delaware High School Students: The letter to area

high schools was discussed for the 2008 awards. Publicity will be earlier for the 2008year and more participation is expected for the upcoming year. Small verbiage waschanged in the letter to reflect the importance of the recipient being a distinguishedchemistry student and the type of book purchase that would be reimbursed.

Other Business:None.

delchem Jan 08:DC 12/17/07 7:41 PM Page 012

Page 7: PresentationofDelawareSectionAwardtoDr.CecilR.Dybowski ...$10 per person for students For reservations or additional information: Please cont act Sujata Bhatia at: sujata.k.bhatia@usa.dupont.com

DEL-CHEM BULLETIN – JANUARY 2008 710 DEL-CHEM BULLETIN – JANUARY 2008

CHEMVETSCHEMVETSTOPIC:

SPEAKER: Dr. Parry Norling

DATE: Tuesday, January 22, 2008

PLACE: DuPont, Chestnut Run

TIME: 12:00 Lunch (Admin. Bldg.)1:00 Lecture (Bldg. 713 auditorium)

INFORMATION:George Parshall (658-2066)

BIOGRAPHY:Dr. Parry Norling retired as an R&D planning director at DuPont. He then served as Chair-man of the Industrial Research Institute. Parry has also been an AAAS Fellow at RANDCorporation's Science and Technology Policy Institute and an adjunct visiting professor atGeorgetown University. He is currently a Visiting Fellow at the Chemical Heritage Foun-dation, a convener of Delaware Dialogues on science, ethics, and religion, and an instruc-tor at the Academy of Life Long Learning. Recently he spoke on “In Innovation isPatience a Virtue?” at the YKI’s (Institute for Surface Chemistry’s) 2007 Member Days inStockholm. His chapter “Insights for R&D Managers” was included in Innovation, Sci-ence, and Institutional Change, Oxford University Press 2006.

ABSTRACT:Dr, Norling will discuss some aspects of Science and Religion:• To what extent is each of our theologies, religious beliefs, or worldviews being shaped

as scientific discoveries change our understanding of our world?• Will some discoveries destroy religious faith?• Do some discoveries neglect or dismiss the spirit?• Can new discoveries undermine or support human morality?• Will science turn out to be inadequate and arrogant in its limited picture of what

is true?• Can it be said that “evolution has hardwired mankind for a belief in or yearning for a

higher power and in turn that belief leads to a disbelief in evolution”?

He will draw from talks and presentations in the Delaware Dialogues on Science Ethicsand Religion series (www.cil-de.org), which has been supported in part by the MetanexusInstitute. The discussion may touch upon: Evolution vs. Intelligent Design, Stem Cells, theunholy alliance of Medical practice and Religion, neuroscience and the soul, Daoism andthe parallels with modern science, and spirituality and health

NEXT MEETING:Tuesday, February 19, 2008. George Parshall will speak on “The Dilemma of DualUse Chemicals.”

DDiirreeccttoorryy ooff SSeerrvviicceess

delchem Jan 08:DC 12/17/07 7:41 PM Page 014

Page 8: PresentationofDelawareSectionAwardtoDr.CecilR.Dybowski ...$10 per person for students For reservations or additional information: Please cont act Sujata Bhatia at: sujata.k.bhatia@usa.dupont.com

DEL-CHEM BULLETIN – JANUARY 2008 98 DEL-CHEM BULLETIN – JANUARY 2008

COMBINED MEETINGProcess Spectroscopy Topical Group/Society for Applied Spectroscopy

From Miniaturized Infrared Sensors to Multifunctional Scanning Probes:Combined Techniques for Enhanced Information

Boris Mizaikoff and Christine Kranz, Georgia Institute of Technology

Date: Friday, February 1, 11:30-2:00; presentation begins at 12:15 PM

Location: Agilent Little Falls Site, 2850 Centerville Rd., Wilmington, DE

Cost: We will use the Agilent cafeteria – typical lunches cost $5-10

Reservations/questions: Call Lois Weyer at 410-392-1273 or email: [email protected]. We need to have guestnames by close of business Thursday, January 31.

AbstractOptical chemical sensor technology in the mid-infrared (MIR) spectral range (3-20 µm) is gaining importancein process monitoring, environmental analysis, security/surveillance applications, and the biomedical field, dueto the increasing demand for robust sensor technology with inherent molecular specificity. Interfacing IR-trans-ducers with continuous measurement situations in the gas and liquid phase becomes increasingly feasible withthe advent of appropriate waveguide technology (e.g., MIR transparent optical fibers and planar waveguides),protective surface coatings (e.g. diamond-like carbon, sol-gels, polymers, etc.), and the availability of advancedlight sources such as room-temperature operated quantum cascade lasers (QCLs) leading to miniaturized IRdiagnostics. Selected examples will highlight recent advances in miniaturizing IR sensor technologies alongwith application examples including extreme environments (e.g., deep sea), and biomedical analysis (e.g., in-vivo surgical monitoring). Recent developments in scanning probe microscopy (SPM) are focusing on the combination of individual SPMtechniques, or on the combination with optical techniques to expand the information content accessible at thenanoscale. In particular, combined AFM-SECM (Atomic Force-Scanning Electrochemical Microscopy) probeshave gained considerable interest for simultaneously providing topographical and laterally resolved electro-chemical information during AFM imaging. Combined SPM probes with an electroactive area integrated intothe AFM probe enable applying a potential to the integrated electrode and recording Faradaic currents resultingfrom electroactive surface processes, such as e.g., corrosion or biological redox activity. These processes can be(electro)chemically detected with spatial resolution, and directly correlated to the topographical informationobtained by the AFM measurement.Consequently, the next-generation of multi-functional analytical platforms ideally combines the benefits of scan-ning probe techniques, electrochemistry, and IR spectroscopy into a unique analytical tool, which will be dis-cussed for the first combination of MIR attenuated total reflection (ATR) spectroscopy with AFM enabling mon-itoring the sample topology at nanometer scales, while simultaneously probing bulk spectroscopic properties.

BiographiesDr. Boris Mizaikoff received his Ph.D. in Analytical Chemistry at the Vienna University of Technology in 1996.Since fall 2000 he has been a faculty member at the Georgia Institute of Technology, School of Chemistry andBiochemistry, heading the Applied Sensors Laboratory (ASL). Today, his research interests focus on opticalsensors, biosensors and biomimetic sensors operating in the mid-infrared spectral range, novel IR light sources(e.g. quantum cascade lasers), system miniaturization and integration based on micro- and nanofabrication,multifunctional scanning nanoprobes (e.g. combination AFM-SECM, NSOM-SECM), scanning probe tip inte-grated nano(bio)sensors, focused ion beam techniques, development of chemical recognition layers for separa-tion and sensing applications (e.g. molecularly templated materials, functionalized sol-gels), chemometric dataevaluation, advanced vibrational spectroscopic techniques including SEIRA and SERS, environmental analyti-cal chemistry, process analytical chemistry, and biomedical diagnostics. Dr. Christine Kranz received her M.S. and Ph.D. degrees in chemistry from Ludwig-Maximilians University inMunich (1992) and Technical University of Munich (1996), Munich, Germany, respectively. After spending ayear as a postdoctoral fellow at Vienna University of Technology, Institute of Analytical Chemistry (Austria),she accepted a position at the School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta,where she is currently appointed as senior research scientist.

DirectionsAgilent is off of Centerville road just south of the intersection with Lancaster Pike (rt. 48). Follow directionsto the lobby and park in front or to the side. Pick up your Visitor badge in at the front desk. The cafeteria isstraight ahead as you enter. Take your lunch to the seminar room (Pennsylvania Room) which is down the hallon the right (looking at the cafeteria entrance).

Another Year Already?Another Year Already?Al Denio, Section Councilor

National Chemistry Week Open HouseWe held this annual outreach event on

November 10 at The Independence School.As President of the Delaware Academy ofChemical Sciences, I organized a displaytable on DuPont’s super strong fiberKevlar. This is the fiber used in bulletproofgarments used to protect our police andmilitary members. It is truly a life savingproduct of DuPont research.The basic discovery was made by

Stephanie L. Kwolek at the PioneeringResearch Laboratory of the Textile FibersDepartment at the Experimental Station.After this event in 1965, it took anotherfive years and the work of many chemistsand engineers before Kevlar was availablecommercially.I called Stephanie and asked if she

would help at our table from noon until 3pm. She graciously agreed to come. Infact, she was the “star of the show.” Shebrought some Kevlar fabric which was cutinto small swatches and then autographedusing a felt-tip pen. This was provided toyoung people along with a single pagehandout on Kevlar.Norm Henry, our Vice President, assist-

ed Stephanie by preparing the fabricswatches. Martha Hollomon arranged forthe loan of a Kevlar vest and Solito Sumu-long provided some Kevlar gloves.Most of the young students who visited

our Kevlar table were in awe to meet thewoman whose great discovery is savinglives every day. I wonder how many ofthese students will be the chemists oftomorrow.

Save The DateThe Delaware Academy of Chemical

Sciences will hold “The Three LegendsLuncheon” on April 3 at the DuPont Coun-try Club. All three “legends” are fromDuPont’s former Textile Fibers Departmentof the last century: Stephanie L. Kwolek,Joe Labovsky and Russ Peterson. Detailswill follow soon.

ACS Government Affairs Committee SummitMartha Hollomon and I represented the

Delaware Section at this event on Novem-ber 12 and 13 in Washington. She alsogave a presentation as part of the trainingprogram. On the 13th we were paired witha member from Michigan and another fromSouth Carolina for a series of visits tooffices in the House and Senate. Ourschedule included the offices of SenatorsBiden, Carper and DeMint (S. Carolina)plus Representatives Castle, Upton (Michi-gan) and Inglis (S. Carolina).We urged support of “robust funding

measures” for NSF, NIST, DOE Scienceand NSF’s educational programs. I’d liketo think we made a favorable impressionbut time will tell.In February we have our annual “Contact

Congress Week” when I organize visits tothe offices of Biden, Carper and Castle.Please contact me if you would like to par-ticipate.

Chemistry and Falling LeavesAs I write this in late November, I pon-

der the problem of falling leaves and myefforts to remove them from our lawn. Yes,the exercise (work) is good for me but myback hurts. We need to quickly solve theproblem of converting this cellulosic mat-ter into ethanol. The leaves in our yard,with the proper chemistry, could make fora hell of a party. I’d prefer a still in our yardrather than a compost pile.

Thank YouMy thanks go to Narmada, John, Sujata,

Josh and Bill for a good 2007 for theDelaware Section, and to all the others whohelped in a variety of ways with our pro-grams and special events. Good luck toSujata as she leads us into the New Year. Ihope to see you all at the January meeting.

delchem Jan 08:DC 12/17/07 7:41 PM Page 016